JP5806226B2 - 加水分解に安定な多目的ポリマー - Google Patents

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Publication number

JP5806226B2

JP5806226B2 JP2012542148A JP2012542148A JP5806226B2 JP 5806226 B2 JP5806226 B2 JP 5806226B2 JP 2012542148 A JP2012542148 A JP 2012542148A JP 2012542148 A JP2012542148 A JP 2012542148A JP 5806226 B2 JP5806226 B2 JP 5806226B2

Authority

JP

Japan

Prior art keywords

monomer

polymer

polyethoxylated

acrylate

methacrylate

Prior art date

2009-12-01

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired - Fee Related

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• 229920000642 polymer Polymers 0.000 title claims description 267
• 239000000178 monomer Substances 0.000 claims description 435
• 239000000203 mixture Substances 0.000 claims description 205
• -1 2- (dimethylamino) propan-2-yl methacrylate Chemical compound 0.000 claims description 93
• 125000000217 alkyl group Chemical group 0.000 claims description 74
• NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 73
• 239000000047 product Substances 0.000 claims description 73
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 60
• 229920002554 vinyl polymer Polymers 0.000 claims description 60
• 150000002734 metacrylic acid derivatives Polymers 0.000 claims description 43
• 239000012986 chain transfer agent Substances 0.000 claims description 35
• 229920001296 polysiloxane Polymers 0.000 claims description 34
• 239000003381 stabilizer Substances 0.000 claims description 28
• 239000004094 surface-active agent Substances 0.000 claims description 28
• 150000003839 salts Chemical class 0.000 claims description 27
• BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 24
• 239000001257 hydrogen Substances 0.000 claims description 22
• 229910052739 hydrogen Inorganic materials 0.000 claims description 22
• 125000003118 aryl group Chemical group 0.000 claims description 21
• 239000003795 chemical substances by application Substances 0.000 claims description 20
• 238000004132 cross linking Methods 0.000 claims description 20
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 20
• GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 claims description 16
• 101150065749 Churc1 gene Proteins 0.000 claims description 16
• 102100038239 Protein Churchill Human genes 0.000 claims description 16
• 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 16
• 238000006243 chemical reaction Methods 0.000 claims description 15
• HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 claims description 14
• CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 12
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 12
• 125000003277 amino group Chemical group 0.000 claims description 12
• 150000003254 radicals Chemical class 0.000 claims description 12
• 229920006395 saturated elastomer Polymers 0.000 claims description 12
• JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 11
• 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 11
• 229920001400 block copolymer Polymers 0.000 claims description 11
• PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 11
• 125000001424 substituent group Chemical group 0.000 claims description 11
• NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 10
• IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 10
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 10
• 239000007795 chemical reaction product Substances 0.000 claims description 10
• 125000000753 cycloalkyl group Chemical group 0.000 claims description 10
• VVOKYOKVMKJIMT-UHFFFAOYSA-N [3-(dimethylamino)-2,2-dimethylpropyl] 2-methylprop-2-enoate Chemical compound CN(C)CC(C)(C)COC(=O)C(C)=C VVOKYOKVMKJIMT-UHFFFAOYSA-N 0.000 claims description 9
• 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 9
• 239000000463 material Substances 0.000 claims description 9
• 229920005604 random copolymer Polymers 0.000 claims description 9
• 239000000126 substance Substances 0.000 claims description 9
• SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 8
• GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims description 8
• VGAJYAOJRBZVNG-UHFFFAOYSA-N [2-(dimethylamino)-2-methylpropyl] 2-methylprop-2-enoate Chemical compound CN(C)C(C)(C)COC(=O)C(C)=C VGAJYAOJRBZVNG-UHFFFAOYSA-N 0.000 claims description 8
• 229920001519 homopolymer Polymers 0.000 claims description 8
• 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
• TVFWYUWNQVRQRG-UHFFFAOYSA-N 2,3,4-tris(2-phenylethenyl)phenol Chemical compound C=1C=CC=CC=1C=CC1=C(C=CC=2C=CC=CC=2)C(O)=CC=C1C=CC1=CC=CC=C1 TVFWYUWNQVRQRG-UHFFFAOYSA-N 0.000 claims description 7
• HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 7
• VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 7
• 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 7
• 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 7
• CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 7
• 239000011203 carbon fibre reinforced carbon Substances 0.000 claims description 7
• 239000004359 castor oil Substances 0.000 claims description 7
• 235000019438 castor oil Nutrition 0.000 claims description 7
• 235000012000 cholesterol Nutrition 0.000 claims description 7
• 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
• 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 7
• 239000000194 fatty acid Substances 0.000 claims description 7
• 229930195729 fatty acid Natural products 0.000 claims description 7
• ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 7
• 230000036541 health Effects 0.000 claims description 7
• 150000002431 hydrogen Chemical group 0.000 claims description 7
• 125000002819 montanyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 7
• HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 claims description 7
• 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 7
• 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 7
• 235000014698 Brassica juncea var multisecta Nutrition 0.000 claims description 6
• 235000006008 Brassica napus var napus Nutrition 0.000 claims description 6
• 240000000385 Brassica napus var. napus Species 0.000 claims description 6
• 235000006618 Brassica rapa subsp oleifera Nutrition 0.000 claims description 6
• 235000004977 Brassica sinapistrum Nutrition 0.000 claims description 6
• 238000009472 formulation Methods 0.000 claims description 6
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 6
• DABQKEQFLJIRHU-UHFFFAOYSA-N 2-Propenoic acid, 2-methyl-, 3,3,5-trimethylcyclohexyl ester Chemical compound CC1CC(OC(=O)C(C)=C)CC(C)(C)C1 DABQKEQFLJIRHU-UHFFFAOYSA-N 0.000 claims description 5
• 125000003545 alkoxy group Chemical group 0.000 claims description 5
• 239000002537 cosmetic Substances 0.000 claims description 5
• 150000004665 fatty acids Chemical class 0.000 claims description 5
• 239000002562 thickening agent Substances 0.000 claims description 5
• 229920001567 vinyl ester resin Polymers 0.000 claims description 5
• 239000003995 emulsifying agent Substances 0.000 claims description 4
• 239000000834 fixative Substances 0.000 claims description 4
• 239000002954 polymerization reaction product Substances 0.000 claims description 4
• 125000003358 C2-C20 alkenyl group Chemical group 0.000 claims description 3
• 239000004480 active ingredient Substances 0.000 claims description 3
• 125000002252 acyl group Chemical group 0.000 claims description 3
• 238000009792 diffusion process Methods 0.000 claims description 3
• 125000005843 halogen group Chemical group 0.000 claims description 3
• 150000003440 styrenes Chemical class 0.000 claims description 3
• 230000000844 anti-bacterial effect Effects 0.000 claims description 2
• 230000002421 anti-septic effect Effects 0.000 claims description 2
• 239000002216 antistatic agent Substances 0.000 claims description 2
• 230000003750 conditioning effect Effects 0.000 claims description 2
• 230000003340 mental effect Effects 0.000 claims description 2
• 230000008447 perception Effects 0.000 claims description 2
• 239000006254 rheological additive Substances 0.000 claims description 2
• 239000000375 suspending agent Substances 0.000 claims description 2
• 239000004599 antimicrobial Substances 0.000 claims 2
• 239000003899 bactericide agent Substances 0.000 claims 1
• 239000000022 bacteriostatic agent Substances 0.000 claims 1
• 239000000969 carrier Substances 0.000 claims 1
• 239000003906 humectant Substances 0.000 claims 1
• JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 39
• 238000006116 polymerization reaction Methods 0.000 description 38
• 239000000839 emulsion Substances 0.000 description 33
• 125000005842 heteroatom Chemical group 0.000 description 32
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 29
• 125000004432 carbon atom Chemical group C* 0.000 description 27
• 239000002253 acid Substances 0.000 description 26
• 150000001875 compounds Chemical class 0.000 description 23
• 239000000499 gel Substances 0.000 description 22
• 238000000034 method Methods 0.000 description 21
• 238000006460 hydrolysis reaction Methods 0.000 description 20
• 239000004816 latex Substances 0.000 description 19
• 229920000126 latex Polymers 0.000 description 19
• 238000007720 emulsion polymerization reaction Methods 0.000 description 18
• 229910052757 nitrogen Inorganic materials 0.000 description 18
• 230000007062 hydrolysis Effects 0.000 description 17
• 150000001412 amines Chemical class 0.000 description 16
• 229920001577 copolymer Polymers 0.000 description 16
• IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 15
• 238000012546 transfer Methods 0.000 description 15
• 150000002148 esters Chemical class 0.000 description 14
• 238000003860 storage Methods 0.000 description 14
• 239000003999 initiator Substances 0.000 description 13
• 230000008719 thickening Effects 0.000 description 13
• 239000002736 nonionic surfactant Substances 0.000 description 12
• 229920000151 polyglycol Polymers 0.000 description 12
• 239000010695 polyglycol Substances 0.000 description 12
• 238000012360 testing method Methods 0.000 description 11
• 125000000623 heterocyclic group Chemical group 0.000 description 10
• QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
• 239000000523 sample Substances 0.000 description 9
• 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 8
• ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical group C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 8
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
• WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
• 230000002378 acidificating effect Effects 0.000 description 8
• 125000000304 alkynyl group Chemical group 0.000 description 8
• 239000011324 bead Substances 0.000 description 8
• 239000011541 reaction mixture Substances 0.000 description 8
• 125000000923 (C1-C30) alkyl group Chemical group 0.000 description 7
• AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 7
• 125000005907 alkyl ester group Chemical group 0.000 description 7
• 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 7
• 238000005886 esterification reaction Methods 0.000 description 7
• 125000000524 functional group Chemical group 0.000 description 7
• 239000007787 solid Substances 0.000 description 7
• 239000000243 solution Substances 0.000 description 7
• OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 6
• OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 6
• WWJCRUKUIQRCGP-UHFFFAOYSA-N 3-(dimethylamino)propyl 2-methylprop-2-enoate Chemical compound CN(C)CCCOC(=O)C(C)=C WWJCRUKUIQRCGP-UHFFFAOYSA-N 0.000 description 6
• MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
• 229930006000 Sucrose Natural products 0.000 description 6
• QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
• DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 6
• 125000003342 alkenyl group Chemical group 0.000 description 6
• XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 6
• 239000003945 anionic surfactant Substances 0.000 description 6
• 239000007864 aqueous solution Substances 0.000 description 6
• 125000002837 carbocyclic group Chemical group 0.000 description 6
• 239000003054 catalyst Substances 0.000 description 6
• 238000004140 cleaning Methods 0.000 description 6
• 229920006037 cross link polymer Polymers 0.000 description 6
• 230000003301 hydrolyzing effect Effects 0.000 description 6
• 230000002209 hydrophobic effect Effects 0.000 description 6
• 230000008569 process Effects 0.000 description 6
• 238000006467 substitution reaction Methods 0.000 description 6
• 239000005720 sucrose Substances 0.000 description 6
• 150000003573 thiols Chemical class 0.000 description 6
• LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 5
• HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 description 5
• QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 5
• SOGAXMICEFXMKE-UHFFFAOYSA-N alpha-Methyl-n-butyl acrylate Natural products CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 5
• JQRRFDWXQOQICD-UHFFFAOYSA-N biphenylen-1-ylboronic acid Chemical compound C12=CC=CC=C2C2=C1C=CC=C2B(O)O JQRRFDWXQOQICD-UHFFFAOYSA-N 0.000 description 5
• 230000003197 catalytic effect Effects 0.000 description 5
• 150000002170 ethers Chemical class 0.000 description 5
• 229910052740 iodine Inorganic materials 0.000 description 5
• ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 5
• 229920005615 natural polymer Polymers 0.000 description 5
• 229920001223 polyethylene glycol Polymers 0.000 description 5
• 239000002685 polymerization catalyst Substances 0.000 description 5
• 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 5
• CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 5
• 238000003756 stirring Methods 0.000 description 5
• PYEWZDAEJUUIJX-UHFFFAOYSA-N 3-(dimethylamino)-2,2-dimethylpropan-1-ol Chemical compound CN(C)CC(C)(C)CO PYEWZDAEJUUIJX-UHFFFAOYSA-N 0.000 description 4
• PYSGFFTXMUWEOT-UHFFFAOYSA-N 3-(dimethylamino)propan-1-ol Chemical compound CN(C)CCCO PYSGFFTXMUWEOT-UHFFFAOYSA-N 0.000 description 4
• 239000004971 Cross linker Substances 0.000 description 4
• 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 4
• NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
• 239000002202 Polyethylene glycol Substances 0.000 description 4
• CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 4
• 238000002479 acid--base titration Methods 0.000 description 4
• 238000012644 addition polymerization Methods 0.000 description 4
• 150000001335 aliphatic alkanes Chemical group 0.000 description 4
• 125000002947 alkylene group Chemical group 0.000 description 4
• 150000001450 anions Chemical class 0.000 description 4
• 229910052799 carbon Inorganic materials 0.000 description 4
• 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 4
• 230000015556 catabolic process Effects 0.000 description 4
• 230000007423 decrease Effects 0.000 description 4
• 238000006731 degradation reaction Methods 0.000 description 4
• 239000008367 deionised water Substances 0.000 description 4
• 229910021641 deionized water Inorganic materials 0.000 description 4
• 230000000694 effects Effects 0.000 description 4
• 238000006266 etherification reaction Methods 0.000 description 4
• 229910052736 halogen Inorganic materials 0.000 description 4
• 150000002367 halogens Chemical group 0.000 description 4
• BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
• BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
• 238000002156 mixing Methods 0.000 description 4
• 125000004433 nitrogen atom Chemical group N* 0.000 description 4
• 125000005702 oxyalkylene group Chemical group 0.000 description 4
• 229910052760 oxygen Inorganic materials 0.000 description 4
• 125000004430 oxygen atom Chemical group O* 0.000 description 4
• 229910052698 phosphorus Inorganic materials 0.000 description 4
• 229920005862 polyol Polymers 0.000 description 4
• 150000003077 polyols Chemical class 0.000 description 4
• 238000001556 precipitation Methods 0.000 description 4
• 125000001453 quaternary ammonium group Chemical group 0.000 description 4
• 150000004756 silanes Chemical class 0.000 description 4
• 239000002904 solvent Substances 0.000 description 4
• 229910052717 sulfur Inorganic materials 0.000 description 4
• 239000000725 suspension Substances 0.000 description 4
• 230000009466 transformation Effects 0.000 description 4
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