JP5438541B2 - Air humidification method - Google Patents

Air humidification method Download PDF

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JP5438541B2
JP5438541B2 JP2010028918A JP2010028918A JP5438541B2 JP 5438541 B2 JP5438541 B2 JP 5438541B2 JP 2010028918 A JP2010028918 A JP 2010028918A JP 2010028918 A JP2010028918 A JP 2010028918A JP 5438541 B2 JP5438541 B2 JP 5438541B2
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humidified
honeycomb
skewed honeycomb
air
hypochlorous acid
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JP2011163705A (en
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彩 中林
佳子 高瀬
隆司 棚橋
雅彦 米田
太年 下津
操 海老原
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Tokyo Electric Power Co Inc
Nichias Corp
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Nichias Corp
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Description

本発明は、斜行ハニカムを用いて被加湿空気の加湿を行う空気加湿方法において、被加湿空気の加湿を中断することなく、斜行ハニカムに付着する菌の除菌を行う空気加湿方法及びそれを実施するための空気加湿装置に関する。   The present invention relates to an air humidifying method for humidifying humidified air using a skewed honeycomb and an air humidifying method for sterilizing bacteria adhering to the skewed honeycomb without interrupting humidification of the humidified air. The present invention relates to an air humidifier.

従来より、被加湿空気を加湿する方法としては、無機繊維からなる斜行ハニカムを用いて、斜行ハニカムの上部より斜行ハニカム内に加湿水を供給し、斜行ハニカムの下面から加湿水を排出しつつ、且つ、斜行ハニカムの前面より斜行ハニカム内に被加湿空気を供給し、斜行ハニカムの後面から加湿空気を排出することにより、斜行ハニカム内で被加湿空気と加湿水とを接触させて、被加湿空気の加湿を行う空気加湿方法が行われている。   Conventionally, humidified air is humidified by using a skewed honeycomb made of inorganic fibers, supplying humidified water into the skewed honeycomb from the top of the skewed honeycomb, and supplying the humidified water from the bottom of the skewed honeycomb. By supplying humidified air into the skewed honeycomb from the front surface of the skewed honeycomb and discharging the humidified air from the rear surface of the skewed honeycomb, the humidified air and the humidified water are discharged in the skewed honeycomb. An air humidification method is performed in which the humidified air is humidified by bringing the air into contact with each other.

このような空気加湿方法では、加湿を続けるうちに、斜行ハニカムに被加湿空気中に浮遊している菌が付着し、付着した菌が繁殖して、斜行ハニカムに存在する菌の量が増加し、異臭等の原因となるため、斜行ハニカムに存在する菌の量が多くなり過ぎた場合には、除菌しなければならない。なお、斜行ハニカムに付着する被加湿空気中に浮遊している菌とは、細菌及び真菌であり、本発明では、これらを総称して、菌と記載する。   In such an air humidification method, while the humidification is continued, bacteria floating in the humidified air adhere to the skewed honeycomb, and the attached bacteria propagate and the amount of the bacteria present in the skewed honeycomb is reduced. Since it increases and causes an unpleasant odor, etc., if the amount of bacteria present in the skewed honeycomb is excessive, it must be sterilized. In addition, the microbe suspended in the humidified air adhering to the skewed honeycomb is a bacterium and a fungus. In the present invention, these are collectively referred to as a bacterium.

従来の空気加湿方法では、斜行ハニカムに存在する菌の量が多くなり過ぎた場合には、斜行ハニカムへ空気を供給をしたまま、斜行ハニカムへの加湿水の供給を止めて、斜行ハニカムを乾燥させることにより、斜行ハニカムに付着した菌の除菌が行われていた。   In the conventional air humidification method, when the amount of bacteria present in the skewed honeycomb is excessive, the supply of humidified water to the skewed honeycomb is stopped while supplying air to the skewed honeycomb, By drying the row honeycomb, the bacteria attached to the skew honeycomb were sterilized.

また、半導体工場の製造エリアなどでは、高い清浄度が要求されるため、斜行ハニカムの前面に高機能フィルタを置くと共に、加湿水を純水とすることにより、斜行ハニカムに菌が繁殖し難くする加湿方法が知られている。   In addition, high cleanliness is required in manufacturing areas of semiconductor factories and so on, so that a high-functional filter is placed on the front of the skewed honeycomb and humidified water is used as pure water, so that bacteria can propagate in the skewed honeycomb. Humidification methods that make it difficult are known.

斜行ハニカムへ空気を供給したまま、斜行ハニカムへの加湿水の供給を止めて、斜行ハニカムを乾燥させることにより、斜行ハニカムに付着した菌の除菌を行う場合、乾燥を行っている間は、被加湿空気の加湿を行うことができない。また、この場合、被加湿空気の加湿を再開したときに、加湿空気中に異臭が発生することがある。   Stop air supply to the skewed honeycomb while supplying air to the skewed honeycomb, and dry the skewed honeycomb to dry the bacteria attached to the skewed honeycomb. While it is, humidified air cannot be humidified. In this case, when humidification of the humidified air is resumed, a strange odor may be generated in the humidified air.

夜間には、人がいなくなるような施設であれば、夜間に、上記のような斜行ハニカムの乾燥を行い、被加湿空気の加湿を再開すれば、乾燥の間、被加湿空気の加湿が行えなくても、また、再開直後に加湿空気が臭くなっても、問題は起こらない。   If it is a facility where there are no people at night, drying the slanted honeycomb as described above at night and resuming humidification of the humidified air will allow humidification of the humidified air during drying. Even if it is not, or if humidified air becomes odor immediately after restarting, no problem will occur.

しかし、病院、製薬工場、食品工場、動物や微生物を取り扱う研究所、オフィスビルや商業ビル等の24時間施設内に人がいるような施設には、24時間連続して加湿空気を供給する必要があるので、被加湿空気の加湿を停止することができず、また、加湿の再開直後に加湿空気が臭くなると、臭気の問題が起こる。   However, it is necessary to supply humidified air continuously for 24 hours to facilities such as hospitals, pharmaceutical factories, food factories, laboratories handling animals and microorganisms, office buildings, commercial buildings, etc. Therefore, the humidification of humidified air cannot be stopped, and if the humidified air becomes odor immediately after the resumption of humidification, an odor problem occurs.

そのため、従来の除菌方法では、これらの問題を回避するために、空気加湿装置を2つ用意し、一方の空気加湿装置で、被加湿空気の加湿を行い、斜行ハニカムに存在する菌の量が多くなり過ぎたときには、被加湿空気の加湿運転を、他方の空気加湿装置に切り替え、他方の空気加湿装置での加湿運転を行っている間に、一方の斜行ハニカムの除菌及び加湿の再開を行い、それらが終了してから、再び、一方の空気加湿装置での加湿運転に切り替えるということが必要であった。   Therefore, in the conventional sterilization method, in order to avoid these problems, two air humidifiers are prepared, and one of the air humidifiers humidifies the humidified air so that the bacteria present in the skewed honeycomb are removed. When the amount becomes too large, the humidifying operation of humidified air is switched to the other air humidifying device, and while the humidifying operation of the other air humidifying device is being performed, the sterilization and humidification of one skewed honeycomb is performed. It was necessary to switch to the humidification operation with one of the air humidifiers again after they were restarted.

しかし、このような方法では、空気加湿装置を2つ併設しなければならず、装置の設置に大きな場所が必要になること、及びメンテナンスコストが高くなってしまうという新たな問題が発生する。   However, in such a method, two air humidifiers must be provided side by side, and a new problem arises that a large space is required for installation of the device and maintenance costs increase.

このようなことから、24時間施設内に人がいるような施設への加湿空気の供給には、ボイラー等で発生させた水蒸気による加湿空気の供給が一般的であった。ところが、蒸気式の場合は、燃料コストが発生すると共に、地球温暖化等の環境への影響が懸念されている。   For this reason, the supply of humidified air using steam generated by a boiler or the like is generally used for supplying humidified air to facilities where people are present in the facility for 24 hours. However, in the case of the steam type, fuel costs are generated and there are concerns about environmental impacts such as global warming.

また、斜行ハニカムの前面に高機能フィルタを置き、加湿水を純水とする方法では、高コストの高機能フィルタ及び純水製造装置が必要である。そのため、コストが高くなり過ぎるので、一般用途での使用は難しい。   Further, in the method in which a high-function filter is placed on the front surface of the skewed honeycomb and the humidified water is pure water, a high-cost high-performance filter and a pure water production apparatus are required. For this reason, the cost becomes too high and it is difficult to use it for general purposes.

従って、本発明の課題は、斜行ハニカムを用いる空気加湿方法であって、空気加湿装置を併設することなく、また、加湿水として純水を使用することなく、連続して加湿空気の供給を行うことができ且つ加湿時に臭気の問題が発生しない空気加湿方法を提供することにある。   Accordingly, an object of the present invention is an air humidification method using a skewed honeycomb, and it is possible to continuously supply humidified air without using an air humidifier and without using pure water as humidified water. An object of the present invention is to provide an air humidification method that can be performed and does not cause odor problems when humidifying.

本発明者らは、上記従来技術における課題を解決すべく、鋭意研究を重ねた結果、斜行ハニカムに供給する加湿水として、次亜塩素酸(HClO)を含有する加湿水を用いることにより、被加湿空気の加湿を行いながら、斜行ハニカムの除菌も行えることを見出し、本発明を完成させるに至った。   As a result of intensive studies to solve the problems in the conventional technology, the present inventors have used a humidified water containing hypochlorous acid (HClO) as the humidified water supplied to the skewed honeycomb, The inventors have found that it is possible to sterilize the skew honeycomb while humidifying the humidified air, and have completed the present invention.

すなわち、本発明(1)は、一方向に向かって伝播する波形形状を有する波形シートが複数積層されてハニカム形状を呈し、隣り合う波形シートの山部の稜線方向が斜めに交差し、且つ、一枚おきに波形シートの山部の稜線方向が略同一方向になるように、該波形シートが積層されており、前面、後面、上面及び下面の4面に通気空洞の開口を有する斜行ハニカムの上部より該斜行ハニカム内に加湿水を供給し、該斜行ハニカムの下面から該加湿水を排出しつつ、且つ、該斜行ハニカムの前面より該斜行ハニカム内に被加湿空気を供給し、該斜行ハニカムの後面から加湿空気を排出することにより、該斜行ハニカム内で該被加湿空気と該加湿水とを接触させて、該被加湿空気の加湿を行う加湿工程を行い、
該加湿工程中に、該加湿水として、次亜塩素酸を含有する加湿水を、該斜行ハニカムの下面から排出される加湿水中の次亜塩素酸濃度が、0.4mg/L以上となるまで、該斜行ハニカム内に供給することにより、該被加湿空気の加湿を行いながら、該斜行ハニカムの除菌を行う加湿兼除菌工程を、間欠的に繰り返し行うこと、
を特徴とする空気加湿方法を提供するものである。
That is, in the present invention (1), a plurality of corrugated sheets having a corrugated shape propagating in one direction are laminated to form a honeycomb shape, the ridge directions of the ridges of adjacent corrugated sheets are obliquely intersected, and The skew honeycomb in which the corrugated sheets are laminated so that the ridge line directions of the crests of the corrugated sheets are almost the same in every other sheet, and the openings of the ventilation cavities are provided on the four surfaces of the front surface, the rear surface, the upper surface and the lower surface The humidified water is supplied into the skewed honeycomb from the upper part of the slanted honeycomb, and the humidified air is supplied from the front surface of the skewed honeycomb into the skewed honeycomb while the humidified water is discharged from the bottom surface of the skewed honeycomb. The humidified air is exhausted from the rear surface of the skewed honeycomb so that the humidified air and the humidified water are brought into contact with each other in the skewed honeycomb to perform humidification of the humidified air.
During the humidification step, the hypochlorous acid concentration in the humidified water discharged from the lower surface of the skewed honeycomb is 0.4 mg / L or higher when humidified water containing hypochlorous acid is used as the humidified water. Until the humidification and sterilization step of sterilizing the skewed honeycomb is performed intermittently while humidifying the humidified air by supplying it into the skewed honeycomb,
An air humidification method characterized by the above is provided.

本発明によれば、斜行ハニカムを用いる空気加湿方法であって、空気加湿装置を併設することなく、また、加湿水として純水を使用することなく、連続して加湿空気の供給を行うことができ且つ菌の繁殖を防いで加湿時に臭気の問題が発生しない空気加湿方法を提供することができる。   According to the present invention, an air humidification method using a skewed honeycomb, wherein humidified air is continuously supplied without an air humidifier and without using pure water as humidified water. Thus, it is possible to provide an air humidification method that prevents the growth of bacteria and does not cause odor problems when humidified.

本発明に係る斜行ハニカムを示す模式図である。It is a mimetic diagram showing a skewed honeycomb concerning the present invention. 本発明の係る斜行ハニカムを構成する波形シートを、通気空洞の形成方向に対して垂直な面で切ったときの斜視図である。It is a perspective view when the corrugated sheet which comprises the skewed honeycomb which concerns on this invention is cut in the surface perpendicular | vertical with respect to the formation direction of a ventilation cavity. 本発明の空気加湿装置の形態例の模式的な端面図である。It is a typical end view of the example of the form of the air humidifier of the present invention. 本発明の空気加湿装置の形態例の模式的な端面図である。It is a typical end view of the example of the form of the air humidifier of the present invention. 本発明の空気加湿装置の形態例の模式的な端面図である。It is a typical end view of the example of the form of the air humidifier of the present invention. 本発明の空気加湿装置の形態例の模式的な端面図である。It is a typical end view of the example of the form of the air humidifier of the present invention.

本発明の空気加湿方法は、一方向に向かって伝播する波形形状を有する波形シートが複数積層されてハニカム形状を呈し、隣り合う波形シートの山部の稜線方向が斜めに交差し、且つ、一枚おきに波形シートの山部の稜線方向が略同一方向になるように、該波形シートが積層されており、前面、後面、上面及び下面の4面に通気空洞の開口を有する斜行ハニカムの上部より該斜行ハニカム内に加湿水を供給し、該斜行ハニカムの下面から該加湿水を排出しつつ、且つ、該斜行ハニカムの前面より該斜行ハニカム内に被加湿空気を供給し、該斜行ハニカムの後面から加湿空気を排出することにより、該斜行ハニカム内で該被加湿空気と該加湿水とを接触させて、該被加湿空気の加湿を行う加湿工程を行い、
該加湿工程中に、該加湿水として、次亜塩素酸を含有する加湿水を、該斜行ハニカム内に供給することにより、該被加湿空気の加湿を行いながら、該斜行ハニカムの除菌を行う加湿兼除菌工程を、間欠的に繰り返し行うこと、
を特徴とする空気加湿方法である。
In the air humidification method of the present invention, a plurality of corrugated sheets having a corrugated shape propagating in one direction are laminated to form a honeycomb shape, and the ridge directions of the ridges of adjacent corrugated sheets are obliquely intersected, and The corrugated sheets are laminated so that the ridge line directions of the crests of the corrugated sheets are substantially the same in every other sheet, and the skewed honeycomb having openings of ventilation cavities on four surfaces of the front surface, the rear surface, the upper surface, and the lower surface Humidified water is supplied from above into the skewed honeycomb, and the humidified water is discharged from the lower surface of the skewed honeycomb, and humidified air is fed into the skewed honeycomb from the front of the skewed honeycomb. The humidifying step of humidifying the humidified air by bringing the humidified air into contact with the humidified water in the skewed honeycomb by discharging humidified air from the rear surface of the skewed honeycomb;
During the humidification step, humidified water containing hypochlorous acid is supplied as the humidified water into the skewed honeycomb so that the humidified air is humidified, and the sterilization of the skewed honeycomb is performed. Performing the humidifying and sterilizing step intermittently and repeatedly,
An air humidification method characterized by the above.

そして、本発明の空気加湿装置は、本発明の空気加湿方法を実施するために用いられる空気加湿装置であり、一方向に向かって伝播する波形形状を有する波形シートが複数積層されてハニカム形状を呈し、隣り合う波形シートの山部の稜線方向が斜めに交差し、且つ、一枚おきに波形シートの山部の稜線方向が略同一方向になるように、該波形シートが積層されており、前面、後面、上面及び下面の4面に通気空洞の開口を有する斜行ハニカムと、
該斜行ハニカムの上部より該斜行ハニカム内に加湿水を供給するための加湿水供給手段と、
該加湿水を貯めるための加湿水タンクと、
該加湿水タンクに補給水を補給するための加湿水補給管と、
該加湿水の一部を排出するための加湿水排出管と、
次亜塩素酸水溶液を供給するための次亜塩素酸水溶液供給管と、
を有することを特徴とする空気加湿装置である。
The air humidifier of the present invention is an air humidifier used for carrying out the air humidification method of the present invention, and a plurality of corrugated sheets having a corrugated shape propagating in one direction are laminated to form a honeycomb shape. Present, the corrugated sheets are laminated so that the ridge directions of the ridges of the adjacent corrugated sheets are diagonally intersected, and the ridge lines of the ridges of the corrugated sheets are in the same direction every other sheet, A skewed honeycomb having openings of ventilation cavities on four surfaces of a front surface, a rear surface, an upper surface and a lower surface;
Humidified water supply means for supplying humidified water into the skewed honeycomb from above the skewed honeycomb;
A humidified water tank for storing the humidified water;
A humidifying water supply pipe for supplying makeup water to the humidifying water tank;
A humidified water discharge pipe for discharging a part of the humidified water;
A hypochlorous acid aqueous solution supply pipe for supplying a hypochlorous acid aqueous solution;
It is an air humidifier characterized by having.

本発明の空気加湿方法は、斜行ハニカムを用いて行われる。本発明の空気加湿方法に用いられる斜行ハニカムの構造について、図1及び図2を参照して説明する。図1は、本発明に係る斜行ハニカムを示す模式図である。図2は、本発明に係る斜行ハニカムを構成する波形シートを、通気空洞の形成方向に対して垂直な面で切ったときの斜視図である。図1中、斜行ハニカム2は、波形形状に加工されている波形シート3を、図1中のA方向に積層して作成されており、四面、すなわち、被加湿空気が供給される面である前面4(図1中、右面)、加湿空気が排出される面である後面5(図1中、左面)、上面6及び下面7に、通気空洞の開口8を有している。波形シート3が積層される方向(A方向)と、斜行ハニカム2に、加湿水10が供給される方向(B方向)と、被加湿空気9が供給される方向(C方向)は、それぞれ直交している。   The air humidification method of the present invention is performed using a skewed honeycomb. The structure of the skew honeycomb used in the air humidification method of the present invention will be described with reference to FIGS. FIG. 1 is a schematic view showing a skewed honeycomb according to the present invention. FIG. 2 is a perspective view when the corrugated sheet constituting the skewed honeycomb according to the present invention is cut along a plane perpendicular to the formation direction of the ventilation cavities. In FIG. 1, the skewed honeycomb 2 is formed by laminating corrugated sheets 3 processed into a corrugated shape in the direction A in FIG. 1, and has four surfaces, that is, surfaces to which humidified air is supplied. A certain front surface 4 (right surface in FIG. 1), rear surface 5 (left surface in FIG. 1) from which humidified air is discharged, upper surface 6 and lower surface 7 have ventilation cavity openings 8. The direction in which the corrugated sheets 3 are laminated (A direction), the direction in which the humidified water 10 is supplied to the skewed honeycomb 2 (B direction), and the direction in which the humidified air 9 is supplied (C direction) are respectively Orthogonal.

図2には、斜行ハニカム2の作成に用いられる波形シート3qを示す。波形シート3qは、一方向に向かって伝播する波形形状に加工されており、斜行ハニカム2中で、他の波形シート3p及び3rに挟み込まれることにより、波形シート3qの山部11が連続する方向に延びた、略半円柱状の通気空洞12が形成される。以下の説明において、山部11の頂点部分の延長線(尾根の部分)を、山部の稜線13と呼ぶ。通気空洞12は山部の稜線13と平行に形成される。図2では、波形シート3qを挟み込んでいる、波形シート3p及び3rを記載していないが、山部11aと11cを結ぶ線上に、波形シート3pの山部の稜線が位置することになるので、波形シート3q及び山部11aと11cを結ぶ線に囲まれる部分が、通気空洞12aである。同様に、山部11bと11dを結ぶ線上に、波形シート3rの山部の稜線が位置することになるので、波形シート3q及び山部11bと11dを結ぶ線に囲まれる部分が、通気空洞12bである。   FIG. 2 shows a corrugated sheet 3q used for producing the skewed honeycomb 2. The corrugated sheet 3q is processed into a corrugated shape that propagates in one direction, and the crest 11 of the corrugated sheet 3q is continuous by being sandwiched between the other corrugated sheets 3p and 3r in the skewed honeycomb 2. A substantially semicircular vent cavity 12 extending in the direction is formed. In the following description, an extension line (ridge portion) of the apex portion of the mountain portion 11 is referred to as a ridge line 13 of the mountain portion. The ventilation cavity 12 is formed in parallel with the ridgeline 13 of the mountain portion. In FIG. 2, the corrugated sheets 3p and 3r sandwiching the corrugated sheet 3q are not described, but the ridge line of the peak portion of the corrugated sheet 3p is located on the line connecting the peak portions 11a and 11c. The portion surrounded by the line connecting the corrugated sheet 3q and the peaks 11a and 11c is the ventilation cavity 12a. Similarly, since the ridge line of the peak portion of the corrugated sheet 3r is located on the line connecting the peak portions 11b and 11d, the portion surrounded by the line connecting the corrugated sheet 3q and the peak portions 11b and 11d is the ventilation cavity 12b. It is.

本発明に係る斜行ハニカムは、波形シートを積層方向(図1では、A方向)から見たときに、波形シートの山部の稜線の方向が、(i)挟まれている両側の波形シートの山部の稜線の方向とは異なる方向であり、すなわち、挟まれている両側の波形シートとは山部の稜線の方向が交差しており、且つ(ii)一枚おきに山部の稜線方向が同一方向となるように積層される。具体例を示すと、(i)波形シート3pの山部の稜線の方向が、波形シート3qの山部の稜線の方向とは異なる方向になるように、すなわち、A方向から見た時に、波形シート3pの山部の稜線と、波形シート3qの山部の稜線が交差するように、且つ(ii)波形シート3pの山部の稜線の方向と、波形シート3rの山部の稜線の方向が同一方向となるように、すなわち、A方向に見た時に、波形シート3pの山部の稜線と、波形シート3rの山部の稜線が平行になるように積層される。   In the skewed honeycomb according to the present invention, when the corrugated sheets are viewed from the stacking direction (direction A in FIG. 1), the ridge line direction of the peak portion of the corrugated sheets is (i) the corrugated sheets on both sides sandwiched The direction of the ridge line of the mountain part is different from the direction of the ridge line of the mountain part, that is, the direction of the ridge line of the mountain part intersects with the corrugated sheets on both sides sandwiched, and (ii) the ridge line of the mountain part every other sheet The layers are stacked so that the directions are the same. As a specific example, (i) the waveform is such that the direction of the ridge line of the peak portion of the corrugated sheet 3p is different from the direction of the ridge line of the peak portion of the corrugated sheet 3q, that is, when viewed from the A direction. (Ii) the direction of the ridgeline of the peak portion of the corrugated sheet 3p and the direction of the ridgeline of the peak portion of the corrugated sheet 3r are such that the ridgeline of the peak portion of the sheet 3p intersects the ridgeline of the peak portion of the corrugated sheet 3q. The ridge lines of the crests of the corrugated sheet 3p and the ridge lines of the crests of the corrugated sheet 3r are stacked so as to be in the same direction, that is, when viewed in the A direction.

通常、斜行ハニカム2は、山部の稜線が交互に斜めに交差し且つ山部の稜線が一枚おきに略同一方向になるように積層された積層物を、前面4、後面5、上面6及び下面7の4面に通気空洞の開口8が形成されるようにカットして製造される。そして、その断面が、前面4、後面5、上面6及び下面7となる。   Usually, the slanted honeycomb 2 is formed by laminating a laminate in which the ridge lines of the mountain portions alternately and obliquely intersect with each other and the ridge lines of the mountain portions are substantially in the same direction, the front surface 4, the rear surface 5, and the upper surface. 6 and the lower surface 7 are cut and manufactured so that the openings 8 of the ventilation cavities are formed. The cross section is a front surface 4, a rear surface 5, an upper surface 6 and a lower surface 7.

通気空洞12の形成方向について、更に詳細に説明する。波形シート3aは、斜行ハニカム2の最も外側の波形シートであり、波形シート3bは、外側から2番目の波形シートである。図1に示すように、C方向と通気空洞12の形成方向の関係、すなわち、C方向に対する波形シート3aの山部の稜線の角度Xは、通常15〜45度、好ましくは25〜35度であり、C方向に対するコルゲート状担体シート3bの山部の稜線の角度Xは、通常15〜45度、好ましくは25〜35度である。また、波形シート3aの山部の稜線と波形シート3bの山部の稜線の交差角度Yは、通常30〜90度、好ましくは50〜70度である。 The formation direction of the ventilation cavity 12 will be described in more detail. The corrugated sheet 3a is the outermost corrugated sheet of the skewed honeycomb 2, and the corrugated sheet 3b is the second corrugated sheet from the outside. As shown in FIG. 1, the relationship between the C direction and the formation direction of the ventilation cavity 12, that is, the angle X 1 of the ridge line of the peak portion of the corrugated sheet 3 a with respect to the C direction is usually 15 to 45 degrees, preferably 25 to 35 degrees. , and the angle X 2 of mountain ridges of the corrugated support sheet 3b is for the C direction, usually 15 to 45 degrees, preferably 25 to 35 degrees. Moreover, the intersection angle Y of the ridgeline of the peak part of the corrugated sheet 3a and the ridgeline of the peak part of the corrugated sheet 3b is usually 30 to 90 degrees, preferably 50 to 70 degrees.

波形シート3の山高さ(図2中、符号h)は、特に制限されないが、好ましくは2.0〜8.0mm、特に好ましくは3.0〜5.0mmである。また、波形シート3のピッチ(図2中、符号p)は、特に制限されないが、好ましくは2.5〜12.0mm、特に好ましくは5.0〜10.0mmである。   The peak height of the corrugated sheet 3 (indicated by h in FIG. 2) is not particularly limited, but is preferably 2.0 to 8.0 mm, and particularly preferably 3.0 to 5.0 mm. Further, the pitch of the corrugated sheet 3 (in FIG. 2, symbol p) is not particularly limited, but is preferably 2.5 to 12.0 mm, particularly preferably 5.0 to 10.0 mm.

すなわち、本発明に係る斜行ハニカムは、一方向に向かって伝播する波形形状を有する波形シートが複数積層されてハニカム形状を呈し、隣り合う波形シートの山部の稜線方向が斜めに交差し、且つ、一枚おきに波形シートの山部の稜線方向が略同一方向になるように、波形シートが積層されており、前面、後面、上面及び下面の4面に通気空洞の開口を有する。   That is, the skewed honeycomb according to the present invention has a honeycomb shape in which a plurality of corrugated sheets having a corrugated shape propagating in one direction is formed, and the ridge line directions of the peak portions of adjacent corrugated sheets are obliquely intersected, In addition, the corrugated sheets are laminated so that the ridge line directions of the crests of the corrugated sheets are almost the same in every other sheet, and there are openings of ventilation cavities on the four surfaces of the front surface, rear surface, upper surface, and lower surface.

本発明に係る斜行ハニカムを構成する波形シートは、基材シートが波形に加工されたものである。このような基材シートは、表面に凹凸があり、内部が多孔質であることが、エレメントの表面積が大きく採れ、エレメントに浸透して流下する水と空気との接触面積が高まる点で好ましい。このような基材シートとしては、例えば、3次元網目構造を有して所定の繊維間空隙率を有するものが挙げられ、具体的には、アルミナ、シリカ及びチタニアからなる群より選択される1又は2以上の充填材又は結合材を含有し、無機繊維からなる無機繊維基材シートが挙げられる。このうち、チタニアを配合したものが酸性のガス状化学汚染物質の除去効率が向上するため好ましい。また、無機繊維基材シートは、通常、充填材又は結合材を60〜93重量%、繊維を7〜40重量%を含み、好ましくは充填材又は結合材を70〜88重量%、繊維を12〜30重量%を含む。無機繊維基材シートの配合比率が範囲内にあると、無機繊維基材シートの水浸透性及び強度が高いため好ましい。なお、充填材及び結合材を含有する無機繊維基材シートは、公知の方法で作製され、例えば、ガラス繊維、セラミック繊維又はアルミナ繊維で作製された無機繊維基材シートを、アルミナゾル等の結合材とアルミナ水和物等の充填材を混合したスラリーに浸漬した後、乾燥し、コルゲート加工し、その後、乾燥処理と熱処理を行い、水分と有機分を除去することにより作製される。無機繊維基材シートが、アルミナ以外にシリカやチタニアを含有する場合、例えば、シリカ及びチタニアの配合量は、アルミナ100重量部に対してそれぞれ通常5〜40重量部である。   The corrugated sheet constituting the skewed honeycomb according to the present invention is obtained by processing a base sheet into a corrugated sheet. It is preferable that such a substrate sheet has irregularities on the surface and is porous inside because the surface area of the element can be increased and the contact area between water and air that permeates and flows down the element increases. Examples of such a base sheet include those having a three-dimensional network structure and a predetermined inter-fiber porosity, and specifically, selected from the group consisting of alumina, silica and titania. Or the inorganic fiber base sheet which contains two or more fillers or binders and consists of inorganic fiber is mentioned. Among these, a mixture containing titania is preferable because the removal efficiency of acidic gaseous chemical pollutants is improved. The inorganic fiber base sheet usually contains 60 to 93% by weight of filler or binder and 7 to 40% by weight of fiber, preferably 70 to 88% by weight of filler or binder and 12 of fiber. Contains -30% by weight. It is preferable that the blending ratio of the inorganic fiber base sheet is within the range because the water permeability and strength of the inorganic fiber base sheet are high. The inorganic fiber base sheet containing the filler and the binder is produced by a known method. For example, the inorganic fiber base sheet made of glass fiber, ceramic fiber or alumina fiber is used as a binder such as alumina sol. After being immersed in a slurry in which a filler such as alumina hydrate is mixed, it is dried, corrugated, and then dried and heat treated to remove moisture and organic components. When the inorganic fiber base sheet contains silica or titania in addition to alumina, for example, the amount of silica and titania is usually 5 to 40 parts by weight with respect to 100 parts by weight of alumina.

また、上記結合材又は充填材を含有する無機繊維基材シートの繊維間空隙率は、通常65〜85%、好ましくは75〜82%である。無機繊維基材シートの繊維間空隙率を上記範囲内とすることにより、ほどよい浸透性を実現でき、空気と水との接触効率を高めることができる。また、上記結合材又は充填材を含有する無機繊維基材シートの厚さ、すなわち、壁の厚さが通常200〜1000μm、好ましくは300〜800μmである。上記結合材又は充填材を含有する無機繊維基材シートが、上記空隙率と上記厚さを有すると、液ガス比及び水の浸透速度が適度な範囲となり、水と空気の接触効率を高めると共に、強度的にも十分となる。   Moreover, the inter-fiber porosity of the inorganic fiber base sheet containing the binder or filler is usually 65 to 85%, preferably 75 to 82%. By setting the inter-fiber porosity of the inorganic fiber base sheet within the above range, moderate permeability can be realized, and the contact efficiency between air and water can be increased. Moreover, the thickness of the inorganic fiber base sheet containing the binder or filler, that is, the wall thickness is usually 200 to 1000 μm, preferably 300 to 800 μm. When the inorganic fiber base sheet containing the binder or filler has the porosity and the thickness, the liquid gas ratio and the water penetration rate are in an appropriate range, and the contact efficiency between water and air is increased. It will be sufficient in strength.

上記無機繊維基材シートをコルゲート状の波形シートに成形する方法としては、径方向に振幅する波形の凹凸が表面に形成された複数の歯車間に平板状シートを通すような公知のコルゲーターを用いる方法が挙げられる。得られた波形シートから上記斜行ハニカムを成形する方法としては、例えば、まず、上記波形シートを縦100mm(成形後の厚み寸法)×横3000mm程度の矩形の裁断型に対し、波の伝播方向が矩形型の一辺に対して15〜45度になるように配置して裁断して矩形の波形シートを作製し、次いで、得られた矩形の波形シートを1枚おきの波の伝播方向が斜交するように配置し、これらを接着して又は接着することなく積層する方法が挙げられる。なお、このようにして製造した場合、上記裁断型の縦の長さが斜行ハニカムの奥行(図1中の斜行ハニカム2のC方向の長さ)となる。   As a method for forming the inorganic fiber base sheet into a corrugated corrugated sheet, a known corrugator is used in which a flat sheet is passed between a plurality of gears having corrugated irregularities that oscillate in the radial direction. A method is mentioned. As a method for forming the above skew honeycomb from the obtained corrugated sheet, for example, first, the wave propagation direction of the corrugated sheet with respect to a rectangular cutting die having a length of about 100 mm (thickness dimension after forming) × width of about 3000 mm. The rectangular corrugated sheet is produced by arranging and cutting so that the angle is 15 to 45 degrees with respect to one side of the rectangular shape, and then the wave propagation direction of every other rectangular corrugated sheet is oblique. The method of arrange | positioning so that it may cross | intersect, and laminating | stacking these without adhere | attaching them is mentioned. When manufactured in this way, the vertical length of the cutting die is the depth of the skewed honeycomb (the length in the C direction of the skewed honeycomb 2 in FIG. 1).

無機繊維基材シートを構成する繊維の平均繊維径は、特に制限されないが、好ましくは1〜20μm、特に好ましくは3〜10μmである。平均繊維径が範囲内にあることにより、斜行ハニカムの機械的強度が高くなる。   The average fiber diameter of the fibers constituting the inorganic fiber base sheet is not particularly limited, but is preferably 1 to 20 μm, particularly preferably 3 to 10 μm. When the average fiber diameter is within the range, the mechanical strength of the skewed honeycomb is increased.

斜行ハニカムの奥行(図1中の斜行ハニカム2のC方向の長さ)は、好ましくは100〜1000mm、特に好ましくは200〜800mmである。   The depth of the skewed honeycomb (the length in the C direction of the skewed honeycomb 2 in FIG. 1) is preferably 100 to 1000 mm, particularly preferably 200 to 800 mm.

本発明の空気加湿装置は、斜行ハニカムを有しており、本発明の空気加湿方法を実施するために用いられる空気加湿装置である。本発明の空気加湿装置について、図3及び図4を参照して説明する。図3及び図4は、本発明の空気加湿装置の形態例の模式的な端面図であり、波形シートの積層方向に対して垂直な面で切ったときの端面図である。そして、図3は、加湿工程を行っている様子を示す図であり、図4は、加湿兼除菌工程を行っている様子を示す図である。よって、図3及び図4の上下方向が加湿水の供給方向であり、図3及び図4の左右方向が被加湿空気の供給方向である。   The air humidifier of the present invention has a skewed honeycomb and is an air humidifier used for carrying out the air humidification method of the present invention. The air humidifier of this invention is demonstrated with reference to FIG.3 and FIG.4. 3 and 4 are schematic end views of an embodiment of the air humidifier of the present invention, and are end views when cut along a plane perpendicular to the corrugated sheet stacking direction. And FIG. 3 is a figure which shows a mode that the humidification process is performed, and FIG. 4 is a figure which shows a mode that the humidification and sterilization process is performed. Therefore, the vertical direction in FIGS. 3 and 4 is the humidifying water supply direction, and the horizontal direction in FIGS. 3 and 4 is the humidified air supply direction.

図3中、空気加湿装置20aは、斜行ハニカム2と、加湿水25を貯めるための加湿水タンク18と、斜行ハニカム2の上面より加湿水25を散水するための散水部12と、散水部12と加湿水タンク18とを繋ぐ送水管13と、加湿用タンク18から散水部12へ加湿水25を送液するための第1送液ポンプ14と、加湿水タンク18に補給水22を補給するため補給水補給管19と、加湿水タンク18に次亜塩素酸水溶液23を供給するための次亜塩素酸水溶液供給管21と、加湿水25の一部を装置外へ排出するための加湿水排出管16aと、を有する。斜行ハニカム2への加湿水25の供給量と、加湿水排出管16aから排出する加湿水25の排出量との割合を調節するために、送水管13には第1弁15が、加湿水排出管16aには第2弁17aが、それぞれ付設されている。加湿水補給管19には、補給水22の供給量を調節するために、第3弁33が付設されている。次亜塩素酸水溶液供給管21には、次亜塩素酸水溶液23の供給量を調節するために、第4弁34が付設されている。   In FIG. 3, the air humidifier 20 a includes a skewed honeycomb 2, a humidified water tank 18 for storing the humidified water 25, a sprinkler 12 for sprinkling the humidified water 25 from the upper surface of the skewed honeycomb 2, A water supply pipe 13 connecting the section 12 and the humidified water tank 18, a first liquid feed pump 14 for feeding the humidified water 25 from the humidifying tank 18 to the sprinkling section 12, and makeup water 22 to the humidified water tank 18. A replenishment water replenishment pipe 19 for replenishment, a hypochlorous acid aqueous solution supply pipe 21 for supplying a hypochlorous acid aqueous solution 23 to the humidification water tank 18, and a part for discharging a part of the humidification water 25 to the outside. A humidified water discharge pipe 16a. In order to adjust the ratio between the supply amount of the humidifying water 25 to the skewed honeycomb 2 and the discharge amount of the humidifying water 25 discharged from the humidifying water discharge pipe 16a, the first valve 15 is provided in the water supply pipe 13 with the humidifying water. A second valve 17a is attached to each discharge pipe 16a. The humidifying water supply pipe 19 is provided with a third valve 33 for adjusting the supply amount of the makeup water 22. A fourth valve 34 is attached to the hypochlorous acid aqueous solution supply pipe 21 in order to adjust the supply amount of the hypochlorous acid aqueous solution 23.

散水部12から供給される加湿水25は、斜行ハニカム2内を下方に向かって流下し、被加湿空気を加湿し、そして、被加湿空気の加湿に使用されなかった分が、斜行ハニカム2の下面7から排出されて、加湿水タンク18に返送される。   The humidified water 25 supplied from the sprinkler 12 flows downward in the skewed honeycomb 2 to humidify the humidified air, and the portion not used for humidifying the humidified air is the skewed honeycomb. 2 is discharged from the lower surface 7 and returned to the humidified water tank 18.

なお、空気加湿装置20aでは、散水部12、送水管13及び第1送液ポンプ14が、本発明の空気加湿装置に係る加湿水供給手段に該当する。   In addition, in the air humidifier 20a, the water sprinkling part 12, the water supply pipe 13, and the 1st liquid feed pump 14 correspond to the humidification water supply means which concerns on the air humidifier of this invention.

空気加湿装置20aを用いて、連続して被加湿空気の加湿を行う方法について説明する。先ず、被加湿空気の加湿を開始する前に、斜行ハニカム2を構成する波形シートが加湿水25で十分湿った状態になるように、第1弁15を開とし、第2弁17aを閉として、第1送液ポンプ14を用いて、斜行ハニカム2に、加湿水タンク18内の加湿水25を供給する運転準備をしておく。   A method of continuously humidifying humidified air using the air humidifier 20a will be described. First, before starting humidification of humidified air, the first valve 15 is opened and the second valve 17a is closed so that the corrugated sheet constituting the skewed honeycomb 2 is sufficiently moistened with the humidified water 25. As described above, preparation for operation for supplying the humidified water 25 in the humidified water tank 18 to the skewed honeycomb 2 using the first liquid feeding pump 14 is performed.

次いで、斜行ハニカム2を構成する波形シートが加湿水25で十分に湿った状態になったならば、第1送液ポンプ14を用いて、斜行ハニカム2の上面8より、斜行ハニカム2内に、加湿水タンク18内の加湿水25を供給し、斜行ハニカム2の下面7から、被加湿空気の加湿に使用されなかった加湿水26を排出すると共に、斜行ハニカム2の前面4より、斜行ハニカム2内に被加湿空気を供給し、斜行ハニカム2の後面5から加湿空気を排出する。斜行ハニカム2内では、被加湿空気と加湿水25とが接触するので、被加湿空気は加湿水25により加湿される。そして、斜行ハニカム2への被加湿空気及び加湿水25の供給を連続して行うことにより、被加湿吸気の加湿を連続して行う。   Next, when the corrugated sheet constituting the skewed honeycomb 2 is sufficiently moistened with the humidifying water 25, the skewed honeycomb 2 is introduced from the upper surface 8 of the skewed honeycomb 2 using the first liquid feeding pump 14. The humidified water 25 in the humidified water tank 18 is supplied to the inside, and the humidified water 26 that has not been used for humidifying the humidified air is discharged from the lower surface 7 of the skewed honeycomb 2. Thus, humidified air is supplied into the skewed honeycomb 2, and the humidified air is discharged from the rear surface 5 of the skewed honeycomb 2. Since the humidified air and the humidified water 25 are in contact with each other in the skewed honeycomb 2, the humidified air is humidified by the humidified water 25. Then, the humidified intake air is continuously humidified by continuously supplying the humidified air and the humidified water 25 to the skewed honeycomb 2.

このようにして、斜行ハニカム2の上部より斜行ハニカム2内に加湿水25を供給し、斜行ハニカム2の下面7から加湿水を排出しつつ、且つ、斜行ハニカム2の前面4より斜行ハニカム2内に被加湿空気を供給し、斜行ハニカム2の後面5から加湿空気を排出することにより、斜行ハニカム2内で被加湿空気と加湿水25とを接触させて、被加湿空気の加湿を行う加湿工程を行うことができる。   In this way, the humidified water 25 is supplied from the upper part of the skewed honeycomb 2 into the skewed honeycomb 2, the humidified water is discharged from the lower surface 7 of the skewed honeycomb 2, and from the front surface 4 of the skewed honeycomb 2. By supplying humidified air into the skewed honeycomb 2 and exhausting the humidified air from the rear surface 5 of the skewed honeycomb 2, the humidified air and the humidified water 25 are brought into contact with each other in the skewed honeycomb 2 to be humidified. The humidification process which humidifies air can be performed.

なお、加湿工程を行っている間、第1弁15及び第2弁17aの開度を調節して、斜行ハニカム2への加湿水25の供給量と加湿水排出管16aからの加湿水25の排出量とを調節することにより、斜行ハニカム2へ加湿水25を供給しながら、加湿水排出管16aから加湿水25の一部を装置外へ排出してもよいし、あるいは、第2弁17aを閉として、加湿水排出管16aから加湿水25を排出しなくてもよい。   During the humidification process, the opening amounts of the first valve 15 and the second valve 17a are adjusted to supply the humidified water 25 to the skewed honeycomb 2 and the humidified water 25 from the humidified water discharge pipe 16a. By adjusting the discharge amount, a part of the humidified water 25 may be discharged from the humidified water discharge pipe 16a to the outside while supplying the humidified water 25 to the skewed honeycomb 2, or the second It is not necessary to close the valve 17a and discharge the humidified water 25 from the humidified water discharge pipe 16a.

加湿工程では、被加湿空気の加湿に使用された分(加湿水排出管16aから加湿水25を排出する場合は、被加湿空気の加湿に使用された分に加えて、加湿水排出管16aから排出された加湿水25の分)、加湿水タンク18内の加湿水25の量が減るので、第3弁33を開として、その減少分に相当する量の補給水22を、加湿水タンク18に補給する。なお、加湿工程を行っている間、第4弁34は閉とする。   In the humidification step, the amount used for humidification of the humidified air (when the humidified water 25 is discharged from the humidified water discharge pipe 16a, in addition to the amount used for humidification of the humidified air, the humidified water discharge pipe 16a Since the amount of the humidified water 25 in the humidified water tank 18 decreases, the third valve 33 is opened, and the amount of makeup water 22 corresponding to the decreased amount is supplied to the humidified water tank 18. To replenish. During the humidification process, the fourth valve 34 is closed.

加湿工程を続けていると、斜行ハニカム2に、被加湿空気中に浮遊している菌が付着し繁殖するので、斜行ハニカム2に存在する菌の量が、時間の経過と共に増えてゆく。   If the humidification process is continued, the microorganisms floating in the humidified air adhere to and propagate on the skewed honeycomb 2, so that the amount of bacteria present in the skewed honeycomb 2 increases with the passage of time. .

そして、斜行ハニカム2に存在する菌の量が多くなり過ぎたとき又は多くなり過ぎる前に、図4に示すように、第3弁33を閉とし、第4弁34を開として、次亜塩素酸水溶液23を供給することにより、加湿水タンク18内の加湿水を、次亜塩素酸を含有する加湿水30とし、斜行ハニカム2に、次亜塩素酸を含有する加湿水を供給する。なお、斜行ハニカム2に、次亜塩素酸を含有する加湿水30を供給している間も、斜行ハニカム2に、被加湿空気を供給する。   Then, when the amount of bacteria present in the skewed honeycomb 2 is excessive or excessive, the third valve 33 is closed and the fourth valve 34 is opened as shown in FIG. By supplying the chloric acid aqueous solution 23, the humidified water in the humidified water tank 18 is changed to the humidified water 30 containing hypochlorous acid, and the humidified water containing hypochlorous acid is supplied to the skewed honeycomb 2. . It should be noted that humidified air is supplied to the skewed honeycomb 2 while the humidified water 30 containing hypochlorous acid is being supplied to the skewed honeycomb 2.

このようにして、斜行ハニカム2の上部より斜行ハニカム2内に次亜塩素酸を含有する加湿水30を供給し、斜行ハニカム2の下面7から次亜塩素酸を含有する加湿水31を排出しつつ、且つ、斜行ハニカム2の前面4より斜行ハニカム2内に被加湿空気を供給し、斜行ハニカム2の後面5から加湿空気を排出することにより、斜行ハニカム2内で被加湿空気の加湿を行いながら、斜行ハニカム2の除菌を行う加湿兼除菌工程を行う。   In this way, the humidified water 30 containing hypochlorous acid is supplied into the skewed honeycomb 2 from the upper part of the skewed honeycomb 2, and the humidified water 31 containing hypochlorous acid is supplied from the lower surface 7 of the skewed honeycomb 2. The humidified air is supplied from the front surface 4 of the skewed honeycomb 2 into the skewed honeycomb 2 and the humidified air is discharged from the rear surface 5 of the skewed honeycomb 2, so that the inside of the skewed honeycomb 2 is discharged. While humidifying the humidified air, a humidification and sterilization step for sterilizing the skewed honeycomb 2 is performed.

空気加湿装置20aを用いる場合、次亜塩素酸水溶液23の供給を開始した直後は、加湿水タンク18内の加湿水は、次亜塩素酸の濃度が非常に低い。そのため、加湿水タンク18内の加湿水、すなわち、次亜塩素酸を含有する加湿水30中の次亜塩素酸の濃度上昇速度を速めるために、第1弁15及び第2弁17aの開度を調節して、斜行ハニカム2に次亜塩素酸を含有する加湿水30を供給しながら、次亜塩素酸を含有する加湿水30の一部を、加湿水排出管17aから装置外へ排出することが好ましい。   When the air humidifier 20a is used, the concentration of hypochlorous acid in the humidified water tank 18 is very low immediately after the supply of the hypochlorous acid aqueous solution 23 is started. Therefore, in order to increase the concentration increase rate of the hypochlorous acid in the humidified water 30 in the humidified water tank 18, that is, the humidified water 30 containing hypochlorous acid, the opening degree of the first valve 15 and the second valve 17a. While the humidified water 30 containing hypochlorous acid is supplied to the skewed honeycomb 2 by adjusting the amount of water, a part of the humidified water 30 containing hypochlorous acid is discharged from the humidified water discharge pipe 17a to the outside of the apparatus. It is preferable to do.

次亜塩素酸は、斜行ハニカム2に存在する菌を除菌する作用を有するので、斜行ハニカム2内に、次亜塩素酸を含有する加湿水30を供給することにより、斜行ハニカム2の除菌を行うことができる。このとき、斜行ハニカム2に、加湿水としても作用する次亜塩素酸を含有する加湿水30を、斜行ハニカム2に供給することにより行われるため、斜行ハニカム2の除菌を行っている間も、被加湿空気の加湿を行うことができる。よって、加湿兼除菌工程を行う前から、加湿兼除菌工程を行っている間もずっと、被加湿空気の加湿を行っているので、被加湿空気の加湿を行っている最中、すなわち、加湿工程の最中に、斜行ハニカム2の除菌を行っている。   Hypochlorous acid has a function of sterilizing bacteria existing in the skewed honeycomb 2, and therefore, supplying the humidified water 30 containing hypochlorous acid into the skewed honeycomb 2 allows the skewed honeycomb 2. Can be sterilized. At this time, since the humidified water 30 containing hypochlorous acid that also acts as humidified water is supplied to the skewed honeycomb 2, the skewed honeycomb 2 is sterilized. The humidified air can be humidified while the air remains. Therefore, before performing the humidification and sterilization process, while the humidification and sterilization process is being performed, the humidified air is being humidified, so during humidification of the humidified air, that is, During the humidification step, the skewed honeycomb 2 is sterilized.

そして、斜行ハニカム2に存在している菌がなくなるまで、加湿水タンク18への次亜塩素酸水溶液23の供給、すなわち、斜行ハニカム2への次亜塩素酸を含有する加湿水30の供給を行う。   The supply of the hypochlorous acid aqueous solution 23 to the humidified water tank 18, that is, the humidified water 30 containing hypochlorous acid to the skewed honeycomb 2, until the bacteria present in the skewed honeycomb 2 disappear. Supply.

次いで、斜行ハニカム2に存在している菌が十分に除菌されると、加湿水タンク18への次亜塩素酸水溶液23の供給を止め、代りに、補給水22を補給して、被加湿空気の加湿を続けて行う。つまり、除菌を止めて、加湿工程を行う。そして、再び、斜行ハニカム2に存在する菌の量が多くなり過ぎたときに、加湿水タンク18へ次亜塩素酸水溶液23を供給して、すなわち、斜行ハニカム2への次亜塩素酸を含有する加湿水30の供給を行い、斜行ハニカム2の除菌を行いつつ、被加湿空気の加湿を行う。以降は、このような操作を繰り返す。   Next, when the bacteria present in the skewed honeycomb 2 are sufficiently sterilized, the supply of the hypochlorous acid aqueous solution 23 to the humidified water tank 18 is stopped, and the makeup water 22 is replenished instead. Continue to humidify the humidified air. That is, sterilization is stopped and a humidification process is performed. Then, again, when the amount of bacteria present in the skewed honeycomb 2 becomes too large, the hypochlorous acid aqueous solution 23 is supplied to the humidified water tank 18, that is, hypochlorous acid to the skewed honeycomb 2. The humidified water 30 containing is supplied, and the humidified air is humidified while sterilizing the skewed honeycomb 2. Thereafter, such an operation is repeated.

このようにして、加湿工程を行っている最中に、加湿兼除菌工程を、間欠的に繰り返し行う。   In this way, the humidification / sterilization step is intermittently repeated during the humidification step.

図3及び図4では、散水部12が、斜行ハニカム2の上面6より上に設置されている旨を示したが、散水部12の設置位置は、加湿効果が低くなり過ぎない範囲であれば、斜行ハニカム2内の上側であってもよい。   3 and 4 show that the water sprinkling part 12 is installed above the upper surface 6 of the skewed honeycomb 2, the installation position of the water sprinkling part 12 may be within a range where the humidification effect does not become too low. For example, the upper side in the skew honeycomb 2 may be used.

また、図3及び図4では、次亜塩素酸水溶液供給管21は、加湿水タンク18に繋がれる旨を示したが、本発明の空気加湿装置では、次亜塩素酸水溶液供給管21は、送水管13等の加湿水供給手段のどこかに繋がれていてもよいし、補給水補給管22に繋がれていてもよい。   3 and 4 show that the hypochlorous acid aqueous solution supply pipe 21 is connected to the humidified water tank 18, but in the air humidifier of the present invention, the hypochlorous acid aqueous solution supply pipe 21 is It may be connected somewhere in the humidification water supply means such as the water supply pipe 13 or may be connected to the makeup water supply pipe 22.

本発明の空気加湿装置のうち、次亜塩素酸水溶液供給管21が、加湿水供給手段に繋がれている形態例では、加湿兼除菌工程のときに、次亜塩素酸の濃度が高い次亜塩素酸水溶液23が、加湿水タンク18内の次亜塩素酸を含有する加湿水30で希釈される前に、斜行ハニカム2に供給されるので、除菌効率が高くなる。   In the air humidifier of the present invention, in the embodiment in which the hypochlorous acid aqueous solution supply pipe 21 is connected to the humidified water supply means, the concentration of hypochlorous acid is high in the humidification and sterilization step. Since the aqueous chlorous acid solution 23 is supplied to the skewed honeycomb 2 before being diluted with the humidified water 30 containing hypochlorous acid in the humidified water tank 18, the sterilization efficiency is increased.

また、本発明の空気加湿装置のうち、次亜塩素酸水溶液供給管21が、補給水補給管22に繋がれている形態例では、加湿兼除菌工程のときに、次亜塩素酸水溶液23は、次亜塩素酸供給管21から補給水補給管19を経て供給される。このとき、次亜塩素酸水溶液23中の次亜塩素酸濃度を調節するために、次亜塩素酸水溶液23を供給すると共に、同時に補給水22も供給することができる。   In the air humidifier of the present invention, in the embodiment in which the hypochlorous acid aqueous solution supply pipe 21 is connected to the make-up water supply pipe 22, the hypochlorous acid aqueous solution 23 is used during the humidification and sterilization step. Is supplied from the hypochlorous acid supply pipe 21 via the makeup water supply pipe 19. At this time, in order to adjust the hypochlorous acid concentration in the hypochlorous acid aqueous solution 23, the hypochlorous acid aqueous solution 23 can be supplied, and at the same time, the makeup water 22 can be supplied.

また、本発明の空気加湿装置は、図5に示す空気加湿装置20bのように、更に、斜行ハニカム2から排出される加湿水(加湿水26及び次亜塩素酸を含有する加湿水31)を受けるための加湿水受器32を有しており、加湿水受器32には、斜行ハニカム2から排出される加湿水を、加湿水タンク18に返送するための返送管27が付設されており、加湿水排出管16bが、返送管27に付設されている形態例であってもよい。空気加湿装置20bでは、返送管27には、斜行ハニカム2から排出される加湿水を、加湿水タンク18に送液するための第2ポンプ28が設置されている。また、加湿水タンク18へ加湿水の返送量と加湿水排出管16bからの加湿水の排出量の割合を調節するために、返送管27には第5弁35が、加湿水排出管16bには第2弁17bが、それぞれ付設されている。空気加湿装置20bでは、加湿水排出管16bは、加湿水受器32に直接繋がれていてもよい。   Further, the air humidifier of the present invention, like the air humidifier 20b shown in FIG. 5, is further humidified water discharged from the skewed honeycomb 2 (humidified water 26 and humidified water 31 containing hypochlorous acid). The humidifying water receiver 32 is provided with a return pipe 27 for returning the humidified water discharged from the skewed honeycomb 2 to the humidifying water tank 18. The humidified water discharge pipe 16b may be attached to the return pipe 27. In the air humidifier 20b, the return pipe 27 is provided with a second pump 28 for feeding the humidified water discharged from the skewed honeycomb 2 to the humidified water tank 18. Further, in order to adjust the ratio of the return amount of the humidified water to the humidified water tank 18 and the discharge amount of the humidified water from the humidified water discharge pipe 16b, a fifth valve 35 is provided in the return pipe 27 and the humidified water discharge pipe 16b is provided. Each has a second valve 17b. In the air humidifier 20b, the humidified water discharge pipe 16b may be directly connected to the humidified water receiver 32.

加湿兼除菌工程のときに、斜行ハニカム2から排出される加湿水31中の次亜塩素酸濃度は、加湿水タンク18内の加湿水30に比べ低い。そして、空気加湿装置20bでは、次亜塩素酸濃度が低い加湿水31から装置外へ排出されるべき加湿水を抜き出すので、加湿水タンク18内の加湿水30へ返送される加湿水31の量を少なくできるため、加湿水タンク18内の加湿水30の次亜塩素酸濃度が低くなるのを低減できる。言い換えると、装置外へ抜き出される加湿水中の次亜塩素酸濃度が低いので、次亜塩素酸の利用効率が高くなる。   During the humidification and sterilization step, the hypochlorous acid concentration in the humidified water 31 discharged from the skewed honeycomb 2 is lower than the humidified water 30 in the humidified water tank 18. And in the air humidifier 20b, since the humidified water which should be discharged | emitted out of the apparatus from the humidified water 31 with low hypochlorous acid density | concentration is extracted, the quantity of the humidified water 31 returned to the humidified water 30 in the humidified water tank 18 Therefore, the hypochlorous acid concentration of the humidified water 30 in the humidified water tank 18 can be reduced. In other words, since the hypochlorous acid concentration in the humidified water drawn out of the apparatus is low, the utilization efficiency of hypochlorous acid is increased.

本発明の空気加湿装置は、図6に示す空気加湿装置20cのように、送水管13から分岐し、且つ、斜行ハニカム2内の途中に設置される第2散水部36を有する形態例であってもよい。なお、斜行ハニカム内の途中とは、上下方向の途中のことであり、言い換えると、加湿水の流下経路の途中ということである。   The air humidifier of the present invention is an embodiment having a second water sprinkling part 36 that branches from the water supply pipe 13 and is installed in the middle of the skewed honeycomb 2 as in the air humidifier 20c shown in FIG. There may be. In the meantime, the middle in the skewed honeycomb means the middle in the vertical direction, in other words, the middle of the flow path of the humidified water.

次亜塩素酸水溶液中の次亜塩素酸は、低濃度になるほど分解し易くなる性質を有している。そして、斜行ハニカム2の下に行くほど、加湿水中の次亜塩素酸濃度が低くなる。そのため、空気加湿装置20cによれば、斜行ハニカム2内を流下することにより、次亜塩素酸濃度が低下した加湿水中の次亜塩素酸濃度を高くすることができるので、次亜塩素酸の分解を低減できる。   Hypochlorous acid in the hypochlorous acid aqueous solution has a property of being easily decomposed as the concentration becomes lower. And the hypochlorous acid density | concentration in humidified water becomes low, so that it goes under the skewed honeycomb 2. Therefore, according to the air humidifier 20c, the hypochlorous acid concentration in the humidified water in which the hypochlorous acid concentration has decreased can be increased by flowing down in the oblique honeycomb 2, so that hypochlorous acid Degradation can be reduced.

本発明の空気加湿方法により得られる加湿空気の温度は、通常、被加湿空気の温度とほぼ同等か又は少し低い温度となる。また、本発明の空気加湿方法では、得られる加湿空気の湿度は、加湿水の量や斜行ハニカムの材質又は設計条件等に異なるが、概ね相対湿度は100%に近い値となる。そして、加湿空気の湿度及び温度は、被加湿空気の湿度及び温度、被加湿空気の供給風量、加湿水の供給量及び温度、斜行ハニカムの大きさ、斜行ハニカムを構成する波形シートの材質及び形状、波形シートの積層の仕方等により、若干変化する。そのため、本発明の空気加湿方法では、加湿空気が供給される空間で要求される湿度及び温度に応じて、その要求値の湿度及び温度となるように、被加湿空気の湿度及び温度、被加湿空気の供給風量、加湿水の供給量及び温度、斜行ハニカムの大きさ、斜行ハニカムを構成する波形シートの材質及び形状、波形シートの積層の仕方等を、適宜選択することが好ましい。なお、加湿空気の温度を調節するためには、空気加湿装置の前段にクーラーやヒーターを設置すること、あるいは、空気加湿装置の後段にヒーターを設置することができる。   The temperature of the humidified air obtained by the air humidification method of the present invention is usually substantially the same as or slightly lower than the temperature of the humidified air. In the air humidification method of the present invention, the humidity of the humidified air obtained varies depending on the amount of humidified water, the material of the skewed honeycomb, the design conditions, and the like, but the relative humidity is generally a value close to 100%. The humidity and temperature of the humidified air are the humidity and temperature of the humidified air, the supply air volume of the humidified air, the supply amount and temperature of the humidified water, the size of the skewed honeycomb, and the corrugated sheet material constituting the skewed honeycomb. It varies slightly depending on the shape, how the corrugated sheets are laminated, and the like. Therefore, in the air humidification method of the present invention, according to the humidity and temperature required in the space to which the humidified air is supplied, the humidity and temperature of the humidified air and the humidified humidity are set so that the required humidity and temperature are obtained. It is preferable to appropriately select the air supply air volume, the supply amount and temperature of the humidified water, the size of the skewed honeycomb, the material and shape of the corrugated sheets constituting the skewed honeycomb, the manner of stacking the corrugated sheets, and the like. In addition, in order to adjust the temperature of humidified air, a cooler or a heater can be installed in the front | former stage of an air humidifier, or a heater can be installed in the back | latter stage of an air humidifier.

加湿工程及び加湿兼除菌工程において、被加湿空気は、屋外空気又は屋内空気であり、被加湿空気の温度は、通常0〜50℃である。   In the humidification step and the humidification / sterilization step, the humidified air is outdoor air or indoor air, and the temperature of the humidified air is usually 0 to 50 ° C.

加湿工程及び加湿兼除菌工程における斜行ハニカムへの被加湿空気の供給風量は、斜行ハニカムの前面(被加湿空気が供給される面)の単位面積当たり単位時間当たり、5m/秒/m(斜行ハニカムの前面)以下、好ましくは0.5〜3.5m/秒/m(斜行ハニカムの前面)である。 The amount of humidified air supplied to the skewed honeycomb in the humidifying step and the humidifying / sterilizing step is 5 m 3 / second / unit time per unit area of the front surface of the skewed honeycomb (surface to which the humidified air is supplied). m 2 (front surface of the skewed honeycomb) or less, preferably 0.5 to 3.5 m 3 / second / m 2 (front surface of the skewed honeycomb).

加湿工程で斜行ハニカムに供給される加湿水としては、特に制限されず、水道水、工業用水、井戸水、地下水等が挙げられる。また、次亜塩素酸を含有する加湿水の次亜塩素酸が溶解されている水としては、特に制限されず、水道水、工業用水、井戸水、地下水等が挙げられる。   The humidifying water supplied to the oblique honeycomb in the humidifying step is not particularly limited, and examples thereof include tap water, industrial water, well water, and ground water. In addition, the water in which the hypochlorous acid containing humidified water containing hypochlorous acid is dissolved is not particularly limited, and examples thereof include tap water, industrial water, well water, and groundwater.

加湿工程における斜行ハニカム内への加湿水の供給量は、斜行ハニカムの上面(加湿水が供給される面)の単位面積当たり単位時間当たり、2〜100L/分/m(斜行ハニカムの上面)、好ましくは5〜80L/分/m(斜行ハニカムの上面)、特に好ましくは10〜60L/分/m(斜行ハニカムの上面)である。また、加湿兼除菌工程における斜行ハニカム内への次亜塩素酸を含有する加湿水の供給量は、斜行ハニカムの上面(次亜塩素酸を含有する加湿水が供給される上面)の単位面積当たり単位時間当たり、2〜100L/分/m(斜行ハニカムの上面)、好ましくは5〜80L/分/m(斜行ハニカムの上面)、特に好ましくは10〜60L/分/m(斜行ハニカムの上面)である。 The amount of humidified water supplied into the skewed honeycomb in the humidification step is 2 to 100 L / min / m 2 per unit area per unit area of the upper surface of the skewed honeycomb (surface to which the humidified water is supplied) (skewed honeycomb) , Preferably 5 to 80 L / min / m 2 (upper surface of the skewed honeycomb), particularly preferably 10 to 60 L / min / m 2 (upper surface of the skewed honeycomb). Further, the amount of humidified water containing hypochlorous acid into the skewed honeycomb in the humidifying and sterilizing step is the upper surface of the skewed honeycomb (upper surface to which humidified water containing hypochlorous acid is supplied). Per unit time per unit area, 2 to 100 L / min / m 2 (upper surface of the skewed honeycomb), preferably 5 to 80 L / min / m 2 (upper surface of the skewed honeycomb), particularly preferably 10 to 60 L / min / m 2 (upper surface of the skewed honeycomb).

加湿工程において、加湿水の温度は、0℃より高く且つ45℃以下、好ましくは5〜40℃である。また、加湿兼除菌工程において、次亜塩素酸を含有する加湿水の温度は、5〜45℃、好ましくは10〜40℃である。   In the humidification step, the temperature of the humidified water is higher than 0 ° C and not higher than 45 ° C, preferably 5 to 40 ° C. In the humidification and sterilization step, the temperature of the humidified water containing hypochlorous acid is 5 to 45 ° C, preferably 10 to 40 ° C.

加湿工程及び加湿兼除菌工程では、斜行ハニカムの上面より上から加湿水又は次亜塩素酸を含有する加湿水を供給してもよいし、あるいは、加湿効果が低くなり過ぎない範囲であれば、斜行ハニカム内から供給してもよい。つまり、加湿工程及び加湿兼除菌工程では、斜行ハニカムの上部より、加湿水又は次亜塩素酸を含有する加湿水を供給する。   In the humidifying step and the humidifying / sterilizing step, humidified water or humidified water containing hypochlorous acid may be supplied from above the upper surface of the skewed honeycomb, or the humidifying effect may not be too low. For example, it may be supplied from within the skewed honeycomb. That is, in the humidification step and the humidification / sterilization step, humidified water or humidified water containing hypochlorous acid is supplied from the upper part of the skewed honeycomb.

加湿工程において、補給水の補給量が、被加湿空気の加湿に使用される加湿水の量(加湿水の一部を排出する場合は、被加湿空気の加湿に使用される加湿水の量及び加湿水の排出量の合計量)と同じになるように、補給水の補給量を設定する。また、加湿兼除菌工程において、次亜塩素酸水溶液の供給量が、被加湿空気の加湿に使用される次亜塩素酸を含有する加湿水の量(次亜塩素酸を含有する加湿水の一部を排出する場合は、被加湿空気の加湿に使用される次亜塩素酸を含有する加湿水の量及び次亜塩素酸を含有する加湿水の排出量の合計量)と同じになるように、次亜塩素酸水溶液の供給量を設定する。   In the humidification step, the replenishment water supply amount is the amount of humidification water used to humidify the humidified air (if part of the humidification water is discharged, the amount of humidification water used to humidify the humidified air and Set the replenishment water replenishment amount so that it is the same as the total amount of humidified water discharge. In addition, in the humidification and sterilization process, the amount of hypochlorous acid aqueous solution supplied is the amount of humidified water containing hypochlorous acid used for humidifying humidified air (humidified water containing hypochlorous acid). When a part of the water is discharged, the total amount of humidified water containing hypochlorous acid and humidified water containing hypochlorous acid used to humidify the humidified air is the same as The amount of hypochlorous acid aqueous solution supplied is set.

加湿兼除菌工程において、次亜塩素酸を含有する加湿水中の次亜塩素酸濃度は、斜行ハニカムに存在している菌を除菌できる範囲で、適宜選択される。例えば、本発明の空気加湿装置を用いて、本発明の空気加湿方法を行う場合は、次亜塩素酸水溶液中の次亜塩素酸濃度を適宜選択することにより、次亜塩素酸を含有する加湿水中の次亜塩素酸濃度を調節する。   In the humidification and sterilization step, the hypochlorous acid concentration in the humidified water containing hypochlorous acid is appropriately selected within a range in which the bacteria present in the skewed honeycomb can be sterilized. For example, when performing the air humidification method of the present invention using the air humidifier of the present invention, the humidification containing hypochlorous acid is appropriately selected by appropriately selecting the concentration of hypochlorous acid in the hypochlorous acid aqueous solution. Adjust hypochlorous acid concentration in water.

加湿兼除菌工程では、斜行ハニカムに存在している菌の除菌が可能となる加湿水中の次亜塩素酸濃度は、0.4mg/L以上、好ましくは1〜80mg/L、特に好ましくは2〜30mg/Lである。   In the humidification and sterilization step, the hypochlorous acid concentration in the humidified water that enables sterilization of the bacteria present in the skewed honeycomb is 0.4 mg / L or more, preferably 1 to 80 mg / L, particularly preferably. Is 2-30 mg / L.

加湿兼除菌工程の開始直後は、加湿水中の次亜塩素酸が除菌に消費されるために、斜行ハニカムから排出される加湿水中の次亜塩素酸濃度は、非常に低い。そして、加湿兼除菌工程を続けると、斜行ハニカム内の除菌が進み、斜行ハニカム内の除菌が、ほぼ終了すると、斜行ハニカムの下面から排出される加湿水中の次亜塩素酸濃度が、0.4mg/L以上、好ましくは1〜80mg/L、特に好ましくは2〜30mg/Lとなる。そのため、加湿兼除菌工程では、少なくとも、斜行ハニカムから排出される加湿水中の次亜塩素酸濃度が、0.4mg/L以上、好ましくは1〜80mg/L、特に好ましくは2〜30mg/Lとなるまで、斜行ハニカムに次亜塩素酸を含有する加湿水を供給する。斜行ハニカムの下面から排出される加湿水中の次亜塩素酸濃度が、0.4mg/L以上、好ましくは1〜80mg/L、特に好ましくは2〜30mg/Lとなるまで、加湿兼除菌工程を行うことにより、斜行ハニカム全体を除菌することができる。なお、斜行ハニカム全体の除菌を確実にするために、斜行ハニカムから排出される加湿水中の次亜塩素酸濃度が、0.4mg/L以上、好ましくは1〜80mg/L、特に好ましくは2〜30mg/Lとなった後も、一定時間、斜行ハニカムに次亜塩素酸を含有する加湿水を供給してもよい。   Immediately after the start of the humidification and sterilization step, hypochlorous acid in the humidified water is consumed for sterilization, so the concentration of hypochlorous acid in the humidified water discharged from the skewed honeycomb is very low. Then, if the humidification and sterilization process is continued, sterilization in the skewed honeycomb proceeds, and when sterilization in the skewed honeycomb is almost finished, hypochlorous acid in the humidified water discharged from the lower surface of the skewed honeycomb The concentration is 0.4 mg / L or more, preferably 1 to 80 mg / L, particularly preferably 2 to 30 mg / L. Therefore, in the humidification and sterilization step, at least the hypochlorous acid concentration in the humidified water discharged from the skewed honeycomb is 0.4 mg / L or more, preferably 1 to 80 mg / L, particularly preferably 2 to 30 mg / L. Until it becomes L, humidified water containing hypochlorous acid is supplied to the skewed honeycomb. Humidification and sterilization until the concentration of hypochlorous acid in the humidified water discharged from the lower surface of the skewed honeycomb becomes 0.4 mg / L or more, preferably 1 to 80 mg / L, particularly preferably 2 to 30 mg / L. By performing the process, the entire oblique honeycomb can be sterilized. In order to ensure the sterilization of the entire skewed honeycomb, the hypochlorous acid concentration in the humidified water discharged from the skewed honeycomb is 0.4 mg / L or more, preferably 1 to 80 mg / L, particularly preferably. May be supplied with humidified water containing hypochlorous acid to the skewed honeycomb for a certain period of time after reaching 2 to 30 mg / L.

また、加湿兼除菌工程では、次亜塩素酸を含有する加湿水中の次亜塩素酸は、菌を除菌することによって消失する他、菌がなくとも、被加湿空気を通風下で斜行ハニカム内を加湿水が流下するだけで、加湿水中から次亜塩素酸が消失する。つまり、斜行ハニカムに菌が存在していない状態(以下、無菌状態とも記載する。)でも、次亜塩素酸を含有する加湿水が、斜行ハニカムを流下することにより、次亜塩素酸を含有する加湿水中の次亜塩素酸濃度が低減する。なお、本発明では、無菌状態とは、斜行ハニカムに付着している菌の量が、50CFU/100cm未満の状態を指す。また、本発明では、斜行ハニカムに次亜塩素酸を含有する加湿水を供給し続けて除菌を行い、斜行ハニカムの下面から排出される加湿水中の次亜塩素酸濃度が、少なくとも0.4mg/L以上となったときの斜行ハニカムの状態が、無菌状態である。 In addition, in the humidification and sterilization process, hypochlorous acid in humidified water containing hypochlorous acid disappears by sterilizing the bacteria, and even if there are no bacteria, the humidified air is slanted under ventilation. Hypochlorous acid disappears from the humidified water simply by flowing the humidified water through the honeycomb. That is, even in a state where bacteria are not present in the skewed honeycomb (hereinafter also referred to as a sterile state), the humidified water containing hypochlorous acid flows down the skewed honeycomb, so that hypochlorous acid is removed. Hypochlorous acid concentration in the humidified water is reduced. In the present invention, the aseptic condition refers to a condition where the amount of bacteria attached to the skewed honeycomb is less than 50 CFU / 100 cm 2 . Further, in the present invention, sterilization is performed by continuously supplying humidified water containing hypochlorous acid to the skewed honeycomb, and the concentration of hypochlorous acid in the humidified water discharged from the lower surface of the skewed honeycomb is at least 0. The state of the skewed honeycomb when it becomes 4 mg / L or more is aseptic.

そのため、該加湿兼除菌工程では、斜行ハニカムに供給される加湿水中の次亜塩素酸濃度は、少なくとも、通風下で斜行ハニカム内を流下するだけで、加湿水中から消失する次亜塩素酸濃度の低減量に、0.4mg/L以上、好ましくは1〜80mg/L、特に好ましくは2〜30mg/Lを、加算した濃度であることが必要である。例えば、無菌状態の斜行ハニカムに、被加湿空気を5m/秒/mで供給しながら、次亜塩素酸を含有する加湿水を供給する場合、斜行ハニカム内を流下したときの次亜塩素酸濃度の低減量が、0.5mg/Lであるとすると、被加湿空気の供給条件が5m/秒/mのときに、斜行ハニカムに供給する加湿水中の濃度は、「0.5mg/L+0.4mg/L=0.9mg/L以上」、好ましくは「0.5mg/L+1〜80mg/L=1.5〜80.5mg/L」、特に好ましくは「0.5mg/L+2〜30mg/L=2.5〜30.5mg/L」必要である。 Therefore, in the humidification and sterilization step, the hypochlorous acid concentration in the humidified water supplied to the skewed honeycomb is at least a hypochlorite that disappears from the humidified water only by flowing down in the skewed honeycomb under ventilation. The acid concentration must be reduced by adding 0.4 mg / L or more, preferably 1 to 80 mg / L, particularly preferably 2 to 30 mg / L. For example, when supplying humidified water containing hypochlorous acid while supplying humidified air at a rate of 5 m 3 / sec / m 2 to a sterile skewed honeycomb, Assuming that the reduction amount of chlorous acid concentration is 0.5 mg / L, when the supply condition of humidified air is 5 m 3 / sec / m 2 , the concentration of the humidified water supplied to the skewed honeycomb is “ 0.5 mg / L + 0.4 mg / L = 0.9 mg / L or more ”, preferably“ 0.5 mg / L + 1-80 mg / L = 1.5-80.5 mg / L ”, particularly preferably“ 0.5 mg / L L + 2-30 mg / L = 2.5-30.5 mg / L ”is necessary.

斜行ハニカム内を流下したときの次亜塩素酸濃度の低減量は、主に、斜行ハニカムの高さ、幅、奥行等の斜行ハニカムの形態や、被加湿空気の供給風量、加湿水の供給量等の運転条件により異なる。そのため、斜行ハニカム内を流下したときの次亜塩素酸濃度の低減量を把握する方法としては、例えば、先ず、斜行ハニカムに次亜塩素酸を含有する加湿水を供給して、予め除菌を行い、斜行ハニカムを無菌状態とする。次いで、空気加湿装置の運転条件で、被加湿空気の供給及び次亜塩素酸を含有する加湿水を供給し、斜行ハニカムの下面から排出される加湿水中の次亜塩素酸濃度を測定する。そして、斜行ハニカムに供給した加湿水中の次亜塩素酸濃度から、斜行ハニカムの下面から排出される加湿水中の次亜塩素酸濃度を減じた値が、斜行ハニカム内を流下したときの次亜塩素酸濃度の低減量である。   The amount of hypochlorous acid concentration when flowing down in the skewed honeycomb mainly depends on the shape of the skewed honeycomb such as the height, width and depth of the skewed honeycomb, the supply air volume of humidified air, and the humidified water. It depends on the operating conditions such as the amount of supply. For this reason, as a method for grasping the amount of reduction in hypochlorous acid concentration when flowing down in the skewed honeycomb, for example, first, humidified water containing hypochlorous acid is supplied to the skewed honeycomb to remove it in advance. Bacteria are sterilized to make the skewed honeycomb aseptic. Next, under the operating conditions of the air humidifier, humidified air is supplied and humidified water containing hypochlorous acid is supplied, and the concentration of hypochlorous acid in the humidified water discharged from the lower surface of the skewed honeycomb is measured. The value obtained by subtracting the hypochlorous acid concentration in the humidified water discharged from the lower surface of the skewed honeycomb from the hypochlorous acid concentration in the humidified water supplied to the skewed honeycomb flows down in the skewed honeycomb. This is a reduction in hypochlorous acid concentration.

そして、先ず、斜行ハニカムの形状及び空気加湿装置の運転条件を決定し、次いで、その運転条件で斜行ハニカム内を流下したときの次亜塩素酸濃度の低減量(A(mg/L))を求め、次いで、斜行ハニカムの下面から排出される加湿水中の次亜塩素酸濃度(B(mg/L))を決定し、そして、斜行ハニカムの下面から排出される加湿水中の次亜塩素酸濃度の値に、斜行ハニカム内を流下したときの次亜塩素酸濃度の低減量を加算した値(A+B)を、斜行ハニカムに供給する加湿水中の次亜塩素酸濃度とする。このようにして、運転条件を設計する。   First, the shape of the skewed honeycomb and the operating condition of the air humidifier are determined, and then the amount of hypochlorous acid reduced (A (mg / L) when flowing through the skewed honeycomb under the operating condition ), And then the hypochlorous acid concentration (B (mg / L)) in the humidified water discharged from the lower surface of the skewed honeycomb is determined, and the next in the humidified water discharged from the lower surface of the skewed honeycomb A value (A + B) obtained by adding the amount of reduction of hypochlorous acid concentration when flowing down in the skewed honeycomb to the value of chlorous acid concentration is the hypochlorous acid concentration in the humidified water supplied to the skewed honeycomb. . In this way, operating conditions are designed.

斜行ハニカムに供給する加湿水中の次亜塩素酸濃度は、斜行ハニカムの形状や空気加湿装置の運転条件等により、適宜選択されるが、概ね0.4mg/L以上、好ましくは1〜80mg/L、特に好ましくは2〜30mg/Lである。   The concentration of hypochlorous acid in the humidified water supplied to the skewed honeycomb is appropriately selected depending on the shape of the skewed honeycomb, the operating conditions of the air humidifier, etc., but is generally about 0.4 mg / L or more, preferably 1 to 80 mg. / L, particularly preferably 2 to 30 mg / L.

また、本発明の空気加湿装置を用いて、本発明の空気加湿方法を行う場合は、加湿水タンクに、次亜塩素酸水溶液を供給すると共に、加湿水排出管から、加湿水の一部を排出することにより、徐々に、加湿水タンク内の加湿水中の次亜塩素酸濃度が高くなっていき、特定の濃度でバランスする。よって、斜行ハニカム内を流下したときの次亜塩素酸濃度の低減量を考慮して、バランス時の斜行ハニカムに供給する次亜塩素酸を含有する加湿水中の次亜塩素酸濃度が、斜行ハニカム全体の除菌が可能となる濃度となるように、次亜塩素酸水溶液中の次亜塩素酸濃度を適宜選択する。   In addition, when performing the air humidification method of the present invention using the air humidifier of the present invention, a hypochlorous acid aqueous solution is supplied to the humidified water tank and a part of the humidified water is discharged from the humidified water discharge pipe. By discharging, the concentration of hypochlorous acid in the humidified water in the humidified water tank gradually increases and balances at a specific concentration. Therefore, considering the amount of reduction in hypochlorous acid concentration when flowing down in the skewed honeycomb, the concentration of hypochlorous acid in the humidified water containing hypochlorous acid supplied to the skewed honeycomb at the time of balance is The concentration of hypochlorous acid in the hypochlorous acid aqueous solution is appropriately selected so that the concentration becomes such that the entire skewed honeycomb can be sterilized.

該加湿兼除菌工程では、斜行ハニカムの下面から排出される加湿水を、加湿水タンクへ返送して、再度、斜行ハニカムに供給する次亜塩素酸を含有する加湿水として使用してもよいし(循環式)、あるいは、斜行ハニカムの下面から排出される加湿水を、加湿水タンクへは返送せずに、装置外へ排出してもよい(非循環掛け流し式)。   In the humidification and sterilization step, the humidified water discharged from the lower surface of the skewed honeycomb is returned to the humidified water tank and used again as the humidified water containing hypochlorous acid supplied to the skewed honeycomb. Alternatively, the humidified water discharged from the lower surface of the skewed honeycomb may be discharged out of the apparatus without returning to the humidified water tank (non-circulating flushing type).

本発明の空気加湿方法では、加湿工程を行っている最中に、例えば、100時間毎に、加湿兼除菌工程を1時間行うとのように、間欠的に加湿兼除菌工程を繰り返し行う。つまり、この形態例では、斜行ハニカムには、加湿水25を99時間供給→次亜塩素酸を含有する加湿水30を1時間供給→加湿水25を99時間供給→次亜塩素酸を含有する加湿水30を1時間供給→・・・とのようにして、空気加湿方法を行う。なお、間欠的にとは、一定の時間を隔ててということである。また、加湿兼除菌工程を行う時間及び時期は、斜行ハニカムに存在する菌の増加量により、適宜選択される。   In the air humidification method of the present invention, during the humidification process, the humidification and sterilization process is repeated intermittently, for example, every 100 hours, the humidification and sterilization process is performed for one hour. . That is, in this embodiment, the slanted honeycomb is supplied with the humidified water 25 for 99 hours → supplied with the humidified water 30 containing hypochlorous acid for 1 hour → supplied with the humidified water 25 for 99 hours → contains hypochlorous acid. The humidifying water 30 to be supplied is supplied for 1 hour, and then the air humidifying method is performed. The term “intermittently” means that a certain time is taken. In addition, the time and timing for performing the humidification and sterilization step are appropriately selected depending on the increase in the number of bacteria present in the skewed honeycomb.

本発明の空気加湿方法及び本発明の空気加湿装置によれば、斜行ハニカムの除菌を行っている間も、被加湿空気の加湿を行うことができるので、斜行ハニカムの除菌のときに、被加湿空気の加湿を止めなくてもよい。また、本発明の空気加湿方法及び本発明の空気加湿装置によれば、斜行ハニカムを乾燥させることなく、斜行ハニカムの除菌を行うことができるので、臭気の問題が発生しない。   According to the air humidification method of the present invention and the air humidification apparatus of the present invention, the humidified air can be humidified while the skewed honeycomb is being sterilized. Furthermore, it is not necessary to stop humidification of the humidified air. Moreover, according to the air humidification method of the present invention and the air humidification apparatus of the present invention, since the skewed honeycomb can be sterilized without drying the skewed honeycomb, the problem of odor does not occur.

次に、実施例を挙げて本発明を更に具体的に説明するが、これは単に例示であって、本発明を制限するものではない。   EXAMPLES Next, although an Example is given and this invention is demonstrated more concretely, this is only an illustration and does not restrict | limit this invention.

<空気加湿装置>
図3に示す構成で、斜行ハニカムとして下記斜行ハニカムAが奥行き方向に2つ設置されている空気加湿装置A(斜行ハニカム設置部位の幅500mm×高さ250mm×奥行200mm)と、下記斜行ハニカムBが高さ方向に3つ設置されている空気加湿装置B(斜行ハニカム設置部位の幅500mm×高さ1500mm×奥行100mm)と、を作製した。
<Air humidifier>
In the configuration shown in FIG. 3, an air humidifier A (width 500 mm × height 250 mm × depth 200 mm of the skewed honeycomb installed portion) in which two skewed honeycombs A described below are installed in the depth direction as the skewed honeycomb, An air humidifier B in which three skew honeycombs B were installed in the height direction (width of the skew honeycomb installation portion 500 mm × height 1500 mm × depth 100 mm) was produced.

<斜行ハニカムA>
・無機繊維基材シート:ガラス繊維からなり、結合材としてアルミナゾル、充填材としてアルミナ水和物を使用、空隙率75%、厚み0.5mm
・セルピッチ10mm、セル山高さ5mm
・稜線角X:30度、稜線角X:30度、稜線の交差角Y:60度
・斜行ハニカムの幅:500mm、斜行ハニカムの高さ:250mm、斜行ハニカムの奥行:100mm
<Slanted honeycomb A>
Inorganic fiber base sheet: made of glass fiber, using alumina sol as a binder and alumina hydrate as a filler, porosity 75%, thickness 0.5 mm
・ Cell pitch 10mm, cell peak height 5mm
・ Ridge angle X 1 : 30 degrees, Ridge angle X 2 : 30 degrees, Intersection angle Y of ridge line: 60 degrees ・ Width of skewed honeycomb: 500 mm, height of skewed honeycomb: 250 mm, depth of skewed honeycomb: 100 mm

<斜行ハニカムB>
・無機繊維基材シート:ガラス繊維からなり、結合材としてアルミナゾル、充填材としてアルミナ水和物を使用、空隙率75%、厚み0.5mm
・セルピッチ10mm、セル山高さ5mm
・稜線角X:30度、稜線角X:30度、稜線の交差角Y:60度
・斜行ハニカムの幅:500mm、斜行ハニカムの高さ:500mm、斜行ハニカムの奥行:100mm
<Slanted honeycomb B>
Inorganic fiber base sheet: made of glass fiber, using alumina sol as a binder and alumina hydrate as a filler, porosity 75%, thickness 0.5 mm
・ Cell pitch 10mm, cell peak height 5mm
Edge line angle X 1 : 30 degrees, Edge line angle X 2 : 30 degrees, Intersection angle Y of edge line: 60 degrees ・ Width of skew honeycomb: 500 mm, height of skew honeycomb: 500 mm, depth of skew honeycomb: 100 mm

<斜行ハニカムの付着菌量の測定>
斜行ハニカムの通風面100cmの付着菌を滅菌綿棒による拭き取り検査法により採取し、生理食塩水で希釈し、定量試験を行った。細菌を標準寒天培地で30℃で1週間培養後、真菌をポテトデキストロース寒天培地で25℃で1週間培養後に、菌数測定を行った。なお、斜行ハニカムの付着菌量の測定では、斜行ハニカムの前面側(被加湿空気の入口側の面)の付着菌を採取した。また、菌の上下方向の採取位置は、斜行ハニカムの下側から20mmの位置から、斜行ハニカムの下側から120mmの位置までの100mmの範囲であり、左右方向の採取位置は、加湿兼除菌工程を行う前が、左右方向の中心から右へ100mmの位置までの100mmの範囲、加湿兼除菌工程行った後が、左右方向の中心から左へ100mmの位置までの100mmの範囲である(縦100mm×横100mm)。
<加湿水中の次亜塩素酸濃度の測定>
吸光光度法であるDPD(ジエチル−p−フェニレン−ジアミン)法を用いて測定した。
<Measurement of amount of bacteria attached to skew honeycomb>
Adherent bacteria having a ventilation surface of 100 cm 2 on the slanted honeycomb were collected by a wiping inspection method using a sterile cotton swab, diluted with physiological saline, and subjected to a quantitative test. Bacteria were cultured on a standard agar medium at 30 ° C. for 1 week, and fungi were cultured on a potato dextrose agar medium at 25 ° C. for 1 week. In the measurement of the amount of adherent bacteria on the skewed honeycomb, the adherent bacteria on the front side of the skewed honeycomb (surface on the inlet side of the humidified air) were collected. Further, the sampling position in the vertical direction of the bacteria is in a range of 100 mm from the position 20 mm from the lower side of the skewed honeycomb to the position 120 mm from the lower side of the skewed honeycomb. Before performing the sterilization process, the range of 100 mm from the center in the left-right direction to the position of 100 mm to the right, and after performing the humidification and sterilization process, in the range of 100 mm from the center of the left-right direction to the position of 100 mm to the left. Yes (length 100mm x width 100mm).
<Measurement of hypochlorous acid concentration in humidified water>
It measured using DPD (diethyl-p-phenylene-diamine) method which is an absorptiometric method.

(実施例1)
予め、空気加湿装置Aにて加湿運転を行い、斜行ハニカムに菌を付着させた。このときの斜行ハニカムの付着菌量は、細菌が14000CFU/100cm、真菌が3400CFU/100cmであった。
Example 1
Humidification operation was performed in advance with the air humidifier A, and bacteria were attached to the skewed honeycomb. At this time, the amount of bacteria attached to the skewed honeycomb was 14000 CFU / 100 cm 2 for bacteria and 3400 CFU / 100 cm 2 for fungi.

<加湿兼除菌工程>
斜行ハニカムの付着菌量が上記量である空気加湿装置Aを用い、斜行ハニカムに、12.6℃の被加湿空気を、2.5m/秒/m(斜行ハニカムの前面の単位面積当たり)で、次亜塩素酸濃度が6.4mg/Lの次亜塩素酸を含有する加湿水(10.3℃)を、60L/分/m(斜行ハニカムの上面の単位面積当たり)で、1時間供給した。このとき、斜行ハニカムの下面から排出される加湿水を、加湿水タンクに戻さずに、全て装置外へ排出した(非循環掛け流し式)。1時間後の斜行ハニカムの付着菌量は、細菌が50CFU/100cm未満、真菌が50CFU/100cm未満、斜行ハニカムの下面から排出される加湿水中の次亜塩素酸濃度が5.3mg/Lであった。
<Humidification and sterilization process>
Using the air humidifier A in which the amount of bacteria attached to the skewed honeycomb is the above amount, humidified air at 12.6 ° C. was applied to the skewed honeycomb at 2.5 m 3 / sec / m 2 (on the front surface of the skewed honeycomb). Humidified water (10.3 ° C.) containing hypochlorous acid having a concentration of hypochlorous acid of 6.4 mg / L per unit area, 60 L / min / m 2 (unit area on the upper surface of the skewed honeycomb) And fed for 1 hour. At this time, all of the humidified water discharged from the lower surface of the skewed honeycomb was discharged outside the apparatus without returning to the humidified water tank (non-circulating flushing type). 1 hour deposition amount of bacteria of the oblique honeycomb after the bacteria is less than 50 CFU / 100 cm 2, less than 2 fungi 50 CFU / 100 cm, the concentration of hypochlorous acid in the humidifying water discharged from the lower surface of the oblique honeycomb is 5.3mg / L.

(実施例2)
予め、空気加湿装置Aにて加湿運転を行い、斜行ハニカムに菌を付着させた。このときの斜行ハニカムの付着菌量は、細菌が32000CFU/100cm、真菌が3100CFU/100cmであった。
<加湿兼除菌工程>
斜行ハニカムの付着菌量が上記量である空気加湿装置Aを用い、斜行ハニカムに、13.7℃の被加湿空気を、2.5m/秒/m(斜行ハニカムの前面の単位面積当たり)で、次亜塩素酸濃度が0.94mg/Lの次亜塩素酸を含有する加湿水(10.8℃)を、60L/分/m(斜行ハニカムの上面の単位面積当たり)で、1時間供給した。このとき、斜行ハニカムの下面から排出される加湿水を、加湿水タンクに戻さずに、全て装置外へ排出した(非循環掛け流し式)。1時間後の斜行ハニカムの付着菌量は、細菌が50CFU/100cm未満、真菌が50CFU/100cm未満、斜行ハニカムの下面から排出される加湿水中の次亜塩素酸濃度が0.63mg/Lであった。
(Example 2)
Humidification operation was performed in advance with the air humidifier A, and bacteria were attached to the skewed honeycomb. At this time, the amount of bacteria adhered to the skewed honeycomb was 32000 CFU / 100 cm 2 for bacteria and 3100 CFU / 100 cm 2 for fungi.
<Humidification and sterilization process>
Using the air humidifier A in which the amount of bacteria attached to the skewed honeycomb is the above amount, humidified air at 13.7 ° C. is applied to the skewed honeycomb at 2.5 m 3 / sec / m 2 (on the front surface of the skewed honeycomb). Humidified water (10.8 ° C.) containing hypochlorous acid having a hypochlorous acid concentration of 0.94 mg / L per unit area, 60 L / min / m 2 (unit area on the upper surface of the skewed honeycomb) And fed for 1 hour. At this time, all of the humidified water discharged from the lower surface of the skewed honeycomb was discharged outside the apparatus without returning to the humidified water tank (non-circulating flushing type). 1 hour deposition amount of bacteria of the oblique honeycomb after the bacteria is less than 50 CFU / 100 cm 2, less than 2 fungi 50 CFU / 100 cm, the concentration of hypochlorous acid in the humidifying water discharged from the lower surface of the oblique honeycomb is 0.63mg / L.

(実施例3)
予め、空気加湿装置Bにて加湿運転を行い、斜行ハニカムに菌を付着させた。このときの斜行ハニカムの付着菌量は、細菌が76000CFU/100cm、真菌が400CFU/100cmであった。
(Example 3)
In advance, a humidification operation was performed with the air humidifier B to attach bacteria to the skewed honeycomb. At this time, the amount of bacteria attached to the skewed honeycomb was 76000 CFU / 100 cm 2 for bacteria and 400 CFU / 100 cm 2 for fungi.

<加湿兼除菌工程>
斜行ハニカムの付着菌量が上記量である空気加湿装置Bを用い、斜行ハニカムに、30.2℃の被加湿空気を、0.7m/秒/m(斜行ハニカムの前面の単位面積当たり)で、次亜塩素酸濃度が4.23mg/Lの次亜塩素酸を含有する加湿水(25.2℃)を、60L/分/m(斜行ハニカムの上面の単位面積当たり)で、20分間供給した。このとき、斜行ハニカムの下面から排出される加湿水を、加湿水タンクに戻さずに、全て装置外へ排出した(非循環掛け流し式)。20分後の斜行ハニカムの付着菌量は、細菌が50CFU/100cm未満、真菌が50CFU/100cm未満、斜行ハニカムの下面から排出される加湿水中の次亜塩素酸濃度が2.49mg/Lであった。
<Humidification and sterilization process>
Using the air humidifier B in which the amount of bacteria attached to the skewed honeycomb is the above amount, humid air at 30.2 ° C. was applied to the skewed honeycomb at 0.7 m 3 / sec / m 2 (on the front surface of the skewed honeycomb). Per unit area) humidified water (25.2 ° C.) containing hypochlorous acid having a hypochlorous acid concentration of 4.23 mg / L was added at 60 L / min / m 2 (unit area on the upper surface of the skewed honeycomb). And fed for 20 minutes. At this time, all of the humidified water discharged from the lower surface of the skewed honeycomb was discharged outside the apparatus without returning to the humidified water tank (non-circulating flushing type). Adhering bacteria of the oblique honeycomb after 20 minutes, the bacteria is less than 50 CFU / 100 cm 2, less than 2 fungi 50 CFU / 100 cm, the concentration of hypochlorous acid in the humidifying water discharged from the lower surface of the oblique honeycomb is 2.49mg / L.

(実施例4)
予め、空気加湿装置Bにて加湿運転を行い、斜行ハニカムに菌を付着させた。このときの斜行ハニカムの付着菌量は、細菌が3700CFU/100cm、真菌が250CFU/100cmであった。
Example 4
In advance, a humidification operation was performed with the air humidifier B to attach bacteria to the skewed honeycomb. The amount of bacteria attached to the skewed honeycomb at this time was 3700 CFU / 100 cm 2 for bacteria and 250 CFU / 100 cm 2 for fungi.

<加湿兼除菌工程>
斜行ハニカムの付着菌量が上記量である空気加湿装置Bを用い、斜行ハニカムに、22.7℃の被加湿空気を、2.5m/秒/m(斜行ハニカムの前面の単位面積当たり)で、次亜塩素酸濃度が3.93mg/Lの次亜塩素酸を含有する加湿水12.6℃を、60L/分/m(斜行ハニカムの上面の単位面積当たり)で、1時間供給した。このとき、斜行ハニカムの下面から排出される加湿水を、加湿水タンクに戻さずに、全て装置外へ排出した(非循環掛け流し式)。1時間後の斜行ハニカムの付着菌量は、細菌が50CFU/100cm未満、真菌が50CFU/100cm未満、斜行ハニカムの下面から排出される加湿水中の次亜塩素酸濃度が1.05mg/Lであった。
<Humidification and sterilization process>
Using the air humidifier B in which the amount of bacteria attached to the skewed honeycomb is the above amount, humidified air at 22.7 ° C. was applied to the skewed honeycomb at 2.5 m 3 / sec / m 2 (on the front surface of the skewed honeycomb). 12.6 ° C. of humidified water containing hypochlorous acid with a concentration of 3.93 mg / L of hypochlorous acid, 60 L / min / m 2 (per unit area of the upper surface of the skewed honeycomb) And supplied for 1 hour. At this time, all of the humidified water discharged from the lower surface of the skewed honeycomb was discharged outside the apparatus without returning to the humidified water tank (non-circulating flushing type). 1 hour deposition amount of bacteria of the oblique honeycomb after the bacteria is less than 50 CFU / 100 cm 2, less than 2 fungi 50 CFU / 100 cm, the concentration of hypochlorous acid in the humidifying water discharged from the lower surface of the oblique honeycomb is 1.05mg / L.

(実施例5)
<加湿>
空気加湿装置Aを用い、斜行ハニカムに、13.8℃の被加湿空気を、2.5m/秒/m(斜行ハニカムの前面の単位面積当たり)で、8.0℃の加湿水を、60L/分/m(斜行ハニカムの上面の単位面積当たり)で、所定時間(1回目は288時間、2回目は168時間、3回目は336時間)供給した。このとき、加湿水タンク内の加湿水の水量が、30Lとなるように、加湿水排出管16aから加湿水25を、排出量と処理風量の重量比(L/G)が0.007の割合で排出すると共に、補給水22(次亜塩素酸濃度0.56mg/L未満、水道水)を供給した。
(Example 5)
<Humidification>
Using the air humidifier A, humidified air at 13.8 ° C. was humidified at 8.0 ° C. at 2.5 m 3 / sec / m 2 (per unit area of the front surface of the slanted honeycomb). Water was supplied at a rate of 60 L / min / m 2 (per unit area of the upper surface of the skewed honeycomb) for a predetermined time (288 hours for the first time, 168 hours for the second time, and 336 hours for the third time). At this time, the ratio of the weight ratio (L / G) of the humidified water 25 from the humidified water discharge pipe 16a to the humidified water discharge pipe 16a is 0.007 so that the amount of humidified water in the humidified water tank is 30L. And supplementary water 22 (hypochlorous acid concentration of less than 0.56 mg / L, tap water) was supplied.

<加湿兼除菌工程>
次いで、上記加湿を行った後の空気加湿装置Aの斜行ハニカムに、13.6℃の被加湿空気を、2.5m/秒/m(斜行ハニカムの前面の単位面積当たり)で供給を続けたまま、加湿水タンク内の加湿水の水量が、30Lとなるように、加湿水排出管16aから次亜塩素酸を含有する加湿水30を、排出量と処理風量の重量比(L/G)が0.007の割合で排出すると共に、補給水22の供給を止め、代りに次亜塩素酸水溶液供給管21より次亜塩素酸水溶液23を、1時間供給した。このとき、斜行ハニカムの下面から排出される加湿水を、加湿水タンクに戻して循環使用した(循環式)。
<Humidification and sterilization process>
Next, the humidified air at 13.6 ° C. is supplied to the skewed honeycomb of the air humidifier A after the above humidification at 2.5 m 3 / sec / m 2 (per unit area of the front surface of the skewed honeycomb). While continuing the supply, the humidified water 30 containing hypochlorous acid is removed from the humidified water discharge pipe 16a so that the amount of humidified water in the humidified water tank becomes 30 L. L / G) was discharged at a rate of 0.007, and the supply of makeup water 22 was stopped. Instead, a hypochlorous acid aqueous solution 23 was supplied from a hypochlorous acid aqueous solution supply pipe 21 for 1 hour. At this time, the humidified water discharged from the lower surface of the skewed honeycomb was returned to the humidified water tank for circulation (circulation type).

そして、288時間加湿(1回目)及び1時間の加湿兼除菌工程(次亜塩素酸水溶液供給管21より次亜塩素酸濃度が13.6mg/Lの次亜塩素酸水溶液23を供給した。)を1回、次いで168時間加湿(2回目)及び1時間の加湿兼除菌工程(次亜塩素酸水溶液供給管21より次亜塩素酸濃度が10.7mg/Lの次亜塩素酸水溶液23を供給した。)を1回、次いで336時間加湿(3回目)及び1時間の加湿兼除菌工程(次亜塩素酸水溶液供給管21より次亜塩素酸濃度が9.6mg/Lの次亜塩素酸水溶液23を供給した。)を1回実施した。
その結果、1回目の加湿後(288時間運転を行った後)の斜行ハニカムの付着菌量は、細菌が8500000CFU/100cm、真菌が860000CFU/100cmであった。また、1回目の加湿兼除菌工程後(1時間運転を行った後)の斜行ハニカムの付着菌量は、細菌が50CFU/100cm未満、真菌が50CFU/100cm未満、斜行ハニカムに供給される加湿水中の次亜塩素酸濃度が1.62mg/L、斜行ハニカムの下面から排出される加湿水中の次亜塩素酸濃度が0.43mg/Lであった。
2回目の加湿後(168時間運転を行った後)の斜行ハニカムの付着菌量は、細菌が450CFU/100cm、真菌が50CFU/100cm未満であった。また、2回目の加湿兼除菌工程後(1時間運転を行った後)の斜行ハニカムの付着菌量は、細菌が50CFU/100cm未満、真菌が50CFU/100cm未満、斜行ハニカムに供給される加湿水中の次亜塩素酸濃度が1.49mg/L、斜行ハニカムの下面から排出される加湿水中の次亜塩素酸濃度が1.36mg/Lであった。
3回目の加湿後(336時間運転を行った後)の斜行ハニカムの付着菌量は、細菌が420000CFU/100cm、真菌が290000CFU/100cmであった。また、3回目の加湿兼除菌工程後(1時間運転を行った後)の斜行ハニカムの付着菌量は、細菌が50CFU/100cm未満、真菌が50CFU/100cm未満、斜行ハニカムに供給される加湿水中の次亜塩素酸濃度が0.76mg/L、斜行ハニカムの下面から排出される加湿水中の次亜塩素酸濃度が0.55mg/Lであった。
Then, humidification (first time) for 288 hours and humidification and sterilization step for 1 hour (hypochlorous acid aqueous solution 23 having a hypochlorous acid concentration of 13.6 mg / L was supplied from the hypochlorous acid aqueous solution supply pipe 21. ) Once, then 168 hours of humidification (second time) and 1 hour of humidification and sterilization step (hypochlorous acid aqueous solution 23 having a hypochlorous acid concentration of 10.7 mg / L from the hypochlorous acid aqueous solution supply pipe 21) 1), then 336 hours of humidification (third time) and 1 hour of humidification and sterilization process (hypochlorous acid concentration of 9.6 mg / L from the hypochlorous acid aqueous solution supply pipe 21) Chloric acid aqueous solution 23 was supplied.) Was performed once.
As a result, the amount of adherent bacteria on the skewed honeycomb after the first humidification (after operation for 288 hours) was 850000 CFU / 100 cm 2 for bacteria and 860000 CFU / 100 cm 2 for fungi. Further, adhesion bacteria of the oblique honeycomb after first humidification and sterilization process (after 1 hour operation), the bacteria is less than 50 CFU / 100 cm 2, fungi than 50 CFU / 100 cm 2, the oblique honeycomb The hypochlorous acid concentration in the supplied humidified water was 1.62 mg / L, and the hypochlorous acid concentration in the humidified water discharged from the lower surface of the skewed honeycomb was 0.43 mg / L.
The amount of bacteria attached to the skewed honeycomb after the second humidification (after operating for 168 hours) was 450 CFU / 100 cm 2 for bacteria and less than 50 CFU / 100 cm 2 for fungi. Further, adhesion bacteria of the oblique honeycomb after the second humidification and sterilization process (after 1 hour operation), the bacteria is less than 50 CFU / 100 cm 2, fungi than 50 CFU / 100 cm 2, the oblique honeycomb The hypochlorous acid concentration in the supplied humidified water was 1.49 mg / L, and the hypochlorous acid concentration in the humidified water discharged from the lower surface of the skewed honeycomb was 1.36 mg / L.
The amount of bacteria attached to the skewed honeycomb after the third humidification (after operation for 336 hours) was 420,000 CFU / 100 cm 2 for bacteria and 290000 CFU / 100 cm 2 for fungi. Further, adhesion bacteria of oblique honeycomb after the third humidifying and sterilization process (after 1 hour operation), the bacteria is less than 50 CFU / 100 cm 2, fungi than 50 CFU / 100 cm 2, the oblique honeycomb The hypochlorous acid concentration in the supplied humidified water was 0.76 mg / L, and the hypochlorous acid concentration in the humidified water discharged from the lower surface of the skewed honeycomb was 0.55 mg / L.

本発明によれば、24時間施設内に人がいるような施設にも、連続して加湿空気の供給が可能な空気加湿装置を提供できる。   ADVANTAGE OF THE INVENTION According to this invention, the air humidifier which can supply humidified air continuously also to a facility where a person exists in a facility for 24 hours can be provided.

Claims (1)

一方向に向かって伝播する波形形状を有する波形シートが複数積層されてハニカム形状を呈し、隣り合う波形シートの山部の稜線方向が斜めに交差し、且つ、一枚おきに波形シートの山部の稜線方向が略同一方向になるように、該波形シートが積層されており、前面、後面、上面及び下面の4面に通気空洞の開口を有する斜行ハニカムの上部より該斜行ハニカム内に加湿水を供給し、該斜行ハニカムの下面から該加湿水を排出しつつ、且つ、該斜行ハニカムの前面より該斜行ハニカム内に被加湿空気を供給し、該斜行ハニカムの後面から加湿空気を排出することにより、該斜行ハニカム内で該被加湿空気と該加湿水とを接触させて、該被加湿空気の加湿を行う加湿工程を行い、
該加湿工程中に、該加湿水として、次亜塩素酸を含有する加湿水を、該斜行ハニカムの下面から排出される加湿水中の次亜塩素酸濃度が、0.4mg/L以上となるまで、該斜行ハニカム内に供給することにより、該被加湿空気の加湿を行いながら、該斜行ハニカムの除菌を行う加湿兼除菌工程を、間欠的に繰り返し行うこと、
を特徴とする空気加湿方法。
A plurality of corrugated sheets having a corrugated shape propagating in one direction are laminated to form a honeycomb shape, and the ridge line directions of the ridge portions of adjacent corrugated sheets intersect diagonally, and the ridge portions of the corrugated sheets are alternated. The corrugated sheets are laminated so that the ridge line directions of the two are substantially the same direction, and the inside of the skewed honeycomb from the upper part of the skewed honeycomb having openings of ventilation cavities on the four surfaces of the front surface, the rear surface, the upper surface, and the lower surface. Supplying humidified water, exhausting the humidified water from the lower surface of the skewed honeycomb, and supplying humidified air into the skewed honeycomb from the front surface of the skewed honeycomb, from the rear surface of the skewed honeycomb Exhausting the humidified air to bring the humidified air into contact with the humidified water in the skewed honeycomb to perform a humidification step of humidifying the humidified air;
During the humidification step, the hypochlorous acid concentration in the humidified water discharged from the lower surface of the skewed honeycomb is 0.4 mg / L or higher when humidified water containing hypochlorous acid is used as the humidified water. Until the humidification and sterilization step of sterilizing the skewed honeycomb is performed intermittently while humidifying the humidified air by supplying it into the skewed honeycomb,
An air humidification method characterized by.
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