JP5548691B2 - レシチン及び可塑剤の組成物及び方法 - Google Patents
レシチン及び可塑剤の組成物及び方法 Download PDFInfo
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- JP5548691B2 JP5548691B2 JP2011535798A JP2011535798A JP5548691B2 JP 5548691 B2 JP5548691 B2 JP 5548691B2 JP 2011535798 A JP2011535798 A JP 2011535798A JP 2011535798 A JP2011535798 A JP 2011535798A JP 5548691 B2 JP5548691 B2 JP 5548691B2
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- JP
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- Prior art keywords
- lecithin
- formulation
- composition
- pigment
- polyoxyethylene
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims description 443
- 239000000787 lecithin Substances 0.000 title claims description 177
- 235000010445 lecithin Nutrition 0.000 title claims description 177
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 title claims description 176
- 229940067606 lecithin Drugs 0.000 title claims description 173
- 239000004014 plasticizer Substances 0.000 title claims description 42
- 238000000034 method Methods 0.000 title claims description 32
- 239000006185 dispersion Substances 0.000 claims description 161
- 239000003973 paint Substances 0.000 claims description 142
- 239000000049 pigment Substances 0.000 claims description 114
- SAOKZLXYCUGLFA-UHFFFAOYSA-N bis(2-ethylhexyl) adipate Chemical compound CCCCC(CC)COC(=O)CCCCC(=O)OCC(CC)CCCC SAOKZLXYCUGLFA-UHFFFAOYSA-N 0.000 claims description 104
- 239000002270 dispersing agent Substances 0.000 claims description 83
- -1 polyoxyethylene Polymers 0.000 claims description 61
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- 229920000223 polyglycerol Polymers 0.000 claims description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
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- 239000003093 cationic surfactant Substances 0.000 claims description 6
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- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
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- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 2
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- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 2
- 102000004190 Enzymes Human genes 0.000 claims description 2
- 108090000790 Enzymes Proteins 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 239000005642 Oleic acid Substances 0.000 claims description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 229920001213 Polysorbate 20 Polymers 0.000 claims description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 2
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical group CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 claims description 2
- 239000004147 Sorbitan trioleate Substances 0.000 claims description 2
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 claims description 2
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 2
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- 150000007942 carboxylates Chemical class 0.000 claims description 2
- 239000004359 castor oil Substances 0.000 claims description 2
- 235000019438 castor oil Nutrition 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical class OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 238000005553 drilling Methods 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 238000011049 filling Methods 0.000 claims description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 2
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 claims description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 2
- 239000010985 leather Substances 0.000 claims description 2
- 150000004702 methyl esters Chemical class 0.000 claims description 2
- 239000006082 mold release agent Substances 0.000 claims description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 claims description 2
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 claims description 2
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 claims description 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 2
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 claims description 2
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 claims description 2
- 239000001816 polyoxyethylene sorbitan tristearate Substances 0.000 claims description 2
- 235000010988 polyoxyethylene sorbitan tristearate Nutrition 0.000 claims description 2
- 229920000053 polysorbate 80 Polymers 0.000 claims description 2
- 238000012545 processing Methods 0.000 claims description 2
- 150000003335 secondary amines Chemical class 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
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- 150000003445 sucroses Chemical class 0.000 claims description 2
- 150000003512 tertiary amines Chemical class 0.000 claims description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 2
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 claims description 2
- 239000004711 α-olefin Substances 0.000 claims description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims 1
- 239000013543 active substance Substances 0.000 claims 1
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 claims 1
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- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 19
- 239000001034 iron oxide pigment Substances 0.000 description 19
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 18
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- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 18
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- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 13
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- PZTAGFCBNDBBFZ-UHFFFAOYSA-N tert-butyl 2-(hydroxymethyl)piperidine-1-carboxylate Chemical compound CC(C)(C)OC(=O)N1CCCCC1CO PZTAGFCBNDBBFZ-UHFFFAOYSA-N 0.000 description 1
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- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 1
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Description
本明細書中に記載の様々な実施形態において、双方の部分が、単独で、同時に、又は他の可塑剤と組み合わせて、可塑剤として用いることができることに留意することは、更に重要である。
以下の例示的で限定されない実施例は、本明細書中に提供される実施形態について更に説明するために提供される。当該技術分野の当業者は、これらの実施例の変形が本発明の範囲内で可能であることが分かるであろう。
Claims (27)
- レシチンと可塑剤とを含むことを特徴とする組成物であって、当該可塑剤がジ(2−エチルヘキシル)アジパート(DEHA)を含み、レシチンと当該可塑剤との重量比が95:5−60:40である、組成物。
- 請求項1に記載の組成物において、前記レシチンが粗濾過されたレシチン、脱油レシチン、化学修飾したレシチン、酵素修飾したレシチン、標準化したレシチン、及びその任意の組合せからなる群から選択されることを特徴とする組成物。
- 請求項1又は2に記載の組成物において、当該組成物が1g/L未満の揮発性有機化合物を含むことを特徴とする組成物。
- 請求項1ないし3のいずれか1項に記載の組成物が、アニオン性界面活性剤、非イオン性界面活性剤、カチオン性界面活性剤、及びその任意の組合せからなる群から選択される共界面活性剤を更に含むことを特徴とする組成物。
- 請求項4に記載の組成物において、前記共界面活性剤の親水親油バランスが10.0ないし24.0であることを特徴とする組成物。
- 請求項4又は請求項5に記載の組成物において、前記非イオン性界面活性剤がソルビタンモノステアラート、ロジンのポリオキシエチレンエステル、ポリオキシエチレンドデシルモノエーテル、ポリオキシエチレンとポリオキシプロピレンとのブロック共重合体、ポリオキシエチレンモノラウラート、ポリオキシエチレンモノヘキサデシルエーテル、ポリオキシエチレンモノオレアート、ポリオキシエチレンモノ(シス−9−オクタデセニル)エーテル、ポリオキシエチレンモノステアラート、ポリオキシエチレンモノオクタデシルエーテル、ポリオキシエチレンジオレアート、ポリオキシエチレンジステアラート、ポリオキシエチレンソルビタンモノラウラート、ポリオキシエチレンソルビタンモノオレアート、ポリオキシエチレンソルビタンモノパルミタート、ポリオキシエチレンソルビタンモノステアラート、ポリオキシエチレンソルビタントリオレアート、ポリオキシエチレンソルビタントリステアラート、オレイン酸のポリグリセロールエステル、ポリオキシエチレンソルビタンヘキサステアラート、ポリオキシエチレンモノテトラデシルエーテル、ポリオキシエチレンソルビタンヘキサオレアート、脂肪酸、トール油、ソルビトールのヘキサエステル、エトキシ化ヒマシ油、エトキシ化ダイズ油、エトキシ化ポリオキシエチレンソルビトールテトラオレアート、グリセロールとポリエチレングリコールとを混合したエステル、アルコール、ポリグリセロールエステル、モノグリセリド、スクロースエステル、その任意の誘導体、及びその任意の組合せからなる群から選択されることを特徴とする組成物。
- 請求項4ないし6のいずれか1項に記載の組成物において、前記アニオン性界面活性剤が直鎖脂肪酸のナトリウム及びカリウム塩、ポリオキシエチレン化された脂肪アルコールのカルボキシラート、直鎖アルキルベンゼンのスルホナート、αオレフィンのスルホナート、スルホン化脂肪酸のメチルエステル、アリールアルカンスルホナート、スルホスクシナートエステル、アルキルフェニルエーテル(ジ)スルホナート、アルキルナフタレンスルホナート、イセチオナート、アルキルエーテルスルファート、硫酸化油、脂肪酸モノエタノールアミドのスルファート、ポリオキシエチレン脂肪酸モノエタノールアミドのスルファート、脂肪族ホスファートエステル、ノニルフェノールホスファートエステル、フッ化アニオン、及びその任意の組合せからなる群から選択されることを特徴とする組成物。
- 請求項4ないし7のいずれか1項に記載の組成物において、前記カチオン性界面活性剤が:脂肪族アミン塩;第一級、第二級、及び第三級アミンを含む脂肪族アルキルの第四級アミン;エステルアミン及び対応するエトキシ化エステルアミン;ならびにその任意の組合せ;からなる群から選択されることを特徴とする組成物。
- 請求項4ないし8のいずれか1項に記載の組成物において、前記レシチンが前記組成物の5ないし95重量パーセントを構成し、前記可塑剤が前記組成物の1ないし20重量パーセントを構成し、界面活性剤が前記組成物の5ないし20重量パーセントを構成することを特徴とする組成物。
- 請求項1ないし9のいずれか1項に記載の組成物において、当該組成物の粘度が2,000センチポイズ以下であることを特徴とする組成物。
- 請求項4ないし10のいずれか1項に記載の組成物において、前記非イオン性界面活性剤及び前記イオン性界面活性剤の比率が1:9ないし9:1であることを特徴とする組成物。
- 請求項1ないし11のいずれか1項に記載の組成物が顔料を更に含むことを特徴とする組成物。
- 請求項12に記載の組成物において、前記顔料が有機顔料、無機顔料、カーボンブラック顔料、及びその任意の組合せからなる群から選択されることを特徴とする組成物。
- 請求項1ないし13のいずれか1項に記載の組成物が樹脂を更に具えることを特徴とする組成物。
- 請求項1ないし14のいずれか1項に記載の組成物を含む生成物。
- 請求項1ないし15のいずれか1項に記載の組成物の分散助剤、研磨助剤、粘度降下剤、又はその任意の組合せとしての使用。
- 請求項15に記載の生成物において、当該生成物の用途が塗料、インク、コーティング、磁性流体、コンクリート、セラミック、繊維用助剤、皮革の最終加工における助剤、プラスチック配合剤、潤滑剤、油田掘削用の添加剤、離型剤、及び化粧品からなる群から選択されることを特徴とする生成物。
- 可塑剤とレシチンとを混合し、ひいては分散剤を生成するステップを具えることを特徴とする方法であって、当該可塑剤がジ(2−エチルヘキシル)アジパート(DEHA)を含み、レシチンと当該可塑剤との重量比が95:5−60:40である、方法。
- 請求項18に記載の方法が、前記分散剤と顔料とを、当該顔料が分散するように混合するステップを更に具えることを特徴とする方法。
- 請求項18又は請求項19に記載の方法が、前記レシチンを加熱するステップを更に具えることを特徴とする方法。
- 請求項18ないし20のいずれか1項に記載の方法が、前記分散剤、前記顔料、又はその組合せと樹脂とを混合するステップを更に具えることを特徴とする方法。
- 請求項18ないし21のいずれか1項に記載の方法が、前記分散剤、前記顔料、又はその組合せと、インク基剤又は塗料基剤と混合するステップを更に具えることを特徴とする方法。
- 請求項18ないし22のいずれか1項に記載の方法において、前記レシチンと前記可塑剤とを混合するステップが、前記レシチンとトリグリセリドとを混合するステップと比較して、前記レシチンの粘度を低減させることを特徴とする方法。
- 請求項23に記載の方法において、前記レシチンの粘度の低減によって、顔料に対する前記分散剤の充填容量が、従来の分散剤と比較して高くできることを特徴とする方法。
- 請求項18ないし24のいずれか1項に記載の方法が、共界面活性剤を前記レシチン、前記可塑剤、又はその組合せに添加するステップを更に具えることを特徴とする方法。
- 請求項18ないし25のいずれか1項に記載の方法によって生成される生成物。
- 請求項26に記載の生成物を表面に塗布するステップを具えることを特徴とする方法。
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