WO2016132881A1 - Biological treatment tank, method for operating same and method for treating organic wastewater - Google Patents

Biological treatment tank, method for operating same and method for treating organic wastewater Download PDF

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Publication number
WO2016132881A1
WO2016132881A1 PCT/JP2016/052994 JP2016052994W WO2016132881A1 WO 2016132881 A1 WO2016132881 A1 WO 2016132881A1 JP 2016052994 W JP2016052994 W JP 2016052994W WO 2016132881 A1 WO2016132881 A1 WO 2016132881A1
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Prior art keywords
biological treatment
treatment tank
carrier
water
tank
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PCT/JP2016/052994
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French (fr)
Japanese (ja)
Inventor
田中 一平
哲 清水
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栗田工業株式会社
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Priority claimed from JP2015183054A external-priority patent/JP6024807B2/en
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Publication of WO2016132881A1 publication Critical patent/WO2016132881A1/en

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/08Aerobic processes using moving contact bodies
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/20Activated sludge processes using diffusers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Definitions

  • the present invention relates to a biological treatment tank that can be widely used for the treatment of organic wastewater such as domestic wastewater, sewage, food factories, pulp factories, semiconductor production wastewater, and liquid crystal production wastewater, its operating method, and organic wastewater treatment method. About.
  • organic wastewater such as domestic wastewater, sewage, food factories, pulp factories, semiconductor production wastewater, and liquid crystal production wastewater
  • the activated sludge method used when biologically treating organic wastewater is widely used for sewage treatment, industrial wastewater treatment, and the like because of its advantages such as good treated water quality and easy maintenance.
  • the BOD volumetric load in the activated sludge method is generally about 0.5 to 0.8 kg / m 3 / d, a large site area is required.
  • 20 to 40% of the decomposed BOD is converted into bacterial cells, that is, sludge, a large amount of excess sludge treatment is also a problem.
  • Patent Document 1 organic wastewater is first treated with bacteria in a first treatment tank, and organic matter contained in the wastewater is oxidatively decomposed and converted into non-aggregating bacterial cells, and then in a second treatment tank. It is described that excess sludge can be reduced by predatory removal of the sticking protozoa. Further, this method enables high-load operation and improves the processing efficiency of the activated sludge method.
  • Patent Document 2 describes a countermeasure against deterioration in processing performance due to fluctuations in the quality of raw water, which is a problem in the processing method of Patent Document 1.
  • the method includes “adding a microbial preparation or seed sludge to the first treatment tank when the quality of the first treated water deteriorates”.
  • Patent Document 3 flocs that are preyed by ultrasonic treatment or mechanical agitation when protozoa or metazoans prey on bacteria, yeast, actinomycetes, algae, molds, wastewater treatment primary sludge or surplus sludge. A method to make the flock size smaller than the animal's mouth is proposed.
  • Patent Document 4 There is a method described in Patent Document 4 as a biological treatment method of organic wastewater by a multi-stage treatment of fluidized bed and activated sludge process.
  • the latter activated sludge method is operated at a low load of BOD sludge load 0.1 kg-BOD / kg-MLSS / d, so that the sludge can be self-oxidized and the amount of sludge extraction can be greatly reduced.
  • a concrete water tank is used as a tank body of a conventional biological treatment tank.
  • the concrete tank has the following problems.
  • Iv It is difficult to check for liquid leakage from the bottom.
  • a new fluidized bed carrier is introduced into the tank and aeration is started.
  • the entire amount of the carrier is put into the tank at a time, most of the carrier remains floating and hardly flows.
  • a gas phase layer is formed between the surface of the carrier group that floats on the water surface due to the entire explosion and the water surface, so that the carrier is not in contact with water and the surface of the carrier is hydrophobic. It is estimated that it takes a long time to get used to. This is because the carrier is made of a material having a bulk specific gravity smaller than 1, such as a sponge.
  • the carrier is gradually introduced into the tank at different timings, and the carrier is caused to flow by aeration while suppressing the floating of the carrier, so that it takes a long time to introduce the whole amount of the carrier.
  • the carrier is replenished or replaced, there are the same problems as described above.
  • JP-A-55-20649 JP 2000-210692 A Japanese Patent Publication No. 60-23832 Japanese Patent No. 3410699
  • the present invention solves such a problem, and allows the carrier to flow quickly at the start of operation or at the time of replenishment or replacement of the carrier, the biological treatment tank having a short start-up time, its operating method, and organic property It aims at providing the processing method of waste water.
  • an object of the present invention is to provide an organic wastewater treatment apparatus that can easily cope with various changes in raw water quality, required water quality, and increased amount of treated water.
  • the biological treatment tank of the present invention is a biological treatment tank provided with an air diffuser at the bottom of the tank, and as the air diffuser, at least a first air diffuser provided on one half side of the bottom of the biological treatment tank And a second air diffuser provided on the other half side, the first supply mode for supplying gas only to the first air diffuser, and the gas to both the first and second air diffusers It is characterized by comprising a gas supply switching means for switching between the second supply mode for supplying gas.
  • the operation method of the biological treatment tank of the present invention is an operation method of the biological treatment tank in which the carrier is caused to flow by aeration from an air diffuser provided at the bottom of the biological treatment tank containing a fluidized bed carrier having a bulk specific gravity smaller than 1.
  • aeration is performed from an air diffuser provided on one half of the bottom of the biological treatment tank to form a vertical circulation flow in the tower.
  • water may be sprayed into the tower. You may sprinkle defoamer containing water.
  • the biological treatment tank is preferably a cylindrical tower having a ratio (H / D) of height (H) to diameter (D) of 1.5 to 5.0. .
  • the organic wastewater biological treatment method of the present invention is a method of biologically treating organic wastewater in a biological treatment tank provided in one or more stages, and at least one biological treatment tank is activated by the operation method of the present invention. It is characterized by that.
  • the first biological treatment water in which the dispersal bacteria are increased is generated by the decomposition of the organic matter by the dispersal bacteria, and the second biological treatment water is produced in the second-stage biological treatment tank. It is preferable to make it.
  • the first biological treatment tank and the second biological treatment tank have towers of the same shape and size, and the height of the towers is preferably 6 to 11 m.
  • a plurality of first biological treatment tanks and second biological treatment tanks may be installed in parallel.
  • the biological treatment tank and the operation method thereof according to the present invention when the fluidized bed carrier is put into the biological treatment tank, aeration is performed from the air diffuser provided on the half of the bottom of the biological treatment tank, and the biological treatment tank is vertically moved. Since a circulating flow is formed, even a fluidized bed carrier having a bulk specific gravity smaller than 1 is quickly immersed in water and flows. For this reason, starting of a biological treatment tank can be accelerated.
  • the fluidized bed carrier can be submerged and fluidized faster.
  • the wettability of the carrier is improved, and aeration bubbles can be prevented from being entangled with the carrier and rising of the carrier.
  • baffle such as a baffle plate or draft tube
  • it will be mixed well by air lift action during single-sided aeration, but it will interfere with mixing when the whole surface is aerated, so the baffle will be installed in the biological treatment tank. It is preferable to have a structure that does not.
  • the method of the present invention is suitable for application when the specific height (H / D) of the biological treatment tank is large.
  • the organic wastewater treatment apparatus used in one aspect of the present invention includes a plurality of water treatment units having towers of standard dimensions (same shape, same size), and each water treatment unit is in advance in a factory. Can be produced. In addition, since the size of each tank is unified, the design and construction of the apparatus are made common and can be performed easily and quickly. The space between the tanks can also be reduced. It is easy to add biological treatment tanks.
  • biological treatment tanks are provided in multiple stages, the biological treatment tank in the previous stage is a dispersion bacteria tank that converts organic matter into dispersal bacteria, and the last biological treatment tank has an adhesive property that prey on the dispersal bacteria.
  • a carrier is provided as a scaffold for filtered predatory microanimals. In this treatment, the micro-animal can be stably maintained, and the treated water quality can be stabilized.
  • FIG. 1 is a longitudinal sectional view of an organic wastewater treatment apparatus according to an embodiment.
  • 2a to 2h are plan views showing examples of arrangement of water treatment units in the organic wastewater treatment apparatus of the present invention.
  • FIG. 3 is an explanatory view of water circulation in the biological treatment tank.
  • FIG. 1 shows an embodiment of a biological treatment apparatus for organic wastewater according to the present invention.
  • a first biological treatment tank 1 and a second biological treatment tank 2 are erected on a foundation 3 and are connected by a pipe 4. Connected in series.
  • the first biological treatment tank 1 is connected to the cylindrical tower 10, the raw water inlet 11 a having a flange structure provided on the lower side surface of the tower 10, and the raw water inlet 11 a,
  • the raw water introduction pipe 11 whose upper end is open above the water surface level, the diffuser pipes 12a and 12b provided at the bottom of the tower body 10, and the lower part of the tower body 10 are provided.
  • the level of the upper end 15a of the outflow pipe 15 is the water level in the tower body 10.
  • the pipe 4 is connected to the end 15 b of the outflow pipe 15.
  • the tower body 10 is filled with a fluidized bed carrier C.
  • the front surface directed toward the center side in the tower body 10 is a screen surface made of a wedge wire or the like.
  • the carrier C does not pass through the screen surface.
  • the diffuser tube 12a is disposed on one half side of the bottom surface of the tower body 10, and the diffuser tube 12b is disposed on the other half side of the bottom surface.
  • the area of the half side region is the area of the bottom surface of the tower body 10 15 to 50%, preferably 20 to 45%.
  • An opening 17 is provided at the top of the tower body 10, and one end of the atmosphere communication pipe 17 is connected thereto.
  • the atmosphere communication pipe 17 extends downward through the tower body 10, and the lower end is drawn out of the tower body 10 in the immediate vicinity of the foundation 3 and is open toward the atmosphere.
  • a reserve seat that can be opened and closed is provided at the top of the tower body 10, and a manhole and a reserve seat are provided at the bottom.
  • the second biological treatment tank 2 includes a cylindrical tower body 20 having the same shape and size as the tower body 10, a flanged structure inlet 21 provided on the lower side surface of the tower body 20, and the inside of the tower body 20.
  • Diffuser pipes 22a and 22b provided at the bottom of the column, a strainer 23 installed slightly below the middle in the vertical direction in the tower body 20, a lower end connected to the strainer 23, and an upper end higher than the water level.
  • the water sprinkler 26 provided in the upper part of the tower body 20 is provided.
  • the level of the upper end portion 25a of the outflow pipe 25 is the water level in the tower body 20.
  • the tower body 20 is filled with a fluidized bed carrier C.
  • the carrier C does not pass through the strainer 23.
  • the diffuser tube 22a is arranged on one half side of the bottom surface of the tower body 20, and the diffuser tube 22b is arranged on the other half side of the bottom surface.
  • the area of the half side region is the area of the bottom surface of the tower body 20 15 to 50%, preferably 20 to 45%.
  • the diffuser tubes 12a, 12b, 22a, and 22b are connected to blowers (not shown) through valves (not shown).
  • the air supply mode first supply mode
  • the air supply mode first supply mode
  • the air supply mode first supply mode
  • the diffuser tubes 22a and 22b first 2 supply modes
  • opening the valve of the air diffuser 12a and closing the valve of the air diffuser 12b air can be supplied to only the air diffuser 12a and one-sided explosion can be performed, and both the valves of the air diffusers 12a and 12b are opened.
  • the blower when the water level is high, a high-pressure blower having a capability of a discharge pressure of 60 kPa or more such as a screw blower or a turbo blower is preferable.
  • An opening 27a is provided at the top of the tower body 20, and one end of the atmosphere communication pipe 27 is connected thereto.
  • the atmosphere communication pipe 27 extends downward in the tower body 20, and the lower end 27 e is drawn out of the tower body 20 in the immediate vicinity of the foundation 3 and is opened toward the atmosphere.
  • the top of the tower body 20 is provided with an openable / closable spare seat, and the lower portion is provided with a manhole and a spare seat.
  • the tower bodies 10 and 20 are preferably made of resin such as FRP in order to eliminate the need for lining, but may be steel plates depending on the water quality.
  • FRP resin such as FRP
  • the first and second biological treatment tanks 1 and 2 are provided with an excess sludge extraction pipe, a drain pipe, a wiring insertion port, a sampling port (not shown), and the like.
  • the inside of the tank is monitored with a camera or a photographing device (preferably with illumination or an infrared camera) having a moving image photographing function.
  • Shooting data is transmitted wirelessly or by wire.
  • the photographing data may be stored in the photographing equipment.
  • a heat insulating material may be wound around the tower in advance.
  • water level gauges pressure gauges, flow meters, water temperature gauges, water quality gauges, and other measuring instruments in water tanks or peripheral equipment, piping, etc.
  • it is used for optimizing the treatment in the water tank in combination with incidental facilities (for example, facilities equipped with water supply, heating, chemical injection, aeration, dehydration functions, etc.).
  • raw water (organic wastewater) is introduced into the first biological treatment tank 1 through the introduction pipe 11, and aerated and diffused by the diffuser pipes 12a and 12b.
  • 70% or more, desirably 80% or more, more desirably 85% or more of the organic component (soluble BOD) is oxidatively decomposed by a sex bacterium (non-aggregating bacterium).
  • the pH of the first biological treatment tank 1 is preferably 6 to 8.5. However, when the raw water such as food manufacturing wastewater contains a lot of oil, or when the raw water such as semiconductor manufacturing wastewater or liquid crystal manufacturing wastewater contains a lot of organic solvent or cleaning agent, the pH is 8 It can be ⁇ 9.
  • the water flow to the 1st biological treatment tank 1 shall be a transient type.
  • the BOD volumetric load of the first biological treatment tank 1 is 1 kg / m 3 / d or more, for example 1 to 20 kg / m 3 / d
  • HRT raw water residence time
  • HRT raw water residence time
  • the filling rate of the carrier in the first biological treatment tank 1 is high, dispersal bacteria are not generated, and bacteria adhere to the carrier or filamentous bacteria grow. Therefore, by setting the filling rate of the carrier added to the first biological treatment tank 1 to 10% or less, for example, 1 to 10% in the case of a fluidized bed carrier, the dispersal bacteria that are easy to prey without being affected by the concentration fluctuation. Generation is possible.
  • the dissolved oxygen (DO) concentration in the first biological treatment tank 1 may be 1 mg / L or less, preferably 0.5 mg / L or less to suppress the growth of filamentous bacteria.
  • the treated water (first biological treated water) of the first biological treatment tank 1 is introduced into the second biological treatment tank 2 in the subsequent stage via the pipes 14, 15, 4 and the inlet 21, aerated, and remains. Reduce excess sludge by oxidative degradation of organic components, self-degradation of dispersible bacteria, and predation of micro-animals.
  • the second biological treatment tank 2 it is necessary to use an operation condition and a treatment apparatus that allow the microanimal and the bacteria to remain in the system in order to use the action of the microanimal having a slower growth rate than the bacteria and the autolysis of the bacteria. . Therefore, in this embodiment, the second biological treatment tank 2 is filled with the fluidized bed carrier C to increase the amount of micro-animal retained in the tank.
  • the shape of the fluidized bed carrier C is arbitrary such as a spherical shape, a pellet shape, a hollow cylindrical shape, a thread shape, and a plate shape, and the size (diameter) is about 0.1 to 10 mm.
  • the material of the carrier C is arbitrary such as a natural material, an inorganic material, or a polymer material, and a gel material may be used.
  • the carrier C has a bulk specific gravity of less than 1 in a dry state, and specifically, a sponge carrier is suitable.
  • the second biological treatment tank 2 may be further filled with a rocking bed carrier in addition to the fluidized bed carrier.
  • the filling rate of the carrier is excessively high, mixing in the tank, sludge decay, etc. may occur.
  • the filling rate is preferably about 0.5 to 30%, particularly about 1 to 10%.
  • the pH of the second biological treatment tank 2 may be 7.0 or less.
  • the second biological treatment tank 2 not only the filtration predation type micro-animal that prey on the dispersed cells but also the aggregate predation type micro-animal that can prey on the floc sludge grows. Since the latter prey on flocs while swimming, if priority is given, sludge is eaten and becomes sludge in which fine floc pieces are scattered (sludge with poor sedimentation). This floc piece causes clogging of the membrane particularly in the membrane activated sludge method in which membrane separation is performed at a later stage. Therefore, in order to thin out the aggregate predatory microanimals, it is desirable to control the SRT to be constant within a range of 60 days or less, preferably 45 days or less. However, if it is less than 15 days, it is unnecessarily frequent, and the number of not only aggregate predation type micro-animals but also filtration predation type micro-animals is excessively reduced.
  • the first biological treatment tank 1 it is necessary to decompose most of the organic matter, that is, 70% or more of the wastewater BOD, desirably 80% or more, and convert it into microbial cells.
  • the organic substances When the organic substances are completely decomposed, flocs are not formed in the second biological treatment tank 2, and there is not enough nutrients for the growth of micro-animals. Only sludge with poor compaction (sludge with poor sedimentation) is excellent. It becomes an occupied biological treatment tank. Therefore, a part of the raw water is bypassed and supplied to the second biological treatment tank 2 so that the sludge load due to the soluble BOD in the second biological treatment tank 2 is 0.025 kg-BOD / kg-MLSS / d or more. You may drive.
  • the MLSS at this time includes MLSS for the carrier adhering.
  • any of solid separation and membrane separation, coagulation sedimentation, and pressurized flotation to obtain a higher quality of treated water May be performed.
  • the amount of coagulant added can be reduced.
  • the sedimentation water from the second biological treatment tank 2 may be agglomerated in a coagulation tank, and then precipitated in a solid-liquid separation tank (sedimentation tank) to separate into treated water and sedimented sludge.
  • first and second biological treatment tanks 1 and 2 when foaming occurs due to aeration, it is preferable to spray the defoamer aqueous solution from the sprinklers 16 and 26 to prevent foaming.
  • FIG. 1 shows an example of an embodiment of the present invention, and the present invention is not limited to the illustrated one.
  • the biological treatment tank may be provided in three or more stages by providing a third biological treatment tank after the first biological treatment tank 1 and the second biological treatment tank 2.
  • the biological treatment can be only a one-stage treatment using a fluidized bed carrier, for example.
  • FIGS. 2 a to 2 h are plan views showing various arrangement patterns of the first biological treatment tank 1 and the second biological treatment tank 2.
  • FIG. 2a shows a first biological treatment tank 1 and a second biological treatment tank 2 installed one by one and connected in series.
  • FIG. 2b shows one first biological treatment tank 1 installed and a plurality of second biological treatment tanks 2 arranged in parallel.
  • FIG. 2c shows a plurality of first biological treatment tanks 1 installed in parallel and one second biological treatment tank 2 installed.
  • FIG. 2d shows a series connection of the first biological treatment tank 1 and the second biological treatment tank 2 arranged in parallel.
  • FIG. 2e and 2f show a plurality of first biological treatment tanks 1 installed in parallel and a plurality of second biological treatment tanks 2 installed in parallel.
  • the number of first biological treatment tanks 1 is the same. More than the second biological treatment tank 2, and the number of the second biological treatment tank 2 is larger than that of the first biological treatment tank 1 in FIG. Although illustration is omitted, the first biological treatment tank 1 and the second biological treatment tank 2 may be the same number.
  • FIG. 2g shows a plurality of second biological treatment tanks 2 and 2 'installed in series.
  • FIG. 2h shows a plurality of FIG. 2g installed in parallel.
  • the remaining first biological treatment tanks are maintained while being stopped and maintained in some of the first biological treatment tanks or the second biological treatment tanks.
  • the operation of the organic wastewater treatment apparatus can be continued using the second biological treatment tank.
  • the first biological treatment tank 1 and the second biological treatment tank 2 can be installed in various patterns, depending on the amount and quality of raw water at the site. It can be an array.
  • at least one of the first biological treatment tank and the second biological treatment tank is additionally installed in parallel or in series with the existing organic wastewater treatment apparatus of the present invention structure to cope with an increase in raw water flow rate and water quality fluctuation. be able to.
  • the tower bodies 10 and 20 have the same shape and the same size, even when many tower bodies 10 and 20 are installed, the tower bodies are installed close to each other, and the space between the tower bodies is increased. It is possible to reduce the installation space of the entire organic wastewater treatment apparatus. Moreover, the manufacturing cost of the tower bodies 10 and 20 is also low.
  • the structure of each tower is the same, so the installation work of the towers and the pipe connection work of each tower are the same, improving work efficiency and shortening the construction period. be able to.
  • Each of the towers 10 and 20 has a diameter of 2.2 to 3.6 m, particularly 2.4 to 3.3 m, a height of 6 to 11 m, particularly 8 to 11 m, and a height H and a diameter D.
  • the ratio H / D is preferably 1.5 to 5.0, more preferably 3.0 to 4.5.
  • the height from the foundation 3 is 4 m or less, particularly 3.0 m or less, for the main pipe connection part, the manhole, the strainer 23, the diffuser pipes 12a, 12b, 22a, 22b and the like.
  • an anaerobic treatment tank may be installed in front of the first biological treatment tank 1 and the treated water of the anaerobic treatment tank may be introduced into the first biological treatment tank.
  • the size of the tower body of the anaerobic treatment tank may be the same as that of the tower bodies 10 and 20.
  • an adjustment tank may be installed in the forefront of the anaerobic or aerobic treatment tank.
  • the adjustment tank include, but are not limited to, a raw water tank for leveling the raw water flow rate, a settling tank for settling solid matter, and a pressurized flotation device.
  • each biological treatment tank is preliminarily attached to the tower with attached equipment such as a diffuser pipe at the factory, transferred to the site, and installed on the foundation.
  • attached equipment such as a diffuser pipe
  • the carrier C is a sponge carrier or the like, it remains floating even if it is put into the tower body 10 or 20, and is hardly submerged even if aeration is performed simultaneously from each air diffuser.
  • aeration single-sided aeration
  • the diffuser pipes 12a and 22a are arranged to be biased to one half of the bottom of the tower bodies 10 and 20, when aeration is performed from the diffuser pipes 12a or 22a, bubbles are mainly formed on the inner peripheral surface of the tower body 10 or 20.
  • a circulation flow in the vertical direction is formed in 20.
  • the carrier C introduced into the tower body 10 or 20 is drawn into the water by this downward flow, and becomes compatible with water and flows in the tower bodies 10 and 20.
  • a fluidized bed carrier having a bulk specific gravity of less than 1 when dry, to which no microorganisms have adhered yet
  • the carrier floats when the entire surface is aerated.
  • the surface of the carrier is hydrophobic, and if it is left as it is, a foam film is formed on the surface and floats, and a gas phase layer is formed by aeration between the carrier layer and the water surface, so that the carrier touches the water. It will not be in a state. Therefore, a large eddy current is formed in the tank by performing single-sided aeration.
  • the fluidized bed carrier is mixed to the inside of the tank while being drawn into the downward flow of the vortex. If the water depth of the tank is deep, a plurality of vortex flows may be formed in the vertical direction as shown in FIG. In the present invention, one or more of these vertical vortex flows are collectively referred to as “vertical flow”.
  • the carrier becomes easy to become familiar with water, especially when the carrier surface is hydrophobic. It is presumed that when the carrier is a porous carrier such as a sponge carrier, water is forcibly soaked into the carrier and the gas inside the carrier is easily replaced with water. In addition, it is considered that the porous carrier is increased in bulk specific gravity (when wet) due to substitution of water in the gas inside the carrier and accumulation of moisture in the carrier, thereby improving sedimentation.
  • the carrier is quickly dispersed in water and starts to flow.
  • the carrier is introduced during single-sided aeration, and the carrier flows into the water after a predetermined time (for example, 5 minutes to 4 days) from the time when the single-sided aeration is started after the introduction of the carrier or after the introduction of the carrier. Then, immediately or after continuing the operation for a while at a low load (for example, 5 minutes to 10 days), the whole blast gas is transferred from all the diffuser tubes 12a and 22a.
  • water can be sprinkled from the water sprinkler 16 and water can be poured onto the carrier to promote the submergence of the carrier. That is, by sprinkling water onto the carrier, the surface can be dried and the carrier in a hydrophobic state can be forcibly adapted to water, and weight can be applied by attaching or penetrating water to the carrier. .
  • This water may be raw water or treated water.
  • the composition of an antifoamer is not specifically limited, The antifoamer composition containing an oil-in-water emulsion can be used.
  • the entire aeration is performed to diffuse from all the diffuser tubes 12a and 12b and the diffuser tubes 22a and 22b.
  • the amount of air diffused during the entire surface aeration is preferably 320 to 600 Nm 3 / h.
  • Single-sided aeration is less diffused than full-surface aeration. For example, when the area of the half-side area by single-sided aeration is 50% of the tower bottom area, the amount of diffused air from single-sided aeration is 160 to 300 Nm 3 / h, half.
  • Example 1 Into the tower 10 having the configuration shown in FIG. 1 having an inner diameter of 2.5 m, a height of 10 m, and a water surface height of 9 m, a 3 mm square sponge carrier 704 kg having a bulk specific gravity of 0.04 g / cm 3 is introduced. When aeration was performed at an aeration amount of 240 Nm 3 / h, all carriers started to flow within 10 min. The area of the region on the half side where the diffuser 12 a is arranged is 50% of the bottom area of the tower body 10.
  • Example 2 In Example 1, when a higher alcohol emulsion type antifoaming agent “Kurires 653” (manufactured by Kurita Kogyo Co., Ltd.) was sprinkled at 100 L / min from the water sprinkler 16 as an antifoaming agent, all the carriers flowed within 5 min. Started.
  • a higher alcohol emulsion type antifoaming agent “Kurires 653” manufactured by Kurita Kogyo Co., Ltd.
  • Example 1 In Example 1, when aeration was performed from the diffuser tubes 12a and 12b at a total aeration amount of 240 Nm 3 / h, most of the carrier floated above the water surface and did not flow even after 7 days.
  • Example 2 In Example 2, when aeration was performed from the diffuser tubes 12a and 12b at a total aeration amount of 240 Nm 3 / h, it took 7 days for all the carriers to start flowing.
  • Comparative Example 3 In Comparative Example 1, when the total amount of aeration from the diffusing tubes 12a and 12b was 480 Nm 3 / h, most of the carrier floated above the water surface and did not flow even after 7 days.
  • Comparative Example 4 In Comparative Example 2, when the total amount of aeration from the diffusing tubes 12a and 12b was 480 Nm 3 / h, it took 5 days for all the carriers to start flowing.

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  • Biodiversity & Conservation Biology (AREA)
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Abstract

Provided are: a method for operating a biological treatment tank, whereby a carrier can be fluidized at an early stage of a step for loading the carrier, e.g., at the start of the operation so that the operation can be started in a short period of time; a method for treating organic wastewater; and a biological treatment tank. A device for biologically treating organic wastewater in a biological treatment tank, wherein, at a step for loading a carrier to the biological treatment tank, air is diffused exclusively from a half side of air diffusion tubes to form a circulation flow within the tank, and then air is diffused from all of the air diffusion tubes. The biological treatment tank is provided with a tower of 6-11 m in height, wherein the ratio of the height of the tower to the diameter thereof is 1.5-5.0.

Description

生物処理槽、その運転方法及び有機性排水の処理方法Biological treatment tank, operation method thereof, and organic wastewater treatment method
 本発明は、生活排水、下水、食品工場、パルプ工場、半導体製造排水、液晶製造排水等の有機性排水の処理に広く利用することができる生物処理槽、その運転方法及び有機性排水の処理方法に関する。 The present invention relates to a biological treatment tank that can be widely used for the treatment of organic wastewater such as domestic wastewater, sewage, food factories, pulp factories, semiconductor production wastewater, and liquid crystal production wastewater, its operating method, and organic wastewater treatment method. About.
 有機性排水を生物処理する場合に用いられる活性汚泥法は、処理水質が良好で、メンテナンスが容易であるなどの利点から、下水処理や産業廃水処理等に広く用いられている。しかしながら、活性汚泥法におけるBOD容積負荷は一般に0.5~0.8kg/m/d程度であるため、広い敷地面積が必要となる。また、分解したBODの20~40%が菌体、即ち汚泥へと変換されるため、大量の余剰汚泥処理も問題となる。 The activated sludge method used when biologically treating organic wastewater is widely used for sewage treatment, industrial wastewater treatment, and the like because of its advantages such as good treated water quality and easy maintenance. However, since the BOD volumetric load in the activated sludge method is generally about 0.5 to 0.8 kg / m 3 / d, a large site area is required. Further, since 20 to 40% of the decomposed BOD is converted into bacterial cells, that is, sludge, a large amount of excess sludge treatment is also a problem.
 有機性排水の高負荷処理に関しては、担体を添加した流動床法が知られている。この方法を用いた場合、3kg/m/d以上のBOD容積負荷で運転することが可能となる。しかしながら、この方法では発生汚泥量は分解したBODの30~50%程度で、通常の活性汚泥法より高くなることが欠点となっている。 For high load treatment of organic waste water, a fluidized bed method with a carrier added is known. When this method is used, it is possible to operate with a BOD volume load of 3 kg / m 3 / d or more. However, this method has a disadvantage that the amount of generated sludge is about 30 to 50% of the decomposed BOD and is higher than that of the normal activated sludge method.
 特許文献1には、有機性排水をまず、第一処理槽で細菌により処理し、排水に含まれる有機物を酸化分解して非凝集性の細菌の菌体に変換した後、第二処理槽で固着性原生動物に捕食除去させることで余剰汚泥の減量化が可能になることが記載されている。さらに、この方法では高負荷運転が可能となり、活性汚泥法の処理効率も向上するとされている。 In Patent Document 1, organic wastewater is first treated with bacteria in a first treatment tank, and organic matter contained in the wastewater is oxidatively decomposed and converted into non-aggregating bacterial cells, and then in a second treatment tank. It is described that excess sludge can be reduced by predatory removal of the sticking protozoa. Further, this method enables high-load operation and improves the processing efficiency of the activated sludge method.
 このように細菌の高位に位置する原生動物や後生動物の捕食を利用した廃水処理方法は、多数考案されている。例えば、特許文献2には、特許文献1の処理方法で問題となる原水の水質変動による処理性能悪化の対策が記載されている。具体的な方法としては、「被処理水のBOD変動を平均濃度の中央値から50%以内に調整する」、「第一処理槽内および第一処理水の水質を経時的に測定する」、「第一処理水の水質悪化時には微生物製剤または種汚泥を第一処理槽に添加する」等の方法をあげている。 Many wastewater treatment methods have been devised that use predation of protozoa and metazoans located at a high level of bacteria. For example, Patent Document 2 describes a countermeasure against deterioration in processing performance due to fluctuations in the quality of raw water, which is a problem in the processing method of Patent Document 1. As specific methods, “adjust BOD fluctuation of treated water to within 50% from median average concentration”, “measure water quality in first treatment tank and first treated water over time”, The method includes “adding a microbial preparation or seed sludge to the first treatment tank when the quality of the first treated water deteriorates”.
 特許文献3では、細菌、酵母、放線菌、藻類、カビ類や廃水処理の初沈汚泥や余剰汚泥を原生動物や後生動物に捕食させる際に超音波処理または機械攪拌により、捕食されるフロックのフロックサイズを動物の口より小さくさせる方法を提案している。 In Patent Document 3, flocs that are preyed by ultrasonic treatment or mechanical agitation when protozoa or metazoans prey on bacteria, yeast, actinomycetes, algae, molds, wastewater treatment primary sludge or surplus sludge. A method to make the flock size smaller than the animal's mouth is proposed.
 流動床と活性汚泥法の多段処理による有機性排水の生物処理方法としては、特許文献4に記載のものがある。この方法では、後段の活性汚泥法をBOD汚泥負荷0.1kg-BOD/kg-MLSS/dの低負荷で運転することで、汚泥を自己酸化させ、汚泥引き抜き量を大幅に低減できるとしている。 There is a method described in Patent Document 4 as a biological treatment method of organic wastewater by a multi-stage treatment of fluidized bed and activated sludge process. In this method, the latter activated sludge method is operated at a low load of BOD sludge load 0.1 kg-BOD / kg-MLSS / d, so that the sludge can be self-oxidized and the amount of sludge extraction can be greatly reduced.
 従来の生物処理槽の槽体としては、コンクリート水槽が用いられている。 A concrete water tank is used as a tank body of a conventional biological treatment tank.
 コンクリート水槽には次の課題がある。
(i)槽本体が現地土木工事となり、更に槽内部装置の設置が槽施工後となり、現地での工期が長くなる。施工・品質管理の面でも不安が残る。
(ii)実用上で水深が通常4m程度までであるため、現地での設置スペースが大きくなる。
(iii)原水負荷増加に対応して設備を増強したい場合であっても、現地土木工事でかつ設置面積が大きいことから、増設が容易に出来ない。
(iv)底部からの液漏れの点検がしづらい。
(V)槽内面ライニング補修を行う必要がある。
The concrete tank has the following problems.
(I) The main body of the tank will be civil engineering work, and the internal equipment will be installed after the tank construction. Concerns remain in terms of construction and quality control.
(Ii) Since the water depth is practically up to about 4 m for practical use, the installation space at the site becomes large.
(Iii) Even if it is desired to reinforce equipment in response to an increase in raw water load, it cannot be easily expanded due to local civil engineering work and a large installation area.
(Iv) It is difficult to check for liquid leakage from the bottom.
(V) It is necessary to repair the tank lining.
 流動床方式の好気性生物処理槽を新たに設置して運転を開始する場合、新品の流動床担体を槽内に投入して曝気を開始する。この際、担体の全量を一度に槽に投入すると、担体の多くが浮上したままとなり、殆ど流動しない。さらには、全面爆気により水面に浮く担体群の層と水面との間に気相の層が形成され、担体が水に接触しない状態になり、かつ担体表面が疎水性になっているため水に馴染むのに長時間を要するものと推定される。これは、担体はスポンジなど、嵩比重が1よりも小さい素材よりなるためである。そのため、従来は担体を少しずつ投入時期を異ならせて槽内に投入し、担体の浮上を抑制しながら曝気により流動させるようにしており、担体の全量投入に長時間を要していた。また、同様に担体の補充や入れ替えの時も上記と同様の問題があった。 When a fluidized bed type aerobic biological treatment tank is newly installed and the operation is started, a new fluidized bed carrier is introduced into the tank and aeration is started. At this time, if the entire amount of the carrier is put into the tank at a time, most of the carrier remains floating and hardly flows. Furthermore, a gas phase layer is formed between the surface of the carrier group that floats on the water surface due to the entire explosion and the water surface, so that the carrier is not in contact with water and the surface of the carrier is hydrophobic. It is estimated that it takes a long time to get used to. This is because the carrier is made of a material having a bulk specific gravity smaller than 1, such as a sponge. For this reason, conventionally, the carrier is gradually introduced into the tank at different timings, and the carrier is caused to flow by aeration while suppressing the floating of the carrier, so that it takes a long time to introduce the whole amount of the carrier. Similarly, when the carrier is replenished or replaced, there are the same problems as described above.
特開昭55-20649号公報JP-A-55-20649 特開2000-210692号公報JP 2000-210692 A 特公昭60-23832号公報Japanese Patent Publication No. 60-23832 特許第3410699号公報Japanese Patent No. 3410699
 本発明は、このような問題を解決し、運転開始時や担体の補充や入れ替えの時に担体を早期に流動させることができ、起動時間が短いものとなる生物処理槽、その運転方法及び有機性排水の処理方法を提供することを目的とする。 The present invention solves such a problem, and allows the carrier to flow quickly at the start of operation or at the time of replenishment or replacement of the carrier, the biological treatment tank having a short start-up time, its operating method, and organic property It aims at providing the processing method of waste water.
 本発明は、その一態様において、様々な原水水質や要求水質の変動、処理水量増大に容易に対応することができる有機性排水の処理装置を提供することを目的とする。 In one aspect of the present invention, an object of the present invention is to provide an organic wastewater treatment apparatus that can easily cope with various changes in raw water quality, required water quality, and increased amount of treated water.
 本発明の生物処理槽は、槽内の底部に散気管を備えた生物処理槽において、該散気管として、少なくとも、該生物処理槽の該底部の一半側に設けられた第1の散気管と、他半側に設けられた第2の散気管とを備えており、該第1の散気管にのみ気体を供給する第1の供給態様と、第1及び第2の散気管の双方に気体を供給する第2の供給態様とを切り替えるための気体供給切替手段を備えたことを特徴とする。 The biological treatment tank of the present invention is a biological treatment tank provided with an air diffuser at the bottom of the tank, and as the air diffuser, at least a first air diffuser provided on one half side of the bottom of the biological treatment tank And a second air diffuser provided on the other half side, the first supply mode for supplying gas only to the first air diffuser, and the gas to both the first and second air diffusers It is characterized by comprising a gas supply switching means for switching between the second supply mode for supplying gas.
 本発明の生物処理槽の運転方法は、嵩比重が1よりも小さい流動床担体を収容した生物処理槽内の底部に設けた散気管から曝気して該担体を流動させる生物処理槽の運転方法において、該生物処理槽内の底部の一半側に設けた散気管から曝気を行って塔体内に上下方向の循環流を形成する工程と、全ての散気管から曝気を行う工程とを含むことを特徴とする。 The operation method of the biological treatment tank of the present invention is an operation method of the biological treatment tank in which the carrier is caused to flow by aeration from an air diffuser provided at the bottom of the biological treatment tank containing a fluidized bed carrier having a bulk specific gravity smaller than 1. The step of performing aeration from an air diffuser provided on one half of the bottom of the biological treatment tank to form a vertical circulation flow in the tower, and the step of performing air from all the air diffusers. Features.
 本発明の一態様では、塔体内に担体を投入した場合、該生物処理槽内の底部の一半側に設けた散気管から曝気を行って塔体内に上下方向の循環流を形成する。 In one aspect of the present invention, when a carrier is introduced into the tower, aeration is performed from an air diffuser provided on one half of the bottom of the biological treatment tank to form a vertical circulation flow in the tower.
 本発明では、塔体内に散水してもよい。消泡剤含有水を散水してもよい。 In the present invention, water may be sprayed into the tower. You may sprinkle defoamer containing water.
 本発明では、前記生物処理槽の槽体は、高さ(H)と直径(D)との比(H/D)が1.5~5.0の筒形の塔体よりなることが好ましい。 In the present invention, the biological treatment tank is preferably a cylindrical tower having a ratio (H / D) of height (H) to diameter (D) of 1.5 to 5.0. .
 本発明の有機性排水の生物処理方法は、有機性排水を1段または多段に設けられた生物処理槽で生物処理する方法において、少なくとも1つの生物処理槽をかかる本発明の運転方法によって起動させることを特徴とする。 The organic wastewater biological treatment method of the present invention is a method of biologically treating organic wastewater in a biological treatment tank provided in one or more stages, and at least one biological treatment tank is activated by the operation method of the present invention. It is characterized by that.
 本発明では、第一段の生物処理槽において、分散菌による有機物の分解により分散菌の増加した第一生物処理水を生成させ、後段の第二生物処理槽において、第二生物処理水を生成させることが好ましい。また、第一生物処理槽及び第二生物処理槽は同一形状及び同一大きさの塔体を有しており、塔体の高さが6~11mであることが好ましい。 In the present invention, in the first-stage biological treatment tank, the first biological treatment water in which the dispersal bacteria are increased is generated by the decomposition of the organic matter by the dispersal bacteria, and the second biological treatment water is produced in the second-stage biological treatment tank. It is preferable to make it. The first biological treatment tank and the second biological treatment tank have towers of the same shape and size, and the height of the towers is preferably 6 to 11 m.
 本発明では、第一生物処理槽及び第二生物処理槽を並列に複数設置してもよい。 In the present invention, a plurality of first biological treatment tanks and second biological treatment tanks may be installed in parallel.
 本発明の生物処理槽及びその運転方法では、生物処理槽への流動床担体投入時に生物処理槽内の底部の一半側に設けられた散気管から曝気を行って生物処理槽内に上下方向の循環流を形成するので、嵩比重が1よりも小さい流動床担体であっても、速やかに水中に没して流動するようになる。このため、生物処理槽の起動を早期化することができる。 In the biological treatment tank and the operation method thereof according to the present invention, when the fluidized bed carrier is put into the biological treatment tank, aeration is performed from the air diffuser provided on the half of the bottom of the biological treatment tank, and the biological treatment tank is vertically moved. Since a circulating flow is formed, even a fluidized bed carrier having a bulk specific gravity smaller than 1 is quickly immersed in water and flows. For this reason, starting of a biological treatment tank can be accelerated.
 この起動時に生物処理槽内に散水を行うことにより、流動床担体をより早く水没させて流動させることができる。この場合、消泡剤含有水を散水することにより、担体の濡れ性が向上すると共に、曝気気泡が担体に絡みついて担体が浮上することを防止することができる。 ¡By spraying water into the biological treatment tank at the time of activation, the fluidized bed carrier can be submerged and fluidized faster. In this case, by sprinkling the antifoaming agent-containing water, the wettability of the carrier is improved, and aeration bubbles can be prevented from being entangled with the carrier and rising of the carrier.
 整流板やドラフトチューブ等の整流部材を内設すると、片面曝気の際にはエアリフト作用でよく混合されるが、全面曝気する際に混合の邪魔になるので、整流部材を生物処理槽内に設置しない構造とすることが好ましい。 If a baffle such as a baffle plate or draft tube is installed inside, it will be mixed well by air lift action during single-sided aeration, but it will interfere with mixing when the whole surface is aerated, so the baffle will be installed in the biological treatment tank. It is preferable to have a structure that does not.
 本発明方法は、生物処理槽の比高(H/D)の大きい場合に適用するのに好適である。 The method of the present invention is suitable for application when the specific height (H / D) of the biological treatment tank is large.
 本発明の一態様で用いる有機性排水の処理装置は、規格寸法(同一形状、同一大きさ)の塔体を有する水処理ユニットを複数個備えたものであり、各水処理ユニットは予め工場にて製作しておくことができる。また、各槽のサイズが統一されているので、装置の設計・施工も共通化され、簡易・迅速に行うことができる。槽同士の間のスペースを小さくすることもできる。生物処理槽の増設も容易である。 The organic wastewater treatment apparatus used in one aspect of the present invention includes a plurality of water treatment units having towers of standard dimensions (same shape, same size), and each water treatment unit is in advance in a factory. Can be produced. In addition, since the size of each tank is unified, the design and construction of the apparatus are made common and can be performed easily and quickly. The space between the tanks can also be reduced. It is easy to add biological treatment tanks.
 本発明の一態様では、生物処理槽を多段に設け、前段の生物処理槽を、有機物を分散菌に変換する分散菌槽とし、最後段の生物処理槽に、分散菌を捕食する固着性の濾過捕食型微小動物の足場として担体を設ける。この処理においては、微小動物を安定して維持し、処理水質を安定化させることができる。 In one embodiment of the present invention, biological treatment tanks are provided in multiple stages, the biological treatment tank in the previous stage is a dispersion bacteria tank that converts organic matter into dispersal bacteria, and the last biological treatment tank has an adhesive property that prey on the dispersal bacteria. A carrier is provided as a scaffold for filtered predatory microanimals. In this treatment, the micro-animal can be stably maintained, and the treated water quality can be stabilized.
図1は実施の形態に係る有機性排水の処理装置の縦断面図である。FIG. 1 is a longitudinal sectional view of an organic wastewater treatment apparatus according to an embodiment. 図2a~2hは本発明の有機性排水の処理装置における水処理ユニット配置例を示す平面図である。2a to 2h are plan views showing examples of arrangement of water treatment units in the organic wastewater treatment apparatus of the present invention. 図3は生物処理槽内の水循環説明図である。FIG. 3 is an explanatory view of water circulation in the biological treatment tank.
 以下に図面を参照して本発明の有機性排水の生物処理装置の実施の形態を詳細に説明する。図1は本発明の有機性排水の生物処理装置の実施の形態を示すものであり、第一生物処理槽1と、第二生物処理槽2とが基礎3上に立設され、配管4によって直列に接続されている。 Embodiments of the organic wastewater biological treatment apparatus of the present invention will be described in detail below with reference to the drawings. FIG. 1 shows an embodiment of a biological treatment apparatus for organic wastewater according to the present invention. A first biological treatment tank 1 and a second biological treatment tank 2 are erected on a foundation 3 and are connected by a pipe 4. Connected in series.
 第一生物処理槽1は、円筒形の塔体10と、該塔体10の下部側面に設けられたフランジ構造の原水流入口11aと、該原水流入口11aに連なり、塔体10内を上方に延在し、上端部が水面位よりも上位にて開放した原水導入管11と、塔体10内の底部に設けられた散気管12a,12bと、該塔体10内の下部に設けられたスクリーンボックス13と、下端が該スクリーンボックス13に連なり、上端が水面位よりも上位にて開放した立上管14と、該立上管14の上端近傍の側面から分岐し、塔体10内を立ち下り、塔体10の下部において塔体10外に引き出された流出配管15と、塔体10の上部に設けられた散水器16等を備えている。 The first biological treatment tank 1 is connected to the cylindrical tower 10, the raw water inlet 11 a having a flange structure provided on the lower side surface of the tower 10, and the raw water inlet 11 a, The raw water introduction pipe 11 whose upper end is open above the water surface level, the diffuser pipes 12a and 12b provided at the bottom of the tower body 10, and the lower part of the tower body 10 are provided. A screen box 13, a lower end connected to the screen box 13, a riser pipe 14 whose upper end is opened higher than the water surface level, and a side wall near the upper end of the riser pipe 14. And an outflow pipe 15 drawn out of the tower body 10 at the lower part of the tower body 10, a water sprinkler 16 provided at the upper part of the tower body 10, and the like.
 流出配管15の上端部15aのレベルが塔体10内の水面位となる。流出配管15の末端15bに前記配管4が接続されている。 The level of the upper end 15a of the outflow pipe 15 is the water level in the tower body 10. The pipe 4 is connected to the end 15 b of the outflow pipe 15.
 塔体10内には流動床担体Cが充填されている。スクリーンボックス13は、塔体10内の中央側を指向した前面がウェッジワイヤ等よりなるスクリーン面となっている。担体Cはこのスクリーン面を不通過となっている。 The tower body 10 is filled with a fluidized bed carrier C. In the screen box 13, the front surface directed toward the center side in the tower body 10 is a screen surface made of a wedge wire or the like. The carrier C does not pass through the screen surface.
 散気管12aは、塔体10の底面の一半側に配置され、散気管12bは該底面の他半側に配置されている。散気管12aを配置した前記一半側と散気管12bを配置した前記他半側との中間を境界として塔体10の底面を二分した場合、該一半側領域の面積は塔体10の底面の面積の15~50%好ましくは20~45%となるように構成されている。 The diffuser tube 12a is disposed on one half side of the bottom surface of the tower body 10, and the diffuser tube 12b is disposed on the other half side of the bottom surface. When the bottom surface of the tower body 10 is divided into two with the middle of the one half side where the diffuser tube 12a is arranged and the other half side where the air diffuser tube 12b is arranged as a boundary, the area of the half side region is the area of the bottom surface of the tower body 10 15 to 50%, preferably 20 to 45%.
 塔体10の頂部に開口17が設けられ、大気連通管17の一端が接続されている。大気連通管17は、塔体10内を通って下方に延設され、下端が基礎3の直近において塔体10外に引き出され、大気に向って開放している。 An opening 17 is provided at the top of the tower body 10, and one end of the atmosphere communication pipe 17 is connected thereto. The atmosphere communication pipe 17 extends downward through the tower body 10, and the lower end is drawn out of the tower body 10 in the immediate vicinity of the foundation 3 and is open toward the atmosphere.
 図示は省略するが、塔体10の頂部には開閉可能な予備座が設けられ、下部にはマンホール及び予備座が設けられている。 Although not shown in the drawings, a reserve seat that can be opened and closed is provided at the top of the tower body 10, and a manhole and a reserve seat are provided at the bottom.
 第二生物処理槽2は、塔体10と同一形状、同一大きさの円筒形の塔体20と、該塔体20の下部側面に設けられたフランジ構造の流入口21と、塔体20内の底部に設けられた散気管22a,22bと、該塔体20内の上下方向中間よりも若干下位に設置されたストレーナ23と、下端が該ストレーナ23に連なり、上端が水面位よりも上位にて開放した立上管24と、該立上管24の上端近傍の側面から分岐し、塔体20内を立ち下り、塔体20の下部において塔体20外に引き出された流出配管25と、塔体20の上部に設けられた散水器26等を備えている。 The second biological treatment tank 2 includes a cylindrical tower body 20 having the same shape and size as the tower body 10, a flanged structure inlet 21 provided on the lower side surface of the tower body 20, and the inside of the tower body 20. Diffuser pipes 22a and 22b provided at the bottom of the column, a strainer 23 installed slightly below the middle in the vertical direction in the tower body 20, a lower end connected to the strainer 23, and an upper end higher than the water level. A riser pipe 24 that is opened and a branch pipe 25 that branches off from the side surface near the upper end of the riser pipe 24, falls inside the tower body 20, and is drawn out of the tower body 20 at the lower part of the tower body 20; The water sprinkler 26 provided in the upper part of the tower body 20 is provided.
 流出配管25の上端部25aのレベルが塔体20内の水面位となる。 The level of the upper end portion 25a of the outflow pipe 25 is the water level in the tower body 20.
 塔体20内には流動床担体Cが充填されている。担体Cはストレーナ23を不通過となっている。 The tower body 20 is filled with a fluidized bed carrier C. The carrier C does not pass through the strainer 23.
 散気管22aは、塔体20の底面の一半側に配置され、散気管22bは該底面の他半側に配置されている。散気管22aを配置した前記一半側と散気管22bを配置した前記他半側との中間を境界として塔体20の底面を二分した場合、該一半側領域の面積は塔体20の底面の面積の15~50%好ましくは20~45%となるように構成されている。 The diffuser tube 22a is arranged on one half side of the bottom surface of the tower body 20, and the diffuser tube 22b is arranged on the other half side of the bottom surface. When the bottom surface of the tower body 20 is divided into two with the middle of the one half side where the diffuser tube 22a is arranged and the other half side where the diffuser tube 22b is arranged as a boundary, the area of the half side region is the area of the bottom surface of the tower body 20 15 to 50%, preferably 20 to 45%.
 散気管12a,12b,22a,22bは、それぞれバルブ(図示略)を介して図示しないブロワに接続されている。各バルブを操作することにより、散気管12a,22aのみへの空気供給態様(第1の供給態様)と、散気管12a,12bの双方、散気管22a,22bの双方への空気供給態様(第2の供給態様)とを切り替えることができる。つまり、散気管12aのバルブを開、散気管12bのバルブを閉とすることにより、散気管12aのみへ空気を供給して片面爆気することができ、散気管12a,12bのバルブを共に開とすることにより、散気管12a,12bへ空気を供給して全面爆気することができる。ブロワとしては、水位が高い場合には、スクリューブロワ、ターボブロワ等の吐出圧力60kPa以上の能力を備える高圧ブロワが好ましい。 The diffuser tubes 12a, 12b, 22a, and 22b are connected to blowers (not shown) through valves (not shown). By operating each valve, the air supply mode (first supply mode) only to the diffuser tubes 12a and 22a, the air supply mode (first supply mode) to both the diffuser tubes 12a and 12b, and the diffuser tubes 22a and 22b (first) 2 supply modes). That is, by opening the valve of the air diffuser 12a and closing the valve of the air diffuser 12b, air can be supplied to only the air diffuser 12a and one-sided explosion can be performed, and both the valves of the air diffusers 12a and 12b are opened. By doing so, it is possible to supply the air to the diffuser tubes 12a and 12b and to blast the entire surface. As the blower, when the water level is high, a high-pressure blower having a capability of a discharge pressure of 60 kPa or more such as a screw blower or a turbo blower is preferable.
 塔体20の頂部に開口27aが設けられ、大気連通管27の一端が接続されている。大気連通管27は、塔体20内を下方に延設され、下端27eは基礎3の直近において塔体20外に引き出され、大気に向って開放している。 An opening 27a is provided at the top of the tower body 20, and one end of the atmosphere communication pipe 27 is connected thereto. The atmosphere communication pipe 27 extends downward in the tower body 20, and the lower end 27 e is drawn out of the tower body 20 in the immediate vicinity of the foundation 3 and is opened toward the atmosphere.
 塔体20の頂部には開閉可能な予備座が設けられ、下部にはマンホール及び予備座が設けられている。 The top of the tower body 20 is provided with an openable / closable spare seat, and the lower portion is provided with a manhole and a spare seat.
 各塔体10,20は、ライニングを不要とするためFRP等の樹脂製が好ましいが、水質によっては鋼板であってもよい。FRPの場合には紫外線による劣化の防止、耐食性の向上を目的として耐候性塗料を塗布するのが好ましい。 The tower bodies 10 and 20 are preferably made of resin such as FRP in order to eliminate the need for lining, but may be steel plates depending on the water quality. In the case of FRP, it is preferable to apply a weather-resistant paint for the purpose of preventing deterioration due to ultraviolet rays and improving corrosion resistance.
 第一及び第二生物処理槽1,2には余剰汚泥の取出管、ドレン管、配線挿通口、サンプリング口(図示略)等が設けられている。槽内の監視は、カメラ又は動画撮影機能を備えた撮影機材(望ましくは照明付きもしくは赤外線カメラ)で行う。撮影データは無線又は有線にて送信する。撮影機材に撮影データを保管してもよい。塔体に予め保温材を巻いておいてもよい。 The first and second biological treatment tanks 1 and 2 are provided with an excess sludge extraction pipe, a drain pipe, a wiring insertion port, a sampling port (not shown), and the like. The inside of the tank is monitored with a camera or a photographing device (preferably with illumination or an infrared camera) having a moving image photographing function. Shooting data is transmitted wirelessly or by wire. The photographing data may be stored in the photographing equipment. A heat insulating material may be wound around the tower in advance.
 必要に応じ、水槽或いは周辺設備、配管等に、水位計、圧力計、流量計、水温計、水質計等の測定器を設置し、運転状況の監視や運転制御、運用管理等に用いる。また、付帯設備(例えば、送水、加温、薬品注入、曝気、脱水機能等を備えた設備)との組合せにより、水槽における処理を最適化するために利用する。 If necessary, install water level gauges, pressure gauges, flow meters, water temperature gauges, water quality gauges, and other measuring instruments in water tanks or peripheral equipment, piping, etc., and use them for monitoring operating conditions, operational control, operational management, etc. In addition, it is used for optimizing the treatment in the water tank in combination with incidental facilities (for example, facilities equipped with water supply, heating, chemical injection, aeration, dehydration functions, etc.).
<通常運転時>
 この有機性排水の処理装置によって有機性排水を処理するには、導入管11を介して原水(有機性排水)を第一生物処理槽1に導入し、散気管12a,12bで曝気し、分散性細菌(非凝集性細菌)により、有機成分(溶解性BOD)の70%以上、望ましくは80%以上、さらに望ましくは85%以上を酸化分解する。この第一生物処理槽1のpHは好ましくは6~8.5とする。ただし、食品製造排水など原水中に油分を多く含む場合や、半導体製造排水や液晶製造排水など原水中に有機性の溶媒や洗浄剤を多く含む場合には分解速度を高くするため、pHは8~9としても良い。
<During normal operation>
In order to treat organic wastewater with this organic wastewater treatment device, raw water (organic wastewater) is introduced into the first biological treatment tank 1 through the introduction pipe 11, and aerated and diffused by the diffuser pipes 12a and 12b. 70% or more, desirably 80% or more, more desirably 85% or more of the organic component (soluble BOD) is oxidatively decomposed by a sex bacterium (non-aggregating bacterium). The pH of the first biological treatment tank 1 is preferably 6 to 8.5. However, when the raw water such as food manufacturing wastewater contains a lot of oil, or when the raw water such as semiconductor manufacturing wastewater or liquid crystal manufacturing wastewater contains a lot of organic solvent or cleaning agent, the pH is 8 It can be ~ 9.
 第一生物処理槽1への通水は、一過式とする。第一生物処理槽1のBOD容積負荷を1kg/m/d以上、例えば1~20kg/m/d、HRT(原水滞留時間)を24h以下、好ましくは8h以下、例えば0.5~8hとすることにより、分散性細菌が優占化した処理水を得ることができ、また、HRTを短くすることでBOD濃度の低い排水を高負荷で処理することができる。 The water flow to the 1st biological treatment tank 1 shall be a transient type. The BOD volumetric load of the first biological treatment tank 1 is 1 kg / m 3 / d or more, for example 1 to 20 kg / m 3 / d, HRT (raw water residence time) is 24 h or less, preferably 8 h or less, for example 0.5 to 8 h By doing so, it is possible to obtain treated water predominated by dispersible bacteria, and by shortening the HRT, wastewater having a low BOD concentration can be treated with a high load.
 第一生物処理槽1には、後段の生物処理槽からの汚泥の一部を返送したり、この第一生物処理槽1を二槽以上の多段構成とすることにより、BOD容積負荷5kg/m/d以上の高負荷処理も可能となる。 By returning a part of the sludge from the subsequent biological treatment tank to the first biological treatment tank 1 or by configuring the first biological treatment tank 1 in a multistage configuration of two or more tanks, a BOD volumetric load of 5 kg / m High load processing of 3 / d or more is also possible.
 第一生物処理槽1における担体の充填率が高い場合、分散菌は生成せず、細菌は担体に付着するか、糸状性細菌が増殖する。そこで、第一生物処理槽1に添加する担体の充填率を、流動床担体の場合は10%以下、例えば1~10%とすることで、濃度変動に影響されず、捕食しやすい分散菌の生成が可能になる。 When the filling rate of the carrier in the first biological treatment tank 1 is high, dispersal bacteria are not generated, and bacteria adhere to the carrier or filamentous bacteria grow. Therefore, by setting the filling rate of the carrier added to the first biological treatment tank 1 to 10% or less, for example, 1 to 10% in the case of a fluidized bed carrier, the dispersal bacteria that are easy to prey without being affected by the concentration fluctuation. Generation is possible.
 第一生物処理槽1の溶存酸素(DO)濃度を1mg/L以下、好ましくは0.5mg/L以下として、糸状性細菌の増殖を抑制しても良い。 The dissolved oxygen (DO) concentration in the first biological treatment tank 1 may be 1 mg / L or less, preferably 0.5 mg / L or less to suppress the growth of filamentous bacteria.
 第一生物処理槽1の処理水(第一生物処理水)を、配管14,15,4、流入口21を介して後段の第二生物処理槽2に導入し、曝気し、残存している有機成分の酸化分解、分散性細菌の自己分解及び微小動物の捕食による余剰汚泥の減量化を行う。 The treated water (first biological treated water) of the first biological treatment tank 1 is introduced into the second biological treatment tank 2 in the subsequent stage via the pipes 14, 15, 4 and the inlet 21, aerated, and remains. Reduce excess sludge by oxidative degradation of organic components, self-degradation of dispersible bacteria, and predation of micro-animals.
 第二生物処理槽2では、細菌に比べ増殖速度の遅い微小動物の働きと細菌の自己分解を利用するため、微小動物と細菌が系内に留まるような運転条件及び処理装置を用いる必要がある。そこで、この実施の形態では、第二生物処理槽2には、流動床担体Cを充填して微小動物の槽内保持量を高めている。 In the second biological treatment tank 2, it is necessary to use an operation condition and a treatment apparatus that allow the microanimal and the bacteria to remain in the system in order to use the action of the microanimal having a slower growth rate than the bacteria and the autolysis of the bacteria. . Therefore, in this embodiment, the second biological treatment tank 2 is filled with the fluidized bed carrier C to increase the amount of micro-animal retained in the tank.
 流動床担体Cの形状は、球状、ペレット状、中空筒状、糸状、板状等の任意であり、大きさ(径)は0.1~10mm程度である。担体Cの材料は、天然素材、無機素材、高分子素材等任意であり、ゲル状物質を用いても良い。担体Cは、乾燥状態において嵩比重が1よりも小さいものであり、具体的にはスポンジ担体が好適である。 The shape of the fluidized bed carrier C is arbitrary such as a spherical shape, a pellet shape, a hollow cylindrical shape, a thread shape, and a plate shape, and the size (diameter) is about 0.1 to 10 mm. The material of the carrier C is arbitrary such as a natural material, an inorganic material, or a polymer material, and a gel material may be used. The carrier C has a bulk specific gravity of less than 1 in a dry state, and specifically, a sponge carrier is suitable.
 第二生物処理槽2には、流動床担体のほかにさらに揺動床担体を充填してもよい。 The second biological treatment tank 2 may be further filled with a rocking bed carrier in addition to the fluidized bed carrier.
 第二生物処理槽2では、微小動物を維持するための多量の足場が必要となるが、過度に担体の充填率が多いと槽内の混合不足、汚泥の腐敗などが起こるため、添加する担体の充填率は、0.5~30%、特に1~10%程度とすることが望ましい。 In the second biological treatment tank 2, a large amount of scaffolding for maintaining micro-animals is required. However, if the filling rate of the carrier is excessively high, mixing in the tank, sludge decay, etc. may occur. The filling rate is preferably about 0.5 to 30%, particularly about 1 to 10%.
 微小動物による捕食を促進させるため、第二生物処理槽2のpHを7.0以下としても良い。 In order to promote predation by minute animals, the pH of the second biological treatment tank 2 may be 7.0 or less.
 第二生物処理槽2では、分散状態の菌体を捕食する濾過捕食型微小動物だけでなく、フロック化した汚泥を捕食できる凝集体捕食型微小動物も増殖する。後者は遊泳しながらフロックを捕食するため、優先化した場合、汚泥は食い荒らされ、微細化したフロック片が散在する汚泥(沈降性の悪い汚泥)となる。このフロック片により、特に後段で膜分離を行う膜式活性汚泥法では膜の目詰まりが発生する。そこで、凝集体捕食型微小動物を間引くため、SRTを60日以下望ましくは45日以下の範囲内で一定に制御することが望ましい。ただし15日未満では不必要に頻繁すぎて凝集体捕食型微小動物だけでなく濾過捕食型微小動物の数が減少しすぎるので15日以上とするのが好ましい。 In the second biological treatment tank 2, not only the filtration predation type micro-animal that prey on the dispersed cells but also the aggregate predation type micro-animal that can prey on the floc sludge grows. Since the latter prey on flocs while swimming, if priority is given, sludge is eaten and becomes sludge in which fine floc pieces are scattered (sludge with poor sedimentation). This floc piece causes clogging of the membrane particularly in the membrane activated sludge method in which membrane separation is performed at a later stage. Therefore, in order to thin out the aggregate predatory microanimals, it is desirable to control the SRT to be constant within a range of 60 days or less, preferably 45 days or less. However, if it is less than 15 days, it is unnecessarily frequent, and the number of not only aggregate predation type micro-animals but also filtration predation type micro-animals is excessively reduced.
 第一生物処理槽1では有機物の大部分、すなわち排水BODの70%以上、望ましくは80%以上を分解し、菌体へと変換しておく必要があるが、第一生物処理槽1で溶解性有機物を完全に分解した場合、第二生物処理槽2ではフロックが形成されず、また、微小動物増殖のための栄養も不足し、圧密性の低い汚泥(沈降性の悪い汚泥)のみが優占化した生物処理槽となる。そこで、原水の一部をバイパスして第二生物処理槽2に供給し、第二生物処理槽2への溶解性BODによる汚泥負荷が0.025kg-BOD/kg-MLSS/d以上となるように運転してもよい。この時のMLSSには担体付着分のMLSSも含む。 In the first biological treatment tank 1, it is necessary to decompose most of the organic matter, that is, 70% or more of the wastewater BOD, desirably 80% or more, and convert it into microbial cells. When the organic substances are completely decomposed, flocs are not formed in the second biological treatment tank 2, and there is not enough nutrients for the growth of micro-animals. Only sludge with poor compaction (sludge with poor sedimentation) is excellent. It becomes an occupied biological treatment tank. Therefore, a part of the raw water is bypassed and supplied to the second biological treatment tank 2 so that the sludge load due to the soluble BOD in the second biological treatment tank 2 is 0.025 kg-BOD / kg-MLSS / d or more. You may drive. The MLSS at this time includes MLSS for the carrier adhering.
 第二生物処理槽2からストレーナ23及び配管24,25を介して取り出される処理水に対して、より高度な処理水水質を得るために固液分離として膜分離、凝集沈殿、加圧浮上のいずれを行ってもよい。凝集沈殿や加圧浮上を行うときは、凝集剤の添加量の低減することができる。第二生物処理槽2からの沈降分離水を凝集槽で凝集処理し、次いで固液分離槽(沈殿槽)で沈殿処理して処理水と沈降汚泥とに分離してもよい。 For the treated water taken out from the second biological treatment tank 2 through the strainer 23 and the pipes 24, 25, any of solid separation and membrane separation, coagulation sedimentation, and pressurized flotation to obtain a higher quality of treated water May be performed. When performing coagulation sedimentation or pressure levitation, the amount of coagulant added can be reduced. The sedimentation water from the second biological treatment tank 2 may be agglomerated in a coagulation tank, and then precipitated in a solid-liquid separation tank (sedimentation tank) to separate into treated water and sedimented sludge.
 第一、第二生物処理槽1,2において、曝気に伴って発泡が生じたときには、散水器16,26から消泡剤水溶液を散水して発泡を防止することが好ましい。 In the first and second biological treatment tanks 1 and 2, when foaming occurs due to aeration, it is preferable to spray the defoamer aqueous solution from the sprinklers 16 and 26 to prevent foaming.
 図1は、本発明の実施の形態の一例を示すものであり、本発明は何ら図示のものに限定されない。例えば、第一生物処理槽1、第二生物処理槽2の後段に第三生物処理槽を設けるなどして、生物処理槽を3段以上に設けてもよい。逆に、生物処理を例えば流動床担体による1段処理のみにすることも可能である。 FIG. 1 shows an example of an embodiment of the present invention, and the present invention is not limited to the illustrated one. For example, the biological treatment tank may be provided in three or more stages by providing a third biological treatment tank after the first biological treatment tank 1 and the second biological treatment tank 2. Conversely, the biological treatment can be only a one-stage treatment using a fluidized bed carrier, for example.
 図2a~2hは、第一生物処理槽1、第二生物処理槽2の種々の配置パターンを示す平面図である。図2aは、第一生物処理槽1、第二生物処理槽2を1基ずつ設置して直列に接続したものである。図2bは、第一生物処理槽1を1基設置し、第二生物処理槽2を並列に複数基設置したものである。図2cは、第一生物処理槽1を並列に複数基設置し、第二生物処理槽2を1基設置したものである。図2dは、第一生物処理槽1及び第二生物処理槽2の直列接続体を並列に複数列設置したものである。 FIGS. 2 a to 2 h are plan views showing various arrangement patterns of the first biological treatment tank 1 and the second biological treatment tank 2. FIG. 2a shows a first biological treatment tank 1 and a second biological treatment tank 2 installed one by one and connected in series. FIG. 2b shows one first biological treatment tank 1 installed and a plurality of second biological treatment tanks 2 arranged in parallel. FIG. 2c shows a plurality of first biological treatment tanks 1 installed in parallel and one second biological treatment tank 2 installed. FIG. 2d shows a series connection of the first biological treatment tank 1 and the second biological treatment tank 2 arranged in parallel.
 図2e、図2fは、第一生物処理槽1を並列に複数基設置し、第二生物処理槽2を並列に複数基設置したものであり、図2eでは第一生物処理槽1の数が第二生物処理槽2よりも多く、図2fでは第二生物処理槽2の数が第一生物処理槽1よりも多い。図示は省略するが、第一生物処理槽1と第二生物処理槽2の数が同数でもよい。 2e and 2f show a plurality of first biological treatment tanks 1 installed in parallel and a plurality of second biological treatment tanks 2 installed in parallel. In FIG. 2e, the number of first biological treatment tanks 1 is the same. More than the second biological treatment tank 2, and the number of the second biological treatment tank 2 is larger than that of the first biological treatment tank 1 in FIG. Although illustration is omitted, the first biological treatment tank 1 and the second biological treatment tank 2 may be the same number.
 図2gは、第二生物処理槽2,2’を直列に複数基設置したものである。図2hは、図2gのものを並列に複数設置したものである。 FIG. 2g shows a plurality of second biological treatment tanks 2 and 2 'installed in series. FIG. 2h shows a plurality of FIG. 2g installed in parallel.
 第一生物処理槽又は第二生物処理槽を並列に設置した場合には、一部の第一生物処理槽又は第二生物処理槽で運転を停止してメンテナンスしながら残りの第一生物処理槽、第二生物処理槽を用いて有機性排水の処理装置の運転を継続させることもできる。 When the first biological treatment tank or the second biological treatment tank is installed in parallel, the remaining first biological treatment tanks are maintained while being stopped and maintained in some of the first biological treatment tanks or the second biological treatment tanks. The operation of the organic wastewater treatment apparatus can be continued using the second biological treatment tank.
 図2a~2hの通り、本発明によると、第一生物処理槽1と第二生物処理槽2を種々のパターンにて設置することができ、現場での原水の水量や水質に応じて所望の配列とすることができる。また、既存の本発明構造の有機性排水の処理装置に対して第一生物処理槽及び第二生物処理槽の少なくとも一方を並列又は直列に追加設置して原水流量の増大や水質変動に対応することができる。 As shown in FIGS. 2a to 2h, according to the present invention, the first biological treatment tank 1 and the second biological treatment tank 2 can be installed in various patterns, depending on the amount and quality of raw water at the site. It can be an array. In addition, at least one of the first biological treatment tank and the second biological treatment tank is additionally installed in parallel or in series with the existing organic wastewater treatment apparatus of the present invention structure to cope with an increase in raw water flow rate and water quality fluctuation. be able to.
 この実施の形態では、塔体10,20が同一形状、同一大きさであるため、各塔体10,20を多数設置する場合でも各塔体を近接して設置し、塔体間のスペースを小さくし、有機性排水処理装置全体の設置スペースを小さくすることができる。また、塔体10,20の製造コストも安価となる。複数の塔体を並列に設置する場合、各塔体の構成が同一であるから、塔体の据付作業や各塔体の配管接続作業が同じとなり、作業効率が向上し、工期の短縮を図ることができる。 In this embodiment, since the tower bodies 10 and 20 have the same shape and the same size, even when many tower bodies 10 and 20 are installed, the tower bodies are installed close to each other, and the space between the tower bodies is increased. It is possible to reduce the installation space of the entire organic wastewater treatment apparatus. Moreover, the manufacturing cost of the tower bodies 10 and 20 is also low. When installing multiple towers in parallel, the structure of each tower is the same, so the installation work of the towers and the pipe connection work of each tower are the same, improving work efficiency and shortening the construction period. be able to.
 各塔体10,20は、直径が2.2~3.6m、特に2.4~3.3mであり、高さが6~11m、特に8~11mであり、高さHと直径Dとの比H/Dが1.5~5.0特に3.0~4.5であることが好ましい。また、主要な配管の接続部やマンホール、ストレーナ23、散気管12a,12b,22a,22bなどは、基礎3からの高さが4m以下、特に3.0m以下であることが好ましい。このように配管接続部、マンホール、ストレーナ23、散気管12a,12b,22a,22bなどを低位置に設けることにより、配管接続作業や機器設置作業、各種メンテナンス作業が高所作業ではなくなり、作業効率及び安全性が向上する。 Each of the towers 10 and 20 has a diameter of 2.2 to 3.6 m, particularly 2.4 to 3.3 m, a height of 6 to 11 m, particularly 8 to 11 m, and a height H and a diameter D. The ratio H / D is preferably 1.5 to 5.0, more preferably 3.0 to 4.5. Moreover, it is preferable that the height from the foundation 3 is 4 m or less, particularly 3.0 m or less, for the main pipe connection part, the manhole, the strainer 23, the diffuser pipes 12a, 12b, 22a, 22b and the like. By providing the pipe connection portion, manhole, strainer 23, diffuser pipes 12a, 12b, 22a, 22b and the like in this way, pipe connection work, equipment installation work, and various maintenance work are not high place work, and work efficiency is improved. And safety is improved.
 本発明では、第一生物処理槽1の前段に嫌気処理槽を設置し、嫌気処理槽の処理水を第一生物処理槽に導入するようにしてもよい。この嫌気処理槽の塔体の大きさも塔体10,20と同一としてもよい。 In the present invention, an anaerobic treatment tank may be installed in front of the first biological treatment tank 1 and the treated water of the anaerobic treatment tank may be introduced into the first biological treatment tank. The size of the tower body of the anaerobic treatment tank may be the same as that of the tower bodies 10 and 20.
 本発明では、嫌気又は好気処理槽の最前段に調整槽を設置してもよい。この調整槽としては、原水流量を平準化するための原水槽、固形物を沈降させるための沈降槽、加圧浮上装置などが例示されるが、これに限定されない。 In the present invention, an adjustment tank may be installed in the forefront of the anaerobic or aerobic treatment tank. Examples of the adjustment tank include, but are not limited to, a raw water tank for leveling the raw water flow rate, a settling tank for settling solid matter, and a pressurized flotation device.
 本発明では、各生物処理槽は、予め塔体に散気管などの付属機器を工場で取り付けておき、現場に移送し、基礎上に据え付けるように施工を行うのが好ましい。これにより、現場作業数を減少させ、工期の短縮や、組み立て精度の向上などを図ることができる。 In the present invention, it is preferable that each biological treatment tank is preliminarily attached to the tower with attached equipment such as a diffuser pipe at the factory, transferred to the site, and installed on the foundation. As a result, the number of work on site can be reduced, the construction period can be shortened, and the assembly accuracy can be improved.
<担体の投入及び運転開始時>
 次に、各生物処理槽1,2の運転を開始する際の流動床担体Cの投入方法を説明する。
<When loading the carrier and starting operation>
Next, a method for charging the fluidized bed carrier C when starting the operations of the biological treatment tanks 1 and 2 will be described.
 担体Cがスポンジ担体等である場合、塔体10又は20内に投入しても浮上したままであり、各散気管から一斉に曝気を行っても殆ど水没しない。 When the carrier C is a sponge carrier or the like, it remains floating even if it is put into the tower body 10 or 20, and is hardly submerged even if aeration is performed simultaneously from each air diffuser.
 そこで、この実施の形態では、担体を塔体10又は20内に投入した後、(又は投入に先立って、)散気管12a又は22aのみから曝気(片面曝気)を行う。散気管12a、22aは塔体10,20内の底部の一半側に偏って配置されているため、該散気管12a又は22aから曝気すると、気泡は主として塔体10又は20内の内周面のうち一半側の内周面に沿って上昇するので、塔体10又は20内には、該一半側に沿う上昇流が形成され、他半側では下降流が形成され、これにより塔体10又は20内に上下方向の循環流が形成される。塔体10又は20内に投入された担体Cは、この下降流によって水中に引き込まれ、水と親和し、塔体10,20内で流動するようになる。 Therefore, in this embodiment, after the carrier is introduced into the tower body 10 or 20, (or prior to the introduction), aeration (single-sided aeration) is performed only from the diffusion tube 12a or 22a. Since the diffuser pipes 12a and 22a are arranged to be biased to one half of the bottom of the tower bodies 10 and 20, when aeration is performed from the diffuser pipes 12a or 22a, bubbles are mainly formed on the inner peripheral surface of the tower body 10 or 20. Of these, since it rises along the inner peripheral surface on one half side, an upflow along the half side is formed in the tower body 10 or 20, and a downflow is formed on the other half side. A circulation flow in the vertical direction is formed in 20. The carrier C introduced into the tower body 10 or 20 is drawn into the water by this downward flow, and becomes compatible with water and flows in the tower bodies 10 and 20.
 この点について図3を参照してさらに詳細に説明する。 This point will be described in more detail with reference to FIG.
 嵩比重が1未満の流動床担体(まだ微生物は付着してないドライ時)を生物反応槽内に添加して運転を開始するとき、全面曝気では担体が浮いてしまう。恐らく担体表面は疎水性になっており、そのままでは表面に泡膜が形成されて浮く上に、担体の層と水面との間に散気による気相の層が形成されて担体が水に触れない状態になってしまう。そこで、片面曝気を行うことにより、槽内に大きな渦流を形成する。この渦流の下向流に引き込まれる形で流動床担体が槽内部まで混合される。槽の水深が深ければ図3のように縦方向に複数の渦流が形成される場合がある。本発明ではこれらの1つまたは複数の上下方向の渦流を総じて「上下方向の循環流」と称する。 When a fluidized bed carrier having a bulk specific gravity of less than 1 (when dry, to which no microorganisms have adhered yet) is added to the biological reaction tank and the operation is started, the carrier floats when the entire surface is aerated. Perhaps the surface of the carrier is hydrophobic, and if it is left as it is, a foam film is formed on the surface and floats, and a gas phase layer is formed by aeration between the carrier layer and the water surface, so that the carrier touches the water. It will not be in a state. Therefore, a large eddy current is formed in the tank by performing single-sided aeration. The fluidized bed carrier is mixed to the inside of the tank while being drawn into the downward flow of the vortex. If the water depth of the tank is deep, a plurality of vortex flows may be formed in the vertical direction as shown in FIG. In the present invention, one or more of these vertical vortex flows are collectively referred to as “vertical flow”.
 本発明では槽内に一時的に下向流を形成して担体を強制的に槽内に引き込むことにより担体が水に馴染みやすくなり、特に担体表面が疎水性であった場合も水に強制的に馴染みやすくし、また担体がスポンジ担体など多孔質担体の場合は担体内部に水が強制的に染み込みやすくなり担体内部のガスが水に置換されやすくなるものと推定される。なお多孔質担体は担体内部のガスが水に置換されて担体内に水分が蓄積することにより嵩比重(ウェット時)が大きくなり、沈降性が上がると考えられる。 In the present invention, by forming a downward flow temporarily in the tank and forcibly pulling the carrier into the tank, the carrier becomes easy to become familiar with water, especially when the carrier surface is hydrophobic. It is presumed that when the carrier is a porous carrier such as a sponge carrier, water is forcibly soaked into the carrier and the gas inside the carrier is easily replaced with water. In addition, it is considered that the porous carrier is increased in bulk specific gravity (when wet) due to substitution of water in the gas inside the carrier and accumulation of moisture in the carrier, thereby improving sedimentation.
 本発明の起動方法によると、担体全量をまとめて塔体10,20内に投入しても、担体が速やかに水中に分散し、流動を開始するようになる。片面曝気中に担体投入し、投入が完了した時点から、または担体投入した後に、片面曝気を開始した時点からの所定時間(例えば5分~4日)経過して担体が水中に流動するようになれば、すぐに、または低負荷でしばらく運転を継続した後に(例えば5分~10日)、すべての散気管12a,22aから曝気を行う全面爆気に移行する。 According to the start-up method of the present invention, even if the entire amount of the carrier is put into the towers 10 and 20, the carrier is quickly dispersed in water and starts to flow. The carrier is introduced during single-sided aeration, and the carrier flows into the water after a predetermined time (for example, 5 minutes to 4 days) from the time when the single-sided aeration is started after the introduction of the carrier or after the introduction of the carrier. Then, immediately or after continuing the operation for a while at a low load (for example, 5 minutes to 10 days), the whole blast gas is transferred from all the diffuser tubes 12a and 22a.
 運転停止時(通水停止、散気停止)には担体が沈降して互いに固着してしまう場合があり、この固着した担体が運転再開時に散気の気泡を多く取り込んで浮上して十分に混合できない恐れがあるが、本発明を転用して、運転再開時には一時的に片面曝気を行って固着した担体をほぐしながら混合して十分に混合された後に全面爆気に切り替えることで担体の浮上を防止しつつ十分に混合することができる。全面爆気を行っている場合などであっても、担体を新たに塔体10又は20に投入したときには、片面曝気を行い、その後全面爆気を再開するようにしてもよい。 When the operation is stopped (water flow stop, aeration stop), the carriers may settle and stick to each other. When this operation is resumed, many of the air bubbles are taken up and floated and mixed sufficiently. Although there is a possibility that it cannot be done, by diverting the present invention, when resuming operation, temporarily aeration on one side and mixing while loosely adhering the fixed carrier, mixing thoroughly and switching to full explosion after switching to full explosion Mix well while preventing. Even when a full-scale explosion is performed, when a carrier is newly put into the tower body 10 or 20, single-sided aeration may be performed, and then the full-scale explosion may be resumed.
 この起動時に、散水器16から水を散水し、担体に水を注ぎかけることにより担体の水没を促進することができる。すなわち、担体に散水することにより、表面が乾燥して疎水性の状態の担体を強制的に水に馴染ませることができる上に、担体に水が付着または浸透することで重みをつけることができる。この水は、原水であってもよく、処理水であってもよい。 At the time of this start-up, water can be sprinkled from the water sprinkler 16 and water can be poured onto the carrier to promote the submergence of the carrier. That is, by sprinkling water onto the carrier, the surface can be dried and the carrier in a hydrophobic state can be forcibly adapted to water, and weight can be applied by attaching or penetrating water to the carrier. . This water may be raw water or treated water.
 起動時に散水器16から消泡剤含有水を散水することにより、曝気気泡を粗大化させ、微細な気泡が担体に絡みついて担体が浮上することを防止する効果も得られる。消泡剤を添加することで、担体の濡れ性が改善されて水がより馴染みやすくなる。すなわち、担体内の気泡が会合して大きくなることで担体外に排出されて水が担体内に侵入しやすくなる。なお、消泡剤の組成は特に限定されず水中油型エマルションを含む消泡剤組成物を用いることができる。 By sprinkling the antifoaming agent-containing water from the water sprinkler 16 at the time of starting, the effect of coarsening the aerated bubbles and preventing the fine bubbles from being entangled with the carrier and floating the carrier is also obtained. By adding an antifoaming agent, the wettability of the carrier is improved and the water becomes more familiar. That is, when bubbles in the carrier are associated and become larger, the bubbles are discharged out of the carrier and water easily enters the carrier. In addition, the composition of an antifoamer is not specifically limited, The antifoamer composition containing an oil-in-water emulsion can be used.
 担体が流動を開始した後は、全ての散気管12a,12b、散気管22a,22bから散気する全面曝気に移行する。全面曝気時の散気量は好ましくは320~600Nm/hである。片面曝気は全面曝気と比べて散気量が少ない。例えば片面曝気による一半側領域の面積が塔底面積の50%の場合は、片面曝気の散気量は半分の160~300Nm/hとなる。 After the carrier starts to flow, the entire aeration is performed to diffuse from all the diffuser tubes 12a and 12b and the diffuser tubes 22a and 22b. The amount of air diffused during the entire surface aeration is preferably 320 to 600 Nm 3 / h. Single-sided aeration is less diffused than full-surface aeration. For example, when the area of the half-side area by single-sided aeration is 50% of the tower bottom area, the amount of diffused air from single-sided aeration is 160 to 300 Nm 3 / h, half.
[実施例1]
 内径2.5m、高さ10m、水面高さ9mの図1に示す構成の塔体10内に担体として3mm角、嵩比重0.04g/cmのスポンジ担体704kgを投入し、散気管12aから曝気量240Nm/hにて曝気したところ、10min以内にすべての担体が流動を開始した。散気管12aを配置した一半側の領域の面積は、塔体10の底面積の50%である。
[Example 1]
Into the tower 10 having the configuration shown in FIG. 1 having an inner diameter of 2.5 m, a height of 10 m, and a water surface height of 9 m, a 3 mm square sponge carrier 704 kg having a bulk specific gravity of 0.04 g / cm 3 is introduced. When aeration was performed at an aeration amount of 240 Nm 3 / h, all carriers started to flow within 10 min. The area of the region on the half side where the diffuser 12 a is arranged is 50% of the bottom area of the tower body 10.
[実施例2]
 実施例1において、さらに散水器16から消泡剤として高級アルコール系エマルション型消泡剤「クリレス653」(栗田工業製)を100L/minにて散水したところ、5min以内にすべての担体が流動を開始した。
[Example 2]
In Example 1, when a higher alcohol emulsion type antifoaming agent “Kurires 653” (manufactured by Kurita Kogyo Co., Ltd.) was sprinkled at 100 L / min from the water sprinkler 16 as an antifoaming agent, all the carriers flowed within 5 min. Started.
[比較例1]
 実施例1において、散気管12a,12bから合計曝気量240Nm/hにて曝気したところ、殆どの担体が水面より上に浮いてしまい7日経過しても流動しなかった。
[Comparative Example 1]
In Example 1, when aeration was performed from the diffuser tubes 12a and 12b at a total aeration amount of 240 Nm 3 / h, most of the carrier floated above the water surface and did not flow even after 7 days.
[比較例2]
 実施例2において、散気管12a,12bから合計曝気量240Nm/hにて曝気したところ、すべての担体が流動を開始するまでに7日を要した。
[Comparative Example 2]
In Example 2, when aeration was performed from the diffuser tubes 12a and 12b at a total aeration amount of 240 Nm 3 / h, it took 7 days for all the carriers to start flowing.
[比較例3]
 比較例1において、散気管12a,12bからの合計曝気量を480Nm/hとしたところ、殆どの担体が水面より上に浮いてしまい7日経過しても流動しなかった。
[Comparative Example 3]
In Comparative Example 1, when the total amount of aeration from the diffusing tubes 12a and 12b was 480 Nm 3 / h, most of the carrier floated above the water surface and did not flow even after 7 days.
[比較例4]
 比較例2において、散気管12a,12bからの合計曝気量を480Nm/hとしたところ、すべての担体が流動を開始するまでに5日を要した。
[Comparative Example 4]
In Comparative Example 2, when the total amount of aeration from the diffusing tubes 12a and 12b was 480 Nm 3 / h, it took 5 days for all the carriers to start flowing.
 以上の実施例及び比較例より、本発明によると、生物処理装置の担体投入時の起動を著しく早期化できることが認められた。 From the above Examples and Comparative Examples, it was confirmed that the start-up of the biological treatment apparatus when the carrier is loaded can be significantly accelerated according to the present invention.
 本発明を特定の態様を用いて詳細に説明したが、本発明の意図と範囲を離れることなく様々な変更が可能であることは当業者に明らかである。
 本出願は、2015年2月16日付で出願された日本特許出願2015-027727及び2015年9月16日付で出願された日本特許出願2015-183054に基づいており、その全体が引用により援用される。
Although the present invention has been described in detail using specific embodiments, it will be apparent to those skilled in the art that various modifications can be made without departing from the spirit and scope of the invention.
This application is based on Japanese Patent Application No. 2015-027727 filed on February 16, 2015 and Japanese Patent Application No. 2015-183054 filed on September 16, 2015, which is incorporated by reference in its entirety. .
 1 第一生物処理槽
 2 第二生物処理槽
 10,20 塔体
 12a,12b,22a,22b 散気管
 23 ストレーナ
DESCRIPTION OF SYMBOLS 1 1st biological treatment tank 2 2nd biological treatment tank 10,20 Tower 12a, 12b, 22a, 22b Air diffuser 23 Strainer

Claims (10)

  1.  嵩比重が1よりも小さい流動床担体を収容した生物処理槽内の底部に設けた散気管から曝気して該担体を流動させる生物処理槽の運転方法において、
     該生物処理槽内の底部の一半側に設けた散気管から曝気を行って塔体内に上下方向の循環流を形成する工程と、全ての散気管から曝気を行う工程とを含むことを特徴とする生物処理槽の運転方法。
    In the operation method of the biological treatment tank in which the carrier is flowed by aeration from an air diffuser provided at the bottom of the biological treatment tank containing a fluidized bed carrier having a bulk specific gravity smaller than 1.
    Characterized in that it includes a step of aerating from an air diffuser provided on one half of the bottom of the biological treatment tank to form a vertical circulation flow in the tower, and an aerating step from all the air diffusers. To operate the biological treatment tank.
  2.  請求項1において、塔体内に担体を投入した場合、該生物処理槽内の底部の一半側に設けた散気管から曝気を行って塔体内に上下方向の循環流を形成することを特徴とする生物処理槽の運転方法。 In Claim 1, when a support | carrier is injected | thrown-in to the tower body, it aerates from the diffuser pipe provided in the half part of the bottom part in this biological treatment tank, The vertical flow is formed in a tower body, It is characterized by the above-mentioned. Operation method of biological treatment tank.
  3.  請求項1又は2において、前記塔体内に整流機構が不存在であることを特徴とする生物処理槽の運転方法。 3. The method for operating a biological treatment tank according to claim 1 or 2, wherein a rectifying mechanism is absent in the tower.
  4.  請求項1ないし3のいずれか1項において、塔体内に散水することを特徴とする生物処理槽の運転方法。 4. The method for operating a biological treatment tank according to any one of claims 1 to 3, wherein the tower is sprinkled with water.
  5.  請求項1ないし4のいずれか1項において、消泡剤含有水を散水することを特徴とする生物処理槽の運転方法。 5. The method for operating a biological treatment tank according to any one of claims 1 to 4, wherein the defoamer-containing water is sprinkled.
  6.  請求項1ないし5のいずれか1項において、前記生物処理槽の槽体は、高さ(H)と直径(D)との比(H/D)が1.5~5.0の筒形の塔体よりなることを特徴とする生物処理槽の運転方法。 The biological treatment tank according to any one of claims 1 to 5, wherein the biological treatment tank has a cylindrical shape having a ratio (H / D) of height (H) to diameter (D) of 1.5 to 5.0. A method for operating a biological treatment tank, comprising:
  7.  有機性排水を1段または多段に設けられた生物処理槽で生物処理する方法において、
     少なくとも1つの生物処理槽を請求項1ないし6のいずれか1項に記載の方法によって起動させることを特徴とする有機性排水の生物処理方法。
    In a method of biologically treating organic wastewater in a biological treatment tank provided in one or more stages,
    A biological treatment method for organic waste water, wherein at least one biological treatment tank is activated by the method according to any one of claims 1 to 6.
  8.  請求項7において、第一段の生物処理槽において、分散菌による有機物の分解により分散菌の増加した第一生物処理水を生成させ、
     後段の第二生物処理槽において、第二生物処理水を生成させることを特徴とする有機性排水の生物処理方法。
    In claim 7, in the first-stage biological treatment tank, the first biological treatment water in which the dispersal bacteria increased by the decomposition of the organic matter by the dispersal bacteria,
    A biological treatment method for organic waste water, wherein second biological treatment water is generated in a second biological treatment tank at a subsequent stage.
  9.  請求項8において、第一生物処理槽及び第二生物処理槽は同一形状及び同一大きさの槽体を有しており、該槽体の高さが6~11mであることを特徴とする有機性排水の生物処理方法。 9. The organic body according to claim 8, wherein the first biological treatment tank and the second biological treatment tank have the same shape and the same size tank body, and the height of the tank body is 6 to 11 m. Biological treatment method for effluent.
  10.  槽内の底部に散気管を備えた生物処理槽において、
     該散気管として、少なくとも、該生物処理槽の該底部の一半側に設けられた第1の散気管と、他半側に設けられた第2の散気管とを備えており、
     該第1の散気管にのみ気体を供給する第1の供給態様と、第1及び第2の散気管の双方に気体を供給する第2の供給態様とを切り替えるための気体供給切替手段を備えたことを特徴とする生物処理槽。
    In a biological treatment tank equipped with an air diffuser at the bottom of the tank,
    As the air diffuser, it comprises at least a first air diffuser provided on one half side of the bottom of the biological treatment tank and a second air diffuser provided on the other half side,
    Gas supply switching means for switching between a first supply mode for supplying gas only to the first diffuser tube and a second supply mode for supplying gas to both the first and second diffuser tubes is provided. A biological treatment tank characterized by that.
PCT/JP2016/052994 2015-02-16 2016-02-02 Biological treatment tank, method for operating same and method for treating organic wastewater WO2016132881A1 (en)

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JPS5637093A (en) * 1979-08-30 1981-04-10 Sumitomo Metal Mining Co Ltd Treating method for waste water to high degree
JPS588585A (en) * 1981-07-09 1983-01-18 Kurita Water Ind Ltd Fluidized-bed type sewage treating device
JPH1024299A (en) * 1996-07-10 1998-01-27 Clean Tec Kk Aerobic treatment of organic sewage and device therefor
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JP2001179280A (en) * 1999-12-24 2001-07-03 Nkk Corp Method and apparatus for treating wastewater
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