JP6168543B2 - Glass collision prevention safety mark and glass collision prevention safety mark construction method - Google Patents

Description

  The present invention relates to a glass collision prevention safety mark and a method for constructing a glass collision prevention safety mark.

  Conventionally, as a glass collision prevention safety mark for preventing a passerby from accidentally colliding with a sheet glass such as a doorway of a building, there has been known, for example, the one shown in Patent Document 1. However, since the safety mark uses a resin-made phosphorescent fluorescent material in which a phosphorescent agent is kneaded with a synthetic resin, further improvement of weather resistance is desired.

  On the other hand, for example, a method as shown in Patent Document 2 is known as a method of manufacturing a phosphorescent material. However, in this manufacturing method, the paste-like mixture has to be laminated by repeating screen printing a plurality of times, and the work is complicated. Further, since the paste-like mixture contains medium, if the medium remains in the phosphor, it becomes dark and there is a possibility that the light emission performance may be deteriorated.

Japanese Patent Laid-Open No. 2006-330551 JP 2012-106918 A

  In view of such conventional circumstances, the present invention has an object to provide a glass collision prevention safety mark and a method for constructing the glass collision prevention safety mark that can be easily and efficiently manufactured without deteriorating light emitting performance. And

In order to achieve the above-mentioned object, the glass collision prevention safety mark according to the present invention is characterized by having a drop-shaped main body made of only a phosphorescent pigment and a glass material, and the main body is outward from the edge of the flat bottom surface. A bulging portion that rises in an arc shape so as to curve toward the center, and an R-shaped portion whose upper surface is curved toward the center from the bulging portion, and the bottom surface is a bonding material whose one side is bonded to a sheet glass It is in having.
Furthermore, it is good for the said sticking material to provide the caulking material with which the clearance gap between the said bulging part and the said plate glass is filled in the circumference | surroundings.

  According to the said structure, since it heats and melt | dissolves glass material, a powdery substance will become liquid state with the melt | dissolved glass material, and surface tension will generate | occur | produce. The surface tension is a tension acting along the surface so that the surface shrinks itself to have as small an area as possible, and the liquefied glass material tends to shrink. As described above, the glass material is liquefied by heating to generate surface tension, whereby an R-shaped portion having a rounded upper surface by the surface tension can be formed.

  The bottom surface may have minute unevenness. The particle size of the phosphorescent pigment is preferably larger than the particle size of the glass material. By increasing the particle diameter of the phosphorescent pigment, more light can be accumulated and the light emission performance is improved. In addition, by reducing the particle size of the glass material, the glass material is easily dissolved, surface tension can be generated at a relatively low temperature, and the heating time can be shortened. In such a case, the particle diameter of the phosphorescent pigment is preferably 120 μm or more and 300 μm or less, and the particle diameter of the glass material is preferably 20 μm or more and 40 μm or less. If it is in the said numerical range, many glass materials will exist around the phosphorescent pigment, the glass material melt | dissolved by the heating will surround the phosphorescent pigment, and a glass material will spread among the phosphorescent pigments. Further, the surface becomes smooth due to the surface tension of the liquefied glass material. Therefore, light from the outside can be efficiently taken into the inside, and more light can be efficiently emitted even during light emission, so that the light emission performance can be further improved.

  The powdery material may be obtained by mixing and stirring the phosphorescent pigment and the glass material at a weight ratio of 5:95 or more and 25:75 or less. If it is in the said numerical range, sufficient light can be accumulate | stored with a phosphorescent pigment, the light emission (luminous accumulation) performance can be ensured, and the surface tension which forms R shape part on an upper surface with glass material can be produced. Moreover, the surface can be smoothed by the surface tension.

In order to achieve the above object, the glass collision prevention safety mark construction method according to the present invention is characterized in that it has a drop-shaped main body made of only a phosphorescent pigment and a glass material, and the main body has a flat bottom edge. A bulging portion that rises in an arc shape so as to curve outward from the ridge, and an R-shaped portion whose upper surface is curved toward the center from the bulging portion, and one side of which is attached to the plate glass on the bottom surface An object is to provide an adhesive and to adhere the main body to the plate glass with the adhesive.
In such a case, a caulking material may be filled in a gap between the bulging portion around the adhesive material and the plate glass.

  According to the characteristics of the glass collision prevention safety mark and the glass collision prevention safety mark according to the present invention, it has become possible to provide simply and efficiently without reducing the light emitting performance.

  Other objects, configurations, and effects of the present invention will become apparent from the following embodiments of the present invention.

It is a figure which shows the granular luminous body which concerns on this invention, (a) is a front view, (b) is a rear view. It is a photograph which shows the state (before a heating) with which the granular material was filled in the sheath. It is a photograph which shows the state of the granular luminous body inside the sheath after a heating. It is a figure explaining a heating process. It is a figure explaining the effect | action of the surface tension at the time of a heating. It is a figure which shows the Example of a granular luminous body, (a) is an example of the mark for evacuation guidance, (b) is a figure which shows an example of the glass collision prevention safety mark. It is a figure which shows an example of construction of a safety mark.

Next, the present invention will be described in more detail with reference to the accompanying drawings as appropriate.
As shown in FIG. 1, the granular phosphor 1 according to the present invention has a drop shape containing a phosphorescent pigment and glass frit as a glass material. The bottom surface 11 of the granular phosphor 1 is a substantially flat surface, and minute irregularities (rough surfaces) are formed on the surface by a bottom surface 31 of the heating container 3 described later. Then, an R-shaped portion 13 is formed which bulges outward from the edge of the bottom surface 11 and bulges upward from the bulged portion 12 toward the center so as to be curved as a whole.

  Here, as the phosphorescent pigment, for example, a pigment obtained by adding and firing a rare earth element activator and a coactivator containing an alkaline earth metal aluminate compound as a main component is used. Examples of the alkaline earth metal include at least one metal element such as calcium, strontium, and barium, and alloys of these metal elements and magnesium. Examples of the rare earth element activator include europium and dysprosium. Examples of the coactivator include elements such as lanthanum, cerium, praseodymium, neodymium, samarium, cadmium, terbium, and dysprosium. In addition to the oxide phosphors described above, phosphorescent pigments include CaS: Bi (purple blue light emission), CaSrS: Bi (blue light emission), ZnS: Cu (green light emission), ZnCdS: Cu (yellow to orange light emission). It is also possible to use sulfide phosphors such as In addition, you may use the above-mentioned compound by mixing suitably, Furthermore, what has a luminous property in another inorganic fluorescent pigment or an organic fluorescent pigment can also be used.

  The material of the glass frit is, for example, at least one alkaline earth metal selected from the group consisting of silicon oxide, aluminum oxide, boron oxide and alkali oxide, and selected from the group consisting of calcium oxide, strontium oxide and magnesium oxide. Those containing oxides are used. The material of the glass frit is not limited to the above material, but a material that melts (liquefies) the above phosphorescent pigment at a temperature at which it can exist as a solid may be used. Further, it is desirable to use a glass frit material with high transparency after heating. The light emission of the phosphorescent pigment is not hindered and the light emission performance is prevented from being lowered.

  The particle size of the phosphorescent pigment is desirably 120 μm or more and 300 μm or less. When the particle size is less than 120 μm, light cannot be stored sufficiently because the particles are small, and the light emission (light storage) performance is lowered. On the other hand, when the particle size exceeds 300 μm, the light emission (light storage) performance can be ensured, but the particles of the light storage pigment become large and the surface of the R-shaped portion 13 cannot be molded smoothly. The particle diameter of the phosphorescent pigment is preferably 170 μm or more and 250 μm or less. The “particle size” shown in the present specification indicates the value of the average particle size d50 in the particle size distribution.

  The particle size of the glass frit is preferably 20 μm or more and 40 μm or less, and the particle size of the glass frit is smaller than the particle size of the phosphorescent pigment. By reducing the particle size of the glass frit, a granular phosphor can be produced by heating at a relatively low temperature of 780 to 800 ° C., and the heating time is about 2 to 5 hours. In addition, since many glass frit particles can exist around the phosphorescent pigment, the glass frit can be introduced between the phosphorescent pigment particles by heating. Therefore, the light from the outside can be more efficiently transmitted to the inside of the phosphor, and more light can be emitted even during light emission. In this embodiment, for example, a phosphorescent pigment having a particle diameter of 250 μm is used, and a glass frit having a particle diameter of 30 μm is used.

Here, the manufacturing process of the granular phosphor 1 will be described.
First, a powdery phosphorescent pigment and a powdery glass frit are mixed and stirred to prepare a powdery product 2. The phosphorescent pigment and the glass frit are mixed and stirred at a weight ratio of 5:95 or more and 25:75 or less. Preferably, the weight ratio of the phosphorescent pigment to the glass frit is 10:90 or more and 20:80 or less. If it is in this numerical range, it can shape | mold into the R shape which curved the upper surface with the surface tension at the time of melt | dissolution of the powdery material 2 at the time of the heating in the heating furnace 4, without reducing the light emission performance by a phosphorescent pigment. The powdery product 2 is very easy to manufacture because it only needs to mix and stir two kinds of powders, a powdery luminous pigment and a powdery glass frit. In addition, since there is no need to mix liquid medium, there is no possibility of deterioration in light emission performance due to darkening caused by an organic solvent such as medium remaining after heating. In addition, the powdery material 2 of this embodiment is obtained by mixing and stirring the phosphorescent pigment and the glass frit at a weight ratio of 10:90.

  Here, Table 1 shows an example of the blending ratio of the phosphorescent pigment and glass frit (phosphorescent pigment: glass frit) and the results of the molded state and surface state of the R-shaped portion 13. The sample 1 (Sample 1) was a phosphorescent pigment (particle size 250 μm, green) manufactured by Nemoto Materials, and the sample 2 (Sample 2) was a phosphorescent pigment (particle size 250 μm, blue) manufactured by Ryojo. In the table, ◎ indicates that both the surface smoothness and the arc shape are good, ○ indicates that there is a roughness only in a part or a shape defect only in a part, △ indicates that there is an overall roughness, × Indicates an overall shape failure.

  When the blending ratio of the phosphorescent pigment and the glass frit is 4: 6, the glass frit is relatively small. Therefore, the bulging portion 12 is not smoothly curved outwardly and is gently upward. Many of the R-shaped portions 13 curved in a convex shape were not formed. In addition, since there are relatively many phosphorescent pigments, many of these surfaces did not become smooth. When the blending ratio is 3: 7, the glass frit is relatively increased, so that the bulging portion 12 is curved outward and the R-shaped portion 13 that curves upward is also molded. However, the surface was not smooth and was generally rough. At a mixing ratio of 2: 8, when the temperature was 750 ° C., the entire surface was rough and not smooth. On the other hand, at 800 ° C. or higher, the bulging portion 12 and the R-shaped portion 13 were molded and the surfaces thereof became smooth in many portions. And, when the blending ratio is 1: 9 and 0.5: 9.5 and 800 ° C. or higher, the glass frit is relatively large, so that it can be molded at a low temperature in a short time compared to others, and the surface smoothness The curved (arc) shape of the R-shaped portion 13 was also good. However, when the blending ratio exceeds 1: 9, the luminous pigment (relatively low in luminance) is slightly reduced because the phosphorescent pigment is relatively reduced.

  Next, as shown in FIG. 2, the prepared powdery substance 2 is filled in a heating container 3. As the heating container 3, an unglazed sheath made of clay is used. The sheath 3 is fired at about 1300 ° C. Therefore, even if the powdery material 2 is filled in the sheath 3 and heated, the powdery material 2 and the sheath 3 do not chemically react and do not affect the light emitting performance. In the present embodiment, the sheath 3 has a tapered shape in which the upper portion is widened. For example, the upper opening has a diameter of 25 mm and the bottom has a diameter of 22 mm. Further, minute irregularities are formed on the surface of the bottom surface 11 of the granular phosphor 1 by the bottom surface 31 of the sheath 3. Accordingly, for example, when the granular phosphor 1 is used for a glass collision prevention safety mark, the adhesion can be improved by the unevenness.

  Before filling the sheath 2 with the powdery material 2, a release agent is attached to the inner surface of the sheath 3 by spray coating. Thereby, the mold release layer 32 can be easily formed substantially equally. As described above, since the sheath 3 has a small diameter, it is difficult to form the release layer 32 substantially uniformly with a brush or a brush. In the non-uniform release layer 32, the mixture filled accordingly becomes non-uniform in the radial direction of the sheath 3. Therefore, a difference occurs in the surface tension due to the melted glass frit, and the shape to be molded is distorted. Providing the release layer 32 prevents the heated powder 2 from adhering to the inner surface of the sheath 3 and facilitates the recovery of the granular phosphor 1 after heating. For example, as a release agent that can be applied by spraying, a compound containing boron nitride (BN) is used.

  Then, as shown in FIG. 4, a plurality of sheaths 3 filled with the powdery material 2 are placed on the shelf plate 41 of the heating furnace 4 and placed in a kiln, and heated at a predetermined temperature. Here, the surface tension is a tension acting along the surface so that the surface of the liquid contracts itself to have as small an area as possible. As shown in FIG. 5, when the powdery material 2 is heated, the powdery glass frit is melted to become a liquid glass component, and surface tension F is generated. On the other hand, the luminous pigment has a higher melting point than the glass frit, and exists as a solid at the melting temperature of the glass frit. Therefore, this surface tension F changes with the content rate of glass frit.

  By the way, as shown in the said Table 1, when heating temperature is 850 degreeC or 900 degreeC, the surface smoothness and the curved shape of the bulging part 12 and the R-shaped part 13 become favorable. However, the phosphorescent performance of the phosphorescent pigment decreases as the heating (firing) temperature increases. Therefore, the heating temperature is 900 ° C. or lower, preferably 850 ° C. or lower. On the other hand, since roughness occurs on the surface at 750 ° C., the temperature is more preferably 750 ° C. and 800 ° C. or less. For example, the heating temperature is adjusted at 780 ° C to 800 ° C.

  The powdery material 2 in this embodiment is obtained by stirring and mixing a powdery phosphorescent pigment and a powdery glass frit at a ratio of 1: 9. The glass frit melts at a low temperature of about 700 ° C., and a surface tension F as shown in FIG. 5 is generated. As shown in FIG. 5, the powdery product 2 is rounded at each side and corner by the surface tension F, and a bulging portion 12 is formed at the periphery. Moreover, since the entire powdery material 2 is reduced to the center (center of the sheath 3) by this surface tension F, the contact portion between the powdery material 2 and the sheath 3 is only the bottom surface 31 of the sheath. Then, an R-shaped portion 13 is formed which rises in an arc shape so that the edge of the contact portion curves outward, and the upper surface is curved from the bulging portion 12 toward the center. After heating for a predetermined time, the shelf board 41 is taken out by slow cooling. The taken-out heated granular phosphor 1 is formed as shown in FIG.

  In this way, the formed granular phosphor 1 is attached to a glass plate 50 such as a doorway of a building, for example, as shown in FIG. It can be implemented as the safety mark 1A. In addition, as shown in FIG. 5B, it is embedded so that the R-shaped portion 13 on the upper surface is exposed along the passages 60 of various buildings such as houses, factories, stores, warehouses, etc. It can also be implemented as an evacuation guidance mark 1B that guides etc. to the doorway.

  Here, the glass collision prevention safety mark 1A as the granular phosphor 1 has a bulging portion 12 formed at the edge thereof. As a result, as shown in FIG. 7, when the glass collision prevention safety mark 1 </ b> A is adhered to the plate glass 50, a gap S is formed between the bulging portion 12 and the plate glass 50. What is necessary is just to fill the material 51, workability | operativity is good, and intensity | strength improves. In addition, as described above, the back surface 11 of the granular phosphor 1 is formed with minute irregularities. Therefore, the adhesiveness between the glass collision prevention safety mark 1A and the adhesive material 52 becomes good, and the adhesive strength is also improved. Thus, the granular phosphor of the present invention can be suitably used as each safety mark without any special processing.

Next, the possibility of another embodiment will be mentioned finally. In the following embodiments, the same members and the like as those in the above embodiments are denoted by the same reference numerals.
In the above embodiment, as the heating container 3, an unglazed sheath made of clay is used. However, the heating container 3 is not limited to the unglazed container as described above, and may be made of various ceramics such as a glazed container or alumina as long as it does not affect the phosphorescent performance after heating. It is also possible to use other containers. However, in the case of a metal, heat resistance is not sufficient because carbonization occurs at about 800 ° C. and the surface becomes rough. A tungsten container may be used, but it is expensive. The above embodiment is excellent in these points.

  In the said embodiment, the mold release layer 32 was formed by spray application of the mold release agent. However, as long as the release layer 32 can be formed uniformly, the present invention is not limited to spray coating. For example, the release layer 32 may be formed by means such as brush coating or brush coating. In such a case, as the release agent, for example, a liquid containing refractory clay, refractory alumina powder, ceramic powder, or the like is used. Of course, as long as the release layer 32 can be formed substantially uniformly, the release agent may be formed on the inner surface of the heating container by other means.

  The “granular phosphor” in the present invention is one having a size such that the glass frit dissolves by heating and is formed as one lump including a phosphorescent pigment, and the lump (phosphorescence) can be visually recognized as a lump alone. Point to.

  INDUSTRIAL APPLICABILITY The present invention can be used as a glass collision prevention safety mark and a glass collision prevention safety mark construction method. Since the present invention comprises a phosphorescent pigment and glass frit, it is excellent in weather resistance, water resistance, heat resistance, friction resistance and chemical resistance, and can be used not only indoors but also outdoors for a long time. In addition to the glass collision prevention safety mark, the granular phosphor can be used as a safety mark such as an evacuation guidance mark installed on the floor or wall of a building, for example. Further, for example, it can be used as an accessory such as an artificial jewel.

1: granular phosphorescent material, 1A: glass collision prevention safety mark, 1B: evacuation guidance mark, 2: powdery material, 3: sheath (heating container), 4: heating furnace, 11: bottom surface, 12: bulging part , 13: R-shaped part, 31: bottom surface, 32: release agent (release layer), 41: shelf board, 50: plate glass, 51: caulking agent, 52: adhesive material, 60: passage, F: surface tension , S: gap

Claims (5)

It has a drop-shaped main body consisting only of phosphorescent pigment and glass material,
The main body includes a bulging portion that rises in an arc shape so as to curve outward from an edge of a flat bottom surface, and an R-shaped portion having a curved upper surface from the bulging portion toward the center,
The bottom surface is a glass collision prevention safety mark having a sticking material whose one side is stuck to a plate glass. 2. The glass collision prevention safety mark according to claim 1, wherein the sticking material includes a caulking material filled in a gap between the bulging portion and the glass sheet around the sticking material. The glass collision prevention safety mark according to claim 1 or 2, wherein the bottom surface has minute irregularities. It has a drop-shaped main body consisting only of phosphorescent pigment and glass material,
The main body includes a bulging portion that rises in an arc shape so as to curve outward from an edge of a flat bottom surface, and an R-shaped portion having a curved upper surface from the bulging portion toward the center,
Provide a sticking material that one side is stuck to the plate glass on the bottom surface,
A construction method of a glass collision prevention safety mark in which the main body portion is adhered to the plate glass by the adhesive material. The construction method of the glass collision prevention safety mark of Claim 4 which fills the clearance gap between the said bulging part around the said sticking material and the said sheet glass with a caulking material.

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