RU2571082C2 - СПОСОБ ПОЛУЧЕНИЯ ε-КАПРОЛАКТОНА И 1,6-ГЕКСАНДИОЛА - Google Patents

СПОСОБ ПОЛУЧЕНИЯ ε-КАПРОЛАКТОНА И 1,6-ГЕКСАНДИОЛА Download PDF

Info

Publication number
RU2571082C2
RU2571082C2 RU2013115238/04A RU2013115238A RU2571082C2 RU 2571082 C2 RU2571082 C2 RU 2571082C2 RU 2013115238/04 A RU2013115238/04 A RU 2013115238/04A RU 2013115238 A RU2013115238 A RU 2013115238A RU 2571082 C2 RU2571082 C2 RU 2571082C2
Authority
RU
Russia
Prior art keywords
hydrogenation
hexanediol
caprolactone
alcohol
alcohols
Prior art date
Application number
RU2013115238/04A
Other languages
English (en)
Russian (ru)
Other versions
RU2013115238A (ru
Inventor
Оливье АБИЙАР
Даниэль БРОЙНИНГЕР
Ева КРЕЧМАР
Рольф Пинкос
Original Assignee
Басф Се
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Басф Се filed Critical Басф Се
Publication of RU2013115238A publication Critical patent/RU2013115238A/ru
Application granted granted Critical
Publication of RU2571082C2 publication Critical patent/RU2571082C2/ru

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D313/00—Heterocyclic compounds containing rings of more than six members having one oxygen atom as the only ring hetero atom
    • C07D313/02—Seven-membered rings
    • C07D313/04—Seven-membered rings not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/86—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by liquid-liquid treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • C07C51/316—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with oxides of nitrogen or nitrogen-containing mineral acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pyrane Compounds (AREA)
RU2013115238/04A 2010-09-08 2011-09-05 СПОСОБ ПОЛУЧЕНИЯ ε-КАПРОЛАКТОНА И 1,6-ГЕКСАНДИОЛА RU2571082C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10175795.3 2010-09-08
EP10175795 2010-09-08
PCT/EP2011/065276 WO2012032002A2 (de) 2010-09-08 2011-09-05 VERFAHREN ZUR HERSTELLUNG VON ε-CAPROLACTON UND 1,6-HEXANDIOL

Publications (2)

Publication Number Publication Date
RU2013115238A RU2013115238A (ru) 2014-10-20
RU2571082C2 true RU2571082C2 (ru) 2015-12-20

Family

ID=44534445

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2013115238/04A RU2571082C2 (ru) 2010-09-08 2011-09-05 СПОСОБ ПОЛУЧЕНИЯ ε-КАПРОЛАКТОНА И 1,6-ГЕКСАНДИОЛА

Country Status (8)

Country Link
EP (1) EP2614056B1 (enExample)
JP (1) JP5855106B2 (enExample)
CN (1) CN103080098B (enExample)
ES (1) ES2506465T3 (enExample)
RU (1) RU2571082C2 (enExample)
SG (1) SG187942A1 (enExample)
TW (1) TWI496764B (enExample)
WO (2) WO2012038848A1 (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2598616B2 (ja) 1994-09-05 1997-04-09 晃立工業株式会社 流紋岩質溶結凝灰岩を破砕してなる細骨材及びその製造方法
CL2013003356A1 (es) 2013-11-22 2014-08-08 Univ Pontificia Catolica Chile Mutantes del gen que codifica la enzina fenilacetona monooxigenasa (pamo) aislada de termofibida fusca o thermononospora fusca con sustitucines en las posiciones 93,94,y 440 (n,d y f, respectivamente) y combinaciones especificas de las posiciones 441,442,443 y/o 444(g o d,p o e,t,v,i o w y q respectivamente ) con alto rendimiento como catalizadores en la conversion de ciclohexanona a epailon-caprolactona y alta estabilidad termica , adn condificante y secuencias amino acidicas codificadas.
GB202109710D0 (en) 2021-07-05 2021-08-18 Johnson Matthey Davy Technologies Ltd Separation process for the production of C5 or C6 alkanediol

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU177867A1 (ru) * Способ получения гександиола-1,6
EP0349861B1 (de) * 1988-07-08 1992-08-26 BASF Aktiengesellschaft Verfahren zur Herstellung von Caprolacton
WO1997031883A1 (de) * 1996-03-01 1997-09-04 Basf Aktiengesellschaft Verfahren zur herstellung von 1,6-hexandiol und caprolacton
WO2008152001A1 (de) * 2007-06-14 2008-12-18 Basf Se VERFAHREN ZUR HERSTELLUNG ε-CAPROLACTON

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3524892A (en) 1962-11-16 1970-08-18 Celanese Corp Hexanediol from cyclohexane
DE1618143C3 (de) 1967-04-27 1975-08-21 Basf Ag, 6700 Ludwigshafen Verfahren zur Gewinnung von epsilon-Hydroxycapronsäurelacton und von Alkandicarbonsäuren
US3597330A (en) * 1967-04-27 1971-08-03 Basf Ag Recovery of epsilon-caprolactone and alkane dicarboxylic acid by acid treatment and vacuum distillation
FR1585375A (enExample) 1968-10-11 1970-01-16
US3624258A (en) * 1969-03-22 1971-11-30 Teijin Ltd Process for the preparation of {68 -caprolactone
DE4141199A1 (de) 1991-12-13 1993-06-17 Sued Chemie Ag Chromfreier katalysator fuer die hydrierung von organischen verbindungen, die die carbonylfunktionen enthalten
DE19607954A1 (de) 1996-03-01 1997-09-04 Basf Ag Verfahren zur Herstellung von 1,6-Hexandiol und Caprolacton
FR2757154B1 (fr) 1996-12-12 2000-01-14 Rhone Poulenc Fibres Procede de preparation de diacides a partir des eaux de lavage des produits d'oxydation du cyclohexane
DE19750532A1 (de) * 1997-11-14 1999-05-20 Basf Ag Verfahren zur Herstellung von 1,6-Hexandiol und 6-Hydroxycapronsäure bzw. deren Estern
GB9724480D0 (en) * 1997-11-19 1998-01-14 Hexagen Technology Limited Screening process
DE10313702A1 (de) 2003-03-27 2004-10-07 Basf Ag Katalysator und Verfahren zur Hydrierung von Carbonylverbindungen
DE102004033556A1 (de) 2004-07-09 2006-02-16 Basf Ag Katalysatorformkörper und Verfahren zur Hydrierung von Carbonylverbindungen
DE102005032726A1 (de) 2005-07-13 2007-01-18 Basf Ag Katalysator und Verfahren zur Hydrierung von Carbonylverbindungen
US8247580B2 (en) * 2007-11-05 2012-08-21 Basf Se Process for preparing ε-caprolactone

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU177867A1 (ru) * Способ получения гександиола-1,6
EP0349861B1 (de) * 1988-07-08 1992-08-26 BASF Aktiengesellschaft Verfahren zur Herstellung von Caprolacton
WO1997031883A1 (de) * 1996-03-01 1997-09-04 Basf Aktiengesellschaft Verfahren zur herstellung von 1,6-hexandiol und caprolacton
WO2008152001A1 (de) * 2007-06-14 2008-12-18 Basf Se VERFAHREN ZUR HERSTELLUNG ε-CAPROLACTON

Also Published As

Publication number Publication date
TW201229014A (en) 2012-07-16
SG187942A1 (en) 2013-03-28
TWI496764B (zh) 2015-08-21
WO2012032002A3 (de) 2012-05-10
WO2012032002A2 (de) 2012-03-15
CN103080098A (zh) 2013-05-01
EP2614056B1 (de) 2014-07-23
ES2506465T3 (es) 2014-10-13
CN103080098B (zh) 2014-11-05
RU2013115238A (ru) 2014-10-20
EP2614056A2 (de) 2013-07-17
WO2012038848A1 (en) 2012-03-29
JP2013537882A (ja) 2013-10-07
JP5855106B2 (ja) 2016-02-09

Similar Documents

Publication Publication Date Title
JP4107396B2 (ja) １，６―ヘキサンジオールおよびカプロラクトンの製造方法
US6008418A (en) Process for preparing 1,6 hexanediol with a level of purity over 99%
US8759594B2 (en) Method for producing 1,6-hexanediol by hydrogenation of oligo- and polyesters
JP5566450B2 (ja) １，６−ヘキサンジオールおよびカプロラクトンの製造方法
JP5586686B2 (ja) １，６−ヘキサンジオールの製造方法
US20120059174A1 (en) Process for preparing epsilon-caprolactone and 1,6-hexanediol
JP5549594B2 (ja) 高純度の１，６−ヘキサンジオール及びその製造方法
US20100168445A1 (en) Process for preparing epsilon-caprolactone
CN101848904B (zh) 生产ε-己内酯的方法
US20100256398A1 (en) Process for preparing epsilon-caprolactone
RU2571082C2 (ru) СПОСОБ ПОЛУЧЕНИЯ ε-КАПРОЛАКТОНА И 1,6-ГЕКСАНДИОЛА
US20110263907A1 (en) Process for preparing 1,6-hexanediol
US6727395B1 (en) Method for producing hexanediol

Legal Events

Date Code Title Description
MM4A The patent is invalid due to non-payment of fees

Effective date: 20160906