JP5449656B2 - Cement molded body and method for producing the same - Google Patents

Cement molded body and method for producing the same Download PDF

Info

Publication number
JP5449656B2
JP5449656B2 JP2007160656A JP2007160656A JP5449656B2 JP 5449656 B2 JP5449656 B2 JP 5449656B2 JP 2007160656 A JP2007160656 A JP 2007160656A JP 2007160656 A JP2007160656 A JP 2007160656A JP 5449656 B2 JP5449656 B2 JP 5449656B2
Authority
JP
Japan
Prior art keywords
water
cement
molded body
exchange resin
ion exchange
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2007160656A
Other languages
Japanese (ja)
Other versions
JP2008308390A (en
Inventor
惠子 阪本
俊昭 岩下
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Big Bio Co Ltd
Original Assignee
Big Bio Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Big Bio Co Ltd filed Critical Big Bio Co Ltd
Priority to JP2007160656A priority Critical patent/JP5449656B2/en
Priority to PCT/JP2008/059163 priority patent/WO2008155966A1/en
Publication of JP2008308390A publication Critical patent/JP2008308390A/en
Application granted granted Critical
Publication of JP5449656B2 publication Critical patent/JP5449656B2/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • C02F1/505—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment by oligodynamic treatment
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/60—Agents for protection against chemical, physical or biological attack
    • C04B2103/67—Biocides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Porous Artificial Stone Or Porous Ceramic Products (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Artificial Fish Reefs (AREA)
  • Revetment (AREA)

Description

本発明は、水浄化作用に優れたセメント製成形体及びその製造方法に関する。   The present invention relates to a cement molded article having an excellent water purification effect and a method for producing the same.

環境汚染の抑制や自然環境の改善、水資源の有効活用などを行うため、河川や池・湖、さらには水槽などにある水を浄化することが求めれらている。水が汚濁したり悪臭を放つ主な原因として、水質の過養分化による微生物や藻類の繁殖が指摘されている。
水を浄化する方法としては、有用微生物を用いて、この微生物等の繁殖を抑制する方法が提案されている。
例えば、酵母菌等の有用微生物をコンクリートの混和剤として使用し、家庭汚水、工場排水、畜産業の処理水の浄化施設の浄化槽の壁面や床のライニングとして、微生物菌を含ませたコンクリートを使用する方法である（例えば、特許文献１又は２参照)。
特開平８−１６９７４５号公報 特開平１０−１１３６８８号公報 In order to control environmental pollution, improve the natural environment, and effectively use water resources, it is required to purify water in rivers, ponds, lakes, and aquariums. It has been pointed out that the proliferation of microorganisms and algae due to over-differentiation of water quality has been pointed out as the main cause of water pollution and odor.
As a method for purifying water, there has been proposed a method for suppressing the propagation of microorganisms and the like using useful microorganisms.
For example, useful microorganisms such as yeast are used as an admixture for concrete, and concrete containing microorganisms is used as a lining for the walls and floors of septic tanks for household sewage, industrial effluent, and livestock industry treatment water. (For example, refer to Patent Document 1 or 2).
JP-A-8-169745 Japanese Patent Application Laid-Open No. 10-113688

しかしながら、コンクリートの原料であるセメントは強アルカリ性であるため、セメントに微生物菌を混ぜ込んでも、殆どの微生物が死滅して狙いの効果が得られず、効能の持続性がないものとなる。
このため、特許文献３では、バチルスサブチルス（Bacillus subtilis）、バチルスツリュゲナイセス（Bacillus thuringiensis）及びバチルススパリカス（Bacillus sphaericus）の特定の微生物菌の混合物をセメントに混合することにより、コンクリートのプレートやブロック状態でも微生物菌による浄化作用を維持することを可能にしたものも提案されている。
国際公開第ＷＯ０２／４８０６９号 However, since cement, which is a raw material for concrete, is strongly alkaline, even if microbial bacteria are mixed in the cement, most of the microorganisms are killed and the intended effect cannot be obtained, and the effect is not sustained.
For this reason, in Patent Document 3, concrete is mixed with a mixture of specific microorganisms of Bacillus subtilis, Bacillus thuringiensis and Bacillus sphaericus into cement. There are also proposals that make it possible to maintain the purification action by microorganisms even in the state of plates and blocks.
International Publication No. WO02 / 48069

セメントを用いたコンクリートブロックなどのセメント製成形体に、微生物菌を利用する場合には、上述のように使用可能な微生物菌が限定される上、浄化作用も限定的なものとなる。しかも、製造工程や製品保管時に高温状態となると微生物菌自体が死滅する場合がある。さらに、微生物菌毎に活発に活動する環境が異なるため、使用環境が限定されると共に、多様な環境に対応するためには、多種多様な微生物菌を含有した製品を用意する必要がある。特に、藻類を発生される微生物に対しては、抑制効果のあるセメント製成形体は得られていない。   When microbial bacteria are used in a cement molded body such as a concrete block using cement, the microbial bacteria that can be used are limited as described above, and the purification action is also limited. In addition, the microorganisms themselves may be killed when they reach a high temperature during the production process or product storage. Furthermore, since the environment in which each microorganism is actively active is different, the usage environment is limited. In order to cope with various environments, it is necessary to prepare products containing various microorganisms. In particular, a cement molded body having an inhibitory effect on microorganisms that generate algae has not been obtained.

他方、抗菌性を有する物質として銀が知られており、銀イオンを含有する抗菌剤（例えば、特許文献４乃至６参照）が提案されている。これらの抗菌剤は、樹脂に混入されたり、溶解性ガラスやシリカゲル等の担体に担持させる状態で使用されている。銀イオンを用いて水の浄化を行うには、水中で銀イオンを徐々に放出可能とすると共に、銀イオンを含む浄化剤を担持する構造体は、セメント製成形体のように多様な形状やサイズに、任意に加工形成することが可能なものが好ましく、また、その製造コストも安価なものが好ましい。そして、何よりも、浄化した水の中で魚などの生物が生息可能であることが求められる。
特開２０００−１９８７０８号公報 特開平８−２６９２１号公報 特開２００５−４７８８４号公報 On the other hand, silver is known as an antibacterial substance, and antibacterial agents containing silver ions (see, for example, Patent Documents 4 to 6) have been proposed. These antibacterial agents are used in a state where they are mixed in a resin or are supported on a carrier such as soluble glass or silica gel. In order to purify water using silver ions, it is possible to gradually release silver ions in water, and structures that carry a purifier containing silver ions have various shapes and shapes such as cement molded bodies. A size that can be arbitrarily formed and processed is preferable, and a product that is inexpensive to manufacture is preferable. Above all, it is required that organisms such as fish can live in the purified water.
JP 2000-198708 A JP-A-8-26921 JP 2005-47884 A

本発明に係る課題は、上述のような問題を解決し、使用環境に依存せずに水中の微生物菌を効果的に殺菌でき、藻類の繁殖を抑制する浄化作用を有し、かつ魚等の生物の生息を可能とするセメント製成形体及びその製造方法を提供することである。
また、上記のような浄化作用等を有しながら、多様な形状やサイズの構造体を安価に提供可能なセメント製成形体及びその製造方法を提供することである。 The problem according to the present invention is to solve the above-mentioned problems, can effectively sterilize microbial bacteria in water without depending on the use environment, has a purification action to suppress the growth of algae, and It is an object of the present invention to provide a cement molded body that enables living organisms and a method for producing the same.
It is another object of the present invention to provide a cement molded body and a method for manufacturing the same, which can provide structures of various shapes and sizes at a low cost while having the above-described purification action and the like.

上記課題を解決するため、請求項１に係る発明は、水に浸漬させることにより水中に銀イオンを放出する銀イオン交換樹脂を含有する多孔質状の水浄化用セメント製成形体である。
本発明に用いる「銀イオン交換樹脂」とは、イオン交換樹脂、特に陽イオン交換樹脂のプロトン等を銀イオンに置換されたものを意味し、例えば、パーフルオロスルホン酸樹脂又はスルホン酸基を有するイオン交換樹脂を、硝酸銀、硫酸銀等の水溶液又はアセトニトリル溶液に所定時間浸漬することにより製造される。 In order to solve the above-mentioned problems, an invention according to claim 1 is a porous water-purified cement molded article for water purification containing a silver ion exchange resin that releases silver ions into water by being immersed in water .
The “silver ion exchange resin” used in the present invention means an ion exchange resin, particularly one obtained by substituting protons of a cation exchange resin with silver ions, and has, for example, a perfluorosulfonic acid resin or a sulfonic acid group. It is produced by immersing the ion exchange resin in an aqueous solution such as silver nitrate or silver sulfate or an acetonitrile solution for a predetermined time.

請求項２に係る発明は、少なくともセメント、骨材、水及び水に浸漬させることにより水中に銀イオンを放出する銀イオン交換樹脂を含む材料を混合し、成型後、養生・硬化させることを特徴とする多孔質状の水浄化用セメント製成形体の製造方法である。 The invention according to claim 2 is characterized by mixing at least cement, aggregate, water, and a material containing silver ion exchange resin that releases silver ions into water by being immersed in water, and curing and hardening after molding. A method for producing a porous water-purified cement molded body.

請求項１に係る発明により、水に浸漬させることにより水中に銀イオンを放出する銀イオン交換樹脂を含有する多孔質状の水浄化用セメント製成形体であるため、銀イオンが水中に放出されることとなり、微生物菌を用いた浄化作用と比較し、水質や温度などの使用環境に依存せず、水中の微生物菌を効果的に殺菌でき、特に、藻類の繁殖を抑制する浄化作用を高めることが可能となる。また、銀イオン交換樹脂であるため、銀イオンの放出が緩やかであり、浄化作用の持続性を高めるだけでなく、水中の銀イオン濃度が魚等の生物の生息を可能とする程度に維持されることから、極めて自然環境に優しい浄化作用を提供することが可能となる。
さらに、セメント製成形体内及び表面では、銀イオン交換樹脂を安定的に保持することが可能であるため、上記浄化作用を有する多様な形状やサイズの構造体を、安価に提供することも可能となる。 The invention according to claim 1 is a porous water-purified cement molded article for water purification containing a silver ion exchange resin that releases silver ions into water by being immersed in water, so that silver ions are released into water. Compared with the purification action using microbial bacteria, it can effectively sterilize microbial bacteria in water without depending on the use environment such as water quality and temperature, and in particular, enhance the purification action to suppress the growth of algae It becomes possible. In addition, since it is a silver ion exchange resin, the release of silver ions is gradual, not only increasing the sustainability of the purification action, but also maintaining the concentration of silver ions in water to the extent that living organisms such as fish can be inhabited. Therefore, it is possible to provide a purification action extremely friendly to the natural environment.
Furthermore, since it is possible to stably hold the silver ion exchange resin in the cement molded body and on the surface, it is possible to provide various shapes and sizes of structures having the purification action at low cost. Become.

しかも、セメント製成形体の構造が多孔質状であるため、銀イオン交換樹脂と水とが接触する面積を拡大することができ、より多くの水を早く浄化させることが可能となる。 And since the structure of the cement-made molded object is porous, the area which a silver ion exchange resin and water contact can be expanded, and it becomes possible to purify more water quickly.

請求項２に係る発明により、本発明に係る多孔質状の水浄化用セメント製成形体の製造方法は、少なくともセメント、骨材、水及び水に浸漬させることにより水中に銀イオンを放出する銀イオン交換樹脂を含む材料を混合し、成型後、養生・硬化させるため、安価な材料を用いて多様な形状やサイズの構造体を容易に形成することが可能であり、製造コストを安価にすることができる。
According to the second aspect of the present invention, there is provided a method for producing a porous water purification cement molded body according to the present invention, wherein silver is released into water by being immersed in at least cement, aggregate, water and water. Since materials containing ion-exchange resin are mixed, cured and cured after molding, it is possible to easily form structures of various shapes and sizes using inexpensive materials, thus reducing manufacturing costs. be able to.

本発明に係るセメント製成形体及びその製造方法について、以下に詳細に説明する。
本発明のセメント製成形体は、銀イオン交換樹脂を含有するセメント製成形体である。特に、セメント製成形体の原料であるセメントなどと一緒に銀イオン交換樹脂を混ぜ合わせ、成型硬化させたものであり、該成形体表面及び内部に銀イオン交換樹脂が保持されているものである。 The cement molded body and the manufacturing method thereof according to the present invention will be described in detail below.
The cement molded body of the present invention is a cement molded body containing a silver ion exchange resin. In particular, a silver ion exchange resin is mixed together with cement, which is a raw material of a molded body made of cement, and is molded and cured, and the silver ion exchange resin is held on the surface and inside of the molded body. .

本発明に用いる「銀イオン交換樹脂」は、イオン交換樹脂、特に陽イオン交換樹脂のプロトン等を銀イオンに置換されたものを使用する。具体的には、パーフルオロスルホン酸樹脂又はスルホン酸基を有するイオン交換樹脂を、硝酸銀、硫酸銀等の水溶液又はアセトニトリル溶液に所定時間浸漬することにより製造される。   As the “silver ion exchange resin” used in the present invention, an ion exchange resin, particularly one obtained by substituting a proton or the like of a cation exchange resin with silver ions, is used. Specifically, it is produced by immersing a perfluorosulfonic acid resin or an ion exchange resin having a sulfonic acid group in an aqueous solution such as silver nitrate or silver sulfate or an acetonitrile solution for a predetermined time.

本発明のセメント製成形体は、セメント、骨材、銀イオン交換樹脂及び水を主原料とし、必要に応じて添加剤を添加することにより、当該成形体を形成する。
セメントには、普通ポルトランドセメントや高炉セメント等の従来から使用されている任意のセメントを使用することができ、特に限定されるものではない。 The cement molded body of the present invention uses cement, aggregate, silver ion exchange resin and water as main raw materials, and forms the molded body by adding additives as necessary.
As the cement, any conventionally used cement such as ordinary Portland cement and blast furnace cement can be used, and the cement is not particularly limited.

骨材としては、砂、天然砕石、セラミックなどの焼結体を粉砕したものなど、各種の粗骨材や細骨材等が利用可能である。淡水を浄化する場合には、骨材には、塩分を含まないものが好ましい。また、骨材として多孔質体を選択し、セメント製成形体の表面積を増加させたり、軽量化を図ることも可能である。このような多孔質な骨材としては、天然軽石や焼結発泡体などが利用できる。
骨材のサイズとしては、用途に応じて異なるが、骨材間の空間を利用して多孔質な成形体を製造するためには、JIS篩による粒径が２．５ｍｍ〜１０ｍｍ程度のものが好適に利用可能である。河川や湖沼など規模の大きい環境で使用する場合には、１０ｍｍを超える骨材を使用し、セメントや銀イオン交換樹脂など、相対的にコストの高い材料の使用を抑制することが、好ましい。 As the aggregate, various coarse aggregates and fine aggregates such as those obtained by pulverizing a sintered body such as sand, natural crushed stone, and ceramic can be used. In the case of purifying fresh water, the aggregate preferably does not contain salt. It is also possible to select a porous body as the aggregate to increase the surface area of the cement molded body or to reduce the weight. As such porous aggregate, natural pumice or sintered foam can be used.
The size of the aggregate varies depending on the application, but in order to produce a porous molded body using the space between the aggregates, the particle size by the JIS sieve is about 2.5 mm to 10 mm. It can be suitably used. When used in large-scale environments such as rivers and lakes, it is preferable to use aggregates exceeding 10 mm and suppress the use of relatively expensive materials such as cement and silver ion exchange resins.

本発明のセメント製成形体に用いる銀イオン交換樹脂は、市場で入手しうる銀イオン交換樹脂であれば使用することができ、例えば、強酸性陽イオン交換樹脂（ムロマチテクノス株式会社製，製品名「Muromac XSC-1416」）を硝酸銀（純正化学株式会社製）に十分に浸漬し、その後、該樹脂を洗浄・乾燥して製造したもの等を用いることができる。   The silver ion exchange resin used for the cement molded body of the present invention can be used as long as it is a commercially available silver ion exchange resin. "Muromac XSC-1416") is sufficiently immersed in silver nitrate (manufactured by Junsei Chemical Co., Ltd.), and then the resin is washed and dried.

添加剤としては、成形体の固化を早める凝固促進剤や逆に固化を遅延させる遅延材、セメントや細かな骨材を多く含む場合でも多孔質な成形体を形成するのに役立つ起泡剤、添加する水の量を抑制する減水剤、成形体を着色するための顔料等の着色剤など、各種の添加材を用途に応じて利用することが可能である。   Additives include a coagulation accelerator that accelerates the solidification of the molded body, a retarder that delays the solidification, a foaming agent that helps to form a porous molded body even when it contains a lot of cement and fine aggregates, Various additives such as a water reducing agent that suppresses the amount of water to be added and a colorant such as a pigment for coloring the molded body can be used depending on applications.

次に、本発明に係るセメント製成形体の製造方法について説明する。
上述した、セメント製成形体の原材料である、セメント、骨材、水及び銀イオン交換樹脂、さらに、必要に応じて添加剤を混合し、均一に混練する。混練した材料を型枠に入れ成型し、養生・硬化させる。
なお、成形体の形状は特に限定されないが、方形のブロックやプレート状、さらには、円柱又は角柱などが可能である。また、表面積を増加させるため、中空部分を有するリング状とすることも可能である。 Next, a method for producing a cement molded body according to the present invention will be described.
Cement, aggregate, water and silver ion exchange resin, which are the raw materials of the above-mentioned cement molded body, and additives as necessary are mixed and kneaded uniformly. The kneaded material is put into a mold, molded, cured and cured.
The shape of the molded body is not particularly limited, but may be a rectangular block or plate shape, or a cylinder or a prism. Further, in order to increase the surface area, it is possible to form a ring having a hollow portion.

セメント製成形体に係る原材料の配合量についても、特に限定されるものではないが、一例として、成形体１ｍ３当たり、骨材として砕石：１５００ｋｇ〜１９５０ｋｇ、セメント量：２５０ｋｇ〜３００ｋｇ、水：ゼロスランプ成型に適する範囲、混和剤：希釈混和剤を３５０ｃｃ程度にする。さらに、銀イオン交換樹脂は、セメントや骨材の合計１００重量部に対し０．００５〜１０重量部となる範囲で添加することが好ましい。
また、多孔質な成形体を得るには、セメント配合量を含有させる骨材に対して少ない量で配合して、骨材間に間隙を形成させたり、または配合材料として起泡剤を添加して、気泡を発生させることで、多孔質成形体とすることができる。 The blending amount of the raw materials related to the cement molded body is not particularly limited, but as an example, per 1 m 3 of the molded body, crushed stone as aggregate: 1500 kg to 1950 kg, cement amount: 250 kg to 300 kg, water: zero Range suitable for slump molding, admixture: diluting admixture is about 350 cc. Furthermore, it is preferable to add silver ion exchange resin in the range which becomes 0.005-10 weight part with respect to a total of 100 weight part of cement and an aggregate.
In addition, in order to obtain a porous molded body, it is blended in a small amount with respect to the aggregate containing the cement blending amount to form a gap between the aggregates, or a foaming agent is added as a blending material. Thus, a porous molded body can be obtained by generating bubbles.

本発明のセメント製成形体は、浄化処理を行う水に浸漬させるだけで、浄化作用を発揮することが可能である。
成形体は、水中において、銀イオン交換樹脂が保持している銀イオンを、水中に緩やかに放出する。該銀イオンは、菌類の表面に付着し、菌類の表面を破壊するだけでなく、菌類の内部まで侵入し、結果として、菌類の細胞自体を破壊することが期待される。 The cement molded body of the present invention can exhibit a purification effect only by being immersed in water for purification treatment.
The molded body slowly releases the silver ions held by the silver ion exchange resin into water. The silver ions are expected to adhere to the surface of the fungus and not only destroy the surface of the fungus but also enter the inside of the fungus, resulting in destruction of the fungal cell itself.

本発明を以下の実施例等により説明する。
但し、以下の実施例等おいて用いる銀イオン交換樹脂は、強酸性陽イオン交換樹脂（ムロマチテクノス株式会社製，製品名「Muromac XSC-1416」）を硝酸銀（純正化学株式会社製）に十分に浸漬し、その後、該樹脂を洗浄・乾燥して製造したものである。
成形体を製造するにあたり、以下の分量で原材料を均一に撹拌混合し、直径９ｃｍ，高さ８ｃｍの円筒状成形体（重量４００ｇ）を作成した。
（１）普通ポルトランドセメント：２０ｋｇ
（２）多孔質骨材：３９ｋｇ
（３）銀イオン交換樹脂：７０ｇ
（４）顔料：６００ｇ The present invention is illustrated by the following examples.
However, the silver ion exchange resin used in the following examples, etc., is a strong acid cation exchange resin (Muromachi Technos Co., Ltd., product name “Muromac XSC-1416”) is sufficient for silver nitrate (Pure Chemical Co., Ltd.). It is produced by dipping and then washing and drying the resin.
In manufacturing the molded body, the raw materials were uniformly stirred and mixed in the following amounts to prepare a cylindrical molded body (weight 400 g) having a diameter of 9 cm and a height of 8 cm.
(1) Ordinary Portland cement: 20kg
(2) Porous aggregate: 39 kg
(3) Silver ion exchange resin: 70 g
(4) Pigment: 600 g

（銀の溶出試験）
実施例の成形体を１リットルの水道水に浸漬し、水分中の銀濃度を測定した。
測定結果を、表１に示す。 (Silver dissolution test)
The molded body of the example was immersed in 1 liter of tap water, and the silver concentration in the water was measured.
The measurement results are shown in Table 1.

Figure 0005449656
Figure 0005449656

表１の結果より、成形体内の銀イオンは最初の数時間の間に急速に、水中に放出されるが、２４時間経過後は、放出量は抑制され、緩やかなものとなっている。   From the results in Table 1, the silver ions in the molded body are rapidly released into water during the first few hours, but after 24 hours, the release amount is suppressed and becomes moderate.

（試験水の色調等の観察）
得られた成形体を用いて、試験水の色調等の以下の試験を行った。
藻体を接種した水に検体（上記実施例の成形体）及び対照品（上記実施例から銀イオン交換樹脂を用いない以外は、実施例と同様に成形体を作成したもの。）を投入し、試験水の色調及び状態を観察し、比較を行った。 (Observation of test water color, etc.)
The following tests, such as the color tone of test water, were done using the obtained molded object.
The specimen (the molded body of the above example) and the control product (the molded body was prepared in the same manner as in the example except that no silver ion exchange resin was used from the above example) were put into the water inoculated with the alga body. The color tone and state of the test water were observed and compared.

試験生物として、藻類（学名：pseudokirchneriella subcapitata，入手先：American Type Culture Collection，入手株番号：ATCC22662株）を用いた。
試験に用いた藻類は、保存培養から植え継ぎを行い、３日間培養し、指数関数的増殖期の藻類懸濁液を得た。次に、藻類の細胞数を計数し、試験水中の細胞濃度が約１×１０５［cells/ml］となるように、脱塩素水道水に添加した。そして、試験水１０リットルに対し検体又は対照品を１個投入した。
試験水の色調及び状態の観察結果を表２に示す。また、試験水のｐＨ及び水温の測定結果を表３に示す。 Algae (scientific name: pseudokirchneriella subcapitata, source: American Type Culture Collection, strain number: ATCC22662) was used as the test organism.
The algae used for the test were transplanted from the preservation culture and cultured for 3 days to obtain an algal suspension in the exponential growth phase. Next, the number of algae cells was counted and added to dechlorinated tap water so that the cell concentration in the test water was about 1 × 10 5 [cells / ml]. Then, one specimen or control product was added to 10 liters of test water.
Table 2 shows the observation results of the color tone and state of the test water. In addition, Table 3 shows the measurement results of the pH and temperature of the test water.

Figure 0005449656
Figure 0005449656

Figure 0005449656
Figure 0005449656

表２の結果より、実施例のセメント製成形体に、藻類が繁殖が効果的に抑制されていることが容易に理解される。   From the results in Table 2, it is easily understood that the algae are effectively inhibited from breeding in the cement molded bodies of the examples.

（魚類急性毒性試験（ヒメダカ））
財団法人日本食品分析センターに依頼し、以下の実験を行った。
検体（上記実施例の成形体）の魚類に対する半数致死濃度の濃度範囲を調べるために、OECD Guidelines for the Testing of Chemicals 203(1992)を参考にして、ヒメダカに対する９６時間急性毒性試験を実施した。
試験は、検体５個を希釈水（水道水を脱塩素したもの）５０リットルに添加し、２４℃±１℃で２４時間溶出した水を検液とした。この検液に希釈水を添加し、１．０，１０，１００（Ｖ／Ｖ％）の濃度の試験水を調整し、濃度区とした。対照区は、希釈水のみとした。
各試験区に１０尾のヒメダカ（全長約2.0cm，体重約0.07ｇ）を入れ、死亡数及び異常な外観・行動を観察した。 (Acute toxicity test for fish (Himedaka))
We asked the Japan Food Analysis Center to conduct the following experiment.
In order to examine the concentration range of the half-lethal concentration for the fish of the specimen (molded body of the above example), a 96-hour acute toxicity test was conducted on medaka with reference to OECD Guidelines for the Testing of Chemicals 203 (1992).
In the test, 5 specimens were added to 50 liters of diluted water (dechlorinated tap water), and water eluted at 24 ° C. ± 1 ° C. for 24 hours was used as a test solution. Dilution water was added to this test solution, and test water having a concentration of 1.0, 10, 100 (V / V%) was adjusted to obtain a concentration group. The control group was diluted water only.
Ten medaka (total length: about 2.0 cm, body weight: about 0.07 g) were placed in each test area, and the number of deaths and abnormal appearance / behavior were observed.

結果として、９６時間後でも、死亡したもの、異常外観及び異常行動は、いずれの試験区においても観察されなかった。
参考までに、試験開始時及び９６時間後の溶存酸素濃度（ＤＯ）及びｐＨを表４に示す。
これらのことから、本発明のセメント製成形体は、生物の生息にも極めて安全なものであることが理解できる。 As a result, even after 96 hours, death, abnormal appearance and abnormal behavior were not observed in any of the test sections.
For reference, Table 4 shows the dissolved oxygen concentration (DO) and pH at the start of the test and after 96 hours.
From these facts, it can be understood that the cement molded body of the present invention is extremely safe for living organisms.

Figure 0005449656
Figure 0005449656

以上のように、本発明によれば、使用環境に依存せずに水中の微生物菌を効果的に殺菌でき、藻類の繁殖を抑制する浄化作用を有し、かつ魚等の生物の生息を可能とするセメント製成形体及びその製造方法を提供することが可能となる。
また、上記のような浄化作用等を有しながら、多様な形状やサイズの構造体を安価に提供可能なセメント製成形体及びその製造方法を提供することも可能となる。 As described above, according to the present invention, it is possible to effectively sterilize microbial bacteria in water without depending on the use environment, to have a purifying action that suppresses the growth of algae, and to inhabit the living organisms such as fish. It is possible to provide a cement molded body and a method for producing the same.
It is also possible to provide a cement molded body and a method for manufacturing the same, which can provide structures of various shapes and sizes at a low cost while having the above-described purification action and the like.

Claims (2)

水に浸漬させることにより水中に銀イオンを放出する銀イオン交換樹脂を含有する多孔質状の水浄化用セメント製成形体。 A porous molded article for cement for water purification containing a silver ion exchange resin that releases silver ions into water when immersed in water . 少なくともセメント、骨材、水及び水に浸漬させることにより水中に銀イオンを放出する銀イオン交換樹脂を含む材料を混合し、成型後、養生・硬化させることを特徴とする多孔質状の水浄化用セメント製成形体の製造方法。 Porous water purification characterized by mixing at least cement, aggregate, water, and a material containing silver ion exchange resin that releases silver ions into water by being immersed in water, and curing and hardening after molding. For producing a molded body for cement.
JP2007160656A 2007-06-18 2007-06-18 Cement molded body and method for producing the same Expired - Fee Related JP5449656B2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2007160656A JP5449656B2 (en) 2007-06-18 2007-06-18 Cement molded body and method for producing the same
PCT/JP2008/059163 WO2008155966A1 (en) 2007-06-18 2008-05-20 Molded cement product and method of producing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2007160656A JP5449656B2 (en) 2007-06-18 2007-06-18 Cement molded body and method for producing the same

Publications (2)

Publication Number Publication Date
JP2008308390A JP2008308390A (en) 2008-12-25
JP5449656B2 true JP5449656B2 (en) 2014-03-19

Family

ID=40156125

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2007160656A Expired - Fee Related JP5449656B2 (en) 2007-06-18 2007-06-18 Cement molded body and method for producing the same

Country Status (2)

Country Link
JP (1) JP5449656B2 (en)
WO (1) WO2008155966A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011041874A (en) * 2009-08-19 2011-03-03 Japan Organo Co Ltd Water treatment device for fuel cell

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3197308B2 (en) * 1991-10-16 2001-08-13 シナネン株式会社 Fungicide
JPH06256052A (en) * 1993-02-26 1994-09-13 Sumitomo Cement Co Ltd Hydraulic cement composition having alga-proofing, antifungal and antimicrobial effect

Also Published As

Publication number Publication date
WO2008155966A1 (en) 2008-12-24
JP2008308390A (en) 2008-12-25

Similar Documents

Publication Publication Date Title
Adak et al. Anti-microbial efficiency of nano silver–silica modified geopolymer mortar for eco-friendly green construction technology
KR101859211B1 (en) Adsorption method of microbes for growth environment of microbes when putting microbes in concrete
KR20130026769A (en) Cement brick for purifying water using microorganism and zeolite, and method for preparing the same
CN104099268A (en) Aquaculture composite microbial agent
WO2002048069A1 (en) Cement paste containing microbial cells
KR100840602B1 (en) Manufacturing method of concrete for purifying water
CN113603427A (en) Microbial erosion resistant protective concrete and preparation method thereof
CN113912350A (en) High-quality concrete based on nano bamboo fibers and preparation method thereof
KR100994335B1 (en) Manufacturing methods of water purification concrete using micro-organisms and solution
KR101553044B1 (en) Water Purification Bio Concrete using Hidrophilic Fiber and Industrial By-Products and Manufacturing Methods of it
JP5449656B2 (en) Cement molded body and method for producing the same
Prabhakar et al. Sewage sludge ash-based mortar as construction material: Mechanical studies, macrofouling, and marine toxicity
KR101448068B1 (en) Concrete using microorganism capsule and manufacturing mrthod of it
KR101892113B1 (en) Manufacturing method of porous concrete with water purification bacteria
KR101156746B1 (en) Porosity concrete composite using composition beneficial microorganisms and functional media and porosity concrete block for restoring river ecology manufactured by this
KR100994315B1 (en) Manufacturing methods of block for the water purification using micro-organisms and solution
CN110255837A (en) A kind of modifying agent for bottom material of pond for breeding and its preparation, application method
Olivia et al. The influence of micro algae on corrosion of steel in fly ash geopolymer concrete: a preliminary study
JP6185953B2 (en) Water purification body containing useful microorganisms
CN107899428B (en) Preparation for preventing MBR membrane pollution and application thereof
KR20100133148A (en) Method for production of high-performance self-purification concrete using effective micro-organisms
KR101409828B1 (en) Concrete composite for Environmental friendly and Method for making with the concrete composite
CN106630180B (en) Improve the preparation method of the slow-release nutrient of chemical production wastewater Biochemical Treatment
KR20080061812A (en) Environmentally favorable revetment block including effective micro-organism
KR101188100B1 (en) Water purification concrete using micro-organisms and solution system and manufacturing methods of it

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20100617

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20110609

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20130129

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20130401

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20131203

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20131225

R150 Certificate of patent or registration of utility model

Ref document number: 5449656

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees