JP5756655B2 - Multi-layer cosmetic - Google Patents

Description

  The present invention relates to vaginal cosmetics.

  Traditionally, vaginal cosmetics are applied to wrinkles for the purpose of having a cosmetic effect that makes the eyes stand out, such as a long lash effect. The characteristics of the application site have the effect of physiological phenomena such as sweat, tears, and sebum. It is easily affected by human unconscious behavior such as blinking and rubbing eyes. For this reason, it has been required to have functions such as water resistance, sebum resistance, and friction resistance. Further, in recent years, the mascara liquid has been strongly demanded to have good elongation in order to prevent it from becoming lumpy during coating and to improve the feel.

  In order to improve water resistance and sebum resistance, a vaginal cosmetic is proposed in which a synthetic resin emulsion is blended to make an O / W / O double emulsion or multiple emulsion (see Patent Document 1). However, this vaginal cosmetic system has poor film-forming ability, poor sebum resistance and water resistance, particularly extremely low friction resistance, and the coating film easily peels off. In addition, the curl-keep effect is poor, and the purpose of the cosmetics for eyelashes to make the eyes stand out has not been sufficiently fulfilled. Furthermore, the liquid became cloudy due to emulsification, and satisfactory color development and gloss were not obtained.

  In addition, cosmetics containing a mixture of a volatile compound and a polymer of polyvinylpyrrolidone have been proposed for the purpose of preventing color migration by improving the film forming ability (see Patent Document 2). However, even in this cosmetic, the film strength is not sufficient, and the coating film cannot be prevented from being peeled off by friction. Furthermore, there was a major drawback of being vulnerable to sebum.

  A water-containing cosmetic containing a spinnable water-soluble polymer has been proposed for the purpose of improving the long lash effect (see Patent Document 3). However, in this water-containing cosmetic, although the spinnability is exhibited, the coating film becomes a water-based film, so that there is a problem that the curl keeping power and water resistance are poor.

  Furthermore, there has been proposed a mascara cosmetic tool in which two types of cosmetic compositions having different functions are filled in a two-agent-containing container (see Patent Document 4). However, in this cosmetic, not only each agent must be applied separately, but also the first agent must wait for it to dry before applying the second agent. The rush effect was not sufficient.

Japanese Patent Publication No. 52-27695 Japanese Patent No. 3001832 JP 2009-234978 A JP 2002-322031 A

  The object of the present invention is excellent in water resistance, sebum resistance, friction resistance and adhesion, in addition to cosmetic effects such as curl and long rush effects, color development and gloss, and can be easily applied with smooth elongation. It is to provide cosmetics for vaginal.

  As a result of intensive studies to achieve the above-mentioned problems, the present inventor has obtained an aqueous layer component, a volatile oil component and a colorant containing a specific water-soluble polymer, a film-forming agent and a polyhydric alcohol. Presents in a multi-layered state without the use of a surfactant, providing a high long rush effect, as well as high cosmetic effects such as curl keeping, coloring, and gloss, and water resistance, sebum resistance, and friction resistance. The present inventors have found that an unprecedented vaginal cosmetic can be obtained that has excellent adhesion and has a smooth elongation and can be easily applied, and has completed the present invention.

That is, in the present invention, (A) at least one oil layer containing volatile oil and (B) colorant, (C) film forming agent, and (D) at least one water layer containing water are not compatible with each other. A multi-layer vaginal cosmetic filled in a state,
The aqueous layer has the following components (E) and (F);
(E) One or more water-soluble polymers selected from poly (meth) acrylate, polyethylene glycol, sodium hyaluronate, polyvinyl alcohol and polyvinylpyrrolidone, and (F) a polyhydric alcohol In addition, the present invention is a multilayer vaginal cosmetic characterized by containing substantially no oil component.

  The multi-layered cosmetic for cosmetics of the present invention has excellent water resistance, sebum resistance, friction resistance, adhesion, and smooth elongation in addition to cosmetic effects such as curl-keep and long rush effects, color development, and gloss. It can be easily applied.

  Embodiments of the present invention will be described below.

  At least one oil layer of the multilayered vaginal cosmetic of the present invention contains (A) a volatile component and (B) a colorant.

  The (A) volatile oil used in the oil layer of the present invention is not particularly limited as long as it is usually used in cosmetics. For example, hydrocarbon oils such as light liquid isoparaffin and isododecane, decamethylcyclopenta Silicones such as siloxane, octamethylcyclotetrasiloxane, methyltrimethicone, and low polymerization degree dimethylpolysiloxane can be used, and these can be used alone or in combination of two or more as required. Among these, volatile hydrocarbons such as light liquid isoparaffin and isododecane are preferable because they are excellent in the effect of enhancing the drying of the oil layer components and forming a strong decorative coating film by volatilization. For example, Marcazole (manufactured by Maruzen Petrochemical Co., Ltd.), IP solvent 1620 (manufactured by Idemitsu Petrochemical Co., Ltd.) and the like can be mentioned.

  The content of (A) volatile oil is not particularly limited, but is preferably 10 to 70% by mass (hereinafter simply indicated as “%”), more preferably 20 to 60%, based on the total amount of oil layer components. is there. Within this range, particularly satisfactory ones can be obtained in terms of adhesion to wrinkles, smoothness during use, and uniformity of the decorative film.

The colorant (B) used in the oil layer of the present invention is not particularly limited as long as it is usually used in cosmetics. For example, carbon black, inorganic powders, glitter powders, organics Examples thereof include powders, pigment powders, composite powders, and the like, which can be used alone or in combination of two or more. Specifically, conger, ultramarine, bengara, yellow iron oxide, black iron oxide, titanium oxide, zinc oxide, titanium / titanium oxide sintered product, cerium oxide, magnesium oxide, zirconium oxide, antimony oxide, magnesium carbonate, calcium carbonate , Chromium oxide, chromium hydroxide, aluminum silicate, magnesium silicate, calcium silicate, barium silicate, magnesium aluminum silicate, magnesium magnesium silicate, mica, synthetic mica, synthetic sericite, sericite, talc, muscovite , Phlogopite, phlogopite, biotite, kaolin, barium sulfate, bentonite, smectite, diatomaceous earth, hydroxyapatite, boron nitride, etc .; bismuth oxychloride, titanium mica, titanium dioxide coated bismuth oxychloride, oxidation Iron coated mica, iron oxide coated Mother titanium, bitumen coated mica titanium, carmine coated mica titanium, organic pigment coated mica titanium, iron oxide / titanium oxide coated synthetic phlogopite, fish phosphorus foil, titanium dioxide coated glass flake, silver coated glass flake, gold coated glass flake, oxidation Bright powder such as iron-coated glass flake polyethylene terephthalate / aluminum / polyurethane laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / polymethyl methacrylate laminated film powder; polyamide resin, polyethylene resin, polyacrylic resin Organic resins such as polyester resins, fluorine resins, cellulose resins, polystyrene resins, copolymer resins such as styrene-acrylic copolymer resins, polypropylene resins, silicone resins, urethane resins, etc. Organic powders such as resin resin powder and N-acyl lysine; Natural organic powders such as starch, silk powder and cellulose powder; Dye powders such as organic tar pigments and lake pigments of organic dyes; Aluminum powder and gold powder Metal powder such as silver powder, fine particle titanium oxide-coated mica titanium, fine particle zinc oxide-coated mica titanium, barium sulfate-coated mica titanium, titanium oxide-containing silicon dioxide, zinc oxide-containing silicon dioxide, and the like. Further, these dyes and pigments may be coated on the surface with silicones, lauroyl lysine, stearoyl glutamate, perfluoroalkyl phosphate diethanolamine salt, polyethylene, other oils, and the like. Also, the form is not particularly limited by the shape of a plate, spindle, needle or the like, the particle diameter, the particle structure such as porous or nonporous.
In the oil layer of the present invention, it is desirable to select and use black iron oxide and / or carbon black from these in terms of color development and gloss.

  (B) As content of a coloring agent, it is preferable in it being 0.01-30% on the basis of oil layer component total amount, More preferably, it is 0.5-20%, More preferably, it is 5.0-15% is there. When the content of the colorant is within this range, a sufficient effect is obtained in terms of gloss and blackness, and the storage stability of the cosmetic itself is good.

  In the present invention, the colorant may be contained in the water layer in addition to the oil layer as long as the effect is not impaired.

  The oil layer of the vaginal cosmetic of the present invention preferably further contains (G) wax and (H) oil-soluble resin, and preferably has a viscosity at 25 ° C. of 1000 to 30000 mPa · s.

  As the component (G) wax, any wax may be used, regardless of its origin such as synthetic, plant-based, animal-based, mineral-based, and petroleum-based ones, as long as it is usually used in cosmetics. For example, paraffin wax, ceresin wax, microcrystalline wax, ethylene propylene copolymer, α-olefin oligomer, mole, montan wax, Fischer Trops wax, geiwa wax, polyethylene wax, carnauba wax, candelilla wax, beeswax, rice bran wax, silicone wax , Rice wax, sunflower wax and the like.

  In the present invention, the (G) wax can be used by appropriately selecting one or two or more of these, and the content thereof is preferably 5 to 30%, particularly preferably based on the total amount of the oil layer component. Is 10-25%. By containing the wax in this range, a sufficient curl keeping effect and adhesion can be obtained, and the elongation becomes good.

  The oil-soluble resin of component (H) used in the present invention is not particularly limited and can be used as long as it is usually used in cosmetics. Examples of this component (H) include rosin resins such as candelilla resin, hydrogenated pentaerythryl rosin acid, hydrogenated abietic acid glycerin, silicone resins such as trimethylsiloxysilicic acid, acrylic-silicone graft copolymer, Examples thereof include vinyl acetate resin, polyvinyl isobutyl ether, polyisobutylene and the like. Among these, trimethylsiloxysilicic acid is preferable from the viewpoint of long-lasting makeup such as the glossiness of the finished decorative film and the strength of the coating film. These components (H) can be used alone or in combination of two or more.

  The content of the oil-soluble resin as this component (H) is preferably 1 to 50%, more preferably 5 to 40%, and still more preferably 10 to 30% based on the total amount of the oil layer component in terms of resin solids. . If it is this range, the glossiness of a decorative film, sebum resistance, and abrasion resistance will improve.

  In addition to the above components, the oil layer of the present invention may contain (I) an oily gelling agent in order to improve elongation and storage stability. For example, dextrin fatty acid ester such as lauric acid dextrin, palmitic acid dextrin, myristic acid dextrin, stearic acid dextrin, oleic acid dextrin, behenic acid dextrin, coconut oil fatty acid dextrin, palmitic acid sucrose ester, aluminum stearate Metal soaps such as rate, magnesium stearate, zinc myristate, amino acid derivatives such as N-lauroyl-L-glutamic acid, α, γ-di-n-butylamine, benzylidene derivatives of sorbitol such as monobenzylidene sorbitol, dibenzylidene sorbitol, Organically modified clay minerals such as benzyldimethylstearylammonium hectorite and dimethyldistearylammonium hectorite, crosslinked silicone and crosslinked Examples thereof include silicone gels such as those obtained by diluting type methylpolysiloxane with silicones, inulin fatty acid esters, and the like.

  The oil layer in the present invention has a viscosity at 25 ° C. of preferably 1000 to 30000 mPa · s at 30 rpm, more preferably 3000 to 25000 mPa · s, as measured with a B-type rotational viscometer (rotor No. 4). Yes, more preferably 5000 to 20000 mPa · s. Within this range, a smooth feeling during use can be obtained, the entanglement with the water layer is good, and a uniform coating film of the oil layer and the water layer can be obtained on the ridge.

  Further, the oil layer of the present invention may contain solid, semi-solid or liquid oil components other than the component (G) and the component (H). These oily components are not particularly limited as long as they are usually used in cosmetics, and any of them can be used. For example, fatty acids such as stearic acid, palmitic acid, 2-ethylhexanoic acid, undecylenic acid, palmitooleic acid, isostearic acid, ricinoleic acid, linoleic acid, oleic acid, macadamia nut oil, olive oil, camellia oil, avocado oil, corn oil , Castor oil, sesame oil, safflower oil, cottonseed oil, soybean oil, jojoba oil, palm oil, palm oil, hardened palm oil, hardened oil, hardened castor oil, egg yolk oil, rapeseed oil, wheat germ oil, peanut oil, rice bran oil Oils and fats, isononyl isononanoate, isotridecyl isononanoate, cetyl octanoate, isopropyl myristate, octyl palmitate, isopropyl palmitate, octyldodecyl myristate, diisostearyl malate, glyceryl trioctanoate, tri (capryl / capric acid) Glicelli , (Capryl / caprin / myristin / stearate) triglyceryl, phytosteryl oleate, octyldodecyl lactate, isopropyl istearate, glyceryl tribehenate, rosin acid pentaerythritol ester, neopentyl glycol dioctanoate, cholesterol fatty acid ester, N-lauroyl -L-glutamate di (cholesteryl, behenyl, octyldodecyl), esters such as macadamia nut oil fatty acid cholesteryl, macadamia nut oil fatty acid phytosteryl, cetyl alcohol, stearyl alcohol, lauryl alcohol, isostearyl alcohol, lanolin alcohol, octyldodecanol, capryl alcohol , Higher alcohols such as oleyl alcohol, liquid paraffin, squalane, petrolatum Hydrocarbons such as polybutene, silicone-based oils such as high polymerization degree dimethylpolysiloxane and methylphenylpolysiloxane, fluorine-modified polysiloxanes, fluorine oils such as perfluorodecane, perfluorooctane and perfluoropolyether, palmitic acid 2- Of fatty acid such as ethylhexyl, cetyl 2-ethylhexanoate, isotridecyl isononanoate and monohydric alcohol, neopentyl glycol dicaprate, neopentyl glycol di-2-ethylhexanoate, polyethylene glycol stearate, etc. Esters having fatty acid and polyhydric alcohols such as esters, trimethylolpropane triisostearate, pentaerythritol tetra-2-ethylhexanoate, diisostearyl malate, etc. Esters of dibasic acids such as tellurium, di-2-ethylhexyl succinate, dialkyl carbonate, macadamia nut oil fatty acid cholesteryl, macadamia nut oil fatty acid phytosteryl and the like, esters of liquid lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin alcohol, etc. The lanolin derivative | guide_body of these etc. are mentioned.

  The oil layer in the present invention preferably contains substantially no aqueous component, but may be in the form of a W / O emulsion or an O / W / O emulsion in which the oil layer is a continuous layer. Further, in this specification, “the oil layer does not substantially contain an aqueous component” means that the content of the aqueous component in the oil layer is less than 5% based on the total amount of the oil layer component, and less than 1%. And more preferred.

At least one water layer of the multi-layer vaginal cosmetic of the present invention contains (C) a film-forming agent and (D) water, and the following components (E) and (F);
(E) Poly (meth) acrylate, polyethylene glycol, sodium hyaluronate, polyvinyl alcohol and polyvinyl pyrrolidone selected from one or more water-soluble polymers, and (F) polyhydric alcohol, It does not contain any oily components.

  Although it does not specifically limit as (C) film formation agent used for the water layer of this invention, It is desirable to use a polymer emulsion. A polymer emulsion will not be specifically limited if it is normally used for cosmetics. Examples include alkyl acrylate copolymer emulsion, polyvinyl acetate emulsion, polyvinyl chloride emulsion, alkyl (meth) acrylate / styrene copolymer emulsion, vinylpyrrolidone / styrene copolymer emulsion, silicone polymer emulsion, acrylamide Polymer emulsion, polyurethane polymer emulsion, alkyl acrylate / vinyl acetate copolymer emulsion, and the like. Among these, an alkyl acrylate copolymer emulsion is most preferable. Examples of the alkyl acrylate copolymer emulsion include the iodosol series (manufactured by Akzo Nobel).

The (C) film-forming agent used in the present invention can be used by selecting one or more types as appropriate, and the content thereof is 0.1 to 40% based on the total amount of water layer components in terms of resin solids. Preferably, it is 1-30%, more preferably 5-20%. When a film-forming agent is used within this range, sufficient water resistance, sebum resistance and friction resistance can be obtained, and the temporal stability of the aqueous layer is also good.
The content of water (D) in the water layer is preferably 20 to 99% by mass based on the total amount of water layer components, from the viewpoints of adhesion to wrinkles, smoothness during use, and uniformity of the decorative film, and further 30 -95 mass% is preferable, and 40-90 mass% is especially preferable.

The water-soluble polymer of component (E) used in the present invention imparts spinnability and is important for producing a long rush effect. Poly (meth) acrylate, polyethylene glycol, sodium hyaluronate, polyvinyl alcohol and 1 type (s) or 2 or more types selected from polyvinylpyrrolidone can be used, and any of those usually used in cosmetics can be used without any particular limitation. Among these, poly (meth) acrylate is preferably used, and sodium salt is particularly preferable.
Examples of the poly (meth) acrylate include AQUALIC L-YS, AQUALIC L-HL (manufactured by Nippon Shokubai Co., Ltd.), Aronbis series (manufactured by Nippon Pure Chemical Co., Ltd.), and the like.

  The component (E) is preferably sodium polyacrylate having an average molecular weight of 2 million or more in view of the long rush effect, and more preferably a partially neutralized product. This sodium polyacrylate partially neutralized product is a part of sodium polyacrylate that has been neutralized with an alkali. Examples of alkali include alkali metal salts such as sodium hydroxide and potassium hydroxide, ammonia, and aqueous ammonia. Primary, secondary or tertiary alkylamines such as triethanolamine, dimethylamine, diethylamine, trimethylamine, triethylamine, triisopropanolamine, monoethanolamine, diethanolamine, diisopropanolamine, polyethanolamine, etc. Examples include primary, secondary or tertiary alkanolamines. As a method for producing a partially neutralized poly (sodium acrylate), a method of partially neutralizing sodium polyacrylate later, and a polymerization after neutralizing a part of acrylic acid at the time of monomer preparation during polymerization However, either method can be applied in the present invention.

  The content of the component (E) is preferably 0.01 to 5% based on the total amount of the water layer components, more preferably 0.03 to 3%, and still more preferably 0.05 to 2%. is there. When the content of the component (E) is within this range, the spinnability and the long lash effect are sufficient, the conformability during application is good, and stickiness does not occur.

The component (F) polyhydric alcohol used in the present invention can be used without particular limitation as long as it is usually used in cosmetics. For example, dihydric alcohols such as ethylene glycol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, diethylene glycol, triethylene glycol, and 1,4-butylene glycol, trihydric alcohols such as glycerin and trioxyisobutane, erythritol, Examples thereof include tetrahydric alcohols such as pentaerythritol, pentahydric alcohols such as xylit and adnit, hexahydric alcohols such as allozulcit, sorbitol, sorbitol liquid, and mannitol.
Among the above components (F), 1,3-butylene glycol and dipropylene glycol are particularly preferable.

  The content of the component (F) is preferably 0.1 to 10%, more preferably 0.5 to 8%, and still more preferably 1 to 5% based on the total amount of the water layer components. When the content of the polyhydric alcohol is within this range, the drying speed is appropriate, a uniform coating film is formed, and stickiness does not occur.

  Moreover, in the aqueous layer used for this invention, water-soluble polymers other than the said component (E) can also be contained as needed. For example, high plant system such as gum arabic, tragacanth, galactan, caro gum, guar gum, caraya gum, carrageenan, xanthan gum, pectin, agar, quisseed (quince), starch (rice, corn, potato, wheat), alge colloid (brown algae extract) Molecules, microbial polymers such as dextran, succinoglucan and pullulan, animal polymers such as collagen, casein, albumin and gelatin, starch polymers such as carboxymethyl starch and methylhydroxypropyl starch, methylcellulose, nitrocellulose, Cellulose polymers such as ethyl cellulose, methyl hydroxypropyl cellulose, sodium cellulose sulfate, hydroxypropyl cellulose, crystalline cellulose, cellulose powder, etc., sodium alginate , Alginate polymers such as propylene glycol alginate, vinyl polymers such as polyvinyl methyl ether and carboxyvinyl polymer, polyoxyethylene polymers, polyoxyethylene polyoxypropylene copolymer polymers, polyoxyacrylates, Examples thereof include acrylic polymers such as polyacrylamide, inorganic water-soluble polymers such as polyethyleneimine, cationic polymers, bentonite, aluminum magnesium silicate, laponite, hectorite, and silicic anhydride.

  The aqueous layer in the present invention preferably contains substantially no oil component, but in this specification, “the water layer does not substantially contain an oil phase component” means the content of the oil component in the water layer. Indicates less than 5% based on the total amount of the water layer components, and more preferably less than 1%.

  In the present invention, the multi-layered bag cosmetic is filled so that the oil layer and the water layer form a separated layer in the container. More preferably, the oil layer is filled on the bottom side in the container, and the water layer is filled on the opening side from the oil layer. The filling ratio is preferably oil layer: water layer = 10: 1 to 10:15, more preferably 10: 2 to 10:10, and still more preferably 10: 3 to 10: 8. Within this range, uniform adhesion between the oil layer and the water layer can be obtained. The oil layer and the water layer may be at least one layer each, but may be two or more layers such as oil layer-water layer-oil layer-water layer.

  The multi-layered cosmetic for cosmetics of the present invention shows various components normally used in cosmetics, for example, wrinkles, as long as necessary in addition to the above-mentioned components and within the range not impairing the effects of the present invention. Fibers, moisturizers, thickeners, fragrances, bactericides, preservatives, UV absorbers, solvents, anti-inflammatory agents, antiandrogens, hair restorers, antioxidants, fresheners, herbal extracts and vitamins, A cuticle protecting component and the like can be appropriately blended.

  The fiber that can be used in the present invention is not particularly limited as long as it is usually used in cosmetics, and any fiber can be used. Examples thereof include synthetic fibers such as nylon and polyester, artificial fibers such as rayon, natural fibers such as cellulose, semi-synthetic fibers such as acetate artificial silk, and the like. In addition, those fibers treated with general oils, silicone oils, fluorine compounds, surfactants and the like can be used.

In order to apply the cosmetics for multi-layered wrinkles of the present invention to wrinkles and to exhibit the cosmetic effects such as long rush effect, curl-keeping power, and gloss, it is necessary to apply on the wrinkles and leave the cosmetics there There is. In this respect, it is preferable to use an applicator that can easily apply an oil layer and an aqueous layer on the ridge.
Thus, the method for using the multi-layered vaginal cosmetic of the present invention comprises applying the above-mentioned multi-layered vaginal cosmetic on the reed using a resin comb-type applicator. The pitch width of the comb is 0.6 to 1.3 mm, more preferably 0.7 to 0.9 mm.

  The applicator used in the method for using the multi-layer cosmetic for cosmetics according to the present invention is an applicator that can apply both an oil layer and an aqueous layer uniformly without forming lumps on the reed. The pitch width is 0.6 to 1.3 mm, more preferably 0.7 to 0.9 mm. More specifically, for example, it is preferably one that is injection-molded with a thermoplastic resin or a thermosetting resin and has a comb pitch width of 0.6 to 1.3 mm.

  Thermoplastic resins include synthetic rubbers such as nitrile rubber and butyl rubber, thermoplastic elastomers such as styrene-butadiene-styrene block copolymer (SBS), styrene-ethylene-butadiene-styrene (SEBS), polyurethane, HDPE, MDPE, Polyethylene (PE) such as LDPE and LLDPE, ethylene-α-olefin copolymer, ethylene-vinyl acetate copolymer (EVA), ethylene-methyl methacrylate copolymer (EMMA), polyolefin resin such as polypropylene, PET, PBT Polyester resin such as acrylate polymer, acrylic resin such as methacrylate polymer, acrylonitrile-butadiene-styrene copolymer (ABS), acrylonitrile-styrene copolymer (AS), polyamide resin, polyacetal resin, etc. As thermosetting resin, diallyl phthalate resin, unsaturated polyester resin, phenol resin, epoxy resin, thermosetting polyurethane, alkyd resin, melamine resin, urea resin, thermosetting polyimide resin, thermosetting acrylic Resin or the like can be used.

  Conventionally, brush type applicators that have been used as wrinkle applicators (for example, screw brushes that are spirally twisted while gripping brush fibers with two strips of metal core wire, or flocking brush fibers around the comb shaft) Can be applied to the eyelids, but it is worse than the comb-type applicator made of resin in terms of the uniformity of the coating film of the oil layer and the water layer and the amount of liquid adhering to the eyelids. Absent.

  The present invention will be described in detail below with reference to examples, but the technical scope of the present invention is not limited to these examples. The blending amount is the content (% by mass) unless otherwise specified. Prior to the examples, the evaluation methods employed in each example will be described.

(1) Sensory evaluation test method According to 25 female panelists, the feeling of use at the time of application (smoothness and goodness), good adhesiveness, makeup collapse due to sebum and friction 8 hours after application (sebum resistance, friction resistance) Property), curl keeping force 1 hour after coating, and actual feeling of long rush effect were evaluated according to the following evaluation criteria.
(Evaluation criteria)
More than 20 people answered good; ◎
１３ 13-19 people; ○
７ 7-12 people;
６ 6 or less; ×
(Evaluation item)
a. Curl keeping force b. Water resistance, sebum resistance, friction resistance c. Adhesion d. Usability (smoothness and goodness)
e. Long rush effect

<Method for preparing multilayer mascara>
-Preparation method of oil layer component A wax, an oil-soluble resin, a volatile oil, and optionally a dextrin fatty acid ester and other oily components are heated and mixed at 80 ° C or higher and uniformly dissolved. Further, a pigment or the like is added and uniformly dispersed using a homomixer, and then cooled to room temperature to obtain an oil layer component.
-Preparation method of water layer component Water-soluble polymer, polyhydric alcohol, and, in some cases, other aqueous components are heated and mixed to 80 ° C or more to dissolve uniformly, and after cooling to room temperature, a film forming agent is added. A water layer component is obtained by stirring with a homomixer.
Filling the same same airtight container with the oil layer component on the bottom surface side and the water layer component on the opening side with a predetermined ratio (oil layer: water layer = 10: 6), the desired multilayer mascara is obtained.
The applicator used was a comb-type applicator having a pitch width of 0.8 mm, which is a PET injection-molded comb.

  Table 1 shows the component composition and evaluation test results of each of the above compositions.

  As is apparent from Table 1, when the multi-layered cosmetic for cosmetics of the present invention is used, it has excellent curl keeping power, water resistance, sebum resistance, friction resistance, adhesion, and feeling in use. The long rush effect was excellent.

(2) Examination of comb type applicator The applicator was examined using the multi-layer mascara of Example 1. As a result, the comb type applicator having a pitch width of 0.8 mm used in Example 1 had a pitch width of 0. Compared with the comb-type applicators of .5 mm and 1.5 mm, both the oil layer and the water layer could be applied simultaneously and uniformly, and it was easy to use and the coating amount on the ridge was also good. Further, in the brush type applicator made of nylon, the oil layer was uniformly applied on the ridge, but the water layer was difficult to be applied satisfactorily.

Claims (3)

In a state where (A) at least one oil layer containing volatile oil, (B) colorant, (C) film forming agent and (D) at least one water layer containing water are incompatible with each other , A multi-layered cosmetic for salmon that is filled on the bottom side in the container and filled with an aqueous layer on the opening side from the oil layer ,
The aqueous layer has the following components (E) and (F);
(E) One or more water-soluble polymers selected from poly (meth) acrylate, polyethylene glycol, sodium hyaluronate, polyvinyl alcohol and polyvinylpyrrolidone, and (F) a polyhydric alcohol And the content of the oil component in the water layer is less than 5% based on the total amount of the water layer component,
The oil layer has the following components (G) and (H);
(G) wax, and
(H) Oil-soluble resin
And the viscosity of the oil layer at 25 ° C. is 1000 to 30000 mPa · s . Oil layer is filled into the bottom side of the vessel, it is filled aqueous layer is on the opening side from the oil layer, the mass ratio of the oil layer: water layer = 10: 1 to 10: multilayer according to claim 1, which is a 15 Cosmetic for salmon. The multi-layer wrinkle cosmetic according to claim 1 or 2 is applied to a wrinkle using a comb-type applicator, and the comb pitch width of the applicator is 0.6 to 1.3 mm. A method for using a multi-layer vaginal cosmetic, characterized by being used.