JP2009072767A - Activated sludge apparatus and treatment method - Google Patents
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
Abstract
Description
本発明は、有機物含有水を処理する活性汚泥装置、及び有機物含有水を活性汚泥装置により処理する方法に関する。 The present invention relates to an activated sludge apparatus for treating organic substance-containing water and a method for treating organic substance-containing water with an activated sludge apparatus.
生物処理槽に固定担体を有する活性汚泥装置は、有機物含有水の処理によく用いられている。活性汚泥浮遊物質濃度(MLSS濃度)が従来の活性汚泥法の2000〜5000mg/Lに対して5000〜10000mg/Lと高めることができるため、処理槽の容積あたりのBOD処理能力を高めることができる。また、発生する余剰汚泥が少ないという利点も有する。特許文献1や特許文献2には様々な材質や形状の固定担体が開示され、生物処理槽が一個から数個に分割された活性汚泥装置が開示されている。固定担体は生物処理槽のほとんどに充填されるのが通常であるが、生物処理槽に使用される固定担体は高価である。コストを低減するために固定担体の量を削減すると、容積当りのBOD処理能力が低下したり、余剰汚泥が増加する問題があった。
かかる事情に鑑み、本発明が解決しようとする課題は、固定担体の充填量が少なくても、容積当りのBOD処理能力が高く、さらに余剰汚泥の増大を防止することができる、活性汚泥装置及び処理方法を提供することにある。 In view of such circumstances, the problem to be solved by the present invention is that the activated sludge apparatus has a high BOD processing capacity per volume and can prevent an increase in excess sludge even when the amount of the fixed carrier is small. It is to provide a processing method.
本発明は、上記課題に対して鋭意検討したところ、有機物含有水を処理する活性汚泥装置において、有機物含有水の流れ方向である上流から下流の方向に、直列に配置された、曝気槽と、生物処理槽と、沈殿槽とを備え、前記生物処理槽が固定担体と、散気手段と、両者を分離するバッフル板とを有し、前記沈殿槽の汚泥を前記生物処理槽に返送する返送手段をさらに備える構成により、上記課題を解決できるという知見を得て、本発明を完成するに至った。 In the activated sludge apparatus for treating the organic matter-containing water, the present invention has been intensively studied with respect to the above-mentioned problems. A biological treatment tank and a sedimentation tank, the biological treatment tank has a fixed carrier, an air diffuser, and a baffle plate for separating the two, and the sludge from the sedimentation tank is returned to the biological treatment tank. The present invention has been completed by obtaining the knowledge that the above problem can be solved by the configuration further comprising means.
すなわち、本発明は下記の通りである。
1.有機物含有水を処理する活性汚泥装置であって、上流から下流の方向に、直列に配置された、曝気槽と、生物処理槽と、沈殿槽とを備え、前記生物処理槽が固定担体と、散気手段と、両者を分離するバッフル板とを有し、前記沈殿槽の汚泥を前記生物処理槽に返送する返送手段をさらに備える、活性汚泥装置。
2.前記生物処理槽が2つ以上に分割されている、1.に記載の活性汚泥装置。
3.前記固定担体が、芯材と該芯材に一部が固定された繊維状物とからなり、かつ該繊維状物を芯材回りに密生せしめて構成された固定担体である1又は2に記載の活性汚泥装置。
4.前記固定担体が、ラセン形状をなしている1.〜3.のいずれかに記載の活性汚泥装置。
5.前記繊維状物が、ポリ塩化ビニリデンである3.又は4.に記載の活性汚泥装置。
6.有機物含有水の処理方法であって、前記有機物含有水を曝気処理する工程、固定担体と、散気手段と、両者を分離するバッフル板とを有する生物処理槽において、散気手段からの気泡を固定担体に当てずに散気し生物処理する工程、沈殿槽において、汚泥を分離する工程、および分離後の前記汚泥を、前記生物処理槽に返送する工程、を含む有機物含有水の処理方法。
That is, the present invention is as follows.
1. An activated sludge apparatus for treating organic substance-containing water, comprising an aeration tank, a biological treatment tank, and a sedimentation tank arranged in series in an upstream to downstream direction, wherein the biological treatment tank is a fixed carrier, An activated sludge apparatus, further comprising a return means for returning the sludge of the settling tank to the biological treatment tank, having an air diffuser and a baffle plate for separating both.
2. The biological treatment tank is divided into two or more. The activated sludge apparatus described in 1.
3. 3. The fixed carrier according to 1 or 2, wherein the fixed carrier comprises a core material and a fibrous material partially fixed to the core material, and the fixed carrier is configured by closely growing the fibrous material around the core material. Activated sludge equipment.
4). The fixed carrier has a spiral shape. ~ 3. The activated sludge apparatus according to any one of the above.
5). 2. The fibrous material is polyvinylidene chloride. Or 4. The activated sludge apparatus described in 1.
6). An organic matter-containing water treatment method comprising: a step of aeration treatment of the organic matter-containing water; a biological treatment tank having a fixed carrier, an air diffuser, and a baffle plate that separates both; A method for treating organic substance-containing water, comprising a step of aeration and biological treatment without contact with a fixed carrier, a step of separating sludge in a sedimentation tank, and a step of returning the separated sludge to the biological treatment tank.
本発明の活性汚泥装置及び処理方法は、固定担体の充填量が少なくても、容積当りのBOD処理能力が高く、さらに余剰汚泥の増大を防止することができるという効果を有する。 The activated sludge apparatus and the treatment method of the present invention have the effect that the BOD treatment capacity per volume is high even when the amount of the fixed carrier filled is small, and an increase in excess sludge can be prevented.
以下の実施形態は、本発明を説明するための例示であり、本発明をこの実施形態にのみ限定する趣旨ではない。本発明は、その要旨を逸脱しない限り、さまざまな形態で実施することができる。 The following embodiment is an example for explaining the present invention, and is not intended to limit the present invention only to this embodiment. The present invention can be implemented in various forms without departing from the gist thereof.
以下に、本発明の活性汚泥装置及び処理方法の実施の形態を詳細に説明する。
本発明は、有機物含有水を処理する活性汚泥装置及び処理方法に関する。本発明における活性汚泥装置とは、水中に含有する有機物等を活性汚泥中に存在する微生物等により生物分解し、活性汚泥を沈殿槽により固液分離し、清澄な処理水を得る装置である。
図1は、本発明による有機物含有水を処理する活性汚泥装置の好ましい一の態様の概略図を示す。図1に示すように、有機物含有水が流れる上流から下流の方向に、直列に配置された曝気槽1と、固定担体と散気手段と両者を分離するバッフル板とを有する生物処理槽2と、沈殿槽3とを備える。さらに、本発明の活性汚泥装置は、前記沈殿槽における汚泥を固定担体を有する生物処理槽へ返送する手段である汚泥返送管6を備える。
Below, embodiment of the activated sludge apparatus and the processing method of this invention is described in detail.
The present invention relates to an activated sludge apparatus and a treatment method for treating organic substance-containing water. The activated sludge apparatus in the present invention is an apparatus that biodegrades organic matter and the like contained in water with microorganisms and the like present in the activated sludge and solid-liquid separates the activated sludge with a sedimentation tank to obtain clear treated water.
FIG. 1 shows a schematic view of one preferred embodiment of an activated sludge apparatus for treating organic substance-containing water according to the present invention. As shown in FIG. 1, the biological treatment tank 2 which has the
本発明の活性汚泥装置における曝気槽は、通常の活性汚泥法に用いられるものを使用することができる。曝気槽において有機物含有水中のBOD成分は、70〜95%程度まで酸化分解することができる。曝気槽のBOD容積負荷は、1kg/m3・日以上、例えば1〜20kg/m3・日とすることができる。
本発明の曝気槽における水力学的滞留時間(HRT)は、24h以下、例えば0.5〜24hとすることができる。汚泥濃度(MLSS)は流入する有機物含有水のBOD濃度により異なり、通常は100〜10000mg/Lとすることができる。曝気槽の水温は15〜40℃が好ましく、20〜37℃がより好ましく、25〜35℃がさらに好ましい。曝気槽のpHはかなり広い範囲で実施することができ、pH6から8の範囲が好ましい。曝気槽の溶存酸素(DO)は0.2mg/L以上が好ましく、1mg/L以上がより好ましい。空気や酸素の曝気方式として、散気管や機械曝気を用いることができる。散気管を用いる場合は、旋回流方式や全面曝気方式が挙げられる。機械曝気としては、機械撹拌方式やエゼクタ方式が挙げられる。BOD容積負荷が大きい場合は、効率のよい曝気方式を用いることが好ましい。
As the aeration tank in the activated sludge apparatus of the present invention, those used in a normal activated sludge method can be used. In the aeration tank, the BOD component in the organic substance-containing water can be oxidatively decomposed to about 70 to 95%. BOD volume load of the aeration tank, 1 kg / m 3 · day or more, for example, be a 1~20kg / m 3 · day.
The hydrodynamic residence time (HRT) in the aeration tank of the present invention can be 24 h or less, for example, 0.5 to 24 h. The sludge concentration (MLSS) varies depending on the BOD concentration of the inflowing organic substance-containing water, and can be usually 100 to 10,000 mg / L. The water temperature of the aeration tank is preferably 15 to 40 ° C, more preferably 20 to 37 ° C, and further preferably 25 to 35 ° C. The pH of the aeration tank can be carried out in a fairly wide range, and a pH range of 6 to 8 is preferred. The dissolved oxygen (DO) in the aeration tank is preferably 0.2 mg / L or more, and more preferably 1 mg / L or more. As an air or oxygen aeration method, an air diffuser or mechanical aeration can be used. In the case of using an air diffuser, a swirling flow method or a full aeration method can be used. Examples of the mechanical aeration include a mechanical stirring method and an ejector method. When the BOD volumetric load is large, it is preferable to use an efficient aeration method.
本発明の曝気槽において、有機物含有水中に窒素やりんが不足する場合は、栄養源として窒素やりんを添加することが好ましい。曝気槽は、必要に応じて2段以上の多段工程であってもよい。また、必要に応じて、流動担体や固定担体などの担体を有してもよいが、大量のBOD成分を分解するために曝気を充分にする必要があるため、流動担体が好ましい。流動担体として、ゲル状担体やプラスチック担体、繊維状担体などが挙げられる。一種類の担体や二種類以上の担体を組合せて使用することができる。流動担体の材料としては、ポリエチレングリコールやポリビニルアルコール、アクリルアミド、ポリエチレン、ポリプロピレン、ポリウレタン、セルロース、ポリエステル等が挙げられる。流動担体の形状としては、球や立方体、円筒形、多孔質体が挙げられる。流動担体の大きさとしては、1〜20mmが好ましく、3〜10mmがさらに好ましい。流動担体を用いる場合はスクリーンで分離することが好ましい。流動担体の充填率としては槽容積の1〜50%であることが好ましく、さらに2〜20%であることがより好ましい。 In the aeration tank of the present invention, when nitrogen or phosphorus is insufficient in the organic substance-containing water, it is preferable to add nitrogen or phosphorus as a nutrient source. The aeration tank may be a multistage process having two or more stages as required. In addition, a carrier such as a fluid carrier or a fixed carrier may be included as necessary, but a fluid carrier is preferable because aeration is necessary to decompose a large amount of BOD components. Examples of the fluid carrier include a gel carrier, a plastic carrier, and a fibrous carrier. One type of carrier or two or more types of carriers can be used in combination. Examples of the material for the fluid carrier include polyethylene glycol, polyvinyl alcohol, acrylamide, polyethylene, polypropylene, polyurethane, cellulose, and polyester. Examples of the shape of the fluid carrier include spheres, cubes, cylinders, and porous bodies. The size of the fluid carrier is preferably 1 to 20 mm, and more preferably 3 to 10 mm. When using a fluid carrier, it is preferable to separate it with a screen. The filling rate of the fluid carrier is preferably 1 to 50% of the tank volume, and more preferably 2 to 20%.
曝気槽に用いる固定担体としては後の生物処理槽の項で述べる固定担体を用いることができる。流動担体や固定担体は曝気槽全体に有してもよいが、槽の一部に有するだけでも効果的である。沈殿槽や生物処理槽から曝気槽への返送汚泥は、通常は必要がないが、流入する有機物含有水の水量やBOD成分が大きく減少する場合等には曝気槽へ返送汚泥を添加する必要があるため、曝気槽へ返送汚泥を添加する手段を設置する。 As the fixed carrier used in the aeration tank, a fixed carrier described in the section of the biological treatment tank later can be used. The fluid carrier or the fixed carrier may be provided in the entire aeration tank, but it is effective to have it in a part of the tank. The return sludge from the sedimentation tank or biological treatment tank to the aeration tank is not usually required, but it is necessary to add the return sludge to the aeration tank when the amount of inflowing organic matter-containing water or the BOD component is greatly reduced. Therefore, a means to add the return sludge to the aeration tank will be installed.
この場合の返送汚泥量は、通水した有機物含有水量に対する容量比で1以下、例えば0.01〜1にすることができる。なお、曝気槽に流入する有機物含有水の成分や処理量を均一に保つため、曝気槽の前段に調整槽を設置するのが好ましい。調整槽の容量は流入量及び流入成分の変動パターン、流量調整後の流量変動許容幅等を考慮して決定することができる。また、有機物含有水に懸濁物質(SS)、油分、有害金属等の生物処理に障害を与える成分が含まれている場合は、曝気槽の前段に沈殿槽、加圧浮上装置、凝集沈殿槽等の前処理手段を設置するのが好ましい。 In this case, the amount of returned sludge can be set to 1 or less, for example, 0.01 to 1 in terms of the volume ratio with respect to the amount of water containing organic matter. In addition, in order to keep the components and processing amount of the organic substance-containing water flowing into the aeration tank uniform, it is preferable to install an adjustment tank in front of the aeration tank. The capacity of the adjustment tank can be determined in consideration of the inflow amount and the fluctuation pattern of the inflow component, the flow rate fluctuation allowable width after the flow rate adjustment, and the like. In addition, when the organic substance-containing water contains components that impede biological treatment such as suspended solids (SS), oil, and toxic metals, a precipitation tank, a pressure levitation device, a coagulation sedimentation tank are placed in front of the aeration tank. It is preferable to install pretreatment means such as the above.
本発明の活性汚泥装置における生物処理槽は、固定担体と散気手段と両者を分離するバッフル板を有する。本発明の生物処理槽は、前段の曝気槽からの排水を流入する構成であればよく、図1に例示するように、曝気槽にて曝気処理された有機物含有水をオーバーフローさせて、本発明の生物処理槽に流入することが好ましい。 The biological treatment tank in the activated sludge apparatus of the present invention has a fixed carrier, an air diffuser, and a baffle plate that separates both. The biological treatment tank of the present invention may have any configuration as long as the wastewater from the previous aeration tank flows in, and as illustrated in FIG. 1, the organic substance-containing water that has been aerated in the aeration tank is overflowed, It is preferable to flow into the biological treatment tank.
本発明に用いられる生物処理槽ではBOD除去、COD除去、窒素除去、リン除去以外に、汚泥の自己消化や捕食、汚泥のフロック化が行われる。生物処理槽は、除去したいものによって種々の形態や運転条件を取ることができる。生物処理槽は、必要に応じて2段以上の多段工程であってもよい。生物処理槽は余剰汚泥の発生を少なくするため、又、糸状性バルキングを防止するために2段以上の多段工程が好ましく、食物連鎖を効率的に成立させる観点やコスト的な観点から3〜6段がより好ましい。BOD除去が主な目的であれば、好気工程だけであってもよい。好気工程を行うための生物処理槽のBOD容積負荷は、前段の曝気槽で有機物含有水中のBOD成分は大部分除去されているので、5kg/m3・日以下、例えば0.05〜5kg/m3・日で行うことができる。生物処理槽のHRTは48h以下、例えば1〜48hとすることができる。MLSSは、通常は2000〜20000mg/Lとすることができ、5000〜20000mg/Lで行うのが好ましい。生物処理槽の水温は15〜40℃が好ましく、20〜37℃がより好ましく、25〜35℃がさらに好ましい。pHはかなり広い範囲で実施することができ、pH6〜8の範囲が好ましい。生物処理槽のDOは0.2mg/L以上が好ましく、1mg/L以上がより好ましい。 In the biological treatment tank used in the present invention, in addition to BOD removal, COD removal, nitrogen removal, and phosphorus removal, sludge self-digestion, predation, and sludge flocification are performed. The biological treatment tank can take various forms and operating conditions depending on what it is desired to remove. The biological treatment tank may be a multistage process having two or more stages as necessary. In order to reduce the generation of excess sludge in the biological treatment tank and to prevent filamentous bulking, a multi-stage process of two or more stages is preferable. From the viewpoint of efficiently establishing a food chain and from the viewpoint of cost, 3-6. A step is more preferred. If the main purpose is to remove BOD, only the aerobic process may be used. The BOD volume load of the biological treatment tank for performing the aerobic process is 5 kg / m 3 · day or less, for example, 0.05 to 5 kg, because most of the BOD components in the organic substance-containing water are removed in the previous aeration tank / M 3 · day. The HRT of the biological treatment tank can be 48 h or less, for example, 1 to 48 h. MLSS can be normally 2000-20000 mg / L, and it is preferable to carry out at 5000-20000 mg / L. 15-40 degreeC is preferable, as for the water temperature of a biological treatment tank, 20-37 degreeC is more preferable, and 25-35 degreeC is further more preferable. The pH can be carried out in a fairly wide range, and a pH range of 6-8 is preferred. The DO of the biological treatment tank is preferably 0.2 mg / L or more, and more preferably 1 mg / L or more.
本発明に用いられる生物処理槽では、窒素やりんの除去を目的にさらに嫌気工程を設けることができる。窒素除去が必要な場合は、脱窒・硝化の二段や脱窒・硝化・第二脱窒・第二硝化の四段等とすることができる。硝化工程の水温は10〜35℃が好ましく、20〜30℃がより好ましい。生物処理槽におけるpHは6.8〜8.5が好ましく、生物処理槽のDOは2mg/L以上が好ましく、生物処理槽の汚泥滞留時間(SRT)は7日間以上とすることが好ましい。脱窒工程にBOD成分が不足する場合はメタノール等のBOD源を添加したり、BOD成分を含む有機物含有水をステップフィードすることができる。 In the biological treatment tank used in the present invention, an anaerobic process can be further provided for the purpose of removing nitrogen and phosphorus. When nitrogen removal is necessary, the denitrification and nitrification can be performed in two stages, denitrification, nitrification, second denitrification, and second nitrification in four stages. The water temperature in the nitrification step is preferably 10 to 35 ° C, more preferably 20 to 30 ° C. The pH of the biological treatment tank is preferably 6.8 to 8.5, the DO of the biological treatment tank is preferably 2 mg / L or more, and the sludge residence time (SRT) of the biological treatment tank is preferably 7 days or more. When the BOD component is insufficient in the denitrification process, a BOD source such as methanol can be added, or organic substance-containing water containing the BOD component can be step-fed.
本発明に用いられる生物処理槽は、固定担体を有している。固定担体は、生物処理槽が種々の生物処理を担うため、細菌だけでなく原生動物や後生動物などの多様な微生物が生育するために用いられる。固定担体は特に限定されないが、形状としてはハニカム状、ラセン状、中空状、スポンジ状、網目状、棒状、線状などが挙げられ、微生物が多く生息でき生物処理槽の流動が良くなることからラセン状が好ましい。また、芯材と該芯材に一部が固定された繊維状物とからなり、かつ、該繊維状物を前記芯材回りに密生せしめて構成された固定担体が好ましい。また、前記芯材の形状は限定されないが、芯材がラセン形状をなしている固定担体が好ましい。芯材には、軟鉄、アルミ、銅などの金属、又は軟質塩化ビニルなどのプラスチックを使用することができる。金属製の芯材には腐食防止のため防水塗装やプラスチック被覆を施すことができる。芯材の直径は材質によって異なり、1mm以上7mm以下が好ましい。さらに、前記繊維状物の材質は特に限定されないが、ポリエチレン、ポリプロピレン、ポリエステル、ポリアミド、ポリ塩化ビニル、ポリ塩化ビニリデン、ポリフッ化ビニリデン、ポリウレタンなどが挙げられ、ポリ塩化ビニリデンが微生物の付着性がよいので好ましい。固定担体は、複数本の固定担体を適当な耐食性材料で製造されたフレームに保持させた固定担体ブロックにして、生物処理槽に浸漬して使用することができる。固定担体ブロックの高さは、生物処理槽の水深に適した高さのものを使用すればよく、0.5m以上6m以下であるのが好ましく、2m以上4m以下がより好ましい。 The biological treatment tank used in the present invention has a fixed carrier. The fixed carrier is used for the growth of various microorganisms such as protozoa and metazoans, as well as bacteria, because the biological treatment tank is responsible for various biological treatments. The fixed carrier is not particularly limited, but examples of the shape include a honeycomb shape, a spiral shape, a hollow shape, a sponge shape, a mesh shape, a rod shape, and a linear shape, because many microorganisms can inhabit and the flow of the biological treatment tank is improved. A helical form is preferred. Also preferred is a fixed carrier composed of a core material and a fibrous material partially fixed to the core material, wherein the fibrous material is densely formed around the core material. The shape of the core material is not limited, but a fixed carrier in which the core material has a spiral shape is preferable. A metal such as soft iron, aluminum, or copper, or a plastic such as soft vinyl chloride can be used for the core material. The metal core can be waterproofed or plastic coated to prevent corrosion. The diameter of the core material varies depending on the material, and is preferably 1 mm or more and 7 mm or less. Furthermore, the material of the fibrous material is not particularly limited, and examples thereof include polyethylene, polypropylene, polyester, polyamide, polyvinyl chloride, polyvinylidene chloride, polyvinylidene fluoride, and polyurethane. Polyvinylidene chloride has good adhesion to microorganisms. Therefore, it is preferable. The fixed carrier can be used by immersing it in a biological treatment tank in the form of a fixed carrier block in which a plurality of fixed carriers are held on a frame made of a suitable corrosion-resistant material. The height of the fixed carrier block may be a height suitable for the water depth of the biological treatment tank, preferably 0.5 m or more and 6 m or less, more preferably 2 m or more and 4 m or less.
生物処理槽の水深は特に限定されないが、水深が浅いと曝気時の酸素溶解効率が低くなり、水深が深いと曝気時の圧力損失が高くなるため、水深は0.5m以上10m以下が好ましく、さらに1.5m以上5m以下がより好ましい。
生物処理槽の固定担体の充填量は、固定担体充填量で表すことができる。ここで固定担体充填量とは「生物処理槽に充填された固定担体の長さ」を「生物処理槽にある活性汚泥の容量」で割り、単位m/m3で表したものである。本発明の生物処理槽における固定担体充填量は、特に限定されないが、10から100m/m3が好ましく、30から70m/m3がより好ましい。本発明で定義された曝気槽を有しない活性汚泥装置(例えば、比較例に用いた図3の装置)では、固定担体充填量は70から120m/m3がよく用いられ、固定担体充填量を70m/m3より少なくすると汚泥発生量が増加したり、BOD容積負荷が上げられないなどの弊害が生じる。
The water depth of the biological treatment tank is not particularly limited, but if the water depth is shallow, the oxygen dissolution efficiency at the time of aeration becomes low, and if the water depth is deep, the pressure loss at the time of aeration becomes high. Therefore, the water depth is preferably 0.5 m or more and 10 m or less, Furthermore, 1.5 m or more and 5 m or less are more preferable.
The filling amount of the fixed carrier in the biological treatment tank can be represented by the fixed carrier filling amount. Here, the fixed carrier filling amount is obtained by dividing the “length of the fixed carrier filled in the biological treatment tank” by the “capacity of activated sludge in the biological treatment tank” and expressing the unit in m / m 3 . The filling amount of the fixed carrier in the biological treatment tank of the present invention is not particularly limited, but is preferably 10 to 100 m / m 3 and more preferably 30 to 70 m / m 3 . In an activated sludge apparatus that does not have an aeration tank as defined in the present invention (for example, the apparatus of FIG. 3 used in the comparative example), a fixed carrier filling amount of 70 to 120 m / m 3 is often used. If it is less than 70 m / m 3, the amount of sludge generated increases and the BOD volumetric load cannot be increased.
固定担体の使用量は、固定担体ブロックの投影床面積1m2当たり、固定担体の表面積として100m2以上3000m2以下が好ましい。また、100m2以上500m2以下であることがより好ましい。100m2以上あれば装置の設置面積効率がよく、500m2以下であれば、曝気によるエアーリフト効果が発揮されて上昇流と下降流とからなる均一な旋回流が得られ、微生物が成育しやすい環境が得られる。固定担体の表面積は更に好ましくは、250m2以上350m2以下である。 The amount of the fixed carrier used is preferably 100 m 2 or more and 3000 m 2 or less as the surface area of the fixed carrier per 1 m 2 of the projected floor area of the fixed carrier block. It is more preferably 100 m 2 or more 500 meters 2 or less. If it is 100 m 2 or more, the installation area efficiency of the apparatus is good, and if it is 500 m 2 or less, the air lift effect by aeration is exhibited and a uniform swirling flow consisting of an upflow and a downflow is obtained, and microorganisms are easy to grow. The environment is obtained. The surface area of the fixed carrier is more preferably 250 m 2 or more and 350 m 2 or less.
また、本発明に用いられる生物処理槽における担体としては、固定担体とともに曝気槽の項で述べた流動担体を使用することができる。担体は生物処理槽全体に有してもよく、槽の一部に有するだけでも効果的である。生物処理槽が2段以上の多段工程の場合、固定担体を用いた工程と流動担体を用いた工程を併用することもできる。 In addition, as the carrier in the biological treatment tank used in the present invention, the fluid carrier described in the section of the aeration tank can be used together with the fixed carrier. The carrier may be provided in the whole biological treatment tank, or it is effective to have the carrier only in a part of the tank. When the biological treatment tank is a multistage process having two or more stages, a process using a fixed carrier and a process using a fluid carrier can be used in combination.
本発明に用いられる生物処理槽は、固定担体と散気手段とを分離するバッフル板を有している。バッフル板は固定担体に直接気泡が当たらずに、生物処理槽の曝気による旋回流を均一にする目的で用いられる。特にBOD負荷が高くMLSSを10,000mg/L以上にする場合は、バッフル板を用いることが効果的である。バッフル板は、散気管により生じる水流に沿うように、固定担体ブロックの近くに仕切壁とほぼ平行かつ垂直に設置することが望ましく、バッフル板の長さは、上端を生物処理槽の運転停止時の液面から0.1〜0.3mの位置に、下端を固定担体ブロックの下端と同じ位置にすることが好ましい。 The biological treatment tank used in the present invention has a baffle plate that separates the fixed carrier and the air diffuser. The baffle plate is used for the purpose of making the swirl flow caused by aeration in the biological treatment tank uniform without bubbles directly hitting the fixed carrier. In particular, when the BOD load is high and the MLSS is set to 10,000 mg / L or more, it is effective to use a baffle plate. It is desirable to install the baffle plate near the fixed carrier block so as to follow the water flow generated by the air diffuser, and to be almost parallel to the partition wall. It is preferable to make the lower end the same position as the lower end of the fixed carrier block at a position of 0.1 to 0.3 m from the liquid surface.
バッフル板を用いると、生物処理槽の旋回流速が槽内に渡って均一になるため、槽内に設置された固定担体各々を通過する流速も均一となり、固定担体に汚泥が均一に付着することとなる。付着した汚泥の表面に好気性菌が、汚泥の内部には通性嫌気性菌が繁殖し、付着汚泥全体として、バランスの良い食物連鎖を形成する微生物生態系を築くことができる。その結果、余剰汚泥の増大を防止できる。また、旋回流速が均一であると、槽内の同一平面上では、溶存酸素濃度が均一となり、生物処理槽内の必要溶存酸素濃度を確保するための曝気量が最小限で済み、電力費を低減することができる。 When a baffle plate is used, the swirl flow rate of the biological treatment tank becomes uniform across the tank, so the flow rate that passes through each fixed carrier installed in the tank also becomes uniform, and sludge adheres uniformly to the fixed carrier. It becomes. Aerobic bacteria propagate on the surface of the attached sludge, facultative anaerobic bacteria propagate inside the sludge, and the microbial ecosystem that forms a well-balanced food chain can be established as the entire attached sludge. As a result, an increase in excess sludge can be prevented. In addition, if the swirl flow rate is uniform, the dissolved oxygen concentration is uniform on the same plane in the tank, and the amount of aeration required to secure the necessary dissolved oxygen concentration in the biological treatment tank is minimized. Can be reduced.
固定担体と散気手段とを分離するバッフル板を用いているので、散気手段より生じた気泡が上昇流を発生させ、この流れが槽全体を旋回する。バッフル板で固定担体と散気手段を分離しているので、散気手段から生じた気泡が直接固定担体に接触せず、固定担体の上方から下降流として固定担体を通過する。このことによって固定担体には汚泥と共に後生動物のミミズやクマムシ、原生動物のゾウリムシ、ワムシ等が付着し、食物連鎖を成立させる事ができる。 Since the baffle plate that separates the stationary carrier and the air diffuser is used, bubbles generated from the air diffuser generate an upward flow, and this flow swirls the entire tank. Since the fixed carrier and the air diffuser are separated by the baffle plate, bubbles generated from the air diffuser do not directly contact the fixed carrier and pass through the fixed carrier as a downward flow from above the fixed carrier. As a result, metazoans such as earthworms and bear beetles, protozoan Paramecium and rotifers adhere to the fixed carrier together with sludge, and a food chain can be established.
本発明の活性汚泥装置における沈殿槽は、前段の生物処理槽から流入する活性汚泥混合液を沈殿分離し清澄な処理水を得るものである。本発明の沈殿槽は、前段の生物処理槽からの排水を流入する構成であればよく、図1に例示するように、生物処理槽における排水のオーバーフローにより、本発明の沈殿槽に流入することが好ましい。
MLSSの調整は、余剰汚泥として引抜くか、生物処理槽への汚泥返送量により行うことができる。余剰汚泥の引抜き量は、流入BOD量に対する重量比率で5〜20%とすることができる。
The sedimentation tank in the activated sludge apparatus of the present invention precipitates and separates the activated sludge mixed solution flowing from the biological treatment tank in the previous stage to obtain a clear treated water. The sedimentation tank of the present invention may be configured so as to flow the wastewater from the biological treatment tank in the previous stage, and as illustrated in FIG. 1, it flows into the sedimentation tank of the present invention due to the overflow of the wastewater in the biological treatment tank. Is preferred.
The adjustment of MLSS can be performed by extracting as excess sludge or by returning the sludge to the biological treatment tank. The amount of excess sludge withdrawn can be set to 5 to 20% by weight ratio to the inflow BOD amount.
本発明の活性汚泥装置は、沈殿槽において分離された汚泥を、前述した生物処理槽へ返送する手段を備える。沈殿槽において分離された汚泥を返送する手段は特に限定されないが、通常の汚泥ポンプを使用することができる。返送汚泥量は特に限定されないが、返送汚泥量が少ないと沈殿槽のMLSSが高くなりすぎ、多いと電力費が高くなる。通水した有機物含有水量(Q)に対する汚泥返送比(容量比)は、好ましくは1〜5であり、より好ましくは2〜4である。先に述べたように汚泥の返送は、生物処理槽だけでなく必要に応じて、一部を曝気槽にも返送することができる。 The activated sludge apparatus of this invention is equipped with the means to return the sludge isolate | separated in the sedimentation tank to the biological treatment tank mentioned above. The means for returning the sludge separated in the settling tank is not particularly limited, but a normal sludge pump can be used. The amount of returned sludge is not particularly limited, but if the amount of returned sludge is small, the MLSS of the sedimentation tank becomes too high, and if it is large, the power cost becomes high. The sludge return ratio (capacity ratio) with respect to the organic substance-containing water amount (Q) that has passed through is preferably 1 to 5, more preferably 2 to 4. As described above, the sludge can be returned not only to the biological treatment tank but also to a part of the aeration tank as necessary.
本発明の活性汚泥装置には、上記の槽及び手段以外に、必要に応じて、他の装置や手段、槽などを併設することができる。例えば、前処理として、ストリッピング装置や加圧浮上装置、オイルスキマー、凝集沈殿装置、ろ過装置、膜分離装置、調整槽等が挙げられる。汚泥処理として、ベルトプレスやフィルタープレス、遠心脱水機、多重円板脱水機、汚泥可溶化装置、嫌気性消化装置等が挙げられる。後処理として、活性炭吸着やオゾン発生装置、紫外線照射装置、殺菌剤添加装置、イオン交換装置、イオン吸着装置、逆浸透膜(RO膜)等が挙げられる。膜分離活性汚泥装置の生物処理を順調に実行するものとして、pH調整装置や温度調整装置、メタノール添加装置、消泡剤添加装置、無機凝集剤添加装置、分離膜用薬液洗浄槽、脱臭装置等が挙げられる。 In the activated sludge apparatus of the present invention, in addition to the tank and means described above, other apparatuses, means, tanks and the like can be provided as needed. Examples of the pretreatment include a stripping device, a pressure levitation device, an oil skimmer, a coagulation sedimentation device, a filtration device, a membrane separation device, and a regulating tank. Examples of the sludge treatment include belt presses, filter presses, centrifugal dehydrators, multiple disk dehydrators, sludge solubilizers, anaerobic digesters, and the like. Post-treatment includes activated carbon adsorption, ozone generator, ultraviolet irradiation device, bactericidal agent addition device, ion exchange device, ion adsorption device, reverse osmosis membrane (RO membrane) and the like. As a means for smoothly performing biological treatment of membrane separation activated sludge apparatus, pH adjustment device, temperature adjustment device, methanol addition device, antifoaming agent addition device, inorganic flocculant addition device, separation membrane chemical cleaning tank, deodorization device, etc. Is mentioned.
次に、本発明の有機物含有水の処理方法について説明する。本発明の処理方法は、前記有機物含有水を曝気処理する工程と、固定担体と散気手段と両者を分離するバッフル板とを有する生物処理槽において、散気手段からの気泡を固定担体に当てずに散気し生物処理する工程と、沈殿槽において、汚泥を分離する工程と、分離後の前記汚泥を、前記生物処理槽に返送する工程と、を含む。
曝気処理工程では、有機物含有水の有機成分を酸化分解させる。また、生物処理工程では、曝気槽に曝気処理された有機物含有水を流入し、固定担体を有する生物処理槽において、BOD除去、窒素除去、リン除去以外に、汚泥の自己消化や捕食、汚泥のフロック化が行われる。次に、沈殿槽において、生物処理槽から流入する汚泥混合液を沈殿により汚泥を分離するとともに、清澄な処理水を得る。
Next, the processing method of the organic substance containing water of this invention is demonstrated. The treatment method of the present invention is a biological treatment tank having a step of aeration treatment of the organic substance-containing water, a baffle plate for separating the fixed carrier and the aeration means, and applying air bubbles from the aeration means to the fixed carrier. And a biological treatment process, a step of separating sludge in a sedimentation tank, and a step of returning the separated sludge to the biological treatment tank.
In the aeration process, the organic component of the organic substance-containing water is oxidatively decomposed. In the biological treatment process, aerated organic material-containing water flows into the aeration tank, and in the biological treatment tank having a fixed carrier, in addition to BOD removal, nitrogen removal, and phosphorus removal, self-digestion and predation of sludge, sludge Flocking is performed. Next, in the sedimentation tank, the sludge mixed liquid flowing from the biological treatment tank is separated by sedimentation, and clear treated water is obtained.
本発明の処理方法では、沈殿槽において分離された汚泥を、固定担体を有する生物処理槽へ返送し、前述の生物処理槽における生物処理工程を行う。このように、一度分離された汚泥を、再度生物処理を行うことで、高いBOD負荷において、余剰汚泥の発生を低減することができる。 In the treatment method of the present invention, the sludge separated in the sedimentation tank is returned to the biological treatment tank having the fixed carrier, and the biological treatment process in the biological treatment tank described above is performed. Thus, once the sludge once separated is subjected to biological treatment again, generation of excess sludge can be reduced at a high BOD load.
以下では、実施例及び比較例を挙げて本発明をより具体的に説明する。
まず、本発明の実施例及び比較例で用いた分析方法について、簡単に説明する。
<BOD容積負荷>
BOD容積負荷は、[一日あたりに流入させた有機物含有水中のBOD成分の重量]を、[曝気槽と生物処理槽にある活性汚泥の容量]で割り、単位kg/m3・日で表示した。
汚泥発生率は、[引抜いた汚泥中の固形分の重量]を、[流入させた有機物含有水中のBOD成分の重量]で割り、百分率(%)で表示した。
<固定担体充填量>
固定担体充填量は、「曝気槽と生物処理槽に充填された固定担体の長さ」を、「曝気槽と生物処理槽にある活性汚泥の容量」で割り、単位m/m3で表示した。
Below, an Example and a comparative example are given and this invention is demonstrated more concretely.
First, analysis methods used in Examples and Comparative Examples of the present invention will be briefly described.
<BOD volumetric load>
The BOD volumetric load is expressed in units of kg / m 3 · day by dividing [weight of BOD component in organic substance-containing water flowed in per day] by [volume of activated sludge in the aeration tank and biological treatment tank]. did.
The sludge generation rate was expressed as a percentage (%) by dividing [weight of the solid content in the extracted sludge] by [weight of the BOD component in the introduced organic substance-containing water].
<Fixed carrier loading amount>
The fixed carrier filling amount is expressed in units of m / m 3 by dividing the “length of the fixed carrier filled in the aeration tank and the biological treatment tank” by the “capacity of activated sludge in the aeration tank and the biological treatment tank”. .
(実施例1)
本実施例に用いた活性汚泥装置を図1に示す。曝気槽1(容量6L)、生物処理槽2(容量18L)及び沈殿槽3(容量4L)は、有機物含有水が流れる上流から下流の方向に、直列に連結されている。曝気槽と生物処理槽には、それぞれ散気管7が設置されており曝気が可能である。生物処理槽は3段に等分されており、第2段と第3段に固定担体4と散気管と両者を分離するバッフル板5とが設置されている。固定担体は、ポリ塩化ビニリデン繊維を長さ1.5cmのループ状にしてその一部をプラスチック被覆された銅製の芯材に密生するように固定し、長さ60cmで外径が8cmのラセン状にしたものを用いた。沈殿槽中の活性汚泥は送液ポンプにより汚泥返送管6を通して生物処理槽の第一段に返送される。汚泥返送比は2とした。水温は25℃で実施した。有機物含有水としてスキムミルク水溶液(BOD約1000mg/L)を用いた。約3週間の馴養運転後、スキムミルク水溶液を48L/日流入し、BOD容積負荷を2kg/m3・日の一定とした。この時のHRTは12時間となる。沈殿槽の活性汚泥を適宜引抜き、生物処理槽のMLSSが約10000mg/Lになるように調整した。曝気槽のMLSSは約300から900mg/Lであった。運転期間中に曝気槽の発泡が見られたのでノニオン系消泡剤を適宜添加した。重曹を適宜添加しpHが約7になるように調整した。処理水のBODは5mg/L以下と良好であった。また、生物処理槽には原生動物及び後生動物が棲みつき、食物連鎖を作っており、汚泥発生率も13%と良好であった。結果を表1に示す。
Example 1
The activated sludge apparatus used in this example is shown in FIG. The aeration tank 1 (capacity 6L), the biological treatment tank 2 (capacity 18L), and the sedimentation tank 3 (capacity 4L) are connected in series from upstream to downstream in which the organic substance-containing water flows.
(実施例2)
本実施例に用いた活性汚泥装置を図2に示す。生物処理槽の第1段を嫌気処理とした。第1段には散気管が設置されておらず、汚泥を撹拌するための撹拌装置10を設置した。また、嫌気処理における脱窒のためのBOD成分を補うために、流入する有機物含有水の30%(0.3Q)を生物処理槽の第一段にステップフィードした。それ以外は実施例1と同様に行った。処理水の全窒素(TN)は15mg/Lと良好であった。生物処理槽には原生動物及び後生動物が棲みつき、食物連鎖を作っており、汚泥発生率も16%と良好であった。結果を表1に示す。
(Example 2)
The activated sludge apparatus used for the present Example is shown in FIG. The first stage of the biological treatment tank was anaerobic treatment. The first stage was not provided with an air diffuser, and a stirring
(比較例1)
本比較例に用いた活性汚泥装置を図3に示す。曝気槽がなく、生物処理槽(容量24L)及び沈殿槽(容量4L)は、有機物含有水が流れる上流から下流の方向に、直列に連結されている。生物処理槽は4段に等分されそれぞれに散気管と固定担体を設置した。それ以外は、実施例1と同様に行った。馴養後、約2週間BOD容積負荷2kg/m3・日を続けた後、糸状性バルキングが発生したので、以降はBOD容積負荷を1.5kg/m3・日に下げて行った。バッフル板が無いためか、固定担体から流出する原生動物及び後生動物が観測され、汚泥発生率も25%と高かった。結果を表1に示す。
(Comparative Example 1)
The activated sludge apparatus used in this comparative example is shown in FIG. There is no aeration tank, and the biological treatment tank (capacity 24L) and the sedimentation tank (capacity 4L) are connected in series from upstream to downstream in which the organic substance-containing water flows. The biological treatment tank was equally divided into four stages, and an aeration tube and a fixed carrier were installed in each. Otherwise, the same procedure as in Example 1 was performed. After acclimatization, BOD volumetric load 2 kg / m 3 · day was continued for about 2 weeks, and then filamentous bulking occurred. Thereafter, the BOD volumetric load was lowered to 1.5 kg / m 3 · day. Probable animals and metazoans that flow out of the fixed carrier were observed because of the absence of baffle plates, and the sludge generation rate was as high as 25%. The results are shown in Table 1.
(比較例2)
比較例1に用いた活性汚泥装置の第1段から第4段のすべてにバッフル板を設置した。それ以外は、比較例1と同様に行った。馴養後、約2週間BOD容積負荷2kg/m3・日を続けた後、糸状性バルキングが発生したので、以降はBOD容積負荷を1.5kg/m3・日に下げて行った。実施例1および2と比較して、BOD容積負荷が低く、固定担体充填量が多いにもかかわらず、汚泥発生率は22%と高かった。結果を表1に示す。
(Comparative Example 2)
Baffle plates were installed in all of the first to fourth stages of the activated sludge apparatus used in Comparative Example 1. Otherwise, the same procedure as in Comparative Example 1 was performed. After acclimatization, BOD volumetric load 2 kg / m 3 · day was continued for about 2 weeks, and then filamentous bulking occurred. Thereafter, the BOD volumetric load was lowered to 1.5 kg / m 3 · day. Compared with Examples 1 and 2, the sludge generation rate was as high as 22% despite a low BOD volumetric load and a large amount of fixed carrier. The results are shown in Table 1.
(比較例3)
実施例1に用いた活性汚泥装置の生物処理槽からバッフル板を取外した。それ以外は、実施例1と同様に行った。約3週間の馴養後、BOD容積負荷を2kg/m3・日の一定とした。バッフル板が無いためか、固定担体から流出する原生動物及び後生動物が観測され、汚泥発生率も25%と高かった。結果を表1に示す。
(Comparative Example 3)
The baffle plate was removed from the biological treatment tank of the activated sludge apparatus used in Example 1. Otherwise, the same procedure as in Example 1 was performed. After acclimatization for about 3 weeks, the BOD volumetric load was kept constant at 2 kg / m 3 · day. Probable animals and metazoans that flow out of the fixed carrier were observed because of the absence of baffle plates, and the sludge generation rate was as high as 25%. The results are shown in Table 1.
表1に示す結果から、本発明の活性汚泥装置は、比較例より固定担体充填量が少ないにも関わらず、BOD容積負荷が大きくとれ、さらに汚泥発生率が少ないことが理解できる。 From the results shown in Table 1, it can be understood that the activated sludge apparatus of the present invention has a large BOD volume load and a low sludge generation rate, although the fixed carrier filling amount is smaller than that of the comparative example.
本発明は、食品や化学等の産業排水、酪農施設等からの排水、レストラン厨房や家庭等からの排水、下水やし尿等の公共排水等に利用可能である。 INDUSTRIAL APPLICABILITY The present invention can be used for industrial wastewater such as food and chemicals, wastewater from dairy facilities, wastewater from restaurant kitchens and households, and public wastewater such as sewage and human waste.
1 曝気槽
2 生物処理槽
3 沈殿槽
4 固定担体
5 バッフル板
6 汚泥返送管
7 散気管
8 有機物含有水
9 処理水
10 撹拌装置
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JP2013141640A (en) * | 2012-01-11 | 2013-07-22 | Kurita Water Ind Ltd | Apparatus and method for biologically treating organic waste water |
WO2013140925A1 (en) * | 2012-03-23 | 2013-09-26 | 水ing株式会社 | Treatment method and treatment device for oil-containing waste water |
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