JP5694203B2 - 染料感応太陽電池用吸着染料溶液のモニタリング装置及び染料溶液の調節装置 - Google Patents
染料感応太陽電池用吸着染料溶液のモニタリング装置及び染料溶液の調節装置 Download PDFInfo
- Publication number
- JP5694203B2 JP5694203B2 JP2011553940A JP2011553940A JP5694203B2 JP 5694203 B2 JP5694203 B2 JP 5694203B2 JP 2011553940 A JP2011553940 A JP 2011553940A JP 2011553940 A JP2011553940 A JP 2011553940A JP 5694203 B2 JP5694203 B2 JP 5694203B2
- Authority
- JP
- Japan
- Prior art keywords
- dye
- dye solution
- storage tank
- solar cell
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000001179 sorption measurement Methods 0.000 title claims description 62
- 238000012806 monitoring device Methods 0.000 title claims description 37
- 238000000034 method Methods 0.000 claims description 38
- 238000012544 monitoring process Methods 0.000 claims description 37
- 238000002835 absorbance Methods 0.000 claims description 32
- 238000012546 transfer Methods 0.000 claims description 28
- 239000002904 solvent Substances 0.000 claims description 20
- 230000008569 process Effects 0.000 claims description 16
- 239000002253 acid Substances 0.000 claims description 15
- 239000003463 adsorbent Substances 0.000 claims description 15
- 238000010979 pH adjustment Methods 0.000 claims description 7
- 230000031700 light absorption Effects 0.000 claims description 5
- 239000003002 pH adjusting agent Substances 0.000 claims description 4
- 238000001139 pH measurement Methods 0.000 claims description 3
- 239000000284 extract Substances 0.000 claims description 2
- 239000000975 dye Substances 0.000 description 260
- 230000008859 change Effects 0.000 description 9
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 229910052707 ruthenium Inorganic materials 0.000 description 8
- 239000003054 catalyst Substances 0.000 description 7
- 239000000758 substrate Substances 0.000 description 6
- 229910000314 transition metal oxide Inorganic materials 0.000 description 6
- -1 TBA cations Chemical class 0.000 description 5
- 239000002699 waste material Substances 0.000 description 5
- 229910010413 TiO 2 Inorganic materials 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000007726 management method Methods 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 230000006837 decompression Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- LTNAYKNIZNSHQA-UHFFFAOYSA-L 2-(4-carboxypyridin-2-yl)pyridine-4-carboxylic acid;ruthenium(2+);dithiocyanate Chemical compound N#CS[Ru]SC#N.OC(=O)C1=CC=NC(C=2N=CC=C(C=2)C(O)=O)=C1.OC(=O)C1=CC=NC(C=2N=CC=C(C=2)C(O)=O)=C1 LTNAYKNIZNSHQA-UHFFFAOYSA-L 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 238000011481 absorbance measurement Methods 0.000 description 1
- 229910021417 amorphous silicon Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/59—Transmissivity
- G01N21/5907—Densitometers
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/26—Oils; Viscous liquids; Paints; Inks
- G01N33/32—Paints; Inks
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/75—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated
- G01N21/77—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator
- G01N21/78—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator producing a change of colour
- G01N21/80—Indicating pH value
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/20—Light-sensitive devices
- H01G9/2059—Light-sensitive devices comprising an organic dye as the active light absorbing material, e.g. adsorbed on an electrode or dissolved in solution
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/20—Light-sensitive devices
- H01G9/2068—Panels or arrays of photoelectrochemical cells, e.g. photovoltaic modules based on photoelectrochemical cells
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/84—Systems specially adapted for particular applications
- G01N2021/8411—Application to online plant, process monitoring
- G01N2021/8416—Application to online plant, process monitoring and process controlling, not otherwise provided for
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/20—Light-sensitive devices
- H01G9/2027—Light-sensitive devices comprising an oxide semiconductor electrode
- H01G9/2031—Light-sensitive devices comprising an oxide semiconductor electrode comprising titanium oxide, e.g. TiO2
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/30—Coordination compounds
- H10K85/341—Transition metal complexes, e.g. Ru(II)polypyridine complexes
- H10K85/344—Transition metal complexes, e.g. Ru(II)polypyridine complexes comprising ruthenium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/542—Dye sensitized solar cells
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Power Engineering (AREA)
- Physics & Mathematics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pathology (AREA)
- Immunology (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Electrochemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Food Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Plasma & Fusion (AREA)
- Hybrid Cells (AREA)
- Photovoltaic Devices (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
Description
又は、染料感応太陽電池モジュールで染料溶液を循環させる移送ラインを有し、染料感応太陽電池用吸着染料溶液を貯蔵する貯蔵槽;前記染料感応太陽電池用吸着染料溶液をモニタリングする前記染料感応太陽電池用吸着染料溶液のモニタリング装置;前記貯蔵槽に貯蔵槽内の染料溶液より高濃度の染料溶液を供給する染料供給装置;前記貯蔵槽に酸又は塩基を供給するpH調節装置;前記移送ライン内の染料溶液の温度又は前記染料感応太陽電池モジュールの温度を測定し制御する温度調節部;前記移送ライン内の染料溶液の圧力又は前記染料感応太陽電池モジュール内の圧力を測定し制御する圧力調節部;及び、前記モニタリング装置から得られた吸光度及びpH値によって前記染料供給装置及びpH調節装置を制御する制御部を含むことを特徴とする染料感応太陽電池の染料吸着装置を提供する。
本発明の染料感応太陽電池用吸着染料溶液のモニタリング装置は、染料感応太陽電池用吸着染料溶液のモニタリング装置において、染料感応太陽電池用吸着染料溶液の吸光度を測定する吸光装置;及び、染料感応太陽電池用吸着染料溶液のpHを測定するpH測定装置を含む構成を有する。
即ち、本発明は染料感応太陽電池の製造のためにTiO2のような遷移金属酸化物多孔層に染料をより効果的に吸着するために染料溶液の状態をモニタリングするものであって、このために従来の染料感応太陽電池用吸着染料溶液のモニタリング装置に、染料溶液内の染料濃度をモニタリングするための、染料感応太陽電池用吸着染料溶液の吸光度を測定する吸光装置を備える。即ち、本発明の染料感応太陽電池用吸着染料溶液の特徴が光を吸収する吸光機能を有することであるという点に着眼して、前記吸光装置は光源を介して発生した光を染料に照射して、照射された光中の染料に吸光された光を除いた残りの光を測定して、染料溶液の吸光度を測定することによって、吸光機能を有する染料の濃度を測定するようにする。
10b 下面ガラス基板(作用極)
40 遷移金属酸化物層
50 封止部
Claims (14)
- 染料感応太陽電池用吸着染料溶液のモニタリング装置において、染料感応太陽電池用吸着染料溶液の吸光度を測定する吸光装置;及び、染料感応太陽電池用吸着染料溶液のpHを測定するpH測定装置を含むことを特徴とする染料感応太陽電池用吸着染料溶液のモニタリング装置。
- 前記吸光装置は、前記染料溶液を貯蔵する貯蔵槽又は移送する移送ラインから直接吸光度を測定し、或いは、前記貯蔵槽又は移送ラインからサンプルを抽出して吸光度を測定し、前記pH測定装置は前記染料溶液を貯蔵する貯蔵槽又は移送する移送ラインから直接pHを測定し、或いは、前記貯蔵槽又は移送ラインからサンプルを抽出してpHを測定することを特徴とする、請求項1に記載の染料感応太陽電池用吸着染料溶液のモニタリング装置。
- 前記吸光装置に適用される光源は、175nm乃至3300nmの波長を有するか、又はUV光源であることを特徴とする、請求項1に記載の染料感応太陽電池用吸着染料溶液のモニタリング装置。
- 染料感応太陽電池用吸着染料溶液の濁度又は伝導度を測定する付加測定装置をさらに含むことを特徴とする、請求項1に記載の染料感応太陽電池用吸着染料溶液のモニタリング装置。
- 染料感応太陽電池用吸着染料溶液を貯蔵する貯蔵槽;前記染料感応太陽電池用吸着染料溶液をモニタリングする請求項1乃至4のうちのいずれか一項の染料感応太陽電池用吸着染料溶液のモニタリング装置;前記貯蔵槽に貯蔵槽内の染料溶液より高濃度の染料溶液を供給する染料供給装置;前記貯蔵槽に酸又は塩基を供給するpH調節装置;及び、前記モニタリング装置から得られた吸光度及びpH値によって前記染料供給装置及びpH調節装置を制御する制御部を含むことを特徴とする染料感応太陽電池用吸着染料溶液の調節装置。
- 前記貯蔵槽に前記染料溶液の溶媒を供給する溶媒供給装置をさらに含み、前記制御部は前記モニタリング装置から得られた吸光度及びpH値によって前記染料供給装置、pH調節装置及び溶媒供給装置を制御することを特徴とする、請求項5に記載の染料感応太陽電池用吸着染料溶液の調節装置。
- 染料吸着用担持体の入出のための移送口を有し、染料感応太陽電池用吸着染料溶液を貯蔵する貯蔵槽;前記染料感応太陽電池用吸着染料溶液をモニタリングする請求項1乃至4のうちのいずれか一項の染料感応太陽電池用吸着染料溶液のモニタリング装置;前記貯蔵槽に貯蔵槽内の染料溶液より高濃度の染料溶液を供給する染料供給装置;前記貯蔵槽に酸又は塩基を供給するpH調節装置;前記貯蔵槽内の染料溶液の温度を測定し制御する温度調節部;前記貯蔵槽内の染料溶液の圧力を測定し制御する圧力調節部;及び、前記モニタリング装置から得られた吸光度及びpH値によって前記染料供給装置及びpH調節装置を制御する制御部を含むことを特徴とする染料感応太陽電池の染料吸着装置。
- 前記貯蔵槽に前記染料溶液の溶媒を供給する溶媒供給装置をさらに含み、前記制御部は前記モニタリング装置から得られた吸光度及びpH値によって前記染料供給装置、pH調節装置及び溶媒供給装置を制御することを特徴とする、請求項7に記載の染料感応太陽電池の染料吸着装置。
- 染料感応太陽電池モジュールで染料溶液を循環させる移送ラインを有し、染料感応太陽電池用吸着染料溶液を貯蔵する貯蔵槽;前記染料感応太陽電池用吸着染料溶液をモニタリングする請求項1乃至4のうちのいずれか一項の染料感応太陽電池用吸着染料溶液のモニタリング装置;前記貯蔵槽に貯蔵槽内の染料溶液より高濃度の染料溶液を供給する染料供給装置;前記貯蔵槽に酸又は塩基を供給するpH調節装置;前記移送ライン内の染料溶液の温度又は前記染料感応太陽電池モジュールの温度を測定し制御する温度調節部;前記移送ライン内の染料溶液の圧力又は前記染料感応太陽電池モジュール内の圧力を測定し制御する圧力調節部;及び、前記モニタリング装置から得られた吸光度及びpH値によって前記染料供給装置及びpH調節装置を制御する制御部を含むことを特徴とする染料感応太陽電池の染料吸着装置。
- 前記貯蔵槽に前記染料溶液の溶媒を供給する溶媒供給装置をさらに含み、前記制御部は前記モニタリング装置から得られた吸光度及びpH値によって前記染料供給装置、pH調節装置及び溶媒供給装置を制御することを特徴とする、請求項9に記載の染料感応太陽電池の染料吸着装置。
- 染料感応太陽電池用吸着染料溶液のモニタリング方法において、染料感応太陽電池用吸着染料溶液の吸光度測定及び染料感応太陽電池用吸着染料溶液のpH測定を同時に行うことを特徴とする染料感応太陽電池用吸着染料溶液のモニタリング方法。
- 前記染料溶液の染料は、前記染料溶液が吸着過程で酸度又は塩基度が変化する染料であることを特徴とする、請求項11に記載の染料感応太陽電池用吸着染料溶液のモニタリング方法。
- 染料感応太陽電池用吸着染料溶液を貯蔵する貯蔵槽の前記染料感応太陽電池用吸着染料溶液を請求項11又は12の染料感応太陽電池用吸着染料溶液のモニタリング方法でモニタリングし、前記モニタリングから得られた吸光度及びpH値によって前記貯蔵槽に貯蔵槽内の染料溶液より高濃度の染料溶液を供給し、或いは、前記貯蔵槽に酸又は塩基を供給することを特徴とする染料感応太陽電池用吸着染料溶液の調節方法。
- 染料感応太陽電池用吸着染料溶液を貯蔵する貯蔵槽の前記染料感応太陽電池用吸着染料溶液を請求項11又は12の染料感応太陽電池用吸着染料溶液のモニタリング方法でモニタリングし、前記モニタリングから得られた吸光度及びpH値によって前記貯蔵槽に貯蔵槽内の染料溶液より高濃度の染料溶液を供給し、前記貯蔵槽に酸又は塩基を供給し、或いは、前記染料溶液の溶媒を供給することを特徴とする染料感応太陽電池用吸着染料溶液の調節方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020090020112A KR101538133B1 (ko) | 2009-03-10 | 2009-03-10 | 염료감응 태양전지 흡착 염료용액의 모니터링 장치 및 염료용액의 조절 장치 |
KR10-2009-0020112 | 2009-03-10 | ||
PCT/KR2010/001415 WO2010104294A2 (ko) | 2009-03-10 | 2010-03-08 | 염료감응 태양전지 흡착 염료용액의 모니터링 장치 및 염료 용액의 조절 장치 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2012520456A JP2012520456A (ja) | 2012-09-06 |
JP5694203B2 true JP5694203B2 (ja) | 2015-04-01 |
Family
ID=42728921
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2011553940A Expired - Fee Related JP5694203B2 (ja) | 2009-03-10 | 2010-03-08 | 染料感応太陽電池用吸着染料溶液のモニタリング装置及び染料溶液の調節装置 |
Country Status (7)
Country | Link |
---|---|
US (1) | US9068941B2 (ja) |
EP (1) | EP2407780A4 (ja) |
JP (1) | JP5694203B2 (ja) |
KR (1) | KR101538133B1 (ja) |
CN (1) | CN102348978B (ja) |
TW (1) | TWI493170B (ja) |
WO (1) | WO2010104294A2 (ja) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101242244B1 (ko) * | 2011-11-07 | 2013-03-11 | 주식회사 세아 이앤티 | 염료감응 태양전지의 제조를 위한 흐름식 염료 흡착장치 |
CN103903866B (zh) * | 2012-12-28 | 2018-10-30 | 中国科学院上海硅酸盐研究所 | 染料敏化太阳能电池制造过程中染料溶液的重复使用与再生方法 |
CN103714977B (zh) * | 2013-12-31 | 2016-09-07 | 中国科学院上海硅酸盐研究所 | 一种提高染料敏化太阳能电池光电转换效率的方法 |
CN105632769B (zh) * | 2015-12-30 | 2018-02-06 | 上海硅酸盐研究所中试基地 | 一种全自动的染料敏化太阳能电池染料敏化设备 |
TWI604622B (zh) | 2016-07-14 | 2017-11-01 | 財團法人工業技術研究院 | 電極吸附染料的方法及其裝置 |
CN113029992B (zh) * | 2021-03-03 | 2022-01-18 | 重庆科技学院 | 一种黏弹性流体在介质表面动态吸附的实验装置及方法 |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH644471A5 (fr) * | 1981-02-02 | 1984-07-31 | Michael Graetzel | Produit destine a etre utilise comme photocatalyseur, procede de preparation de ce produit et utilisation de ce produit. |
US4591550A (en) * | 1984-03-01 | 1986-05-27 | Molecular Devices Corporation | Device having photoresponsive electrode for determining analytes including ligands and antibodies |
US5500188A (en) * | 1984-03-01 | 1996-03-19 | Molecular Devices Corporation | Device for photoresponsive detection and discrimination |
DE3914185A1 (de) * | 1989-04-28 | 1990-10-31 | Ciba Geigy Ag | Verfahren zur steuerung und optimierung industrieller prozesse |
CN102226766B (zh) * | 1998-08-26 | 2017-03-01 | 医药及科学传感器公司 | 基于光学的感测装置 |
JP2001164480A (ja) * | 1999-12-03 | 2001-06-19 | Toray Ind Inc | ポリエステル布帛の染色方法 |
US6913713B2 (en) * | 2002-01-25 | 2005-07-05 | Konarka Technologies, Inc. | Photovoltaic fibers |
KR100400438B1 (ko) * | 2000-10-13 | 2003-10-01 | 주식회사 엔비텍 | 광전기화학적 금속부식 방지 시스템 |
ATE462130T1 (de) * | 2001-06-27 | 2010-04-15 | Atlantic Business Ct Of Excell | Verfahren und vorrichtung zur überwachung von substanzen |
US20040211458A1 (en) * | 2003-04-28 | 2004-10-28 | General Electric Company | Tandem photovoltaic cell stacks |
KR100578798B1 (ko) * | 2003-12-12 | 2006-05-11 | 삼성에스디아이 주식회사 | 염료감응 태양전지 및 그 제조 방법 |
JP4666926B2 (ja) * | 2004-02-13 | 2011-04-06 | 住友大阪セメント株式会社 | 色素増感型太陽電池 |
US20060249201A1 (en) * | 2005-05-09 | 2006-11-09 | Solaris Nanosciences, Inc. | Rechargeable dye sensitized solar cell |
US7446207B2 (en) * | 2005-09-27 | 2008-11-04 | Ctci Foundation | Organic dye used in dye-sensitized solar cell |
DE102005053995A1 (de) * | 2005-11-10 | 2007-05-24 | Basf Ag | Verwendung von Rylenderivaten als Photosensibilisatoren in Solarzellen |
TW200805687A (en) * | 2006-07-11 | 2008-01-16 | Rich Power Technologies Ltd | Dye-sensitized solar cell and method of manufacturing the same |
KR20080054971A (ko) * | 2006-12-14 | 2008-06-19 | 삼성전자주식회사 | 염료감응형 태양전지 및 그 제조방법 |
KR20080072425A (ko) * | 2007-02-02 | 2008-08-06 | 주식회사 동진쎄미켐 | 염료감응 태양전지 및 그 제조방법 |
KR20080079894A (ko) * | 2007-02-28 | 2008-09-02 | 삼성에스디아이 주식회사 | 염료감응 태양전지 및 이의 제조방법 |
US7804149B2 (en) * | 2007-04-02 | 2010-09-28 | The University Of Utah Research Foundation | Nanostructured ZnO electrodes for efficient dye sensitized solar cells |
CN101299054B (zh) * | 2008-05-23 | 2010-12-08 | 南京大学 | 染料敏化纳米薄膜太阳能电池i-v特性和转换效率特性的测量方法 |
-
2009
- 2009-03-10 KR KR1020090020112A patent/KR101538133B1/ko active IP Right Grant
-
2010
- 2010-03-08 WO PCT/KR2010/001415 patent/WO2010104294A2/ko active Application Filing
- 2010-03-08 CN CN201080011516.6A patent/CN102348978B/zh not_active Expired - Fee Related
- 2010-03-08 EP EP20100750985 patent/EP2407780A4/en not_active Withdrawn
- 2010-03-08 JP JP2011553940A patent/JP5694203B2/ja not_active Expired - Fee Related
- 2010-03-08 US US13/255,451 patent/US9068941B2/en not_active Expired - Fee Related
- 2010-03-09 TW TW099106751A patent/TWI493170B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
KR101538133B1 (ko) | 2015-07-22 |
EP2407780A2 (en) | 2012-01-18 |
US9068941B2 (en) | 2015-06-30 |
TWI493170B (zh) | 2015-07-21 |
WO2010104294A3 (ko) | 2010-12-16 |
EP2407780A4 (en) | 2013-04-24 |
WO2010104294A2 (ko) | 2010-09-16 |
TW201111767A (en) | 2011-04-01 |
KR20100101761A (ko) | 2010-09-20 |
US20120037270A1 (en) | 2012-02-16 |
CN102348978B (zh) | 2015-01-14 |
CN102348978A (zh) | 2012-02-08 |
JP2012520456A (ja) | 2012-09-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5694203B2 (ja) | 染料感応太陽電池用吸着染料溶液のモニタリング装置及び染料溶液の調節装置 | |
Boschloo et al. | Spectroelectrochemistry of nanostructured NiO | |
Chen et al. | Surface modifications of (ZnSe) 0.5 (CuGa2. 5Se4. 25) 0.5 to promote photocatalytic Z-scheme overall water splitting | |
Bloor et al. | Solar-driven water oxidation and decoupled hydrogen production mediated by an electron-coupled-proton buffer | |
Qi et al. | A simple post-treatment with urea solution to enhance the photoelectric conversion efficiency for TiO2 dye-sensitized solar cells | |
Hara et al. | Long-term stability of organic–dye-sensitized solar cells based on an alkyl-functionalized carbazole dye | |
Song et al. | ZnO/PbS core/shell nanorod arrays as efficient counter electrode for quantum dot-sensitized solar cells | |
Tang et al. | Effect of the adsorbed concentration of dye on charge recombination in dye-sensitized solar cells | |
WO2005112183A1 (ja) | 光電変換素子、及び半導体電極 | |
Ke et al. | Degradation mechanism of ZnO-based dye-sensitized solar cells | |
Sun et al. | Dye-sensitized photocathodes for oxygen reduction: efficient H 2 O 2 production and aprotic redox reactions | |
KR20120062219A (ko) | 태양전지 모듈 | |
KR101034618B1 (ko) | 자외선 경화형 우레탄아크릴레이트를 포함하는 염료감응태양전지용 겔형 고분자 전해질, 이를 포함하는 염료감응태양전지 및 염료감응 태양전지의 제조방법 | |
Hossain et al. | Microstructured ZnO photoelectrode grown on the sputter-deposited ZnO passivating-layer for improving the photovoltaic performances | |
EP2541673A1 (en) | Apparatus for manufacturing dye-sensitized solar cell, and method of manufacturing dye-sensitized solar cell | |
Mohanty et al. | Effect of aging conditions on the performance of dip coated platinum counter electrode based dye sensitized solar cells | |
JP2007117811A (ja) | 光触媒膜、水分解用半導体光電極およびこれを用いた水分解装置 | |
KR100990970B1 (ko) | 산란층을 포함하는 염료감응 태양전지용 겔형 고분자 전해질, 이를 포함하는 염료감응 태양전지 및 염료감응 태양전지의 제조방법 | |
KR101488223B1 (ko) | 광 흡수 증대 수단이 구비된 염료감응형 태양전지 제조방법 및 그 태양전지 | |
JP2013110066A (ja) | 色素増感型太陽電池の製造装置及び色素増感型太陽電池の製造方法 | |
KR20100076925A (ko) | 자외선 경화형 우레탄아크릴레이트를 포함하는 염료감응 태양전지용 겔형 고분자 전해질, 이를 포함하는 염료감응 태양전지 및 염료감응 태양전지의 제조방법 | |
Dai et al. | Facile pyrolytic synthesis of copper zinc tin sulfide thin films for efficient counter electrodes in quantum dot sensitized solar cells | |
TWI725699B (zh) | 染料敏化太陽能電池及其形成方法 | |
CN108288546B (zh) | 镍、钴取代的锌钨杂多配合物/结晶紫有序薄膜的光电转换性能 | |
Wang et al. | Photo-induced degradation of Ru (II) complex absorbed on anatase TiO 2 thin film electrode |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20130225 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20140514 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140520 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140820 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20150120 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20150204 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5694203 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |