JP5494967B2 - Battery with temperature sensor - Google Patents

Description

  The present invention relates to a battery with a temperature sensor capable of measuring its own temperature for ensuring safety and the like.

  Batteries such as battery packs and lithium ion secondary batteries need to be measured and controlled to control the state of charge and ensure safety against temperature rise. For this reason, what attached the temperature sensor to the secondary battery or the battery pack conventionally is known.

For example, Patent Document 1 proposes a battery pack in which a temperature sensor in which a small thin plate thermistor element is covered with an insulating film is adhered to the surface of a secondary battery.
Patent Document 2 proposes a battery and a battery pack in which a thermistor is disposed as a heat-sensitive protective element on the electrode lead portion of the battery.
Further, Patent Document 3 proposes an electronic device in which a temperature sensor for detecting the temperature of a battery case into which a battery is inserted is pressed and positioned by a predetermined temperature detection portion of the battery case.

JP-A-8-128901 JP 2003-45492 A JP 2004-349119 A

The following problems remain in the conventional technology.
That is, in the techniques described in Patent Documents 1 to 3, the temperature sensor is disposed in close contact with the side surface of a battery such as a battery pack or a secondary battery. In this case, the temperature of the side surface of the battery is partially measured. The entire battery cannot be measured. In addition, the temperature sensor is locally fixed to the side surface of the battery, and the intimate contact area is small and the local heat capacity due to the volume of the temperature sensor makes it difficult to measure the temperature accurately and the response is low. was there. In addition, the temperature sensor alone is likely to fluctuate rapidly due to outside air, etc., and the temperature sensor is fixed to the side, so the overall shape of the battery is uneven, making installation and storage difficult, and securing the installation location difficult There is also the inconvenience of becoming.

  The present invention has been made in view of the above-mentioned problems, and provides a battery with a temperature sensor that can accurately measure the temperature of the entire battery, has excellent responsiveness, suppresses unevenness of the outer shape as much as possible, and is easy to install and store. The purpose is to do.

The present invention employs the following configuration in order to solve the above problems. That is, the battery with a temperature sensor of the present invention includes a battery body and a heat sensitive portion that is provided so as to cover the outer periphery of the battery body and extends in the circumferential direction of the outer periphery and changes its electrical resistance in accordance with the temperature. And a film-like temperature sensor.
This battery with a temperature sensor includes a film-like temperature sensor that is provided so as to cover the outer periphery of the battery body and has a heat-sensitive portion that extends in the circumferential direction of the outer periphery and changes its electrical resistance in accordance with the temperature. Therefore, the temperature can be measured over a wide range of the outer periphery of the battery body, and the temperature of the entire battery can be measured more accurately than in the conventional case where the temperature sensor is closely fixed locally. Further, the temperature of the film-like temperature sensor fluctuates in a place where the outside air wind is received, but the influence is reduced because the average temperature is measured on the wide outer peripheral surface of the covered battery body. Furthermore, since the outer periphery of the battery body is covered with a flexible and thin film-like temperature sensor, the outer shape is less likely to be uneven and the heat capacity is small. For this reason, the responsiveness of temperature measurement is high, and it is easy to secure a place for installation and storage.
In the present invention, not only a secondary battery such as a lithium ion secondary battery, a nickel hydride battery, a nickel cadmium battery, or a lithium polymer secondary battery, but also a battery pack in which one or more secondary batteries are housed in a container. Is also included as a battery body.

Moreover, the battery with a temperature sensor of the present invention is characterized in that the heat sensitive part extends over the entire circumference of the battery body.
That is, in this battery with a temperature sensor, since the heat sensitive portion extends over the entire circumference of the battery body, it is possible to measure the average temperature over the entire circumference of the battery body, and to obtain the average of the battery body with higher accuracy. The temperature can be measured.

In the battery with a temperature sensor of the present invention, the film-like temperature sensor includes an insulating film, a thin-film heat-sensitive portion formed on the insulating film and extending in a circumferential direction of the outer periphery, and the heat-sensitive part. And a pair of lead wires connected to the section.
That is, in this battery with a temperature sensor, the film-like temperature sensor has the thin film-like heat-sensitive portion formed on the insulating film and extending in the circumferential direction of the outer periphery. The film-like temperature sensor can be adhered easily and in a high contact state, and temperature measurement with high accuracy and high response becomes possible.

Furthermore, in the battery with a temperature sensor of the present invention, the heat sensitive part is formed on the insulating film and the pair of pattern electrodes to which the pair of lead wires are connected, the insulating film and the pair of pattern electrodes. And a thin film thermistor portion patterned thereon.
That is, in this battery with a temperature sensor, the heat sensitive part includes a thin film thermistor part patterned on an insulating film. Accurate and highly responsive temperature measurement is possible.

Moreover, the battery with a temperature sensor of the present invention is characterized in that the heat sensitive part is a platinum resistance thermometer formed by patterning a platinum film on the insulating film.
That is, in this battery with a temperature sensor, the heat sensitive part is a platinum resistance thermometer that is patterned with a platinum film on an insulating film. Therefore, temperature measurement with higher accuracy and higher response becomes possible.

The present invention has the following effects.
That is, according to the battery with a temperature sensor according to the present invention, the battery has a heat-sensitive portion that is provided so as to cover the outer periphery of the battery body and extends in the circumferential direction of the outer periphery to change the electric resistance according to the temperature. Since the film-like temperature sensor is provided, the temperature of the entire battery can be accurately measured and the response is excellent, and the outer shape unevenness is suppressed as much as possible, and installation and storage are facilitated. Therefore, the temperature of the battery body can be measured with high accuracy and high responsiveness, and the charged state can be controlled with high accuracy, and excessive heat generation can be prevented to ensure high safety.

It is a perspective view which shows 1st Embodiment of the battery with a temperature sensor which concerns on this invention. In 1st Embodiment, it is a perspective view which shows a film-like temperature sensor. In 1st Embodiment, it is a perspective view which shows the manufacturing method of a film-form temperature sensor in order of a process. In 1st Embodiment, it is a perspective view which shows the fixing method of the film-shaped temperature sensor to a battery main body in order of a process. In 2nd Embodiment of the battery with a temperature sensor which concerns on this invention, it is a perspective view which shows a film-form temperature sensor. In 2nd Embodiment, it is a perspective view which shows the manufacturing method of a film-form temperature sensor in order of a process. In 3rd Embodiment of the battery with a temperature sensor which concerns on this invention, it is a perspective view which shows the fixing method of the film-shaped temperature sensor to a battery main body in order of a process.

  Hereinafter, a first embodiment of a battery with a temperature sensor according to the present invention will be described with reference to FIGS. 1 to 4. In each drawing used for the following description, the scale is appropriately changed in order to make each member recognizable or easily recognizable.

As shown in FIGS. 1 and 2, the battery 1 with a temperature sensor of the present embodiment is provided so as to cover a cylindrical battery body 2 and the outer periphery of the battery body 2 and extend in the circumferential direction of the outer periphery. And a film-like temperature sensor 4 having a heat-sensitive part 3 whose electric resistance changes depending on the temperature.
The film-like temperature sensor 4 includes an insulating film 5, a thin-film heat-sensitive part 3 formed on the insulating film 5 and extending in the circumferential direction of the outer periphery, and a pair connected to the heat-sensitive part 3. Lead wire 6.

The heat sensitive part 3 extends over the entire circumference of the battery body 2.
As shown in FIG. 2, the heat sensitive part 3 is formed on a pair of pattern electrodes 7 formed on an insulating film 5 and connected to a pair of lead wires 6, and on the insulating film 5 and the pair of pattern electrodes 7. And a patterned thin film thermistor section 8.

The battery body 2 is, for example, a lithium ion secondary battery. The battery body 2 is provided with a pair of lead terminals 9 that are lead wires protruding downward in the axial direction.
The insulating film 5 is, for example, a polyimide resin sheet and is formed in a strip shape with a length equal to or longer than the entire circumference of the battery body 2.
The pair of pattern electrodes 7 is formed by patterning a laminated metal film of, for example, a NiCr film and a Pt film, and has comb-shaped electrode portions having a comb-shaped pattern arranged in an opposed state. The comb-shaped electrode portions of these pattern electrodes 7 are arranged so as to extend along the extending direction of the strip-shaped insulating film 5 (winding direction around the battery body 2). Further, a plating part 10 is formed on the base end part of the pair of pattern electrodes 7 as a lead part of the lead wire 6. Furthermore, one end of the lead wire 6 is joined to the plated portion 10 with a solder material 11.

  The thin film thermistor portion 8 is made of a thin film thermistor material made of nitride such as TiAlN, TiN, NbAlN, NbN, etc., and is patterned on the insulating film 5 in a rectangular strip shape so as to cover the comb electrode portions of the pattern electrodes 7 facing each other. Has been.

Next, the manufacturing method of the battery 1 with a temperature sensor of this embodiment is demonstrated with reference to FIGS.
First, for example, a NiCr film (Ni: Cr = 80 mol%: 20 mol%) is formed to a thickness of 10 nm on the insulating film 5 of a polyimide resin sheet having a thickness of 50 μm shown in FIG. Further, a Pt film having a thickness of 200 nm is formed thereon.

  Next, as shown in FIG. 3B, a resist solution is applied onto the stacked NiCr film and Pt film with a bar coater, pre-baked at 80 ° C. for 10 minutes, and then a predetermined comb electrode is formed with an exposure apparatus. It is exposed to the pattern shape of the structure, and unnecessary portions are removed. Further, the pair of pattern electrodes 7 is patterned in a predetermined pattern by dry etching with Ar.

On the insulating film 5 on which the pattern electrode 7 is formed, as shown in FIG. 3C, a TiAlN thin film thermistor portion 8 having a predetermined shape and a thickness of 500 nm is formed by reactive sputtering through a metal mask. Film.
Thereafter, as shown in FIG. 3 (d), a polyimide coverlay film 12 with an adhesive is placed on the insulating film 5 so as to cover the thin film thermistor portion 8, and 2N / cm at 150 ° C. by a press machine. Pressurize with pressure for 30 min to adhere. At this time, the polyimide cover lay film 12 is bonded except for the base end portions of the pair of pattern electrodes 7 forming the plating portion 10.

Next, as shown in FIG. 3E, a Ni plating layer having a thickness of 3 μm and a Sn plating layer having a thickness of 10 μm are formed on the base end portions of the pair of pattern electrodes 7 by a plating solution. The plating part 10 is used.
Furthermore, the film-like temperature sensor 4 shown in FIG. 2 is produced by joining one end of each lead wire 6 to the plated portion 10 with the solder material 11.

Next, a film with a double-sided adhesive (not shown) is wound around the outer periphery of the battery main body 2 shown in FIG. 4A, and the film-like temperature sensor 4 is placed on the film with the double-sided adhesive, as shown in FIG. As shown in FIG. 2, the battery body 2 is wrapped and adhered so as to cover the outer periphery of the battery body 2. At this time, the film-like temperature sensor 4 is bonded so that the heat-sensitive part 3 makes one round of the outer peripheral surface of the battery body 2.
Further, as shown in FIG. 4C, the outer periphery of the battery body 2 is wrapped so that the insulating film 5 of the film-like temperature sensor 4 is covered with the insulating tape 13, whereby the temperature sensor of this embodiment is attached. Battery 1 is produced.

As described above, in the battery 1 with the temperature sensor of the present embodiment, the thermosensitive part 3 that is provided so as to cover the outer periphery of the battery body 2 and extends in the circumferential direction of the outer periphery to change the electric resistance according to the temperature. Since the film-like temperature sensor 4 is provided, the temperature of the battery body 2 can be measured over a wide area on the outer periphery of the battery body 2, and the temperature of the battery body 2 as a whole can be measured as compared to a conventional local temperature sensor closely adhered and fixed. Can be measured accurately.
In particular, by extending the thermosensitive part 3 over the entire circumference of the battery body 2, the average temperature in the entire circumference of the battery body 2 can be measured, and the average temperature of the battery body can be measured with higher accuracy. it can.

  Further, the temperature of the film-like temperature sensor 4 fluctuates in a place where the outside air is received, but the influence is reduced because the average temperature on the wide outer peripheral surface of the covered battery body 2 is measured. Furthermore, since the outer periphery of the battery body 2 is covered with the flexible and thin film-like temperature sensor 4, the outer shape is unlikely to have irregularities and has a small heat capacity. For this reason, the responsiveness of temperature measurement is high, and it is easy to secure a place for installation and storage.

  Moreover, since the film-shaped temperature sensor 4 has the thin film-shaped heat sensitive part 3 formed on the insulating film 5 and extending in the circumferential direction of the outer periphery, it is easily and high on the outer periphery of the battery body 2 with high flexibility. The film-like temperature sensor 4 can be adhered in a close contact state, and temperature measurement with high accuracy and high response becomes possible. In particular, since the heat sensitive part 3 includes the thin film thermistor part 8 patterned on the insulating film 5, the wide outer periphery of the battery body 2 is covered with the thin film thermistor part 8 having a large area, so that the higher accuracy and Highly responsive temperature measurement is possible.

  Next, 2nd Embodiment and 3rd Embodiment of the battery with a temperature sensor which concern on this invention are described below with reference to FIGS. Note that, in the following description of the embodiment, the same components described in the above embodiment are denoted by the same reference numerals, and the description thereof is omitted.

The difference between the second embodiment and the first embodiment is that, in the first embodiment, the thermosensitive part 3 is a thin film thermistor provided with a thin film thermistor part 8, whereas the battery with a temperature sensor of the second embodiment is As shown in FIG. 5, the heat-sensitive part 23 is a platinum resistance thermometer 28 patterned in a meander-shaped linear pattern with a Pt (platinum) film on the insulating film 5.
That is, in the film temperature sensor 24 of the second embodiment, the Pt film formed on the insulating film 5 is patterned in a meander shape so that the platinum resistance thermometer 28 extends in the circumferential direction of the outer periphery of the battery body 2. Is provided.

Next, the manufacturing method of the battery with a temperature sensor of 2nd Embodiment is demonstrated with reference to FIG. 5 and FIG.
First, as shown in FIG. 6A, a NiCr film (Ni: Cr = 80 mol%: 20 mol%) is formed to a thickness of 10 nm on the insulating film 5 of a polyimide resin sheet having a thickness of 50 μm, for example, by sputtering. Further, a Pt film having a thickness of 200 nm is formed thereon.

  Next, as shown in FIG. 6B, a resist solution is applied on the stacked NiCr film and Pt film with a bar coater, pre-baked at 80 ° C. for 10 minutes, and then a predetermined meander structure is formed with an exposure apparatus. The pattern is exposed to light, and unnecessary portions are removed. Further, the platinum resistance thermometer 28 is patterned in a predetermined pattern by dry etching with Ar.

  Thereafter, as shown in FIG. 6 (c), a polyimide coverlay film 12 with an adhesive is placed on the insulating film 5 so as to cover the platinum resistance thermometer 28, and 2N / Pressurize with a pressure of cm for 30 minutes to adhere. The polyimide cover lay film 12 is bonded except for the pair of base end portions of the platinum resistance thermometer 28 where the plated portion 10 is formed.

Next, as shown in FIG. 6D, a Ni plating layer having a thickness of 3 μm and a Sn plating layer having a thickness of 10 μm are formed on the pair of base end portions of the platinum resistance thermometer 28 by a plating solution. A pair of plating portions 10 is used.
Furthermore, the film-like temperature sensor 24 shown in FIG. 5 is produced by joining one end of each lead wire 6 to the plated portion 10 with the solder material 11.

  Next, similarly to the first embodiment, a film with a double-sided adhesive (not shown) is wound around the outer periphery of the battery body 2, and the film-like temperature sensor 24 is placed on the film with a double-sided adhesive (not shown). Adhere so that the outer periphery of 2 may be covered. At this time, the film-like temperature sensor 24 is bonded so that the heat-sensitive part 23 goes around the outer peripheral surface of the battery body 2 substantially. Furthermore, the battery with temperature sensor of the second embodiment is manufactured by wrapping the outer periphery of the battery body 2 so as to cover the insulating film 5 of the film-like temperature sensor 24 with the insulating tape 13.

  As described above, in the battery with the temperature sensor of the second embodiment, the heat sensitive part 23 is the platinum resistance thermometer 28 patterned with the Pt film on the insulating film 5. The extending platinum resistance thermometer 28 enables temperature measurement with higher accuracy and higher response.

Next, the difference between the third embodiment and the first embodiment is that, in the first embodiment, the battery body 2 is a cylindrical lithium ion secondary battery, whereas the temperature sensor of the third embodiment is provided. As shown in FIG. 7, the battery 31 is that the battery body 32 is a thin plate battery pack.
That is, the battery 31 with a temperature sensor of the third embodiment is provided so as to cover the battery body 32 that is a thin plate-shaped battery pack and the outer periphery of the battery body 32 as shown in FIG. And a film-like temperature sensor 4 having a heat-sensitive portion 3 that extends in the circumferential direction of the outer periphery and changes its electrical resistance in accordance with the temperature.

  In order to produce the battery 31 with temperature sensor of the third embodiment, first, the film-like temperature sensor 4 is produced in the same manner as in the first embodiment, and then the battery main body 32 shown in FIG. A film with a double-sided adhesive (not shown) is wound around the outer periphery, and the film-like temperature sensor 4 is wound on the film with a double-sided adhesive so as to cover the outer periphery of the battery body 32 as shown in FIG. Glue. At this time, the film-like temperature sensor 4 is bonded so that the heat-sensitive part 3 makes one round of the outer peripheral surface of the battery body 32.

  Further, as shown in FIG. 7C, the outer periphery of the battery main body 32 is wrapped so that the insulating film 13 of the film-like temperature sensor 4 is covered with the insulating tape 13, whereby the temperature sensor according to the third embodiment. The attached battery 31 is produced. In the first embodiment, the film-like temperature sensor 4 is installed by protruding the lead wire 6 in the direction opposite to the lead terminal 9. In the third embodiment, the lead wire 6 protrudes in the same direction as the lead terminal 9. The film temperature sensor 4 is installed.

  As described above, also in the battery 31 with a temperature sensor of the third embodiment, the battery 31 is provided so as to cover the outer periphery of the thin plate-shaped battery body 32 and extends in the circumferential direction of the outer periphery to change the electric resistance according to the temperature. Since the film-like temperature sensor 4 having the heat sensitive part 3 is provided, the temperature can be measured in a wide area on the outer periphery of the battery main body 32, and the battery is compared with a conventional one in which the temperature sensor is closely adhered and fixed. The temperature of the entire main body 32 can be accurately measured.

  The technical scope of the present invention is not limited to the above embodiments, and various modifications can be made without departing from the spirit of the present invention.

  DESCRIPTION OF SYMBOLS 1,31 ... Battery with temperature sensor, 2, 31 ... Battery body, 3, 23 ... Heat sensitive part, 4, 24 ... Film temperature sensor, 5 ... Insulating film, 6 ... Lead wire, 7 ... Pattern electrode, 8 ... Thin film thermistor, 28 ... Platinum resistance thermometer

Claims (4)

A battery body;
A film-like temperature sensor provided over the outer periphery of the battery body and having a heat-sensitive portion that extends in the circumferential direction of the outer periphery and changes its electrical resistance in accordance with the temperature ;
The battery with a temperature sensor, wherein the film-like temperature sensor is in close contact with the outer periphery of the battery body, and the heat sensitive part extends over the entire periphery of the battery body . The battery with a temperature sensor according to claim 1 ,
The film temperature sensor is an insulating film,
The thin film-shaped heat-sensitive part formed on the insulating film and extending in the circumferential direction of the outer periphery;
A battery with a temperature sensor, comprising: a pair of lead wires connected to the heat sensitive part. The battery with a temperature sensor according to claim 2 ,
A pair of pattern electrodes formed on the insulating film and connected to the pair of lead wires;
A battery with a temperature sensor, comprising: a thin film thermistor portion patterned on the insulating film and the pair of pattern electrodes. The battery with a temperature sensor according to claim 2 ,
The battery with a temperature sensor, wherein the heat sensitive part is a platinum resistance thermometer that is patterned with a platinum film on the insulating film.

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