JP5855106B2 - ε−カプロラクトン及び１，６−ヘキサンジオールの製造法 - Google Patents

ε−カプロラクトン及び１，６−ヘキサンジオールの製造法 Download PDF

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Publication number
JP5855106B2
JP5855106B2 JP2013527563A JP2013527563A JP5855106B2 JP 5855106 B2 JP5855106 B2 JP 5855106B2 JP 2013527563 A JP2013527563 A JP 2013527563A JP 2013527563 A JP2013527563 A JP 2013527563A JP 5855106 B2 JP5855106 B2 JP 5855106B2
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Prior art keywords
alcohol
hydrogenation
hexanediol
acid
caprolactone
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JP2013527563A
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Japanese (ja)
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JP2013537882A5 (enExample
JP2013537882A (ja
Inventor
アビィヤール オリヴィエ
アビィヤール オリヴィエ
ブロイニンガー ダニエル
ブロイニンガー ダニエル
クレチュマー エヴァ
クレチュマー エヴァ
ピンコス ロルフ
ピンコス ロルフ
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BASF SE
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BASF SE
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D313/00—Heterocyclic compounds containing rings of more than six members having one oxygen atom as the only ring hetero atom
    • C07D313/02—Seven-membered rings
    • C07D313/04—Seven-membered rings not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/86—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by liquid-liquid treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • C07C51/316—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with oxides of nitrogen or nitrogen-containing mineral acids

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pyrane Compounds (AREA)
JP2013527563A 2010-09-08 2011-09-05 ε−カプロラクトン及び１，６−ヘキサンジオールの製造法 Expired - Fee Related JP5855106B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10175795.3 2010-09-08
EP10175795 2010-09-08
PCT/EP2011/065276 WO2012032002A2 (de) 2010-09-08 2011-09-05 VERFAHREN ZUR HERSTELLUNG VON ε-CAPROLACTON UND 1,6-HEXANDIOL

Publications (3)

Publication Number Publication Date
JP2013537882A JP2013537882A (ja) 2013-10-07
JP2013537882A5 JP2013537882A5 (enExample) 2014-10-23
JP5855106B2 true JP5855106B2 (ja) 2016-02-09

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ID=44534445

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2013527563A Expired - Fee Related JP5855106B2 (ja) 2010-09-08 2011-09-05 ε−カプロラクトン及び１，６−ヘキサンジオールの製造法

Country Status (8)

Country Link
EP (1) EP2614056B1 (enExample)
JP (1) JP5855106B2 (enExample)
CN (1) CN103080098B (enExample)
ES (1) ES2506465T3 (enExample)
RU (1) RU2571082C2 (enExample)
SG (1) SG187942A1 (enExample)
TW (1) TWI496764B (enExample)
WO (2) WO2012038848A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2598616B2 (ja) 1994-09-05 1997-04-09 晃立工業株式会社 流紋岩質溶結凝灰岩を破砕してなる細骨材及びその製造方法

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CL2013003356A1 (es) 2013-11-22 2014-08-08 Univ Pontificia Catolica Chile Mutantes del gen que codifica la enzina fenilacetona monooxigenasa (pamo) aislada de termofibida fusca o thermononospora fusca con sustitucines en las posiciones 93,94,y 440 (n,d y f, respectivamente) y combinaciones especificas de las posiciones 441,442,443 y/o 444(g o d,p o e,t,v,i o w y q respectivamente ) con alto rendimiento como catalizadores en la conversion de ciclohexanona a epailon-caprolactona y alta estabilidad termica , adn condificante y secuencias amino acidicas codificadas.
GB202109710D0 (en) 2021-07-05 2021-08-18 Johnson Matthey Davy Technologies Ltd Separation process for the production of C5 or C6 alkanediol

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3524892A (en) 1962-11-16 1970-08-18 Celanese Corp Hexanediol from cyclohexane
DE1618143C3 (de) 1967-04-27 1975-08-21 Basf Ag, 6700 Ludwigshafen Verfahren zur Gewinnung von epsilon-Hydroxycapronsäurelacton und von Alkandicarbonsäuren
US3597330A (en) * 1967-04-27 1971-08-03 Basf Ag Recovery of epsilon-caprolactone and alkane dicarboxylic acid by acid treatment and vacuum distillation
FR1585375A (enExample) 1968-10-11 1970-01-16
US3624258A (en) * 1969-03-22 1971-11-30 Teijin Ltd Process for the preparation of {68 -caprolactone
DE3823213A1 (de) * 1988-07-08 1990-01-11 Basf Ag Verfahren zur herstellung von caprolacton
DE4141199A1 (de) 1991-12-13 1993-06-17 Sued Chemie Ag Chromfreier katalysator fuer die hydrierung von organischen verbindungen, die die carbonylfunktionen enthalten
DE19607954A1 (de) 1996-03-01 1997-09-04 Basf Ag Verfahren zur Herstellung von 1,6-Hexandiol und Caprolacton
MY118128A (en) * 1996-03-01 2004-09-30 Basf Ag The preparation of 1, 6-hexanediol and caprolactone
FR2757154B1 (fr) 1996-12-12 2000-01-14 Rhone Poulenc Fibres Procede de preparation de diacides a partir des eaux de lavage des produits d'oxydation du cyclohexane
DE19750532A1 (de) * 1997-11-14 1999-05-20 Basf Ag Verfahren zur Herstellung von 1,6-Hexandiol und 6-Hydroxycapronsäure bzw. deren Estern
GB9724480D0 (en) * 1997-11-19 1998-01-14 Hexagen Technology Limited Screening process
DE10313702A1 (de) 2003-03-27 2004-10-07 Basf Ag Katalysator und Verfahren zur Hydrierung von Carbonylverbindungen
DE102004033556A1 (de) 2004-07-09 2006-02-16 Basf Ag Katalysatorformkörper und Verfahren zur Hydrierung von Carbonylverbindungen
DE102005032726A1 (de) 2005-07-13 2007-01-18 Basf Ag Katalysator und Verfahren zur Hydrierung von Carbonylverbindungen
WO2008152001A1 (de) * 2007-06-14 2008-12-18 Basf Se VERFAHREN ZUR HERSTELLUNG ε-CAPROLACTON
US8247580B2 (en) * 2007-11-05 2012-08-21 Basf Se Process for preparing ε-caprolactone

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2598616B2 (ja) 1994-09-05 1997-04-09 晃立工業株式会社 流紋岩質溶結凝灰岩を破砕してなる細骨材及びその製造方法

Also Published As

Publication number Publication date
TW201229014A (en) 2012-07-16
RU2571082C2 (ru) 2015-12-20
SG187942A1 (en) 2013-03-28
TWI496764B (zh) 2015-08-21
WO2012032002A3 (de) 2012-05-10
WO2012032002A2 (de) 2012-03-15
CN103080098A (zh) 2013-05-01
EP2614056B1 (de) 2014-07-23
ES2506465T3 (es) 2014-10-13
CN103080098B (zh) 2014-11-05
RU2013115238A (ru) 2014-10-20
EP2614056A2 (de) 2013-07-17
WO2012038848A1 (en) 2012-03-29
JP2013537882A (ja) 2013-10-07

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