JP5779974B2 - Method for producing original plate for pattern alignment layer for three-dimensional display - Google Patents

Description

  The present invention relates to a three-dimensional display pattern alignment layer original plate capable of easily and in large quantities producing a pattern alignment film capable of forming a high-quality pattern retardation film for a three-dimensional display device.

  Conventionally, as a flat panel display, a two-dimensional display has been mainstream, but in recent years, a flat panel display capable of three-dimensional display has begun to attract attention, and some of them are commercially available. . Further, in future flat panel displays, it is a natural tendency to be capable of three-dimensional display, and flat panel displays capable of three-dimensional display are being studied in a wide range of fields.

  In order to perform three-dimensional display on a flat panel display, it is usually necessary to display a right-eye video and a left-eye video separately to the viewer in some manner. As a method for separately displaying the right-eye video and the left-eye video, for example, a passive method is known. Such a passive three-dimensional display method will be described with reference to the drawings. FIG. 17 is a schematic diagram illustrating an example of a passive three-dimensional display. As shown in FIG. 17, in this method, first, the pixels constituting the flat panel display are divided into a plurality of types of pixels, that is, a right-eye video display pixel and a left-eye video display pixel. The pixel displays a right-eye image, and the other group of pixels displays a left-eye image. In addition, the image for the right eye and the image for the left eye are converted into circularly polarized light by using a linearly polarizing plate and a pattern retardation film in which a patterned retardation layer corresponding to the division pattern of the pixel is formed. In addition, viewers can wear 3D display by wearing right-eye and left-eye circular polarizing glasses so that the right-eye video reaches only the right eye and the left-eye video only reaches the left eye. Things are passive.

  Such a passive method has an advantage that three-dimensional display can be easily performed by using the pattern retardation film and the corresponding circular polarizing glasses.

  By the way, as described above, in the passive method, it is essential to use a pattern retardation film. However, such a pattern retardation film has not been widely researched and developed, and can be used as a standard technique. There is nothing that has been established. In this regard, Patent Document 1 discloses that as a pattern retardation film, a photo-alignment film having an alignment regulating force controlled in a pattern on a glass substrate and the photo-alignment film are formed. A pattern retardation plate having a retardation layer patterned so as to correspond to a film pattern is disclosed. However, since the pattern retardation plate disclosed in Patent Document 1 is indispensable to use a glass plate, it is expensive and does not mean that a large area can be manufactured. There was a difficulty in its practicality.

  Further, in Patent Document 2, a phase difference layer containing a liquid crystal compound is formed on an alignment layer that has been subjected to a rubbing treatment in a pattern, whereby a region in which the alignment directions of the liquid crystal compounds are orthogonal is formed in a pattern. A retardation film is disclosed. However, the rubbing process is a generally known means as an alignment process for aligning the liquid crystal compounds, but it has been difficult to clearly divide the rubbing direction into 0 degrees and 90 degrees in a fine region. The alignment regulating power for the liquid crystal compound is relatively weak. For this reason, when a pattern phase difference plate is produced by a method such as Patent Document 2, the boundary of the pattern in the retardation layer becomes unclear and ambiguous, and defects in liquid crystal alignment occur near the boundary, and light leaks from there. Occurs, and the contrast of the display is lowered.

JP 2005-49865 A JP 2003-207641 A

  The present invention has been made in view of such a situation, and is capable of easily and in large quantities producing a pattern alignment film capable of forming a high-quality pattern retardation film for a three-dimensional display device. The main object is to provide an original plate for a pattern alignment layer for display.

  In order to solve the above-described problems, the present invention provides a first pattern portion having a fine uneven shape formed in a certain direction and a second pattern portion having a fine uneven shape formed in a direction different from the first pattern portion. An original for a pattern alignment layer for three-dimensional display is provided.

According to the present invention, by having the first pattern portion and the second pattern portion formed on the surface in different directions with fine uneven shapes, such a three-dimensional display pattern alignment layer original plate (hereinafter simply referred to as an original plate). Can be used for three-dimensional display having an alignment layer in which the first alignment region and the second alignment region are formed in a pattern without using an expensive material such as a photo-alignment material. A pattern alignment film (hereinafter sometimes simply referred to as a pattern alignment film) can be formed easily and in large quantities.
Further, by using such a pattern alignment film and forming, for example, a retardation layer containing a liquid crystal compound on the alignment layer having the alignment region described above, a three-dimensional display pattern used in a three-dimensional display device A retardation film (hereinafter sometimes simply referred to as a pattern retardation film) can be produced easily and in large quantities.
Further, by using such an original plate, it is possible to suppress a decrease in the alignment regulating force in the vicinity of the boundary between the first alignment region and the second alignment region, so that it corresponds to the first alignment region and the first alignment region. There is an advantage that the boundary between the first retardation region and the second retardation region, which are retardation layers, can be clarified. As a result, liquid crystal alignment defects that are likely to occur near the boundary between adjacent patterns can be suppressed, so that light leakage from the vicinity of the boundary can be suppressed, and as a result, a decrease in contrast when used in a display is suppressed. be able to. Therefore, a high-quality pattern retardation film can be formed by using such an original plate.

  In the present invention, the substrate is preferably a roll substrate. This is because the pattern alignment film can be formed easily and in large quantities, and the production efficiency can be increased.

  In the present invention, it is preferable that the formation directions of the fine unevenness formed in the first pattern portion and the second pattern portion differ by 45 ° or 90 °. This is because it can be suitably used for a three-dimensional display device.

  In the present invention, the material constituting the substrate is preferably a metal material. It is because it can be made excellent in durability.

  The present invention includes a substrate having a first pattern portion having a fine uneven shape formed in a certain direction and a second pattern portion having a fine pattern formed in a direction different from the first pattern portion on the surface. A method for producing a master for a pattern alignment layer for dimension display, comprising: preparing a base material; forming a fine unevenness shape in a certain direction on the entire surface of the base material; and the entire surface of the base material And a second pattern forming step of forming a fine uneven shape in a fixed direction in a direction different from the first pattern forming step in the scraped region. Provided is a method for producing a three-dimensional display pattern alignment layer master.

  According to the present invention, there is provided a substrate having on its surface a first pattern portion having a fine uneven shape formed in a certain direction and a second pattern portion having the fine uneven shape formed in a direction different from the first pattern portion. The original master for a three-dimensional display pattern alignment layer can be obtained easily and accurately.

  In the present invention, the above-described three-dimensional display pattern alignment layer original plate and the alignment layer forming layer made of the alignment layer forming resin composition are brought into contact with each other and then pressurized, and the alignment layer forming layer is subjected to the above-described process. A three-dimensional display pattern forming layer for forming an original surface shape, a curing step for hardening the alignment layer forming layer after the forming step, and the three-dimensional display for forming the alignment layer forming layer. There is provided a method for producing a pattern alignment film for three-dimensional display, comprising a peeling step of peeling from a pattern alignment layer master for use.

  According to the present invention, by using the original plate, a pattern alignment film capable of forming a high-quality pattern retardation film can be easily and in large quantities.

  The present invention provides a retardation layer containing a rod-shaped compound having refractive index anisotropy on an alignment layer included in a three-dimensional display pattern alignment film formed by the above-described method for manufacturing a three-dimensional display pattern alignment film. The coating step of applying the coating liquid and the rod-shaped compound contained in the coating film of the retardation layer forming coating liquid are formed in the first and second alignment regions included in the alignment layer. An alignment step of aligning along the direction of the concavo-convex shape, and a method for producing a three-dimensional display pattern phase difference film.

  According to the present invention, a pattern retardation film for a three-dimensional display device can be formed by using a pattern alignment film formed using the above-described original plate.

  According to the original plate for a three-dimensional display pattern alignment layer of the present invention, there is an effect that a pattern alignment film capable of forming a high-quality pattern retardation film can be produced easily and in large quantities.

It is the schematic which shows an example of the original plate for 3D display pattern orientation layers of this invention. It is a schematic plan view which shows the surface of the original plate of FIG. It is the sectional view on the AA line of FIG. It is explanatory drawing explaining the fine uneven | corrugated shape in this invention. It is explanatory drawing explaining the fine uneven | corrugated shape in this invention. It is explanatory drawing explaining the fine uneven | corrugated shape in this invention. It is a schematic plan view which shows the surface of the other example of the original plate for three-dimensional display pattern orientation layers of this invention. It is explanatory drawing explaining the 1st pattern part and 2nd pattern part in this invention. It is process drawing which shows an example of the manufacturing method of the original plate for 3D display pattern orientation layers of this invention. FIG. 10 is a sectional view taken along line B-B in FIG. 9. It is process drawing which shows an example of the manufacturing method of the pattern orientation film for three-dimensional displays of this invention. It is explanatory drawing explaining the pressurization method in this invention. It is explanatory drawing explaining the pressurization method in this invention. It is explanatory drawing explaining the transparent film base material used for this invention. It is process drawing which shows an example of the manufacturing method of the pattern retardation film for three-dimensional displays of this invention. It is explanatory drawing explaining the other process in this invention. It is the schematic which shows the example of the liquid crystal display device which can display a three-dimensional image | video with a passive system.

The present invention relates to a master for a three-dimensional display pattern alignment layer, a method for manufacturing the same, a method for manufacturing a pattern alignment film for three-dimensional display using the same, and a method for manufacturing a pattern retardation film for three-dimensional display.
Hereinafter, a method for producing a three-dimensional display pattern alignment layer master, a three-dimensional pattern alignment layer master, a three-dimensional pattern alignment film manufacturing method, and a three-dimensional pattern retardation film manufacturing method of the present invention Will be described in detail.

A. First, a three-dimensional display pattern alignment layer master according to the present invention will be described.
The original plate of the present invention comprises a substrate having a first pattern portion having a fine uneven shape formed in a certain direction and a second pattern portion having a fine uneven shape formed in a direction different from the first pattern portion on the surface. It is characterized by having.

Such an original plate of the present invention will be described with reference to the drawings. FIG. 1 is a schematic view showing an example of an original plate of the present invention. 2 is a schematic plan view of the surface of the original plate in FIG. 1, and FIG. 3 is a cross-sectional view taken along line AA in FIG. As illustrated in FIGS. 1 to 3, the original plate 10 of the present invention is formed with a first pattern portion 2 a having a fine concavo-convex shape formed in a certain direction and a fine concavo-convex shape formed in a direction different from the first pattern portion 2 a. It has the roll-shaped base material 1 which equips the surface with the made 2nd pattern part 2b.
In this example, the original plate is a roll plate whose base material is a roll-shaped base material, and the formation direction of the fine irregularities on the surfaces of the first pattern portion and the second pattern portion is the rotation direction of the original plate. On the other hand, it is 90 ° and 0 °, and shows a difference of 90 °. Moreover, the arrow in FIG. 2 shows the formation direction of fine uneven | corrugated shape.

According to the present invention, an expensive material such as a photo-alignment material can be obtained by using such an original plate by having the first pattern portion and the second pattern portion formed on the surface in directions with different fine uneven shapes. A first alignment region in which rod-like compounds having refractive index anisotropy can be arranged in a certain direction without using, and a second alignment region in which rod-like compounds can be arranged in a direction different from the first alignment region. However, a pattern alignment film having an alignment layer formed in a pattern corresponding to the patterns of the first pattern portion and the second pattern portion can be formed easily and in large quantities.
In addition, when such a pattern alignment film is used and, for example, a retardation layer containing the rod-shaped compound is formed on the alignment layer having the alignment region, the first alignment region and the second alignment region are formed. Has a phase difference layer (first phase difference region and second phase difference region) having different arrangement directions of rod-shaped compounds according to the orientation regulating force of the substrate, and easily and in large quantities produces a pattern phase difference film used in a three-dimensional display device It becomes possible to do.
Further, by using the original plate on which the first pattern portion and the second pattern portion in which the fine concavo-convex shape is formed in advance as in the present invention, the first alignment region and the second alignment region are sufficiently near the boundary. It can be assumed that a fine uneven shape is formed on the surface. For this reason, it is possible to suppress a decrease in the alignment regulating force in both regions, and the boundary between the first retardation region and the second retardation region, which are retardation layers corresponding to the first alignment region and the first alignment region. There is an advantage that can be clarified. As a result, liquid crystal alignment defects that are likely to occur near the boundary between adjacent patterns can be suppressed, so that light leakage from the vicinity of the boundary can be suppressed, and as a result, a decrease in contrast when used in a display is suppressed. be able to. Therefore, a high-quality pattern retardation film can be formed by using such an original plate.

The original plate for a pattern alignment layer for three-dimensional display of the present invention has a substrate.
Hereafter, each structure of the original for pattern orientation layers for three-dimensional displays of this invention is demonstrated in detail.

1. Base material The base material used for this invention equips the surface with a 1st pattern part and a 2nd pattern part.

(1) 1st pattern part and 2nd pattern part The 1st pattern part in this invention is a site | part formed in the surface of a base material, and a fine uneven | corrugated shape is formed in the fixed direction.
Moreover, the 2nd pattern part in this invention is a site | part formed in the surface of a base material, and a fine uneven | corrugated shape is formed in the direction different from the said 1st pattern part.

(I) Fine concavo-convex shape The fine concavo-convex shape in the present invention is formed in a certain direction, and an alignment layer capable of arranging rod-shaped compounds in a certain direction by transferring such a fine concavo-convex shape. Can be formed.

  The fine concavo-convex shape in the present invention is not particularly limited as long as the rod-shaped compound can be arranged in a certain direction when transferred to the alignment layer. Here, since the rod-like compound has an array property parallel to the longitudinal direction of the line-shaped uneven structure on the surface on which the line-shaped uneven structure is formed, the fine uneven shape in the present invention is composed of a line-shaped uneven structure. It is preferable that This is because according to such a line-shaped uneven structure, the direction in which the rod-shaped compounds are arranged can be determined in advance.

The form in which the line-shaped uneven structure is formed in the present invention may be an aspect in which minute line-shaped uneven structures are randomly formed in a substantially constant direction, or the line-shaped uneven structure is formed in a stripe shape. An aspect may be sufficient.
Specifically, in the present invention, even if the first pattern portion and the second pattern portion are both formed with a fine line-shaped uneven structure as the fine uneven shape randomly in a substantially constant direction. It is also possible that the line-shaped uneven structure is formed in stripes on both sides. Furthermore, as illustrated in FIG. 4, a mode in which both are combined may be used.

Here, a mode in which minute line-shaped uneven structures are randomly formed in a substantially constant direction is, for example, a line-shaped uneven structure such as a minute scratch formed when the surface is rubbed. Means an aspect formed in a substantially constant direction. Specifically, the cross-sectional shape of the minute line-shaped uneven structure is not particularly limited as long as it has an uneven structure and the rod-shaped compound can be arranged in a predetermined direction. It can be a substantially trapezoid or the like. Moreover, it may not be a fixed shape.
On the other hand, the aspect in which the line-shaped uneven structure is formed in a stripe shape means an aspect in which convex portions formed in a wall shape are formed in a stripe shape at regular intervals. The size of the line-shaped concavo-convex structure is relatively larger than the above-mentioned random mode, and for example, the concavo-convex shape such as a minute scratch formed when the surface is rubbed is not included. is there.

In the present invention, the fine uneven shape formed on the surface of the first pattern portion and the fine uneven shape formed on the surface of the second pattern portion may be the same or different. Also good. In particular, in the present invention, it is preferable that the fine concavo-convex shape formed on at least one surface of the first pattern portion or the second pattern portion already described is the above-described stripe-like line concavo-convex structure. In the aspect in which the minute line-shaped uneven structure is randomly formed in a substantially constant direction and the aspect in which the fine line-shaped uneven structure is formed in the stripe-like line-shaped uneven structure, the latter may exhibit a stronger alignment regulating force on the rod-shaped compound. Therefore, since the fine concavo-convex shape formed on at least one surface of the first pattern portion or the second pattern portion is a stripe-like line concavo-convex structure, the pattern alignment film to which such a fine concavo-convex shape is transferred This is because the boundary between the right-eye and left-eye retardation layers (first retardation region and second retardation region) of the pattern retardation film can be clarified.
In the present invention, as shown in FIG. 4 described above, the fine unevenness formed in one pattern portion is a stripe-like line uneven structure, and the fine unevenness formed in the other pattern portion. It is preferable that a line-shaped uneven structure having a minute shape is randomly formed in a substantially constant direction. As a method of forming the first pattern portion and the second pattern portion, a fine line-shaped uneven structure is randomly formed in a substantially constant direction on the entire surface of the base material by, for example, a method such as polishing, and then the surface of the base material is changed to a bite or the like. The first pattern portion can be used by forming a striped line-shaped uneven structure as a fine uneven shape while cutting the fine uneven shape formed on the entire surface into a pattern shape by cutting into a pattern shape with This is because the second pattern portion can be easily and accurately formed.

  When a striped line-shaped uneven structure is formed, the height, width, and period of the line-shaped uneven structure are not particularly limited as long as the rod-shaped compound can be arranged. In particular, in the present invention, the width of the striped line-shaped uneven structure is preferably in the range of 1 nm to 100,000 nm, more preferably in the range of 10 nm to 10,000 nm, and in the range of 100 nm to 1000 nm. Is more preferable. The height of the striped line-shaped uneven structure is preferably in the range of 1 nm to 1000 nm, more preferably in the range of 10 nm to 100 nm, and further in the range of 20 nm to 50 nm. preferable. Furthermore, the period of the striped line-shaped uneven structure is preferably in the range of 2 nm to 200000 nm, more preferably in the range of 20 nm to 20000 nm, and still more preferably in the range of 200 nm to 2000 nm.

  In addition, when the minute line-shaped uneven structure is formed at random, the height, width, and period of the minute line-shaped uneven structure are not particularly limited as long as the rod-shaped compound can be arranged. Absent. Among them, in the present invention, the width of the fine line-shaped uneven structure is preferably in the range of 0.1 nm to 10000 nm, more preferably in the range of 0.1 nm to 1000 nm, and 0.1 nm to 100 nm. More preferably, it is within the range. The height of the fine line-shaped uneven structure is preferably in the range of 0.1 nm to 10000 nm, more preferably in the range of 0.1 nm to 1000 nm, and in the range of 0.1 nm to 100 nm. More preferably. Furthermore, the period of the fine line-shaped uneven structure is preferably in the range of 0.1 nm to 10000 nm, more preferably in the range of 0.1 nm to 1000 nm, and in the range of 0.1 nm to 100 nm. More preferably.

Here, the height, width, and period of the line-shaped uneven structure mean the distances indicated by l, m, and n in FIG.
FIG. 5 is an explanatory diagram showing a case where the cross-sectional shape of the striped line-shaped uneven structure or the minute line-shaped uneven structure is a rectangular shape.

As the formation direction of the fine unevenness formed on the surface of the first pattern portion and the second pattern portion in the present invention, both are formed in different directions, and the pattern alignment film formed using the original plate of the present invention, Although it will not specifically limit if a desired three-dimensional image can be displayed, It is preferable that it differs by 45 degrees or 90 degrees. It is because it can be used suitably for manufacturing a three-dimensional display apparatus because the said formation direction is the said direction.
The direction different from 45 ° or 90 ° is not particularly limited as long as it can accurately form a pattern alignment film capable of forming a three-dimensional display device using the original plate of the present invention. It is preferably within a range of 45 ° (or 90 °) ± 3 °, and more preferably within a range of about 45 ° (or 90 °) ± 2 °, and in particular, 45 ° (or 90 ° °) It is preferably within a range of about ± 1 °. This is because a high-performance three-dimensional display device can be formed.

  Here, by having the first pattern portion and the second pattern portion, the first alignment region and the second alignment region can be formed in a pattern on the alignment layer, and the retardation layer is formed according to the pattern. In FIG. 5, the retardation layer (first retardation region) formed on the first alignment region and the retardation layer (second retardation region) formed on the second alignment region are arranged in a pattern. Will be. Here, when the formation directions of the fine unevenness formed in the first pattern portion and the second pattern are orthogonal to each other, the first alignment region included in the pattern alignment film formed using the original plate of the present application In the first and second alignment regions, the direction in which the rod-shaped compounds are arranged is a direction orthogonal to each other, and in the first retardation region and the second retardation region, the direction in which the refractive index is largest (slow axis direction) is They are orthogonal to each other. For this reason, in the present invention, corresponding to the pattern in which the first pattern portion and the second pattern portion are formed, the first retardation region having a slow axis direction different by 90 ° in the retardation layer, and the second A patterned retardation film in which retardation regions are arranged in a pattern can be obtained. Therefore, it can be suitably used for manufacturing a three-dimensional display device.

On the other hand, when the formation direction is an angle of 45 °, that is, the arrangement direction of the rod-shaped compounds in the first retardation region and the second retardation region of the pattern retardation film formed using the original plate of the present application. Is in a direction that makes an angle of 45 °, the in-plane retardation values of the first retardation region and the second retardation region correspond to λ / 2 minutes, and the λ / 4 plate By using in combination, a three-dimensional display device can be easily manufactured.
Here, the fact that a three-dimensional display device can be easily manufactured by combining with a λ / 4 plate in the case of the formation direction will be described in more detail. FIG. 6 is a schematic diagram showing an example of a case where a liquid crystal display device capable of three-dimensional display is manufactured using a combination of a pattern retardation film formed using the original plate of the present invention and a λ / 4 plate. . As illustrated in FIG. 6, a liquid crystal display device using a combination of a pattern retardation film formed using the original plate of the present invention and a λ / 4 plate is capable of three-dimensional display by a passive method. The principle is as follows.

  First, the color filter pixels constituting the flat panel display are divided into a plurality of two types of pixels, a right-eye video display pixel and a left-eye video display pixel, and the right-eye video is divided into one group of pixels. The left eye image is displayed on the other group of pixels. Next, as the pattern retardation film, the first retardation region of the retardation layer is formed so as to correspond to the arrangement pattern of the left-eye image display pixels, and the second retardation region is the arrangement pattern of the right-eye image display pixels. Prepare one that is formed to correspond to. And such a pattern phase difference film is arrange | positioned at the display surface side of a 2nd linearly-polarizing plate, Furthermore, (lambda) / 4 board is arrange | positioned at the display surface side of a pattern phase difference film. At this time, the direction of the slow axis of the first retardation region and the direction of the polarization axis of the second linear polarizing plate intersect at 45 °, and further, the slow axis direction of the first retardation region and λ / The slow axis directions of the four plates are set in a parallel or orthogonal relationship. By disposing the pattern retardation film and the λ / 4 plate in this manner, images displayed by the right-eye image display pixel and the left-eye image display pixel (hereinafter referred to as “right-eye image” and “left-eye image”, respectively) Is visually recognized by the observer through the following route.

That is, each image displayed by the right-eye image display pixel and the left-eye image display pixel is first transmitted through the second linearly polarizing plate, and thus is converted into linearly polarized light. Here, in FIG. 6, since the polarization axis of the second linear polarizing plate is in the 0 ° direction, each image transmitted through the second polarizing plate is also linearly polarized in the 0 ° direction. Next, each image converted into linearly polarized light (0 °) in this way enters the pattern phase difference film, but the image for the left eye passes through the first phase difference region, and the image for the right eye is the first image. Since it passes through the two phase difference regions, the left-eye image is transmitted through the pattern retardation film as linearly polarized light (L1) having a polarization axis of 90 °, but the right-eye image has no change and the polarization axis is 0 °. The pattern retardation film is transmitted through the linearly polarized light (L2). Next, when L1 and L2 are incident on the λ / 4 plate, the left-eye image is converted into right-handed circularly polarized light (C1), and the right-eye image is converted into left-handed circularly polarized light (C2). It will be.
As described above, the right-eye image and the left-eye image that have passed through the pattern retardation film and the λ / 4 plate are converted into circularly polarized light orthogonal to each other. Wearing circularly polarized glasses with circularly polarized lenses that are orthogonal to each other so that the right-eye image passes only through the right-eye lens and the left-eye image passes only through the left-eye lens. Can reach only the right eye, and the left-eye video can reach only the left eye, and three-dimensional display becomes possible.

In this invention, when the said base material is a roll-shaped base material, the formation direction of any one fine uneven | corrugated shape of a 1st pattern part and a 2nd pattern part is a direction parallel to the rotation direction of a roll. Preferably there is.
Specifically, when the formation direction of the fine unevenness of the first pattern portion and the second pattern portion is different by 45 °, it is 0 ° / 45 ° or 0 ° / 135 ° with respect to the rotation direction. It is preferable that when the formation direction is 90 ° different, it is preferably 0 ° / 90 ° with respect to the rotation direction. As a method for forming the first pattern portion and the second pattern portion, a fine line-shaped uneven structure is randomly formed in a substantially constant direction as a fine uneven shape on the entire surface of the roll base material by, for example, a method such as polishing, By cutting the surface of the material into a pattern in the direction of rotation of the roll base with a tool or the like, the fine uneven shape formed on the entire surface is cut into a pattern, and a striped line uneven structure is formed as the fine uneven shape This is because the first pattern portion and the second pattern portion can be easily and accurately formed.
Specifically, the fine concavo-convex shape formed in the first pattern portion and the second pattern portion has a direction of 0 ° / 45 ° with respect to the rotation direction. The ones shown can be mentioned. Moreover, as a thing of 0 degree / 90 degrees with respect to a rotation direction, what is illustrated in FIG. 7 can be mentioned, for example. FIG. 7 is a schematic plan view showing the surface of the original plate, and the reference numerals in FIG. 7 indicate the same members as those in FIGS. .

(Ii) 1st pattern part and 2nd pattern part As a pattern in which the 1st pattern part and 2nd pattern part in this invention are formed, with a pattern phase difference film formed using the original plate of this invention, desired pattern As long as it can display a three-dimensional image, it can be appropriately determined according to the application of the present invention, and is not particularly limited.
Examples of such a pattern include a belt-like pattern, a mosaic pattern, and a staggered pattern. In particular, in the present invention, the first pattern portion and the second pattern portion are formed in a belt-like pattern parallel to each other, that is, the first alignment region and the second alignment region formed using the original plate of the present invention. And it is preferable that the 1st phase difference area | region and 2nd phase difference area | region formed corresponding to a 1st orientation area | region and a 2nd orientation area | region are formed in the strip | belt-shaped pattern mutually parallel. Since the first phase difference region and the second phase difference region can be easily formed into strip-like patterns parallel to each other, a pattern in which a pixel portion is formed in the three-dimensional display device, the first phase difference region, This is because it is easy to make the second phase difference region correspond to each other.
Specific examples of the first pattern portion and the second pattern portion that are formed in a strip-like pattern parallel to each other include those already described with reference to FIGS.

  When the first pattern portion and the second pattern portion in the present invention are formed in a parallel strip shape, the formation direction of the first pattern portion and the second pattern portion, that is, the direction of the parallel strip shape, Although it will not specifically limit if the surface shape of an original plate can be accurately shape | molded to a use layer, When a base material is a roll base material, it has already demonstrated to FIGS. 1-3. As shown, the direction is preferably along the rotation direction of the roll. This is because it is easy to form the first pattern portion and the second pattern portion.

As the widths of the first pattern portion and the second pattern portion in this step, both widths may be the same or different.
However, in the present invention, it is preferable that the widths of the first pattern portion and the second pattern portion are the same. Normally, the right-eye pixel and the left-eye pixel portion are formed with the same width. Therefore, by setting the widths of the first pattern portion and the second pattern portion to the same width, This is because the first alignment region and the second alignment region of the alignment layer formed corresponding to the pattern portion can have the same width. As a result, in the case of manufacturing a liquid crystal display device capable of three-dimensional display by forming a pattern alignment film using the original plate of the present invention, a pattern in which the first alignment region and the second alignment region are formed, and a liquid crystal In the color filter used in the display device, it becomes easy to make the correspondence with the pattern in which the pixel portion is formed, and as a result, it is easy to use the pattern alignment film formed using the original plate of the present invention. This is because a three-dimensional liquid crystal display device can be manufactured. In addition, since the pixel portion used in the light emitting display device is also formed with the same width, the original plate of the present invention is used by setting the widths of the first alignment region and the second alignment region to the same width. When a light-emitting display device capable of three-dimensional display is manufactured using the pattern alignment film formed in this manner, the pattern in which the first alignment region and the second alignment region are formed and the light-emitting display device are used. As a result, it is easy to make a three-dimensional light emitting display device using a pattern alignment film formed by using the original plate of the present invention. Because you will be able to. For the purpose of improving the color purity and contrast of the light emitting display device, a color filter may be disposed between the light emitting display device and the pattern alignment film formed using the original plate of the present invention. The pixel portion is formed in the pattern of the first pattern portion and the second pattern portion, that is, the pattern in which the first alignment region and the second alignment region are formed, and the color filter used in the light emitting display device. It is preferable to make the corresponding pattern correspond.

  The specific width of the first pattern portion and the second pattern portion is appropriately determined according to the use of the pattern alignment film formed using the original plate of the present invention. For example, when used for manufacturing a liquid crystal display device capable of three-dimensional display, the widths of the first pattern portion and the second pattern portion correspond to the widths in which the pixel portions for the right eye and the left eye are formed. It will be determined as appropriate. As described above, the widths of the first pattern portion and the second pattern portion are not particularly limited, but are usually preferably in the range of 50 μm to 1000 μm, and more preferably in the range of 100 μm to 600 μm. .

The thicknesses of the first pattern portion and the second pattern portion used in the present invention may be the same, but are preferably different. As a method of forming the 1st pattern portion and the 2nd pattern portion, a fine line-shaped uneven structure is randomly formed in a substantially constant direction on the entire surface of the substrate by a method such as polishing, and then the surface of the substrate is formed with a tool or the like. By cutting into a pattern, it is possible to use a method of forming a striped line-shaped uneven structure as a fine uneven shape while removing the fine uneven shape formed on the entire surface into a pattern. This is because the second pattern portion can be easily and accurately formed.
As the difference in thickness between the first pattern portion and the second pattern portion, when the pattern retardation film is formed using the pattern alignment film formed using the original plate of the present invention, the first retardation is obtained. The region and the second phase difference region are not particularly limited as long as they can be formed with high accuracy, but are preferably in the range of 1 nm to 2000 nm, for example, in particular, in the range of 10 nm to 1000 nm. It is preferable that it is in the range of 100 nm-500 nm especially. This is because the rod-shaped compounds contained in the first phase difference region and the second phase difference region can be arranged with high accuracy when the thickness difference is within the above range.

Note that the difference in thickness between the first pattern portion and the second pattern portion means a distance indicated by D1 in FIG. Moreover, as shown in FIG. 8, it shall mean the thickness containing the fine uneven | corrugated shape formed in the surface.
Moreover, since the reference numerals in FIG. 8 indicate the same members as those in FIG. 3, description thereof is omitted here.

(2) Substrate The shape of the substrate used in the present invention is not particularly limited as long as the first pattern portion and the second pattern portion can be provided on the surface. Alternatively, it may be a roll, but it is preferably a roll, that is, the substrate is a roll substrate. This is because the pattern alignment film can be formed easily and in large quantities, and the production efficiency can be increased.

Here, the roll shape is not particularly limited as long as the first pattern portion and the second pattern portion can be accurately formed on the surface, but specifically, a roll shape, a sleeve shape, or the like. Among them, a sleeve shape is preferable.
This is because the shape of the sleeve makes it possible to produce a pattern alignment film with high production efficiency using the original plate of the present invention. In addition, the sleeve-shaped base material is advantageous in that it is lighter than a roll-shaped base material and is easy to handle.
Here, specifically as a roll-shaped base material, a roll with a shaft, a pipe without a shaft, etc. can be mentioned. Here, the shaftless pipe refers to a cylindrical base material having a thickness of 3000 μm or more.
The sleeve shape represents a strip of a seamless base material, and the sleeve-shaped base material can be easily deformed by air pressure or stress, and specifically, a cylinder having a thickness of 1000 μm or less. It refers to a shaped substrate.
In the case of a roll shape such as a roll shape or a sleeve shape, the base material in the present invention is preferably seamless without a seam, but has a seam obtained by making a plate-like base material into a cylindrical shape. Also good.

The material constituting the substrate in the present invention is not particularly limited as long as the first pattern portion and the second pattern portion can be accurately formed. For example, nickel, copper, aluminum, tin, chromium , Stainless steel (SUS), iron and other metal materials; inorganic oxides such as SiO ₂ , SiO _x , Al ₂ O ₃ , GeO ₂ , TiO ₂ , Cr ₂ O ₃ , ZrO ₃ , Ta ₂ O ₅ , Nb ₂ O ₃ Inorganic nitrides such as Si ₃ N ₄ and AlN; Inorganic oxynitrides such as SiO _x N _y ; Inorganic carbides such as SiC; Inorganic materials such as DLC (diamond-like carbon); Among these, metal materials are preferable, and nickel, chromium, copper, stainless steel (SUS), iron, aluminum, etc. are particularly preferable. In particular, nickel is preferably copper. It is because it can be made excellent in durability by being the said material. Moreover, it is because the 1st pattern part and 2nd pattern part which have fine uneven | corrugated shape on the surface can be formed easily.

2. Original Plate The original plate of the present invention has the above-mentioned base material, but may have other configurations as necessary.
Specifically, a support substrate or the like that is disposed on the surface opposite to the surface on which the first pattern portion and the second pattern portion of the substrate are formed and supports the substrate can be exemplified. In addition, since it can be the same as that used for a general original plate as such a support base, description here is abbreviate | omitted.

  As the use of the original plate of the present invention, it is used for the formation of a pattern alignment film used for the production of a pattern retardation film used in a three-dimensional display device. Is preferably used for forming a pattern alignment film for a patterned retardation film.

B. Method for Producing 3D Display Pattern Orientation Layer Master Next, a method for producing the 3D display pattern orientation layer master of the present invention will be described.
In the method for producing a master for a pattern alignment layer for three-dimensional display according to the present invention, a first pattern portion in which a fine uneven shape is formed in a certain direction and the fine uneven shape is formed in a direction different from the first pattern portion. A method for producing an original plate for a three-dimensional display pattern alignment layer having a base material provided with a second pattern portion on the surface, wherein the base material is prepared, and fine irregularities are formed in a certain direction on the entire surface of the base material. The first pattern forming step and the fine uneven shape formed on the entire surface of the base material are scraped into a pattern shape, and the fine uneven shape is formed in a fixed direction in a direction different from the first pattern forming step. And a second pattern forming step to be formed.

  A method for producing such an original plate for a three-dimensional display pattern alignment layer according to the present invention will be described with reference to the drawings. FIG. 9 is a process diagram showing an example of a method for producing a three-dimensional display pattern alignment layer master according to the present invention, and FIG. 10 is a cross-sectional view taken along line BB in FIG. As illustrated in FIG. 9 and FIG. 10, the method for producing a three-dimensional display pattern alignment layer master according to the present invention prepares a substrate (roll-shaped substrate) 1 (FIG. 9A and FIG. 10 ( a)), by polishing the entire surface of the substrate 1, a fine uneven shape (a minute line-like uneven structure randomly formed in a substantially constant direction) is formed in a constant direction (FIG. 9B and FIG. 10 (b)), and then formed on the entire surface of the base material 1 by cutting the base material 1 into a strip shape parallel to the rotation direction using a diamond tool having a fine concavo-convex shape formed at the tip. A fine uneven shape is formed by cutting a fine uneven shape into a pattern, and forming a fine uneven shape (stripe-like line uneven structure) in a certain direction in a direction different from the fine uneven shape formed on the entire surface in the shaved area. Is a first pattern formed in a certain direction 2nd pattern formation process (FIG. 9 (FIG. 9) which forms the original 10 which has the base material 1 which equips the surface with the 2nd pattern part 2b in which the 2nd part 2a and the fine uneven | corrugated shape were formed in the direction different from the said 1st pattern part 2a. c) and FIG. 10 (c)).

  According to the present invention, there is provided a substrate having on its surface a first pattern portion having a fine uneven shape formed in a certain direction and a second pattern portion having the fine uneven shape formed in a direction different from the first pattern portion. The original master for a three-dimensional display pattern alignment layer can be obtained easily and accurately.

The method for producing a master for a pattern alignment layer for three-dimensional display according to the present invention includes a first pattern forming step and a second pattern forming step.
Hereinafter, each process of the manufacturing method of the original for pattern orientation layers for three-dimensional displays of this invention is demonstrated in detail.
The original plate manufactured by the manufacturing method of the present invention can be the same as that described in the section “A. Three-dimensional display pattern alignment layer original plate”, and the description thereof is omitted here. To do.

1. 1st pattern formation process The 1st pattern formation process in this invention is a process of preparing a base material and forming fine uneven | corrugated shape in a fixed direction on the whole surface of the said base material.

The material and shape constituting the base material used in this step are not particularly limited as long as a fine uneven shape can be formed on the surface, and the above-mentioned “A. Master plate for pattern alignment layer for three-dimensional display”. The description is omitted here because it can be the same as that described in the section.
In addition, regarding the fine uneven shape formed in a certain direction on the entire surface of the substrate, particularly if it can exhibit a desired alignment regulating force for the rod-shaped compound when transferred to the alignment layer. It is not limited, and can be the same as the content described in the section of “A. Three-dimensional display pattern alignment layer master”.

In this step, the method for forming the fine uneven shape on the entire surface of the substrate is not particularly limited as long as it can form a desired fine uneven shape on the entire surface of the substrate in a certain direction. In the case of forming a fine line-shaped uneven structure as a fine uneven shape at random in a substantially constant direction, a method of polishing the surface of the substrate such as a rubbing treatment can be exemplified.
Moreover, when forming a striped line-like uneven shape as the fine uneven shape, a method of cutting with a cutting tool such as a diamond cutting tool having a fine uneven shape at the tip can be cited.
In this step, the polishing method is particularly preferable. This is because the formation of fine irregularities on the entire surface of the substrate can be carried out easily and in a short time. Moreover, it is because the formation direction of the fine uneven shape can be set with a high degree of freedom.

  The polishing method in this step is not particularly limited as long as it is a method capable of randomly forming a minute line-like uneven structure in a substantially constant direction, and a general polishing method used for rubbing treatment or the like can be used. Can be made of, for example, grinding stone, paper polishing, tape polishing, sand blasting, shot blasting, grit blasting, blasting such as glass bead blasting, synthetic fibers such as nylon, polypropylene, vinyl chloride resin, etc. Brush graining method using brush material such as synthetic resin hair, non-woven fabric, animal hair, steel wire, wire graining method by scratching with metal wire, brush polishing method while supplying slurry liquid containing abrasive (brush graining Method), ball grain method, buffing method such as liquid honing method, Yottopiningu method, or the like can be mentioned. In this step, the tape polishing method and the paper polishing method are particularly preferable. This is because the direction of minute line-shaped irregularities can be easily controlled.

  In this step, the direction in which the fine concavo-convex shape is formed is not particularly limited as long as a desired fine concavo-convex shape can be formed. However, a direction other than a direction parallel to the rotation direction is preferable, and in particular, a direction of 90 ° or 45 ° with respect to the rotation direction is preferable. When the forming direction is a direction other than the direction parallel to the rotation direction, the direction of scraping the fine uneven shape formed in this step performed in the second pattern forming step and the forming direction of the fine uneven shape are rotated by the roll. This is because the second pattern forming step can be facilitated. Moreover, it is because it is easy to make the formation direction of the fine uneven | corrugated shape formed at this process and a 2nd pattern formation process into a different direction. Furthermore, the direction of 45 ° or 90 ° with respect to the rotation direction makes it easy to set the direction of forming the fine unevenness formed in this step and the second pattern forming step to 90 ° or 45 °. Because it becomes.

  In this step, the total surface of the substrate is not particularly limited as long as it includes at least the surface on which the first pattern portion is formed, among the surfaces of the substrate, but the first pattern portion It is preferable that the surface includes the surface on which the second pattern portion is formed. This is because it is easy to form fine irregularities.

2. Second pattern forming step In the second pattern forming step of the present invention, the fine uneven shape formed on the entire surface of the substrate is scraped into a pattern, and the scraped area is different from the first pattern forming step. This is a step of forming a fine uneven shape in a certain direction.

In this step, the fine uneven shape formed on the entire surface of the substrate is scraped into a pattern, and the fine uneven shape is formed in a fixed direction in a direction different from the first pattern forming step in the scraped region. The method is not particularly limited as long as it is a method capable of accurately forming the second pattern portion in the shaved area and the first pattern portion in the non-shaved area, and is cut by a polishing method, a cutting tool or the like. The method can be used.
In this step, it is preferable to use a cutting method with a cutting tool. The fine uneven shape formed on the entire surface of the substrate can be easily scraped, and the fine uneven shape can be formed in a fixed direction in a direction different from the first pattern forming step in the stably scraped region. Because.

  The area to be scraped in this step is not particularly limited as long as the area to be scraped can be the second pattern portion and the area not to be scraped can be the first pattern portion. It can be the same as the pattern in which the first pattern portion and the second pattern portion described in the section “Pattern for pattern alignment layer” are formed.

  The depth of the base material scraped off in this step is not particularly limited as long as it can scrape off all the fine irregularities formed in the first pattern forming step. This can be the same as the difference in thickness between the first pattern portion and the second pattern portion described in the section “1. Substrate” of “Display pattern alignment layer master”.

In this step, the formation direction of the fine unevenness formed in the scraped region is not particularly limited as long as it is different from the formation direction of the fine unevenness formed in the first pattern forming step. The first pattern described in the section “1. Substrate” of “A. Three-dimensional display pattern alignment layer master” is formed in the direction of forming the fine unevenness formed in this step and the first pattern forming step. It is possible to have the same relationship as the formation direction of the fine concavo-convex shape of the portion and the second pattern portion.
Especially in this process, when the said base material is a roll base material, it is preferable that it is the rotation direction of a roll. This is because, by being in the rotating direction of the roll, for example, even when a fine uneven shape is formed by a method of cutting with a cutting tool or the like, it can be easily formed.

3. Method for Producing Three-Dimensional Display Pattern Orientation Layer Master The method for producing a master of the present invention includes a first pattern formation step and a second pattern formation step, and other steps as necessary. It may be a thing.
Examples of such other steps include a removal step of removing the polishing residue and the like of the base material after the first pattern formation step and the second pattern formation step. Examples of the removal method include a suction method, a removal method using a solvent, and the like.

C. Method for Producing 3D Display Pattern Orientation Film Next, a method for producing a 3D display pattern orientation film of the present invention will be described.
The method for producing a three-dimensional display pattern alignment film according to the present invention comprises contacting the above-described three-dimensional display pattern alignment layer master with an alignment layer forming layer made of an alignment layer forming resin composition. A molding step of applying pressure to mold the shape of the surface of the original pattern alignment layer for three-dimensional display on the alignment layer forming layer, a curing step of curing the alignment layer forming layer after the molding step, and And a peeling step of peeling the alignment layer forming layer from the three-dimensional display pattern alignment layer master.

A method for producing such a three-dimensional display pattern alignment film of the present invention will be described with reference to the drawings. FIG. 11 is a process diagram showing an example of a method for producing a pattern alignment film for three-dimensional display according to the present invention. First, as illustrated in FIG. 11, the alignment layer forming layer is formed by applying the alignment layer forming resin composition on the transparent film substrate 11 (FIG. 11A), After the alignment layer forming layer 12 'is placed on the roll plate (original plate) 10 having the roll base 1 having the first pattern portion 2a and the second pattern portion 2b on the surface, the pressure roll (FIG. 11B), the shapes of the first pattern portion 2a and the second pattern portion 2b of the original plate (roll plate) 10 are formed on the alignment layer forming layer 12 ′. A first alignment region and a second alignment region (12a and 12b) having surface shapes corresponding to the first pattern portion 2a and the second pattern portion 2b are formed, and then a roll plate is formed on the alignment layer forming layer 12 ′. Irradiate ultraviolet rays in contact with 10 (FIG. 11 (c)), the alignment layer forming layer 12 'is cured, and the alignment layer forming layer 12' is peeled off from the roll plate 10, whereby the transparent film substrate 11 and the transparent film substrate 11 are separated. A pattern alignment film 20 having the alignment layer 12 formed thereon is obtained (FIG. 11D).
In this example, FIGS. 11A to 11B are shaping processes, FIG. 11C is a curing process, and FIG. 11D is a peeling process.

  According to the present invention, by using the above original plate, a pattern alignment film capable of forming a pattern retardation film can be produced easily and in large quantities.

The manufacturing method of the pattern alignment film of this invention includes a shaping | molding process, a hardening process, and a peeling process at least.
Hereafter, each process included in the manufacturing method of the pattern orientation film of this invention is demonstrated in detail.

1. Molding step The molding step in the production method of the present invention is the step of bringing the original plate and the alignment layer forming layer comprising the alignment layer forming resin composition into contact with each other, and then applying pressure to the alignment layer forming layer. This is a step of shaping the shape of the original plate surface.
The original plate can be the same as that described in the section “A. Three-dimensional display pattern alignment layer original plate”, and the description is omitted here.

(1) Orientation layer formation layer The orientation layer formation layer used for this process consists of a resin composition for orientation layer formation.

The resin composition for forming an alignment layer used in this step is not particularly limited as long as the surface shape of the original plate can be shaped by applying pressure after contacting the original plate. Examples include ionizing radiation curable resin compositions, thermosetting resin compositions, electron beam curable resin compositions, and thermoplastic resin compositions.
Any of these constituent materials can be suitably used in this step, but among these, an ionizing radiation curable resin composition is preferably used. This is because by using the ionizing radiation curable resin composition, a product with high productivity can be obtained. When an ionizing radiation curable resin composition is used as the alignment layer forming resin composition, the alignment layer formed according to the present invention is composed of a cured ionizing radiation curable resin composition.

  Specific examples of the ionizing radiation curable resin composition used in the present invention include polymerizable oligomers and monomers having an acryloyl group such as urethane acrylate, epoxy acrylate, polyester acrylate, polyether acrylate, and melamine acrylate, and acrylic acid and acrylamide. , Acrylonitrile, Styrene, Polymerizable oligomers with polymerizable vinyl groups, Monomers, etc., or those with additives such as sensitizers added to them, if necessary, Photopolymerization initiators, etc. Can be mentioned. Moreover, you may contain a solvent as needed.

  Such a solvent is not particularly limited as long as it can uniformly dissolve or disperse the monomer and the like. Examples thereof include hydrocarbon solvents such as benzene and hexane, methyl ethyl ketone, methyl isobutyl ketone, and cyclohexanone. Ketone solvents, ether solvents such as tetrahydrofuran and 1,2-dimethoxyethane, alkyl halide solvents such as chloroform and dichloromethane, ester solvents such as methyl acetate, ethyl acetate, butyl acetate, propylene glycol monomethyl ether acetate, Examples include amide solvents such as N, N-dimethylformamide, sulfoxide solvents such as dimethyl sulfoxide, anone solvents such as cyclohexane, and alcohol solvents such as methanol, ethanol, and propanol. That is, the present invention is not limited to these. Further, the solvent used in this step may be one kind or a mixed solvent of two or more kinds of solvents.

  Moreover, as a thermosetting resin composition and a thermoplastic resin composition, what contains an acrylic resin, a fluorine resin, a polyester resin, a polycarbonate resin, a cycloolefin resin, a cycloolefin copolymer resin etc. can be used.

  In addition, the alignment layer forming resin composition used in this step absorbs, as necessary, an antioxidant for suppressing changes to oxygen, a light stabilizer for suppressing changes to light, and ultraviolet light. Even if it contains an ultraviolet absorber, a viscosity modifier for adjusting the viscosity, a refractive index modifier for adjusting the refractive index, a fluorine-based or silicon-based lubricant for improving moldability, etc. good.

The viscosity of the alignment layer forming resin composition used in this step is not particularly limited as long as the shape of the original plate surface can be molded into the alignment layer forming layer by pressing. For example, at 25 ° C., it is preferably within a range of 5 mPa · s to 200000 mPa · s, more preferably within a range of 10 mPa · s to 100000 mPa · s, particularly 30 mPa · s to 3000 mPa · s. More preferably, it is in the range.
In the case of a melt-type resin, for example, the melt flow index (MFI) at 190 ° C. is preferably 0.1 g / 10 min or more, more preferably 1.0 g / 10 min or more, In particular, it is preferably 5.0 g / 10 min or more. This is because when the viscosity is within the above range, the moldability can be improved.

  The thickness of the alignment layer forming layer used in this step is not particularly limited as long as the surface shape of the original plate can be accurately shaped. It can be the same as the orientation layer of the phase difference film. Specifically, it can be in the range of 0.5 μm to 20 μm.

(2) Molding step In this step, the alignment layer forming layer made of the alignment layer forming resin composition is brought into contact with the original plate and then pressed, and the shape of the surface of the original plate is applied to the alignment layer forming layer. Is a process of shaping.

  The pressure applied at the time of pressurization in this step is not particularly limited as long as it can stably shape the surface shape of the original plate on the alignment layer forming layer, and is used in this step. The orientation layer forming resin composition is appropriately selected according to the viscosity and the like, and using the orientation layer forming resin composition and the original plate, the extent of the shape of the original plate to the orientation layer forming layer is determined. It can be shaped or found by repeating experiments while adjusting the pressure. For example, when the alignment layer-forming resin composition having the above-described viscosity is used, the pressure is preferably in the range of 10 MPa / cm to 2000 MPa / cm, and more preferably 100 MPa / cm to 1000 MPa / cm. It is preferably within the range, and particularly preferably within the range of 150 MPa / cm to 500 MPa / cm. If the pressure is too low, the alignment layer forming layer does not enter the original plate so much that the height of the convex structure in the fine concavo-convex shape may be insufficient, and the pressure is too high. This is because the alignment layer forming layer may enter the original plate too much and not come out of the original plate.

In this step, the method for pressurizing the pressure is not particularly limited as long as the surface shape of the original plate can be stably formed on the alignment layer forming layer. For example, a belt press method, a roll A method using a touch method or the like can be given.
Hereinafter, a method of applying the pressure to the alignment layer forming layer using these methods will be described with reference to the drawings.

FIG. 12 is an explanatory view for explaining a pressurizing method according to the present invention. FIG. 12 exemplifies a method of pressurizing by a roll touch method. The unwinding machine 51a for unwinding the transparent film substrate 11 and the alignment layer forming layer 12 ′ are discharged by discharging the alignment layer forming resin composition. The alignment layer forming die 53 to be formed, the ultraviolet irradiation device 55 for irradiating the alignment layer forming layer 12 ′ with ultraviolet rays, and the alignment layer forming layer from the original plate (roll plate in this example) 10 with a peeling roll. A pressure roll 50 having elasticity such as rubber that presses the alignment layer forming layer 12 'against the roll plate. The method of pressurizing using the pattern orientation film manufacturing apparatus which has this is illustrated. In the roll touch method, since the pressure roll is deformed by using a pressure roll having elasticity such as rubber, the contact time between the roll plate and the alignment layer forming layer can be extended. It is possible to stably mold a desired fine uneven shape on the forming layer.
Moreover, FIG. 13 is explanatory drawing explaining the pressurization method in this invention. FIG. 13 exemplifies a method of applying pressure by a belt press method. An alignment layer forming die 53 for discharging the alignment layer forming resin composition directly onto the original plate (roll plate in this example) 10, The method of pressurizing using the pattern alignment film manufacturing apparatus which has the pressure belt 56 is illustrated. In the belt press method, when a roll plate is used as an original plate, a pressure can be applied to the alignment layer forming layer by confronting the roll plate and the pressure belt. Since the belt press method can lengthen the contact time between the roll plate and the alignment layer forming layer, it is possible to stably mold a desired fine uneven shape on the alignment layer forming layer.
Note that reference numerals not described in FIG. 13 can be the same as those in FIG. 12, and thus description thereof is omitted here.

The forming method in this step is not particularly limited as long as the surface shape of the original plate can be accurately formed on the alignment layer forming layer. For example, the original plate is used as the alignment layer forming layer. The method of pressing can be mentioned, and among them, the above-mentioned alignment layer-forming resin composition is applied on the above-mentioned pattern alignment layer master, and the alignment layer-forming layer is formed by a filling treatment and the above-mentioned alignment layer formation A method of applying pressure after performing a disposition treatment of disposing a transparent film substrate on the protective layer (first embodiment), applying the alignment layer-forming resin composition on the transparent film substrate, and A method of applying pressure after performing an alignment layer forming layer forming process for forming an alignment layer forming layer and a contact process for bringing the alignment layer forming layer into contact with the pattern alignment layer master (second embodiment) Aspect), the original plate for pattern alignment layer In coating the above alignment layer-forming resin composition, filling process for forming the alignment layer forming layer, after the process of pressurizing (Third embodiment) is preferably. This is because the first alignment region and the second alignment region can be formed stably.
Hereinafter, such a molding method will be described.

(A) 1st embodiment The shaping method of this aspect is the filling process which coats the said resin composition for orientation layer formation on the said original plate, and forms the said layer for orientation layer formation, and the object for said orientation layer formation And a placement process of placing a transparent film substrate on the layer, followed by pressurization. By patterning using such a molding method, a pattern alignment film in which an alignment layer is laminated can be easily formed on a transparent film substrate.

  The transparent film substrate used in this embodiment is not particularly limited as long as it is made of a resin material and has a predetermined transparency. Especially, it is preferable that the transparent film base material used for this invention is a thing with low phase difference property. More specifically, the transparent film substrate used in the present invention preferably has an in-plane retardation value (Re value) in the range of 0 nm to 10 nm, and preferably in the range of 0 nm to 5 nm. More preferably, it is further in the range of 0 nm to 3 nm. When the in-plane retardation value of the transparent substrate is larger than the above range, for example, a three-dimensional display device obtained when a three-dimensional display device is manufactured using a pattern alignment film manufactured by the manufacturing method of the present invention. This is because the display quality may deteriorate.

  The transparent film substrate used in this embodiment preferably has a transmittance in the visible light region of 80% or more, and more preferably 90% or more. Here, the transmittance | permeability of a transparent film base material can be measured by JISK7361-1 (the test method of the total light transmittance of a plastic transparent material).

  Examples of the transparent film substrate used in this embodiment include acetyl cellulose resins such as triacetyl cellulose, polyester resins such as polyethylene terephthalate and polyethylene naphthalate, olefin resins such as polyethylene and polymethylpentene, and acrylic resins. Resin, polyurethane resin, polyethersulfone, polycarbonate, polysulfone, polyether, polyetherketone, (meth) acrylonitrile, cycloolefin polymer, cycloolefin copolymer, etc. Since the in-plane retardation of the film substrate is likely to approach zero, resins such as acetyl cellulose resins, cycloolefin polymers, cycloolefin copolymers, and acrylic resins are preferred.

  About the thickness of a transparent film base material, it can determine suitably according to the use of the pattern orientation film manufactured with the manufacturing method of this invention, the material which comprises a transparent film base material, etc., It is limited especially Usually, it is preferably in the range of 20 μm to 188 μm, and more preferably in the range of 30 μm to 90 μm.

  In addition, when the said orientation layer consists of ultraviolet curable resin, you may form the primer layer for improving the adhesiveness of a transparent film base material and ultraviolet curable resin on a transparent film base material. This primer layer may be any layer that has adhesiveness to both the transparent film substrate and the ultraviolet curable resin, is visible optically transparent, and allows ultraviolet light to pass through. Polymer type and urethane type can be used.

  As a transparent film base material in this aspect, you may have an anti-glare layer or the antireflection layer 15 etc. on the surface opposite to the surface in which the said orientation layer is formed so that it may illustrate in FIG. This is because, when a display device is manufactured, a pattern retardation film capable of obtaining a display device with good display quality can be formed.

  In this aspect, since such an antireflection layer is formed, when a liquid crystal display device is manufactured using the pattern alignment film manufactured by the manufacturing method of the present invention, a liquid crystal display device having a good display quality. There is an advantage that can be obtained. Note that only one or both of the antireflection layer and the antiglare layer may be used.

  The antiglare layer is a layer having a function of reducing screen reflection caused by external light from the sun, a fluorescent lamp, or the like entering and reflecting on the display screen of the display device. On the other hand, the antireflection layer improves the image contrast by suppressing the regular reflectance of the surface, and as a result, has a function of improving the visibility of the image. The antiglare layer and antireflection layer used in this embodiment are not particularly limited as long as they have a desired antiglare function or antireflection function, and are used for display devices for the purpose of improving display image quality. Generally known ones can be used. Examples of the antiglare layer include a resin layer in which fine particles are dispersed, and examples of the antireflection layer include a layer having a configuration in which a plurality of layers having different refractive indexes are stacked. . If an antireflection layer is provided on the outermost surface of the antiglare layer, the visibility of the image in the bright room can be further improved.

The method for coating the alignment layer forming resin composition on the original plate performed in the filling process in this embodiment is not particularly limited as long as it can form an alignment layer forming layer having a uniform thickness. For example, a roll coating method, a T-die coating method, a cast coating method, a blade coating method, a bar coating method, a wire bar coating method, or a known method can be used.
In this embodiment, among them, a method that does not require the addition of a solvent to the alignment layer forming resin composition is preferable, and in particular, a melt extrusion method and a non-sol coating method can be preferably used. It is because a drying process etc. can be made unnecessary and it can be excellent in process passage property.
Here, as the melt extrusion method, for example, a method in which the alignment layer forming resin composition is thermally melted in a temperature range of not less than the glass transition temperature and not more than the thermal decomposition temperature, and extruded using a T die, etc. Is mentioned.
In addition, after the filling process, a drying process or a half-cure process using heat, UV, or EB can be appropriately performed.

  As a method of disposing the transparent film substrate on the alignment layer forming layer performed in the disposition treatment in this embodiment, the method can sufficiently adhere the alignment layer forming layer and the transparent film substrate. The method is not particularly limited, and examples thereof include a method in which a roll-shaped transparent film substrate is continuously unwound on the alignment layer forming layer on the original plate.

(B) 2nd embodiment The shaping method of this aspect is the layer formation process for alignment layer formation which coats the said resin composition for alignment layer formation on a transparent film base material, and forms the said layer for alignment layer formation. And a contact treatment in which the alignment layer forming layer and the original plate are brought into contact with each other, and then pressure is applied. By such a shaping method, a patterned retardation film in which an alignment layer is laminated on a transparent film substrate can be easily formed.
In this case, the alignment layer forming resin may contain a solvent compatible with the alignment layer forming resin. When it contains a solvent, it is desirable to apply a drying treatment for evaporating the solvent after coating the alignment layer-forming resin composition on the transparent film substrate. In addition, as a solvent, a solvent permeation layer can be formed between the transparent film substrate and the alignment layer forming layer by penetrating into the transparent film substrate, and therefore occurs at the interface between the transparent film substrate and the alignment layer. It is possible to prevent the wiggle and poor adhesion.

  The method for coating the alignment layer-forming resin composition on the transparent film substrate performed in the alignment layer-forming layer forming treatment in this embodiment is a method that can form an alignment layer-forming layer having a desired thickness. What is necessary is just to be the same as the filling process as described in the above-mentioned section “(a) First embodiment”.

  The method for bringing the alignment layer forming layer performed in the contact treatment in this embodiment into contact with the original plate is particularly limited as long as the alignment layer forming layer can be sufficiently adhered to the original plate. Instead, it can be the same as the placement process described in the section “(a) First Embodiment”.

(C) Third Embodiment The molding method of this aspect is a method in which the alignment layer-forming resin composition is applied on the original plate, and after the filling treatment for forming the alignment layer-forming layer, pressurization is performed. Is the method. By such a shaping method, for example, a pattern alignment film consisting only of an alignment layer can be easily obtained.
The method of coating the alignment layer forming resin composition on the original plate performed in the filling process in this embodiment is particularly limited as long as the alignment layer forming layer having a desired thickness can be formed. However, it may be the same as the filling process described in the section “(a) First embodiment”.

(4) First alignment region and second alignment region The first alignment region and the second alignment region formed in the alignment layer forming layer by performing this step are obtained by shaping the surface shape of the original plate. is there.
Therefore, the first alignment region and the second alignment region formed in the alignment layer forming layer are formed in patterns corresponding to the first pattern portion and the second pattern portion of the original plate, respectively. In addition, the shape and size of these regions, and the shape and direction of the fine concavo-convex shape also correspond to the first pattern portion and the second pattern portion of the original plate.
For this reason, a long alignment layer is formed by using a roll original plate in which fine irregularities are formed in the first pattern portion and the second pattern portion in directions of 90 ° and 0 ° with respect to the rotation direction of the roll, respectively. In the case where it is molded into the working layer, the fine irregular shape formed in the direction of 90 ° with respect to the longitudinal direction (longitudinal direction) in the first orientation region corresponding to the first pattern portion is the second pattern portion. Corresponding to this, a fine uneven shape formed in the direction of 0 ° with respect to the longitudinal direction is formed in the second alignment region.

2. Curing Step The curing step in the production method of the present invention is a step of curing the alignment layer forming layer after the shaping step.

  In this step, the method for curing the alignment layer forming layer is appropriately selected according to the alignment layer forming resin composition constituting the alignment layer forming layer. When the forming resin composition is an ionizing radiation curable resin composition, examples include an ultraviolet curing method and an electron beam curing method. When the alignment layer forming resin composition is a thermosetting resin composition, heating is performed. Examples thereof include a curing method and a normal temperature curing method. Moreover, when using a thermoplastic resin composition as the said resin composition for alignment layer formation, it can be made to harden | cure by the cooling method which makes a cooling roll etc. contact.

  As a method of irradiating with ultraviolet rays in the ultraviolet curing method in this step, a method of irradiating from the surface opposite to the surface in contact with the original of the alignment layer forming layer is usually used. If necessary, a method of irradiating from the surface in contact with the original plate may be used as necessary. This is because it can be sufficiently cured in a short time.

In the case of curing by an ultraviolet curing method in this step, the curing rate (reaction rate) of the alignment layer forming layer is preferably in the range of 20% to 97%, and more preferably in the range of 30% to 90%. It is preferable to be within. When the obtained pattern alignment film is stored, fine irregularities and patterns are crushed, resulting in shape defects, bleeding is likely to occur, and the liquid crystal coating surface side of the alignment layer is contaminated, causing liquid crystal alignment defects. This is because such a problem can be prevented. Another advantage is that it is possible to ensure adhesion to the liquid crystal layer.
In addition, the curing rate is the number of moles of the functional group having reactivity included in the alignment layer after performing this step, and the reactivity included in the alignment layer forming layer before performing this step. When the number of moles of the functional group possessed is Y, it is represented by (Y-X) / Y × 100 (%).

In this step, the alignment layer forming layer may be heated when the ultraviolet ray is irradiated by the ultraviolet curing method. This is because the reaction efficiency can be improved.
In this step, the method for heating the alignment layer forming layer is not particularly limited as long as it can bring the alignment layer forming layer to a desired temperature, and a known heating method may be used. Specific examples include a method using a temperature-adjustable original plate and a method using an infrared irradiation device, a hot air blower, and the like.

3. Peeling process The peeling process in the manufacturing method of this invention is a process performed after the said shaping process, and peeling the said layer for alignment layer formation from the said original plate.
The peeling method in this step is not particularly limited as long as the original plate can be peeled without damaging the cured alignment layer forming layer. Specifically, a method of peeling using a peeling roll as shown in FIG.

  The order of performing this step is not particularly limited as long as it is performed after the shaping step, but is preferably performed after the curing step. By performing the curing step in a state where the original plate and the alignment layer forming layer are in contact with each other, the shape of the original plate surface molded into the alignment layer forming layer can be stably cured, This is because the shape of the surface of the obtained alignment layer can be made highly accurate.

4. Manufacturing method of pattern alignment film for three-dimensional display The manufacturing method of the present invention includes the shaping step, the curing step, and the peeling step, but has other steps as necessary. Also good.
Examples of such other processes include a winding process for winding the pattern alignment film obtained after the peeling process into a roll, and a cleaning process for periodically cleaning the surface of the original plate.
Moreover, you may have a lamination process which laminates | stacks a transparent film base material on the said orientation layer as needed. In addition, as a lamination | stacking method of an orientation layer and a transparent film base material, like the above-mentioned orientation layer formation layer formation process, the method of coating the orientation layer formation resin composition on a transparent film base material, or the said orientation Examples thereof include a method in which a transparent film substrate is thermocompression-bonded to the layer and a method in which the transparent film substrate is bonded through an adhesive or the like.

Furthermore, you may have a 2nd hardening process for more fully hardening the layer for alignment layer formation after the said hardening process and peeling process. This is because the pattern alignment film can be made more excellent in hardness. Further, the time required for the curing step and the peeling step can be shortened, and the process can be made highly flexible.
Specifically, when the alignment layer-forming resin composition is an ionizing radiation-curable resin composition, the surface that contacts the original of the alignment layer-forming layer using an ultraviolet curing method as the curing step. After curing and transferring the surface shape, the alignment layer forming layer is peeled from the original plate by the peeling step, and then, as a second hardening step, the surface of the alignment layer forming layer that is in contact with the original plate. Ultraviolet irradiation can be performed.
In the case where the alignment layer forming resin composition is a resin composition having ionizing radiation curability and thermoplasticity, first, after performing the shaping step in a state of being heated and melted, After curing the surface of the alignment layer forming layer in contact with the original plate using a cooling method as a curing step and transferring the surface shape, the alignment layer forming layer is released from the original plate by the peeling step, and then As the second curing step, an ultraviolet curing method in which ultraviolet irradiation is performed on the surface of the alignment layer forming layer that contacts the original plate can be used.

The curing method for the alignment layer forming layer in the second curing step can be the same as in the curing step.
The ultraviolet irradiation method used in the ultraviolet curing method in this step may be a method of irradiating from the surface in contact with the original of the alignment layer forming layer or a method of irradiating from the opposite surface of the contact surface, but the above contact It is preferable that it is the method of irradiating from the surface to perform. This is because the alignment layer can maintain the surface shape of the original plate more stably.

5. Pattern Alignment Film A pattern alignment film obtained by the manufacturing method of the present invention has at least an alignment layer including a first alignment region and a second alignment region formed corresponding to the first pattern portion and the second pattern portion. However, it usually has a transparent film substrate.
Further, as described above, it may have an antireflection layer or an antiglare layer.

  As an application of the pattern alignment film obtained by the production method of the present invention, it can be used to form a pattern retardation film used in a display device for three-dimensional display, and in particular, there is no alignment defect and high quality is required. It is preferably used for forming a patterned retardation film.

D. 3. Manufacturing method of pattern retardation film for three-dimensional display Next, the manufacturing method of the pattern retardation film for three-dimensional display of this invention is demonstrated.
The method for producing a three-dimensional display pattern retardation film of the present invention comprises a refractive index difference on an alignment layer included in the three-dimensional display pattern alignment film formed by the above-described method for producing a three-dimensional display pattern alignment film. A coating step of applying a retardation layer-forming coating solution containing a rod-like compound having a directivity, and a rod-like compound contained in the coating film of the retardation layer-forming coating solution; And an alignment step of aligning along the direction of the fine unevenness formed in the alignment region and the second alignment region.

  A method for producing such a pattern retardation film of the present invention will be described with reference to the drawings. FIG. 15 is a process diagram showing an example of a method for producing a patterned retardation film of the present invention. As illustrated in FIG. 15, the pattern retardation film manufacturing method of the present invention is formed by the above-described pattern alignment film manufacturing method, and corresponds to the first pattern portion and the second pattern portion of the pattern alignment layer master. A coating solution for forming a retardation layer containing a rod-shaped compound having refractive index anisotropy is applied onto the alignment layer 12 having the first alignment region 12a and the second alignment region 12b formed in the above manner. (FIG. 15 (a)), and the coating film 13 'is heated to convert the rod-like compound contained in the coating film 13' into the first orientation region 12a and the second orientation region contained in the orientation layer 12. The phase difference layer 13 having the first phase difference region 13a and the second phase difference region 13b on the alignment layer 12 by arranging the fine concavo-convex shape formed in the direction 12b (FIG. 15B). Forming and par This is the turn phase difference film 30 (FIG. 15C).

  According to the present invention, a pattern retardation film for a three-dimensional display device can be easily formed by using a pattern alignment film formed using the above-described original plate.

The manufacturing method of the pattern phase difference film of this invention has an application | coating process and an orientation process at least.
Hereinafter, each process of the manufacturing method of the pattern phase difference film of this invention is demonstrated in detail.

1. Coating Step The coating step in the present invention is a coating for forming a retardation layer containing a rod-like compound having refractive index anisotropy on an alignment layer included in the pattern alignment film formed by the above-described method for producing a pattern alignment film. This is a step of applying a liquid.
The pattern alignment film formed by the above-described pattern alignment film manufacturing method is the same as the contents described in the section “C. Manufacturing method of pattern alignment film for three-dimensional display”. Description is omitted.

  The rod-shaped compound contained in the retardation layer forming coating solution used in this step has refractive index anisotropy, and is arranged in a regular manner along the alignment regulating force of the alignment region. There is no particular limitation as long as a desired retardation can be imparted to the retardation layer. Especially, it is preferable that the rod-shaped compound used for this process is a liquid crystalline material which shows liquid crystallinity. This is because the liquid crystalline material has a large refractive index anisotropy, so that it becomes easy to impart desired retardation to the patterned retardation film produced by the production method of the present invention.

  As said liquid crystalline material used for this process, the material which shows liquid crystal phases, such as a nematic phase and a smectic phase, can be mentioned, for example. In this step, any material exhibiting any of these liquid crystal phases can be suitably used, but it is particularly preferable to use a liquid crystalline material exhibiting a nematic phase. This is because a liquid crystalline material exhibiting a nematic phase is easily arranged regularly as compared with liquid crystalline materials exhibiting other liquid crystal phases.

  In this step, it is preferable to use a material having spacers at both ends of the mesogen as the liquid crystalline material exhibiting the nematic phase. Since the liquid crystalline material having spacers at both ends of the mesogen is excellent in flexibility, by using such a liquid crystalline material, the pattern retardation film produced by the production method of the present invention can be made excellent in transparency. It is.

  Furthermore, as the rod-shaped compound used in this step, those having a polymerizable functional group in the molecule are preferably used, and among them, those having a polymerizable functional group capable of three-dimensional crosslinking are more preferably used. Since the rod-shaped compound has a polymerizable functional group, the rod-shaped compound can be polymerized and fixed, so that a retardation layer having excellent alignment stability and hardly causing a change in retardation with time is obtained. Because you can. In addition, when the rod-shaped compound which has a polymerizable functional group is used, the phase difference layer formed by performing this process will contain the rod-shaped compound bridge | crosslinked by the polymerizable functional group.

  The “three-dimensional cross-linking” means that liquid crystal molecules are polymerized three-dimensionally to form a network (network) structure.

  Examples of the polymerizable functional group include polymerizable functional groups that are polymerized by the action of ionizing radiation such as ultraviolet rays and electron beams, or heat. Representative examples of these polymerizable functional groups include radically polymerizable functional groups or cationic polymerizable functional groups. Further, representative examples of radically polymerizable functional groups include functional groups having at least one addition-polymerizable ethylenically unsaturated double bond, and specific examples include vinyl groups having or not having substituents, An acrylate group (generic name including an acryloyl group, a methacryloyl group, an acryloyloxy group, and a methacryloyloxy group) and the like can be given. Moreover, an epoxy group etc. are mentioned as a specific example of the said cation polymerizable functional group. In addition, examples of the polymerizable functional group include an isocyanate group and an unsaturated triple bond. Among these, from the viewpoint of the process, a functional group having an ethylenically unsaturated double bond is preferably used.

Furthermore, the rod-like compound in this step is a liquid crystalline material exhibiting liquid crystallinity, and those having the polymerizable functional group at the terminal are particularly preferable. By using such a rod-like compound, for example, it can be polymerized three-dimensionally into a network (network) structure, so that it has column stability and excellent optical characteristics. This is because the above can be formed.
In this step, even when a liquid crystalline material having a polymerizable functional group at one end is used, the alignment can be stabilized by crosslinking with other molecules.

  Specific examples of the rod-like compound used in this step include compounds represented by the following formulas (1) to (17).

  In addition, in this process, only 1 type may be used for the said rod-shaped compound, or 2 or more types may be mixed and used for it. For example, when the rod-shaped compound is used by mixing a liquid crystalline material having one or more polymerizable functional groups at both ends and a liquid crystalline material having one or more polymerizable functional groups at one end, The polymerization density (crosslinking density) and the optical properties are preferably adjusted by adjusting the ratio. Further, from the viewpoint of ensuring reliability, a liquid crystalline material having one or more polymerizable functional groups at both ends is preferable, but from the viewpoint of liquid crystal alignment, it is preferable that there is one polymerizable functional group at both ends. .

  The content of the rod-shaped compound used in this step in the coating solution for forming the retardation layer is set to a desired value for the viscosity of the coating solution for forming the retardation layer depending on the coating method applied on the alignment layer. There is no particular limitation as long as it is possible. Especially in this process, it is preferable that it exists in the range of 5 mass%-30 mass% in the said coating liquid for phase difference layer formation, and it exists in the range of 10 mass%-20 mass% especially. Is preferred.

The retardation layer forming coating solution used in this step contains at least the rod-like compound, but usually contains a solvent. Moreover, you may contain another compound as needed.
Such a solvent is not particularly limited as long as it can uniformly dissolve or disperse the rod-like compound, but it is described in the above section “C. Method for producing pattern alignment film for three-dimensional display”. It can be similar to the content.

The other compound is not particularly limited as long as it does not impair the arrangement order of the rod-like compound in the retardation layer formed by this step. As said other compound used for this process, a chiral agent, a polymerization initiator, a polymerization inhibitor, a plasticizer, surfactant, a silane coupling agent etc. can be mentioned, for example.
In this step, when the polymerizable liquid crystal material is used as the rod-shaped compound, it is preferable to use a polymerization initiator or a polymerization inhibitor as the other compound.

  Examples of the polymerization initiator include benzophenone, methyl o-benzoylbenzoate, 4,4-bis (dimethylamine) benzophenone, 4,4-bis (diethylamine) benzophenone, α-amino acetophenone, 4,4-dichloro. Benzophenone, 4-benzoyl-4-methyldiphenyl ketone, dibenzyl ketone, fluorenone, 2,2-diethoxyacetophenone, 2,2-dimethoxy-2-phenylacetophenone, 2-hydroxy-2-methylpropiophenone, p- tert-Butyldichloroacetophenone, thioxanthone, 2-methylthioxanthone, 2-chlorothioxanthone, 2-isopropylthioxanthone, diethylthioxanthone, benzyldimethyl ketal, benzylmethoxyethyl acetal, benzo Methyl ether, benzoin butyl ether, anthraquinone, 2-tert-butylanthraquinone, 2-amylanthraquinone, β-chloroanthraquinone, anthrone, benzanthrone, dibenzsuberone, methyleneanthrone, 4-azidobenzylacetophenone, 2,6-bis (p- Azidobenzylidene) cyclohexane, 2,6-bis (p-azidobenzylidene) -4-methylcyclohexanone, 2-phenyl-1,2-butadion-2- (o-methoxycarbonyl) oxime, 1-phenyl-propanedione-2 -(O-ethoxycarbonyl) oxime, 1,3-diphenyl-propanetrione-2- (o-ethoxycarbonyl) oxime, 1-phenyl-3-ethoxy-propanetrione-2- (o-benzoyl) oxy , Michler's ketone, 2-methyl-1 [4- (methylthio) phenyl] -2-morpholinopropan-1-one, 2-benzyl-2-dimethylamino-1- (4-morpholinophenyl) -butanone, naphthalene Sulfonyl chloride, quinoline sulfonyl chloride, n-phenylthioacridone, 4,4-azobisisobutyronitrile, diphenyl disulfide, benzthiazole disulfide, triphenylphosphine, camphorquinone, Adeka N1717, carbon tetrabromide, tri Examples include combinations of photoreducing dyes such as bromophenyl sulfone, benzoin peroxide, eosin, and methylene blue with reducing agents such as ascorbic acid and triethanolamine. In this step, these photopolymerization initiators can be used alone or in combination of two or more.

  Furthermore, when using the said photoinitiator, a photoinitiator adjuvant can be used together. Examples of such photopolymerization initiation assistants include tertiary amines such as triethanolamine and methyldiethanolamine, and benzoic acid derivatives such as ethyl 2-dimethylaminoethylbenzoate and ethyl 4-dimethylamidebenzoate. Yes, but not limited to these.

  Examples of the polymerization inhibitor include diphenylpicrylhydrazide, tri-p-nitrophenylmethyl, p-benzoquinone, p-tert-butylcatechol, picric acid, copper chloride, methylhydroquinone, methoquinone, tert-butylhydroquinone and the like. Although a polymerization inhibitor for the reaction can be used, a hydroquinone polymerization inhibitor is preferred from the viewpoint of storage stability, and methyl hydroquinone is particularly preferred.

  In addition, other compounds as shown below can be added to the retardation layer forming coating solution in this step. Other compounds that can be added include, for example, a polyester (meth) acrylate obtained by reacting a (meth) acrylic acid with a polyester prepolymer obtained by condensing a polyhydric alcohol with a monobasic acid or polybasic acid; a polyol Polyurethane (meth) acrylate obtained by reacting a group and a compound having two isocyanate groups with each other and then reacting the reaction product with (meth) acrylic acid; bisphenol A type epoxy resin, bisphenol F type epoxy resin , Epoxy resins such as novolac type epoxy resin, polycarboxylic acid polyglycidyl ester, polyol polyglycidyl ether, aliphatic or cycloaliphatic epoxy resin, amino group epoxy resin, triphenolmethane type epoxy resin, dihydroxybenzene type epoxy resin, (Meta) Photopolymerizable compound in epoxy (meth) acrylate obtained by reacting an acrylic acid; photopolymerizable liquid crystal compound having an acryl group or methacryl group and the like.

  The coating method for the retardation layer forming coating liquid in this step is not particularly limited as long as it can stably form a coating film made of the retardation layer forming coating liquid on the alignment layer. . In this step, specifically, it can be the same as the method for forming the alignment layer forming layer described in the above section “C. Method for producing pattern alignment film for three-dimensional display”.

  The thickness of the coating film formed in this step is not particularly limited as long as it is within the range in which a predetermined retardation can be achieved after the orientation step described later, and is manufactured by the manufacturing method of the present invention. It is appropriately determined according to the use of the pattern retardation film.

  In this step, in particular, when the direction in which the rod-like compounds in the first alignment region and the second alignment region are arranged is a direction orthogonal to each other such as 45 ° / 135 ° or 0 ° / 90 °, The in-plane retardation of the first retardation region and the second retardation region formed on the first alignment region and the second alignment region is set to a thickness that falls within a range corresponding to λ / 4 minutes. It is preferable to apply. This is because the linearly polarized light becomes circularly polarized light that is orthogonal to each other by transmitting through these phase difference regions, so that it can be suitably used for manufacturing a display device that can easily perform three-dimensional display. .

  Further, the rod-like compounds in the first alignment region and the second alignment region are arranged such that the direction in which the rod-like compounds in the first alignment region and the second alignment region are arranged is 0 ° / 45 ° or 0 ° / 135 °. When the direction is an angle of 45 °, the in-plane retardation value is applied only to the first retardation region so as to have a thickness corresponding to λ / 2 minutes. Alternatively, it is preferable that the in-plane retardation values of the first retardation region and the second retardation region are applied so as to have thicknesses in a range corresponding to λ / 2. This is because, by using in combination with the λ / 4 plate in which the direction of the slow axis of the first phase difference region and the slow axis are parallel, it can be easily used for manufacturing a three-dimensional display device. .

In this step, when the in-plane retardation after the alignment step is set to a thickness within a range corresponding to λ / 4 minutes, the specific thickness depends on the type of rod-shaped compound. Will be decided. However, if the thickness is a rod-like compound that is generally used in this step, it is usually preferable that the thickness after the alignment step is in the range of 0.1 μm to 1.9 μm, and 0.25 μm. More preferably, it is within the range of ˜1.75 μm, and even more preferably within the range of 0.5 μm to 1.5 μm.
When the distance is within a range corresponding to λ / 2 minutes, it is usually preferably within a range of 0.5 μm to 4 μm, and preferably within a range of 1 μm to 3 μm. More preferably, it is more preferably in the range of 1.5 μm to 2.5 μm.

2. Alignment Step The alignment step in the present invention is a micro uneven shape formed in the first alignment region and the second alignment region included in the alignment layer, with the rod-shaped compound included in the coating film of the retardation layer forming coating solution. It is the process of arranging along the direction.

  The method for arranging the rod-shaped compounds in this step along the direction of the fine unevenness formed in the first alignment region and the second alignment region is particularly limited as long as it can be arranged in a desired direction. However, when the rod-shaped compound is a liquid crystalline material, a method of heating the coating film to a temperature higher than the liquid crystal phase forming temperature of the rod-shaped compound is used. Specifically, although it differs depending on the kind of the rod-like compound, a method of heating within a range of 50 ° C to 60 ° C can be mentioned.

The retardation layer formed in this step is formed of the alignment layer formed by using the above-described pattern alignment film manufacturing method, so that the first retardation region and the second retardation region are The first alignment region and the second alignment region are formed in the same pattern as the pattern formed.
In addition, the pattern which consists of a 1st phase difference area | region and a 2nd phase difference area | region is formed in the phase difference layer formed in this process, for example, putting a sample in polarizing plate cross Nicol, It can be evaluated by confirming that the bright line and the dark line are reversed when rotated. At this time, when the pattern composed of the first phase difference region and the second phase difference region is fine, the pattern may be observed with a polarizing microscope. Further, the direction (angle) of the slow axis in each pattern may be measured by AxoScan described later.

The in-plane retardation value of the retardation layer formed by this step is not particularly limited as long as a desired three-dimensional image can be displayed. Use of the patterned retardation film produced by the present invention It can be appropriately determined according to the above. Accordingly, the numerical range of the specific in-plane retardation indicated by the first retardation region and the second retardation region is not particularly limited, depending on the use of the pattern retardation film produced by the present invention. What is necessary is just to adjust suitably.
In this step, in the case where the in-plane retardation value of the retardation layer corresponds to λ / 4 minutes, specifically, it is preferably in the range of 100 nm to 160 nm, More preferably within the range of 150 nm, even more preferably within the range of 120 nm to 140 nm.
In the case where the in-plane retardation value corresponds to λ / 2 minutes, it is usually preferably in the range of 200 nm to 300 nm, more preferably in the range of 220 nm to 280 nm, and 230 nm. Particularly preferably, it is in the range of ˜270 nm.

Here, the in-plane retardation value is an index indicating the degree of birefringence in the in-plane direction of the refractive index anisotropic body, and the refractive index in the slow axis direction having the largest refractive index in the in-plane direction is represented by Nx. When the refractive index in the fast axis direction orthogonal to the slow axis direction is Ny and the thickness in the direction perpendicular to the in-plane direction of the refractive index anisotropic body is d,
Re [nm] = (Nx−Ny) × d [nm]
It is a value represented by. The in-plane retardation value (Re value) can be measured by, for example, KOBRA-WR manufactured by Oji Scientific Instruments Co., Ltd. by the parallel Nicol rotation method, and the in-plane retardation value of a minute region is AXOMETRICS (USA). Measurements can also be made using a Mueller matrix with an AxoScan made by the manufacturer. In the present specification, unless otherwise stated, the Re value means a value at a wavelength of 589 nm.

3. Method for Producing Pattern Retardation Film The method for producing a pattern phase difference film of the present invention includes at least the coating step and the orientation step. If necessary, a coating solution for forming a retardation layer is provided after the coating step. When the polymerizable liquid crystal material is used as the rod-like compound, a drying step for drying the coating film may be provided.

As a method for drying the coating film in the drying step, a commonly used drying method such as a heat drying method, a reduced pressure drying method, a gap drying method, or the like can be used. Further, the drying method in this step is not limited to a single method, and a plurality of drying methods may be employed, for example, by changing the drying method sequentially according to the amount of remaining solvent.
Furthermore, as a method for drying the coating film, a method of applying a drying air adjusted to a certain temperature to the coating film can be used. When using such a drying method, the method is applied to the coating film. The wind speed of the drying wind is preferably 3 m / second or less, and particularly preferably 30 m / minute or less.

  What is necessary is just to determine arbitrarily as a polymerization method of the polymeric liquid crystal material in the said superposition | polymerization process according to the kind of polymeric functional group which polymeric liquid crystal material has. In particular, in this step, a method of curing by irradiation with actinic radiation is preferable. The actinic radiation is not particularly limited as long as it is a radiation capable of polymerizing the polymerizable liquid crystal material, but it is usually preferable to use ultraviolet light or visible light from the viewpoint of the ease of the apparatus. .

Further, in the present invention, an adhesive layer forming step (FIGS. 16A to 16B) for forming the adhesive layer 16 on the retardation layer as illustrated in FIG. 16 and a separator laminating step for laminating the separator 17 ( 16 (b) to (c)), and after the orientation step, a long pattern retardation film is cut, and a cutting step for obtaining a pattern retardation film formed on a sheet is obtained. Also good.
In addition, about the code | symbol in FIG. 16, since it shows the same member as the thing of FIG. 15, description here is abbreviate | omitted.

In the present invention, each of these steps is performed independently, that is, after unwinding the long pattern alignment film or the like from the state wound in a roll shape for each step and performing a predetermined treatment. Although it may be wound, it is preferable that all the steps are performed continuously, that is, the raw material is rolled to roll.
Specifically, when the pattern alignment film manufactured by the above-described method for manufacturing a pattern alignment film is long, the pattern retardation film as the final product is rolled from the long pattern alignment film. It is preferable to be manufactured by roll-to-roll without being wound into a shape.

4). Pattern Retardation Film As a use of the pattern retardation film produced according to the present invention, it can be used for a display device for three-dimensional display, and in particular, used for a display device that requires high quality and low cost. Is preferred.

  The present invention is not limited to the above embodiment. The above-described embodiment is an exemplification, and the present invention has any configuration that has substantially the same configuration as the technical idea described in the claims of the present invention and that exhibits the same effects. Are included in the technical scope.

  Hereinafter, the present invention will be specifically described with reference to examples.

[Example]
A copper plate having a size of 10 cm × 10 cm was prepared, polished in the left-right direction with an abrasive (Kaneyo TM manufactured by Kaneyo Soap Co., Ltd.), and washed. Then, it cut | disconnected so that the space | interval of a stripe might be set to 500 micrometers in the up-down direction with the diamond byte which has the unevenness | corrugation with a pitch of 200 nm produced by FIB process. Thereafter, a UV curable resin (Unidic RC23-207 manufactured by DIC Corporation) was applied onto the copper plate, and a primer for improving adhesion (Unidic RC20-075 manufactured by DIC Corporation) was applied thereon. A film (Fuji Film manufactured by Fuji Film Co., Ltd.) was placed and adhered, and irradiated with ultraviolet rays to be cured.
Next, the said transparent film base material was peeled from the copper plate, and the alignment layer was formed on the said transparent film base material by shaping an uneven | corrugated shape on a transparent film base material. When the cross-sectional shape of the alignment layer was observed with an SEM, 200 nm pitch irregularities and irregular fine irregularities were alternately observed.
Next, a solution obtained by adding 5% by weight of a photopolymerization initiator (Irgacure 184 manufactured by BASF Corporation) to a solution of a liquid crystalline material represented by the following structural formula dissolved in cyclohexanone at a solid content of 15% is used as the alignment layer. The film was coated on a transparent film substrate with a spin coater, dried at 80 ° C. for 10 minutes, and cured by irradiating with ultraviolet rays to prepare a pattern retardation film.
When the prepared pattern retardation film was placed in a polarizing plate crossed Nicol and rotated, stripes with a width of 500 μm appeared as a repeating pattern of light, dark, light, and dark. Inverted.
In addition, although the abrasive | polishing agent was used for this rubbing, you may use the cloth for rubbing currently used for LCD manufacture.

  When the pattern retardation film was bonded in correspondence with the left and right lines of the color filter of the liquid crystal display capable of three-dimensional display and viewed with left and right circularly polarized glasses, a three-dimensional image was seen.

DESCRIPTION OF SYMBOLS 1 ... Base material 2a ... 1st pattern part 2b ... 2nd pattern part 10 ... Master plate for pattern orientation layer 11 for three-dimensional display 11 ... Transparent film base material 12 ... Orientation layer 12a ... 1st orientation area 12b ... 2nd orientation area 13 ... retardation layer 13a ... first retardation region 13b ... second retardation region 20 ... pattern alignment film 30 ... pattern retardation film

Claims (1)

For three-dimensional display having a roll-shaped substrate having on its surface a first pattern portion having a fine uneven shape formed in a certain direction and a second pattern portion having the fine uneven shape formed in a direction different from the first pattern. A method for producing a pattern alignment layer master,
A first pattern forming step of preparing the roll-shaped substrate, and forming a fine uneven shape in a certain direction on the entire surface of the roll-shaped substrate;
Fine irregularities formed on the entire surface of the roll-shaped substrate, by using the byte scraping the band-shaped and the rotational direction of the roll-shaped substrate, and said the area scraped first pattern forming step A second pattern forming step of forming fine concavo-convex shapes in different directions in different directions;
A method for producing a master for a pattern alignment layer for three-dimensional display, comprising: