JP6108516B2 - Gas detector - Google Patents

Description

  The present invention relates to a gas detection apparatus using a gas sensor whose resistance value changes according to the concentration of a detection target gas.

Conventionally, as this type of gas detection device, a device using a gas sensor (sensing element) having a gas sensitive body mainly composed of a metal oxide semiconductor such as tin oxide (SnO ₂ ) has been provided (for example, a patent). Reference 1). This gas detection device detects a detection target gas by utilizing the property that when a reducing gas such as a flammable gas comes into contact with the surface of the gas sensitive body, the resistance value of the gas sensitive body decreases due to the oxidation-reduction action. . In addition, the gas detection apparatus described in Patent Document 1 includes an incomplete combustion gas such as carbon monoxide (CO) generated during incomplete combustion and a combustible gas by appropriately combining the temperature and material of the gas sensitive body. Detect both.

  In Patent Document 1, the gas detection device includes a gas detection unit that detects a resistance value of a gas sensor (gas sensitive body) and detects a concentration of a detection target gas from the resistance value. However, the resistance value of the gas sensor varies greatly depending on the ambient temperature, and especially during the detection period when the temperature of the gas sensor is low, the influence of the ambient temperature becomes significant. There is a possibility of misdetecting the gas to be detected. Therefore, the gas detection device described in Patent Document 1 prevents erroneous detection due to a change in the ambient temperature by performing temperature compensation based on the ambient temperature detected by the temperature sensor unit.

Japanese Patent No. 3742587

  By the way, as described above, a gas sensor whose resistance value changes usually has a dependency on absolute humidity, and the resistance value changes if the relative humidity changes even if the ambient temperature is constant. Therefore, in the gas detection device configured to detect the detection target gas from the resistance value of the gas sensor, it is necessary to correct the resistance value based on humidity in order to improve detection accuracy.

  However, the absolute humidity sensor is relatively expensive, has a short life compared to the gas sensor, and is unsuitable for mounting in a gas detection device because of its dependence on gas. Therefore, in a general gas detection apparatus, correction based on humidity is indirectly performed using the output of the temperature sensor unit using the correlation between the temperature and the absolute humidity. For this reason, with a general gas detection device, if the ambient temperature is constant, the resistance value fluctuation due to the relative humidity fluctuation cannot be corrected, and the detection accuracy of the detection target gas is high when the humidity dependence of the gas sensor is large. It may drop and become insufficient.

  The present invention has been made in view of the above-described reasons, and an object thereof is to provide a gas detection device in which the detection accuracy of the detection target gas is not easily lowered even when the humidity dependency of the gas sensor is large.

The gas detection device of the present invention includes a gas sensor whose resistance value changes according to the concentration of the detection target gas, a detection processing unit that detects the detection target gas in the atmosphere based on the resistance value of the gas sensor, and a standard atmosphere A storage unit that stores in advance as known data the resistance value of the gas sensor associated with the humidity in the control unit; and a control unit that controls the temperature of the gas sensor so as to switch between the first set temperature and the second set temperature. And when the temperature of the gas sensor is at the first set temperature, the detection processing unit calculates a correction value according to the humidity in the atmosphere from the resistance value of the gas sensor and the known data in the storage unit. And when the temperature of the gas sensor is at the second set temperature, the detection result of the detection target gas is detected using the correction value obtained immediately before by the calculation unit. The detection target gas is a plurality of types of gases, and the first set temperature is such that the sensitivity of the gas sensor with respect to all of the plurality of types of gases is less than a predetermined value. The second set temperature is a plurality of types of temperatures at which the sensitivity of the gas sensor with respect to each of the plurality of types of gas is equal to or higher than the predetermined value, and the control unit is configured to perform the first setting. While alternately switching between the temperature and the second set temperature, the plurality of types of temperatures as the second set temperature and the first set temperature are periodically repeated. The temperature is controlled, and the calculation unit is when the temperature of the gas sensor is the first set temperature and immediately before the temperature of the gas sensor is switched from the first set temperature to the second set temperature. , The correction unit calculates the correction value, and the correction unit switches the temperature of the gas sensor from the second set temperature to the first set temperature when the temperature of the gas sensor is the second set temperature. Immediately before, the detection result is corrected using the correction value .

  The gas detector further includes a temperature sensor that changes an output value according to a temperature in the atmosphere, and the calculation unit is configured to correct the correction value associated with a temperature change in the atmosphere based on an output value of the temperature sensor. It is desirable to compensate for these changes.

  In this gas detection device, a filter that delays a reaction speed of the gas sensor with respect to humidity compared with a reaction speed of the gas sensor with respect to the detection target gas is provided in an inflow path of the detection target gas to the gas sensor. More desirable.

  In this gas detection device, it is more desirable that the humidity dependency of the resistance value is greater when the gas sensor is at the first set temperature than when the gas sensor is at the second set temperature.

  In the present invention, since the detection processing unit includes a calculation unit that calculates a correction value according to the humidity in the atmosphere and a correction unit that corrects the detection result of the detection target gas with the correction value, the influence of humidity in the atmosphere There is an advantage that it is difficult to receive. That is, the calculation unit calculates a correction value according to the humidity in the atmosphere from the resistance value of the gas sensor and the known data when the gas sensor is at the first set temperature at which the gas sensor has low sensitivity to the detection target gas. The correction unit corrects the detection result of the detection target gas using the correction value obtained by the calculation unit immediately before the gas sensor is at the second set temperature at which the gas sensor is highly sensitive to the detection target gas. Therefore, even if the ambient temperature is constant, the detection processing unit can obtain the detection result of the detection target gas excluding the influence of the humidity change by the correction. Therefore, even when the humidity dependence of the gas sensor is large, detection of the detection target gas is possible. The accuracy is difficult to decrease.

  According to another configuration of the present invention, the calculation unit compensates for the change in the correction value accompanying the temperature change in the atmosphere based on the output value of the temperature sensor, so that the detection target gas can be detected with higher accuracy. .

  According to still another configuration of the present invention, the reaction speed of the gas sensor with respect to humidity can be delayed compared to the reaction speed of the gas sensor with respect to the detection target gas by the filter provided in the inflow path of the detection target gas to the gas sensor. Therefore, even if the humidity in the atmosphere changes suddenly after the correction value is calculated and before the detection result is corrected, the gas detection device can detect the detection target gas without being affected by the sudden humidity change. Detection is possible.

  Further, according to still another configuration of the present invention, the humidity dependency of the resistance value is larger at the first set temperature than at the second set temperature, so that the calculation unit calculates the resistance value of the gas sensor. When the correction value is calculated using this, the humidity in the atmosphere is easily reflected in the correction value. Therefore, the calculation unit can obtain the correction value according to the humidity with high accuracy, and the correction unit can correct the detection result with high accuracy.

It is a block diagram which shows the gas detection apparatus which concerns on embodiment. It is a front view which shows the principal part of the gas sensor used for the gas detection apparatus which concerns on embodiment. It is the partially broken perspective view which shows the gas sensor used for the gas detection apparatus which concerns on embodiment. It is a time chart which shows operation | movement of the gas detection apparatus which concerns on embodiment. It is a graph which shows the temperature-humidity dependence of a gas sensor. It is a flowchart which shows operation | movement of the microcomputer of the gas detection apparatus which concerns on embodiment. It is a graph which shows the instruction | indication density | concentration before correction | amendment in the gas detection apparatus which concerns on embodiment. It is a graph which shows the instruction | indication density | concentration after correction | amendment in the gas detection apparatus which concerns on embodiment. It is a graph which shows the instruction | indication density | concentration before correction | amendment in the gas detection apparatus which concerns on embodiment. It is a graph which shows the instruction | indication density | concentration after correction | amendment in the gas detection apparatus which concerns on embodiment.

  As shown in FIG. 1, the gas detection device 1 of the present embodiment detects a gas to be detected in the atmosphere based on the gas sensor 2 whose resistance value changes according to the concentration of the gas to be detected and the resistance value of the gas sensor 2. The detection circuit 3 is provided. Hereinafter, carbon monoxide (CO) generated during incomplete combustion will be described as an example of a detection target gas.

As shown in FIG. 2, the gas sensor 2 includes a so-called sintered body type gas sensitive body 20 which is formed into a substantially spherical shape mainly composed of a metal oxide semiconductor such as tin oxide (SnO ₂ ). This gas sensor 2 has a gas sensitive body 20 embedded with a heater-use electrode 21 made of coiled platinum, and senses the detection electrode 22 made of a noble metal wire so as to penetrate the center of the coil of the heater-use electrode 21. It is embedded in the gas body 20.

  The gas sensor 2 includes a pair of lead wires 23 and 24 drawn from both ends of the heater combined electrode 21 to the outside of the gas sensing body 20 and a lead wire 25 drawn from one end of the resistance detection 22 to the outside of the gas sensing body 20. And have. These lead wires 23 to 25 are electrically connected to terminals 26 to 28, respectively. Each terminal 26-28 is hold | maintained at the base 11 so that the base 11 made from a synthetic resin formed in the substantially disc shape (refer FIG. 3) may penetrate in the thickness direction.

  Further, the gas sensor 2 has a housing 13 composed of a base 11 and a bottomed cylindrical cover 12 attached to the base 11 so as to cover the gas sensitive body 20 as shown in FIG. The bottom plate 120 of the cover 12 is formed with a circular opening 121 serving as an inlet for the detection target gas into the housing 13, and a stainless steel wire mesh (not shown) is attached to the opening 121. Yes.

  Furthermore, in this embodiment, a bottomed cylindrical outer housing 14 that is slightly larger than the cover 12 is attached to the gas sensor 2 so as to cover the cover 12. The bottom plate 140 of the outer housing 14 is formed with a circular opening 141 serving as an inlet for the gas to be detected into the outer housing 14, and a stainless steel wire mesh 142 is attached to the opening 141.

  The outer housing 14 is set to have a height dimension larger than that of the cover 12, and the filter 15 is accommodated in a gap formed between the bottom plate 140 and the bottom plate 120 of the cover 12. The filter 15 provided in the inflow path of the detection target gas to the gas sensor 2 is an activated carbon filter here and has a function of removing interfering gases other than the detection target gas. Specifically, the filter 15 has a function of removing alcohol or preventing adhesion of siloxane contained in a deodorant or the like to the surface of the gas sensor 2. Further, the filter 15 has a function of delaying the reaction speed of the gas sensor 2 with respect to humidity as compared with the reaction speed of the gas sensor 2 with respect to the detection target gas. The filter 15 is not limited to activated carbon, and may be formed of, for example, silica gel or a material that combines silica gel and activated carbon.

  The detection circuit 3 controls the heating of the gas sensitive body 20 of the gas sensor 2 configured as described above, and detects the detection target gas based on the resistance value of the heated gas sensitive body 20. Hereinafter, the configuration of the detection circuit 3 will be described with reference to FIG.

  The detection circuit 3 includes a power supply circuit 30 that outputs DC power stabilized at a substantially constant voltage (for example, 5 V), and further operates as a microcomputer (hereinafter referred to as a microcomputer) that operates using the output of the power supply circuit 30 as a power supply. 31 is provided as a main configuration.

  The microcomputer 31 includes a control unit 32 for driving the gas sensor 2, a reading unit 33 and an acquisition unit 34 for reading the resistance value of the gas sensor 2, and detection for detecting a detection target gas in the atmosphere based on the resistance value of the gas sensor 2. And a processing unit 35. Furthermore, the microcomputer 31 has an output unit 36 that outputs the detection result of the detection processing unit 35, a temperature acquisition unit 37 that acquires temperature information for temperature compensation, and a storage unit 38 that stores various data. The microcomputer 31 implements the function of each unit described above by executing a program stored in the storage unit 38.

The output terminal of the positive electrode of the power supply circuit 30 is connected to a terminal 26 connected to one end of the heater serving electrode 21 in the gas sensor 2 with a MOSFET (Metal-Oxide-Semiconductor). It is electrically connected via a switching element 40 composed of a field-effect transistor. Further, the negative output terminal of the power supply circuit 30 is electrically connected to a terminal 27 connected to the other end of the heater electrode 21. That is, the heater combined electrode 21 of the gas sensor 2 is connected between the output terminals of the power supply circuit 30 via the switching element 40.

  The switching element 40 is made of a p-type MOSFET, and has a source connected to the positive output terminal of the power supply circuit 30 and a drain connected to the terminal 26 of the gas sensor 2. A pull-up resistor 41 is connected between the source and gate of the switching element 40. The gate of the switching element 40 is connected to the output of the control unit 32 of the microcomputer 31 via the capacitor 42.

  Therefore, when the output of the control unit 32 is inverted from the H (high) level to the L (low) level, the switching element 40 is turned on, and the heater combined electrode 21 is energized from the power supply circuit 30 via the switching element 40. The combined electrode 21 is heated. On the other hand, when the output of the control unit 32 is inverted from the L level to the H level, the switching element 40 is turned off, and the energization to the heater electrode 21 is stopped. The microcomputer 31 performs duty control in the control unit 32 so that the heater combined electrode 21 is energized for a predetermined time every predetermined period, thereby averaging the heater voltage applied to the heater combined electrode 21 per unit time. Adjust the value.

  In this configuration, the control unit 32 can change the average value of the heater voltage by changing the duty ratio, thereby changing the temperature of the gas sensitive body 20. Here, the control unit 32 senses so as to alternately switch between a first set temperature at which the sensitivity of the gas sensor 2 to the detection target gas is less than a predetermined value and a second set temperature at which the sensitivity is equal to or higher than the predetermined value. The temperature of the gas body 20 is controlled. In this embodiment, since the detection target gas is carbon monoxide, the temperature at which the gas sensor 2 has sufficient sensitivity to carbon monoxide is set to the second set temperature, and the gas sensor 2 has almost sensitivity to carbon monoxide. The temperature that is not present is set as the first set temperature.

  Here, as shown in FIG. 4, the control unit 32 sets the average value of the heater voltage to about 0.9 V, the insensitive period T1 in which the gas sensitive body 20 is heated to the first set temperature, and the average value of the heater voltage. The detection period T2 in which the gas sensitive body 20 is heated to the second set temperature at 0.2 V is alternately switched. During the dead period T1, the gas sensitive body 20 is heated to about 400 ° C. which is the first set temperature, and during the detection period T2, the gas sensitive body 20 is heated to about 80 ° C. which is the second set temperature. . As an example, the control unit 32 controls the heater voltage so that 25 seconds is one period, 5 seconds of the one period is the dead period T1, and the remaining 20 seconds are the detection period T2.

  Further, the terminal 28 connected to the detection electrode 22 in the gas sensor 2 is electrically connected to one output of the reading unit 33 of the microcomputer 31 via the load resistor 43, and the reading unit 33 via the load resistor 44. Is electrically connected to the other output. The load resistor 43 and the load resistor 44 have different resistance values. The reading unit 33 energizes one load resistor 43 during the insensitive period T1 and energizes the other load resistor 44 during the insensitive period T2, so that the load resistor 43, which energizes in the insensitive period T1 and the detecting period T2, 44 is switched. Further, the terminal 28 of the gas sensor 2 is also electrically connected to the input of the acquisition unit 34 of the microcomputer 31.

  As a result, when the output of either one of the reading unit 33 becomes H level, the voltage divided by any one of the load resistors 43 and 44 and the resistance component of the gas sensitive body 20 is supplied to the acquisition unit 34 as a detection voltage. Will be entered. That is, since the resistance value of the gas sensitive body 20 is a resistance value between the terminal 27 connected to the heater electrode 21 and the terminal 28 connected to the detection electrode 22, the resistance value is input to the acquisition unit 34. The detection voltage is a voltage corresponding to the resistance value of the gas sensor (gas sensitive body 20) 2. The acquisition unit 34 may convert the detection voltage into a resistance value of the gas sensor 2 or may output the detection voltage to the detection processing unit 35 as it is.

  The detection processing unit 35 detects the detection target gas in the atmosphere based on the resistance value of the gas sensor 2 acquired by the acquisition unit 34. That is, in the gas sensor 2, when the detection target gas comes into contact with the surface of the gas sensitive body 20, the resistance value of the gas sensitive body 20 decreases due to the oxidation-reduction action. The concentration of the detection target gas can be detected from the corresponding resistance value. In the present embodiment, the detection processing unit 35 detects carbon monoxide, which is a detection target gas, using the resistance value of the gas sensor 2 immediately before the end of the detection period T2.

  Furthermore, the detection processing unit 35 compares the resistance value of the gas sensor 2 immediately before the end of the detection period T2 with an alarm value stored in advance in the storage unit 38, thereby issuing an alarm (notifying). Alarm judgment is performed to determine whether At this time, if the resistance value of the gas sensor 2 is below the alarm value, the detection processing unit 35 determines that the detection target gas exceeding the predetermined determination concentration is generated and issues an alarm. The alarm value is a resistance value of the gas sensor 2 in the detection period T2 when the concentration of the detection target gas (here, carbon monoxide) is a determination concentration (for example, 300 ppm), and is stored in the storage unit 38 in advance.

  The output unit 36 receives the detection result of the detection processing unit 35, changes the lighting state of a light emitting diode (not shown) connected to the microcomputer 31, or a buzzer (not shown) or a speaker (not shown). ) To notify the user of the detection result. That is, when the detection processing unit 35 determines that the resistance value of the gas sensor 2 is lower than the alarm value, the output unit 36 issues an alarm in response to the alarm signal from the detection processing unit 35. The output unit 36 may function as an interface that outputs a detection signal indicating the concentration of the detection target gas in the atmosphere. In this case, the detection processing unit 35 obtains the concentration of the detection target gas based on the resistance value of the gas sensor 2, and the output unit 36 outputs a detection signal representing the concentration obtained by the detection processing unit 35 to the external device.

  By the way, in this embodiment, the memory | storage part 38 has memorize | stored previously the resistance value of the gas sensor 2 linked | related with the humidity in standard atmosphere as known data. Further, the detection processing unit 35 includes a calculation unit 351 that obtains a correction value according to humidity in the atmosphere using known data in the storage unit 38, and a correction unit that corrects the detection result of the detection target gas using the correction value. 352.

  That is, the gas sensor 2 has a dependency on the absolute humidity. As illustrated in FIG. 5, even if the ambient temperature is constant, the resistance value of the gas sensitive body 20 changes if the relative humidity changes. Therefore, the gas detection device 1 of the present embodiment improves the detection accuracy by correcting the resistance value of the gas sensor (gas sensitive body 20) 2 using a correction value corresponding to humidity. In FIG. 5, the horizontal axis is the ambient temperature, the vertical axis is the ratio (R / Ro) between the resistance value R and the alarm value Ro of the gas sensor 2, and the relative humidity is 35% ((1) in the figure), 50%. The data at (2 in the figure), 65% ((3) in the figure), and 95% ((4) in the figure) are shown.

  Here, the known data is a resistance value of the gas sensor 2 in the dead period T1 in a clean atmosphere (in the standard atmosphere) having a predetermined ambient temperature and relative humidity and no detection target gas, and is stored in the storage unit 38 in advance. It is remembered. The alarm value is a resistance value of the gas sensor 2 in the detection period T2 when only the concentration of the detection target gas is set as the determination concentration while maintaining the same ambient temperature and relative humidity as the known data. The process of detecting the resistance value as known data and writing it in the storage unit 38 under such conditions is called “air adjustment”, and the process of detecting the resistance value as an alarm value and writing it in the storage unit 38 is “ "Gas adjustment".

  The calculation unit 351 detects the current resistance value of the gas sensor 2 and the known data in the storage unit 38 during the dead period T1 when the temperature of the gas sensor 2 is at the first set temperature and the sensitivity of the gas sensor 2 to the detection target gas is sufficiently low. From this, a correction value corresponding to the humidity in the atmosphere is calculated. During the dead period T1, the resistance value of the gas sensor 2 mainly depends on the humidity in the atmosphere and is not significantly affected by the concentration of the detection target gas. Therefore, the calculation unit 351 uses the resistance value of the gas sensor 2 to It is possible to estimate the humidity. The calculation unit 351 calculates a correction value from the resistance value of the gas sensor 2 and the known data at every end point of the dead period T1 that is periodically repeated, that is, immediately before switching to the detection period T2.

  On the other hand, the correction unit 352 corrects the calculation unit 351 during the detection period T2 in which the temperature of the gas sensor 2 is at the second set temperature and the sensitivity of the gas sensor 2 with respect to the detection target gas is sufficiently high, and during the immediately preceding dead period T1. The resistance value of the gas sensor 2 is corrected using the value. In the detection period T2, since the resistance value of the gas sensor 2 is influenced not only by the humidity in the atmosphere but also by the concentration of the detection target gas, the correction unit 352 removes the influence of the humidity by the correction. Can be obtained. The correction unit 352 corrects the resistance value of the gas sensor 2 with the correction value at every end point of the periodically repeated detection period T2, that is, immediately before switching to the dead period T1.

  Moreover, the gas detection apparatus 1 of this embodiment is further provided with the temperature sensor 45 which consists of a thermistor whose resistance value (output value) changes according to the temperature (ambient temperature) in the atmosphere as shown in FIG. The temperature sensor 45 is connected between the output terminals of the power supply circuit 30 through a voltage dividing resistor 46. A connection point between the temperature sensor 45 and the resistor 46 is electrically connected to the temperature acquisition unit 37 of the microcomputer 31. The temperature acquisition unit 37 acquires the voltage across the resistor 46 to measure the resistance value of the temperature sensor 45 corresponding to the ambient temperature, and outputs the measurement result to the detection processing unit 35.

  When calculating the correction value, the calculation unit 351 of the detection processing unit 35 compensates for the change in the correction value accompanying the change in the ambient temperature based on the output value of the temperature sensor 45 (measurement result of the temperature acquisition unit 37). That is, as shown in FIG. 5, even if the relative humidity is the same, the resistance value of the gas sensor 2 changes if the ambient temperature changes. Therefore, the calculation unit 351 removes the change in the resistance value of the gas sensor 2 due to the ambient temperature change. After that, a correction value is calculated. Specifically, the calculation unit 351 sets the ambient temperature during air adjustment for which known data is set as a reference temperature (for example, 20 ° C.), and calculates a resistance value change corresponding to the difference between the current ambient temperature and the reference temperature. By subtracting (or adding) from the resistance value of the gas sensor 2, temperature compensation of the resistance value is performed. Then, the calculation unit 351 calculates a correction value corresponding to the humidity in the atmosphere using the resistance value of the gas sensor 2 after temperature compensation and the known data.

  Next, the operation | movement for the alarm determination in the microcomputer 31 comprised as mentioned above is demonstrated with reference to the flowchart of FIG.

  The microcomputer 31 performs on / off control of the switching element 40 with the output of the control unit 32, thereby heating the gas sensitive body 20 to about 400 ° C. with the average value of the heater voltage being about 0.9V (S1). At this time (dead period T1), the microcomputer 31 applies a predetermined read voltage between the detection electrode 22 of the gas sensor 2 and the heater combined electrode 21 via the one load resistor 43 from the read unit 33.

  The microcomputer 31 takes in the detection voltage at the acquisition unit 34 immediately before switching from the dead period T1 to the detection period T2, and detects the resistance value of the gas sensitive body 20 at the end of the dead period T1 (S2). At this time, the microcomputer 31 takes in the divided voltage of the temperature sensor 45 and the resistor 46 by the temperature acquisition unit 37 and detects the ambient temperature from the resistance value of the temperature sensor 45 (S3). The microcomputer 31 compensates the resistance value change accompanying the ambient temperature change by the calculation unit 351, and then calculates a correction value according to the humidity in the atmosphere using the resistance value of the compensated gas sensor 2 and the known data. (S4).

  Next, the microcomputer 31 performs on / off control of the switching element 40 with the output of the control unit 32, thereby heating the gas sensitive body 20 to about 80 ° C. with the average value of the heater voltage being about 0.2V (S5). . At this time (detection period T <b> 2), the microcomputer 31 applies a predetermined read voltage between the detection electrode 22 of the gas sensor 2 and the heater combined electrode 21 through the other load resistor 44 from the reading unit 33.

  The microcomputer 31 takes in the detection voltage at the acquisition unit 34 immediately before switching from the detection period T2 to the dead period T1, and detects the resistance value of the gas sensitive body 20 at the end of the detection period T2 (S6). Then, the microcomputer 31 corrects the resistance value of the gas sensitive body 20 by the correction unit 352 using the correction value obtained in the immediately preceding dead period T1 (S7), and the corrected resistance value is set in advance. Alarm judgment is performed by comparing the level with the alarm value that is present (S8). Here, if the corrected resistance value is below the alarm value (S8: Yes), the microcomputer 31 issues a notification from the output unit 36 (S9), and if the corrected resistance value is equal to or greater than the alarm value ( S8: No), the monitoring operation is continued without issuing a report.

  The microcomputer 31 repeatedly performs the alarm determination of the detection target gas (carbon monoxide) by repeatedly executing the operations of S1 to S9 described above.

Next, correction of the detection result according to the humidity change performed by the detection processing unit 35 will be described with a specific example. Below, as an example, the ambient temperature of 20 ° C., the relative humidity of 65% (absolute humidity of 11.2 g / m ³ ), and the gas sensor 2 in the insensitive period T1 in a clean atmosphere (in the standard atmosphere) with no detection target gas. A case where the resistance value is given as known data will be described. Here, a case where the ambient temperature is constant (20 ° C.) and only the relative humidity is changed in order to examine the influence of humidity is illustrated.

  FIG. 7 shows each time point after 10 minutes, 2 hours, 4 hours, 6 hours, and 22 hours after the passage of 65 hours with the relative humidity of 65%, and then the transition to 90% relative humidity. The data which measured the density | concentration of the detection object gas in this detection period T2 are represented. In FIG. 7, the vertical axis represents the concentration (indicated concentration) indicated by the resistance value of the gas sensor 2, and the measurement results at each time point are arranged in time series and plotted in the horizontal axis direction. In FIG. 7, data in the standard atmosphere and in each atmosphere where the concentration of the detection target gas is 50 ppm, 150 ppm, 300 ppm, and 500 ppm are (0), (1), (2), (3), ( 4).

  Since the gas detection device 1 of this embodiment is provided with the filter 15 in the inflow path of the detection target gas to the gas sensor 2, the reaction speed of the gas sensor 2 with respect to humidity is compared with the reaction speed of the gas sensor 2 with respect to the detection target gas. Is late. For this reason, in the gas detection device 1, after the humidity in the atmosphere changes, the resistance value of the gas sensor 2 gradually changes with time, and the indicated concentration indicated by the resistance value gradually changes. For example, when focusing on the detection target gas concentration of 150 ppm ((2) in the figure), the indication concentration is 160 ppm at the time of 65% relative humidity, whereas the humidity changes at 22 hours after the transition to 90% relative humidity. As a result, the indicated concentration has changed to 220 ppm.

  Therefore, the gas detection device 1 calculates the ratio α (= R0 / R1) between the known data R0 and the current resistance value R1 of the gas sensor 2 by the calculation unit 351 in the dead period T1 at each time point. Since the calculated ratio α reflects the change in humidity in the atmosphere (change from 65% to 90%), the calculation unit 351 calculates the correction value β (= f (α)) is calculated. In the detection period T2 at each time point, the gas detection device 1 multiplies the current resistance value of the gas sensor 2 by the correction value β obtained in the immediately preceding dead period T1 by the correction unit 352, thereby obtaining the resistance value of the gas sensor 2. to correct. Since the correction value β is determined according to the humidity in the atmosphere, the correction unit 352 can remove the influence of the humidity change in the atmosphere from the resistance value of the gas sensor 2 by multiplying the correction value β.

  As a result, as shown in FIG. 8, in the data of the detection target gas concentration of 150 ppm, the indicated concentration at the time when 22 hours have passed after the shift to the relative humidity of 90% is improved from 220 ppm before correction to 155 ppm. In FIG. 8, the vertical axis represents the indicated concentration indicated by the resistance value (after correction) of the gas sensor 2, and the measurement results at each time point are arranged in time series and plotted in the horizontal axis direction. In FIG. 8, as in FIG. 7, data in the standard atmosphere and in each atmosphere where the concentration of the detection target gas is 50 ppm, 150 ppm, 300 ppm, and 500 ppm are respectively (0), (1), (2), (3) and (4).

  In short, even if the humidity in the atmosphere changes by correcting the resistance value of the gas sensor 2, the indicated concentration (155 ppm) indicated by the resistance value (after correction) of the gas sensor 2 and the actual detection target gas concentration of 150 ppm The error becomes smaller. Here, in the example shown in FIG. 8, the correction formula (f (α)) is determined so that the correlation between the correction value β and the change ratio of the data measured in the atmosphere with the detection target gas concentration of 150 ppm is improved. Yes.

  7 and 8 exemplify data when the relative humidity in the atmosphere is increased. However, the present invention is not limited to this example, and the present embodiment is implemented even when the relative humidity in the atmosphere is decreased as shown in FIGS. The gas detection device 1 according to the embodiment can correct a change in resistance value caused by a change in humidity. FIGS. 9 and 10 show the time after 1 hour, 5 hours, 21 hours, 28 hours, and 45 hours after the passage of the relative humidity of 65% overnight and after the transition to 40% relative humidity. The data which measured the density | concentration of the detection target gas in the detection period T2 of each time are represented. 9 and 10, the vertical axis represents the concentration (indicated concentration) indicated by the resistance value of the gas sensor 2, and the measurement results at each time point are arranged in time series and plotted in the horizontal axis direction. FIG. Reference numeral 10 denotes data after correction. In FIGS. 9 and 10, data in the standard atmosphere and in each atmosphere where the concentration of the detection target gas is 50 ppm, 150 ppm, 300 ppm, and 500 ppm are (0), (1), (2), and (3), respectively. , (4).

  For example, focusing on the detection target gas concentration of 150 ppm ((2) in the figure), in FIG. 9, the indicated concentration is 160 ppm when the relative humidity is 65%, whereas 45 hours have passed after the transition to the relative humidity of 40%. In this case, the indicated concentration changes to 136 ppm due to the influence of humidity change. On the other hand, in the data after correction, as shown in FIG. 10, the data of the detection target gas concentration of 150 ppm shows that the indication concentration at the time when 45 hours have passed after the shift to the relative humidity of 40% is from 136 ppm before the correction. Improved to 144 ppm.

  According to the gas detection device 1 of the present embodiment described above, the detection processing unit 35 corrects the detection result of the detection target gas with the correction unit 351 that calculates a correction value according to the humidity in the atmosphere. Since the correction unit 352 is included, there is an advantage that it is not easily affected by humidity in the atmosphere. That is, the calculation unit 351 determines the current resistance value of the gas sensor 2 and the known data in the storage unit 38 when the temperature of the gas sensor 2 is at the first set temperature and the sensitivity of the gas sensor 2 to the detection target gas is sufficiently low. From the above, a correction value corresponding to the humidity in the atmosphere is calculated. When the temperature of the gas sensor 2 is at the second set temperature and the sensitivity of the gas sensor 2 with respect to the detection target gas is sufficiently high, the correction unit 352 uses the correction value obtained immediately before to calculate the resistance value of the gas sensor 2. to correct.

  Therefore, even if the ambient temperature is constant, the detection processing unit 35 can obtain the resistance value of the gas sensor 2 excluding the influence of the humidity change by correction, and the detection target gas even when the humidity dependency of the gas sensor 2 is large. There is an advantage that the detection accuracy is difficult to decrease. In addition, in this gas detection device 1, the correction value corresponding to the humidity is calculated using the known data stored in advance in the storage unit 38 and the resistance value of the gas sensor 2, so that it is based on the humidity without using an absolute humidity sensor. The detection result can be corrected.

  Moreover, the gas detection apparatus 1 of this embodiment is provided with the temperature sensor 45, and the calculation part 351 changes the correction value accompanying ambient temperature (temperature in an atmosphere) change based on the output value (resistance value) of the temperature sensor 45. Therefore, the detection target gas can be detected with higher accuracy. In short, the calculation unit 351 calculates the correction value after removing the change in the resistance value of the gas sensor 2 due to the ambient temperature change, so the correction unit 352 uses the correction value according to only the humidity in the atmosphere. 2 can be corrected with high accuracy.

  Furthermore, since the gas detection device 1 has the filter 15 that delays the reaction speed of the gas sensor 2 with respect to humidity as compared with the reaction speed of the gas sensor 2 with respect to the detection target gas, even if there is a sudden humidity change, the gas sensor 1 2 resistance values can be corrected. That is, the gas detection apparatus 1 calculates the correction value, and even if the humidity in the atmosphere changes suddenly until the resistance value is corrected, the filter 15 serves as a buffer and the reaction of the gas sensor 2 is delayed. It is possible to prevent a sudden change in humidity from affecting the resistance value to be corrected. Therefore, even if there is a sudden humidity change, the gas detection device 1 does not suddenly change the resistance value when detecting the detection target gas, and based on the resistance value corrected with an appropriate correction value, The detection target gas can be detected.

  Moreover, since the filter 15 provided in the inflow path of the detection target gas to the gas sensor 2 has a function of removing interfering gases other than the detection target gas, the gas detection device 1 has a resistance value of the gas sensor 2 due to the interfering gas. There is an advantage that it is not easily affected by changes. That is, when the gas detection device 1 calculates the correction value corresponding to the humidity in the atmosphere by the calculation unit 351 when the temperature of the gas sensor 2 is at the first set temperature, the resistance value of the gas sensor 2 due to the interfering gas is calculated. Less susceptible to change. That is, since the calculation unit 351 can calculate the correction value with almost no influence of the interfering gas, the correction unit 352 uses the correction value according to only the humidity in the atmosphere to accurately calculate the resistance value of the gas sensor 2. Correction can be made.

  By the way, in the said embodiment, although 1st preset temperature is set to temperature (about 400 degreeC) higher than 2nd preset temperature (about 80 degreeC), it is not restricted to this example, It is with respect to detection object gas. The gas sensor 2 can be set as appropriate as long as the sensitivity of the gas sensor 2 is less than a predetermined value. In this case, it is preferable that the humidity dependency of the resistance value of the gas sensor 2 is larger when the gas sensor 2 is at the first set temperature than when the gas sensor 2 is at the second set temperature. That is, if the humidity dependency of the resistance value is large at the first set temperature, the humidity is easily reflected in the correction value when the calculation unit 351 calculates the correction value using the resistance value of the gas sensor 2. As a result, the calculation unit 351 can obtain a correction value according to humidity with high accuracy, and the correction unit 352 can correct the resistance value of the gas sensor 2 with high accuracy.

Further, in the gas detection device 1, the detection target gas may not be carbon monoxide but may be flammable gas methane (CH ₄ ), and in this case, the first set temperature and the second set temperature The relationship is the reverse of the above embodiment. That is, since the gas sensor 2 has sufficient sensitivity to methane when the temperature of the gas sensitive body 20 is about 400 ° C., the first set temperature is set to about 80 ° C., and the second set temperature is about 400 ° C. Set to ° C. Even in this case, the calculation unit 351 calculates the correction value according to the humidity in the atmosphere during the insensitive period in which the gas sensor 2 is at the first set temperature, and the correction unit 352 detects that the gas sensor 2 is at the second set temperature. During the period, the resistance value of the gas sensor 2 is corrected using the correction value obtained immediately before.

  Furthermore, the gas detection apparatus 1 may use a plurality of types of gases as detection target gases. For example, when two types of gases, carbon monoxide and methane, are used as detection target gases, the gas detection device 1 has a temperature (about 80 ° C.) at which the gas sensor 2 has sufficient sensitivity for carbon monoxide and sufficient for methane. Two temperatures, a temperature having a sensitivity (about 400 ° C.), are set as the second set temperature. In this case, the gas detection device 1 sets the temperature at which the sensitivity of the gas sensor 2 is less than a predetermined value for both carbon monoxide and methane as the first set temperature, and the control unit 32 sets the first setting. The heater voltage is controlled so as to periodically repeat the temperature and the two second set temperatures. At this time, the first set temperature may be an intermediate temperature between the two second set temperatures, or may be a temperature higher or lower than any second set temperature.

  In this case, the calculation unit 351 calculates a correction value corresponding to the humidity in the atmosphere during the dead period in which the gas sensor 2 is at the first set temperature, and the correction unit 352 detects that the gas sensor 2 is at the second set temperature. During the period, the resistance value of the gas sensor 2 is corrected using the correction value obtained immediately before. That is, the detection processing unit 35 corrects the resistance value of the gas sensor 2 by the correction unit 352 when the gas sensor 2 is at one second set temperature at which the gas sensor 2 has sufficient sensitivity to carbon monoxide. The resistance value is used to detect carbon monoxide as the detection target gas. Further, when the gas sensor 2 is at the other second set temperature at which the gas sensor 2 has sufficient sensitivity to methane, the correction processing unit 352 corrects the resistance value of the gas sensor 2 and corrects the resistance value after correction. Detect methane as the detection target gas. Thereby, the gas detection apparatus 1 can detect multiple types of gas in the detection period with one gas sensor 2.

  In the above embodiment, the calculation unit 351 uses the function (f (α)) of the resistance value ratio α of the gas sensor 2 as the correction value β. However, the present invention is not limited to this configuration. The current relative humidity may be obtained based on the value and the known data, and the correction value may be calculated from this relative humidity. In this case, the resistance value of the gas sensor 2 that is associated with each relative humidity on a one-to-one basis for a plurality of relative humidity is stored as known data in the storage unit 38, and further a correspondence that represents the correspondence between the relative humidity and the correction value. A table is stored in advance. The calculation unit 351 obtains the relative humidity in the current atmosphere by comparing the resistance value of the gas sensor 2 with the known data, and calculates a correction value corresponding to the obtained relative humidity by referring to the correspondence table.

  Moreover, in the said embodiment, the filter 15 which has a function which delays the reaction speed of the gas sensor 2 with respect to humidity, and removes interfering gas other than detection target gas is provided in the inflow path | route of detection target gas to the gas sensor 2. However, the filter 15 may be omitted. That is, the filter 15 acts as a buffer when the humidity changes suddenly, delays the reaction of the gas sensor 2, and makes it difficult for the resistance value of the gas sensor 2 to change due to the interfering gas. If the performance is satisfied, the filter 15 may be omitted.

DESCRIPTION OF SYMBOLS 1 Gas detection apparatus 2 Gas sensor 15 Filter 32 Control part 35 Detection process part 351 Calculation part 352 Correction | amendment part 38 Memory | storage part 45 Temperature sensor

Claims (4)

A gas sensor whose resistance value changes according to the concentration of the detection target gas, a detection processing unit for detecting the detection target gas in the atmosphere based on the resistance value of the gas sensor, and the gas sensor associated with humidity in a standard atmosphere A storage unit that previously stores the resistance value of the gas sensor as known data, and a control unit that controls the temperature of the gas sensor so as to switch between the first set temperature and the second set temperature,
The detection processing unit calculates a correction value according to humidity in the atmosphere from the resistance value of the gas sensor and the known data in the storage unit when the temperature of the gas sensor is at the first set temperature. And a correction unit that corrects the detection result of the detection target gas using the correction value obtained immediately before by the calculation unit when the temperature of the gas sensor is at the second set temperature. ,
The detection target gas is a plurality of types of gases,
The first set temperature is a temperature at which the sensitivity of the gas sensor with respect to all of the plurality of types of gases is less than a predetermined value,
The second set temperature is a plurality of types of temperatures at which the sensitivity of the gas sensor with respect to each of the plurality of types of gases is equal to or higher than the predetermined value,
The control unit alternately switches between the first set temperature and the second set temperature, and each of the plurality of types of temperatures and the first set temperature as the second set temperature is a cycle. Control the temperature of the gas sensor to be repeated automatically ,
The calculation unit calculates the correction value when the temperature of the gas sensor is the first set temperature and immediately before the temperature of the gas sensor is switched from the first set temperature to the second set temperature. Calculate
The correction unit sets the correction value when the temperature of the gas sensor is the second set temperature and immediately before the temperature of the gas sensor is switched from the second set temperature to the first set temperature. A gas detection apparatus using the correction result to correct the detection result . A temperature sensor whose output value changes according to the temperature in the atmosphere;
The gas detection device according to claim 1, wherein the calculation unit compensates for a change in the correction value accompanying a temperature change in the atmosphere based on an output value of the temperature sensor.   The filter for delaying the reaction speed of the gas sensor with respect to humidity as compared with the reaction speed of the gas sensor with respect to the detection target gas is provided in an inflow path of the detection target gas to the gas sensor. Or the gas detection apparatus of 2.   The humidity dependency of the resistance value is larger when the gas sensor is at the first set temperature than when the gas sensor is at the second set temperature. The gas detection apparatus as described.

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