JP6098867B2 - Livestock manure manufacturing method - Google Patents

Livestock manure manufacturing method Download PDF

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JP6098867B2
JP6098867B2 JP2012261164A JP2012261164A JP6098867B2 JP 6098867 B2 JP6098867 B2 JP 6098867B2 JP 2012261164 A JP2012261164 A JP 2012261164A JP 2012261164 A JP2012261164 A JP 2012261164A JP 6098867 B2 JP6098867 B2 JP 6098867B2
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feces
manure compost
livestock manure
chicken
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邦彦 小倉
邦彦 小倉
利明 大倉
利明 大倉
道文 高山
道文 高山
芳胤 染谷
芳胤 染谷
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株式会社リオン
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/133Renewable energy sources, e.g. sunlight
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/20Waste processing or separation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/78Recycling of wood or furniture waste

Description

本発明は家畜糞堆製造方法に係り、特に、家畜糞を用いて製造され家畜糞堆肥製造方法に関する。 The present invention relates to livestock manure compost Manufacturing method, in particular, production method relates manufactured livestock manure compost fertilizer that will be manufactured using livestock manure.

牛糞,豚糞,鶏糞等の家畜糞を堆肥化する方法が広く知られている(例えば、特許文献1)。
特許文献1の堆肥製造方法では、鶏糞に木片チップと微生物を混入した60℃以上の混合物を、堆肥舎で6.5日間、その後発酵槽で23.5日間発酵させる。得られた発酵物から、選別機で木片チップを回収した後、鶏糞堆肥を養生施設に送り、切返しをしながら60℃以上で3.8日間発酵させて、鶏糞堆肥が完成する。
このように製造された家畜糞堆肥は、低コストなだけでなく、含有するリン酸の殆どが、植物の根から分泌される有機酸により溶解・吸収される緩効性で、土壌に固定されにくく持続性ある水不溶クエン酸溶性リン酸であって、化成肥料のリン酸と同様以上の高い肥効を示す。
A method of composting livestock feces such as cattle feces, pig feces and chicken feces is widely known (for example, Patent Document 1).
In the method for producing compost of Patent Document 1, a mixture of wood chips and microorganisms mixed with chicken manure is fermented at 60 ° C. or more for 6.5 days and then in a fermenter for 23.5 days. From the obtained fermented material, chip chips are collected by a sorter, and then the chicken manure compost is sent to a curing facility and fermented at 60 ° C. or higher for 3.8 days while being turned over to complete the chicken manure compost.
Livestock manure compost produced in this way is not only low in cost, but also has a slow release, in which most of the phosphoric acid contained is dissolved and absorbed by organic acids secreted from the plant roots, and is fixed to the soil. It is a difficult and long-lasting water-insoluble citric acid-soluble phosphoric acid, and exhibits a high fertilizing effect similar to the phosphoric acid of chemical fertilizer.

また、家畜糞堆肥は、毎日膨大な量が発生し廃棄物となるべき家畜糞をリサイクルするものであって、畜産業側の廃棄コストを大幅に削減すると同時に、耕種側でも、高価な化成リン酸肥料の代替品となるため、畜産業側,耕種側双方の大幅なコスト削減につながるものである。
更に、天然資源であるリン鉱石は枯渇の危機に瀕しており、リン鉱石をほぼ全量輸入に依存しているわが国において、リン資源の確保は重要な課題となっている中、化成肥料と同様以上の肥効を示し、リン酸を含有する家畜糞堆肥は、化成肥料の代替品として益々重要度を増している。
In addition, livestock manure compost recycles livestock manure, which is generated in large amounts every day and should become waste. It greatly reduces the disposal costs on the livestock industry side, and at the same time, it is an expensive chemical phosphorus on the farming side. Since it becomes a substitute for acid fertilizer, it leads to significant cost reduction on both the livestock industry side and the farming side.
In addition, phosphorus ore, which is a natural resource, is on the verge of depletion, and in Japan, which depends on almost all imports of phosphorus ore, securing phosphorus resources is an important issue. Livestock manure compost showing the above-mentioned fertilization effect and containing phosphoric acid is becoming increasingly important as a substitute for chemical fertilizer.

特開2008−13380号公報(段落0014〜0015,図1)JP 2008-13380 (paragraphs 0014 to 0015, FIG. 1)

しかし、特許文献1記載の堆肥製造方法によれば、家畜糞堆肥の完成までに1か月以上を要し、その間、大量の家畜糞を保管,処理する施設が必要となる。近年の大規模農業化に伴い増大化した家畜糞に対して堆肥化が間に合わず、一方、家畜糞を野積みにすると、地下水が汚染される恐れがあるため、条例等によって野積みが禁止されている。家畜糞の処理は、農場経営における課題となっている。
更に、長期間の家畜糞堆肥製造中及び耕種側での堆肥使用中において、悪臭による環境悪化の懸念もある。家畜糞処理時の悪臭を抑制するために、脱臭剤を使用する方法もあるが、悪臭を完全に元から取り除く脱臭剤は知られていない。
However, according to the compost production method described in Patent Document 1, it takes one month or more to complete livestock manure compost, and a facility for storing and processing a large amount of livestock manure is required during that period. Composting is not in time for livestock excrement that has increased in recent years due to large-scale agriculture. On the other hand, if livestock excrement is piled up, groundwater may be contaminated. ing. The treatment of livestock dung is a challenge in farm management.
Furthermore, in the long term livestock manure composting and in compost use in hydroponic seed side, Ru concerns mower of environmental degradation due to bad smell. There is a method of using a deodorizing agent in order to suppress malodors during the treatment of livestock excrement, but no deodorizing agent that completely removes malodors from the original is known.

本発明は、上記事情に鑑みてなされたものであって、その目的は、家畜糞から短期間で製造され糞臭のない家畜糞堆肥製造方法を提供することにある。
本発明の他の目的は、堆肥製造中及び完成後において悪臭のない家畜糞堆肥製造方法を提供することにある。
The present invention was made in view of the above circumstances, an object thereof is to provide a livestock manure compost fertilizer Manufacturing method no fecal odor that will be manufactured in a short period of time from the livestock manure.
Another object of the present invention is to provide a malodor-free livestock manure compost fertilizer Manufacturing method during composting and after completion.

前記課題は、請求項の家畜糞堆肥製造方法によれば、家畜糞がpH5未満であるときには、前記家畜糞をpH5以上に調整するpH調整工程と、前記家畜糞に、玄武岩および安山岩を含む群からなる少なくとも一の堆積岩土壌の無機酸抽出液又は該抽出液の水溶液であって、該抽出液又は該抽出液の水溶液に含まれる金属中で鉄を最も多く含み、該鉄が液中で、pH5より高いpHで、Fe(OH) として存在する家畜糞処理剤を添加する添加工程を行うことにより、含有窒素量の2倍以上の量で、かつ、含有カリウム量の2倍以上の量のリン酸を含み、フェリハイドライトと家畜糞中の有機物との複合体を含む糞臭のない家畜糞堆肥を製造することにより解決される。
このように構成しているので、家畜糞の糞臭が極めて短期間で除去され、従来1か月〜3か月程度かかっていた家畜糞堆肥の製造期間を、数日〜2週間程度まで、大幅に短縮することができる。
その結果、家畜糞堆肥製造において、発酵工程を行う必要がなく、製造設備の簡素化及び製造工程の更なる短縮化が可能となる。
更に、本発明の家畜糞堆肥製造方法によれば、家畜糞堆肥製造中も、仕掛品に糞臭が発生せず、近隣住民への悪臭公害対策が不要となり、家畜糞堆肥製造施設の設置場所の自由度が高まる。
また、大規模農業化に伴い増大化した家畜糞を、簡単な設備で素早く処理することが可能である。
また、添加工程でpH5以上の家畜糞を添加しているため、混合物中の家畜糞処理剤のpHを5以上に保持することが可能となり、家畜糞処理剤中に、フェリハイドライトの原料となるFe(OH)(水酸化鉄)を存在させることが可能となる。その結果、家畜糞に家畜糞処理剤を添加することによって、Fe(OH)からフェリハイドライトの複合体が形成され、複合体形成時、有機物の芳香環や−SH基等が切断されて、糞臭が除去される。また、Fe(OH)からフェリハイドライトの複合体形成時、Fe(OH)の鉄が反応して2価になるときに発生するスーパーオキサイドによっても、家畜糞中の臭い物質が酸化分解されて、糞臭が除去される。
According to the method for producing livestock manure compost according to claim 1 , when the livestock feces are less than pH 5 , the livestock feces include a pH adjusting step for adjusting the livestock feces to pH 5 or more, and the livestock feces include basalt and andesite An inorganic acid extract of at least one sedimentary rock soil consisting of a group or an aqueous solution of the extract, wherein the extract contains the most iron in the metal contained in the extract or the aqueous solution of the extract, , at higher pH than pH 5, by performing the adding step of adding the livestock manure treatment agent present as Fe (OH) 3, in an amount at least twice the nitrogen content, and, more than twice the content amount of potassium This is achieved by producing livestock manure compost free of fecal odor containing a complex of ferrihydrite and organic matter in livestock feces.
Because it is configured in this way, the fecal odor of livestock feces is removed in a very short period of time, and the production period of livestock feces compost, which has conventionally taken about 1 to 3 months, can be from several days to about 2 weeks, It can be greatly shortened.
As a result, in the production of livestock manure compost, it is not necessary to perform a fermentation process, and it is possible to simplify the production facility and further shorten the production process.
Furthermore, according to the method for producing livestock manure compost of the present invention, during the production of livestock manure compost, feces odor does not occur in the work in progress, and no odor pollution measures are required for neighboring residents, and the place where the livestock manure compost production facility is installed The degree of freedom increases.
In addition, livestock excrement that has increased with large-scale agriculture can be quickly processed with simple equipment.
In addition , since livestock feces having a pH of 5 or more are added in the addition step, it becomes possible to maintain the pH of the livestock fecal treatment agent in the mixture at 5 or more. Fe (OH) 3 (iron hydroxide) can be present. As a result, a ferrihydrite complex is formed from Fe (OH) 3 by adding a livestock feces treatment agent to livestock feces, and when the complex is formed, the aromatic ring or —SH group of the organic matter is cleaved. , Fecal odor is removed. In addition, when a complex of Fe (OH) 3 and ferrihydrite is formed, odorous substances in livestock feces are also oxidatively decomposed by superoxide generated when iron of Fe (OH) 3 reacts to become divalent. As a result, fecal odor is removed.

また、フェリハイドライトの原料となるFe(OH)(水酸化鉄)を存在させることにより、家畜糞中の有機物がアルミニウム、マグネシウム等の他の元素と複合体を形成してしまうことを防止できる。家畜糞中の有機物との複合体を、生体や生態系に悪影響を及ぼす可能性が極めて小さい鉄を含むものとすることが可能となるのである。さらに、反応が起こる表面積が大きく、またpH変化によって起こる変異荷電特性に起因する物理化学反応力が大きいフェリハイドライトを含む複合体を形成することが可能となるのである。 In addition, the presence of Fe (OH) 3 (iron hydroxide), the raw material for ferrihydrite, prevents organic matter in livestock feces from forming complexes with other elements such as aluminum and magnesium. it can. The complex with the organic matter in livestock feces can contain iron that has a very low possibility of adversely affecting the living body and the ecosystem. Furthermore, it is possible to form a complex containing ferrihydrite having a large surface area in which the reaction occurs and a large physicochemical reaction force due to the mutated charge characteristic caused by pH change.

また、フェリハイドライトは、酸素吸着による酸化防止効果、肉類の鮮度保持効果、嫌気性菌の繁殖抑制による抗菌・制菌効果等を有することが知られており、本実施形態によりできた家畜糞中の有機物とフェリハイドライトとの複合体は、これらの効果をも奏する。
更に、家畜糞中の有機物が、フェリハイドライドとの複合体を形成することにより、堆肥中のリン酸等の肥料成分が溶脱し難く、安定した堆肥とすることができる。
In addition, ferrihydrite is known to have an antioxidant effect due to oxygen adsorption, a meat freshness retaining effect, an antibacterial and antibacterial effect due to the inhibition of anaerobic bacterial growth, and the like. The complex of the organic substance and ferrihydrite therein also has these effects.
Furthermore, when the organic matter in livestock feces forms a complex with ferrihydride, fertilizer components such as phosphoric acid in the compost are not easily leached and stable compost can be obtained.

また、含有窒素量の2倍以上の量で、かつ、含有カリウム量の2倍以上の量のリン酸を含み、フェリハイドライトと家畜糞中の有機物との複合体を含むため、化成肥料以上の肥効を示す家畜糞堆肥の製造が可能となり、高価な化成リン酸肥料の代替品となるため、耕種側の肥料コストを大幅に削減できる。また、枯渇の危機に瀕しているリン鉱石を補うリン資源を提供することができる。 In addition, it contains phosphoric acid in an amount more than twice the amount of nitrogen and more than twice the amount of potassium, and contains a complex of ferrihydrite and organic matter in livestock dung, making it more than chemical fertilizer It becomes possible to produce livestock manure compost showing the fertilizer effect, and it becomes an alternative to expensive chemical phosphate fertilizer, so that the fertilizer cost on the cultivating side can be greatly reduced. In addition, phosphorus resources can be provided to supplement phosphorus ore that is in danger of depletion.

また、前記添加工程では、前記家畜糞に、木材チップを含む水分調整材の添加を行うことなく、前記家畜糞処理剤を添加するように構成してもよい。Moreover, you may comprise so that the said livestock feces treatment agent may be added to the said livestock feces, without adding the moisture adjusting material containing a wood chip to the said livestock feces.
このように構成しているので、木材チップ等の水分調整材の添加も回収も不要であり、簡易に家畜糞堆肥を製造できる。Since it comprises in this way, addition and collection | recovery of moisture adjusting materials, such as a wood chip, are unnecessary, and livestock manure compost can be manufactured easily.

前記添加工程の後で、発酵工程を経ることなく、前記家畜糞処理剤が添加された前記家畜糞を乾燥させる乾燥工程を行うように構成してもよい。
このように、乾燥工程を行うことにより、乾燥した取引し易い形態の堆肥を得ることができる。
また、発酵工程を行わないため、家畜糞堆肥の製造にかかる日数を大幅に短縮できる。製造設備の簡素化及び製造工程の更なる短縮化が可能となる。家畜糞の糞臭が極めて短期間で除去され、従来1か月〜3か月程度かかっていた家畜糞堆肥の製造期間を、数日〜2週間程度まで、大幅に短縮することができる。
You may comprise so that the drying process of drying the said livestock feces to which the said livestock feces treatment agent was added may be performed after the said addition process, without passing through a fermentation process.
Thus, by performing the drying step, it is possible to obtain a compost having a dry and easy to trade form.
Moreover, since the fermentation process is not performed, the number of days required for production of livestock manure compost can be greatly reduced. Simplification of manufacturing equipment and further shortening of the manufacturing process are possible. The fecal odor of livestock feces is removed in a very short period of time, and the production period of livestock feces compost, which conventionally takes about 1 to 3 months, can be greatly shortened to several days to about 2 weeks.

また、前記添加工程の後、前記乾燥工程前に、前記家畜糞処理剤が添加された前記家畜糞を撹拌して均一混合物を得る撹拌工程を行い、前記乾燥工程では、前記均一混合物を15日間未満の日数乾燥させるように構成してもよい。
このように構成すると、家畜糞堆肥製造方法において、発酵工程を行わないため、家畜糞堆肥の製造にかかる日数を大幅に短縮できる。また、木材チップ等の水分調整材の添加も回収も不要であり、簡易に家畜糞堆肥を製造できる。
Further, after the addition step and before the drying step, the livestock manure treatment agent performs homogeneous mixture resulting Ru stirring step by stirring the livestock manure that is added, the drying step is, the homogeneous mixture 15 You may comprise so that it may dry for days less than a day.
If comprised in this way, in a livestock dung compost manufacturing method, since a fermentation process is not performed, the days concerning manufacture of livestock dung compost can be reduced significantly. In addition, it is not necessary to add or recover moisture adjusting materials such as wood chips, and it is possible to easily produce livestock manure compost.

また、前記添加工程では、前記家畜糞処理剤を前記家畜糞に散布し、前記乾燥工程は、5日以上の日数の天日干しにより行うように構成してもよい。
このように構成すると、乾燥装置等大掛かりな製造設備導入が不要で、製造コストや製造方法導入の手間等が省かれ、簡易に家畜糞堆肥を製造できる。また、大掛かりな設備が不要なため、農家の大小を問わず家畜糞堆肥の製造ができる。
In the addition step, the livestock feces treatment agent may be sprayed on the livestock feces, and the drying step may be performed by sun-drying for 5 days or more .
With this configuration, it is not necessary to introduce a large-scale manufacturing facility such as a drying apparatus, and the manufacturing cost and the labor for introducing the manufacturing method are omitted, so that livestock manure compost can be easily manufactured. Moreover, since no large-scale equipment is required, it is possible to produce livestock manure compost regardless of the size of the farmer.

本発明によれば、家畜糞の糞臭が極めて短期間で除去され、従来1か月〜3か月程度かかっていた家畜糞堆肥の製造期間を、数日〜2週間程度まで、大幅に短縮することができる。
その結果、家畜糞堆肥製造において、発酵工程を行う必要がなく、製造設備の簡素化及び製造工程の更なる短縮化が可能となる。
更に、本発明の家畜糞処理剤は、家畜糞堆肥製造中も、仕掛品に糞臭が発生せず、近隣住民への悪臭公害対策が不要となり、家畜糞堆肥製造施設の設置場所の自由度が高まる。
また、大規模農業化に伴い増大化した家畜糞を、簡単な設備で素早く処理することが可能である。
According to the present invention, the fecal odor of livestock feces is removed in a very short period of time, and the production period of livestock feces compost, which previously took about 1 to 3 months, has been greatly shortened to several days to about 2 weeks. can do.
As a result, in the production of livestock manure compost, it is not necessary to perform a fermentation process, and it is possible to simplify the production facility and further shorten the production process.
Furthermore, the livestock manure treatment agent of the present invention does not generate feces odors in the work in progress during the production of livestock manure compost, eliminates the need for foul odor pollution measures to neighboring residents, and provides freedom in the location of the livestock manure compost production facility. Will increase.
In addition, livestock excrement that has increased with large-scale agriculture can be quickly processed with simple equipment.

以下、本発明の実施形態について説明する。なお、以下に説明する構成は、本発明を限定するものではなく、本発明の趣旨に沿って各種改変することができることは勿論である。
本実施形態は、家畜糞処理液と鶏糞を原料として、鉄水和酸化物の一種であるフェリハイドライトと鶏糞中の有機物との複合体からなる鶏糞堆肥を製造する方法である。
本実施形態では、家畜糞として鶏糞を用いるが、そのほか、牛,豚,羊,山羊等を含むあらゆる家畜の糞についても適用可能である。
ここで、フェリハイドライトと鶏糞中の有機物との複合体とは、非晶質フェリハイドライト(以下フェリハイドライトという)と有機物との複合体をいう。
Hereinafter, embodiments of the present invention will be described. In addition, the structure demonstrated below does not limit this invention, Of course, it can change variously along the meaning of this invention.
This embodiment is a method for producing chicken manure compost composed of a complex of ferrihydrite, which is a kind of iron hydrated oxide, and organic matter in chicken manure, using livestock manure treatment liquid and chicken manure as raw materials.
In this embodiment, chicken manure is used as the animal manure, but it can also be applied to any animal manure including cattle, pigs, sheep, goats and the like.
Here, the complex of ferrihydrite and organic matter in chicken manure refers to a complex of amorphous ferrihydrite (hereinafter referred to as ferrihydrite) and organic matter.

フェリハイドライト(Ferrihydrite)とは、一般式5Fe・9HOで表される非晶質水和酸化物である。一般的には、地球表層において初期段階で形成される低結晶度の鉄鉱物として知られている。
フェリハイドライトは、有機化合物のカルボキシル基やカルボニル基のOH端、O端と配位結合する性質があり凝集体を形成する。比表面積が約200(m/g)と大きく、有機化合物のOH端、O端との反応に供される場が広いため、触媒能が高く、凝集体を形成する能力が高いことが分かっている。
また、本実施形態の家畜糞処理液及びその希釈液が、特許請求の範囲の家畜糞処理剤に該当する。
Ferrihydrite is an amorphous hydrated oxide represented by the general formula 5Fe 2 O 3 .9H 2 O. Generally, it is known as a low-crystallinity iron mineral formed at an early stage in the earth's surface layer.
Ferrihydrite has the property of coordinating with the OH end and O end of a carboxyl group or carbonyl group of an organic compound, and forms an aggregate. The specific surface area is as large as about 200 (m 2 / g), and the field used for the reaction with the OH end and O end of organic compounds is wide, so the catalytic ability is high and the ability to form aggregates is high. ing.
Moreover, the livestock feces treatment liquid and its dilution liquid of this embodiment correspond to the livestock feces treatment agent of a claim.

(家畜糞処理液)
本実施形態の家畜糞処理液は、玄武岩、安山岩等の堆積岩土壌に、無機酸を添加して抽出した天然由来のイオン化ミネラル濃縮液を用いる。このイオン化ミネラル濃縮液としては、例えば、株式会社リオン製のクレイエクストラクトを使用することができる。
家畜糞処理液は、玄武岩、安山岩等の堆積岩土壌(粘土)に、濃度10〜20重量%の硫酸水溶液を添加して酸可溶成分を抽出したものである。なお、硫酸の代わりに、硝酸、これらの無機酸を混合したもの、またはその水溶液等を用いてもよいが、濃度10〜20重量%の硫酸水溶液を用いると、家畜糞処理液を効率よく得ることができる。
(Livestock dung treatment liquid)
As the livestock feces treatment liquid of this embodiment, a naturally-derived ionized mineral concentrate extracted by adding an inorganic acid to sedimentary rock soil such as basalt and andesite is used. As this ionized mineral concentrate, for example, a clay extract manufactured by Rion Co., Ltd. can be used.
The livestock dung treatment liquid is an acid-soluble component extracted by adding a 10-20 wt% sulfuric acid aqueous solution to sedimentary rock soil (clay) such as basalt and andesite. In addition, instead of sulfuric acid, nitric acid, a mixture of these inorganic acids, or an aqueous solution thereof may be used. However, when a sulfuric acid aqueous solution having a concentration of 10 to 20% by weight is used, a livestock excrement treatment liquid is efficiently obtained. be able to.

本実施形態の家畜糞処理液は、鉄(Fe)を主要構成成分とし、その他マンガン(Mn)、マグネシウム(Mg)、カルシウム(Ca)等のカチオンも含む。ただし、マグネシウム量およびカルシウム量の和は、ミネラル液に含有される鉄の量の30重量%未満である。
家畜糞処理液は、鉄を7000〜15000(ppm)程度含み、pHは、0.1〜0.2程度である。
また、家畜糞処理液に含まれる高分子の径は、3〜8(nm)程度である。
The livestock feces treatment liquid of this embodiment contains iron (Fe) as a main component, and also contains cations such as manganese (Mn), magnesium (Mg), and calcium (Ca). However, the sum of the amount of magnesium and the amount of calcium is less than 30% by weight of the amount of iron contained in the mineral liquid.
The livestock dung treatment liquid contains about 7000 to 15000 (ppm) of iron, and the pH is about 0.1 to 0.2.
Moreover, the diameter of the polymer contained in the livestock feces treatment liquid is about 3 to 8 (nm).

本実施形態の家畜糞処理液に含まれる鉄は、pHによって異なる形態で存在する。pH3以下では、鉄は、Fe+、pH3〜pH4では、Fe3+とFe(OH) 、pH4〜pH5では、Fe3+とFe(OH)2+とFe(OH) 、pH5より高いpHでは、Fe(OH)2+とFe(OH) とFe(OH)として存在する。 Iron contained in the livestock feces treatment liquid of the present embodiment exists in different forms depending on pH. The pH3 or less, iron, Fe 3 +, in PH3~pH4, the Fe 3+ and Fe (OH) 2 +, pH4~pH5 , higher than the Fe 3+ and Fe (OH) 2+ and Fe (OH) 2 +, pH5 In pH, it is present as Fe (OH) 2+ and Fe (OH) 2 + and Fe (OH) 3.

また、本実施形態の家畜糞処理液の母材である土壌を硫酸抽出した残渣は、純鉄(Fe(3+))と、非結晶質の針鉄鉱(α−FeOOH)とを含んでいる。ここで、純鉄(Fe(3+))とは、変化しにくい安定した鉄をいい、酸化されず、溶出しないという性質を有する鉄をいう。   Moreover, the residue which extracted the soil which is a base material of the livestock manure processing liquid of this embodiment with sulfuric acid contains a pure iron (Fe (3+)) and an amorphous goethite ((alpha) -FeOOH). Here, pure iron (Fe (3+)) refers to stable iron that does not easily change, and refers to iron that is not oxidized and does not elute.

本実施形態の家畜糞処理液の一例の組成を、表1に示す。

Figure 0006098867
Table 1 shows the composition of an example of the livestock feces treatment liquid of this embodiment.
Figure 0006098867

また、本実施形態で用いられる家畜糞処理液の母材である土壌を硫酸で抽出した残渣の一例を、メスバウア分光分析法で測定した結果、常磁性のFe(3+)と、スピネル8面体位置のFe、スピネル・4面体位置のFeと、α−Feとを含んでいることが分かった。残渣に含まれるFeのうち、6%が常磁性のFe(3+)、38%がスピネル・8面体位置のFe、31%がスピネル・4面体位置のFe、25%がα−Feであるとの測定結果を得た。 Moreover, as a result of measuring an example of the residue which extracted the soil which is a base material of the livestock feces treatment liquid used by this embodiment with sulfuric acid by Mossbauer spectroscopy, paramagnetic Fe (3+) and spinel octahedral position Fe 3 O 4 , spinel-tetrahedral Fe 3 O 4 and α-Fe 2 O 3 were found to be contained. Among the Fe contained in the residue, 6% of the paramagnetic Fe (3 +), 38% of Fe 3 O 4 of spinel octahedral positions, 31% Fe 3 O 4 of spinel tetrahedral position, 25% A measurement result of α-Fe 2 O 3 was obtained.

本実施形態の家畜糞処理液は、消臭殺菌効果を有する。
これは、Fe(OH)からフェリハイドライトの複合体が形成され、複合体形成時、有機物の芳香環や−SH基等が切断されて、糞臭が除去されると考えられる。
また、家畜糞処理液のpH5以上における主成分Fe(OH)の鉄が次の化学式(1)により反応して2価になるときに発生するスーパーオキサイドにより、臭い物質を酸化分解すると考えられる。
4Fe(OH)+8H→4Fe2++10HO+O・・・(化学式1)
The livestock feces treatment liquid of this embodiment has a deodorizing and sterilizing effect.
This is considered to be because a ferrihydrite complex is formed from Fe (OH) 3, and when the complex is formed, the aromatic ring or —SH group of the organic substance is cleaved to remove feces odor.
Further, it is considered that the odorous substance is oxidatively decomposed by superoxide generated when iron of the main component Fe (OH) 3 at pH 5 or higher of the livestock manure treatment solution reacts to become divalent by the following chemical formula (1). .
4Fe (OH) 3 + 8H + → 4Fe 2+ + 10H 2 O + O 2 (Chemical formula 1)

また、一般的に、酸化状態では、Oが電子受容体となるため、酸化状態における有機物の最終産物はCOとHOであるが、還元状態では、NO,SO,COが電子受容体となるため、有機物の最終産物としてN,HS,CHも発生する。
式1の反応の酸化還元電位は、EH=―0.183Vであり、メタンガスの発生する電位はEH=―0.253Vであるため、嫌気状態になるのを防ぎ、メタンガス等の発生を抑制する。
In general, since O 2 becomes an electron acceptor in an oxidized state, the final products of organic substances in the oxidized state are CO 2 and H 2 O. In the reduced state, NO 3 , SO 4 , CO 2 Becomes an electron acceptor, and N 2 , H 2 S, and CH 4 are also generated as a final product of organic matter.
Since the oxidation-reduction potential of the reaction of Formula 1 is EH = −0.183 V and the potential generated by methane gas is EH = −0.253 V, it prevents an anaerobic state and suppresses the generation of methane gas and the like. .

(家畜糞堆肥の製造方法)
本実施形態の家畜糞堆肥の製造方法について、鶏糞を用いて鶏糞堆肥を製造する場合を例として説明する。
まず、家畜糞処理液を、水で10倍〜3000倍に希釈し、pH5以上、好ましくはpH5〜6の希釈液を得る。このとき、同じ倍率で希釈しても、希釈に用いる水の種類によって得られる希釈液のpHが変化するが、本実施形態では、純水を用いる。
次いで、採卵鶏の鶏糞を準備する。採卵鶏の鶏糞としては、pH5以上のものを用いる。なお、鶏の腸内pHを下げるよう腸内pH調整を行わなければ、採卵鶏の鶏糞のpHは通常6前後であり、そのまま用いることができる。鶏糞のpHが5未満の場合、pH5以上に調整する。
(Manufacturing method of livestock manure compost)
About the manufacturing method of livestock manure compost of this embodiment, the case where chicken manure compost is manufactured using chicken manure is explained as an example.
First, the livestock excrement treatment solution is diluted 10 to 3000 times with water to obtain a diluted solution of pH 5 or more, preferably pH 5 to 6. At this time, even if it is diluted at the same magnification, the pH of the diluted solution obtained varies depending on the type of water used for dilution. In this embodiment, pure water is used.
Next, chicken droppings of the egg-collecting chicken are prepared. As chicken droppings of the egg-collecting chicken, one having a pH of 5 or more is used. If the intestinal pH is not adjusted to lower the intestinal pH of the chicken, the pH of the chicken manure of the egg-laying chicken is usually around 6, and can be used as it is. If the pH of the chicken manure is less than 5, adjust to pH 5 or higher.

家畜糞処理液は、pH5未満では、Fe(OH)が存在せず、Fe3+とFe(OH)2+とFe(OH) の形態となる。Fe3+とFe(OH)2+とFe(OH) の形態のときには、鶏糞中の有機物は、鉄ではなくアルミニウム、マグネシウム、カルシウム等の他の元素と複合体を形成してしまうため、鉄と有機物との複合体であるフェリハイドライトができない。したがって、フェリハイドライトを形成させるためには、家畜糞堆肥製造方法の各工程において、鶏糞と家畜糞処理液の希釈液を混合したもののpHが、5以上になっていることが必要である。 Livestock manure treatment liquid, is less than pH 5, there is no Fe (OH) 3, the Fe 3+ and Fe (OH) 2+ and Fe (OH) 2 + form. Because when the Fe 3+ and Fe (OH) 2+ and Fe (OH) 2 + mode, the organic matter in the manure is aluminum rather than iron, magnesium, resulting in formation of other elements and complexes such as calcium, iron Ferrihydrite, which is a complex of organic and organic matter, is not possible. Therefore, in order to form ferrihydrite, it is necessary that the pH of the mixture of the chicken feces and the diluted livestock feces treatment solution is 5 or more in each step of the method for producing livestock manure compost.

次いで、採卵鶏の鶏糞1kg当たり0.2〜1.5Lの希釈液を、公知のスプレーを用いて鶏糞に散布する添加工程を行った後、5〜15分間撹拌混合する撹拌工程を行い、鶏糞と処理液の混合物を得る。なお、希釈液の添加量は、鶏糞の水分量に応じて決められる。また、添加工程は、スプレーを用いた散布に限られず、希釈液をそのまま注入したり、振り掛けたりしてもよい。
混合物をシート上に薄く広げ、5〜14日間天日干しにより、水分が10〜25%程度になるよう乾燥する乾燥工程を行い、乾燥混合物を得る。ここで、天日干しの日数を5日以上としたのは、5日未満であると、家畜糞特有の臭気が完全に除去されないためである。また、14日間以下としたのは、14日間天日干しすれば家畜糞特有の臭気が略完全に除去されるためである。また、14日より長い日数天日干しをすると、鶏糞の処理効率が低下し、処理待ちの鶏糞を保管する施設を大型化する必要が生じるためである。
なお、本実施形態では、天日干しにより乾燥工程を行うが、コンベア式乾燥機,ドラム式乾燥機等の乾燥機で乾燥してもよい。
乾燥混合物を粉砕して粉砕物を得て、家畜糞堆肥を完成する。
Subsequently, after performing the addition process which spreads 0.2-1.5L dilution liquid per kg of egg droppings of egg-laying chicken to chicken droppings using a well-known spray, the stirring process which stirs and mixes for 5 to 15 minutes is performed, chicken droppings And a mixture of the treatment liquid is obtained. In addition, the addition amount of a dilution liquid is determined according to the water content of chicken manure. Moreover, an addition process is not restricted to spraying using a spray, You may inject | pour dilution liquid as it is or sprinkle it.
The mixture is thinly spread on a sheet and dried in the sun for 5 to 14 days so that the water content is about 10 to 25% to obtain a dry mixture. Here, the reason why the number of sun-dried days is set to 5 days or more is that if it is less than 5 days, the odor peculiar to livestock droppings is not completely removed. The reason why the period is 14 days or less is that the odor peculiar to livestock excrement is almost completely removed by drying in the sun for 14 days. Moreover, if it is sun-dried for days longer than 14 days, the processing efficiency of chicken manure will fall, and it will be necessary to enlarge the facility which stores the chicken manure waiting for processing.
In the present embodiment, the drying process is performed by sun drying, but drying may be performed by a dryer such as a conveyor dryer or a drum dryer.
The dried mixture is pulverized to obtain a pulverized product, thereby completing livestock manure compost.

本実施形態の家畜糞堆肥製造方法では、家畜糞処理液の希釈液のpHを5以上に調整し、かつ、pH5以上の鶏糞を用いているため、以降の工程において、家畜糞処理液の希釈液のpHを5以上に保持することが可能となり、家畜糞処理液の希釈液中に、フェリハイドライトの原料となるFe(OH)(水酸化鉄)を存在させることが可能となる。 In the method for producing livestock manure compost according to the present embodiment, the pH of the diluted solution of the livestock manure treatment liquid is adjusted to 5 or more, and the chicken manure having a pH of 5 or more is used. The pH of the liquid can be maintained at 5 or more, and Fe (OH) 3 (iron hydroxide), which is a ferrihydrite raw material, can be present in the diluted livestock feces treatment liquid.

(家畜糞堆肥)
上記家畜糞堆肥の製造方法により製造された鶏糞堆肥は、緑色から黒色の粉末からなり、粉末状の家畜糞堆肥製品の形態においても、粉末に水を加えたペースト状の形態においても、従来の家畜糞堆肥特有の悪臭がない。
また、鶏糞堆肥は、pH8以下であるとよい。pH8より高くなると、独特のみそ臭が生じる場合があるが、pH8以下になると、このみそ臭が和らげられるか、なくなるためである。
なお、鶏糞堆肥は、鶏に与えた飼料,水や、鶏の生育した環境などにより、組成や性質が変化するため、鶏糞堆肥のpHが同じであっても、みそ臭が生じる場合も生じない場合もあり、みそ臭の発生頻度が異なる。鶏糞堆肥がpH6以下となると、どのような条件でも、ほぼ完全にみそ臭の発生が防止される。
(Livestock manure compost)
The chicken manure compost produced by the above method for producing livestock manure compost is composed of a green to black powder, which is the same as that in the form of a livestock manure compost product in the form of a powder or in the form of a paste in which water is added to the powder. There is no odor peculiar to livestock manure compost.
Further, the chicken manure compost is preferably pH 8 or less. When the pH is higher than 8, a unique miso odor may be generated. However, when the pH is 8 or less, the miso odor is relieved or eliminated.
In addition, because the composition and properties of chicken manure compost change depending on the feed, water, and the environment in which the chicken grew, etc., even if the pH of the chicken manure compost is the same, no miso odor is produced. In some cases, the frequency of miso odor is different. When the chicken manure compost has a pH of 6 or less, the occurrence of miso odor is almost completely prevented under any conditions.

以下、上記家畜糞堆肥の製造方法により製造した鶏糞堆肥の実施例1〜5について説明する。
(実施例1)
家畜糞処理液を水で10倍希釈した希釈液0.5Lを、採卵鶏の鶏糞2kgに散布して、5分間撹拌混合した後、数分間放置して、鶏糞と処理液の混合物2.5kgを得た。混合物をシート上に薄く広げ、7日間天日干しをして、0.35kgの乾燥混合物を得た。次いで、混合乾燥物を粉砕して粉砕物を得て、家畜糞堆肥を完成した。
Hereinafter, Examples 1 to 5 of chicken manure compost produced by the above method for producing livestock manure compost will be described.
Example 1
Sprinkle 0.5 L of a diluted solution of livestock dung treatment solution with water on 2 kg of egg droppings of egg-laying chicken, stir and mix for 5 minutes, and then leave it for a few minutes to mix 2.5 kg of chicken dung and treatment solution. Got. The mixture was spread thinly on a sheet and sun-dried for 7 days to obtain 0.35 kg of a dry mixture. Next, the mixed dried product was pulverized to obtain a pulverized product, thereby completing livestock manure compost.

(実施例2)
家畜糞処理液を水で100倍希釈した希釈液0.5Lを、採卵鶏の鶏糞2kgに散布して、5分間撹拌混合した後、数分間放置して、鶏糞と処理液の混合物2.5kgを得た。混合物をシート上に薄く広げ、7日間天日干しをして、0.28kgの乾燥混合物を得た。次いで、混合乾燥物を粉砕して粉砕物を得て、家畜糞堆肥を完成した。
(Example 2)
Sprinkle 0.5 L of a diluted solution of livestock dung treatment solution with water on 2 kg of chicken dung of egg-laying chickens, stir and mix for 5 minutes, and leave for a few minutes to mix 2.5 kg of chicken dung and treatment solution. Got. The mixture was thinly spread on a sheet and sun-dried for 7 days to obtain 0.28 kg of a dry mixture. Next, the mixed dried product was pulverized to obtain a pulverized product, thereby completing livestock manure compost.

(実施例3)
家畜糞処理液を水で1000倍希釈した希釈液0.3Lを、採卵鶏の鶏糞1kgに散布して、5分間撹拌混合した後、数分間放置して、鶏糞と処理液の混合物1.3kgを得た。混合物をシート上に薄く広げ、7日間天日干しをして、0.14kgの乾燥混合物を得た。次いで、混合乾燥物を粉砕して粉砕物を得て、家畜糞堆肥を完成した。
(Example 3)
Sprinkle 0.3 L of livestock feces treatment solution diluted 1000 times with water onto 1 kg of chicken feces of egg-collecting chicken, stir and mix for 5 minutes, and then leave for several minutes to mix 1.3 kg of chicken feces and treatment solution Got. The mixture was thinly spread on a sheet and sun-dried for 7 days to obtain 0.14 kg of a dry mixture. Next, the mixed dried product was pulverized to obtain a pulverized product, thereby completing livestock manure compost.

(実施例4)
家畜糞処理液を水で500倍希釈した希釈液0.5Lを、採卵鶏の鶏糞2kgに散布して、5分間撹拌混合した後、数分間放置して、鶏糞と処理液の混合物2.5kgを得た。混合物をシート上に薄く広げ、11日間天日干しをして、0.45kgの乾燥混合物を得た。このうち0.215kgの乾燥混合物を廃棄して0.235kgの乾燥混合物をサンプルとした。次いで、混合乾燥物を粉砕して粉砕物を得て、家畜糞堆肥を完成した。
Example 4
0.5 L of diluted solution of livestock excrement treatment solution diluted with water 500 times is sprinkled on 2 kg of poultry manure of egg-laying hens, stirred for 5 minutes and then allowed to stand for several minutes, then 2.5 kg of chicken feces and treatment solution mixture Got. The mixture was thinly spread on a sheet and sun-dried for 11 days to obtain 0.45 kg of a dry mixture. Of this, 0.215 kg of the dry mixture was discarded and 0.235 kg of the dry mixture was used as a sample. Next, the mixed dried product was pulverized to obtain a pulverized product, thereby completing livestock manure compost.

(実施例5)
家畜糞処理液を水で1000倍希釈した希釈液0.5Lを、採卵鶏の鶏糞2kgに散布して、5分間撹拌混合した後、数分間放置して、鶏糞と処理液の混合物2.5kgを得た。混合物をシート上に薄く広げ、11日間天日干しをして、0.469kgの乾燥混合物を得た。このうち0.134kgの乾燥混合物を廃棄して0.335kgの乾燥混合物をサンプルとした。次いで、混合乾燥物を粉砕して粉砕物を得て、家畜糞堆肥を完成した。
(Example 5)
After diluting 0.5L of the livestock dung treatment solution 1000 times with water, spray it on 2kg of chicken dung of egg-laying chickens, stir and mix for 5 minutes, leave it for several minutes, and then mix 2.5kg of chicken dung and treatment solution. Got. The mixture was thinly spread on a sheet and sun-dried for 11 days to obtain 0.469 kg of a dry mixture. Of these, 0.134 kg of the dry mixture was discarded and 0.335 kg of the dry mixture was used as a sample. Next, the mixed dried product was pulverized to obtain a pulverized product, thereby completing livestock manure compost.

(試験例1)
以上のように調整した実施例1〜5の家畜糞堆肥の臭気について試験した結果を表2に示す。
(Test Example 1)
Table 2 shows the results of testing for the odor of livestock manure compost of Examples 1 to 5 adjusted as described above.

Figure 0006098867
Figure 0006098867

実施例1,2,4,5では、原料である鶏糞の臭気を100とした場合、撹拌工程中の臭気が50程度であった。また、乾燥工程開始後6日目に、鶏糞特有の臭気が全く感じられず、臭気が完全に除去された。また、その後、そのまま糞臭が復活することなく、製品形態である家畜糞堆肥及び家畜糞堆肥に水を添加したペーストに至るまで、糞臭のないものであった。   In Examples 1, 2, 4, and 5, the odor during the stirring step was about 50 when the odor of chicken dung as a raw material was set to 100. Further, on the sixth day after the start of the drying process, no odor peculiar to chicken manure was felt, and the odor was completely removed. Moreover, after that, the feces odor was not restored as it was, and there was no fecal odor up to the product form of livestock manure compost and the paste in which water was added to the livestock manure compost.

また、実施例3では、原料である鶏糞の臭気を100とした場合、撹拌工程中の臭気が50程度であった。また、7日間の乾燥工程終了後、感じられるか感じられないかの境界程度の臭気を有していた。乾燥工程終了後の臭気は、従来の鶏糞堆肥の臭気よりも非常に弱いレベルであった。   Moreover, in Example 3, when the odor of chicken droppings as a raw material was set to 100, the odor during the stirring process was about 50. Moreover, after the completion of the drying process for 7 days, it had an odor about the boundary of whether it was felt or not felt. The odor after the drying process was very weaker than the odor of conventional chicken manure compost.

実施例2に係る家畜糞堆肥の分析結果を、表3に示す。   Table 3 shows the analysis results of livestock manure compost according to Example 2.

Figure 0006098867
Figure 0006098867

実施例2に係る鶏糞堆肥は、リン酸量が8.6%で、窒素量の2.77倍、カリウム量の4.10倍であった。従来の鶏糞堆肥は、リン酸量が4〜6%でカリウム量の2倍未満であるため、従来の鶏糞堆肥と対比しても、リン酸の含有比率が高いことが分かった。   The chicken manure compost according to Example 2 had a phosphoric acid content of 8.6%, a nitrogen content of 2.77 and a potassium content of 4.10. Conventional chicken manure compost has a phosphoric acid content of 4 to 6% and less than twice the amount of potassium. Therefore, it has been found that the content ratio of phosphoric acid is high even when compared with conventional chicken manure compost.

(実施例6)
家畜糞処理液を水で10倍希釈した希釈液1Lを、採卵鶏の鶏糞10kgに散布して、水分60%とし、10分間撹拌混合した後、数分間放置して、鶏糞と処理液の混合物を得た。混合物をシート上に薄く広げ、7日間天日干しをして、乾燥混合物を得た。次いで、混合乾燥物を粉砕して粉砕物を得て、家畜糞堆肥を完成した。
得られた家畜糞堆肥は、pH5.54で、無臭であった。
(Example 6)
1 L of diluted solution of livestock dung treatment solution diluted 10-fold with water is sprinkled on 10 kg of chicken dung of egg-laying chicken to make water 60%, stirred and mixed for 10 minutes, then left for several minutes to mix chicken dung and treatment solution Got. The mixture was thinly spread on a sheet and sun-dried for 7 days to obtain a dry mixture. Next, the mixed dried product was pulverized to obtain a pulverized product, thereby completing livestock manure compost.
The obtained livestock manure compost had a pH of 5.54 and was odorless.

(実施例7)
家畜糞処理液を水で10倍希釈した希釈液1Lを、pH6.33の採卵鶏の鶏糞10kgに散布して、水分60%とし、10分間撹拌混合した後、数分間放置して、鶏糞と処理液の混合物を得た。混合物をシート上に薄く広げ、7日間天日干しをして、乾燥混合物を得た。次いで、混合乾燥物を粉砕して粉砕物を得て、家畜糞堆肥を完成した。
得られた家畜糞堆肥は、pH5.17で、無臭であった。
(Example 7)
1 L of a diluted solution obtained by diluting livestock feces treatment solution 10 times with water is sprayed on 10 kg of chicken feces of an egg-collecting chicken having a pH of 6.33 to obtain a moisture content of 60%. After stirring and mixing for 10 minutes, the mixture is allowed to stand for several minutes. A mixture of treatment liquids was obtained. The mixture was thinly spread on a sheet and sun-dried for 7 days to obtain a dry mixture. Next, the mixed dried product was pulverized to obtain a pulverized product, thereby completing livestock manure compost.
The obtained livestock manure compost had a pH of 5.17 and was odorless.

(実施例8)
家畜糞処理液を水で10倍希釈した希釈液1Lを、採卵鶏の鶏糞10kgに散布して、水分60%とし、10分間撹拌混合した後、数分間放置して、鶏糞と処理液の混合物を得た。混合物をシート上に薄く広げ、7日間天日干しをして、乾燥混合物を得た。次いで、混合乾燥物を粉砕して粉砕物を得て、家畜糞堆肥を完成した。
得られた家畜糞堆肥は、pH7.56で、若干のみそ臭があったが、肥料臭気としては、合格品として許容される程度であった。
(Example 8)
1 L of diluted solution of livestock dung treatment solution diluted 10-fold with water is sprinkled on 10 kg of chicken dung of egg-laying chicken to make water 60%, stirred and mixed for 10 minutes, then left for several minutes to mix chicken dung and treatment solution Got. The mixture was thinly spread on a sheet and sun-dried for 7 days to obtain a dry mixture. Next, the mixed dried product was pulverized to obtain a pulverized product, thereby completing livestock manure compost.
The obtained livestock manure compost had a pH of 7.56 and had a slight odor, but the fertilizer odor was only acceptable as an acceptable product.

(実施例9)
家畜糞処理液を水で5倍希釈した希釈液1Lを、対比例1で用いたものと同じ採卵鶏の鶏糞10kgに散布して、水分60%とし、10分間撹拌混合した後、数分間放置して、鶏糞と処理液の混合物を得た。混合物をシート上に薄く広げ、7日間天日干しをして、乾燥混合物を得た。次いで、混合乾燥物を粉砕して粉砕物を得て、家畜糞堆肥を完成した。
得られた家畜糞堆肥は、pH8.03で、若干のみそ臭があったが、肥料臭気としては、合格品として許容される程度であった。
Example 9
1 L of diluted solution of livestock dung treatment solution diluted 5 times with water is sprayed on 10 kg of chicken dung of the same egg-laying hen used in the proportional 1 to make the moisture 60%, and stirred and mixed for 10 minutes, then left for several minutes Thus, a mixture of chicken manure and treatment liquid was obtained. The mixture was thinly spread on a sheet and sun-dried for 7 days to obtain a dry mixture. Next, the mixed dried product was pulverized to obtain a pulverized product, thereby completing livestock manure compost.
The obtained livestock manure compost had a pH of 8.03 and had a slight odor, but the fertilizer odor was only acceptable as an acceptable product.

(試験例2)
実施例6〜9で製造した鶏糞堆肥について、pHと臭気との関連を検討した。
実施例8,9より、家畜糞処理液で処理した鶏糞堆肥は、pH7.56,pH8.03で若干のみそ臭があったが、許容できる程度のわずかなみそ臭であった。従って、pH8以下程度で、アルカリ性の家畜糞堆肥特有のみそ臭がなくなることが分かった。
また実施例6,7より、家畜糞処理液で処理した鶏糞堆肥は、pH5.54,pH5.17で、全くの無臭になっていた。
実施例6〜9では、家畜糞処理液により、中性又は酸性の鶏糞堆肥となっており、アルカリ特有の悪臭がしないことが確認された。臭気の確認をしたところ、アンモニアの発生も抑えられており、真の発酵食品と同程度の系に入っているものと思われた。
(Test Example 2)
Regarding the chicken manure compost produced in Examples 6 to 9, the relationship between pH and odor was examined.
From Examples 8 and 9, chicken manure compost treated with the livestock manure treatment solution had a slight odor at pH 7.56 and pH 8.03, but a slight miso odor that was acceptable. Accordingly, it has been found that the odor is unique only to alkaline livestock manure compost at a pH of about 8 or less.
Further, from Examples 6 and 7, the chicken manure compost treated with the livestock manure treatment solution had pH 5.54 and pH 5.17 and was completely odorless.
In Examples 6-9, it became neutral or acidic chicken manure compost with livestock manure treatment liquid, and it was confirmed that there is no malodor peculiar to alkali. When the odor was confirmed, the generation of ammonia was suppressed, and it seemed that it was in the same system as the true fermented food.

Claims (5)

家畜糞がpH5未満であるときには、前記家畜糞をpH5以上に調整するpH調整工程と、
前記家畜糞に、玄武岩および安山岩を含む群からなる少なくとも一の堆積岩土壌の無機酸抽出液又は該抽出液の水溶液であって、該抽出液又は該抽出液の水溶液に含まれる金属中で鉄を最も多く含み、該鉄が液中で、pH5より高いpHで、Fe(OH)として存在する家畜糞処理剤を添加する添加工程とを行うことにより、
含有窒素量の2倍以上の量で、かつ、含有カリウム量の2倍以上の量のリン酸を含み、フェリハイドライトと家畜糞中の有機物との複合体を含む糞臭のない家畜糞堆肥を製造することを特徴とする家畜糞堆肥製造方法。
When the livestock feces are less than pH 5, a pH adjustment step of adjusting the livestock feces to pH 5 or higher;
An inorganic acid extract of the at least one sedimentary rock soil composed of a group including basalt and andesite, or an aqueous solution of the extract, and iron in the metal contained in the extract or the aqueous solution of the extract. The addition step of adding the animal feces treatment agent present as Fe (OH) 3 at a pH higher than pH 5 and containing the most iron,
Livestock manure compost free of fecal odor, containing phosphoric acid in an amount more than twice the amount of nitrogen and more than twice the amount of potassium, and containing a complex of ferrihydrite and organic matter in livestock feces A method for producing livestock manure compost characterized by producing
前記添加工程では、前記家畜糞に、木材チップを含む水分調整材の添加を行うことなく、前記家畜糞処理剤を添加することを特徴とする請求項1記載の家畜糞堆肥製造方法。   2. The method for producing livestock manure compost according to claim 1, wherein, in the adding step, the livestock feces treatment agent is added to the livestock feces without adding a moisture adjusting material containing wood chips. 前記添加工程の後で、発酵工程を経ることなく、前記家畜糞処理剤が添加された前記家畜糞を乾燥させる乾燥工程を行うことを特徴とする請求項1又は2記載の家畜糞堆肥製造方法。   The method for producing livestock manure compost according to claim 1 or 2, wherein a drying step of drying the livestock feces to which the livestock feces treatment agent has been added is performed after the addition step without passing through a fermentation step. . 前記添加工程の後、前記乾燥工程前に、前記家畜糞処理剤が添加された前記家畜糞を撹拌して均一混合物を得る撹拌工程を行い、
前記乾燥工程では、前記均一混合物を15日間未満の日数乾燥させることを特徴とする請求項3記載の家畜糞堆肥製造方法。
After the addition step, before the drying step, perform a stirring step of stirring the livestock feces to which the livestock fecal treatment agent has been added to obtain a uniform mixture,
4. The method for producing livestock manure compost according to claim 3, wherein in the drying step, the uniform mixture is dried for less than 15 days.
前記添加工程では、前記家畜糞処理剤を前記家畜糞に散布し、
前記乾燥工程は、5日以上の日数の天日干しにより行うことを特徴とする請求項3又は4記載の家畜糞堆肥製造方法。
In the adding step, the livestock feces treatment agent is sprayed on the livestock feces,
The method for producing livestock manure compost according to claim 3 or 4, wherein the drying step is performed by sun-drying for 5 days or more.
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