JP6016875B2 - 前処理されたポリオールを伴うチューインガム - Google Patents
前処理されたポリオールを伴うチューインガム Download PDFInfo
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- JP6016875B2 JP6016875B2 JP2014242999A JP2014242999A JP6016875B2 JP 6016875 B2 JP6016875 B2 JP 6016875B2 JP 2014242999 A JP2014242999 A JP 2014242999A JP 2014242999 A JP2014242999 A JP 2014242999A JP 6016875 B2 JP6016875 B2 JP 6016875B2
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- gum
- polyol
- particles
- chewing gum
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- 229920005862 polyol Polymers 0.000 title claims description 232
- 150000003077 polyols Chemical class 0.000 title claims description 232
- 235000015218 chewing gum Nutrition 0.000 title claims description 164
- 229940112822 chewing gum Drugs 0.000 title claims description 161
- 239000000203 mixture Substances 0.000 claims description 227
- 239000002245 particle Substances 0.000 claims description 186
- 239000000463 material Substances 0.000 claims description 144
- 239000008199 coating composition Substances 0.000 claims description 73
- 239000007788 liquid Substances 0.000 claims description 72
- 238000000576 coating method Methods 0.000 claims description 62
- 229910010272 inorganic material Inorganic materials 0.000 claims description 59
- 239000011147 inorganic material Substances 0.000 claims description 59
- 239000011248 coating agent Substances 0.000 claims description 56
- 230000002829 reductive effect Effects 0.000 claims description 44
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 33
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 33
- 239000000600 sorbitol Substances 0.000 claims description 33
- 229960002920 sorbitol Drugs 0.000 claims description 33
- 235000010356 sorbitol Nutrition 0.000 claims description 33
- 239000011236 particulate material Substances 0.000 claims description 31
- 229920000084 Gum arabic Polymers 0.000 claims description 30
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- 239000000205 acacia gum Substances 0.000 claims description 30
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 22
- 238000011049 filling Methods 0.000 claims description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 21
- 239000001506 calcium phosphate Substances 0.000 claims description 19
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 claims description 17
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- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 claims description 17
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- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 claims description 17
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- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 claims description 16
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- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 11
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- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims description 10
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- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 8
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 8
- 229960001708 magnesium carbonate Drugs 0.000 claims description 8
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- 235000019739 Dicalciumphosphate Nutrition 0.000 claims description 7
- NEFBYIFKOOEVPA-UHFFFAOYSA-K dicalcium phosphate Chemical compound [Ca+2].[Ca+2].[O-]P([O-])([O-])=O NEFBYIFKOOEVPA-UHFFFAOYSA-K 0.000 claims description 7
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- SERLAGPUMNYUCK-BLEZHGCXSA-N (2xi)-6-O-alpha-D-glucopyranosyl-D-arabino-hexitol Chemical compound OCC(O)[C@@H](O)[C@H](O)[C@H](O)CO[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O SERLAGPUMNYUCK-BLEZHGCXSA-N 0.000 description 12
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- WGIWBXUNRXCYRA-UHFFFAOYSA-H trizinc;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O WGIWBXUNRXCYRA-UHFFFAOYSA-H 0.000 description 1
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Classifications
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
- A23G4/10—Chewing gum characterised by the composition containing organic or inorganic compounds characterised by the carbohydrates used, e.g. polysaccharides
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
- A23G4/064—Chewing gum characterised by the composition containing organic or inorganic compounds containing inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/18—Chewing gum characterised by shape, structure or physical form, e.g. aerated products
- A23G4/20—Composite products, e.g. centre-filled, multi-layer, laminated
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/18—Chewing gum characterised by shape, structure or physical form, e.g. aerated products
- A23G4/20—Composite products, e.g. centre-filled, multi-layer, laminated
- A23G4/205—Hollow products, e.g. with inedible or edible filling, fixed or movable within the cavity
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/30—Artificial sweetening agents
- A23L27/33—Artificial sweetening agents containing sugars or derivatives
- A23L27/34—Sugar alcohols
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
- A23L29/206—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
- A23L29/25—Exudates, e.g. gum arabic, gum acacia, gum karaya or tragacanth
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/30—Foods or foodstuffs containing additives; Preparation or treatment thereof containing carbohydrate syrups; containing sugars; containing sugar alcohols, e.g. xylitol; containing starch hydrolysates, e.g. dextrin
- A23L29/37—Sugar alcohols
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
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Description
当該微粒子クランチ物質は、クランチ物質コーティング組成物でコーティングされた第1のポリオールの粒子を含む。この第1のポリオールは、ポリオール粒子が低レベルの吸湿性を有しかつ所望のサイズの微粒子クランチ物質を得ることができる限り、特に限定されない。この第1のポリオールの例としては、水素化されたイソマルチュロース、マルチトール、キシリトール、エリスリトール、または上記のポリオールのうちの少なくとも1つを含む組み合わせが挙げられる。1つの特定の実施形態では、第1のポリオールは水素化されたイソマルチュロースである。イソマルトとしても知られる水素化されたイソマルチュロースは、二糖アルコールである。イソマルトは、イソマルチュロースを水素化することにより調製することができる。この水素化の生成物は、6−O−α−D−グルコピラノシル−D−ソルビトール(1,6−GPS);1−O−α−D−グルコピラノシル−D−ソルビトール(1,1−GPS);1−O−α−D−グルコピラノシル−D−マンニトール(1,1−GPM);6−O−α−D−グルコピラノシル−D−マンニトール(1,6−GPM);およびこれらの混合物を含む可能性がある。いくつかの市販のイソマルト物質は1,6−GPS、および1,1−GPMのほとんど等モル量の混合物を含む。他のイソマルト物質は、純粋な1,6−GPS;1,1−GPS;1,6−GP;および1,1−GPMを含むことができる。さらに他のイソマルト物質は、いずれかの比の1,6−GPS;1,1−GPS;1,6−GPM;および1,1−GPMの混合物を含むことができる。
いくつかの実施形態では、ポリオールの粒子および無機材料の粒子を含むポリオール組成物が提供される。このポリオール組成物の中に含まれるポリオール粒子は、吸湿性ポリオール粒子である。「吸湿性(の)」ポリオールは、その周囲から容易に水を吸収するポリオールを指し、他方で、「非吸湿性(の)」ポリオールは、その周囲から容易に水を吸収しないポリオールを指す。「低吸湿性」を持つポリオールは、その周囲から非常に少ない水しか吸収しない。当該無機材料の粒子は、ポリオール粒子の上にコーティングされ、無機材料の粒子でコーティングされていないポリオールと比べて、低下した吸湿性を有するポリオール組成物を生じる。
本願明細書に開示されるチューインガム組成物は、製造されるガムのタイプ、すなわちチューインガムまたは風船ガムに合うように変更することができる。本願明細書で使用する場合、用語「風船ガム」および「チューインガム」はほとんど同義で使用され、ともにあらゆるガム組成物を包含することが意図されている。
噛まれている間長く続くクランチを提供しかつ商業的に許容できる貯蔵時間を有するクランチ質チューインガム組成物が本願明細書に開示される。いくつかの実施形態では、このクランチ質チューインガムは、ガムベースおよび微粒子クランチ物質を含むガムコアを有する。この微粒子クランチ物質は、クランチ物質コーティング組成物でコーティングされた第1のポリオールの粒子から構成される。1つの実施形態では、このクランチ物質コーティング組成物はアラビアガムを含む。別の実施形態では、アラビアガムに対する第1のポリオール粒子の重量比は約4:1〜約1:1である。
低下した吸湿性を有するポリオール組成物を含有する多要素系チューインガムが本願明細書に開示される。この多要素系チューインガム組成物は、少なくとも1つの液体充填部組成物と、この液体充填部組成物に隣接しかつそれを取り囲むガム領域とを含む。1つの実施形態では、液体充填部組成物と、この液体充填部組成物を取り囲むガム領域であって、このガム領域は、ガムベースおよび低下した吸湿性を有するポリオール組成物を含むガム領域とを含むチューインガム組成物が提供される。低下した吸湿性を有するポリオール組成物は、吸湿性ポリオールの粒子および無機材料の粒子を含み、この吸湿性ポリオールの粒子はこの無機材料の粒子でコーティングされている。
微粒子クランチ物質の調製
水素化されたイソマルチュロース(イソマルト)をコアポリオール粒子として使用して、微粒子クランチ物質を調製した。この水素化されたイソマルチュロース物質(Isomaltidex 16500;カーギル(Cargill))は、6−O−α−D−グルコピラノシル−D−ソルビトール(1,6−GPS)および1−O−α−D−グルコピラノシル−D−マンニトール二水和物(1,1−GPM)の50:50ブレンドである。このイソマルト物質は、0.5mm〜3.5mmのD90粒径を有する。
クランチ質チューインガムの調製
表1に示すガム配合を用いて、ペレットの形態のチューインガムの試料を、従来の方法によって調製した。実施例1に記載したようにして調製した微粒子クランチ物質をこのチューインガム組成物の中に含めた。
下記の表に示す一般のガム配合物を用いて、従来の方法を使用して、チューインガム試料を調製する。
低下した吸湿性を有するポリオール組成物の調製
低下した吸湿性を有するポリオール組成物を作製する方法は、ソルビトールなどのポリオールを、ケイ酸カルシウム、ヒュームドシリカ、タルク、珪藻土、軽石粉、カオリン、ベントナイト、ゼオライト、リン酸三カルシウム、リン酸二カルシウム、炭酸カルシウム、炭酸マグネシウムまたはこれらの組み合わせの粒子と合わせることを含む。本実施例はソルビトールを利用するが、他方で、マルチトール、キシリトール、ラクチトール、および/またはポリグリシトールなどの他のポリオールを使用することもできる。
液体中心充填チューインガムの調製
表4〜表6に提示する組成物に従って、3つの領域、ガム領域、液体充填部および外側コーティング、を含むガムピースを調製する。
Claims (13)
- 低下した吸湿性を有するポリオール組成物であって、
ソルビトール、マルチトール、キシリトール、ラクチトール、ポリグリシトールまたはこれらのポリオールのうちの少なくとも1つを含む組み合わせから選択されるポリオールの粒子と、
無機材料の粒子と
を含み、
前記無機材料の前記粒子は、前記ポリオール粒子上にコーティングされており、
前記無機材料は、50μm未満のD50粒径を有し、
前記無機材料は、ヒュームドシリカ、ケイ酸カルシウム、タルク、珪藻土、軽石粉、カオリン、ベントナイト、ゼオライト、リン酸三カルシウム、リン酸二カルシウム、炭酸カルシウム、炭酸マグネシウムおよびこれらの無機材料のうちの少なくとも1つを含む組み合わせからなる群から選択され、かつ
前記無機材料は、ポリオールの前記粒子および無機材料の前記粒子の総重量に基づき、1重量%以上4重量%以下の量で存在する、ポリオール組成物。 - 低下した吸湿性を有するポリオール組成物であって、
ソルビトール、マルチトール、キシリトール、ラクチトール、ポリグリシトールまたはこれらのポリオールのうちの少なくとも1つを含む組み合わせから選択されるポリオール
の粒子と、
無機材料の粒子と
を含み、
前記無機材料の前記粒子は、前記ポリオール粒子上にコーティングされており、
前記無機材料は、50μm未満のD50粒径を有し、
前記無機材料は、ヒュームドシリカ、ケイ酸カルシウム、タルク、珪藻土、軽石粉、カオリン、ベントナイト、ゼオライト、リン酸三カルシウム、リン酸二カルシウム、炭酸カルシウム、炭酸マグネシウムおよびこれらの無機材料のうちの少なくとも1つを含む組み合わせからなる群から選択され、かつ
前記ポリオール粒子は、前記無機材料を用いたコーティングの後に、50μm未満のD50粒径を有する、ポリオール組成物。 - チューインガム組成物であって、
液体充填部組成物と、
前記液体充填部組成物を取り囲むガム領域であって、前記ガム領域は、ガムベースおよび低下した吸湿性を有するポリオール組成物を含む、ガム領域と、
前記ガム領域を取り囲む任意の外側コーティングと
を含み、
前記ポリオール組成物は、吸湿性糖アルコールの粒子および無機材料の粒子を含み、
前記吸湿性糖アルコールの粒子は、前記無機材料の粒子でコーティングされており、
前記無機材料は、50μm未満のD50粒径を有し、
前記無機材料は、ヒュームドシリカ、ケイ酸カルシウム、タルク、珪藻土、軽石粉、カオリン、ベントナイト、ゼオライト、リン酸三カルシウム、リン酸二カルシウム、炭酸カルシウム、炭酸マグネシウムおよびこれらの無機材料のうちの少なくとも1つを含む組み合わせからなる群から選択され、かつ
前記無機材料は、前記吸湿性糖アルコールの粒子および前記無機材料の粒子の総重量に基づき、1重量%以上4重量%以下の量で存在する、チューインガム組成物。 - 3週間の期間の後、前記チューインガム組成物は、前記液体充填部組成物の減少した喪失を呈する、請求項3に記載のチューインガム。
- 前記吸湿性糖アルコールは、ソルビトール、マルチトール、キシリトール、ラクチトール、ポリグリシトール、およびこれらの吸湿性ポリオールのうちの少なくとも1つを含む組み合わせからなる群から選択される、請求項3または請求項4に記載のチューインガム。
- 低下した吸湿性を有する前記ポリオール組成物は、前記チューインガム組成物の総重量に基づき、10重量%を超える量で存在する、請求項3から請求項5のいずれか1項に記載のチューインガム。
- 前記液体充填部組成物は前記チューインガム組成物の20重量%までを構成し、前記ガム領域は、前記チューインガム組成物の40重量%以上97重量%以下を構成する、請求項3から請求項6のいずれか1項に記載のチューインガム。
- 低下した吸湿性を有する前記ポリオール組成物は、50μm未満のD50粒径を有する、請求項3から請求項7のいずれか1項に記載のチューインガム。
- ガムコアを含み、
前記ガムコアは、ガムベース、微粒子クランチ物質および水不溶性微粒子物質を含み、
前記微粒子クランチ物質は、クランチ物質コーティング組成物でコーティングされた糖アルコールの粒子を含み、
前記クランチ物質コーティング組成物はアラビアガムを含み、
前記微粒子クランチ物質の中に存在する前記アラビアガムは、前記微粒子クランチ物質中に、前記微粒子クランチ物質の重量に基づき、0.5〜10重量%存在する、クランチ質チューインガム組成物。 - 前記クランチ物質コーティング組成物は5重量%以上50重量%以下のアラビアガムを含む、請求項9に記載のクランチ質チューインガム組成物。
- 5μm以上60μm以下のD50粒径を有する水不溶性微粒子物質をさらに含む、請求項9または請求項10に記載のクランチ質チューインガム組成物。
- 前記水不溶性微粒子物質は、前記ガムコアの重量に基づいて、0.01重量%以上5重量%以下の量で存在する、請求項9から請求項11のいずれか1項に記載のクランチ質チューインガム組成物。
- 前記水不溶性微粒子物質は、石英ガラス、軽石粉、珪藻土、カオリン、ベントナイト、ゼオライト、リン酸三カルシウム、炭酸カルシウム、炭酸マグネシウムおよびこれらの微粒子物質のうちの少なくとも1つを含む組み合わせからなる群から選択される、請求項9から請求項12のいずれか1項に記載のクランチ質チューインガム組成物。
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-
2011
- 2011-04-29 EP EP11717919.2A patent/EP2563162B1/en active Active
- 2011-04-29 MX MX2015006977A patent/MX345284B/es unknown
- 2011-04-29 CN CN201180032508.4A patent/CN102958379B/zh active Active
- 2011-04-29 ES ES11717919.2T patent/ES2548909T3/es active Active
- 2011-04-29 JP JP2013508279A patent/JP5659295B2/ja active Active
- 2011-04-29 EP EP15165641.0A patent/EP2939547A1/en not_active Withdrawn
- 2011-04-29 PL PL11717919T patent/PL2563162T3/pl unknown
- 2011-04-29 WO PCT/US2011/034531 patent/WO2011137329A2/en active Application Filing
- 2011-04-29 MX MX2012012746A patent/MX2012012746A/es active IP Right Grant
- 2011-04-29 US US13/643,887 patent/US20130209605A1/en not_active Abandoned
- 2011-04-29 CN CN201510359038.2A patent/CN105124126A/zh active Pending
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EP2939547A1 (en) | 2015-11-04 |
CN102958379B (zh) | 2015-07-22 |
CN102958379A (zh) | 2013-03-06 |
WO2011137329A2 (en) | 2011-11-03 |
WO2011137329A3 (en) | 2011-12-29 |
EP2941966A1 (en) | 2015-11-11 |
EP2563162B1 (en) | 2015-07-01 |
US20130209605A1 (en) | 2013-08-15 |
EP2563162A2 (en) | 2013-03-06 |
JP2015042187A (ja) | 2015-03-05 |
MX345284B (es) | 2017-01-24 |
CN105124126A (zh) | 2015-12-09 |
ES2548909T3 (es) | 2015-10-21 |
JP5659295B2 (ja) | 2015-01-28 |
JP2013526859A (ja) | 2013-06-27 |
MX2012012746A (es) | 2012-11-21 |
PL2563162T3 (pl) | 2015-12-31 |
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