CN1521214A - Process for preparing luminous wax product - Google Patents
Process for preparing luminous wax product Download PDFInfo
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- CN1521214A CN1521214A CNA031019838A CN03101983A CN1521214A CN 1521214 A CN1521214 A CN 1521214A CN A031019838 A CNA031019838 A CN A031019838A CN 03101983 A CN03101983 A CN 03101983A CN 1521214 A CN1521214 A CN 1521214A
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Abstract
The present invention relates to the making process of one kind of luminescent wax product. The luminescent wax product is produced through mixing luminescent material and heated and molten wax, deposition into mold, vacuum defoaming, cooling to form and demolding. The luminescent wax product may have proper form and color and thus become one wax made artistic work showing features at day and night. The present invention raises the application potential and value of wax.
Description
Technical field
The present invention has a luminiferous wax work manufacture method about a kind of, and it refers to a kind of manufacture method of wax work especially, and it is to utilize to add luminescent material in manufacture craft, makes it produce a kind of have luminiferous wax artwork or related products.
Technical background
The phenomenon that the material absorbing energy is emitted light is called luminous (Luminescence), owing to involve the difference of electron energy transition and spin behind this material irradiation, luminescence phenomenon can be divided into fluorescent (Fluorescence) and phosphorescence (Phosphorescence) two classes; And the formation unit of this type of luminescent material has comprised the active center (Activator) of host lattice (Host Lattice) and transition metal ion based on mineral compound, adds another kind of composition sometimes and increase luminosity and efficient in lattice.Luminescent material is mainly used in based on the photoelectricity of electroluminescence and the information related industries, fluorescent lamp, LED, screen backlight etc. as everyone knows, and wherein luminous efficiency is high and be referred to as phosphor body (Phosphors) the visible region person.
Tool holds photosensitiveness phosphor body (generally claiming phosphorescent substance) and excites with daylight (or being equivalent to other energy of ultraviolet outside) irradiation, in stop to excite the back with naked eyes the Yu brightness (After Glow) of (several 10 minutes to a few hours) still visible the reasonable time, commonly use the long timeliness phosphorescent substance of tool and be mainly Cu or the adulterated zinc sulphide of Co, it can send the green glow that wavelength is 530nm after uviolizing, the light of this section wavelength is the most responsive zone of human eye, so often be applied to making the dark display material time display of clock and watch (as be used for), and be to increase its phosphorescence fluorescent lifetime, it is radioactive often to add tool
3H or
147Pm; Be the consideration of environmental protection, nearest Japanese such as mountain, a village justice man of virtue and ability of special chemical limited-liability company at all discloses (No. the 076319th, TaiWan, China patent of invention) with MAl
2O
4(M is Ca, Sr, Ba) is the compound of parent, by adding 0.001 mole simultaneously more than the %, 10 moles of following europiums (Eu) of % are activator at least a element (being selected from cerium, praseodymium, neodymium, samarium, yttrium, dysprosium, erbium, ytterbium, gold-plating, manganese, tin, bismuth) below activator and the same range as mole number.This new phosphorescent substance is after the ultraviolet ray and radiation of visible light with 200-450nm under the room temperature, it holds the more traditional zinc sulphide (ZnS) of photosensitiveness (Yu brightness time) for long, and this new compound is not had a radioactivity, more difficult and airborne moisture effect, except that can be applicable to indoor demonstration, also can be used in outdoor.
Again, from MAl
2O
4For after the phosphorescent substance on basis is found, now developed the product of multiple practicality, as night the emergency exit indicate, night pedestrains safety clothes, toy etc., yet these a little products are all plasthetics.Traditional practice is with MAl
2O
4Phosphorescent substance mixes ejection formation again with the plastic cement particle through heating, and these a little products are subject to the characteristic of plastic cement itself, can't make exquisite artwork etc.
Therefore, how to propose a kind of novelty and have luminiferous wax work manufacture method at the problems referred to above, not only can improve on traditional artwork that the luminous material is not applied to close with wax phase, can get again daytime the tool plastic arts and night the tool characteristics of luminescence wax work, be not to use for a long time the thing that the person eagerly looks forward to and the inventor is intended to solve always, and the inventor is based on the research of engaging in wax product related products for many years, exploitation, and sale practical experience, it is the idea of thinking and improveing, poor its people's expertise, through research and design in many ways, special topic is inquired into, finally work out the luminiferous wax work manufacture method of having of a kind of improvement, can solve the above problems.
Summary of the invention
Main purpose of the present invention, be to provide a kind of luminiferous wax work manufacture method that has, it is to add a luminous material in wax work, wax work with the tool characteristics of luminescence that is applied to make various exquisitenesses, to make the tool luminous artwork of various exquisitenesses, promote the potential market that wax phase closes product by manufacture method of the present invention.
Secondary objective of the present invention is to provide a kind of luminiferous wax work manufacture method that has, and making method of the present invention is simple and easy, but mass production, so the product of gained has more the industry using value.
Another purpose of the present invention is to provide a kind of luminiferous wax work manufacture method that has, and this wax work can be according to suitable shape-designing, is made into a wax artwork or a candle finished product that day and night has characteristic concurrently.
The present invention be with the phosphorescent substance of the tool characteristics of luminescence (or fluorescent material) be heated the fusion the wax uniform mixing after, this mixing solutions is poured in the mould, again through the moulding of vacuum froth breaking cooling curing, after the demoulding, get final product the luminiferous wax work of tool.Manufacture craft of the present invention is simple and easy, easily mass production.
Description of drawings
Fig. 1: it is the manufacturing flow chart of a preferred embodiment of the present invention;
Fig. 2: it is SrAl
2O
4: Eu, Dy type phosphorescent substance and wax phase are that (a) that mix gained tool phosphorescent wax work at 100: 100 excites and (b) emmission spectrum figure to weight ratio (%);
Fig. 3: it is SrAl
2O
4: Eu, Dy type phosphorescent substance and wax phase are to mix (a) X-ray diffraction collection of illustrative plates of gained tool phosphorescent wax work and (b) standard SrAl at 100: 100 to weight ratio (%)
2O
4: the X-ray diffraction collection of illustrative plates of Eu, Dy powder;
Fig. 4 A: it is SrAl
2O
4: Eu, Dy type phosphorescent substance are X with wax phase to weight ratio (%): the wax work that 100 (wherein X is 2,5,10,20 and 100) are mixed gained absorbs daylight or ultraviolet synoptic diagram daytime;
Fig. 4 B: it is SrAl
2O
4: Eu, Dy type phosphorescent substance are X with wax phase to weight ratio (%): the wax work that 100 (wherein X is 2,5,10,20 and 100) are mixed gained is emitted the synoptic diagram of phosphorescence in the dark place; And
Fig. 5: it is SrAl
2O
4: Eu, Dy type phosphorescent substance and Maitreya Buddha's artwork of wax mixing gained are emitted the photomap of phosphorescence in the dark place.
The explanation of preferred embodiment
Further understand and understanding for constitutional features of the present invention and the effect reached are had, sincerely help with preferred embodiment and cooperate detailed explanation, be described as follows:
The present invention is because commonly use the deficiency of tool luminous plastic cement products, and not being applied to the special applications of wax on artwork is worth, by making method of the present invention, painted through suitable shape-designing or wax product, can get daytime tool appearance art and night the tool characteristics of luminescence candle product, can be applicable to make the tool luminous artwork of various exquisitenesses, promote the potential value that wax phase closes product.
See also Fig. 1, it is the manufacturing flow chart of a preferred embodiment of the present invention; As shown in the figure, the present invention refers to the making method of the luminiferous wax work of a kind of tool especially, and its key step includes at least:
In step 10, this luminous material is one of them person who is selected from a phosphorescent substance or a fluorescent material and combination thereof, and this phosphorescent substance is a strontium alumina type (SrAl
2O
4), zinc sulphide type (ZnS) or the identical fluorescent material of other functions; Moreover the fusing point of this wax stock is generally all between about 37.78-148.89 ℃ (being 100-300 °F), and its temperature is between 50-200 ℃ during with the mixing of this luminescent material and wax stock, and its best mixing temperature is higher than 20-40 ℃ of this wax stock fusing point.
In step 40, the operational condition of this vacuum froth breaking is 1-5 * 10
-2Holder (torr), its optimum operation condition is 2 * 10
-2Holder (torr).Wherein in manufacture method of the present invention, still can when mixing, add tinting material, to change its color, to increase its color change, the color representation that helps artwork, in addition also can be in wax work inside, the part or surface makes color with coating or spraying method or moulding improves, make the finished product of manufacture method made of the present invention become one and day and night have functional wax artwork or candle finished product concurrently.
Embodiment:
The wax of 100g numbering 145 (fusing point is 62.78 ℃, promptly 145) is fused with hot water bath or oil bath heating in container, add the SrAl of Xg
2O
4: (wherein X is 2,5,10 for Eu, Dy phosphorescence powder, 20 and 100),, this mixing solutions is poured in the mould to be higher than the about 20-40 of wax fusing point ℃ condition uniform mixing, through the vacuum froth breaking, make it to naturally cool to room temperature, again through demoulding get final product the luminiferous wax work of tool.
See also Fig. 2, it is SrAl
2O
4: Eu, Dy type phosphorescent substance and wax phase are to mix the phosphorescent wax work of gained tool at 100: 100 to weight ratio (%), wherein (a) is excitation spectrum, by in the collection of illustrative plates as can be known this product can absorb ultraviolet and the visible light of 300-450nm, nationality is with the savings energy, (b) of Fig. 2 is emmission spectrum, and it can emit the yellow green light of 450-600nm as can be known.
See also Fig. 3, it is SrAl
2O
4: Eu, Dy type phosphor are to mix (a) X-ray diffraction collection of illustrative plates of gained tool phosphorescent wax work at 100: 100 with wax phase to weight ratio (%), through with the standard SrAl of (b)
2O
4: Eu, Dy powder X-ray diffraction collection of illustrative plates relatively show SrAl in the wax work of the present invention
2O
4: the chemical structure of Eu is oblique system (Monoclinic), and lattice parameter is a=8.45 , b=8.82 and c=5.16 , and α=90 °, β=93.35 ° and γ=90 °; This result and standard SrAl
2O
4The type structure conforms to, and manufacture craft of the present invention as can be known still can keep the structure of original phosphorescent substance.
See also Fig. 4 A, it is SrAl
2O
4: Eu, Dy type phosphorescent substance are X with wax phase to weight ratio (%): the wax work that 100 (wherein X is 2,5,10,20 and 100) are mixed gained absorbs daylight or ultraviolet situation daytime, can be absorbed ultraviolet and the visible light of 300-450nm by Fig. 2 (a) product of the present invention as can be known.Show then among Fig. 4 B that aforementioned sample emits the photograph of phosphorescence, the sustainable 5-18 of this phosphorescent characteristics hour in the dark place.
Fig. 5, it is SrAl
2O
4: Eu, Dy type phosphorescent substance and Maitreya Buddha's artwork of wax mixing gained are emitted the photograph of phosphorescence in the dark place, by the finished product tool practicality that can show the inventive method among the figure.
In sum, the present invention one has novelty, progressive and can supply the industry user.
The above person of thought, it only is a preferred embodiment of the present invention, be not to be used for limiting scope of the invention process, change and modification according to the described shape of the present patent application claim, structure, feature and spiritual institute are impartial for it such as, all should be included in the claim of the present invention.
Claims (11)
1. one kind has luminiferous wax work manufacture method, and its key step comprises at least:
Wax is fused fully at least one wax stock heating;
It is even to add at least one luminous material mixing, makes it be liquid uniformly;
Liquid pouring is gone into a mould;
Carry out behind the vacuum froth breaking its cooling curing; And
Demoulding promptly creates a luminiferous wax work.
2. wax work manufacture method as claimed in claim 1, this luminous material are one of them persons who is selected from a phosphorescent substance or a fluorescent material and combination thereof.
3. wax work manufacture method as claimed in claim 2, wherein this phosphorescent substance is a strontium alumina type, zinc sulphide type or the identical fluorescent material of other functions.
4. wax work manufacture method as claimed in claim 1, wherein the fusing point of this wax stock is between 37.78-148.89 ℃.
5. wax work manufacture method as claimed in claim 1, wherein the mixing temperature of this luminescent material and wax stock is 50-200 ℃.
6. wax work manufacture method as claimed in claim 1, wherein the mixing temperature of this luminescent material and wax stock is higher than 20-40 ℃ of this wax stock fusing point.
7. wax work manufacture method as claimed in claim 1, wherein the operational condition of this vacuum froth breaking is 1-5 * 10
-2Holder.
8. wax work manufacture method as claimed in claim 7, wherein the operational condition of this vacuum froth breaking is 2 * 10
-2Holder.
9. wax work manufacture method as claimed in claim 1, wherein this manufacture method still can add to change the tinting material of its color when mixing.
10. wax work manufacture method as claimed in claim 1, wherein this manufacture method still can be in wax work inside, part or surface do color or moulding improvement with coating or spraying method.
11. wax work manufacture method as claimed in claim 1, wherein the made finished product of this manufacture method is one day and night to have functional wax artwork or candle finished product concurrently.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA031019838A CN1521214A (en) | 2003-01-30 | 2003-01-30 | Process for preparing luminous wax product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA031019838A CN1521214A (en) | 2003-01-30 | 2003-01-30 | Process for preparing luminous wax product |
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| Publication Number | Publication Date |
|---|---|
| CN1521214A true CN1521214A (en) | 2004-08-18 |
Family
ID=34281535
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|---|---|---|---|
| CNA031019838A Pending CN1521214A (en) | 2003-01-30 | 2003-01-30 | Process for preparing luminous wax product |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103305350A (en) * | 2013-07-08 | 2013-09-18 | 肖崇华 | Flash candle and production method thereof |
| CN107227207A (en) * | 2017-07-12 | 2017-10-03 | 中山南星工艺品有限公司 | A kind of process for making of Simulated electrical candle |
| CN109591308A (en) * | 2018-11-23 | 2019-04-09 | 迪亚姆展示设备(昆山)有限公司 | A kind of based crystal wax cosmetics displaying manufacture craft of stage property |
| CN109796775A (en) * | 2019-01-24 | 2019-05-24 | 福州麦克纳诺生物科技有限公司 | The fluorescence paraffin and preparation method of perovskite quantum dot functionalization |
-
2003
- 2003-01-30 CN CNA031019838A patent/CN1521214A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103305350A (en) * | 2013-07-08 | 2013-09-18 | 肖崇华 | Flash candle and production method thereof |
| CN107227207A (en) * | 2017-07-12 | 2017-10-03 | 中山南星工艺品有限公司 | A kind of process for making of Simulated electrical candle |
| CN107227207B (en) * | 2017-07-12 | 2021-03-12 | 中山南星工艺品有限公司 | Manufacturing process method of simulated electronic candle |
| CN109591308A (en) * | 2018-11-23 | 2019-04-09 | 迪亚姆展示设备(昆山)有限公司 | A kind of based crystal wax cosmetics displaying manufacture craft of stage property |
| CN109796775A (en) * | 2019-01-24 | 2019-05-24 | 福州麦克纳诺生物科技有限公司 | The fluorescence paraffin and preparation method of perovskite quantum dot functionalization |
| CN109796775B (en) * | 2019-01-24 | 2021-05-11 | 福州麦克纳诺生物科技有限公司 | Perovskite quantum dot functionalized fluorescent paraffin and preparation method thereof |
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