JP5676586B2 - 耐衝撃性プロピレンポリマー組成物の製造方法 - Google Patents
耐衝撃性プロピレンポリマー組成物の製造方法 Download PDFInfo
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- JP5676586B2 JP5676586B2 JP2012515473A JP2012515473A JP5676586B2 JP 5676586 B2 JP5676586 B2 JP 5676586B2 JP 2012515473 A JP2012515473 A JP 2012515473A JP 2012515473 A JP2012515473 A JP 2012515473A JP 5676586 B2 JP5676586 B2 JP 5676586B2
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- 125000000217 alkyl group Chemical group 0.000 description 7
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- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 3
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- 125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
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- 125000001637 1-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C(*)=C([H])C([H])=C([H])C2=C1[H] 0.000 description 2
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 2
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- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
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- 229940087101 dibenzylidene sorbitol Drugs 0.000 description 2
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- 238000004817 gas chromatography Methods 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
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- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
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- 230000007704 transition Effects 0.000 description 2
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- BEDHCUAJOBASSZ-UHFFFAOYSA-N (2-cyclopentyl-1,3-dimethoxypropan-2-yl)cyclopentane Chemical compound C1CCCC1C(COC)(COC)C1CCCC1 BEDHCUAJOBASSZ-UHFFFAOYSA-N 0.000 description 1
- VFIOZKTXVHLWRA-UHFFFAOYSA-N (2-ethylpiperidin-1-yl)-dimethoxy-(1,1,1-trifluoropropan-2-yl)silane Chemical compound CCC1CCCCN1[Si](OC)(OC)C(C)C(F)(F)F VFIOZKTXVHLWRA-UHFFFAOYSA-N 0.000 description 1
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- WNVMVIYFKFGESM-UHFFFAOYSA-N bis(2-methylpropyl) 2,3-di(propan-2-yl)butanedioate Chemical compound CC(C)COC(=O)C(C(C)C)C(C(C)C)C(=O)OCC(C)C WNVMVIYFKFGESM-UHFFFAOYSA-N 0.000 description 1
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- BTJCEVZMRIJBSM-UHFFFAOYSA-N dimethoxy-methyl-(1,1,1-trifluoropropan-2-yl)silane Chemical compound CO[Si](C)(OC)C(C)C(F)(F)F BTJCEVZMRIJBSM-UHFFFAOYSA-N 0.000 description 1
- 125000005982 diphenylmethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
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- 239000005457 ice water Substances 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
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- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
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- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
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- 230000003287 optical effect Effects 0.000 description 1
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- 125000003538 pentan-3-yl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])[H] 0.000 description 1
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- 239000000843 powder Substances 0.000 description 1
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- 230000000284 resting effect Effects 0.000 description 1
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- NETBVGNWMHLXRP-UHFFFAOYSA-N tert-butyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C(C)(C)C NETBVGNWMHLXRP-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
- C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/16—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of silicon, germanium, tin, lead, titanium, zirconium or hafnium
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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| EP09163192.9 | 2009-06-19 | ||
| EP09163192 | 2009-06-19 | ||
| US26963509P | 2009-06-26 | 2009-06-26 | |
| US61/269,635 | 2009-06-26 | ||
| PCT/EP2010/058437 WO2010146074A1 (en) | 2009-06-19 | 2010-06-16 | Process for the preparation of impact resistant propylene polymer compositions |
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| JP2012530170A JP2012530170A (ja) | 2012-11-29 |
| JP2012530170A5 JP2012530170A5 (OSRAM) | 2013-07-04 |
| JP5676586B2 true JP5676586B2 (ja) | 2015-02-25 |
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| EP (1) | EP2443159B1 (OSRAM) |
| JP (1) | JP5676586B2 (OSRAM) |
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| BR (1) | BRPI1014019B1 (OSRAM) |
| ES (1) | ES2672731T3 (OSRAM) |
| RU (1) | RU2536682C2 (OSRAM) |
| WO (1) | WO2010146074A1 (OSRAM) |
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| BR112012006532B1 (pt) | 2009-09-22 | 2019-08-20 | Basell Poliolefine Italia S.R.L. | Composições de polímero de propileno |
| WO2011036014A1 (en) | 2009-09-22 | 2011-03-31 | Basell Poliolefine Italia S.R.L. | Propylene polymer compositions |
| CN102597022B (zh) * | 2009-11-19 | 2014-11-19 | 巴塞尔聚烯烃意大利有限责任公司 | 用于制备耐冲击丙烯聚合物组合物的方法 |
| EP2666790B1 (en) * | 2011-01-19 | 2015-03-04 | China Petroleum & Chemical Corporation | Solid catalyst component and catalyst for olefin polymerization |
| RU2598073C2 (ru) * | 2011-04-12 | 2016-09-20 | Базелль Полиолефин Италия С.Р.Л. | Компоненты катализатора для полимеризации олефинов |
| BR112013028699B1 (pt) * | 2011-05-11 | 2021-03-16 | Basell Poliolefine Italia S.R.L | composições de poliolefina e de poliolefina enchida bem como artigos, folhas ou películas para cobertura e enchimento interno para cabos industriais ou embainhamento de cabos compreendendo as referidas composições |
| WO2013004507A1 (en) * | 2011-07-01 | 2013-01-10 | Basell Poliolefine Italia S.R.L. | Polypropylene films and sheets |
| WO2013050384A2 (en) * | 2011-10-07 | 2013-04-11 | Total Research & Technology Feluy | High-fluidity heterophasic propylene copolymer with improved rigidity |
| EP2594593A1 (en) | 2011-11-17 | 2013-05-22 | Basell Poliolefine Italia S.r.l. | Process for the preparation of heterophasic propylene polymer compositions |
| EP2682505A1 (en) * | 2012-07-06 | 2014-01-08 | Basell Poliolefine Italia S.r.l. | Polypropylene fiber |
| EP2722348A1 (en) * | 2012-10-16 | 2014-04-23 | Basell Poliolefine Italia S.r.l. | Process for the preparation of propylene random copolymers |
| WO2014139811A2 (en) | 2013-03-15 | 2014-09-18 | Basell Poliolefine Italia S.R.L. | Process for the preparation of propylene terpolymers and terpolymers obtained thereby |
| EP2829557A1 (en) * | 2013-07-22 | 2015-01-28 | Basell Poliolefine Italia S.r.l. | Sterilisable article made of propylene copolymer |
| TWI639626B (zh) * | 2013-09-30 | 2018-11-01 | 中國石油化工科技開發有限公司 | Catalyst composition for olefin polymerization and application thereof |
| CN105636994B (zh) * | 2013-10-24 | 2021-03-26 | 巴塞尔聚烯烃意大利有限公司 | 多孔丙烯聚合物的制备方法 |
| BR112018002018B1 (pt) | 2015-08-04 | 2022-05-17 | Basell Poliolefine Italia S.R.L. | Componente catalisador pré-polimerizado, sistema de catalisador e processo em fase gasosa para polimerização de olefinas |
| CA3004383C (en) * | 2015-11-17 | 2020-07-21 | Borealis Ag | High flow tpo composition with excellent low temperature impact |
| PL3170864T3 (pl) * | 2015-11-17 | 2019-04-30 | Borealis Ag | Wysokopłynąca kompozycja TPO o doskonałej równowadze właściwości mechanicznych, do wyposażenia wewnętrznego pojazdu |
| US9777084B2 (en) | 2016-02-19 | 2017-10-03 | Formosa Plastics Corporation, Usa | Catalyst system for olefin polymerization and method for producing olefin polymer |
| JP6860326B2 (ja) * | 2016-11-07 | 2021-04-14 | サンアロマー株式会社 | ポリプロピレン組成物およびこれを成形してなるマット調フィルム |
| BR112021008495A2 (pt) * | 2018-12-04 | 2021-08-03 | Basell Poliolefine Italia S.R.L. | processo para a preparação de um polímero de polipropileno. |
| CN114058113B (zh) * | 2020-08-10 | 2023-09-26 | 中国石油天然气股份有限公司 | 高抗冲透明聚丙烯树脂及其制备方法 |
| WO2022084033A1 (en) * | 2020-10-19 | 2022-04-28 | Basell Poliolefine Italia S.R.L. | Polypropylene composition |
| US12319756B2 (en) | 2021-06-25 | 2025-06-03 | Braskem S. A. | Propylene preliminary polymerization |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DK133012C (da) | 1968-11-21 | 1976-08-09 | Montedison Spa | Katalysator til polymerisation af alkener |
| YU35844B (en) | 1968-11-25 | 1981-08-31 | Montedison Spa | Process for obtaining catalysts for the polymerization of olefines |
| IT1098272B (it) * | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| IL117114A (en) | 1995-02-21 | 2000-02-17 | Montell North America Inc | Components and catalysts for the polymerization ofolefins |
| FI952175A7 (fi) | 1995-05-05 | 1996-11-06 | Borealis As | Menetelmä ja katalysaattorikomponentti olefiinien homo- tai kopolymeroimiseksi |
| KR100700957B1 (ko) | 1999-04-15 | 2007-03-28 | 바셀 테크놀로지 컴퍼니 비.브이. | 올레핀 중합반응을 위한 성분 및 촉매 |
| JP4644352B2 (ja) * | 2000-10-19 | 2011-03-02 | 日本ポリプロ株式会社 | プロピレン−エチレンブロック共重合体の製造方法 |
| TWI268939B (en) | 2001-12-12 | 2006-12-21 | Basell Poliolefine Spa | Process for the polymerization of olefins |
| EP1525231B1 (en) * | 2002-07-02 | 2007-12-05 | Basell Poliolefine Italia S.r.l. | Catalyst system for the polymerization of olefins |
| US7005487B2 (en) | 2002-07-02 | 2006-02-28 | Basell Poliolefine Italia S.R.L. | Catalyst system for the polymerization of olefins |
| PL374508A1 (en) | 2002-08-01 | 2005-10-31 | Basell Poliolefine Italia S.P.A. | Highly stereoregular polypropylene with improved properties |
| TW200427763A (en) * | 2003-04-03 | 2004-12-16 | Basell Poliolefine Spa | Impact resistant polyolefin compositions |
| CN1274724C (zh) * | 2003-09-18 | 2006-09-13 | 中国石油化工股份有限公司 | 一种生产烯烃聚合物的方法及其聚合物 |
| KR20070112105A (ko) * | 2004-10-04 | 2007-11-22 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 엘라스토머 폴리올레핀 조성물 |
| RU2374265C2 (ru) | 2004-10-14 | 2009-11-27 | Базелль Полиолефин Италия С.Р.Л. | Способ газофазной полимеризации олефинов |
| EP1849807A1 (en) * | 2006-04-24 | 2007-10-31 | Total Petrochemicals Research Feluy | Catalyst composition for the copolymerization of propylene |
| WO2007122239A1 (en) * | 2006-04-24 | 2007-11-01 | Total Petrochemicals Research Feluy | Use of a ziegler-natta catalyst to make a polypropylene homopolymer or random copolymer having a high melt flow rate |
| EP2029637B1 (en) | 2006-06-21 | 2010-04-21 | Total Petrochemicals Research Feluy | Catalyst composition for the (co)polymerization of propylene. |
| US20100029869A1 (en) | 2006-12-20 | 2010-02-04 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins and catalysts therefrom obtained |
| KR20090101192A (ko) | 2006-12-22 | 2009-09-24 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 올레핀 중합용 촉매 성분 및 그로부터 수득된 촉매 |
| WO2009050045A2 (en) | 2007-10-15 | 2009-04-23 | Basell Poliolefine Italia S.R.L. | Process for the preparation of high fluidity propylene polymers |
| EP2222719A2 (en) * | 2007-12-20 | 2010-09-01 | Basell Poliolefine Italia S.R.L. | Highly stereoregular polypropylene with improved properties |
| EP2225288B1 (en) * | 2007-12-21 | 2018-08-29 | W.R. Grace & CO. - CONN. | Self-limiting catalyst composition with bidentate internal donor |
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Also Published As
| Publication number | Publication date |
|---|---|
| EP2443159B1 (en) | 2018-04-25 |
| BRPI1014019B1 (pt) | 2019-10-22 |
| KR101769275B1 (ko) | 2017-08-18 |
| ES2672731T3 (es) | 2018-06-15 |
| CN107043491A (zh) | 2017-08-15 |
| BRPI1014019A2 (pt) | 2016-04-12 |
| EP2443159A1 (en) | 2012-04-25 |
| CN102803310A (zh) | 2012-11-28 |
| JP2012530170A (ja) | 2012-11-29 |
| RU2012101804A (ru) | 2013-07-27 |
| US20120083576A1 (en) | 2012-04-05 |
| KR20120042763A (ko) | 2012-05-03 |
| RU2536682C2 (ru) | 2014-12-27 |
| WO2010146074A1 (en) | 2010-12-23 |
| US9068028B2 (en) | 2015-06-30 |
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