JP5607024B2 - プロピレンの製造方法 - Google Patents

プロピレンの製造方法 Download PDF

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Publication number
JP5607024B2
JP5607024B2 JP2011502746A JP2011502746A JP5607024B2 JP 5607024 B2 JP5607024 B2 JP 5607024B2 JP 2011502746 A JP2011502746 A JP 2011502746A JP 2011502746 A JP2011502746 A JP 2011502746A JP 5607024 B2 JP5607024 B2 JP 5607024B2
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zeolite
catalyst
reaction
temperature
propylene
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JPWO2010101121A1 (ja
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義和 高松
隆介 宮崎
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Asahi Kasei Chemicals Corp
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Asahi Kasei Chemicals Corp
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/90Regeneration or reactivation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44Noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027Powdering
    • B01J37/0045Drying a slurry, e.g. spray drying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/04Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12Treating with free oxygen-containing gas
    • B01J38/14Treating with free oxygen-containing gas with control of oxygen content in oxidation gas
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/42Addition of matrix or binder particles
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2011502746A 2009-03-02 2010-03-01 プロピレンの製造方法 Active JP5607024B2 (ja)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2011502746A JP5607024B2 (ja) 2009-03-02 2010-03-01 プロピレンの製造方法

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2009048369 2009-03-02
JP2009048369 2009-03-02
PCT/JP2010/053265 WO2010101121A1 (ja) 2009-03-02 2010-03-01 プロピレンの製造方法
JP2011502746A JP5607024B2 (ja) 2009-03-02 2010-03-01 プロピレンの製造方法

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JPWO2010101121A1 JPWO2010101121A1 (ja) 2012-09-10
JP5607024B2 true JP5607024B2 (ja) 2014-10-15

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US (1) US8450551B2 (cg-RX-API-DMAC7.html)
JP (1) JP5607024B2 (cg-RX-API-DMAC7.html)
BR (1) BRPI1009564B1 (cg-RX-API-DMAC7.html)
TW (1) TWI399358B (cg-RX-API-DMAC7.html)
WO (1) WO2010101121A1 (cg-RX-API-DMAC7.html)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011135785A1 (en) * 2010-04-30 2011-11-03 Toyota Jidosha Kabushiki Kaisha Propylene production method
JP2013138974A (ja) * 2011-12-28 2013-07-18 Tokyo Institute Of Technology 不飽和炭化水素製造用触媒の製造方法および不飽和炭化水素の製造方法
JP5928256B2 (ja) * 2012-08-31 2016-06-01 三菱化学株式会社 プロピレンの製造方法
JP6404352B2 (ja) * 2014-08-01 2018-10-10 千代田化工建設株式会社 複合体触媒、複合体触媒の製造方法、低級オレフィンの製造方法および複合体触媒の再生方法
US11492264B2 (en) * 2018-03-23 2022-11-08 Ngk Insulators, Ltd. Seed crystals, method of producing seed crystals, method of producing seed crystals attachment support, and method of producing zeolite membrane complex

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4849194A (en) * 1987-05-26 1989-07-18 Mobil Oil Corporation Measurement and control of zeolite synthesis
JPH03293031A (ja) * 1990-04-10 1991-12-24 Tosoh Corp 高耐熱水性ゼオライト及びその製造方法
JPH1052646A (ja) * 1996-04-18 1998-02-24 Sanyo Sekiyu Kagaku Kk 高シリカゼオライト系触媒
JP2005232122A (ja) * 2004-02-23 2005-09-02 Mitsubishi Chemicals Corp プロピレンの製造方法
JP2005281254A (ja) * 2004-03-30 2005-10-13 Mitsubishi Chemicals Corp プロピレンの製造方法
JP2007191444A (ja) * 2006-01-20 2007-08-02 Tokyo Institute Of Technology プロピレンの製造方法、触媒の再生方法、固体酸触媒
JP2009518162A (ja) * 2005-12-01 2009-05-07 ビーエーエスエフ、カタリスツ、エルエルシー オレフィン炭化水素小分子用の熱水的に安定したAg−ゼオライト炭化水素トラップ

Family Cites Families (14)

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Publication number Priority date Publication date Assignee Title
US4150062A (en) * 1976-12-20 1979-04-17 Mobil Oil Corporation Light olefin processing
JPS58145616A (ja) * 1982-02-22 1983-08-30 Teijin Yuka Kk 新規結晶性アルミノシリケ−トゼオライト及びその製造法
US4845063A (en) * 1982-10-15 1989-07-04 Mobil Oil Corporation Zeolite catalyst of improved hydrothermal stability
US4527001A (en) * 1983-11-15 1985-07-02 Union Carbide Corporation Small olefin interconversions
US4605807A (en) * 1984-04-27 1986-08-12 Atlantic Richfield Company Process for catalytic conversion of ethylene to higher hydrocarbons
JPS6168319A (ja) * 1984-09-10 1986-04-08 Asahi Chem Ind Co Ltd 結晶性アルミノシリケ−トの合成法
JPH05147925A (ja) * 1991-11-27 1993-06-15 Tosoh Corp ゼオライト及びその製造方法
JP3547791B2 (ja) * 1994-04-22 2004-07-28 水澤化学工業株式会社 高耐熱水性高シリカゼオライト及びその製造方法
EP1061116A1 (en) 1999-06-16 2000-12-20 Fina Research S.A. Production of olefins
RU2240312C1 (ru) 2001-02-14 2004-11-20 Асахи Касеи Кабусики Кайся Способ получения эпсилон-капролактама
WO2005056504A1 (ja) * 2003-12-12 2005-06-23 Mitsubishi Chemical Corporation プロピレンの製造方法
JP4774813B2 (ja) 2005-06-03 2011-09-14 三菱化学株式会社 プロピレンの製造方法
WO2007114195A1 (ja) * 2006-03-30 2007-10-11 Mitsubishi Chemical Corporation プロピレンの製造方法
TW200918487A (en) 2007-09-06 2009-05-01 Asahi Kasei Chemicals Corp Process for production of propylene

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4849194A (en) * 1987-05-26 1989-07-18 Mobil Oil Corporation Measurement and control of zeolite synthesis
JPH03293031A (ja) * 1990-04-10 1991-12-24 Tosoh Corp 高耐熱水性ゼオライト及びその製造方法
JPH1052646A (ja) * 1996-04-18 1998-02-24 Sanyo Sekiyu Kagaku Kk 高シリカゼオライト系触媒
JP2005232122A (ja) * 2004-02-23 2005-09-02 Mitsubishi Chemicals Corp プロピレンの製造方法
JP2005281254A (ja) * 2004-03-30 2005-10-13 Mitsubishi Chemicals Corp プロピレンの製造方法
JP2009518162A (ja) * 2005-12-01 2009-05-07 ビーエーエスエフ、カタリスツ、エルエルシー オレフィン炭化水素小分子用の熱水的に安定したAg−ゼオライト炭化水素トラップ
JP2007191444A (ja) * 2006-01-20 2007-08-02 Tokyo Institute Of Technology プロピレンの製造方法、触媒の再生方法、固体酸触媒

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
JPN6014021372; Na Young Kang, et al.: 'The effect of Na2SO4 salt on the synthesis of ZSM-5 by template free crystallization method' Microporous and Mesoporous Materials vol.118 no.1-3, 20090201, p.361-372 *

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BRPI1009564A2 (cg-RX-API-DMAC7.html) 2016-03-22
US20120004490A1 (en) 2012-01-05
BRPI1009564B1 (pt) 2017-12-26
WO2010101121A1 (ja) 2010-09-10
US8450551B2 (en) 2013-05-28
TWI399358B (zh) 2013-06-21
JPWO2010101121A1 (ja) 2012-09-10
TW201036939A (en) 2010-10-16

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