JP5904937B2 - 変性ＺｎＯナノ粒子 - Google Patents
変性ＺｎＯナノ粒子 Download PDFInfo
- Publication number
- JP5904937B2 JP5904937B2 JP2012516694A JP2012516694A JP5904937B2 JP 5904937 B2 JP5904937 B2 JP 5904937B2 JP 2012516694 A JP2012516694 A JP 2012516694A JP 2012516694 A JP2012516694 A JP 2012516694A JP 5904937 B2 JP5904937 B2 JP 5904937B2
- Authority
- JP
- Japan
- Prior art keywords
- zinc oxide
- oxide nanoparticles
- zno
- modified
- nanoparticles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000002105 nanoparticle Substances 0.000 title claims description 139
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 277
- 239000011787 zinc oxide Substances 0.000 claims description 115
- 238000000034 method Methods 0.000 claims description 67
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 55
- 239000002904 solvent Substances 0.000 claims description 48
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 claims description 40
- 239000000725 suspension Substances 0.000 claims description 38
- 150000001412 amines Chemical class 0.000 claims description 28
- 229910021529 ammonia Inorganic materials 0.000 claims description 26
- 229920003023 plastic Polymers 0.000 claims description 26
- 239000004033 plastic Substances 0.000 claims description 26
- 239000000654 additive Substances 0.000 claims description 21
- 238000006243 chemical reaction Methods 0.000 claims description 20
- 230000008569 process Effects 0.000 claims description 20
- 150000001282 organosilanes Chemical class 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 239000011368 organic material Substances 0.000 claims description 17
- 239000003381 stabilizer Substances 0.000 claims description 16
- 239000006096 absorbing agent Substances 0.000 claims description 15
- 239000003973 paint Substances 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 11
- 230000009471 action Effects 0.000 claims description 9
- 239000002798 polar solvent Substances 0.000 claims description 9
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 claims description 9
- 150000002148 esters Chemical class 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 6
- 239000003960 organic solvent Substances 0.000 claims description 6
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 4
- 150000004756 silanes Chemical class 0.000 claims description 4
- 230000000087 stabilizing effect Effects 0.000 claims description 4
- 150000003141 primary amines Chemical class 0.000 claims description 3
- 239000005022 packaging material Substances 0.000 claims description 2
- UQMOLLPKNHFRAC-UHFFFAOYSA-N tetrabutyl silicate Chemical compound CCCCO[Si](OCCCC)(OCCCC)OCCCC UQMOLLPKNHFRAC-UHFFFAOYSA-N 0.000 claims description 2
- 229940095070 tetrapropyl orthosilicate Drugs 0.000 claims description 2
- ZQZCOBSUOFHDEE-UHFFFAOYSA-N tetrapropyl silicate Chemical compound CCCO[Si](OCCC)(OCCC)OCCC ZQZCOBSUOFHDEE-UHFFFAOYSA-N 0.000 claims description 2
- 229910018557 Si O Inorganic materials 0.000 claims 1
- 230000007717 exclusion Effects 0.000 claims 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 claims 1
- -1 siloxy compound Chemical class 0.000 description 75
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 48
- 239000002245 particle Substances 0.000 description 48
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 38
- 239000000203 mixture Substances 0.000 description 36
- 229920000642 polymer Polymers 0.000 description 35
- 239000000243 solution Substances 0.000 description 31
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 24
- 229920000620 organic polymer Polymers 0.000 description 19
- 238000000576 coating method Methods 0.000 description 18
- 239000011248 coating agent Substances 0.000 description 17
- 239000007787 solid Substances 0.000 description 17
- 238000002156 mixing Methods 0.000 description 16
- 239000000843 powder Substances 0.000 description 16
- 150000001875 compounds Chemical class 0.000 description 15
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 14
- 238000009472 formulation Methods 0.000 description 13
- 239000012669 liquid formulation Substances 0.000 description 12
- 239000001993 wax Substances 0.000 description 12
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 11
- 235000011114 ammonium hydroxide Nutrition 0.000 description 11
- 239000006185 dispersion Substances 0.000 description 11
- 229910044991 metal oxide Inorganic materials 0.000 description 11
- 150000004706 metal oxides Chemical class 0.000 description 11
- 230000001699 photocatalysis Effects 0.000 description 11
- 239000000377 silicon dioxide Substances 0.000 description 11
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 9
- 239000011159 matrix material Substances 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 8
- 239000004698 Polyethylene Substances 0.000 description 8
- 230000003993 interaction Effects 0.000 description 8
- 230000003287 optical effect Effects 0.000 description 8
- 229920000573 polyethylene Polymers 0.000 description 8
- 239000011701 zinc Substances 0.000 description 8
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 7
- 239000012964 benzotriazole Substances 0.000 description 7
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 7
- 239000004094 surface-active agent Substances 0.000 description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- 229910004298 SiO 2 Inorganic materials 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 230000015556 catabolic process Effects 0.000 description 6
- 238000006731 degradation reaction Methods 0.000 description 6
- 239000000975 dye Substances 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 6
- FZMJEGJVKFTGMU-UHFFFAOYSA-N triethoxy(octadecyl)silane Chemical compound CCCCCCCCCCCCCCCCCC[Si](OCC)(OCC)OCC FZMJEGJVKFTGMU-UHFFFAOYSA-N 0.000 description 6
- 239000004743 Polypropylene Substances 0.000 description 5
- 230000000996 additive effect Effects 0.000 description 5
- CBHOOMGKXCMKIR-UHFFFAOYSA-N azane;methanol Chemical compound N.OC CBHOOMGKXCMKIR-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 239000002537 cosmetic Substances 0.000 description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 5
- 229920000098 polyolefin Polymers 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000002834 transmittance Methods 0.000 description 5
- ONTODYXHFBKCDK-UHFFFAOYSA-N 2-(2,4-dimethylphenyl)-1,3,5-triazine Chemical compound CC1=CC(C)=CC=C1C1=NC=NC=N1 ONTODYXHFBKCDK-UHFFFAOYSA-N 0.000 description 4
- FMRHJJZUHUTGKE-UHFFFAOYSA-N Ethylhexyl salicylate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1O FMRHJJZUHUTGKE-UHFFFAOYSA-N 0.000 description 4
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 4
- 239000004952 Polyamide Substances 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000002296 dynamic light scattering Methods 0.000 description 4
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 4
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 4
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- 229920002647 polyamide Polymers 0.000 description 4
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- 229920000515 polycarbonate Polymers 0.000 description 4
- 239000011164 primary particle Substances 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 125000006850 spacer group Chemical group 0.000 description 4
- 125000001424 substituent group Chemical group 0.000 description 4
- 125000003542 3-methylbutan-2-yl group Chemical group [H]C([H])([H])C([H])(*)C([H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- 239000004594 Masterbatch (MB) Substances 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- 238000006887 Ullmann reaction Methods 0.000 description 3
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 150000001343 alkyl silanes Chemical class 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 3
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 125000004430 oxygen atom Chemical group O* 0.000 description 3
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
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- 239000011541 reaction mixture Substances 0.000 description 3
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
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- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- YZYKBQUWMPUVEN-UHFFFAOYSA-N zafuleptine Chemical compound OC(=O)CCCCCC(C(C)C)NCC1=CC=C(F)C=C1 YZYKBQUWMPUVEN-UHFFFAOYSA-N 0.000 description 3
- OIQXFRANQVWXJF-QBFSEMIESA-N (2z)-2-benzylidene-4,7,7-trimethylbicyclo[2.2.1]heptan-3-one Chemical compound CC1(C)C2CCC1(C)C(=O)\C2=C/C1=CC=CC=C1 OIQXFRANQVWXJF-QBFSEMIESA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- CGXOAAMIQPDTPE-UHFFFAOYSA-N 1,2,2,6,6-pentamethylpiperidin-4-amine Chemical compound CN1C(C)(C)CC(N)CC1(C)C CGXOAAMIQPDTPE-UHFFFAOYSA-N 0.000 description 2
- NWHNXXMYEICZAT-UHFFFAOYSA-N 1,2,2,6,6-pentamethylpiperidin-4-ol Chemical compound CN1C(C)(C)CC(O)CC1(C)C NWHNXXMYEICZAT-UHFFFAOYSA-N 0.000 description 2
- BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical class C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- FTVFPPFZRRKJIH-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidin-4-amine Chemical compound CC1(C)CC(N)CC(C)(C)N1 FTVFPPFZRRKJIH-UHFFFAOYSA-N 0.000 description 2
- VDVUCLWJZJHFAV-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidin-4-ol Chemical compound CC1(C)CC(O)CC(C)(C)N1 VDVUCLWJZJHFAV-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- STEYNUVPFMIUOY-UHFFFAOYSA-N 4-Hydroxy-1-(2-hydroxyethyl)-2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CC(O)CC(C)(C)N1CCO STEYNUVPFMIUOY-UHFFFAOYSA-N 0.000 description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 2
- XUXUHDYTLNCYQQ-UHFFFAOYSA-N 4-amino-TEMPO Chemical group CC1(C)CC(N)CC(C)(C)N1[O] XUXUHDYTLNCYQQ-UHFFFAOYSA-N 0.000 description 2
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- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
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- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
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- BLFLLBZGZJTVJG-UHFFFAOYSA-N benzocaine Chemical compound CCOC(=O)C1=CC=C(N)C=C1 BLFLLBZGZJTVJG-UHFFFAOYSA-N 0.000 description 2
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- 125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
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- KEMQGTRYUADPNZ-UHFFFAOYSA-N heptadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)=O KEMQGTRYUADPNZ-UHFFFAOYSA-N 0.000 description 2
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- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 2
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- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/04—Compounds of zinc
- C09C1/043—Zinc oxide
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
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- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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| EP2501472A1 (de) * | 2009-11-20 | 2012-09-26 | Basf Se | Mehrlagenkatalysator zur herstellung von carbonsäuren und/oder carbonsäureanhydriden mit vanadiumantimonat in wenigstens einer katalysatorlage und verfahren zur herstellung von phthalsäureanhydrid mit niedriger hotspottemperatur |
| US20110230668A1 (en) * | 2010-03-19 | 2011-09-22 | Basf Se | Catalyst for gas phase oxidations based on low-sulfur and low-calcium titanium dioxide |
| TW201206896A (en) | 2010-04-13 | 2012-02-16 | Basf Se | Process for controlling a gas phase oxidation reactor for preparation of phthalic anhydride |
| US8859459B2 (en) | 2010-06-30 | 2014-10-14 | Basf Se | Multilayer catalyst for preparing phthalic anhydride and process for preparing phthalic anhydride |
| US9212157B2 (en) | 2010-07-30 | 2015-12-15 | Basf Se | Catalyst for the oxidation of o-xylene and/or naphthalene to phthalic anhydride |
| JP5874436B2 (ja) * | 2012-02-22 | 2016-03-02 | 堺化学工業株式会社 | 酸化亜鉛粒子及びその製造方法 |
| US9915757B1 (en) | 2013-06-24 | 2018-03-13 | The Research Foundation For The State University Of New York | Increased thermal stabilization of optical absorbers |
| GB2518202B (en) * | 2013-09-13 | 2017-01-04 | Shayonano Singapore Pte Ltd | Composite pigments |
| JP5846322B2 (ja) * | 2013-09-30 | 2016-01-20 | 住友大阪セメント株式会社 | 無機粒子分散液、無機粒子含有組成物、塗膜、塗膜付きプラスチック基材、表示装置 |
| EP3083491A1 (en) | 2013-12-16 | 2016-10-26 | Council of Scientific and Industrial Research | Functionalized zinc oxide nanoparticles for photocatalytic water splitting |
| WO2016050277A1 (en) * | 2014-09-30 | 2016-04-07 | Kemijski inštitut | Process for the preparation of functionalized zinc oxide nanoparticulate powders |
| US20190218370A1 (en) * | 2016-06-15 | 2019-07-18 | Quarzwerke Gmbh | Filled plastic material |
| CN106366701B (zh) * | 2016-08-24 | 2018-02-27 | 江苏爱特恩高分子材料有限公司 | 一种高分散氧化锌的制备方法 |
| CN107089677B (zh) * | 2017-06-07 | 2018-07-10 | 首都医科大学宣武医院 | 基于丝素蛋白生物模板调控的氧化锌纳米颗粒制备方法 |
| US11702345B2 (en) * | 2017-12-27 | 2023-07-18 | Rhodia Operations | Silica suspensions |
| CN114920281A (zh) * | 2022-05-27 | 2022-08-19 | 上饶师范学院 | 一种球形纳米氧化锌的制备方法 |
| CN116355280B (zh) * | 2023-02-28 | 2025-04-04 | 浙江恒逸石化研究院有限公司 | 一种聚酯原位聚合用纳米氧化锌分散液及其制备方法 |
| CN116479539B (zh) * | 2023-03-13 | 2024-09-13 | 浙江恒逸石化研究院有限公司 | 一种高分散性聚酯纤维用氧化锌抗菌分散液的制备方法 |
| CN117778078A (zh) * | 2023-12-18 | 2024-03-29 | 安徽省含山县锦华氧化锌厂 | 一种水基润滑剂高分散纳米氧化锌的制备方法 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| LU87030A1 (fr) | 1987-10-28 | 1989-05-08 | Oreal | Utilisation en cosmetique de nouvelles substances a titre de reflecteurs du rayonnement infrarouge,compositions cosmetiques les contenant et leur utilisation pour la protection de l'epiderme humain contre le rayonnement infrarouge |
| DE3841957A1 (de) | 1988-12-14 | 1990-06-28 | Bosch Gmbh Robert | Antiblockierregelsystem |
| TW221381B (enExample) | 1992-04-28 | 1994-03-01 | Du Pont | |
| JPH11209695A (ja) * | 1998-01-27 | 1999-08-03 | Jsr Corp | コーティング用組成物および硬化体 |
| DE19805121A1 (de) | 1998-02-09 | 1999-08-12 | Basf Ag | Verfahren zur Herstellung farbstoffenthaltender, wässriger Polymerisatdispersionen |
| FI109324B (fi) | 1998-11-06 | 2002-07-15 | Rehuraisio Oy | Rehu ja menetelmä sen valmistamiseksi |
| CN1312233C (zh) | 1999-01-11 | 2007-04-25 | 昭和电工株式会社 | 化妆料、表面疏水化二氧化硅被覆金属氧化物粒子、二氧化硅被覆金属氧化物溶胶、以及它们的制法 |
| ITMI992438A1 (it) | 1999-11-23 | 2001-05-23 | Great Lakes Chemical Europ | Miscele stabilizzanti per polimeri organici |
| DE10018429A1 (de) * | 2000-04-14 | 2001-10-18 | Bayer Ag | Kunststoffe die mit zinkoxidhaltigen, abriebfesten Multischichten stabilisiert sind |
| WO2001093812A1 (fr) * | 2000-06-05 | 2001-12-13 | Showa Denko K.K. | Préparation cosmétique |
| US6500415B2 (en) * | 2000-06-05 | 2002-12-31 | Showa Denko K.K. | Cosmetic composition |
| DE10046927A1 (de) | 2000-09-21 | 2002-04-25 | Basf Ag | Farbmittelhaltige wässrige Polymerdispersion |
| DE50104223D1 (de) | 2001-08-08 | 2004-11-25 | Degussa | Mit Siliziumdioxid umhüllte Metalloxidpartikel |
| US7347986B2 (en) * | 2001-09-14 | 2008-03-25 | Showa Denko K.K. | Silica-coated mixed crystal oxide particle, production process thereof and cosmetic material using the same |
| EP1511802B1 (en) | 2002-06-05 | 2010-09-08 | Showa Denko K.K. | Powder comprising silica-coated zinc oxide, organic polymer composition containing the powder and shaped article thereof |
| DE10244212A1 (de) * | 2002-09-23 | 2004-03-25 | Bayer Aktiengesellschaft | Zinkoxiddispersionen in halogen- und wasserfreien Dispersionsmedien |
| DE102005056622A1 (de) * | 2005-11-25 | 2007-05-31 | Merck Patent Gmbh | Nanopartikel |
| JP2007277072A (ja) * | 2006-03-16 | 2007-10-25 | Jsr Corp | 酸化物微粒子分散体およびその製造方法 |
| DE102006024288A1 (de) | 2006-05-24 | 2007-11-29 | Merck Patent Gmbh | Nanopartikel |
| DE102006051634A1 (de) * | 2006-11-02 | 2008-05-08 | Evonik Degussa Gmbh | Oberflächenmodifizierte Zink-Silicium-Oxidpartikel |
| ATE507267T1 (de) * | 2007-04-13 | 2011-05-15 | Asahi Glass Co Ltd | Verfahren zur herstellung einer mit hydrophobiertem siliziumoxid belegter metalloxidpartikel |
| CN100554340C (zh) * | 2007-10-15 | 2009-10-28 | 江苏河海纳米科技股份有限公司 | 一种无机粉体有机表面改性的方法 |
| EP2376564A2 (de) * | 2008-12-12 | 2011-10-19 | Basf Se | Dispersionen enthaltend funktionalisierte oxidische nanopartikel |
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2010
- 2010-06-22 WO PCT/EP2010/058798 patent/WO2010149646A1/de not_active Ceased
- 2010-06-22 CN CN201080028584.3A patent/CN102459471B/zh not_active Expired - Fee Related
- 2010-06-22 EP EP10725770A patent/EP2445974A1/de not_active Withdrawn
- 2010-06-22 BR BRPI1014426A patent/BRPI1014426A2/pt not_active IP Right Cessation
- 2010-06-22 US US13/379,247 patent/US20120097068A1/en not_active Abandoned
- 2010-06-22 JP JP2012516694A patent/JP5904937B2/ja not_active Expired - Fee Related
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|---|---|
| MX2011013219A (es) | 2012-01-20 |
| MX324453B (es) | 2014-10-14 |
| US20120097068A1 (en) | 2012-04-26 |
| BRPI1014426A2 (pt) | 2016-04-12 |
| WO2010149646A1 (de) | 2010-12-29 |
| CN102459471B (zh) | 2014-08-13 |
| EP2445974A1 (de) | 2012-05-02 |
| CN102459471A (zh) | 2012-05-16 |
| JP2012530671A (ja) | 2012-12-06 |
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