JP6130301B2 - 金属処理 - Google Patents
金属処理 Download PDFInfo
- Publication number
- JP6130301B2 JP6130301B2 JP2013548891A JP2013548891A JP6130301B2 JP 6130301 B2 JP6130301 B2 JP 6130301B2 JP 2013548891 A JP2013548891 A JP 2013548891A JP 2013548891 A JP2013548891 A JP 2013548891A JP 6130301 B2 JP6130301 B2 JP 6130301B2
- Authority
- JP
- Japan
- Prior art keywords
- voltage
- metal object
- anodizing
- anodization
- current
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 239000002184 metal Substances 0.000 title claims description 79
- 229910052751 metal Inorganic materials 0.000 title claims description 78
- 238000012545 processing Methods 0.000 title description 6
- 238000000034 method Methods 0.000 claims description 65
- 238000002048 anodisation reaction Methods 0.000 claims description 57
- 238000007743 anodising Methods 0.000 claims description 39
- 238000005259 measurement Methods 0.000 claims description 31
- 239000003792 electrolyte Substances 0.000 claims description 30
- 239000002344 surface layer Substances 0.000 claims description 18
- 239000003899 bactericide agent Substances 0.000 claims description 12
- 230000001965 increasing effect Effects 0.000 claims description 11
- 230000003647 oxidation Effects 0.000 claims description 9
- 238000007254 oxidation reaction Methods 0.000 claims description 9
- 239000007769 metal material Substances 0.000 claims description 7
- 238000006722 reduction reaction Methods 0.000 claims description 7
- 229910044991 metal oxide Inorganic materials 0.000 claims description 5
- 150000004706 metal oxides Chemical class 0.000 claims description 5
- 239000003638 chemical reducing agent Substances 0.000 claims description 4
- 229910001463 metal phosphate Inorganic materials 0.000 claims description 4
- 230000001419 dependent effect Effects 0.000 claims description 3
- 238000012544 monitoring process Methods 0.000 claims description 3
- 239000007943 implant Substances 0.000 description 74
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 36
- 239000000243 solution Substances 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- 230000015572 biosynthetic process Effects 0.000 description 16
- 230000008569 process Effects 0.000 description 16
- 229910052709 silver Inorganic materials 0.000 description 15
- 239000004332 silver Substances 0.000 description 15
- 239000010936 titanium Substances 0.000 description 15
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 14
- 229910052719 titanium Inorganic materials 0.000 description 14
- 235000011121 sodium hydroxide Nutrition 0.000 description 12
- 239000010410 layer Substances 0.000 description 11
- 238000002161 passivation Methods 0.000 description 11
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- 239000008151 electrolyte solution Substances 0.000 description 8
- -1 silver ions Chemical class 0.000 description 8
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 8
- 229910045601 alloy Inorganic materials 0.000 description 7
- 239000000956 alloy Substances 0.000 description 7
- 230000008859 change Effects 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- 230000000844 anti-bacterial effect Effects 0.000 description 6
- 208000015181 infectious disease Diseases 0.000 description 6
- 229910001069 Ti alloy Inorganic materials 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 5
- 229910021607 Silver chloride Inorganic materials 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 210000000988 bone and bone Anatomy 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 4
- 229910001961 silver nitrate Inorganic materials 0.000 description 4
- 241000894007 species Species 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 229910052720 vanadium Inorganic materials 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 229910000883 Ti6Al4V Inorganic materials 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 238000005868 electrolysis reaction Methods 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 230000003746 surface roughness Effects 0.000 description 3
- 238000001356 surgical procedure Methods 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 102000029797 Prion Human genes 0.000 description 2
- 108091000054 Prion Proteins 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000002158 endotoxin Substances 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 230000000813 microbial effect Effects 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 210000001519 tissue Anatomy 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 238000002604 ultrasonography Methods 0.000 description 2
- 206010005949 Bone cancer Diseases 0.000 description 1
- 208000018084 Bone neoplasm Diseases 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 206010072064 Exposure to body fluid Diseases 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 230000005355 Hall effect Effects 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000032770 biofilm formation Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 210000001124 body fluid Anatomy 0.000 description 1
- 239000010839 body fluid Substances 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 239000004053 dental implant Substances 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 229910021397 glassy carbon Inorganic materials 0.000 description 1
- 210000001624 hip Anatomy 0.000 description 1
- 210000004394 hip joint Anatomy 0.000 description 1
- 238000011540 hip replacement Methods 0.000 description 1
- 229910052588 hydroxylapatite Inorganic materials 0.000 description 1
- 238000002513 implantation Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000000399 orthopedic effect Effects 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 1
- 238000000275 quality assurance Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000008237 rinsing water Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- UKHWJBVVWVYFEY-UHFFFAOYSA-M silver;hydroxide Chemical compound [OH-].[Ag+] UKHWJBVVWVYFEY-UHFFFAOYSA-M 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 210000004872 soft tissue Anatomy 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 229940078499 tricalcium phosphate Drugs 0.000 description 1
- 229910000391 tricalcium phosphate Inorganic materials 0.000 description 1
- 235000019731 tricalcium phosphate Nutrition 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
- C25D11/16—Pretreatment, e.g. desmutting
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/024—Anodisation under pulsed or modulated current or potential
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D21/00—Processes for servicing or operating cells for electrolytic coating
- C25D21/12—Process control or regulation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Automation & Control Theory (AREA)
- Prostheses (AREA)
- Materials For Medical Uses (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB1100605.3A GB201100605D0 (en) | 2011-01-14 | 2011-01-14 | Metal treatment |
| GB1100605.3 | 2011-01-14 | ||
| GBGB1106733.7A GB201106733D0 (en) | 2011-04-21 | 2011-04-21 | Metal treatment |
| GB1106733.7 | 2011-04-21 | ||
| PCT/GB2012/050068 WO2012095672A2 (en) | 2011-01-14 | 2012-01-13 | Metal treatment |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014503693A JP2014503693A (ja) | 2014-02-13 |
| JP2014503693A5 JP2014503693A5 (enExample) | 2015-02-26 |
| JP6130301B2 true JP6130301B2 (ja) | 2017-05-17 |
Family
ID=45531884
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013548891A Active JP6130301B2 (ja) | 2011-01-14 | 2012-01-13 | 金属処理 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US9809894B2 (enExample) |
| EP (1) | EP2663671B1 (enExample) |
| JP (1) | JP6130301B2 (enExample) |
| WO (1) | WO2012095672A2 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023032948A1 (ja) | 2021-08-31 | 2023-03-09 | 株式会社丸ヱム製作所 | 生体適合性膜、及び該膜を有する生体適合性材料 |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5536287B1 (ja) * | 2012-08-06 | 2014-07-02 | 三菱レイヨン株式会社 | モールドの製造方法、および微細凹凸構造を表面に有する成形体の製造方法 |
| GB201508385D0 (en) * | 2015-05-15 | 2015-07-01 | Accentus Medical Ltd | Metal treatment |
| EP3981444A1 (en) | 2017-03-30 | 2022-04-13 | Biomet Manufacturing, LLC | Methods of modifying the porous surface of implants |
| KR102048707B1 (ko) * | 2017-09-29 | 2019-11-27 | (주)알루코 | Al-Mg-Zn 합금 고광택 아노다이징 공법 |
| US11230786B2 (en) * | 2019-06-17 | 2022-01-25 | Nanopec, Inc. | Nano-porous anodic aluminum oxide membrane for healthcare and biotechnology |
| EP4054333A4 (en) | 2019-12-10 | 2024-01-10 | A3 Surface Inc. | ANODIZED BIOCIDAL METAL MATERIAL, METHOD FOR MANUFACTURING THE MATERIAL AND METHOD FOR REACTIVATING THE MATERIAL |
| CA3183538A1 (en) | 2020-07-02 | 2022-01-06 | Mary K. CANTY | Method for optimizing treatment of infected metallic implants by measuring charge transfer |
| WO2024089448A1 (en) * | 2022-10-25 | 2024-05-02 | Ecospec Noveltech Pte Ltd | System and method for in-situ formation of barrier coating on metallic article in contact with or exposed to water within a water system |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4487666A (en) * | 1984-03-30 | 1984-12-11 | Sprague Electric Company | Electrolytically forming a lot of valve-metal-bodies for use in capacitors |
| JPH0432577A (ja) * | 1990-05-25 | 1992-02-04 | Kobe Steel Ltd | 塗膜密着性及び耐食性に優れた塗装AlまたはAl合金材 |
| JP3335757B2 (ja) * | 1994-03-17 | 2002-10-21 | 株式会社半導体エネルギー研究所 | 陽極酸化方法 |
| JP2000282294A (ja) * | 1999-03-31 | 2000-10-10 | Kobe Steel Ltd | 耐熱割れ性および腐食性に優れた陽極酸化皮膜の形成方法並びに陽極酸化皮膜被覆部材 |
| US20040050709A1 (en) * | 2002-09-17 | 2004-03-18 | The Boeing Company | Accelerated sulfuric acid and boric sulfuric acid anodize process |
| US7033466B2 (en) * | 2002-09-27 | 2006-04-25 | United Technologies Corporation | Electrochemical stripping using single loop control |
| US20050045482A1 (en) * | 2003-08-25 | 2005-03-03 | Storms Edmund K. | Electrolytic heat source |
| JP2005287985A (ja) * | 2004-04-05 | 2005-10-20 | Gha:Kk | 炎症/臭い抑制部材及びその製造方法並びにこれを用いた義体及びギブス |
| US20090292346A1 (en) * | 2005-03-31 | 2009-11-26 | St. Jude Medical Ab | Porous Niobium Oxide as Electrode Material and Manufacturing Process |
| DE102007026086B4 (de) * | 2007-06-04 | 2009-03-05 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zur Ausbildung einer dielektrischen Dünnschicht auf einem Titansubstrat, mit dem Verfahren hergestelltes Titansubstrat mit Dünnschicht sowie seine Verwendung |
| AU2008306596B2 (en) * | 2007-10-03 | 2013-04-04 | Accentus Plc | Method of manufacturing metal with biocidal properties |
| CN102449207B (zh) * | 2009-03-30 | 2015-05-27 | 阿山特斯医疗有限公司 | 金属处理 |
-
2012
- 2012-01-13 EP EP12701260.7A patent/EP2663671B1/en active Active
- 2012-01-13 JP JP2013548891A patent/JP6130301B2/ja active Active
- 2012-01-13 US US13/979,459 patent/US9809894B2/en active Active
- 2012-01-13 WO PCT/GB2012/050068 patent/WO2012095672A2/en not_active Ceased
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023032948A1 (ja) | 2021-08-31 | 2023-03-09 | 株式会社丸ヱム製作所 | 生体適合性膜、及び該膜を有する生体適合性材料 |
Also Published As
| Publication number | Publication date |
|---|---|
| US9809894B2 (en) | 2017-11-07 |
| EP2663671B1 (en) | 2017-10-11 |
| EP2663671A2 (en) | 2013-11-20 |
| JP2014503693A (ja) | 2014-02-13 |
| US20130319869A1 (en) | 2013-12-05 |
| WO2012095672A3 (en) | 2013-08-01 |
| WO2012095672A2 (en) | 2012-07-19 |
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