JP5760512B2 - Patch transfer medium manufacturing method and patch transfer medium - Google Patents

Description

  The present invention relates to a method for producing a patch transfer medium. More specifically, the present invention relates to a patch transfer capable of transferring a patch formed by protecting a printed layer with a hard coat layer having excellent scratch resistance and a substrate to a fibrous substrate with good transferability. The present invention relates to a medium manufacturing method and a patch transfer medium.

  In the present specification, “ratio”, “part”, “%” and the like indicating the composition are based on mass unless otherwise specified, and the “/” mark indicates that they are integrally laminated. “PET” is an abbreviation, synonym, functional expression, common name, or industry term for “polyethylene terephthalate” and “dry lamination” for “DLM”. The “hologram” also includes “hologram and those having a light diffractive function such as a diffraction grating. Furthermore, the ionizing radiation curable resin is cured by irradiation with ionizing radiation to become an ionizing radiation curable resin.

(Background Art) In recent years, personal preferences have been diversified and personalized, and many personal products have a tendency to produce a variety of small lots. For stationery and apparel products, there is a demand for only one product per person. However, traditional fabric materials such as cloth and paper, such as decoration on T-shirts, can be directly screen-printed or transferred to T-shirts after printing on transfer paper by offset or screen printing. After transfer, there was a problem that the decoration became the outermost surface and was inferior in durability. In addition, a hard coat layer heat transfer film having a heat transferable resin layer is superimposed on the decorative surface, and the heat transferable resin layer having transparency is transferred using an iron or a heating roll to form a protective layer on the decoration. Things have been done. However, since the above protective layer needs to be partially transferred at the time of transfer by an iron or a heat roll, it needs to have a foil cutting property. In this case, since the protective layer has to be a resin film having a thickness of about several microns, there is a disadvantage that durability such as tough scratch resistance and chemical resistance cannot be provided. Furthermore, there are types that transfer with PET and OPP films, but the films are particularly inferior in scratch resistance due to sharp objects, are easily scratched, and if the film or transfer part is thick, the flexibility of the fibrous material is impaired. However, there is a problem that if the clothes are worn, the mobility is lowered, and if the clothes are bags, the texture is impaired. Furthermore, if there is a fragile layer such as a printed layer or a reflective layer between the fibrous material and the transparent substrate when transferred to the fibrous material, it will be eroded and destroyed during washing, falling off, In addition, when using an iron when transferring to a fibrous material, it is difficult to control the temperature. For example, when it is 200 ° C. or higher, even if there is a release layer, it is softened or melted by high heat and difficult to peel off. There was also a problem.
Therefore, decorations on fabric materials such as cloth and paper can be easily transferred by anyone by heating and pressing a patch transfer medium with printing and holograms with excellent design properties with an iron etc., and are flexible even after transfer. Transfer medium that can be manufactured at a low cost without impairing movement, without lowering the motility of clothes, without sacrificing the texture of bags, and without being damaged or dropped off during washing. are Me manufacturing method GaMotomu.

JP 2008-9134 A JP 2002-274060 A JP 2004-284096 A JP 2010-5887 A

(Prior Art) Conventionally, the present applicant has known a hologram transfer foil provided with a base material, a peelable resin layer, a hologram layer also serving as a protective function, a reflective layer, and an adhesive layer (see, for example, Patent Document 1). .) However, it is a partial transfer at the time of transfer, and in order to improve the foil cutting property, the hologram layer must be a resin film with a thickness of about several microns, and is transferred to the surface of the medium to become the outermost surface. When used repeatedly, there is a drawback in that it lacks durability such as tough scratch resistance and solvent resistance.
In addition, the applicant has laminated a sheet base material provided with a resin layer and a transparent sheet provided with a hologram forming layer and a receiving layer, and the transparent sheet portion including the hologram forming layer and the receiving layer is subjected to a half cut process. An intermediate transfer recording medium that peels between a resin layer and a transparent sheet is disclosed (for example, see Patent Documents 2 to 3). However, the receiving layer is essential, and the image is printed on the receiving layer and retransferred, and there is no mention of imparting durability such as scratch resistance or solvent resistance of the image printed on the medium. There are drawbacks.
Further, the present applicant applies the patch 21 obtained by half-cutting the transfer portion 23 composed of the hard coat layer 14 / adhesive layer 29 / transparent substrate 11 / hologram layer 15 / reflection layer 17 / printing layer 18 / adhesive layer 19. A method of manufacturing the provided patch transfer medium is disclosed (for example, see Patent Document 4). However, the transfer portion 23 composed of the hard coat layer 14 / adhesive layer 29 / transparent substrate 11 / hologram layer 15 / reflection layer 17 / printing layer 18 / adhesive layer 19 is directly transferred to the fibrous material 101. The hologram layer 15 / reflective layer 17 / printing layer 18 having the property of protection is not sufficient, and there is a problem that they are slightly broken or dropped off during washing.

  In order to solve the above-described problems, the present inventors have made extensive studies and have completed the present invention. Its purpose is that anyone can easily transfer to a fiber material by heating and pressing with an iron etc., and does not impair flexibility even after transfer, and if it is a clothes, it will not reduce mobility, if it is a bag Another object of the present invention is to provide a patch transfer medium manufacturing method and a patch transfer medium that can be manufactured at low cost without damaging the texture and without being destroyed or falling off during washing.

In order to solve the above-described problems, the patch transfer medium manufacturing method according to the first aspect of the present invention is such that the transfer portion 23 half-cut into a desired shape on the surface of the release layer 13 of the support base 31 is provided. A method of manufacturing a patch transfer medium that is detachably laminated so as to form a patch 21, comprising: (1) a transparent base material 11, and a hologram layer 15 and a reflective layer 17 on one surface of the transparent base material 11. And a transfer material preparation step for preparing the transfer material 10 provided with the printing layer 18; (2) a support base 31 and a resin layer containing a thermosetting resin as a main component on one surface of the support base 31; And a support material preparation step of preparing a support material 30 for providing the release layer 13 by curing with heat, and (3) an ionizing radiation curable resin as a main component on the surface of the release layer 13 of the support material 30. Hard coat layer 1 that can be removed by curing the resin layer with ionizing radiation And the hard coat layer forming step of providing a, (4) ionizing radiation such the printed layer 18 side and a heat or UV-electron beam dry lamination method of the hard coat layer 14 surface and the transfer material 10 of the support member 30 A laminating step of forming a laminated body through the adhesive layer 29 cured in step (5), and an adhesive layer forming step of providing an adhesive layer 19 made of hot melt on the surface of the transparent substrate 11 where the laminated body is exposed. (6) Layer comprising the hard coat layer 14, the adhesive layer 29, the printing layer 18, the reflective layer 17, the hologram layer 15, the transparent base material 11, and the adhesive layer 19 serving as the transfer portion 23 A method for manufacturing a patch transfer medium, comprising: a half-cut processing step in which only a component part is subjected to a half-cut process in a desired shape to form a patch 21.
Method for producing a patch transfer medium according to the invention of claim 2, in claim 1, that is not provided the hologram layer 15 and the reflective layer 17 is a manufacturing method of the patch transfer medium to feature.
A patch transfer medium 20 according to a third aspect of the invention is the patch transfer medium 20 manufactured by the method for manufacturing a patch transfer medium according to the first or second aspect, wherein the hard coat layer 14 and the adhesive layer 29 are used. The printing layer 18, the reflection layer 17, the hologram layer 15, the transparent substrate 11 and the adhesive layer 19, or the hard coat layer 14, the adhesive layer 29, the printing layer 18, and the transparent substrate 11. And the transfer portion 23 composed of the adhesive layer 19 is subjected to a half-cut process to form a patch 21, and the patch 21 is detachably laminated on the surface of the release layer 13 of the support base 31. This is a featured patch transfer medium.
The patch transfer fibrous material according to the invention of claim 4 is formed by superposing the adhesive layer 19 surface of the patch transfer medium 20 of claim 3 and the transfer material made of the fiber material 101, and heating with an iron. After pressing, the support substrate 31 and the release layer 13 are peeled off and removed, whereby the patch 21 is transferred to the transfer body 101 and the outermost surface becomes the hard coat layer 14. The patch transfer fiber material.
The patch transfer fibrous material according to the invention of claim 5 is as defined in claim 4,
A thickness of the hard coat layer 14 is 3 to 7 [mu] m, a thickness of the adhesive layer 29 is 3 to 7 [mu] m, patch transfer to feature a thickness of the transparent substrate 11 is 12~25μm It is a fibrous material.

According to the first aspect of the present invention, since the printed layer 18 / the reflective layer 17 / the hologram layer 15 having excellent design properties are protected between the hard coat layer 14 and the transparent substrate 11, Even after transfer, it does not impair flexibility, and if worn, it will not reduce mobility, and if it is a bag, it will not damage the texture, and it will not be destroyed or dropped off during washing. There is an effect that can be manufactured.
According to the second aspect of the present invention, since the printed layer 18 having excellent design properties is protected between the hard coat layer 14 and the transparent base material 11, it is flexible even after transfer and has a good quality feeling. And, there is an effect that it can be manufactured at a low cost without being destroyed or dropped off during washing.
According to the third aspect of the present invention, it is possible to easily perform transfer by anyone by heating and pressurizing with an iron or the like and to produce at low cost.
According to the present invention of claim 4, printing and holograms having excellent design properties are decorated by transfer to a fibrous material, and have flexibility even after transfer, and have good mobility and good quality if worn. In addition, there is an effect that a patch transfer fibrous material that does not break or fall off even during washing can be obtained.
According to the present invention of claim 5, since flexibility is not lost even after transfer, if it is a garment, the mobility is not lowered, if it is a bag, the texture is not impaired, and it is also destroyed during washing. The patch transfer fiber material that does not fall off can be obtained.

It is a step figure showing a manufacturing method of a patch transfer medium of the present invention. It is sectional drawing of the transfer material prepared at the transfer material preparation process of step 1 of the manufacturing method of the patch transfer medium of this invention. It is sectional drawing of the support material prepared at the support material preparation process of step 2 of the manufacturing method of the patch transfer medium of this invention. It is sectional drawing after the hard-coat layer formation process of step 3 of the manufacturing method of the patch transfer medium of this invention. It is description of the lamination process of step 4 of the manufacturing method of the patch transfer medium of this invention, and sectional drawing of the laminated body after a lamination process. It is sectional drawing after the contact bonding layer formation process of step 5 of the manufacturing method of the patch transfer medium of this invention. It is sectional drawing of the patch transfer medium which shows one Example of this invention. It is explanatory drawing explaining the transfer to a fiber base material using the patch transfer medium of this invention. It is sectional drawing of the patch transfer fibrous raw material which shows one Example of this invention transcribe | transferred using the patch transfer medium of this invention. It is explanatory drawing explaining transfer to a fiber base material using the patch transfer medium in the case of not providing a hologram layer and a reflection layer.

  Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.

  (Patch Transfer Medium Manufacturing Method) The patch transfer medium manufacturing method of the present invention will be described. As shown in FIG. 1, the method for producing a patch transfer medium of the present invention includes (1) a transparent substrate 11 in step 1S1, and a hologram layer 15, a reflective layer 17 and a printed layer on one surface of the transparent substrate 11. A transfer material preparation step for preparing the transfer material 10 provided with 18, a (2) support base 31 in step 2S2, and a resin layer mainly composed of a thermosetting resin on one surface of the support base 31 A support material preparing step of preparing a support material 30 for providing the release layer 13 by curing with heat, and (3) in step 3S3, ionizing radiation curable resin is mainly applied to the surface of the release layer 13 of the support material 30. A hard coat layer forming step of providing a hard coat layer 14 that can be peeled off by curing a resin layer as a component with ionizing radiation; and (4) the surface of the hard coat layer 14 of the support material 30 and the transfer material 10 in step 4S4. The printed layer 18 side of Laminating process for forming a laminate through the adhesive layer 29 by the lamination method, and (5) adhesion for providing an adhesive layer 19 made of hot melt on the surface of the transparent substrate 11 exposed in the laminate in step 5S5 (6) Step 6S6 (6) The hard coat layer 14, the adhesive layer 29, the print layer 18, the reflective layer 17, the hologram layer 15, the transparent substrate 11 and A half-cut treatment step in which only the layer constituting portion composed of the adhesive layer 19 is subjected to a half-cut treatment in a desired shape to form a patch 21. That is, the manufactured patch transfer medium 20 is detachably laminated so that the transfer portion 23 half-cut into a desired shape becomes the patch 21 on the surface of the release layer 13 of the support base 31.

  (No hologram) In the present invention, as shown in FIG. 10, the hologram layer 15 and the reflective layer 17 need not be provided. In this case, (1) the transparent substrate 11 in step 1S1 and the transparent layer It becomes a transfer material preparation step of preparing the transfer material 10 having the printing layer 18 provided on one surface of the substrate 11, and in step 6S6 (6) the hard coat layer 14 and the adhesive layer 29 that become the transfer portion 23. Only the layer constituent portion composed of the print layer 18, the transparent base material 11, and the adhesive layer 19 may be a half-cut treatment step in which a half-cut treatment is applied to a desired shape to obtain a patch 21.

  (Step 1) Step 1S1 prepares (1) the transparent base material 11 of Step 1S1 and a transfer material 10 in which the hologram layer 15, the reflective layer 17 and the print layer 18 are provided on one surface of the transparent base material 11. . As shown in FIG. 2, the transfer material 10 includes a transparent substrate 11 and a hologram layer 15, a reflective layer 17, and a print layer 18 on one surface of the transparent substrate 11.

  (Transparent substrate) As the transparent substrate 11, the hard coat layer 14, the adhesive layer 29, the printing layer 18, the reflective layer 17, the hologram layer 15, the transparent substrate 11, The layer structure composed of the adhesive layer 19 is a transfer part 23, which is cut as a part of the transfer part 23 and transferred to the fibrous base material 101 which is a transfer target. Various materials can be applied depending on the application as long as they have transparency and durability such as weather resistance, friction resistance, and chemical resistance. For example, polyester resins such as polyethylene terephthalate and polyethylene naphthalate, polyamide resins, vinyl resins such as polyvinyl chloride, acrylic resins, imide resins, engineering resins such as polyarylate, polycarbonate, cyclic polyolefin resins, cellophane Examples thereof include cellulosic films. The transparent substrate 11 may be a copolymer resin containing these resins as a main component, a mixture (including an alloy), or a laminate composed of a plurality of layers. The transparent substrate 11 may be a stretched or unstretched film, but a film stretched in a uniaxial direction or a biaxial direction is preferable for the purpose of improving strength. The thickness is usually about 2.5 to 50 μm, but it does not lose flexibility even after transfer, does not deteriorate the mobility if it is clothing, does not impair the texture if it is a bag, and is also washable A thickness of 12 to 25 μm is preferred so that it will not be destroyed or fall off sometimes. Prior to coating, the transparent substrate 11 is subjected to easy adhesion treatment such as corona discharge treatment, plasma treatment, primer (also called an anchor coat, adhesion promoter, or easy adhesive) coating treatment, alkali treatment, etc. May be. Moreover, you may add additives, such as a filler, a plasticizer, a coloring agent, and an antistatic agent, as needed. A biaxially stretched polyethylene terephthalate film is preferably used because of its good heat resistance and mechanical strength.

  (Hologram layer) The hologram layer 15 may contain an ionizing radiation curable resin as a main component, and may contain additives such as silicone and filler as necessary.

  The ionizing radiation curable resin is preferably (1) an isocyanate having three or more isocyanate groups in the molecule, and (2) at least one hydroxyl group and at least two (meth) acryloyloxy groups in the molecule. Preferably using an ionizing radiation curable resin containing a polyfunctional (meth) acrylate having, or (3) a urethane (meth) acrylate oligomer which is a reaction product of a polyhydric alcohol having at least two hydroxyl groups in the molecule. May contain polyethylene wax, applied, dried, and cured with ionizing radiation to form an ionizing radiation curable resin.

  The ionizing radiation curable resin containing the urethane (meth) acrylate oligomer (referred to herein as the ionizing radiation curable resin composition M) is a cured ionizing radiation curable resin containing the urethane (meth) acrylate oligomer. Examples thereof include photocurable resins disclosed in Japanese Patent Application Laid-Open No. 2001-329031. Specific examples include MHX405 varnish (made by The Inktec Co., Ltd., ionizing radiation curable resin product name) and Iupimer UV · V3031 (manufactured by Mitsubishi Chemical Co., Ltd., product name of ionizing radiation curable resin).

  (Hologram layer formation) The hologram layer 15 is formed with the above-mentioned ionizing radiation curable resin as a main component, and silicone, filler, photopolymerization initiator, plasticizer, stabilizer, surfactant, etc. are added as necessary. , Dispersed or dissolved in a solvent, applied by a known coating method such as roll coating, gravure coating, comma coating, die coating, etc., dried and reacted (cured) with ionizing radiation after shaping the hologram (relief) Good. The thickness of the hologram layer 15 is usually about 1 to 10 μm, preferably 2 to 5 μm.

  (Hologram) Next, predetermined fine unevenness (relief structure) such as a hologram that exhibits a light diffraction effect is formed on the surface of the hologram layer 15 and cured. A hologram is a recording of interference fringes due to the interference of light between object light and reference light in an uneven relief shape, such as a laser reproduction hologram such as a Fresnel hologram, a white light reproduction hologram such as a rainbow hologram, There are color holograms utilizing the above principle, computer generated holograms (CGH), holographic diffraction gratings and the like. The relief shape is a concavo-convex shape, and is not particularly limited, and may have a fine concavo-convex shape such as light diffusion, light scattering, light reflection, light diffraction, etc., such as Fourier transform or lenticular lens. , A light diffraction pattern, and a moth eye. Further, although it does not have a light diffraction function, it may be a hairline pattern, a mat pattern, a line pattern, an interference pattern, or the like that expresses a unique glitter.

  A relief shape is formed (also referred to as replication) on the surface of the hologram layer 15. Hologram shaping can be formed by a known method. For example, when recording diffraction gratings or interference fringes of holograms as reliefs of surface irregularities, a master on which the diffraction gratings or interference fringes are recorded in irregularities is pressed. The concave / convex pattern of the original can be duplicated by using it as a mold (referred to as a stamper) and by superimposing the original on the resin layer and heat-pressing both of them with an appropriate means such as a heating roll.

  Further, the hologram pattern formed on the hologram layer 15 may be single or plural. The hologram layer 15 is irradiated with ionizing radiation during or after embossing with a stamper to cure the ionizing radiation curable resin. The ionizing radiation curable resin becomes an ionizing radiation curable resin (fine irregularities = relief structure = hologram) when it is cured (reacted) by irradiation with ionizing radiation such as ultraviolet rays or electron beams after the relief is formed.

(Reflection layer) Since the reflection layer 17 is provided on the reflection layer 17 on the relief surface of the hologram layer 15 provided with a predetermined relief structure, the reflection reflection and / or diffraction effect is enhanced. If the rate is higher, it is not particularly limited. The reflective layer 17 may be a metallic glossy reflective layer such as a metal thin film by a vacuum thin film method or the like, or a transparent reflective layer, but the metallic glossy reflective layer is partially provided and the transparent reflective layer is formed on the transfer target. Even if it is transferred to the surface of the image, it is preferable because the image can be observed. The transparent reflection layer has a substantially colorless and transparent hue, and its optical refractive index is different from that of the hologram layer. A hologram can be produced. For example, there are a thin film having a higher refractive index than the hologram layer 15 and a thin film having a lower refractive index. Examples of the former include ZnS, TiO ₂ , Al ₂ O ₃ , Sb ₂ S ₃ , SiO, SnO _2. ITO, etc., and examples of the latter include LiF, MgF ₂ , and AlF ₃ . Preferably, it is a metal oxide or nitride, specifically, Be, Mg, Ca, Cr, Mn, Cu, Ag, Al, Sn, In, Te, Fe, Co, Zn, Ge, Pb, Cd , Bi, Se, Ga, Rb, Sb, Pb, Ni, Sr, Ba, La, Ce, Au, and other oxides or nitrides, and the like can be exemplified by a mixture of two or more thereof. Also, a general light-reflective metal thin film such as aluminum can be used when it has a thickness of 200 mm or less. The transparent metal compound is formed on the relief surface of the hologram layer 15 by vacuum such as vapor deposition, sputtering, ion plating, and CVD so that the thickness of the relief layer of the hologram layer 15 is about 10 to 2000 nm, preferably 20 to 1000 nm. It may be provided by a thin film method or the like.

  (Print layer) The print layer 18 is not particularly limited, and may be printed by a known printing method such as gravure printing, screen printing or flexographic printing. The color of the printed pattern is not particularly limited, and any color, single color, multiple color, metallic, or the like may be used. The pattern of the image is not particularly limited, and may be any character, symbol, number, illustration, photograph, or the like. Since the pattern is transferred and observed from the surface of the hard coat layer 14, it may be printed so that it can be normally observed. If this is used and transferred to, for example, a T-shirt, a T-shirt having a hologram and a pattern according to preference can be obtained.

  (Step 2) Step 2S2 is (2) providing the release layer 13 on the support base 31 and one surface of the support base 31 by curing a resin layer mainly composed of a thermosetting resin with heat. A support material 30 is prepared. As shown in FIG. 3, the support material 30 is provided with a release layer 13 on a support base material 31.

  (Supporting base material) The supporting base material 31 is not particularly limited. For example, condenser paper, glassine paper, sulfuric acid paper, high-size paper, synthetic paper (polyolefin-based, polystyrene-based), high-quality paper, coated paper , Synthetic resin or emulsion-impregnated paper, polyester resins such as polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, polyamide resins, vinyl resins such as polyvinyl chloride, acrylic resins, imide resins, polyarylate, etc. Examples include engineering resins, polycarbonates, cyclic polyolefin resins, and cellulose films such as cellophane. When the peelable resin layer 33 described later is provided on the support base 31, the surface of the support base 31 may be subjected to corona discharge treatment or a primer layer may be provided in order to improve adhesion.

  The support material 30 preferably has a thickness of 10 μm to 100 μm. If the sheet base material is too thin, the patch transfer medium 20 that is obtained loses its so-called stiffness, and cannot be conveyed by a thermal transfer printer, or curled on the patch transfer medium 20 by iron transfer. And wrinkles occur. On the other hand, if the support material 30 is too thick, the resulting patch transfer medium 20 becomes too thick, and the force to drive and drive the thermal transfer printer becomes too great, causing the thermal transfer printer to fail or not be transported normally.

  (Release layer) The release layer 13 is usually a release resin, a resin containing a release agent, a curable resin that is cross-linked by ionizing radiation, and preferably a melamine-based resin, which will be described later. By combining with the hard coat layer 14 to be peeled, the peelability from the release layer 13 is stabilized, and the transferability at the time of transfer can be improved. The release layer 13 is formed by dispersing or dissolving the resin in a solvent, applying and drying the resin by a known coating method such as roll coating or gravure coating, and baking at a temperature of about 150 ° C to 200 ° C. The thickness of the release layer 13 is usually about 0.01 μm to 5.0 μm, preferably about 0.5 μm to 3.0 μm.

  (Heat resistant slipping layer) In the patch transfer medium 20, a heat resistant slipping layer may be provided on the surface opposite to the peelable resin layer 33 surface of the support base 31 as required. Since retransfer to the transfer target 101 using the patch transfer medium 20 is performed by a thermal transfer printer such as an iron, a thermal head, or a heat roll, a heat resistant slipping layer is formed to prevent adverse effects such as sticking and wrinkles due to heat. It may be provided. The resin for forming the heat-resistant slipping layer may be any conventionally known resin such as polyvinyl butyral resin, polyvinyl acetoacetal resin, acrylic resin, cellulose resin, aromatic polyamide resin, polyimide resin, polycarbonate resin, etc. Is mentioned.

  The slipperiness-imparting agent that is added to or overcoated the heat-resistant slipping layer is, for example, a layer composed of a polyalcohol polymer compound, a polyisocyanate compound, and a phosphate ester compound, and a filler may be further added. preferable. The heat resistant slipping layer is prepared by dissolving or dispersing the above-described resin, slipperiness-imparting agent, and filler with an appropriate solvent, and, for example, gravure printing or screen printing on the back surface of the support substrate 31. It may be formed by applying and drying with the like.

  (Step 3) In step 3S3, (3) a hard coat layer 14 is provided on the surface of the release layer 13 of the support member 30 by curing a resin layer containing an ionizing radiation curable resin as a main component with ionizing radiation. The configuration is as shown in FIG.

  (Hard Coat Layer) The hard coat layer 14 contains at least an ionizing radiation curable resin as a main component, and contains a filler as necessary. The ionizing radiation curable resin before curing includes (i) isocyanates having 3 or more isocyanate groups in the molecule, and (b) at least one hydroxyl group and at least two (meth) acryloyloxy groups in the molecule. A urethane (meth) acrylate oligomer that is a reaction product of polyfunctional (meth) acrylates or (C) polyhydric alcohols having at least two hydroxyl groups in the molecule, and is a urethane-modified acrylate resin having ionizing radiation curability. is there. The details of the preferred urethane (meth) acrylate oligomer are preferably photocurable resins disclosed in JP-A-2001-329031. Specific examples include MHX405 varnish (made by The Inktec Co., Ltd., ionizing radiation curable resin product name) and Iupimer UV · V3031 (manufactured by Mitsubishi Chemical Co., Ltd., product name of ionizing radiation curable resin).

  (Filler) Examples of the filler include micro silica and polyethylene wax, and examples of the polyethylene wax include polyethylene resin particles and beads, and spherical beads are preferable. The addition amount is about 0.01 to 10 parts by mass, preferably 0.1 to 5 parts by mass with respect to 100 parts by mass of the ionizing radiation curable resin. After the transfer, the hard coat layer 14 becomes the outermost layer, and the contained filler protects the medium from mechanical friction and abrasion, and also protects unique information such as an image to be described later.

  (1) By including polyethylene wax, the hard coat layer 14 becomes the outermost surface layer after transfer, but it can be used in extremely harsh environments, used for a long period of time, and / or repeatedly used many times. It protects the transferred material from solvents, mechanical friction, and abrasion, and is resistant to scratches and has excellent durability. (2) Since the hard coat layer 14 is in contact with the release layer 13 obtained by thermally curing a resin layer mainly composed of a thermosetting resin such as a melamine resin, the hard coat layer 14 and the release layer are in contact with each other. It peels between 13 and becomes stable peelability. Further, between the release layer 13 which is a thermosetting resin and the hard coat layer 14 which is an ionizing radiation curable resin, that is, both are separated between the cross-linked cured resins. Even when the temperature becomes high, none of the layers is softened and / or melted by heat, and can be peeled stably.

  The hard coat layer 14 containing an ionizing radiation curable resin and a filler preferably contains a polyester resin. The polyester resin has a number average molecular weight of 13,000 to 30,000, and 2 to 10 hydroxyl groups per molecule. The polyester polyol having is preferable in terms of flexibility and low shrinkage during curing. Examples of the polyester resin include Byron-200, Byron-103, Byron-600 (above, trade name manufactured by Toyobo Co., Ltd.), Aron Melt PES310-S30 (trade name manufactured by Toagosei Chemical Industry Co., Ltd.), etc. Thermoplastic saturated copolyester resins such as UE3400 series, UE3500 series, UE3600 series (above, product names manufactured by Unitika Ltd.) are particularly preferred.

  The blending ratio of the polyester resin to the ionizing radiation curable resin is preferably based on mass, and the ionizing radiation curable resin: polyester resin = 100: 10 to 40 is preferable, and if it is less than this range, the flexibility of the hard coat layer 14 after curing is insufficient. And the shrinkage | contraction property at the time of hardening warps greatly, and when it exceeds this range, hard coat property will be insufficient.

  (Formation of hard coat layer) First, an uncured hard coat layer may be formed and cured by irradiation with ionizing radiation. Add polyethylene wax to the above ionizing radiation curable resin, and if necessary, add polyester resin, photopolymerization initiator, plasticizer, stabilizer, surfactant, etc., disperse or dissolve in solvent, roll coat, gravure An uncured hard coat layer is formed by applying and drying by a known coating method such as coating, comma coating or die coating. The ionizing radiation may be classified according to the quantum energy of the electromagnetic wave, but in this specification, all ultraviolet rays (UV-A, UV-B, UV-C), visible light, gamma rays, X-rays, electrons It is defined as including a line. Accordingly, as the ionizing radiation, an electron beam (EB), gamma ray, X-ray, ultraviolet ray (UV), visible light, or the like can be applied, but EB or UV is preferable, and UV is more preferable from the viewpoint of handling and cost.

  (Thickness of hard coat layer) In the present invention, even in extremely harsh environments, there is no expiration date, long-term use, and / or many repeated use, solvent and mechanical friction and wear, In particular, the thickness of the hard coat layer 14 is about 1 to 25 μm in order to protect it from scratching and to provide durability against scratching. If it is a bag, 3 to 7 μm is preferable because it does not impair the texture and is not destroyed or dropped off during washing.

  (Step 4) Step 4S4 (4) The hard coat layer 14 surface of the support material 30 and the print layer 18 surface of the transfer material 10 are formed into a laminate 50 via the adhesive layer 29 by the dry lamination method, and shown in FIG. It becomes the composition like this.

  (Lamination process) The surface of the hard coat layer 14 provided on the surface of the release layer 13 of the support material 30 and the surface of the printing layer 18 of the transfer material 10 are laminated by a dry lamination method through an adhesive 19. The dry lamination method is a method in which an adhesive dispersed or dissolved in a solvent is applied and dried, and after laminating and laminating bonded substrates, the adhesive is aged for several hours to several days at room temperature to 120 ° C. It is a method of laminating two kinds of materials by curing.

  (Adhesive) As an adhesive for the adhesive layer 29 used in the dry lamination method, an adhesive that cures by heat or ionizing radiation such as ultraviolet rays or electron beams can be applied. As the thermosetting adhesive, specifically, for example, a polymer obtained by reaction of a polyfunctional isocyanate and a hydroxyl group-containing compound, specifically, an aromatic polyisocyanate such as tolylene diisocyanate, or the like , A two-component curable urethane system obtained by reacting a polyfunctional isocyanate such as an aliphatic polyisocyanate such as hexamethylene diisocyanate with a hydroxyl group-containing compound such as a polyether polyol, polyester polyol or polyacrylate polyol In addition to adhesives, polyester urethane adhesives, polyether urethane adhesives, acrylic adhesives, polyester adhesives, polyamide adhesives, epoxy adhesives, etc. can be applied, but two-component curable urethane adhesives Agents are preferred.

In the dry lamination method, the adhesive layer 29 composition containing these as a main component is dissolved or dispersed in an organic solvent, and this is applied to the hard coating of the support material 30 by a known coating method such as roll coating or gravure coating. It is applied to the surface of the layer 14 and dried to form an adhesive layer 29. The adhesive layer 29 is immediately overlapped with the surface of the printing layer 18 of the transfer material 10 and then aged at room temperature to 120 ° C. for several hours to several days. Adhere by curing. The reverse side may be applied to the surface on which the adhesive layer 29 composition is applied. Further, an easy adhesion treatment or a primer layer may be provided on the hard coat layer 14 surface of the support material 30 and / or the print layer 18 surface of the transfer material 10 in order to promote adhesion.
The film thickness of the adhesive layer 29 is about 0.1 to 20 μm (dry state), preferably without losing flexibility even after transfer, and if it is a garment, the mobility is not lowered. Aging (curing) over time at room temperature is preferred because it does not impair the texture, and is not destroyed or dropped off during washing, so 3-7 μm is suitable and flexibility is not lost. Is preferable.

  (Step 5) Step 5S5 is an adhesive layer forming step in which (5) the adhesive layer 19 made of hot melt is provided on the surface of the transparent substrate 11 where the laminate 50 is exposed, and has a configuration as shown in FIG.

(Adhesive layer) The adhesive layer 19 is not particularly limited as long as it is a heat-sensitive or pressure-sensitive adhesive that does not have adhesiveness at normal temperature or normal pressure, and exhibits adhesive force only when heated or pressurized. A resin having a relatively low melting point such as a vinyl resin, a vinyl chloride-vinyl acetate copolymer resin, a polyurethane resin, or a polyester resin is preferable. The resin as described above may be melted by heat to form a liquid, which may be applied and cooled by roll coating, comma coating, or hot malt applicator method. Further, the adhesive layer 19 may contain a white pigment, an extender pigment, and a fluorescent brightening agent, which can improve the whiteness after transfer or conceal the color of the fibrous base material 101.
Since the transferred material penetrates through the porous fibrous base material 101, the thickness is preferably about 15 to 150 μm, and 15 to 50 μm is preferable so as not to impair flexibility.

  (Step 6) Step 6S6 is (6) a layer constituent part consisting of a hard coat layer 14, an adhesive layer 29, a printing layer 18, a reflection layer 17, a hologram layer 15, a transparent base material 11, and an adhesive layer 19 serving as a transfer portion 23. This is a half-cut process step in which only a desired shape is subjected to a half-cut process to form a patch 21, and the patch 21 is detachably laminated on the surface of the release layer 13 of the support material 30.

  (Half-cut process) As a half-cut treatment method, a method of moving the upper die up and down by inserting the patch transfer medium 20 in a stacked state before cutting between the upper die attached with a cutter blade and the pedestal, or a cylinder There is no particular limitation as long as it is a method capable of half-cutting, such as a type of rotary cutter method or a heat treatment method using laser processing means. It is not necessary to remove the patch 21 portion and other portions, but as shown in the cross section of the patch transfer medium 20 shown in FIG. It is preferable to keep it (referring to those skilled in the art as scrap removal). When the patch 21 is transferred to the transfer target, the transparent substrate 11 is not cut at the half-cut portion and can be transferred reliably.

  In general, half-cutting is performed by continuously cutting around the patch 21 in units of one round, and by partially providing uncut (no cut) parts such as four corners or perforated parts. It is possible to prevent troubles in which the half-cut portion is peeled off during handling such as transporting a thermal transfer printer. In addition, at least one part of the support material 30 is not cut and is made continuous. If the cutting depth is too deep in the half-cut processing, the support base material 31 is cut, and the printer is cut at the half-cut processing section during printer conveyance, which easily causes a conveyance trouble.

  Although it does not specifically limit as a shape of the patch 21, For example, a rectangle, an ellipse, a round shape, a donut shape etc. can be illustrated. The half-cut patch 21 portion may be smaller than the entire size of the transfer target body, and the patch 21 portion may be partially removed from the transfer body. Furthermore, the entire width of the patch transfer medium 20 may be wider than the width of the surface to which the transfer target is transferred.

  (Patch Transfer Medium) The transfer portion 23 of the patch transfer medium 20 is half-cut into a patch 21 and is detachably laminated on the surface of the release layer 13 of the support material 30. As described above, the patch transfer medium 20 of the present invention manufactured by the method of manufacturing a patch transfer medium of the present invention has a hard coat layer 14 / adhesive on the surface of the release layer 13 comprising the support base 31 / release layer 13. A patch 21 obtained by half-cutting the transfer portion 23 composed of the layer 29 / printing layer 18 / reflection layer 17 / hologram layer 15 / transparent substrate 11 / adhesive layer 19 is detachably stacked.

  (Patch Transfer Fiber Base Material) As shown in FIG. 8, the adhesive layer 19 surface of the patch transfer medium 20 of the present invention and the transfer material made of the fiber material 101 were superposed and heated and pressed with an iron or the like. After that, the support substrate 31 / release layer 13 is peeled off and removed, whereby the patch 21 is transferred to the fibrous material 101 and becomes the patch transfer fibrous material 100 of FIG.

  (Transfer to be transferred) The fibrous material 101 is a transferred material, but is not particularly limited as long as it is a fibrous material. Paper fibers, woven fabrics, non-woven fabrics such as paper pulp, natural or synthetic resin fibers, and glass fibers are used. Etc. can be exemplified. The form is not particularly limited, and examples thereof include paper such as notebooks and catalogs, clothing such as T-shirts, aprons, and hats, and shoes. Further, the medium of the fibrous material 101 may be colored, printed, or otherwise decorated on at least a part thereof.

  (Transfer method) As a transfer method for transferring to a transfer target, a known transfer method may be used, and an iron is exemplified. For example, hot stamping by hot stamping (foil stamping), transfer by a hot roll, thermal head (heat sensitive) A known method such as a thermal printer (also called a thermal transfer printer) using a printing head) can be applied. Further, it may be transferred by heating in accordance with the shape of the patch 21.

  (Durability) It is peeled off at the interface between the release layer 13 and the hard coat layer 14 by transfer, and the hard coat layer 14 / adhesive layer 29 / printing layer 18 / reflection layer 17 / A patch 21 comprising the hologram layer 15 / transparent substrate 11 / adhesive layer 19 is transferred. That is, the hard coat layer 14 surface is the front surface, the transparent base material 11 is the back surface, and the three layers of the print layer 18 / reflective layer 17 / hologram layer 15 or one layer of the print layer 18 having excellent design properties are provided. Strong protection. Even after repeated use, the surface of the patch transfer fibrous material 100 is protected and can be maintained from mechanical and chemical damage for a long period of time. In particular, the hard coat layer 14 is excellent in tough scratch resistance even when scratched by a sharp object. Further, when the hard coat layer 14 is an ionizing radiation curable resin containing a polyester resin, it has excellent tough scratch resistance and flexibility, withstands bending of the patch transfer fibrous material 100, and at the time of curing. The transferability is stable because there is little shrinkage and no warping. Furthermore, the film-like transparent substrate 11 is excellent in physical and scientific durability such as heat resistance and solvent resistance. Furthermore, the hologram of the hologram layer 15 and the design of the printed layer 18 are excellent in design and security.

  If the transferred patch 21 is too thick, the flexibility of the fibrous material 101 will be hindered, the flexibility will be lost after the transfer, and if it is clothing, the mobility will be reduced, and if it is a bag, the texture will be damaged. In addition, there is a drawback that the folds and cross-sections are broken or fallen off even when washing. However, in particular, if the thickness of the hard coat layer is 3 to 7 μm, the thickness of the adhesive layer 29 is 3 to 7 μm, and the thickness of the transparent substrate 11 is 12 to 25 μm, it is strongly protected. It is flexible even after transfer, and if it is clothes, it has good mobility and good quality, and it is difficult to break or fall off even during washing. Further, the hard coat layer 14 is 3 to 7 μm, the adhesive layer 29 is 3 to 7 μm, the printed layer 18 is 0 to 6 μm, the reflective layer 17 is 0.02 to 1 μm, the hologram layer 15 is 2 to 5 μm, and the transparent substrate 11 Is 12 to 25 μm, the adhesive layer 19 is 15 to 50 μm, and the total thickness of the patch 21 is preferably about 35 to 101 μm.

  EXAMPLES Hereinafter, although an Example and a comparative example demonstrate this invention further in detail, it is not limited to this.

Example 1
(S1) A transparent material 11 and a transfer material preparation step of preparing a transfer material 10 in which the hologram layer 15, the reflective layer 17, and the print layer 18 are provided on one surface of the transparent substrate 11. Using a 16 μm thick PET film, the following hologram layer composition was applied to one surface of the substrate 11 with a gravure reverse coater so that the thickness after drying was 3 μm and dried at 100 ° C. .
・ <Hologram layer composition>
Iupimer UV-V3031 (Mitsubishi Chemical Corporation, UV curable resin trade name) 100 parts Reactive silicone (Shin-Etsu Chemical Co., trade name X-22-1602) 0.5 part Polyethylene wax (average particle size 3-5 μm, Spherical) 2 parts Photopolymerization initiator (manufactured by Ciba, trade name Irgacure 184) 5 parts Solvent (methyl ethyl ketone: ethyl acetate = 1: 1) 300 parts Next, 2P method from the diffraction grating by the two-beam interference method to the layer surface A press die having a pseudo continuous pattern duplicated in (1) was attached to an embossing roller of a duplicating apparatus and heated and pressed (embossed) with an opposing roller to form a relief composed of a fine uneven pattern. Immediately after the shaping, the hologram layer 15 was formed by irradiating and curing with ultraviolet rays using a high-pressure mercury lamp.
Titanium oxide having a thickness of 50 nm was formed on the relief surface of the hologram layer 15 by a vacuum deposition method to form a transparent reflective layer 17. Printed with transparent pink ink on the surface of the reflective layer 17 through a primer layer made of an equal mixture of polyester resin and vinyl chloride-vinyl acetate copolymer resin, with a small heart shape scattered by silk screen printing. The printing material 18 was provided by drying, and the transfer material 10 having a layer structure of transparent substrate 11 / hologram layer 15 / reflection layer 17 / printing layer 18 was obtained.
(S2) A support base material 31 and a support material 30 that provides the release layer 13 on one surface of the support base material 31 by curing a resin layer mainly composed of a thermosetting resin with heat are prepared. Support material preparation step Using a PET film having a thickness of 50 μm as the support substrate 31, a heat-resistant slipping layer composition composed of a known polyimide resin is applied to one surface so that the coating amount after drying is 2 μm. And then drying at 100 ° C. to form a heat-resistant slipping layer, applying the following release layer resin composition (coating solution) to the other side by gravure coating to a thickness of 2 μm and drying. Then, baking was performed at 180 ° C. for 20 seconds to form the release layer 13, and the support material 30 composed of the heat resistant slipping layer / support base material 31 / release layer 13 was obtained.
・ <Resin layer resin composition>
TCM01 medium (Dainippon Ink Co., Ltd., melamine resin trade name) 25 parts Solvent (MEK: toluene = 1: 1) 75 parts (S3) Main component of ionizing radiation curable resin on the surface of the release layer 13 of the support 30 A hard coat layer forming step of curing the resin layer with ionizing radiation to provide a removable hard coat layer 14 The following hard coat layer composition is applied to the surface of the release layer 13 of the support 30 with a gravure reverse coater. After coating and drying at 100 ° C. so that the thickness after drying was 5 μm, the hard coat layer 14 was provided by irradiating with an ultraviolet ray using a high-pressure mercury lamp and curing.
・ <Hard coat layer composition>
Iupimer UV-V3031 (manufactured by Mitsubishi Chemical Corporation, UV curable resin product name) 100 parts Elitel 3520EA (manufactured by Unitika Co., Ltd., copolymerized polyester resin product name) 20 parts Polyethylene wax (average particle size 3 to 5 μm, spherical) 5 parts light Polymerization initiator (trade name Irgacure 184, manufactured by Ciba) 5 parts Solvent (methyl ethyl ketone: ethyl acetate = 1: 1) 300 parts (S4) The hard coat layer 14 surface of the support material 30 and the printing of the transfer material 10 Laminating process of layer 18 surface with adhesive layer 29 by dry lamination method To the above hard coat layer surface, the thickness after drying the following primer layer composition with a gravure coater becomes 0.5 μm The primer layer was formed by coating and drying at 100 ° C. The following adhesive layer composition was applied to the primer layer surface with a gravure reverse coater so as to have a thickness of 5 μm, and immediately pressed onto the printing layer 18 surface of the transfer material 10 and laminated at room temperature. The laminate 50 was cured for one day.
・ Primer layer composition
Byron 300 (trade name, manufactured by Toyobo Co., Ltd.) 50 parts Vinyl chloride vinyl acetate copolymer resin 50 parts Solvent (toluene: ethyl acetate = 1: 1) 300 parts <Adhesive layer composition>
Takelac A-310 (manufactured by Takeda Pharmaceutical Company Limited, trade name) 100 parts Isocyanate curing agent A-10 (manufactured by Takeda Pharmaceutical Company Limited, trade name) 5 parts Solvent (toluene: ethyl acetate = 1: 1) 200 parts (S5) Adhesive layer forming step of providing an adhesive layer 19 made of hot melt on the surface of the transparent substrate 11 where the laminate is exposed The thickness of the following hot melt composition is applied to the surface of the transparent substrate 11 of the laminate 50. It was melted at 150 ° C. using a hot melt applicator so as to be 30 μm, coated and cooled to obtain an adhesive layer 19. <Adhesive layer composition>
Elitel UE-3700 (manufactured by Unitika Ltd., hot melt, trade name) 100 parts (S6) The hard coat layer 14, the adhesive layer 29, the printing layer 18, the reflective layer 17, and the hologram to be the transfer part 23 A half-cut processing step in which only a layer constituent portion composed of the layer 15, the transparent base material 11 and the adhesive layer 19 is subjected to a half-cut process in a desired shape to form a patch 21. Is a half-cut part that can perform half-cut processing and debris removal between the upper mold and the pedestal attached with a hard coat layer 14 / adhesive layer 29 / printing layer 18 / reflection layer 17 / hologram layer serving as the transfer part 23 15 / transparent substrate 11 / adhesive layer 19 is formed into a layered portion of 54 mm × 85 mm and round-cut (patch 21) is half-cut to remove residue To give the patch transfer medium 20 of Example 1 of the continuously wound Tojo patch 21 is releasably laminated from the release layer 13 side.

As shown in FIG. 8, the adhesive layer 19 surface of the patch transfer medium 20 of Example 1 and the fibrous base material 101 are stacked on a polyester T-shirt and pressed with a heated iron from the patch transfer medium 20 surface. Then, the heat-resistant slipping layer / support base material 31 / release layer 13 was peeled off and removed to obtain a T-shirt (patch transfer fibrous material 100) onto which the patch 21 was transferred. The patch transfer medium 20 had good releasability at the time of transfer and could be transferred stably and normally.
The surface of the T-shirt is covered with a patch 21 (hard coat layer 14 / adhesive layer 29 / printing layer 18 / reflection layer 17 / hologram layer 15 / transparent substrate 11 / adhesive layer 19). The patch transfer fibrous material 100 which became the outermost surface was obtained. The hard coat layer 14 surface is the front surface and the transparent base material 11 is the back surface, and the three layers of the printed layer 18 / reflective layer 17 / hologram layer 15 having excellent design properties are firmly protected.

  Even after repeated use, the surface of the patch transfer fibrous material 100 can be protected and protected from mechanical and chemical damage over a long period of time. Especially, the hard coat layer 14 is strong against scratching by sharp objects. Excellent scratch resistance. Further, the film-like transparent substrate 11 was excellent in physical scientific durability such as heat resistance and solvent resistance. Furthermore, the hologram of the hologram layer 15 and the design of the printed layer 18 were excellent in design and security.

  (Washing test) According to JIS L-0217 103 method, washing was carried out by repeating washing at 40 ° C., 12 minutes, rinsing at 40 ° C., 2.5 minutes three times, but printing and holograms were destroyed during washing, It did not fall off and kept flexibility. Since the flexibility was not lost, the mobility was sufficient even when worn.

(Example 2) A patch transfer medium 20 of Example 2 was obtained in the same manner as Example 1 except that the hologram layer 15 and the reflective layer 17 were not provided.
Even after repeated use, the surface of the patch transfer fibrous material 100 can be protected from mechanical and chemical damage over a long period of time. In particular, the hard coat layer 14 is strong against scratching by sharp objects. Excellent scratch resistance. Further, the film-like transparent substrate 11 was excellent in physical scientific durability such as heat resistance and solvent resistance. Furthermore, the hologram of the hologram layer 15 and the design of the printed layer 18 were excellent in design and security. In the washing test according to JIS L-0217 103 method, washing was carried out by repeating washing at 40 ° C. for 12 minutes, rinsing at 40 ° C. for 2.5 minutes three times, but the printing was destroyed or dropped off during washing. The motility was sufficient even when worn.

  (Industrial Applicability) The main use of the patch transfer fiber material (medium) obtained by transferring the patch using the patch transfer medium of the present invention and the patch transfer medium is, for example, a T-shirt. Clothing, cartons, cases, packaging materials such as exterior paper, accessories such as bags, appreciation tickets, envelopes, tags, bookmarks, calendars, posters, brochures, nameplates, report paper, stationery, building materials, Panels, emblems, footwear, shoes, etc. However, after transfer, the hard coat layer is the outermost surface and has excellent scratch resistance and can be manufactured at a low cost with a patch having a hologram or printing that is excellent in design and is transferred by heating and pressing with an iron or the like. If it is a use, it will not specifically limit.

DESCRIPTION OF SYMBOLS 10: Transfer material 11: Base material 13: Release layer 14: Hard coat layer 15: Hologram layer 17: Reflective layer 18: Print layer 19: Adhesive layer 20: Patch transfer medium 21: Patch 23: Transfer part 29: Adhesive Layer 30: Support material 31: Support base material 50: Laminate body 100: Patch transfer fiber material 101: Fiber material

Claims (5)

A method for producing a patch transfer medium, which is laminated so as to be peelable so that a transfer part that is half-cut into a desired shape on a release layer surface of a support substrate becomes a patch,
(1) a transfer material preparation step of preparing a transparent material and a transfer material provided with a hologram layer, a reflective layer, and a print layer on one surface of the transparent substrate;
(2) A supporting material preparation step of preparing a supporting material for providing the release layer by curing a resin layer mainly composed of a thermosetting resin on one surface of the supporting substrate and heat. When,
(3) a hard coat layer forming step of providing a hard coat layer that can be peeled off by curing a resin layer mainly composed of an ionizing radiation curable resin with ionizing radiation on the surface of the release layer of the support material;
(4) A laminating process in which the hard coat layer surface of the support material and the printing layer surface of the transfer material are laminated via an adhesive layer that is cured by heat or ionizing radiation such as ultraviolet rays or electron beams by a dry lamination method. When,
(5) an adhesive layer forming step of providing an adhesive layer made of hot melt on the surface of the transparent substrate where the laminate is exposed;
(6) The hard coat layer, the adhesive layer, the printing layer, the reflection layer, the hologram layer, the transparent base material, and the adhesive layer, which are to be the transfer portion, are formed in a desired shape only. A half-cut processing step for applying a half-cut process to make a patch;
A method for producing a patch transfer medium, comprising: Method for producing a patch transfer medium according to claim 1, feature that said not provided a hologram layer and the reflective layer. A patch transfer medium manufactured by the method for manufacturing a patch transfer medium according to claim 1 or 2,
The hard coat layer, the adhesive layer, the print layer, the reflective layer, the hologram layer, the transparent substrate and the adhesive layer, or the hard coat layer, the adhesive layer, the print layer, and the transparent substrate. And a patch transfer medium, wherein the transfer portion composed of the adhesive layer is subjected to a half-cut process to form a patch, and the patch is laminated to the release layer surface of the support base so as to be peeled off. The adhesive layer surface of the patch transfer medium according to claim 3 and a transfer material made of a fibrous material are overlapped and heated and pressed with an iron, and then the support substrate and the release layer are peeled off and removed. Thus, the patch transfer fibrous material, wherein the patch is transferred to the transfer medium, and the outermost surface is a hard coat layer. A thickness of the hard coat layer is 3 to 7 [mu] m, the thickness of the adhesive layer is at 3 to 7 [mu] m, according to claim 4 in which the thickness of the transparent substrate is a feature that it is 12~25μm Patch transfer fiber material.

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