JP5415260B2 - フレグランス化合物 - Google Patents

フレグランス化合物 Download PDF

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Publication number
JP5415260B2
JP5415260B2 JP2009514609A JP2009514609A JP5415260B2 JP 5415260 B2 JP5415260 B2 JP 5415260B2 JP 2009514609 A JP2009514609 A JP 2009514609A JP 2009514609 A JP2009514609 A JP 2009514609A JP 5415260 B2 JP5415260 B2 JP 5415260B2
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Japan
Prior art keywords
dimethyl
enal
methyl
carbaldehyde
phenyl
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Japanese (ja)
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JP2009540066A5 (https=
JP2009540066A (ja
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フラックスマン,フェリックス
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ジボダン エス エー
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K1/00Housing animals; Equipment therefor
    • A01K1/015Floor coverings, e.g. bedding-down sheets ; Stable floors
    • A01K1/0152Litter
    • A01K1/0155Litter comprising organic material
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/40Unsaturated compounds
    • C07C59/76Unsaturated compounds containing keto groups
    • C07C59/90Unsaturated compounds containing keto groups containing singly bound oxygen-containing groups
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K1/00Housing animals; Equipment therefor
    • A01K1/015Floor coverings, e.g. bedding-down sheets ; Stable floors
    • A01K1/0152Litter
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00Carboxylic acid amides
    • C07C233/01Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/02Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
    • C07C233/09Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with carbon atoms of carboxamide groups bound to carbon atoms of an acyclic unsaturated carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/74Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups combined with dehydration
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/04Saturated compounds containing keto groups bound to acyclic carbon atoms
    • C07C49/12Ketones containing more than one keto group
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/20Unsaturated compounds containing keto groups bound to acyclic carbon atoms
    • C07C49/203Unsaturated compounds containing keto groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/20Unsaturated compounds containing keto groups bound to acyclic carbon atoms
    • C07C49/255Unsaturated compounds containing keto groups bound to acyclic carbon atoms containing ether groups, groups, groups, or groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/76Ketones containing a keto group bound to a six-membered aromatic ring
    • C07C49/84Ketones containing a keto group bound to a six-membered aromatic ring containing ether groups, groups, groups, or groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/602Dicarboxylic acid esters having at least two carbon-to-carbon double bonds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/66Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
    • C07C69/73Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids
    • C07C69/738Esters of keto-carboxylic acids or aldehydo-carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00Essential oils; Perfumes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00Essential oils; Perfumes
    • C11B9/0007Aliphatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00Essential oils; Perfumes
    • C11B9/0007Aliphatic compounds
    • C11B9/0015Aliphatic compounds containing oxygen as the only heteroatom
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00Essential oils; Perfumes
    • C11B9/0007Aliphatic compounds
    • C11B9/0015Aliphatic compounds containing oxygen as the only heteroatom
    • C11B9/0019Aliphatic compounds containing oxygen as the only heteroatom carbocylic acids; Salts or esters thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00Essential oils; Perfumes
    • C11B9/0061Essential oils; Perfumes compounds containing a six-membered aromatic ring not condensed with another ring
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/001Softening compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2072Aldehydes-ketones
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2093Esters; Carbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/32Amides; Substituted amides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes
    • C11D3/502Protected perfumes
    • C11D3/507Compounds releasing perfumes by thermal or chemical activation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00Systems containing only non-condensed rings
    • C07C2601/12Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Environmental Sciences (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Animal Husbandry (AREA)
  • Zoology (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Fats And Perfumes (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Cosmetics (AREA)
JP2009514609A 2006-06-15 2007-06-13 フレグランス化合物 Active JP5415260B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB0611770.9A GB0611770D0 (en) 2006-06-15 2006-06-15 Compounds
GB0611770.9 2006-06-15
PCT/CH2007/000294 WO2007143873A1 (en) 2006-06-15 2007-06-13 Fragrance compounds

Publications (3)

Publication Number Publication Date
JP2009540066A JP2009540066A (ja) 2009-11-19
JP2009540066A5 JP2009540066A5 (https=) 2010-07-15
JP5415260B2 true JP5415260B2 (ja) 2014-02-12

Family

ID=36775628

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2009514609A Active JP5415260B2 (ja) 2006-06-15 2007-06-13 フレグランス化合物

Country Status (10)

Country Link
US (4) US8575386B2 (https=)
EP (1) EP2032516B1 (https=)
JP (1) JP5415260B2 (https=)
KR (1) KR20090024701A (https=)
CN (1) CN101472874B (https=)
BR (1) BRPI0713765B1 (https=)
ES (1) ES2394222T3 (https=)
GB (1) GB0611770D0 (https=)
MX (1) MX2008015444A (https=)
WO (1) WO2007143873A1 (https=)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0611770D0 (en) * 2006-06-15 2006-07-26 Givaudan Sa Compounds
US8389466B2 (en) * 2008-04-07 2013-03-05 Symrise Ag Use of carboxylic acid esters as a fragrance substance
KR101463727B1 (ko) * 2009-12-17 2014-11-21 더 프록터 앤드 갬블 캄파니 악취 결합 중합체 및 악취 제어 성분을 포함하는 청향 조성물
EP2585034A2 (en) * 2010-06-25 2013-05-01 Givaudan SA Encapsulated compositions comprising aldehyde fragrance precursors
US8414870B2 (en) * 2010-12-06 2013-04-09 Sytheon, Ltd. Benzylidene substituted 2,4-pentanedione compounds and use thereof as stabilizers
US8617528B2 (en) 2010-12-06 2013-12-31 Sytheon Ltd. Compositions and methods for stabilizing ingredients using 2,4-pentanedione compounds
EP2850055A1 (en) * 2012-05-16 2015-03-25 Solvay SA Manufacture of 1-substituted methylidene compounds
BR112017007005B1 (pt) * 2014-11-10 2021-11-09 Givaudan Sa Melhorias em ou referentes a compostos orgânicos
WO2016074699A1 (en) * 2014-11-10 2016-05-19 Givaudan Sa Improvments in or relating to organic compounds
WO2016074118A1 (en) 2014-11-10 2016-05-19 Givaudan Sa Improvements in or relating to organic compounds
EP3468526B1 (en) * 2016-06-08 2021-05-12 Takasago International Corporation Fragrance material
GB201620044D0 (en) * 2016-11-28 2017-01-11 Givaudan Sa Improvements in or relating to organic compounds
WO2019059375A1 (ja) * 2017-09-25 2019-03-28 高砂香料工業株式会社 香料前駆体
EP3533786A1 (en) 2018-03-02 2019-09-04 Givaudan SA Thioether precursors for fragrant ketones and aldehydes
US12024692B2 (en) 2018-12-17 2024-07-02 Givaudan Sa Method of extending the olfactory effect of a fragrance accord comprising 4-(dodecylthio)-4-methylpentan-2-one
SG11202105724TA (en) 2018-12-17 2021-07-29 Givaudan Sa A method of countering malodour in a washing machine comprising the addition of a fragrance precursor
US12264295B2 (en) 2019-03-20 2025-04-01 Firmenich Sa Encapsulated pro-perfume compounds
CN114096651A (zh) 2019-06-27 2022-02-25 弗门尼舍有限公司 已加香消费产品
CN111333509B (zh) * 2020-04-14 2022-06-10 东莞波顿香料有限公司 苹果风味化合物及其制备方法和食品添加剂
WO2022261956A1 (en) * 2021-06-18 2022-12-22 Givaudan Sa Fragrance compounds
WO2023065200A1 (en) 2021-10-21 2023-04-27 Givaudan Sa Organic compounds
WO2023065203A1 (en) 2021-10-21 2023-04-27 Givaudan Sa Organic compounds
CN114560887B (zh) * 2022-02-15 2024-01-26 安徽美致诚药业有限公司 一种制备奥利司他的中间体的制备方法
CN120936587A (zh) 2023-03-30 2025-11-11 奇华顿股份有限公司 不饱和醚香料前体
WO2025003204A1 (en) 2023-06-27 2025-01-02 Givaudan Sa Organic compounds and their use for generating a fragrant alcohol
GB202404060D0 (en) 2024-03-21 2024-05-08 Givaudan Sa Fragrance compositions exhibiting enhanced intensity
WO2025196224A1 (en) 2024-03-21 2025-09-25 Givaudan Sa Fragrance compositions exhibiting enhanced intensity

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GB857163A (en) * 1957-01-19 1960-12-29 Council Scient Ind Res A process for the preparation of tridecane-1:13-dicarboxylic acid or its ester, suitable for the preparation of exaltone (cyclopentadecanone)
FR92123E (fr) 1966-10-12 1968-09-27 Rhone Poulenc Sa Nouveau procédé de préparation de l'acide chrysanthémique
US3789797A (en) 1971-11-12 1974-02-05 Star Kist Foods Cat litter
JPS4879755A (https=) * 1972-01-29 1973-10-25
AU5677773A (en) 1972-07-14 1974-12-12 Princeton Biomedix, Incorporated Pharmaceutically useful compounds and methods of producing and using same
US4437429A (en) 1981-08-04 1984-03-20 Aquarium Pharmaceuticals, Inc. Animal litter
DE3423249A1 (de) * 1984-06-23 1986-01-02 Hüls AG, 4370 Marl Verfahren zur herstellung von alkyliden- und arylidenverbindungen
JPS62226934A (ja) 1986-03-26 1987-10-05 Nippon Petrochem Co Ltd ノルボルネン誘導体
FR2642967B1 (fr) 1989-02-15 1991-06-07 Oreal Utilisation en cosmetique de diorganopolysiloxanes a fonction benzalmalonate et nouvelles compositions cosmetiques contenant ces composes, destinees a la protection de la peau et des cheveux
DE4101737C2 (de) * 1990-01-29 2001-04-26 Aventis Res & Tech Gmbh & Co Verfahren zur Herstellung von olefinischen Verbindungen aus Carbonyl-Verbindungen und Diazoalkanen
DE4104737A1 (de) * 1991-02-15 1992-08-20 Siegel Geb Gmbh Co Kg Schwenktuere fuer kundenfuehrungsanlagen
JP3477242B2 (ja) * 1994-06-07 2003-12-10 小川香料株式会社 2−アセチル−2−アルケン酸アルキルからなる香料
FR2818144A1 (fr) 2000-12-18 2002-06-21 Oreal Compositions antisolaires a base d'un melange synergetique de filtres et utilisations
GB0501237D0 (en) 2005-01-21 2005-03-02 Givaudan Sa Organic compounds
GB0611770D0 (en) * 2006-06-15 2006-07-26 Givaudan Sa Compounds

Also Published As

Publication number Publication date
EP2032516A1 (en) 2009-03-11
US8575386B2 (en) 2013-11-05
US20140031270A1 (en) 2014-01-30
KR20090024701A (ko) 2009-03-09
US9057041B2 (en) 2015-06-16
US20090202464A1 (en) 2009-08-13
MX2008015444A (es) 2008-12-12
BRPI0713765B1 (pt) 2017-04-18
US20150247109A1 (en) 2015-09-03
CN101472874B (zh) 2012-11-14
US20160286753A1 (en) 2016-10-06
US9447364B2 (en) 2016-09-20
GB0611770D0 (en) 2006-07-26
EP2032516B1 (en) 2012-09-26
JP2009540066A (ja) 2009-11-19
CN101472874A (zh) 2009-07-01
WO2007143873A1 (en) 2007-12-21
US9585362B2 (en) 2017-03-07
ES2394222T3 (es) 2013-01-23

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