JP6153073B2 - 鉛蓄電池 - Google Patents
鉛蓄電池 Download PDFInfo
- Publication number
- JP6153073B2 JP6153073B2 JP2013161725A JP2013161725A JP6153073B2 JP 6153073 B2 JP6153073 B2 JP 6153073B2 JP 2013161725 A JP2013161725 A JP 2013161725A JP 2013161725 A JP2013161725 A JP 2013161725A JP 6153073 B2 JP6153073 B2 JP 6153073B2
- Authority
- JP
- Japan
- Prior art keywords
- mass
- acid
- lead
- negative electrode
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000002253 acid Substances 0.000 title claims description 24
- -1 alkali metal salt Chemical class 0.000 claims description 37
- 239000007773 negative electrode material Substances 0.000 claims description 37
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 34
- 229910052799 carbon Inorganic materials 0.000 claims description 31
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 28
- 229910001415 sodium ion Inorganic materials 0.000 claims description 27
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 25
- 229910001416 lithium ion Inorganic materials 0.000 claims description 25
- 229930185605 Bisphenol Natural products 0.000 claims description 24
- 229910052782 aluminium Inorganic materials 0.000 claims description 22
- 150000003839 salts Chemical class 0.000 claims description 22
- 235000010443 alginic acid Nutrition 0.000 claims description 17
- 239000000783 alginic acid Substances 0.000 claims description 17
- 229960001126 alginic acid Drugs 0.000 claims description 17
- 229920000615 alginic acid Polymers 0.000 claims description 17
- 150000004781 alginic acids Chemical class 0.000 claims description 16
- 229920002125 Sokalan® Polymers 0.000 claims description 15
- 239000004584 polyacrylic acid Substances 0.000 claims description 15
- 239000008151 electrolyte solution Substances 0.000 claims description 14
- 229920002845 Poly(methacrylic acid) Polymers 0.000 claims description 7
- 229910052783 alkali metal Inorganic materials 0.000 claims description 7
- YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 claims description 6
- 239000007774 positive electrode material Substances 0.000 claims description 6
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 claims description 5
- 108010020346 Polyglutamic Acid Proteins 0.000 claims description 4
- 229920002643 polyglutamic acid Polymers 0.000 claims description 4
- 239000006229 carbon black Substances 0.000 description 17
- 230000001172 regenerating effect Effects 0.000 description 14
- 238000007600 charging Methods 0.000 description 13
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 12
- 230000035515 penetration Effects 0.000 description 12
- 230000000694 effects Effects 0.000 description 7
- 239000003792 electrolyte Substances 0.000 description 7
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 6
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 5
- 239000000661 sodium alginate Substances 0.000 description 5
- 235000010413 sodium alginate Nutrition 0.000 description 5
- 229940005550 sodium alginate Drugs 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- 238000010280 constant potential charging Methods 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229910014474 Ca-Sn Inorganic materials 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 230000005856 abnormality Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 229920005610 lignin Polymers 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 3
- 125000000542 sulfonic acid group Chemical group 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000000648 calcium alginate Substances 0.000 description 2
- 235000010410 calcium alginate Nutrition 0.000 description 2
- 229960002681 calcium alginate Drugs 0.000 description 2
- OKHHGHGGPDJQHR-YMOPUZKJSA-L calcium;(2s,3s,4s,5s,6r)-6-[(2r,3s,4r,5s,6r)-2-carboxy-6-[(2r,3s,4r,5s,6r)-2-carboxylato-4,5,6-trihydroxyoxan-3-yl]oxy-4,5-dihydroxyoxan-3-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylate Chemical compound [Ca+2].O[C@@H]1[C@H](O)[C@H](O)O[C@@H](C([O-])=O)[C@H]1O[C@H]1[C@@H](O)[C@@H](O)[C@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@H](O2)C([O-])=O)O)[C@H](C(O)=O)O1 OKHHGHGGPDJQHR-YMOPUZKJSA-L 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 210000001787 dendrite Anatomy 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 229910003002 lithium salt Inorganic materials 0.000 description 2
- 159000000002 lithium salts Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000003204 osmotic effect Effects 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920001444 polymaleic acid Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 2
- 239000012744 reinforcing agent Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 229910003481 amorphous carbon Inorganic materials 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000003273 ketjen black Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229910000464 lead oxide Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013161725A JP6153073B2 (ja) | 2013-08-02 | 2013-08-02 | 鉛蓄電池 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013161725A JP6153073B2 (ja) | 2013-08-02 | 2013-08-02 | 鉛蓄電池 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015032481A JP2015032481A (ja) | 2015-02-16 |
| JP2015032481A5 JP2015032481A5 (enrdf_load_stackoverflow) | 2015-11-05 |
| JP6153073B2 true JP6153073B2 (ja) | 2017-06-28 |
Family
ID=52517640
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013161725A Expired - Fee Related JP6153073B2 (ja) | 2013-08-02 | 2013-08-02 | 鉛蓄電池 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP6153073B2 (enrdf_load_stackoverflow) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016121510A1 (ja) * | 2015-01-28 | 2016-08-04 | 日立化成株式会社 | 鉛蓄電池及びそれを備える自動車 |
| JP6528842B2 (ja) * | 2015-03-05 | 2019-06-12 | 日立化成株式会社 | 鉛蓄電池 |
| WO2016204049A1 (ja) * | 2015-06-18 | 2016-12-22 | 日立化成株式会社 | 鉛蓄電池 |
| ES2900658T3 (es) * | 2015-10-06 | 2022-03-17 | Arcactive Ltd | Electrodo mejorado de batería de plomo-ácido |
| JP6468163B2 (ja) * | 2015-10-21 | 2019-02-13 | 日立化成株式会社 | 鉛蓄電池 |
| WO2017212590A1 (ja) * | 2016-06-08 | 2017-12-14 | 日立化成株式会社 | 鉛蓄電池 |
| JP6458829B2 (ja) * | 2017-06-29 | 2019-01-30 | 株式会社Ｇｓユアサ | 鉛蓄電池 |
| SG11202102408TA (en) * | 2018-09-25 | 2021-04-29 | Gs Yuasa Int Ltd | Lead-acid battery |
| CN112753128A (zh) * | 2018-09-26 | 2021-05-04 | 株式会社杰士汤浅国际 | 铅蓄电池用隔离件和铅蓄电池 |
| JP6760347B2 (ja) * | 2018-10-10 | 2020-09-23 | 日立化成株式会社 | 鉛蓄電池 |
| JP6958693B2 (ja) * | 2018-10-10 | 2021-11-02 | 昭和電工マテリアルズ株式会社 | 鉛蓄電池 |
| KR102103311B1 (ko) * | 2018-10-23 | 2020-04-23 | 주식회사 한국아트라스비엑스 | 안정적인 내구성 사이클을 제공할 수 있는 납축전지의 전해액 제조방법 |
| JP7470403B2 (ja) * | 2020-06-12 | 2024-04-18 | 積水フーラー株式会社 | 湿気硬化型ホットメルト接着剤 |
| EP4228051A4 (en) * | 2020-11-27 | 2025-07-09 | Gs Yuasa Int Ltd | LEAD STORAGE BATTERY |
| CN118867252B (zh) * | 2024-09-26 | 2025-02-07 | 浙江埃登达新能源材料有限公司 | 一种耐高温储能电池用负极添加剂 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001313064A (ja) * | 2000-04-28 | 2001-11-09 | Mase Shunzo | 鉛蓄電池およびその添加剤 |
| JP2004022440A (ja) * | 2002-06-19 | 2004-01-22 | Hitachi Ltd | 鉛蓄電池 |
| JP2007027076A (ja) * | 2005-07-19 | 2007-02-01 | Mase Shunzo | ハイブリッド車用鉛蓄電池 |
| BRPI0519554B1 (pt) * | 2005-09-27 | 2016-09-27 | Furukawa Battery Co Ltd | acumulador de chumbo . |
| JP2008243489A (ja) * | 2007-03-26 | 2008-10-09 | Furukawa Battery Co Ltd:The | 鉛蓄電池 |
| WO2012086008A1 (ja) * | 2010-12-21 | 2012-06-28 | 新神戸電機株式会社 | 鉛蓄電池 |
| EP2731189A4 (en) * | 2011-07-05 | 2015-04-08 | Gs Yuasa Int Ltd | LEAD-ACID BATTERY FLOODED |
| JP5909974B2 (ja) * | 2011-10-06 | 2016-04-27 | 株式会社Ｇｓユアサ | 鉛蓄電池 |
| CN105977549B (zh) * | 2011-10-18 | 2019-03-29 | 日立化成株式会社 | 铅蓄电池 |
-
2013
- 2013-08-02 JP JP2013161725A patent/JP6153073B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2015032481A (ja) | 2015-02-16 |
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