JP7123572B2 - Multilayer film-forming cosmetics - Google Patents

Description

The present invention relates to a multi-layered film-forming cosmetic that can be applied to coat keratinous materials such as eyelashes, eyebrows, hair and nails.

Film-forming cosmetics that can be applied to coat keratinous materials such as eyelashes, eyebrows, hair, and nails are required to have various effects from the functional aspect. For example, eyelash cosmetics such as mascara have effects such as making eyelashes look thicker and longer, giving eyelashes a sense of volume, curling effect (effect of curling eyelashes upward), and curl retention effect. (effect to maintain curl over time), long-lasting makeup effect over time (water resistance, sebum resistance), and other functional effects are desired.

On the other hand, recently, in addition to the above functional effects, visual effects (hereinafter referred to as , this effect is also called an aesthetic effect).

Cosmetics for eyelashes are usually contained in containers whose contents cannot be seen. As a result of making the cosmetic for eyelashes into a two-layer structure of an oil layer and a water layer, there is only a cosmetic for eyelashes in which the oil layer and the water layer are not compatible with each other (Patent Documents 1 and 2).

JP 2012-180316 A JP 2012-180317 A

However, since Patent Documents 1 and 2 are eyelash cosmetics in which the water layer is not compatible, there is a problem that the functional aspects such as curling effect, curl retention effect, and makeup lasting effect over time are not sufficient. . In order to obtain a sufficient functional effect such as a curling effect, for example, it is necessary to make the eyelash cosmetic composition an oily composition or a water-in-oil type composition. Unlike Patent Documents 1 and 2, it does not separate, so layers cannot be formed naturally. In other words, it is extremely difficult to achieve both a functional effect and an aesthetic effect due to the layer structure in a multi-layered film-forming cosmetic composition of an oily composition or a water-in-oil composition.

The present invention has been made in view of the above problems, and an object of the present invention is to provide a multi-layered film-forming cosmetic that has an aesthetic effect that has not hitherto been available and has sufficient functional effects.

The multilayer film-forming cosmetic of the present invention is a multilayer film-forming cosmetic comprising at least a lower layer comprising an oily or water-in-oil composition and an upper layer comprising an oily or water-in-oil composition, It has an interface formed by the lower layer and the upper layer, and the visible characteristics are different between the lower layer and the upper layer.

The visible attribute is preferably hue, lightness, saturation, luminance or transparency.

The viscosity of the composition constituting the lower layer is preferably 10000 Pa·s or more at 35 to 45°C.

The multilayer film-forming cosmetic of the present invention may have a discharge portion at the interface where the lower layer composition protrudes toward the upper layer in a substantially conical shape.

The multilayer film-forming cosmetic of the present invention is preferably packed in a transparent container.

Preferably, the compositions of the underlayer and overlayer can be mixed to change the visible properties of the underlayer and overlayer.

The multilayer film-forming cosmetic of the present invention is preferably for eyelashes.

The composition of the multilayer film-forming cosmetic of the present invention preferably contains a film-forming agent.
The coating agent is preferably trimethylsiloxysilicate or tri(trimethylsiloxy)silylpropylcarbamate pullulan.
The content of trimethylsiloxysilicate or pullulan tri(trimethylsiloxy)silylpropylcarbamate is preferably 0.05 to 60% by mass based on the total amount of the lower layer composition.

The composition of the multilayer film-forming cosmetic of the present invention preferably contains a thickener.
Preferably, the thickening agent comprises palmitic acid or silica dimethylsilylate.

The multilayer film-forming cosmetic of the present invention is a multilayer film-forming cosmetic comprising at least a lower layer comprising an oily or water-in-oil composition and an upper layer comprising an oily or water-in-oil composition, Since it has an interface formed by the lower layer and the upper layer, and the visible characteristics are different between the lower layer and the upper layer, it has an unprecedented aesthetic effect and is composed of an oily or water-in-oil type composition. , the functional effect can also be provided.

FIG. 1 is a schematic diagram showing one embodiment of the multilayer film-forming cosmetic of the present invention. FIG. 2 is a schematic diagram of the interface portion of another embodiment of the multilayer film-forming cosmetic of the present invention.

The multilayer film-forming cosmetic of the present invention will be described in detail below.
The multilayer film-forming cosmetic of the present invention is a multilayer film-forming cosmetic comprising at least a lower layer comprising an oily or water-in-oil composition and an upper layer comprising an oily or water-in-oil composition, It has an interface formed by the lower layer and the upper layer, and the visible characteristics are different between the lower layer and the upper layer.
Here, the multilayer film-forming cosmetic can be used for coating keratinous materials such as eyelashes, eyebrows, hair and nails.

First, the configuration of the multilayer film-forming cosmetic of the present invention will be described with reference to the drawings. As shown in FIG. 1, the multilayer film-forming cosmetic 10 of the present invention comprises a lower layer 1 made of an oily or water-in-oil composition and an upper layer 2 made of an oily or water-in-oil composition. This film-forming cosmetic comprises a container 3 containing compositions of a lower layer 1 and an upper layer 2, and an applicator 4 attached to and detached from the container 3. The container 3 is a transparent container so that the lower layer 1 and the upper layer 2 are placed outside the container and visible. In FIG. 1, the lower layer 1 schematically shows the black composition and the upper layer 2 the transparent composition.

The combination of the composition of the lower layer 1 and the upper layer 2 consists of the lower layer 1 made of the oily composition and the upper layer 2 made of the oily composition, the lower layer 1 made of the water-in-oil composition and the upper layer 2 made of the water-in-oil type composition. Alternatively, the lower layer 1 may be composed of an oily composition and the upper layer 2 may be composed of a water-in-oil composition, or the lower layer 1 may be composed of a water-in-oil composition and the upper layer 2 may be composed of an oily composition.

The multilayer film-forming cosmetic 10 of the present invention has an interface 5 formed by the lower layer 1 and the upper layer 2, and the lower layer 1 and the upper layer 2 have different visible properties. Here, in addition to the case where the lower layer 1 and the upper layer 2 do not mix at the interface through a clear plane, if the lower layer 1 and the upper layer 2 can be visually distinguished, the lower layer 1 and the upper layer 2 are mixed at the interface. You can match. In order to simplify the explanation, FIG. 1 shows a two-layer structure of a lower layer 1 and an upper layer 2, but it is not limited to a two-layer structure, and a multi-layer structure of three or more layers may be used. good. In the case of three or more layers, the upper layer is the upper layer and the lower layer is the lower layer.

The visible attribute is preferably hue, lightness, saturation, luminance or transparency. Here, hue is the difference between colors such as red, blue, green, and yellow, brightness is the brightness of a color, saturation is the vividness of a color, and brightness is the degree of brightness. It means things that cannot be expressed only by lame, such as lame and no lame, fiber and no fiber. In addition, transparency means that the background can be seen when filled in a transparent container.

Visible traits may differ in one trait between the lower layer and the upper layer, or may differ in combination of multiple traits. For example, the bottom layer is black and the top layer is blue (differences in hue only), the bottom layer is black and the top layer is bright blue (differences in hue and saturation), the bottom layer is blue with glitter, and the top layer is black without glitter (hue and saturation). difference in brightness), blue with high brightness in the lower layer and transparent with lame in the upper layer (differences in hue, brightness, brightness and transparency), and the like.

In FIG. 1, the entire container 3 is a transparent container. However, for example, when the lower layer is transparent with color and the upper layer is transparent with lame, the longitudinal half of the container is transparent and the other half is transparent. If a colored container is used in which pictures, letters, etc. are arranged on the colored half side, the pictures and letters can be visually recognized from the outside of the container, and the aesthetic effect can be greatly improved. Alternatively, a transparent window may be arranged in a normal container (non-transparent container) so that the portion near the interface 5 can be visually recognized. In this case, the aesthetic effect can also be improved by appropriately changing the shape of the window portion.

FIG. 2 is a schematic diagram of the interface portion of another embodiment of the multilayer film-forming cosmetic of the present invention. As shown in FIG. 2, at the interface 5, the composition of the lower layer 1 may have a discharge portion 6 protruding toward the upper layer 2 in a substantially conical shape. The term "substantially conical" means that the apex of the cone is at the center of the bottom of the cone, and that it is not at the center. It also means that the line connecting the apex of the cone to all the points on the circumference of the circle of the bottom of the cone may be a straight line, a curve, or an inverted icicle-like shape. Furthermore, the substantially conically protruding discharge portion may be in contact with the side surface of the container to form a semi-conical discharge portion (6a).

The discharge part as described above occurs when the composition constituting the lower layer contains air during the production of the multilayer film-forming cosmetic. That is, as will be described later, a multilayer film-forming cosmetic is produced by filling a container with a composition that constitutes a lower layer, then filling a container with a composition that constitutes an upper layer, and cooling the container to room temperature. If air is contained in the composition constituting part is formed. Such ejection portions are random from the formation process, which enhances the aesthetic effect.

Furthermore, since the multilayer film-forming cosmetic of the present invention comprises an oily or water-in-oil type composition in the lower layer and an oily or water-in-oil type composition in the upper layer, the lower layer and the upper layer are gradually mixed during use. However, in the process of mixing (the process of use), the visible characteristics of the lower layer and the upper layer are mixed and changed, and various forms are generated there, which also enhances the aesthetic effect. You can enjoy the change of its form.

The viscosity of the composition constituting the lower layer is preferably 10000 Pa·s or more at 35 to 45°C. When the viscosity is within this range, even if the upper layer is filled on top of the lower layer in the manufacturing process, the lower layer and the upper layer do not mix, making it possible to produce a multilayer film-forming cosmetic. Here, the viscosity is a value measured with a rheometer Physician MCR301 manufactured by Anton Paar. Specifically, it is a value measured as a shear stress when a parallel plate type measuring jig has a diameter of 25 mm, a strain swing angle gamma of 5%, a frequency f of 1 Hz, and a shear rate of 0.3 s ^-1 .
When there are three or more layers, the viscosity of the composition constituting the lowermost layer and the composition constituting the upper layer is preferably 10000 Pa·s or more at 35 to 45°C.

Next, the oily composition or the water-in-oil composition constituting the lower layer and the upper layer of the multilayer film-forming cosmetic of the present invention will be described by taking eyelash cosmetic as an example. The oil-based composition or water-in-oil type composition constituting the lower layer and upper layer of the eyelash cosmetic is a film agent, a thickener, an oil such as a volatile oil, a wax, a It can be prepared using a dextrin fatty acid ester, an organically modified clay mineral, a coloring material, or the like. Other multilayer film-forming cosmetics (for eyebrows, hair, nails, etc.) can also be prepared using materials that have been widely used for multilayer film-forming cosmetics.

Film agents include, for example, siliconized pullulan, trimethylsiloxysilicate, dimethylamino methacrylate quaternary salt, vinylpyrrolidone/methacrylic acid-N,N-dimethyl-ethylantinioethyl salt copolymer, silicone/polyether Polyurethane resin, (methacryloyloxyethyl carboxybetaine/methacrylalkyl) copolymer, dextrin, (vinylpyrrolidone/VA) copolymer, alkyl acrylate copolymer ammonium, polyvinyl alcohol, polyethyl acrylate, (alkyl acrylate/octylacrylamide) copolymer, ( acrylates/propyl trimethicone methacrylate) copolymer, polyvinyl acetate, (alkyl acrylate/dimethicone) copolymer, polyether graft acrylic silicone, trimethylsiloxysilicate, fluoro-modified silicone resin, and the like. A preferred siliconized pullulan is tri(trimethylsiloxy)silylpropylcarbamate pullulan.

The amount of the coating agent, as a pure content, is preferably 0.05 to 60% by mass, preferably 0.1 to 30% by mass, based on the total amount of the lower layer composition. It is preferably 0.05 to 60% by mass, preferably 0.1 to 45% by mass, based on the total amount of the upper layer composition. If the blending amount of the film-forming agent is less than 0.05% by mass, the long-lasting effect and the curling effect are inferior. Moreover, when it exceeds 60 mass %, it is inferior to the hot water removal effect.

Thickeners include plant-based polymers such as gum arabia, gum tragacanth, galactan, guar gum, carob gum, karaya gum, carrageenan, pectin, agar, starch, and glycyrrhizic acid, and microbial-based polymers such as xanthan gum, dextran, succinoglucan, and bullulan. , collagen, casein, albumin, gelatin, and other animal-based polymers; semi-synthetic water-soluble polymers, such as starch-based polymers, cellulose-based polymers, and alginic acid-based polymers; , polyoxyethylene-based polymers, polyoxyethylene-polyoxypropylene copolymer-based polymers, acrylic polymers, polyethyleneimine, cationic polymers, and other synthetic water-soluble polymers.
The blending amount of the thickener is preferably 0.05 to 35% by mass, more preferably 0.2 to 30% by mass. If the blending amount of the thickener is less than 0.05% by mass, the viscosity may not be maintained. Moreover, when it exceeds 35 mass %, it may become difficult to apply|coat.

Examples of volatile oils include hydrocarbon oils such as light liquid isoparaffin and isododecane, chain polysiloxane oils such as low molecular weight volatile dimethylpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexa Cyclic silicone oils such as siloxane and the like are included.
The volatile oil content is preferably 10 to 80% by mass, more preferably 30 to 60% by mass. If the blending amount of the volatile oil is less than 10% by mass, it may become difficult to apply. Moreover, if it exceeds 80% by mass, the viscosity may not be maintained.

Examples of oils include hydrocarbon oils such as heavy isoparaffin, squalane, and liquid paraffin; esters such as noate, isopropyl myristate, and myristyl myristate; oils and fats such as olive oil, avocado oil, jojoba oil, sunflower oil, safflower oil, camellia oil, macadamia nut oil, mink oil, liquid lanolin, lanolin acetate, and castor oil; Silicone oils such as dimethylpolysiloxane, methylphenylpolysiloxane, highly polymerized gum-like dimethylpolysiloxane, polyether-modified silicone, amino-modified silicone; fluorine-modified dimethylpolysiloxane, fluorine-modified methylphenylpolysiloxane, perfluoropolyether , fluorine-based oils such as perfluorocarbon, and the like.

Waxes include, for example, beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax, wart wax, whale wax, montan wax, bran wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugar cane wax, isopropyl lanolin fatty acid, hexyl laurate, reduction Lanolin, jojoba wax, hard lanolin, shellac wax, POE lanolin alcohol ether, POE lanolin alcohol acetate, POE cholesterol ether, lanolin fatty acid polyethylene glycol, POE hydrogenated lanolin alcohol ether, ceresin, polyethylene wax, microcrystalline wax, sugar wax, paraffin, etc. mentioned.
The blending amount of wax is preferably 1 to 20% by mass, more preferably 3 to 15% by mass. If the wax content is less than 1% by mass, the curling effect may be poor. On the other hand, if it exceeds 20% by mass, it may become clumpy, resulting in poor luck.

The dextrin fatty acid ester is preferably an ester compound of fatty acid having 8 to 24 carbon atoms and dextrin having an average degree of polymerization of 10 to 50. Examples include dextrin palmitate, dextrin stearate, dextrin palmitate stearate, dextrin isostearate, (palmitate/2-ethylhexanoate) dextrin, and the like.
The content of the dextrin fatty acid ester is preferably 1-40% by mass, more preferably 3-30% by mass. If the blending amount of the dextrin fatty acid ester is less than 1% by mass, the stability may be poor. Moreover, when it exceeds 40 mass %, it may become impossible to apply|coat uniformly.

Organically modified clay minerals include natural or synthetic montmorillonite groups such as montmorillonite, saponite, and hectorite (commercially available products include Veegum, Kunipia, Laponite, etc.), and synthetic mica known as sodium silicic mica and sodium or lithium teniolite. obtained by treating the clay mineral with a quaternary ammonium salt-type cationic surfactant. Examples thereof include disteardimonium hectorite, dimethylalkylammonium hectorite, distearyldimethylammonium chloride-treated aluminum magnesium silicate, and the like.
The blending amount of the organically modified clay mineral is preferably 1 to 10% by mass, more preferably 2 to 8% by mass. If the content of the clay mineral is less than 1% by mass, thixotropy may not be obtained. Moreover, when it exceeds 10 mass %, it may become impossible to apply|coat uniformly.

The coloring material is not particularly limited as long as it is generally used in makeup cosmetics, but hydrophobic coloring materials are preferably used. For example, red iron oxide, yellow iron oxide, black iron oxide, inorganic white pigments (e.g., zinc oxide, etc.); inorganic red pigments (e.g., iron titanate, etc.); inorganic purple pigments (e.g., mango violet, cobalt violet etc.); Inorganic green pigments (e.g., chromium oxide, chromium hydroxide, cobalt titanate, etc.); Inorganic blue pigments (e.g., ultramarine blue, Prussian blue, etc.); Bismuth chloride, titanium oxide-coated talc, colored titanium oxide-coated mica, bismuth oxychloride, fish scale foil, etc.); metal powder pigments (e.g., aluminum powder, copper powder, etc.); organic pigments such as zirconium, barium, or aluminum lake (e.g., Red No. 201, Red No. 202, Red No. 204, Red No. 205, Red No. 220, Red No. 226, Red No. 228, Red No. 405, Orange No. 203, Orange No. 204, Yellow No. 205, Yellow No. 401, Blue 404 Red No. 3, Red No. 104, Red No. 106, Red No. 227, Red No. 230, Red No. 401, Red No. 505, Orange No. 205, Yellow No. 4, Yellow No. 5, Yellow No. 202, Yellow No. 203, Green No. 3, Blue No. 1, etc.); natural pigments (eg, chlorophyll, β-carotene, etc.);
The content of the coloring material is preferably 0.001 to 30% by mass, more preferably 2 to 20% by mass.

In addition, fibers, moisturizing agents, chemicals, preservatives, fragrances, antioxidants, ultraviolet absorbers, and the like can be blended into eyelash cosmetics within limits that do not impair the effects of the present invention.

The multilayer film-forming cosmetic of the present invention can be produced according to a method commonly used for oil-based or water-in-oil composition film-forming cosmetics. In the case of an oil-based composition, the oil-phase components are heated to about 90° C. and mixed uniformly to obtain an oil-based composition for the lower layer, which is filled in a container, and the similarly prepared oil-based composition for the upper layer is added. It can be prepared by cooling to room temperature after filling. In the case of a water-in-oil composition, first, the oil phase components are heated to about 90° C. and mixed uniformly to form an oil phase, and the water phase components are uniformly mixed at room temperature to form a water phase, The water-in-oil composition is added to the oil phase while stirring to emulsify, and this is filled into a container as the water-in-oil composition for the lower layer, and then the water-in-oil composition for the lower layer prepared in the same manner is filled as the upper layer. After that, it can be prepared by cooling to room temperature. In the case of a film-forming cosmetic having an oily composition as the lower layer and a water-in-oil composition as the upper layer, or a film-forming cosmetic having a water-in-oil composition as the lower layer and an oily composition as the upper layer, the preparation is carried out in the same manner as described above. be able to.

EXAMPLES Next, the present invention will be described more specifically with reference to examples. The present invention is by no means limited by the following examples. Unless otherwise specified, the blending amount is % by mass.

(Preparation of Oily Composition Constituting Lower Layer)
Oil-based compositions were prepared by heating each component to about 90° C. and uniformly mixing them according to the formulations shown in Compositions 2, 5 and 7 in Table 1. The viscosities of these oil-based compositions under the measurement conditions described above were 10,000 Pa·s or more at 40°C.
Also, oil-based compositions were prepared in the same manner with the formulations shown in Compositions 9 and 10 in Table 1. The viscosity of these oily compositions was less than 10000 Pa·s at 40°C.

(Preparation of water-in-oil composition constituting lower layer)
In the formulations shown in compositions 1, 3, 4 and 6 in Table 1, the oil phase components other than water were heated to about 90°C and uniformly mixed to form an oil phase, and water was added while stirring the oil phase. and emulsified to prepare a water-in-oil composition. The viscosities of these water-in-oil compositions under the above measurement conditions were all 10000 Pa·s or more at 40°C.
A water-in-oil composition was prepared in the same manner with the formulation shown in composition 8 in Table 1. The viscosity of this water-in-oil composition under the measurement conditions described above was less than 10000 Pa·s at 40°C.

(Preparation of Oily Composition Constituting Upper Layer)
Oil-based compositions were prepared by heating each component to about 90° C. and uniformly mixing them according to the formulations shown in Compositions 4 and 5 in Table 2.

(Preparation of water-in-oil composition constituting upper layer)
In the formulations shown in compositions 1, 2 and 3 in Table 2, the oil phase components other than water are heated to about 90°C and mixed uniformly to form an oil phase, and water is added while stirring the oil phase to emulsify. to prepare a water-in-oil composition.

(Example 1-6)
In the combination shown in Table 3, the container was filled with the lower layer composition at 40 ° C., immediately filled with the upper layer composition at 40 ° C. without cooling, and then cooled to room temperature to produce a two-layer eyelash cosmetic. . In Example 1-6, both the lower layer and the upper layer are a combination of oily compositions, but there is an interface formed by the lower layer and the upper layer, and as shown in Table 3, the lower layer and the upper layer have different visible characteristics. rice field. It should be noted that, in some of the examples, a discharge part was observed in which the composition in the lower layer protruded toward the upper layer in a substantially conical shape.

(Examples 7-15)
In the combination shown in Table 4, the container was filled with the lower layer composition at 40 ° C., immediately filled with the upper layer composition at 40 ° C. without cooling, and then cooled to room temperature to produce a two-layer eyelash cosmetic. . Examples 7-15 are a combination of an oil-based composition for the lower layer and a water-in-oil composition for the upper layer, but have an interface formed by the lower layer and the upper layer, and as shown in Table 4, the upper layer and the lower layer are visible. The possible attributes were different. It should be noted that, in some of the examples, a discharge part was observed in which the composition in the lower layer protruded toward the upper layer in a substantially conical shape.

(Examples 16-23)
In the combination shown in Table 5, the container was filled with the lower layer composition at 40 ° C., immediately filled with the upper layer composition at 40 ° C. without cooling, and then cooled to room temperature to produce a two-layer eyelash cosmetic. . Examples 16-23 are a combination of a water-in-oil composition in the lower layer and an oily composition in the upper layer, but have an interface formed by the lower layer and the upper layer, and are visible in the upper layer and the lower layer as shown in Table 5. The possible attributes were different. It should be noted that, in some of the examples, a discharge part was observed in which the composition in the lower layer protruded toward the upper layer in a substantially conical shape.

(Examples 24-35)
In the combination shown in Table 6, the container was filled with the lower layer composition at 40 ° C., immediately filled with the upper layer composition at 40 ° C. without cooling, and then cooled to room temperature to produce a two-layer eyelash cosmetic. . Examples 24-35 are combinations of water-in-oil compositions in both the lower and upper layers, but have an interface formed between the lower and upper layers, with visible characteristics in the upper and lower layers as shown in Table 6. was different. It should be noted that, in some of the examples, a discharge part was observed in which the composition in the lower layer protruded toward the upper layer in a substantially conical shape.

An attempt was made to produce a two-layer eyelash cosmetic composition by combining lower layer compositions 8 to 10 and upper layer compositions 1 to 5, but in this case, the lower layer composition and the upper layer composition were mixed. and no interface was formed between the lower layer and the upper layer.

Reference Signs List 1 Lower layer 2 Upper layer 3 Container 4 Applicator 5 Interfaces 6, 6a Discharge part 10 Multi-layer film-forming cosmetic

Claims (9)

A multilayer film-forming cosmetic comprising at least a lower layer comprising an oily or water-in-oil composition and an upper layer comprising an oily or water-in-oil composition,
Having an interface formed by the lower layer and the upper layer, and having different visible characteristics between the lower layer and the upper layer,
The viscosity of the composition constituting the lower layer is 10000 Pa s or more at 35 to 45 ° C.,
At the interface, the composition in the lower layer has a discharge part protruding in a substantially conical shape toward the upper layer, and the discharge part is filled in a transparent container including a semi-conical discharge part in contact with the side surface of the container. A multi-layered film-forming cosmetic. 2. The multilayer film-forming cosmetic according to claim 1, wherein said visible characteristic is hue, brightness, saturation, brightness or transparency. 3. The multilayer film-forming cosmetic according to claim 1 or 2 , wherein the compositions of said lower layer and said upper layer are mixed to change the visible characteristics of said lower layer and said upper layer. The multilayer film-forming cosmetic composition according to any one of claims 1 to 3 , wherein the multilayer film-forming cosmetic composition is for eyelashes. The multilayer film-forming cosmetic composition according to any one of claims 1 to 4 , wherein the multilayer film-forming cosmetic composition contains a film-forming agent. 6. The multilayer film-forming cosmetic composition according to claim 5 , wherein said film-forming agent is trimethylsiloxysilicate or pullulan tri(trimethylsiloxy)silylpropylcarbamate. 7. The multilayer film-forming cosmetic according to claim 6 , wherein said trimethylsiloxysilicate or tri(trimethylsiloxy)silylpropylcarbamate pullulan is 0.05 to 60% by mass based on the total amount of the lower layer composition. The multilayer film-forming cosmetic according to any one of claims 1 to 7 , wherein the composition contains a thickening agent. 9. The multilayer film-forming cosmetic according to claim 8 , wherein the thickener contains palmitic acid or dimethylsilyl silica.

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