JP6097490B2 - 酸化物の製造方法 - Google Patents
酸化物の製造方法 Download PDFInfo
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- JP6097490B2 JP6097490B2 JP2012094458A JP2012094458A JP6097490B2 JP 6097490 B2 JP6097490 B2 JP 6097490B2 JP 2012094458 A JP2012094458 A JP 2012094458A JP 2012094458 A JP2012094458 A JP 2012094458A JP 6097490 B2 JP6097490 B2 JP 6097490B2
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- 238000004519 manufacturing process Methods 0.000 title claims description 21
- 238000000034 method Methods 0.000 claims description 19
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 16
- 239000011148 porous material Substances 0.000 claims description 16
- 239000002041 carbon nanotube Substances 0.000 claims description 15
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 14
- 239000002184 metal Substances 0.000 claims description 14
- 239000011259 mixed solution Substances 0.000 claims description 12
- 239000000126 substance Substances 0.000 claims description 12
- 239000002109 single walled nanotube Substances 0.000 claims description 11
- 150000004703 alkoxides Chemical class 0.000 claims description 10
- 239000004065 semiconductor Substances 0.000 claims description 9
- 239000011777 magnesium Substances 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 239000010936 titanium Substances 0.000 claims description 8
- 239000006228 supernatant Substances 0.000 claims description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 229910052749 magnesium Inorganic materials 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- 229910052718 tin Inorganic materials 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- 229910052726 zirconium Inorganic materials 0.000 claims description 5
- OSXGKVOYAKRLCS-UHFFFAOYSA-N 2-methylpropan-2-olate;tin(4+) Chemical compound CC(C)(C)O[Sn](OC(C)(C)C)(OC(C)(C)C)OC(C)(C)C OSXGKVOYAKRLCS-UHFFFAOYSA-N 0.000 claims description 4
- 238000005119 centrifugation Methods 0.000 claims description 3
- 239000000835 fiber Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- SYRHIZPPCHMRIT-UHFFFAOYSA-N tin(4+) Chemical group [Sn+4] SYRHIZPPCHMRIT-UHFFFAOYSA-N 0.000 claims description 2
- 238000010586 diagram Methods 0.000 description 8
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 description 7
- 229910003472 fullerene Inorganic materials 0.000 description 7
- 125000000524 functional group Chemical group 0.000 description 7
- 239000011135 tin Substances 0.000 description 7
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 238000009210 therapy by ultrasound Methods 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 4
- 238000003917 TEM image Methods 0.000 description 3
- 150000007942 carboxylates Chemical class 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- 150000001875 compounds Chemical group 0.000 description 3
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 230000009878 intermolecular interaction Effects 0.000 description 3
- 150000004032 porphyrins Chemical class 0.000 description 3
- 125000002924 primary amino group Chemical class [H]N([H])* 0.000 description 3
- 125000000467 secondary amino group Chemical class [H]N([*:1])[*:2] 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 238000009713 electroplating Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000002048 multi walled nanotube Substances 0.000 description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000011941 photocatalyst Substances 0.000 description 2
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 238000001771 vacuum deposition Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000007772 electroless plating Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- -1 etc. Chemical group 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 238000002525 ultrasonication Methods 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/542—Dye sensitized solar cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Description
前記遠心分離して得られた上清に、スズ、チタン、アルミ、ケイ素、マグネシウム、ジルコニウムから選択される少なくとも1種の金属を含む金属アルコキシドであって、前記金属アルコキシドはTin(IV)tetra tert-butoxideであり、前記Tin(IV)tetra tert-butoxideを滴下して、前記酸化物を製造することを特徴とする。
Claims (5)
- 繊維状であり、かつ、200〜400nmの開口幅の細孔を有し、前記細孔はハニカム構造を構成する酸化物の製造方法であって、フラロデンドロンの水溶液と、単層ナノチューブ、多層カーボンナノチューブから選択される少なくとも1つのカーボンナノチューブとの混合液を遠心分離し、
前記遠心分離して得られた上清に、スズ、チタン、アルミ、ケイ素、マグネシウム、ジルコニウムから選択される少なくとも1種の金属を含む金属アルコキシドであって、前記金属アルコキシドはTin(IV)tetra tert-butoxideであり、前記Tin(IV)tetra tert-butoxideを滴下して、前記酸化物を製造することを特徴とする酸化物の製造方法。 - 前記フラロデンドロンは、下記式[化1]、
- 前記混合液が超音波処理されている請求項1又は2に記載の方法。
- 前記繊維状の酸化物の繊維の長さは、5〜50μmである請求項1〜3のいずれか1項に記載の方法。
- 請求項1〜4のいずれか1項に記載の方法から製造された酸化物であって、前記酸化物は、繊維状であり、かつ、200〜400nmの開口幅の細孔を有し、前記細孔はハニカム構造を構成する酸化物からなる半導体材料を製造する方法。
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JP2012094458A JP6097490B2 (ja) | 2012-04-18 | 2012-04-18 | 酸化物の製造方法 |
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JP2012094458A JP6097490B2 (ja) | 2012-04-18 | 2012-04-18 | 酸化物の製造方法 |
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JP6097490B2 true JP6097490B2 (ja) | 2017-03-15 |
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Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
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JP6225399B2 (ja) * | 2014-03-11 | 2017-11-08 | 国立大学法人 岡山大学 | コアシェル型カーボンナノチューブ複合材料及びその製造方法 |
CN106315538A (zh) * | 2015-06-30 | 2017-01-11 | 中国科学院上海微系统与信息技术研究所 | 一种多孔碳的制备方法 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2003335515A (ja) * | 2002-05-17 | 2003-11-25 | National Institute Of Advanced Industrial & Technology | 微細孔を有する三次元高規則性ナノポーラス無機多孔体及びその製造方法並びにその評価方法 |
JP4698981B2 (ja) * | 2003-08-01 | 2011-06-08 | 日揮触媒化成株式会社 | 繊維状酸化チタン粒子とその製造方法ならびに該粒子の用途 |
US7482297B2 (en) * | 2004-09-29 | 2009-01-27 | The University Of Akron | Size controlled fibers, tubes and channels synthesized by heterogeneous deposition via sol-gel processing |
JP2006213534A (ja) * | 2005-02-01 | 2006-08-17 | Kawamura Inst Of Chem Res | 無機酸化物周期構造体 |
GB0518139D0 (en) * | 2005-09-06 | 2005-10-12 | Univ Cambridge Tech | Synthesis of rutile structure titanium oxide nanostructures |
JP5145603B2 (ja) * | 2006-09-19 | 2013-02-20 | 国立大学法人北海道大学 | 含金属複合構造体及びその製造方法 |
US8968604B2 (en) * | 2007-04-27 | 2015-03-03 | Kuraray Co., Ltd. | Single-walled carbon nanotube dispersion liquid and method for producing single-walled carbon nanotube dispersion liquid |
EP2154690A4 (en) * | 2007-04-27 | 2015-04-01 | Kuraray Co | TRANSPARENT CONDUCTIVE FILM AND PROCESS FOR PRODUCING TRANSPARENT CONDUCTIVE FILM |
JP4633179B2 (ja) * | 2008-06-20 | 2011-02-16 | 大阪瓦斯株式会社 | 酸化チタン構造体 |
JP5545694B2 (ja) * | 2008-10-29 | 2014-07-09 | Dic株式会社 | カーボン含有金属酸化物中空粒子及びその製造方法 |
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- 2012-04-18 JP JP2012094458A patent/JP6097490B2/ja active Active
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