JP5994253B2 - Biological treatment apparatus and method for organic wastewater - Google Patents

Description

  The present invention relates to a biological treatment apparatus and method for organic wastewater that can be used for treatment of organic wastewater in a wide concentration range such as domestic wastewater, sewage, food factory wastewater, pulp factory wastewater, semiconductor production wastewater, and liquid crystal production wastewater. In particular, the present invention relates to an organic wastewater biological treatment apparatus and method capable of improving the treatment efficiency and reducing the amount of excess sludge generation without deteriorating the quality of the treated water.

The activated sludge method used when biologically treating organic wastewater is widely used for sewage treatment, industrial wastewater treatment, and the like because of its advantages such as good treated water quality and easy maintenance. However, since the BOD volumetric load in the activated sludge method is generally about 0.5 to 0.8 kg / m ³ / d, a large site area is required. Moreover, since about 20% of the decomposed BOD is converted into bacterial cells, that is, sludge, a large amount of excess sludge treatment is also a problem.

For high load treatment of organic waste water, a fluidized bed method with a carrier added is known. When this method is used, it is possible to operate with a BOD volume load of ³ kg / m ³ / d or more. However, this method has a disadvantage that the amount of generated sludge is about 30% of the decomposed BOD, which is higher than the normal activated sludge method.

  In Patent Document 1, organic wastewater is first treated with bacteria in a first treatment tank, and organic matter contained in the wastewater is oxidatively decomposed and converted into non-aggregating bacterial cells, and then in a second treatment tank. It is described that excess sludge can be reduced by predatory removal of the sticking protozoa. Further, this method enables high-load operation and improves the processing efficiency of the activated sludge method.

In this way, many wastewater treatment methods using predation of protozoa and metazoans located at higher levels of bacteria have been proposed.
For example, Patent Document 2 proposes a countermeasure for deterioration in processing performance due to fluctuations in the quality of raw water, which is a problem in the processing method of Patent Document 1. As specific methods, “adjust BOD fluctuation of treated water to within 50% from median average concentration”, “measure water quality in first treatment tank and first treated water over time”, The method includes “adding a microbial preparation or seed sludge to the first treatment tank when the quality of the first treated water is deteriorated”.
Moreover, in patent document 3, when precipitating sludge and surplus sludge of bacteria, yeast, actinomycetes, algae, molds and wastewater treatment to protozoa and metazoans, ultrasonic treatment or mechanical agitation We have proposed a method to make the food flock size smaller than the animal's mouth.

  In addition, there exists a thing of patent document 4 as invention regarding the multistage process of a fluid bed and an activated sludge process. In this method, the latter activated sludge method is operated at a low load of BOD sludge load 0.1 kg-BOD / kg-MLSS / d, so that the sludge can be self-oxidized and the amount of sludge extraction can be greatly reduced.

  In addition, the present inventor found that when a polyurethane foam rocking bed was used as a micro animal holding carrier, there was no problem of a decrease in oxygen dissolution efficiency, and sludge with good sedimentation was generated, and a patent application was filed earlier ( Patent Document 5).

Japanese Patent Laid-Open No. 55-20649 JP 2000-210692 A Japanese Patent Publication No. 60-23832 Japanese Patent No. 3410699 Japanese Patent Application No. 2011-159719

  The multistage activated sludge method utilizing the predatory action of micro animals as described in Patent Document 4 is actually used for organic wastewater treatment. Depending on the target wastewater, the treatment efficiency is improved, about 50%. The amount of generated sludge can be reduced. However, the sludge reduction effect is not stable at present.

  In addition, in the swing bed carrier made of polyurethane foam proposed in Patent Document 5, the number of micro-animals that can be held in the tank is limited. The problem remains that SS is higher than when fluidized bed carriers are used.

  The present invention is a multi-stage activated sludge method that uses the predatory action of micro-animals, stably maintaining a large number of micro-animals in a bio-treatment tank with micro-animals, It is an object of the present invention to provide an apparatus and a method for stabilizing water quality and sludge reduction effect.

  As a result of intensive studies to solve the above-described problems, the present inventors have found that in a biological treatment system that performs biological treatment with microanimals, in an identical or different biological treatment tank, metazoans can easily produce eggs. It was found that a large number of micro-animals can be stably maintained by adding a fluidized bed carrier as a scaffold for a fixed filter-feeding micro-animal that prey on dispersible bacteria while installing the carrier.

  The present invention has been achieved on the basis of such findings, and the gist thereof is as follows.

[1] Organic wastewater is introduced into the first biological treatment tank of the aerobic biological treatment tank provided in two or more stages and biologically treated with bacteria, including dispersed bacteria from the first biological treatment tank In a biological treatment device for organic wastewater that passes the first biological treatment water through the biological treatment tanks after the second biological treatment tank and performs biological treatment, the micro-animal is held as the biological treatment tank after the second biological treatment tank. An organic wastewater biological treatment apparatus comprising at least one carrier tank for biological treatment with a carrier to be supported, wherein the carrier tank is provided with an oscillating bed carrier and a fluidized bed carrier. A biological treatment apparatus for organic wastewater, which is added to the inside.

[2] Organic wastewater is introduced into the first biological treatment tank of the aerobic biological treatment tank provided in two or more stages and biologically treated with bacteria, including dispersed bacteria from the first biological treatment tank In a biological treatment device for organic wastewater that passes the first biological treatment water through the biological treatment tanks after the second biological treatment tank and performs biological treatment, the micro-animal is held as the biological treatment tank after the second biological treatment tank. An organic wastewater biological treatment apparatus comprising at least two carrier tanks for biological treatment with a carrier to be used, wherein a fluidized bed carrier is added to the tank at a filling rate of 5 to 50% as the carrier tank. A bed support tank, and a bed swing tank provided with a bed support of 0.5 to 30% in the bed, and the treated water of the fluid bed support tank is supplied to the bed support tank. A biological treatment apparatus for organic wastewater, characterized by comprising means for introducing.

[3] Organic wastewater is introduced into the first biological treatment tank of the aerobic biological treatment tank provided in two or more stages and biologically treated with bacteria, including dispersed bacteria from the first biological treatment tank In a biological treatment device for organic wastewater that passes the first biological treatment water through the biological treatment tanks after the second biological treatment tank and performs biological treatment, the micro-animal is held as the biological treatment tank after the second biological treatment tank. An organic wastewater biological treatment apparatus provided with at least two carrier tanks for biological treatment with a carrier, wherein the fluidized bed carrier tank has a fluidized bed carrier added to the tank, and the fluidized tank. A swing bed carrier tank having a swing bed carrier provided in the tank for biological treatment by extracting a part of the treated water from the bed carrier tank, and treating the treated water in the swing bed carrier tank with the fluidized bed carrier Organic wastewater organisms characterized by having means to return to the inlet side of the tank Management apparatus.

[4] In any one of [1] to [3], the first biological treatment tank is a fluidized bed carrier tank having a carrier filling rate of 20% or less, relative to all biological treatment tanks after the second biological treatment tank. An organic wastewater biological treatment apparatus, wherein the fluidized bed carrier has a carrier filling rate of 5 to 50% and the rocking bed carrier has a carrier filling rate of 0.5 to 30%.

[5] The biological treatment apparatus for organic wastewater according to any one of [1] to [4], comprising solid-liquid separation means for solid-liquid separation of the treated water in the last biological treatment tank.

[6] Organic wastewater is introduced into the first biological treatment tank of the aerobic biological treatment tank provided in two or more stages and biologically treated with bacteria, and the dispersed bacteria from the first biological treatment tank are included. In the biological treatment method for organic wastewater, the first biological treatment water is passed through the biological treatment tank after the second biological treatment tank and biological treatment is performed, and a micro animal is held as the biological treatment tank after the second biological treatment tank. An organic wastewater biological treatment method using at least one carrier tank for biological treatment with a carrier to be supported, wherein the carrier tank is provided with an oscillating bed carrier and a fluidized bed carrier is added to the tank. A method for biological treatment of organic wastewater, wherein

[7] Organic wastewater is introduced into the first biological treatment tank of the aerobic biological treatment tank provided in two or more stages and biologically treated with bacteria, including dispersed bacteria from the first biological treatment tank In the biological treatment method for organic wastewater, the first biological treatment water is passed through the biological treatment tank after the second biological treatment tank and biological treatment is performed, and a micro animal is held as the biological treatment tank after the second biological treatment tank. A biological treatment method for organic waste water using at least two carrier tanks for biological treatment with a carrier to be used, wherein a fluidized bed carrier tank is added to the tank at a filling rate of 5 to 50% as the carrier tank. And an oscillating bed carrier tank in which the oscillating bed carrier is provided at a filling rate of 0.5 to 30%, and the treated water of the fluidized bed carrier tank is introduced into the oscillating bed carrier tank. A biological treatment method for organic wastewater.

[8] Organic wastewater is introduced into the first biological treatment tank of the aerobic biological treatment tank provided in two or more stages and biologically treated with bacteria, and the dispersed bacteria from the first biological treatment tank are included. In the biological treatment method for organic wastewater, the first biological treatment water is passed through the biological treatment tank after the second biological treatment tank and biological treatment is performed, and a micro animal is held as the biological treatment tank after the second biological treatment tank. A biological treatment method of organic waste water using at least two carrier tanks for biological treatment with a carrier to be used, wherein the fluidized bed carrier tank has a fluidized bed carrier added to the tank, and the fluidized bed. A swing bed carrier tank provided with a swing bed carrier in a tank through which a part of the treated water of the carrier tank is passed, and the treated water of the swing bed carrier tank is supplied to the inlet of the fluid bed carrier tank Biological treatment method for organic wastewater, which is returned to the side.

[9] In any one of [6] to [8], the first biological treatment tank is a fluidized bed carrier tank having a carrier filling rate of 20% or less, and the whole biological treatment tank after the second biological treatment tank A biological treatment method for organic wastewater, wherein the fluidized bed carrier has a carrier filling rate of 5 to 50% and the rocking bed carrier has a carrier filling rate of 0.5 to 30%.

[10] The biological treatment method for organic wastewater according to any one of [6] to [9], wherein the treated water in the last biological treatment tank is subjected to solid-liquid separation.

  In the present invention, in a multi-stage activated sludge method utilizing the predatory action of a micro animal, a dispersible bacterium is obtained by using a fluidized bed carrier and a rocking bed carrier in combination as a micro animal holding carrier used in a biological treatment system with micro animals. In this biological treatment system, a large number of fixed filtration predation type micro-animals that efficiently prey can be stably maintained in the biological treatment system, so that the solid-liquid separation property of sludge and the quality of treated water can be improved.

It is a systematic diagram which shows embodiment of the biological treatment apparatus and method of the organic waste water of this invention. It is a systematic diagram which shows other embodiment of the biological treatment apparatus and method of the organic waste water of this invention. It is a systematic diagram which shows other embodiment of the biological treatment apparatus and method of the organic waste water of this invention. It is a systematic diagram which shows other embodiment of the biological treatment apparatus and method of the organic waste water of this invention. It is a systematic diagram which shows other embodiment of the biological treatment apparatus and method of the organic waste water of this invention. It is a systematic diagram which shows other embodiment of the biological treatment apparatus and method of the organic waste water of this invention.

  Embodiments of an organic wastewater biological treatment apparatus and method according to the present invention will be described below in detail with reference to the drawings.

1 to 6 are system diagrams showing an embodiment of the biological treatment apparatus and method for organic waste water of the present invention.
1 to 6, 1 is a first biological treatment tank, 2 is a second biological treatment tank, 3 is a solid-liquid separator (in FIGS. 1, 3 and 6, a precipitation tank), 4 is a third biological treatment tank, 5 Is a return water biological treatment tank, and the first biological treatment tank 1, the second biological treatment tank 2, the third biological treatment tank 4, and the return water biological treatment tank 5 are provided with a diffusion pipe (not shown). Further, 1A and 2A are fluidized bed carriers, and 2B, 4B and 5B are swing bed carriers. 1 to 6, members having the same function are denoted by the same reference numerals.

  In the embodiment shown in FIGS. 1 and 2, raw water (organic wastewater) is introduced into the first biological treatment tank 1 and 70% or more of organic components (soluble BOD) due to dispersible bacteria (non-aggregating bacteria). Preferably, 80% or more, more preferably 85% or more is oxidatively decomposed. The pH of the first biological treatment tank 1 is 6 to 8.5. However, when the raw water such as food manufacturing wastewater contains a lot of oil, or when the raw water such as semiconductor manufacturing wastewater or liquid crystal manufacturing wastewater contains a lot of organic solvents and cleaning agents, the pH is set to 8.0 to increase the decomposition rate. It is good also as -9.0.

Moreover, the water flow to the 1st biological treatment tank 1 is normally made into a transient type, and the BOD volumetric load of the 1st biological treatment tank 1 is 1 kg / m < ³ > / d or more, for example, 1-20 kg / m < ³ > / d, By setting the HRT (raw water retention time) to 24 h or less, preferably 8 h or less, for example 0.5 to 8 h, it is possible to obtain treated water predominated by dispersible bacteria, and by shortening the HRT. Wastewater with a low BOD concentration can be treated with a high load.

By returning a part of the sludge from the subsequent biological treatment tank to the first biological treatment tank 1, making the first biological treatment tank 1 a multistage configuration of two or more tanks, or adding a carrier , High load processing with a BOD volumetric load of 5 kg / m ³ / d or more is also possible.

  The fluidized bed carrier 1A may be added to the first biological treatment tank 1, and in this case, the shape of the carrier to be used is arbitrary such as a spherical shape, a pellet shape, a hollow cylindrical shape, a thread shape, a plate shape, a cubic shape, a rectangular parallelepiped shape, etc. In addition, the size is arbitrary at a diameter of about 0.1 to 10 mm. Further, the material of the carrier is any material such as a natural material, an inorganic material, and a polymer material, and a gel material may be used. Moreover, when the filling rate of the support | carrier added to the 1st biological treatment tank 1 is high, dispersible bacteria do not produce | generate, but bacteria adhere to a support | carrier or a filamentous bacteria grows. Therefore, by setting the filling rate of the fluidized bed carrier to be added to the first biological treatment tank 1 to 1 to 20%, desirably 5 to 10%, it is possible to generate dispersible bacteria that are not affected by concentration fluctuations and are easy to prey. It becomes possible.

Further, the first biological treatment tank 1 may suppress the growth of filamentous bacteria by setting the dissolved oxygen (DO) concentration to 1 mg / L or less, preferably 0.5 mg / L or less.
In addition, when dissolved organic matter is completely decomposed in the first biological treatment tank 1, flocs are not formed in the second biological treatment tank 2, and nutrients for microanimal growth are insufficient, and sludge with low compactness is used. Only becomes the dominant biological treatment tank. Therefore, it is preferable that the decomposition rate of the organic component in the first biological treatment tank 1 is not 100% but 95% or less, desirably 85 to 90%.

  The treated water in the first biological treatment tank 1 (first biological treated water) is passed through the second biological treatment tank 2 in the subsequent stage, where the remaining organic components are oxidatively decomposed and the dispersible bacteria are self-degraded. In addition, the excess sludge is reduced and partly flocked by predation of minute animals.

  In the second biological treatment tank 2, it is necessary to use an operation condition and a treatment apparatus that allow the microanimal and the bacteria to remain in the system in order to use the action of the microanimal having a slower growth rate than the bacteria and the autolysis of the bacteria. . In the embodiment of FIGS. 1 and 2, the swinging bed carrier 2 </ b> B is installed in the aeration tank of the second biological treatment tank 2 and the fluidized bed carrier 2 </ b> A is added to increase the amount of micro-animal retained in the tank. In the fluidized bed carrier 2A, inhabited micro-animals can efficiently prey on dispersed microorganisms, while the rocking bed carrier 2B has low shearing force and becomes a spawning place and habitat for eggs, and more stable predation. Micro animal maintenance becomes possible. For this reason, the fluidized bed carrier 2A and the rocking bed carrier 2B having different forms as described above are used together, and the fluidized bed and the rocking bed are formed in the second biological treatment tank 2, whereby the features of each carrier can be obtained. While effectively increasing the amount of micro-animals, especially dispersible bacteria, that can be efficiently fed into the tank of sludge solid-liquid segregation and improving the quality of treated water, The predatory action can be sufficiently exhibited.

  The shape of the fluidized bed carrier 2A to be added to the second biological treatment tank 2 is arbitrary such as a spherical shape, a pellet shape, a hollow cylindrical shape, a thread shape, a plate shape, a cubic shape, a rectangular parallelepiped shape, and the size is about 0.1 to 10 mm. The diameter is arbitrary. Further, the material of the carrier is any material such as a natural material, an inorganic material, and a polymer material, and a gel material may be used. The fluidized bed carrier 2A for micro animals can be made of the same material and shape as the fluidized bed carrier for dispersible bacteria used in the first biological treatment tank 1, although the object to be fixed is different.

  On the other hand, the rocking bed carrier 2B provided in the second biological treatment tank 2 is different from the fluidized bed carrier 2A, and at least a part of the carrier is fixed to any one of the bottom surface, the side surface, and the upper part of the second biological treatment tank 2. The shape of the fixed bed carrier is arbitrary, such as a thread shape, a plate shape, or a strip shape. The material of the swing bed carrier 2B is arbitrary such as a natural material, an inorganic material, or a polymer material, and a gel material may be used. Desirably, it is a porous flexible polyurethane foam. For example, the second biological treatment tank 2 may have a plate shape or strip shape having a length of 100 to 400 cm, a width of 5 to 200 cm, and a thickness of 0.5 to 5 cm. desirable.

Such an oscillating bed carrier 2B is preferably installed in the second biological treatment tank 2 such that the longitudinal direction of the plate or strip is the depth direction (vertically downward) of the second biological treatment tank 2. Is done. At this time, the direction of the short side direction of the rocking bed carrier 2B is not particularly limited. It can be installed in the treatment tank 2.
When the capacity of the second biological treatment tank 2 is larger than the size of the swing bed carrier 2B, a plurality of pieces with fasteners attached to the upper and lower surfaces of the carrier are prepared. A predetermined number of sheets are juxtaposed in the depth direction and / or the width direction, a fastener attached to the carrier is fixed to a frame material made of a material such as SUS, and the unit is further formed as necessary. A plurality of stages are provided in the direction of water flow in the biological treatment tank 2.

  A porous sponge carrier such as a thin plate-like or strip-like flexible polyurethane foam having such dimensions has sufficient elasticity and bends in the flow of water in the tank (the shape is not maintained). Therefore, even if it is thin, it has sufficient mechanical strength and will not be damaged. Moreover, by bending, it mixes uniformly, without inhibiting the water flow in a tank, and a sludge containing liquid comes to flow uniformly also into the porous structure of a support | carrier. That is, as a material having elasticity and strength that does not hinder water flow and is not easily damaged, in the present invention, as the carrier for holding a micro animal, together with the fluidized bed carrier, preferably as described above. A plate-like or strip-like flexible polyurethane foam having a specific dimension is used as the swing bed carrier.

  The carrier filling rate in the second biological treatment tank 2 is 5 to 50%, particularly 10 to 40% for the fluidized bed carrier 2A, and 0.5 to 30%, especially 1 for the rocking bed carrier 2B. It is preferable to set it to 10%. If any carrier has a low filling rate, the number of micro-animals cannot be increased. If the filling rate is too high, water permeability and aeration are inhibited.

  In the second biological treatment tank 2, not only the filtration predation type micro-animal that prey on the dispersed cells, but also the aggregate predation type micro-animal that can prey on the flocked sludge grows. Since the latter prey on flocs while swimming, if this microanimal is prioritized, sludge is eaten and becomes sludge in which fine floc pieces are scattered. By this floc piece, when the biologically treated water in the second biological treatment tank is solid-liquid separated in the sedimentation tank, the treated water is deteriorated, and when the solid-liquid separation is performed in the membrane separator, clogging of the membrane occurs. Therefore, in order to thin out aggregate predation type micro-animals, it is desirable to draw out sludge within a range of SRT (solid content retention time) of 60 days or less, preferably 45 days or less, together with the outflow of treated water SS. However, if the SRT is less than 15 days, the withdrawal is too frequent and the number of not only the aggregate-feeding micro-animals but also the filter-feeding micro-animals is too small.

  In the present invention, when a large amount of organic matter remains in the first biological treatment water flowing into the second biological treatment tank 2, the oxidative decomposition is performed in the subsequent treatment tank. It is known that when oxidative degradation of organic matter by bacteria occurs in the second biological treatment tank 2 where a large amount of micro animals are present, as a countermeasure to escape from predation of micro animals, it grows in a form that is difficult to be predated. The bacterial group thus grown is not preyed on by the micro-animals, and their decomposition depends only on autolysis, and the effect of reducing the amount of sludge generated is reduced. Therefore, as described above, in the first biological treatment tank 1, it is necessary to decompose most of the organic matter, that is, 70% or more of the raw water BOD, desirably 80% or more, and convert it into cells. When dissolved organic matter is completely decomposed in one biological treatment tank 1, flocs are not formed in the second biological treatment tank 2, and nutrition for microanimal growth is insufficient. Only sludge with low compaction is superior. It becomes an occupied biological treatment tank. Therefore, as described above, in the first biological treatment tank 1, it is necessary to decompose most of the organic matter, that is, 70% or more of the wastewater BOD, desirably 80% or more, and convert it into cells. Therefore, when expressed in terms of sludge load due to the soluble BOD in the second biological treatment tank 2, 0.025 to 0.05 kg-BOD / kg-MLSS / d, and 0 for the soluble TOC sludge load. It is desirable to operate at 005 to 0.05 kg-soluble TOC / kg-MLSS / d. Here, MLSS refers to the concentration of suspended sludge and includes sludge for carrier adhesion.

  In the embodiment of FIG. 1, the treated water in the second biological treatment tank 2 is fed to a solid-liquid separation device (precipitation tank in FIG. 1) 3 for solid-liquid separation, and the separated water is taken out as treated water and separated. The sludge is returned to the second biological treatment tank 2 as return sludge.

  Thus, by reducing the treated water in the second biological treatment tank 2 into solid-liquid separation and returning the separated sludge to the second biological treatment tank 2, it is possible to prevent a decrease in the amount of minute animals in the system, This solid-liquid separation device 3 is not necessarily required, and the effluent water of the second biological treatment tank 2 may be treated water as shown in FIG.

  Further, the solid-liquid separation device 3 is not limited to a sedimentation tank, and a floating separation device or a membrane separation device may be used. When a membrane separation device is used as the solid-liquid separation device, the generation of filamentous bacteria is suppressed in the previous stage. However, since organic substances are sufficiently removed, blockage of the film due to adhesion of organic substances and bacteria to the film surface can be suppressed.

  The embodiment shown in FIGS. 3 and 4 is a two-stage configuration of a second biological treatment tank 2 filled with a fluidized bed carrier 2A and a third biological treatment tank 4 filled with an oscillating bed carrier 4B. The biological treatment tank filled with the fluidized bed carrier and the biological treatment tank filled with the rocking bed carrier are separated, and the second biological treatment tank 2 filled with the fluidized bed carrier 2A and the third filled with the rocking bed carrier 4B. 1 and 2 is different from the embodiment shown in FIGS. 1 and 2 in that water is sequentially passed through the biological treatment tank 4, and the carrier filling rate and the preferred specifications of the carrier are shown in FIG. Same as 2 above.

  In the embodiment shown in FIGS. 3 and 4, dispersible bacteria are grown by decomposing organic matter in the first biological treatment tank 1, and in the second biological treatment tank 2, decomposition of residual organic matter and predation removal of the dispersible bacteria are performed. In the third biological treatment tank 4, predation removal and flocking of the remaining dispersible bacteria are performed.

  In such a biological treatment, since the dispersible bacteria are reduced in the second biological treatment tank 2, the third biological treatment tank 4 can be handled only by the swing bed carrier 4B having a low predation efficiency. In the third biological treatment tank 4, the rocking bed carrier 4B can promote the egg laying / growth of the minute animals and can stably hold the amount of the minute animals.

  In the embodiment of FIG. 3, the treated water in the third biological treatment tank 4 is fed to a solid-liquid separation device (precipitation tank in FIG. 3) 3 for solid-liquid separation, and the separated water is taken out as treated water and separated. The sludge is returned to the second biological treatment tank 2 as return sludge.

  As in the embodiment of FIG. 1, the treated water in the third biological treatment tank 4 is solid-liquid separated in this way, and the separated sludge is returned to the third biological treatment tank 4. Although the decrease can be prevented, the solid-liquid separation device 3 is not necessarily required, and as shown in FIG. 4, the outflow water of the third biological treatment tank 4 may be treated water. In this case, microorganisms can be replenished by returning the treated water of the third biological treatment tank 4 to the second biological treatment tank 2.

  Further, the solid-liquid separation device 3 is not limited to a sedimentation tank, and a floating separation device or a membrane separation device may be used. When a membrane separation device is used as the solid-liquid separation device, the generation of filamentous bacteria is suppressed in the previous stage. However, since organic substances are sufficiently removed, blockage of the film due to adhesion of organic substances and bacteria to the film surface can be suppressed.

  The embodiment of FIG. 5 is provided with a return water biological treatment tank 5 for biological treatment of a part of the biological treatment water in the second biological treatment tank 2, and the second biological treatment tank 2 is provided with only a fluidized bed carrier 2A. 2 is different from the embodiment shown in FIG. 2 in that the return water biological treatment tank 5 is provided with the swing bed carrier 5B. Other configurations are the same as those shown in FIG. Same as in.

  In the embodiment of FIG. 5, dispersible bacteria are grown by decomposing organic matter in the first biological treatment tank 1, and in the second biological treatment tank 2, residual organic matter is decomposed and predatory removal of the dispersible bacteria is performed. In the return water biological treatment tank 5, predation removal of residual dispersible bacteria and flocation of sludge are performed.

  In this way, a part of the treated water in the second biological treatment tank 2 is taken out, and in the return water biological treatment tank 5, the residual dispersible bacteria are predated and removed, and then returned to the second biological treatment tank 2 to be treated with the first biological treatment. Biological treatment with the treated water in the tank 1 can reduce the load of organic matter and dispersible bacteria in the second biological treatment tank 2. Since the carrier of this return water biological treatment tank 5 is the rocking bed carrier 5A, it is suitable for egg laying / growth of minute animals, and the amount of minute animals can be stably maintained.

  Of the biological treatment water in the second biological treatment tank 2, the amount of treated water treated in the return water biological treatment tank 5 and returned to the inlet side of the second biological treatment tank 2 is returned without impairing the biological treatment efficiency. In order to effectively obtain the above-described effect by the aquatic treatment tank 5, it is preferable to set the amount of outflow water of the second biological treatment tank 2 to about 1/4 to 1/1.

  Also in the embodiment shown in FIG. 5, as in the embodiment shown in FIG. 1, a precipitation tank for separating the treated water in the second biological treatment tank 2 into a solid-liquid separation, a flotation separator, a membrane separator, etc. A solid-liquid separator may be provided. In that case, it is preferable to return the separated sludge separated by solid-liquid separation to the second biological treatment tank 2.

  In the embodiment shown in FIG. 6, in the embodiment shown in FIG. 1, a coagulation tank 6 is provided between the second biological treatment tank 2 and the solid-liquid separation device 3, and the biological treatment water in the second biological treatment tank 2 is provided. Is agglomerated in the agglomeration tank 6, and the agglomerated water is solid-liquid separated by the solid-liquid separator 3 and the separated sludge is discharged out of the system as surplus sludge. The filling rate and the preferred specifications of the carrier are the same as in FIG. The solid-liquid separation method may be any of precipitation separation, flotation separation, and membrane separation.

  The flocculant added to the flocculant tank 6 in the embodiment shown in FIG. 6 includes inorganic flocculants such as polyaluminum chloride (PAC), ferric chloride, polyferric sulfate, and / or various polymer flocculants. An agent can be used. According to the present invention, in the second biological treatment tank 2 provided with the fluidized bed carrier 2A and the rocking bed carrier 2B, sludge having excellent solid-liquid separation properties is generated. Can be reduced.

  1 to 6 show an example of an embodiment of the present invention, and the present invention is not limited to the illustrated one. For example, the first biological treatment tank may have a multi-stage configuration of two or more stages as described above, or may be configured as shown in FIGS. 2 and 4 by omitting the solid-liquid separation device in FIGS. Good. In addition, as described above, in the second biological treatment tank, since an appropriate organic load is required, a part of the raw water is directly introduced into the second biological treatment tank, bypassing the first biological treatment tank. By doing so, you may make it drive | operate so that the sludge load by soluble BOD to a 2nd biological treatment tank may be 0.025kg-BOD / kg-MLSS / d or more. Note that, as described above, the MLSS at this time includes the MLSS for carrier adhesion.

Hereinafter, the present invention will be described more specifically with reference to Examples and Comparative Examples.
In the following examples and comparative examples, the treated raw water contains artificial substrates of COD _Cr : 1250 mg / L and BOD: 800 mg / L.

[Example 1]
As shown in FIG. 2, the organic waste water treatment according to the present invention was performed using an experimental apparatus in which a first biological treatment tank 1 having a capacity of 88 L and a second biological treatment tank 2 having a capacity of 150 L were connected. .
The treatment conditions for each biological treatment tank were as follows.

<First biological treatment tank>
DO: 0.5 mg / L
Fluidized bed carrier: 5 mm square, flexible polyurethane foam carrier Fluidized bed carrier filling factor: 5%
COD _Cr volumetric load: 8.6 kg-COD _Cr / m ³ / d
HRT: 3.5h
pH: 7.0
<Second biological treatment tank>
DO: 2-3 mg / L
Fluidized bed carrier: Soft polyurethane foam carrier with a 5 mm square and approximately cubic shape Fluidized bed carrier filling rate: 10%
Oscillating floor carrier: plate-shaped flexible polyurethane foam carrier (length: 100 cm x width 30 cm x thickness 1 cm)
Oscillating bed carrier filling rate: 2%
HRT: 6.0h
pH: 7.0

The plate-like flexible polyurethane foam carrier as the swing bed carrier 2B of the second biological treatment tank 2 was placed vertically in the tank (the length direction of the carrier is the depth direction of the tank). The upper and lower ends of the swinging floor carrier 2B are fixed to a frame, and the frame is fixed to the wall surface of the tank.
The COD _Cr volume load in the entire apparatus was 3.2 kg-COD _Cr / m ³ / d, and the HRT in the entire apparatus was 9.5 h.

As a result, SS of treated water (effluent of the second biological treatment tank 2) is 187 mg / L, the sludge conversion rate was _{0.15kg-SS / kg-COD Cr} .

[Example 2]
As shown in FIG. 1, using an experimental apparatus in which a first biological treatment tank 1 having a capacity of 88 L, a second biological treatment tank 2 having a capacity of 150 L, and a solid-liquid separator (precipitation tank) 3 are connected. Treatment of organic waste water according to the present invention was performed.
In the second embodiment, a sedimentation tank is provided as the solid-liquid separation device 3, the biologically treated water in the second biological treatment tank 2 is settled and separated in the sedimentation tank, the separated water is taken out as treated water, and the separated sludge is treated in the second biological treatment. Other processing conditions are the same as in Example 1 except that the sludge was extracted from the second biological treatment tank 2 so that the SRT was 30 days after returning to the tank 2.

As a result, SS in the treated water is below 20 mg / L, excess sludge fraction and combined sludge conversion rate withdrawn from the second biological treatment tank 2 was a _{0.11kg-SS / kg-COD Cr} .

[Example 3]
As shown in FIG. 4, using an experimental apparatus in which a first biological treatment tank 1 having a capacity of 88L, a second biological treatment tank 2 having a capacity of 75L, and a third biological treatment tank 4 having a capacity of 75L are connected. The organic waste water was treated according to the present invention.
The treatment conditions for each biological treatment tank were as follows.

<First biological treatment tank>
DO: 0.5 mg / L
Fluidized bed carrier: 5 mm square, flexible polyurethane foam carrier Fluidized bed carrier filling factor: 5%
COD _Cr volumetric load: 8.6 kg-COD _Cr / m ³ / d
HRT: 3.5h
pH: 7.0
<Second biological treatment tank>
DO: 2-3 mg / L
Fluidized bed carrier: Soft polyurethane foam carrier with a 5 mm square and a substantially cubic shape Swing bed carrier filling rate: 10% (based on the total of the second biological treatment tank and the third biological treatment tank)
HRT: 3h
pH: 7.0
<Third biological treatment tank>
DO: 2-3 mg / L
Oscillating floor carrier: plate-shaped flexible polyurethane foam carrier (length: 100 cm x width 30 cm x thickness 1 cm)
Oscillating bed carrier filling rate: 2% (based on the total of the second biological treatment tank and the third biological treatment tank)
HRT: 3h
pH: 7.0

In addition, the plate-shaped flexible polyurethane foam support | carrier as the rocking | swiveling bed support | carrier 4B of the 3rd biological treatment tank 4 was arrange | positioned in the tank vertically long (it makes the length direction of a support | carrier the depth direction of a tank). The upper and lower ends of the rocking floor carrier 4B are fixed to a frame, and the frame is fixed to the wall surface of the tank.
The COD _Cr volume load in the entire apparatus was 3.2 kg-COD _Cr / m ³ / d, and the HRT in the entire apparatus was 9.5 h.

As a result, SS of treated water (effluent of the second biological treatment tank 2) is 155 mg / L, the sludge conversion ratio was _{0.124kg-SS / kg-COD Cr} .

[Example 4]
As shown in FIG. 3, the first biological treatment tank 1 having a capacity of 88L, the second biological treatment tank 2 having a capacity of 75L, the third biological treatment tank 4 having a capacity of 75L, and a solid-liquid separator (precipitation tank). 3 was used to treat the organic waste water according to the present invention.
In the fourth embodiment, a sedimentation tank is provided as the solid-liquid separation device 3, the biologically treated water in the third biological treatment tank 4 is settled and separated in the sedimentation tank, the separated water is taken out as treated water, and the separated sludge is treated in the second biological treatment. Other processing conditions are the same as in Example 3 except that the sludge was extracted from the second biological treatment tank 2 so that the SRT was 30 days after returning to the tank 2.

As a result, SS in the treated water is below 20 mg / L, excess sludge fraction and combined sludge conversion rate withdrawn from the second biological treatment tank 2 was a _{0.10kg-SS / kg-COD Cr} .

[Example 5]
As shown in FIG. 6, an experiment in which a first biological treatment tank 1 with a capacity of 88 L, a second biological treatment tank 2 with a capacity of 150 L, a coagulation tank 6, and a solid-liquid separation device (precipitation tank) 3 are connected. The apparatus was used to treat organic wastewater according to the present invention.
In Example 5, a precipitation tank is provided as the coagulation tank 6 and the solid-liquid separation device 3, and the biological treatment water in the second biological treatment tank 2 is used as the coagulant in the coagulation tank 6 with an inorganic coagulant (10% polyaluminum chloride). (PAC)) 150 mg / L and 1 mg / L of an anionic polymer flocculant (Krita Kogyo Co., Ltd. “Clifflock (registered trademark) A331”) are added, and the flocculated water is separated into solid and liquid in a precipitation tank. The other treatment conditions are the same as in Example 1 except that the separated water is taken out as treated water and the separated sludge is discharged out of the system as excess sludge.

As a result, SS in the treated water is below 5 mg / L, the sludge conversion ratio of extracted sludge from the sedimentation tank became _{0.15kg-SS / kg-COD Cr} ( excluding PAC content is).

[Comparative Example 1]
In Example 1, when the treatment was performed under the same treatment conditions except that the second biological treatment tank was not provided with an oscillating bed carrier and only the fluidized bed carrier was filled at a fluidized bed carrier filling rate of 40%, the treatment was performed. SS of water in the 250mg / L, the sludge conversion rate was _{0.20kg-SS / kg-COD Cr} .

[Comparative Example 2]
In Example 5, the second biological treatment tank is not provided with a rocking bed carrier, only the fluidized bed carrier is filled at a fluidized bed carrier filling rate of 40%, the amount of inorganic flocculant added to the coagulation tank is 300 mg / L, and the polymer The treatment was performed under the same treatment conditions except that the amount of the flocculant added was 2 mg / L. As a result, the SS of the treated water was 5 mg / L or less, and the sludge conversion rate of the sludge drawn from the settling tank was 0. 20 kg-SS / kg-COD _Cr (excluding PAC content).

[Comparative Example 3]
In Example 1, the first biological treatment tank is omitted, the capacity of the second biological treatment tank is 186 L, no swing bed carrier is provided in the second biological treatment tank, and only the fluidized bed carrier is 40 When the treatment was carried out under the same treatment conditions except that it was filled in%, the SS of the treated water was 500 mg / L, and the sludge conversion rate was 0.40 kg-SS / kg-COD _Cr .

  The biological wastewater treatment apparatus and method of the present invention can be used to treat organic wastewater in a wide concentration range such as domestic wastewater, sewage, food factory wastewater, pulp factory wastewater, semiconductor production wastewater, and liquid crystal production wastewater. .

1 First biological treatment tank 2 Second biological treatment tank 3 Solid-liquid separation device (precipitation tank)
4 Third biological treatment tank 5 Return water biological treatment tank 1A, 2A Fluidized bed carrier 2B, 4B, 5B Oscillating bed carrier

Claims (10)

The first organism containing the dispersed bacteria from the first biological treatment tank by introducing organic wastewater into the first biological treatment tank of the aerobic biological treatment tank provided in two or more stages and biologically treating with bacteria In the biological treatment equipment for organic wastewater, which treats the treated water by passing it through the biological treatment tank after the second biological treatment tank,
As a biological treatment tank after the second biological treatment tank, an organic wastewater biological treatment apparatus provided with at least one carrier tank for biological treatment with a carrier for holding micro-animals,
An organic wastewater biological treatment apparatus, wherein the carrier tank is provided with a swing bed carrier in the tank and a fluidized bed carrier is added to the tank. The first organism containing the dispersed bacteria from the first biological treatment tank by introducing organic wastewater into the first biological treatment tank of the aerobic biological treatment tank provided in two or more stages and biologically treating with bacteria In the biological treatment equipment for organic wastewater, which treats the treated water by passing it through the biological treatment tank after the second biological treatment tank,
As a biological treatment tank after the second biological treatment tank, an organic wastewater biological treatment apparatus provided with at least two carrier tanks for biological treatment with a carrier for holding micro-animals,
As the carrier tank, a fluid bed carrier tank in which a fluid bed carrier is added at a filling rate of 5 to 50% in the tank, and a rocking bed in which a rocking bed carrier is provided at a filling rate of 0.5 to 30%. A floor carrier tank,
An organic wastewater biological treatment apparatus comprising means for introducing treated water from the fluidized bed carrier tank into the rocking bed carrier tank. The first organism containing the dispersed bacteria from the first biological treatment tank by introducing organic wastewater into the first biological treatment tank of the aerobic biological treatment tank provided in two or more stages and biologically treating with bacteria In the biological treatment equipment for organic wastewater, which treats the treated water by passing it through the biological treatment tank after the second biological treatment tank,
As a biological treatment tank after the second biological treatment tank, an organic wastewater biological treatment apparatus provided with at least two carrier tanks for biological treatment with a carrier for holding micro-animals,
As the carrier tank, a fluidized bed carrier tank in which a fluidized bed carrier is added to the tank, and a swing bed carrier is provided in the tank for extracting a part of the treated water from the fluidized bed carrier tank and biologically treating it. A swing bed carrier tank,
An organic wastewater biological treatment apparatus comprising means for returning treated water from the rocking bed carrier tank to the inlet side of the fluidized bed carrier tank.   The first biological treatment tank according to any one of claims 1 to 3, wherein the first biological treatment tank is a fluidized bed carrier tank with a carrier filling rate of 20% or less, and the fluidized bed with respect to all biological treatment tanks after the second biological treatment tank. A biological treatment apparatus for organic waste water, wherein the carrier filling rate of the carrier is 5 to 50%, and the carrier filling rate of the swing bed carrier is 0.5 to 30%.   5. The organic wastewater biological treatment apparatus according to claim 1, further comprising solid-liquid separation means for solid-liquid separation of the treated water in the last biological treatment tank. The first organism containing the dispersed bacteria from the first biological treatment tank by introducing organic wastewater into the first biological treatment tank of the aerobic biological treatment tank provided in two or more stages and biologically treating with bacteria In the biological treatment method for organic wastewater, the treated water is passed through a biological treatment tank after the second biological treatment tank and biologically treated.
As a biological treatment tank after the second biological treatment tank, a biological treatment method for organic wastewater using at least one carrier tank for biological treatment with a carrier for holding a micro animal,
A biological treatment method for organic waste water, wherein the carrier tank is provided with a swing bed carrier in the tank and a fluid bed carrier is added to the tank. The first organism containing the dispersed bacteria from the first biological treatment tank by introducing organic wastewater into the first biological treatment tank of the aerobic biological treatment tank provided in two or more stages and biologically treating with bacteria In the biological treatment method for organic wastewater, the treated water is passed through a biological treatment tank after the second biological treatment tank and biologically treated.
As a biological treatment tank after the second biological treatment tank, a biological treatment method for organic wastewater using at least two carrier tanks for biological treatment with a carrier for holding a microanimal,
As the carrier tank, a fluid bed carrier tank in which a fluid bed carrier is added at a filling rate of 5 to 50% in the tank, and a rocking bed in which a rocking bed carrier is provided at a filling rate of 0.5 to 30%. Using a floor carrier tank,
A biological treatment method for organic wastewater, characterized in that treated water in the fluidized bed carrier tank is introduced into the rocking bed carrier tank. The first organism containing the dispersed bacteria from the first biological treatment tank by introducing organic wastewater into the first biological treatment tank of the aerobic biological treatment tank provided in two or more stages and biologically treating with bacteria In the biological treatment method for organic wastewater, the treated water is passed through a biological treatment tank after the second biological treatment tank and biologically treated.
As a biological treatment tank after the second biological treatment tank, a biological treatment method of organic wastewater using at least two carrier tanks for biological treatment with a carrier holding a micro animal,
As the carrier tank, a fluid bed carrier tank in which a fluid bed carrier is added to the tank, and a rocking bed carrier provided in a tank through which a part of the treated water of the fluid bed carrier tank is passed. Using a floor carrier tank,
A biological treatment method for organic waste water, wherein treated water in the rocking bed carrier tank is returned to the inlet side of the fluidized bed carrier tank.   The first biological treatment tank according to any one of claims 6 to 8, wherein the first biological treatment tank is a fluidized bed carrier tank with a carrier filling rate of 20% or less, and the fluidized bed with respect to all biological treatment tanks after the second biological treatment tank. A biological treatment method for organic waste water, wherein the carrier filling rate of the carrier is 5 to 50%, and the carrier filling rate of the swing bed carrier is 0.5 to 30%.   The biological treatment method for organic wastewater according to any one of claims 6 to 9, wherein the treated water in the last biological treatment tank is subjected to solid-liquid separation.

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