JP5619052B2 - Fuel cell - Google Patents

Description

  Embodiments described herein relate generally to a fuel cell.

  A fuel cell generally comprises an electrolyte membrane, an electrode catalyst layer, a gas diffusion layer, and a separator, and these four members are combined to form a basic structure called a cell. The main components of the electrode catalyst layer are a catalyst-carrying conductor and an electrolyte added for proton transfer. In the anode catalyst layer, electrons are taken out by an oxidation reaction of hydrogen, and protons are generated. The generated protons move through the electrolyte in the anode catalyst layer to the electrolyte membrane and are supplied to the cathode catalyst layer. In the cathode catalyst layer, a reduction reaction of oxygen occurs, and water is generated by a reaction with protons supplied from the anode catalyst layer.

  The catalyst-carrying conductor constituting the electrode catalyst layer is a particle having a size of several tens of nm, and generally a proton conductive resin is used as the electrolyte. When an electrode catalyst layer is prepared by applying a slurry obtained by mixing these, the diameter of the voids present in the catalyst layer is on the nano order and becomes very small. As a result, in the middle to high current density region of the cathode catalyst layer, there arises a problem that the generated water blocks the voids in the catalyst layer and inhibits gas diffusion. In addition, the smaller the gap diameter, the easier it is to hold water by capillary action, which causes flooding. Therefore, in order to solve these problems, many inventions have been proposed in which the diameter of the void formed in the cathode catalyst layer is devised by changing the particle diameter of the catalyst-supporting conductor constituting the cathode catalyst layer. Yes.

JP 2006-294594 A JP 2008-186798 A JP-A-8-227716

  The problem to be solved by the present invention is to provide a fuel cell in which the gas diffusibility of the cathode catalyst layer is improved.

According to the embodiment, the electrolyte membrane, the anode catalyst layer and the anode gas diffusion layer disposed on one surface of the electrolyte membrane, and the cathode catalyst layer and the cathode gas diffusion layer disposed on the other surface of the electrolyte membrane. A fuel cell is provided. The cathode catalyst layer includes binder particles obtained by binding catalyst-carrying conductive particles or aggregates thereof with a proton conductive resin , and the cathode catalyst layer is formed on a surface of a base material that supports the cathode catalyst layer. It is produced by creating a gas flow in a direction perpendicular to the gas, and depositing the binding particles on the base material according to the gas flow, and the binding particles are more than the average diameter of the voids in the binding particles. The average diameter of the voids between the particles is larger.

It is sectional drawing of the fuel battery cell which concerns on embodiment. It is a figure which shows the cathode catalyst layer which concerns on embodiment. It is an enlarged view of binder particles. It is a figure which shows an example of the preparation methods of the cathode catalyst layer which concerns on embodiment. FIG. 3 is a view showing a particle size distribution of binder particles in Example 1. FIG. 3 is a diagram showing a void distribution in the cathode catalyst layer of Example 1. It is a conceptual diagram which shows the distance between particle | grains when a binding particle is located in a line. FIG. 3 is a view showing a void distribution in a cathode catalyst layer of Comparative Example 1. It is a figure which shows the relationship between a current density and a cell voltage.

  Hereinafter, embodiments will be described with reference to the drawings.

  FIG. 1 is a cross-sectional view of a fuel cell according to an embodiment.

  The fuel cell 1 has a structure in which a membrane electrode assembly in which an anode 2 and a cathode 3 are bonded to both surfaces of an electrolyte membrane 4 is sandwiched between an anode separator 9 and a cathode separator 10.

  The anode 2 is formed by laminating an anode catalyst layer 5 and an anode gas diffusion layer 6 in this order from the side in contact with the electrolyte membrane 4. On the other hand, the cathode 3 is formed by laminating the cathode catalyst layer 7 and the cathode gas diffusion layer 8 in this order from the side in contact with the electrolyte membrane 4.

  When actually generating power, a fuel cell stack is generally used in which a plurality of the fuel cells 1 that are unit cells are stacked in the thickness direction.

  Hereinafter, each member of the fuel cell shown in FIG. 1 will be described in detail.

  The anode catalyst layer 5 and the cathode catalyst layer 7 are layers where the reaction actually proceeds there. Specifically, the oxidation reaction of hydrogen proceeds in the anode catalyst layer 5, and the reduction reaction of oxygen proceeds in the cathode catalyst layer 7. Both the anode catalyst layer 5 and the cathode catalyst layer 7 contain a catalyst and an electrolyte having proton conductivity.

  FIG. 2 is a conceptual diagram showing a cathode catalyst layer of the fuel battery cell according to the embodiment. The cathode catalyst layer 7 has a structure in which binder particles 15 made of catalyst-carrying conductive particles and proton conductive resin are deposited on a substrate 16. FIG. 3 is an enlarged view of the binder particles. The binder particles 15 have a structure in which a plurality of particles of the catalyst-carrying conductive particles 11 or aggregates thereof are aggregated, and the proton conductive resin 14 enters the voids in the aggregate. The catalyst-carrying conductive particles 11 have a configuration in which the conductive particles 12 carry the catalyst 13. The particle diameter of the binder particles 15 is preferably distributed in the range of 0.6 to 10 μm, particularly 1 to 10 μm, and the average particle diameter is preferably 1 to 7 μm. By setting the size of the binder particles as described above, when the binder particles are deposited as shown in FIG. 2, a relatively large gap is formed between the binder particles. Here, the particle diameter was calculated by an image analysis method in which the area of the particle was obtained from the image and the equivalent circle diameter of the particle was calculated assuming that the particle was a circle. Moreover, the average particle diameter averaged the particle diameter of 3000 particle samples.

  Carbon black having a diameter of 10 to 50 nm is mainly used as the conductive particles 12, and platinum having a diameter of several nm is mainly used as the catalyst 13. In addition to the platinum-based elements such as palladium, ruthenium, iridium, rhodium, and osmium, the catalyst 13 includes metals such as iron, nickel, manganese, vanadium, molybdenum, gallium, and aluminum, alloys thereof, and oxidation of these metals. Or a double oxide or a carrier thereof.

  As the proton conductive resin 14, a fluorine-based or hydrocarbon-based resin can be used. Examples of the fluororesin include DuPont Nafion (registered trademark), Asahi Kasei Aciplex (registered trademark), and Asahi Glass Flemion (registered trademark). The proton conductive resin 14 plays a role of improving the mobility of protons that move from the anode catalyst layer 5 to the electrolyte membrane 4 and the cathode catalyst layer 7 as power generation proceeds.

  Below, the preparation methods of the cathode catalyst layer 7 are demonstrated.

  First, binder particles are prepared. A slurry containing catalyst-carrying conductive particles and proton conductive resin is prepared and dried to obtain a powder. The obtained dry powder is pulverized to obtain binder particles. As a stirrer for slurry preparation, a homogenizer, an ultrasonic disperser, a bead mill, etc. can be used. For drying the slurry, a drying method such as drying in a drying oven or spray drying, reduced pressure drying such as an evaporator or freeze drying, or a combination of heating drying and reduced pressure drying can be used.

  Subsequently, the binder particles produced as described above are deposited on the substrate. The deposition of the binder particles on the substrate is a method of dropping the binder particles on the substrate, creating a gas flow in a direction perpendicular to the surface of the substrate having air permeability, and binding according to the flow. The method may be performed by any method known in the art, such as a method of depositing particles on a substrate, or a method of compressing a substrate and binder particles in a mold. In this, a method of creating a gas flow in a direction perpendicular to the surface of the substrate having air permeability and depositing the binder particles on the substrate according to the flow will be described with reference to FIG.

  FIG. 4 is a diagram illustrating an example of a method for producing a cathode catalyst layer according to the embodiment. That is, the cathode catalyst layer is formed by creating a gas flow in the chamber 21 in a direction perpendicular to the surface of the substrate 16 and depositing the binder particles 15 on the substrate 16.

  More specifically, first, the base material 16 is set on the table 24. The center of the table 24 is a metal mesh, for example, so that gas can pass through. As the base material 16, a base material having air permeability is used. The seal 25 is a member for preventing the gas flowing from the base material upstream space 22 to the base material downstream space 23 from flowing around the base material 16. A gas flow is created, and the binding particles 15 are placed on the flow. When the gas carrying the binding particles 15 passes through the surface of the base material 16, the base material 16 captures the binding particles 15 like a filter, and the binding particles 15 are deposited on the base material 16. The gas passes through the inside of the base material 16 and the metal mesh portion of the table 24 as it is, and exits to the base material downstream space 23.

  On the other hand, a generally used method for producing a catalyst layer is to apply a slurry containing catalyst-carrying conductive particles, proton conductive resin, water, alcohol, and the like with a coating machine such as a die coater, and then apply the coating. This is a method of drying a membrane.

  Therefore, the difference between the method for preparing the cathode catalyst layer of the present embodiment and a general method is in which stage the drying process is performed. In the cathode catalyst layer preparation method of the present embodiment, drying is performed after the slurry is prepared. In a general method, drying is performed after the slurry is applied to form a coating film. Due to this difference, the film forming method also differs between the two.

  When the cathode catalyst layer is produced by depositing the binder particles on the substrate as in this embodiment, voids are formed between the deposited binder particles (hereinafter also referred to as voids between the binder particles). ). As a result, voids between the binder particles having a large diameter are distributed throughout the cathode catalyst layer. The gap between the binder particles is much larger than the gap formed when a slurry containing the conventional catalyst-carrying conductive particles and proton conductive resin is applied to produce the electrode catalyst layer. By having such a large gap, flooding can be prevented and a gas passage can be secured even in an environment where flooding in a medium to high current density region is likely to occur. Therefore, according to the cathode catalyst layer of the present embodiment, gas diffusion inhibition due to the generated water hardly occurs, and gas diffusibility can be improved. As a result, since diffusion polarization can be suppressed, good power generation characteristics can be obtained.

  On the other hand, when only such a large gap exists, there is a concern that a sufficient reaction area cannot be obtained and the characteristics of the fuel cell are deteriorated. However, since the binder particles are aggregates of catalyst-carrying conductive particles or aggregates thereof, voids are also present inside the binder particles (hereinafter also referred to as voids within the binder particles). Since the voids in the binder particles are smaller in diameter than the voids between the binder particles, a sufficient reaction area can be secured and good power generation characteristics can be obtained.

  The void diameter of the voids between the binder particles is preferably distributed in the range of more than 0.1 μm and not more than 10 μm, and the average void diameter is preferably 0.3 to 5 μm. The void diameter of the voids in the binder particles is preferably distributed in the range of 0.01 to 0.1 μm, and the average void diameter is preferably 0.01 to 0.05 μm.

  Here, the void diameter refers to the size of the space existing between and within the particles, and was measured by a mercury intrusion method. The mercury intrusion method is a method for increasing the pressure of mercury step by step and obtaining the distribution of voids by the degree of penetration of mercury at each pressure, and measuring the volume of voids that exist within a certain range of void diameters. is there. The average void diameter is calculated by adding the product of each void diameter and the void volume in the area of the void diameter based on the relationship between the void diameter and the void volume measured by the mercury intrusion method, and dividing by the total void volume. To calculate.

  As described in Patent Documents 1 and 2 described above as prior art documents, according to the method of changing the catalyst particle size in the thickness direction of the catalyst layer, flooding is eliminated in a layer having a large catalyst particle size. be able to. However, in a layer with small catalyst particles, flooding occurs and improvement in gas diffusivity cannot be expected. Further, by laminating a plurality of catalyst layers having different gap diameters, the contact resistance may be increased, leading to a decrease in power generation characteristics.

  The invention described in Patent Document 3 is an invention that focuses on the particles that make up the catalyst layer. However, there is a high possibility that carbon agglomeration occurs in the process of producing the catalyst layer, and the voids in the catalyst layer are managed. Difficult to do. Therefore, the effect of preventing flooding cannot be expected.

  According to the cathode catalyst layer of the fuel cell according to the embodiment, the problems in the prior art can be solved.

  The anode catalyst layer 5 may be formed by a general method, although the binder particles may be deposited on the base material by the same method as the method for preparing the cathode catalyst layer 7 described above. Similar to the cathode catalyst layer 7, the anode catalyst layer 5 contains a catalyst and a proton conductive electrolyte. As the anode catalyst, a supported catalyst in which metal particles are supported on a carbon support is used. The metal particles include platinum and a second metal other than platinum, and it is preferable to use ruthenium, nickel, or the like as the second metal. Use of platinum is preferable from the viewpoint of hydrogen oxidation reaction activity, heat resistance, and the like.

  As the proton conductive electrolyte contained in the anode catalyst layer 5, the same material as the proton conductive resin of the cathode catalyst layer 7 can be used. The anode catalyst layer 5 and the cathode catalyst layer 7 do not need to have a single-layer structure as shown in FIG. 1, and may have a multilayer structure having two or more layers.

  Next, components other than the catalyst layer will be described.

  The electrolyte membrane 4 is a proton conductive membrane disposed between the anode catalyst layer 5 and the cathode catalyst layer 7. The electrolyte membrane 4 has a function of selectively transmitting protons generated in the anode catalyst layer 5 to the cathode catalyst layer 7 along the film thickness direction. The electrolyte membrane 4 also has a function as a partition wall that prevents mixing of the fuel gas supplied to the anode side and the oxidant gas supplied to the cathode side. As the electrolyte contained in the electrolyte membrane 4, the same material as the proton conductive resin of the cathode catalyst layer 7 can be used.

  The anode gas diffusion layer 6 plays a role of uniformly supplying fuel to the anode catalyst layer 5 and also functions as a current collector for the anode catalyst layer. The cathode gas diffusion layer 8 functions to supply the oxidant uniformly to the cathode catalyst layer 7 and also functions as a current collector for the cathode catalyst layer.

  The anode gas diffusion layer 6 and the cathode gas diffusion layer 8 are generally made of a porous material, for example, a sheet-like material made of carbon paper, carbon cloth, nonwoven fabric, carbon fabric, paper-like paper body, felt or the like. Etc.

  The gas diffusion layer preferably exhibits functions such as electron conductivity and water repellency. When the gas diffusion layer has excellent electron conductivity, electrons generated by the power generation reaction are effectively transported, and the power generation performance of the fuel cell is improved. Further, if the gas diffusion layer has excellent water repellency, the generated water is efficiently discharged. In order to ensure high water repellency, the material constituting the gas diffusion layer can be subjected to water repellency treatment. As a method therefor, for example, a solution containing a fluorine-based resin such as polytetrafluoroethylene (PTFE) is applied to a material constituting a gas diffusion layer such as carbon paper, and dried in the air or an inert gas such as nitrogen. There is a technique to make it. At this time, carbon powder may be mixed in the solution in order to further improve the water repellency.

  The separator is a porous member made of carbon or metal as a constituent material, and is disposed outside the membrane electrode assembly including the anode 2, the cathode 3, and the electrolyte membrane 4. An anode separator 9 is disposed on the anode side, and a cathode separator 10 is disposed on the cathode side.

  A fuel cell is generally composed of a stack formed by stacking a plurality of fuel cells having a structure as shown in FIG. The separator has a function of flowing fluids such as a fuel gas, an oxidant gas and a refrigerant, and a function of maintaining the mechanical strength of the stack, in addition to the function of electrically connecting the single cells in series. Further, a fuel gas (or oxidant gas) that flows through the separator, and an oxidant gas (or fuel gas) that flows through the separator of another cell disposed adjacent to the separator through the separator, It also has a reactive gas blocking function to prevent mixing through the separator. Furthermore, the heat generated by the cell power generation can be removed by providing the separator with a coolant passage and flowing the coolant.

  The material of the anode separator 9 and the cathode separator 10 is not particularly limited as long as it has electrical conductivity. For example, a dense carbon graphite, a carbon material such as a carbon plate, and a metal material such as stainless steel can be used. More preferably, it is made of a porous material.

As the fuel of the fuel cell of the present embodiment, for example, H ₂ reformed from city gas, LPG or the like is used as the fuel gas. The fuel gas passes through the fuel gas flow path provided in the anode separator 9, diffuses in the anode gas diffusion layer 6, and reaches the anode catalyst layer 5. Hydrogen in the fuel gas generates protons and electrons by a hydrogen oxidation reaction on the metal particles of the anode catalyst layer 5. Protons reach the cathode catalyst layer 7 via the electrolyte membrane 4, and electrons flow to the external device as so-called electricity. Oxygen reduction on the catalytic metal particles of the cathode catalyst layer 7 with oxygen in the air, protons supplied from the anode catalyst layer 5 via the electrolyte membrane 4, and electrons reaching the cathode via the external device When the reaction occurs, water is generated.

<Example 1>
(Preparation of binder particles)
Platinum-supported carbon was added to water, followed by 2-propanol and a proton conductive resin (for example, Nafion manufactured by DuPont). Here, the solid content was 5 to 10%, and the proton exchange resin was added so as to be 25 to 35% with respect to the total solid content. Next, it stirred for 30 minutes with the stirrer (for example, homogenizer). At that time, the slurry was stirred while cooling in a container containing water so that the temperature of the slurry would not rise. The prepared slurry was put in a container, thinned and placed in a drying furnace. The drying temperature was 70 ° C., which is lower than the boiling point of ethanol contained in the proton exchange resin, and drying was performed for about 3 hours. Finally, the dried slurry was placed in a pulverizer with a rotating blade and pulverized for 3 minutes to obtain binder particles.

(Preparation of cathode catalyst layer)
A cathode catalyst layer was produced using the binder particles produced above. First, Toray carbon paper was placed on a table installed in the chamber. The center of the table was made of metal mesh to allow gas to pass through. A cathode catalyst layer was prepared by creating a flow of N ₂ gas in the chamber and depositing the binder particles on the carbon paper.

(Fabrication of fuel cell)
A fuel cell was produced using the cathode catalyst layer produced above.

  For the anode gas diffusion layer, a solution obtained by mixing carbon powder and polytetrafluoroethylene in a carbon paper so as to have a solid content weight ratio of 6: 4 is coated with a coating machine so that the thickness after drying becomes 20 μm. It was produced by.

  The anode catalyst layer is composed of a catalyst in which a platinum-ruthenium alloy, which is metal particles having a particle diameter of several nanometers, is supported on carbon, and a slurry composed of a proton exchange resin. It was prepared and applied on the anode gas diffusion layer.

  In the cathode gas diffusion layer, a slurry obtained by mixing carbon powder and polytetrafluoroethylene having an average particle size of 0.3 μm in a solid content weight ratio of 6: 4 in carbon paper is dried by a coater. It produced by apply | coating so that it might be set to 20 micrometers.

  As the electrolyte membrane, a perfluorocarbon sulfonic acid membrane (for example, Nafion manufactured by DuPont) was used. An anode catalyst layer and a cathode catalyst layer are arranged on both sides of the electrolyte membrane, an anode diffusion layer is arranged outside the anode catalyst layer, and a cathode catalyst layer is arranged outside the cathode catalyst layer, and these are laminated and thermocompression bonded. Integrated. The pressing temperature was set to 150 ° C. or higher, which is a temperature higher than the glass transition point of the electrolyte membrane.

  The membrane / electrode assembly produced as described above was sandwiched between separators and thermocompression bonded to obtain a fuel cell. The pressing temperature was 130 ° C. or higher, which is the melting point of the adhesive.

<Comparative Example 1>
For comparison with the cathode catalyst layer produced in Example 1, a catalyst layer was produced by a general method in which a solution in which materials were mixed was applied by a coating machine and the coating film was dried.

  Until the preparation of the solution, the same procedure as in Example 1 was performed. The prepared solution was applied in a film form on carbon paper using a bar coater, and then put in a drying furnace and dried as it was to prepare a cathode catalyst layer. The drying temperature was 70 ° below the boiling point of ethanol.

  A fuel cell was produced in the same manner as in Example 1 using the cathode catalyst layer produced as described above.

<Test Example 1: Particle size distribution of binder particles>
The particle size distribution of the binder particles produced in Example 1 was measured. The measurement was performed using a CCD camera capable of displaying a minimum of 0.5 μm.

  The result is shown in FIG. It can be seen that the particle size is widely distributed over 0.6 to 10 μm, and the average particle size is 3 μm. In the case of physically pulverizing the powder, it is generally known that the lower limit of the particle diameter is several μm.

<Test Example 2: Void distribution in cathode catalyst layer>
The void distribution of the cathode catalyst layer produced in Example 1 and Comparative Example 1 was measured. The measurement was performed by a mercury intrusion method.

  FIG. 6 is a diagram showing the void distribution in the cathode catalyst layer of Example 1. FIG. In FIG. 6, the peak observed in the vicinity of 0.01 to 0.1 μm is considered to be derived from voids in the binder particles. It is considered that the peak observed in the vicinity of greater than 0.1 and not more than 10 μm is derived from voids between the binder particles. Since the cathode catalyst layer of Example 1 is formed by depositing binder particles having an average particle diameter of 3 μm on the substrate, a large void of 0.1 to 10 μm is formed between the binder particles. It is formed. Therefore, it is possible to obtain a cathode catalyst layer having a larger gap than before.

  The reason why the peak in the vicinity of 0.1 to 10 μm is considered to be derived from the voids between the binder particles will be described with reference to FIG. FIG. 7 is a conceptual diagram showing the interparticle distance when the binding particles are closely arranged.

  Assuming that the binding particles are arranged in a fine structure of a face-centered cubic lattice type, the gap between the particles is about 0.4 R on the densest surface. Here, R means the diameter of the particle. Therefore, when the binder particles having an average particle diameter of 3 μm prepared in Example 1 are arranged, the gap diameter of the gap between the binder particles is about 1.2 μm. This is a value when a gap having a size close to the lower limit value in the case of a fine structure is assumed. Considering that there is a distribution in the actual void diameter, it is considered that the peak in the vicinity of 0.1 to 10 μm in FIG. 6 is derived from the voids between the binder particles.

  Further, the total volume of all the voids existing in the binding particle portion of the cathode catalyst layer produced in Example 1 is 0.36 ml / g, and the total volume of all the voids between the binding particles is 0.26 ml / g. Met. Therefore, it was found that 50% or more of the total volume of all the voids existing in the binder particle portion of the cathode catalyst layer originates from the voids between the binder particles.

  FIG. 8 is a diagram showing the void distribution in the cathode catalyst layer of Comparative Example 1. It was found that most of the peaks were observed around 0.01 to 0.1 μm, and there were almost no large voids. The peak observed in the vicinity of 0.01 to 0.1 μm is considered to originate from voids corresponding to voids in the binder particles in the cathode catalyst layer of Example 1. Therefore, it can be said that the cathode catalyst layer of Comparative Example 1 does not have voids corresponding to the voids between the binder particles of the cathode catalyst layer of Example 1.

<Test Example 4: IV characteristics of fuel cell>
For the fuel cells fabricated in Example 1 and Comparative Example 1, the relationship between current density and cell voltage was measured. The reformed simulation gas was supplied to the anode and air was supplied to the cathode, and the measurement was performed from the low current density side to the high current density side. The measurement was performed using an electronic load device and taking out the current from the battery.

  FIG. 9 is a diagram showing the relationship between current density and cell voltage. Compared with the fuel cell of Comparative Example 1, the fuel cell of Example 1 was confirmed to have a smaller decrease in cell voltage in the medium to high current density region. This is an effect of improving the gas diffusibility of the cathode catalyst layer in the fuel cell of Example 1.

  According to the embodiment or the example, the gas diffusibility of the cathode catalyst layer can be improved.

  Although several embodiments of the present invention have been described, these embodiments are presented by way of example and are not intended to limit the scope of the invention. These embodiments can be implemented in various other forms, and various omissions, replacements, and changes can be made without departing from the spirit of the invention. These embodiments and their modifications are included in the scope and gist of the invention, and are also included in the invention described in the claims and the equivalents thereof.

  DESCRIPTION OF SYMBOLS 1 ... Fuel cell, 2 ... Anode, 3 ... Cathode, 4 ... Electrolyte membrane, 5 ... Anode catalyst layer, 6 ... Anode gas diffusion layer, 7 ... Cathode catalyst layer, 8 ... Cathode gas diffusion layer, 9 ... Anode separator, DESCRIPTION OF SYMBOLS 10 ... Cathode separator, 11 ... Catalyst carrying conductive particle, 12 ... Conductive particle, 13 ... Catalyst, 14 ... Proton conductive resin, 15 ... Binder particle, 16 ... Base material, 21 ... Chamber, 22 ... Upstream base material Side space, 23 ... base material downstream side space, 24 ... table, 25 ... seal.

Claims (4)

An electrolyte membrane;
An anode catalyst layer and an anode gas diffusion layer disposed on one surface of the electrolyte membrane;
A fuel cell comprising a cathode catalyst layer and a cathode gas diffusion layer disposed on the other surface of the electrolyte membrane,
The cathode catalyst layer includes binder particles obtained by binding catalyst-carrying conductive particles or aggregates thereof with a proton conductive resin , and the cathode catalyst layer is formed on a surface of a base material that supports the cathode catalyst layer. Produced by making a gas flow in a direction perpendicular to the gas, and depositing the binding particles on the substrate according to the gas flow;
The fuel cell, wherein an average diameter of voids between the binding particles is larger than an average diameter of voids in the binding particles.   The particle diameter of the binder particles is 0.6 to 10 μm, the void diameter of the voids in the binder particles is 0.01 to 0.1 μm, and the void diameter of the voids between the binder particles is 0.00. The fuel cell according to claim 1, wherein the fuel cell is greater than 1 μm and 10 μm or less.   2. The fuel cell according to claim 1, wherein 50% or more of the total volume of all the voids existing in the binder particle portion of the cathode catalyst layer is derived from the voids between the binder particles. Forming a slurry containing catalyst-carrying conductive particles and proton conductive resin, drying the slurry, and then pulverizing to form binder particles;
Forming a gas flow in a direction perpendicular to the surface of the base material of the cathode catalyst layer, and depositing the binding particles on the base material according to the gas flow. 2. A method for producing a cathode catalyst layer in a fuel cell according to 1.

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