JP5735752B2 - 無溶媒乳化方法 - Google Patents
無溶媒乳化方法 Download PDFInfo
- Publication number
- JP5735752B2 JP5735752B2 JP2010091993A JP2010091993A JP5735752B2 JP 5735752 B2 JP5735752 B2 JP 5735752B2 JP 2010091993 A JP2010091993 A JP 2010091993A JP 2010091993 A JP2010091993 A JP 2010091993A JP 5735752 B2 JP5735752 B2 JP 5735752B2
- Authority
- JP
- Japan
- Prior art keywords
- resin
- toner
- emulsion
- mixing
- particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title claims description 63
- 238000004945 emulsification Methods 0.000 title description 8
- 229920005989 resin Polymers 0.000 claims description 151
- 239000011347 resin Substances 0.000 claims description 151
- 239000002245 particle Substances 0.000 claims description 81
- 239000000839 emulsion Substances 0.000 claims description 64
- 238000002156 mixing Methods 0.000 claims description 50
- 239000000203 mixture Substances 0.000 claims description 49
- 239000004094 surface-active agent Substances 0.000 claims description 41
- 239000003795 chemical substances by application Substances 0.000 claims description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 38
- 239000003960 organic solvent Substances 0.000 claims description 17
- 230000002378 acidificating effect Effects 0.000 claims description 15
- 230000003472 neutralizing effect Effects 0.000 claims description 12
- 229920001225 polyester resin Polymers 0.000 claims description 7
- 239000004645 polyester resin Substances 0.000 claims description 7
- 239000003153 chemical reaction reagent Substances 0.000 claims description 4
- 239000000155 melt Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims 1
- 239000012071 phase Substances 0.000 description 56
- 239000003086 colorant Substances 0.000 description 17
- 239000000654 additive Substances 0.000 description 15
- 239000001993 wax Substances 0.000 description 15
- 230000002776 aggregation Effects 0.000 description 12
- 239000012670 alkaline solution Substances 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 12
- 239000000243 solution Substances 0.000 description 11
- 239000007864 aqueous solution Substances 0.000 description 10
- 238000010438 heat treatment Methods 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 10
- 238000005054 agglomeration Methods 0.000 description 9
- 239000003054 catalyst Substances 0.000 description 9
- 230000009477 glass transition Effects 0.000 description 9
- 239000002904 solvent Substances 0.000 description 8
- 238000004581 coalescence Methods 0.000 description 7
- 238000006386 neutralization reaction Methods 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 238000004132 cross linking Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 229920006038 crystalline resin Polymers 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000011342 resin composition Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 229920006127 amorphous resin Polymers 0.000 description 4
- 230000001112 coagulating effect Effects 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 3
- 238000004220 aggregation Methods 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000007771 core particle Substances 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000003384 imaging method Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
- 239000004926 polymethyl methacrylate Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 125000002843 carboxylic acid group Chemical group 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000011874 heated mixture Substances 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- CKRJGDYKYQUNIM-UHFFFAOYSA-N 3-fluoro-2,2-dimethylpropanoic acid Chemical compound FCC(C)(C)C(O)=O CKRJGDYKYQUNIM-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 239000000644 isotonic solution Substances 0.000 description 1
- 230000009191 jumping Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- 238000000614 phase inversion technique Methods 0.000 description 1
- 238000012643 polycondensation polymerization Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
- C08J3/05—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media from solid polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/40—Mixing liquids with liquids; Emulsifying
- B01F23/41—Emulsifying
- B01F23/411—Emulsifying using electrical or magnetic fields, heat or vibrations
- B01F23/4111—Emulsifying using electrical or magnetic fields, heat or vibrations using vibrations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/70—Pre-treatment of the materials to be mixed
- B01F23/711—Heating materials, e.g. melting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F31/00—Mixers with shaking, oscillating, or vibrating mechanisms
- B01F31/80—Mixing by means of high-frequency vibrations above one kHz, e.g. ultrasonic vibrations
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/0802—Preparation methods
- G03G9/0804—Preparation methods whereby the components are brought together in a liquid dispersing medium
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/0802—Preparation methods
- G03G9/081—Preparation methods by mixing the toner components in a liquefied state; melt kneading; reactive mixing
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/087—Binders for toner particles
- G03G9/08742—Binders for toner particles comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- G03G9/08755—Polyesters
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/087—Binders for toner particles
- G03G9/08784—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775
- G03G9/08791—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775 characterised by the presence of specified groups or side chains
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/087—Binders for toner particles
- G03G9/08784—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775
- G03G9/08795—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775 characterised by their chemical properties, e.g. acidity, molecular weight, sensitivity to reactants
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/087—Binders for toner particles
- G03G9/08784—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775
- G03G9/08797—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775 characterised by their physical properties, e.g. viscosity, solubility, melting temperature, softening temperature, glass transition temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F2215/00—Auxiliary or complementary information in relation with mixing
- B01F2215/04—Technical information in relation with mixing
- B01F2215/0413—Numerical information
- B01F2215/0436—Operational information
- B01F2215/0454—Numerical frequency values
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/06—Unsaturated polyesters
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/426,454 US8124309B2 (en) | 2009-04-20 | 2009-04-20 | Solvent-free emulsion process |
| US12/426,454 | 2009-04-20 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2010248511A JP2010248511A (ja) | 2010-11-04 |
| JP5735752B2 true JP5735752B2 (ja) | 2015-06-17 |
Family
ID=42234500
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010091993A Active JP5735752B2 (ja) | 2009-04-20 | 2010-04-13 | 無溶媒乳化方法 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US8124309B2 (US08124309-20120228-C00002.png) |
| EP (1) | EP2243800B1 (US08124309-20120228-C00002.png) |
| JP (1) | JP5735752B2 (US08124309-20120228-C00002.png) |
| CA (1) | CA2700696C (US08124309-20120228-C00002.png) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8435714B2 (en) * | 2009-04-20 | 2013-05-07 | Xerox Corporation | Solvent-free emulsion process using acoustic mixing |
| US8568952B2 (en) | 2012-01-25 | 2013-10-29 | Xerox Corporation | Method for manufacturing photoreceptor layers |
| US8735033B2 (en) * | 2012-03-29 | 2014-05-27 | Xerox Corporation | Toner process using acoustic mixer |
| US8877018B2 (en) * | 2012-04-04 | 2014-11-04 | Xerox Corporation | Process for the preparation of hydroxy gallium phthalocyanine |
| US8932792B2 (en) | 2012-11-27 | 2015-01-13 | Xerox Corporation | Preparation of polyester latex emulsification by direct steam injection |
| US9228099B2 (en) | 2012-12-21 | 2016-01-05 | Xerox Corporation | Phase change ink composition and process for preparing same |
| US8858896B2 (en) | 2013-01-14 | 2014-10-14 | Xerox Corporation | Toner making process |
| US8889331B2 (en) * | 2013-03-01 | 2014-11-18 | Xerox Corporation | Acoustic method to prepare polyester resin emulsions |
| US9291925B2 (en) | 2013-03-08 | 2016-03-22 | Xerox Corporation | Phase immersion emulsification process and apparatus |
| US9243148B2 (en) | 2013-03-29 | 2016-01-26 | Xerox Corporation | Preparation of pigment dispersions and toner compositions |
| US9358513B2 (en) | 2013-04-10 | 2016-06-07 | Xerox Corporation | Method and system for magnetic actuated mixing |
| US9234090B2 (en) | 2013-04-10 | 2016-01-12 | Xerox Corporation | Method and system for magnetic actuated milling for pigment dispersions |
| US8871420B1 (en) | 2013-04-10 | 2014-10-28 | Xerox Corporation | Method and system for magnetic actuated mixing to prepare latex emulsion |
| US20160008820A1 (en) | 2014-07-10 | 2016-01-14 | Xerox Corporation | Magnetic actuated-milled pigment dispersions and process for making thereof |
| JP6606842B2 (ja) * | 2015-03-25 | 2019-11-20 | 富士ゼロックス株式会社 | 樹脂粒子分散液の製造方法及びトナー粒子の製造方法 |
| JP6510918B2 (ja) | 2015-07-14 | 2019-05-08 | 理想科学工業株式会社 | 着色樹脂粒子分散体、その製造方法及びインクジェットインク |
| US11098167B2 (en) * | 2015-09-30 | 2021-08-24 | Sekisui Plastics Co., Ltd. | Polymer particles and use thereof |
| US10162279B2 (en) | 2016-07-29 | 2018-12-25 | Xerox Corporation | Solvent free emulsification processes |
| JP2022546467A (ja) | 2019-08-29 | 2022-11-04 | ダウ グローバル テクノロジーズ エルエルシー | ポリオレフィン固体と炭素固体との均質な混合物を作製する方法 |
| JP2022545119A (ja) | 2019-08-29 | 2022-10-25 | ダウ グローバル テクノロジーズ エルエルシー | ポリオレフィン固体と有機過酸化物との均質混合物を作製する方法 |
| KR20220051183A (ko) | 2019-08-29 | 2022-04-26 | 다우 글로벌 테크놀로지스 엘엘씨 | 폴리올레핀 고체와 고체 첨가제의 균질 혼합물을 제조하는 방법 |
| CA3147977A1 (en) | 2019-08-29 | 2021-03-04 | Dow Global Technologies Llc | Method of making a homogeneous mixture of polyvinyl chloride solids and additive |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3590000A (en) | 1967-06-05 | 1971-06-29 | Xerox Corp | Solid developer for latent electrostatic images |
| US3800588A (en) | 1971-04-30 | 1974-04-02 | Mts System Corp | Multiple axis control system for vibration test apparatus |
| US3847604A (en) | 1971-06-10 | 1974-11-12 | Xerox Corp | Electrostatic imaging process using nodular carriers |
| US4298672A (en) | 1978-06-01 | 1981-11-03 | Xerox Corporation | Toners containing alkyl pyridinium compounds and their hydrates |
| DE2966986D1 (en) | 1979-07-26 | 1984-06-20 | Baker Chem Co J T | Reagent for the quantitative determination of water, and its use |
| US4338390A (en) | 1980-12-04 | 1982-07-06 | Xerox Corporation | Quarternary ammonium sulfate or sulfonate charge control agents for electrophotographic developers compatible with viton fuser |
| US4937166A (en) | 1985-10-30 | 1990-06-26 | Xerox Corporation | Polymer coated carrier particles for electrophotographic developers |
| US4935326A (en) | 1985-10-30 | 1990-06-19 | Xerox Corporation | Electrophotographic carrier particles coated with polymer mixture |
| US5236629A (en) | 1991-11-15 | 1993-08-17 | Xerox Corporation | Conductive composite particles and processes for the preparation thereof |
| US5330874A (en) | 1992-09-30 | 1994-07-19 | Xerox Corporation | Dry carrier coating and processes |
| US5346797A (en) | 1993-02-25 | 1994-09-13 | Xerox Corporation | Toner processes |
| US5364729A (en) | 1993-06-25 | 1994-11-15 | Xerox Corporation | Toner aggregation processes |
| US5418108A (en) | 1993-06-25 | 1995-05-23 | Xerox Corporation | Toner emulsion aggregation process |
| US5403693A (en) | 1993-06-25 | 1995-04-04 | Xerox Corporation | Toner aggregation and coalescence processes |
| JPH08120091A (ja) * | 1994-10-21 | 1996-05-14 | Sekisui Chem Co Ltd | ウレタン樹脂エマルジョンの製造方法 |
| US5501935A (en) | 1995-01-17 | 1996-03-26 | Xerox Corporation | Toner aggregation processes |
| US5527658A (en) | 1995-03-13 | 1996-06-18 | Xerox Corporation | Toner aggregation processes using water insoluble transition metal containing powder |
| US5585215A (en) | 1996-06-13 | 1996-12-17 | Xerox Corporation | Toner compositions |
| US5650255A (en) | 1996-09-03 | 1997-07-22 | Xerox Corporation | Low shear toner aggregation processes |
| US5650256A (en) | 1996-10-02 | 1997-07-22 | Xerox Corporation | Toner processes |
| US5853943A (en) | 1998-01-09 | 1998-12-29 | Xerox Corporation | Toner processes |
| US6063827A (en) | 1998-07-22 | 2000-05-16 | Xerox Corporation | Polyester process |
| US6214507B1 (en) | 1998-08-11 | 2001-04-10 | Xerox Corporation | Toner compositions |
| US7323136B1 (en) * | 2000-02-01 | 2008-01-29 | William Marsh Rice University | Containerless mixing of metals and polymers with fullerenes and nanofibers to produce reinforced advanced materials |
| US6821703B2 (en) * | 2000-10-27 | 2004-11-23 | Dainippon Ink And Chemicals, Inc. | Method for producing polyester resin particle dispersion material, method for producing polyester resin particles, and method for producing electrophotographic spherical toner |
| US6593049B1 (en) | 2001-03-26 | 2003-07-15 | Xerox Corporation | Toner and developer compositions |
| US6756176B2 (en) | 2002-09-27 | 2004-06-29 | Xerox Corporation | Toner processes |
| US6830860B2 (en) * | 2003-01-22 | 2004-12-14 | Xerox Corporation | Toner compositions and processes thereof |
| JP4634273B2 (ja) * | 2005-10-14 | 2011-02-16 | 花王株式会社 | 樹脂乳化液の製造方法 |
| JP2008080257A (ja) * | 2006-09-28 | 2008-04-10 | Nippon Paint Co Ltd | 振動ミキサーを用いたエマルションの製造方法およびそれから得られる水性塗料組成物 |
-
2009
- 2009-04-20 US US12/426,454 patent/US8124309B2/en active Active
-
2010
- 2010-04-13 EP EP10159712.8A patent/EP2243800B1/en active Active
- 2010-04-13 CA CA2700696A patent/CA2700696C/en not_active Expired - Fee Related
- 2010-04-13 JP JP2010091993A patent/JP5735752B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2010248511A (ja) | 2010-11-04 |
| CA2700696A1 (en) | 2010-10-20 |
| EP2243800B1 (en) | 2013-12-25 |
| EP2243800A2 (en) | 2010-10-27 |
| US8124309B2 (en) | 2012-02-28 |
| CA2700696C (en) | 2014-01-14 |
| US20100266948A1 (en) | 2010-10-21 |
| EP2243800A3 (en) | 2012-10-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5735752B2 (ja) | 無溶媒乳化方法 | |
| JP5603557B2 (ja) | 樹脂エマルジョンを製造するための無溶媒転相法 | |
| JP5541561B2 (ja) | トナー組成物 | |
| US8697327B2 (en) | Toner production process and toner | |
| KR101489698B1 (ko) | 토너 조성물 | |
| JP5649935B2 (ja) | トナープロセス | |
| JP5367978B2 (ja) | トナー組成物 | |
| CA2562956C (en) | Emulsion containing epoxy resin | |
| JP5451258B2 (ja) | トナー組成物 | |
| KR20100044136A (ko) | 토너 조성물 및 방법 | |
| JP2010271715A (ja) | トナーおよびその製造方法 | |
| JP5864868B2 (ja) | ポリエステル樹脂を有するトナー | |
| JP5555057B2 (ja) | レオロジー調節を含むトナー作製方法 | |
| JP5681391B2 (ja) | 自己乳化性粒子、及び自己乳化性粒子からエマルジョンを作製する無溶媒プロセス | |
| JP2010140025A (ja) | トナープロセス | |
| JP5872890B2 (ja) | 静電潜像現像用トナーの製造方法 | |
| JP2011186455A (ja) | トナーの組成物および工程 | |
| JP5189787B2 (ja) | 樹脂乳化液の製造方法 | |
| JP5558944B2 (ja) | ポリエステルの合成方法 | |
| JP2005049394A (ja) | 静電荷像現像用トナーの製造方法 | |
| JP2011123484A (ja) | トナー組成物 | |
| JP2003122051A (ja) | 静電荷像現像用トナーの製造方法 | |
| JP2012098684A (ja) | トナープロセス | |
| JP5606879B2 (ja) | トナー組成物 | |
| JP2011248359A (ja) | 乳化凝集プロセス |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20130411 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20140806 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140818 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20141114 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20150406 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20150417 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 5735752 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |