JP5415260B2 - フレグランス化合物 - Google Patents
フレグランス化合物 Download PDFInfo
- Publication number
- JP5415260B2 JP5415260B2 JP2009514609A JP2009514609A JP5415260B2 JP 5415260 B2 JP5415260 B2 JP 5415260B2 JP 2009514609 A JP2009514609 A JP 2009514609A JP 2009514609 A JP2009514609 A JP 2009514609A JP 5415260 B2 JP5415260 B2 JP 5415260B2
- Authority
- JP
- Japan
- Prior art keywords
- dimethyl
- enal
- methyl
- carbaldehyde
- phenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 150000001875 compounds Chemical class 0.000 title claims description 31
- 239000003205 fragrance Substances 0.000 title claims description 22
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 36
- 229910052760 oxygen Inorganic materials 0.000 claims description 20
- 239000001301 oxygen Substances 0.000 claims description 20
- 229910052757 nitrogen Inorganic materials 0.000 claims description 19
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 14
- 150000003934 aromatic aldehydes Chemical class 0.000 claims description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 13
- -1 undeca-10-en-1- Chemical compound 0.000 claims description 13
- 229910052710 silicon Chemical group 0.000 claims description 12
- 150000002430 hydrocarbons Chemical class 0.000 claims description 11
- 229930195733 hydrocarbon Natural products 0.000 claims description 8
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical group O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 7
- NFAVNWJJYQAGNB-UHFFFAOYSA-N 2-methylundecanal Chemical compound CCCCCCCCCC(C)C=O NFAVNWJJYQAGNB-UHFFFAOYSA-N 0.000 claims description 6
- OHRBQTOZYGEWCJ-UHFFFAOYSA-N 3-(3-propan-2-ylphenyl)butanal Chemical compound CC(C)C1=CC=CC(C(C)CC=O)=C1 OHRBQTOZYGEWCJ-UHFFFAOYSA-N 0.000 claims description 6
- NUJGJRNETVAIRJ-UHFFFAOYSA-N octanal Chemical compound CCCCCCCC=O NUJGJRNETVAIRJ-UHFFFAOYSA-N 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- LMETVDMCIJNNKH-UHFFFAOYSA-N [(3,7-Dimethyl-6-octenyl)oxy]acetaldehyde Chemical compound CC(C)=CCCC(C)CCOCC=O LMETVDMCIJNNKH-UHFFFAOYSA-N 0.000 claims description 4
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 claims description 4
- 238000009833 condensation Methods 0.000 claims description 4
- 230000005494 condensation Effects 0.000 claims description 4
- KSMVZQYAVGTKIV-UHFFFAOYSA-N decanal Chemical compound CCCCCCCCCC=O KSMVZQYAVGTKIV-UHFFFAOYSA-N 0.000 claims description 4
- HFJRKMMYBMWEAD-UHFFFAOYSA-N dodecanal Chemical compound CCCCCCCCCCCC=O HFJRKMMYBMWEAD-UHFFFAOYSA-N 0.000 claims description 4
- FXHGMKSSBGDXIY-UHFFFAOYSA-N heptanal Chemical compound CCCCCCC=O FXHGMKSSBGDXIY-UHFFFAOYSA-N 0.000 claims description 4
- WPFVBOQKRVRMJB-UHFFFAOYSA-N hydroxycitronellal Chemical compound O=CCC(C)CCCC(C)(C)O WPFVBOQKRVRMJB-UHFFFAOYSA-N 0.000 claims description 4
- GYHFUZHODSMOHU-UHFFFAOYSA-N nonanal Chemical compound CCCCCCCCC=O GYHFUZHODSMOHU-UHFFFAOYSA-N 0.000 claims description 4
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- BGEHHAVMRVXCGR-UHFFFAOYSA-N tridecanal Chemical compound CCCCCCCCCCCCC=O BGEHHAVMRVXCGR-UHFFFAOYSA-N 0.000 claims description 4
- KMPQYAYAQWNLME-UHFFFAOYSA-N undecanal Chemical compound CCCCCCCCCCC=O KMPQYAYAQWNLME-UHFFFAOYSA-N 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- MMFCJPPRCYDLLZ-CMDGGOBGSA-N (2E)-dec-2-enal Chemical compound CCCCCCC\C=C\C=O MMFCJPPRCYDLLZ-CMDGGOBGSA-N 0.000 claims description 2
- HZYHMHHBBBSGHB-ODYTWBPASA-N (2E,6Z)-nona-2,6-dienal Chemical compound CC\C=C/CC\C=C\C=O HZYHMHHBBBSGHB-ODYTWBPASA-N 0.000 claims description 2
- MIHSPYMZXYONJN-RMKNXTFCSA-N (2e)-2,4-dimethylhepta-2,6-dienal Chemical compound C=CCC(C)\C=C(/C)C=O MIHSPYMZXYONJN-RMKNXTFCSA-N 0.000 claims description 2
- WBNJCBPWAMSDMR-YFVJMOTDSA-N (2e,6e)-3,7,11-trimethyldodeca-2,6-dienal Chemical compound CC(C)CCC\C(C)=C\CC\C(C)=C\C=O WBNJCBPWAMSDMR-YFVJMOTDSA-N 0.000 claims description 2
- CIXAYNMKFFQEFU-UHFFFAOYSA-N (4-Methylphenyl)acetaldehyde Chemical compound CC1=CC=C(CC=O)C=C1 CIXAYNMKFFQEFU-UHFFFAOYSA-N 0.000 claims description 2
- 239000001727 (E)-dec-2-enal Substances 0.000 claims description 2
- 239000001541 (E)-dodec-2-enal Substances 0.000 claims description 2
- SSNZFFBDIMUILS-ZHACJKMWSA-N (E)-dodec-2-enal Chemical compound CCCCCCCCC\C=C\C=O SSNZFFBDIMUILS-ZHACJKMWSA-N 0.000 claims description 2
- 239000001118 (E)-tridec-2-enal Substances 0.000 claims description 2
- OCXBCRILLZNZPA-CSKARUKUSA-N (e)-3-propylhept-2-enal Chemical compound CCCC\C(CCC)=C\C=O OCXBCRILLZNZPA-CSKARUKUSA-N 0.000 claims description 2
- YGFGZTXGYTUXBA-UHFFFAOYSA-N (±)-2,6-dimethyl-5-heptenal Chemical compound O=CC(C)CCC=C(C)C YGFGZTXGYTUXBA-UHFFFAOYSA-N 0.000 claims description 2
- 239000001709 1,2-dimethylcyclohex-3-ene-1-carbaldehyde Substances 0.000 claims description 2
- COJYJCJUBHUSDJ-UHFFFAOYSA-N 2,3,5,5-tetramethylhexanal Chemical compound CC(C)(C)CC(C)C(C)C=O COJYJCJUBHUSDJ-UHFFFAOYSA-N 0.000 claims description 2
- MZZRKEIUNOYYDF-UHFFFAOYSA-N 2,4-dimethylcyclohex-3-ene-1-carbaldehyde Chemical compound CC1C=C(C)CCC1C=O MZZRKEIUNOYYDF-UHFFFAOYSA-N 0.000 claims description 2
- UEGBWDUVDAKUGA-UHFFFAOYSA-N 2,6,10-trimethylundec-9-enal Chemical compound CC(C)=CCCC(C)CCCC(C)C=O UEGBWDUVDAKUGA-UHFFFAOYSA-N 0.000 claims description 2
- RMPKHUJAYKUKPH-UHFFFAOYSA-N 2,6-dimethyloct-5-enal Chemical compound CCC(C)=CCCC(C)C=O RMPKHUJAYKUKPH-UHFFFAOYSA-N 0.000 claims description 2
- FSKGFRBHGXIDSA-UHFFFAOYSA-N 2-(4-propan-2-ylphenyl)acetaldehyde Chemical compound CC(C)C1=CC=C(CC=O)C=C1 FSKGFRBHGXIDSA-UHFFFAOYSA-N 0.000 claims description 2
- IZQUWQPXCQLTJY-UHFFFAOYSA-N 2-(4-propan-2-ylphenyl)propanal Chemical compound CC(C)C1=CC=C(C(C)C=O)C=C1 IZQUWQPXCQLTJY-UHFFFAOYSA-N 0.000 claims description 2
- SSNZFFBDIMUILS-UHFFFAOYSA-N 2-Dodecenal Natural products CCCCCCCCCC=CC=O SSNZFFBDIMUILS-UHFFFAOYSA-N 0.000 claims description 2
- BSAIUMLZVGUGKX-UHFFFAOYSA-N 2-Nonenal Natural products CCCCCCC=CC=O BSAIUMLZVGUGKX-UHFFFAOYSA-N 0.000 claims description 2
- MBDOYVRWFFCFHM-UHFFFAOYSA-N 2-hexenal Chemical compound CCCC=CC=O MBDOYVRWFFCFHM-UHFFFAOYSA-N 0.000 claims description 2
- VDBFZEMBBKEKPI-UHFFFAOYSA-N 2-methyl-4-(2,6,6-trimethylcyclohex-2-en-1-yl)butanal Chemical compound O=CC(C)CCC1C(C)=CCCC1(C)C VDBFZEMBBKEKPI-UHFFFAOYSA-N 0.000 claims description 2
- LBICMZLDYMBIGA-UHFFFAOYSA-N 2-methyldecanal Chemical compound CCCCCCCCC(C)C=O LBICMZLDYMBIGA-UHFFFAOYSA-N 0.000 claims description 2
- IQVAERDLDAZARL-UHFFFAOYSA-N 2-phenylpropanal Chemical compound O=CC(C)C1=CC=CC=C1 IQVAERDLDAZARL-UHFFFAOYSA-N 0.000 claims description 2
- WTPYRCJDOZVZON-UHFFFAOYSA-N 3,5,5-Trimethylhexanal Chemical compound O=CCC(C)CC(C)(C)C WTPYRCJDOZVZON-UHFFFAOYSA-N 0.000 claims description 2
- BCEQJZNLIKMDEU-UHFFFAOYSA-N 3,7-dimethylnona-2,6-dienal Chemical compound CCC(C)=CCCC(C)=CC=O BCEQJZNLIKMDEU-UHFFFAOYSA-N 0.000 claims description 2
- UCSIFMPORANABL-UHFFFAOYSA-N 3,7-dimethyloctanal Chemical compound CC(C)CCCC(C)CC=O UCSIFMPORANABL-UHFFFAOYSA-N 0.000 claims description 2
- WFEISWUNAJPLRX-UHFFFAOYSA-N 30168-23-1 Chemical compound C12CCCC2C2CC(=CCCC=O)C1C2 WFEISWUNAJPLRX-UHFFFAOYSA-N 0.000 claims description 2
- MQBIZQLCHSZBOI-UHFFFAOYSA-N 4-(4-Methyl-3-pentenyl)-3-cyclohexene-1-carboxaldehyde Chemical compound CC(C)=CCCC1=CCC(C=O)CC1 MQBIZQLCHSZBOI-UHFFFAOYSA-N 0.000 claims description 2
- MXGRYXNVQNESIN-UHFFFAOYSA-N 4-tert-butylcyclohexane-1-carbaldehyde Chemical compound CC(C)(C)C1CCC(C=O)CC1 MXGRYXNVQNESIN-UHFFFAOYSA-N 0.000 claims description 2
- AQJANVUPNABWRU-UHFFFAOYSA-N 8,8-dimethyl-2,3,4,5,6,7-hexahydro-1h-naphthalene-2-carbaldehyde Chemical compound C1C(C=O)CCC2=C1C(C)(C)CCC2 AQJANVUPNABWRU-UHFFFAOYSA-N 0.000 claims description 2
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 claims description 2
- FZJUFJKVIYFBSY-UHFFFAOYSA-N bourgeonal Chemical compound CC(C)(C)C1=CC=C(CCC=O)C=C1 FZJUFJKVIYFBSY-UHFFFAOYSA-N 0.000 claims description 2
- CWRKZMLUDFBPAO-UHFFFAOYSA-N dec-4-enal Chemical compound CCCCCC=CCCC=O CWRKZMLUDFBPAO-UHFFFAOYSA-N 0.000 claims description 2
- AKMSQWLDTSOVME-UHFFFAOYSA-N dec-9-enal Chemical compound C=CCCCCCCCC=O AKMSQWLDTSOVME-UHFFFAOYSA-N 0.000 claims description 2
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 claims description 2
- SDQFDHOLCGWZPU-UHFFFAOYSA-N lilial Chemical compound O=CC(C)CC1=CC=C(C(C)(C)C)C=C1 SDQFDHOLCGWZPU-UHFFFAOYSA-N 0.000 claims description 2
- BOPPSUHPZARXTH-UHFFFAOYSA-N ocean propanal Chemical compound O=CC(C)CC1=CC=C2OCOC2=C1 BOPPSUHPZARXTH-UHFFFAOYSA-N 0.000 claims description 2
- RUMOYJJNUMEFDD-UHFFFAOYSA-N perillyl aldehyde Chemical compound CC(=C)C1CCC(C=O)=CC1 RUMOYJJNUMEFDD-UHFFFAOYSA-N 0.000 claims description 2
- VMUNAKQXJLHODT-UHFFFAOYSA-N tridec-2-enal Chemical compound CCCCCCCCCCC=CC=O VMUNAKQXJLHODT-UHFFFAOYSA-N 0.000 claims description 2
- ZFMUIJVOIVHGCF-UHFFFAOYSA-N undec-9-enal Chemical compound CC=CCCCCCCCC=O ZFMUIJVOIVHGCF-UHFFFAOYSA-N 0.000 claims description 2
- ZFNVDHOSLNRHNN-UHFFFAOYSA-N xi-3-(4-Isopropylphenyl)-2-methylpropanal Chemical compound O=CC(C)CC1=CC=C(C(C)C)C=C1 ZFNVDHOSLNRHNN-UHFFFAOYSA-N 0.000 claims description 2
- 239000001381 (E)-non-2-enal Substances 0.000 claims 1
- BSAIUMLZVGUGKX-BQYQJAHWSA-N (E)-non-2-enal Chemical compound CCCCCC\C=C\C=O BSAIUMLZVGUGKX-BQYQJAHWSA-N 0.000 claims 1
- UFIGFUXPZVBIIZ-UHFFFAOYSA-N OC(CCCC1=CCC(CC1)C=O)(C)C.CC1=CC(C(C(C1)C)C=O)C Chemical compound OC(CCCC1=CCC(CC1)C=O)(C)C.CC1=CC(C(C(C1)C)C=O)C UFIGFUXPZVBIIZ-UHFFFAOYSA-N 0.000 claims 1
- 239000004615 ingredient Substances 0.000 claims 1
- UUEVFMOUBSLVJW-UHFFFAOYSA-N oxo-[[1-[2-[2-[2-[4-(oxoazaniumylmethylidene)pyridin-1-yl]ethoxy]ethoxy]ethyl]pyridin-4-ylidene]methyl]azanium;dibromide Chemical compound [Br-].[Br-].C1=CC(=C[NH+]=O)C=CN1CCOCCOCCN1C=CC(=C[NH+]=O)C=C1 UUEVFMOUBSLVJW-UHFFFAOYSA-N 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 7
- 150000001299 aldehydes Chemical class 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000003599 detergent Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 3
- 125000003342 alkenyl group Chemical group 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 230000006870 function Effects 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 0 *C(C(C(*)=O)=C(*)N)=O Chemical compound *C(C(C(*)=O)=C(*)N)=O 0.000 description 2
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 2
- PXDFBOUIQZZHAI-UHFFFAOYSA-N 2-methylundec-2-enal Chemical compound CCCCCCCCC=C(C)C=O PXDFBOUIQZZHAI-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- GKKZMYDNDDMXSE-UHFFFAOYSA-N Ethyl 3-oxo-3-phenylpropanoate Chemical compound CCOC(=O)CC(=O)C1=CC=CC=C1 GKKZMYDNDDMXSE-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 125000005119 alkyl cycloalkyl group Chemical group 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 125000001316 cycloalkyl alkyl group Chemical group 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- 150000002148 esters Chemical group 0.000 description 2
- WPJYXPXGZDVAIM-UHFFFAOYSA-N ethyl 2-acetyl-4-methyltridec-2-enoate Chemical compound CCCCCCCCCC(C)C=C(C(C)=O)C(=O)OCC WPJYXPXGZDVAIM-UHFFFAOYSA-N 0.000 description 2
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 125000000555 isopropenyl group Chemical group [H]\C([H])=C(\*)C([H])([H])[H] 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 230000005923 long-lasting effect Effects 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- QAFGEOHWEQLURJ-DHZHZOJOSA-N (2e)-2,4-diethylhepta-2,6-dienal Chemical compound C=CCC(CC)\C=C(/CC)C=O QAFGEOHWEQLURJ-DHZHZOJOSA-N 0.000 description 1
- OFHHDSQXFXLTKC-UHFFFAOYSA-N 10-undecenal Chemical compound C=CCCCCCCCCC=O OFHHDSQXFXLTKC-UHFFFAOYSA-N 0.000 description 1
- LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 description 1
- GAPYQTUUEULTAW-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethyl 2-(1-hydroxyethylidene)dec-3-enoate Chemical compound CCCCCCC=CC(=C(C)O)C(=O)OCCOCCOC GAPYQTUUEULTAW-UHFFFAOYSA-N 0.000 description 1
- GWVQBFQJAVXIIX-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethyl 3-oxobutanoate Chemical compound COCCOCCOC(=O)CC(C)=O GWVQBFQJAVXIIX-UHFFFAOYSA-N 0.000 description 1
- ORMHZBNNECIKOH-UHFFFAOYSA-N 4-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-1-carbaldehyde Chemical compound CC(C)(O)CCCC1=CCC(C=O)CC1 ORMHZBNNECIKOH-UHFFFAOYSA-N 0.000 description 1
- 125000004172 4-methoxyphenyl group Chemical group [H]C1=C([H])C(OC([H])([H])[H])=C([H])C([H])=C1* 0.000 description 1
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 1
- 239000005695 Ammonium acetate Substances 0.000 description 1
- WOFAGNLBCJWEOE-UHFFFAOYSA-N Benzyl acetoacetate Chemical compound CC(=O)CC(=O)OCC1=CC=CC=C1 WOFAGNLBCJWEOE-UHFFFAOYSA-N 0.000 description 1
- RMHIYTUMNQCILZ-UHFFFAOYSA-N C(C)(C)(C)C1=CC=C(C=C1)C(CC(=O)C1=CC=C(C=C1)OC)=O.C(CC(=O)OCC1=CC=CC=C1)(=O)OCC1=CC=CC=C1 Chemical compound C(C)(C)(C)C1=CC=C(C=C1)C(CC(=O)C1=CC=C(C=C1)OC)=O.C(CC(=O)OCC1=CC=CC=C1)(=O)OCC1=CC=CC=C1 RMHIYTUMNQCILZ-UHFFFAOYSA-N 0.000 description 1
- DCJTYLOLQVFAJZ-UHFFFAOYSA-N CC1(CC(CCC1)C(C)C(C(=O)O)C(=O)O)C Chemical compound CC1(CC(CCC1)C(C)C(C(=O)O)C(=O)O)C DCJTYLOLQVFAJZ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000402754 Erythranthe moschata Species 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 1
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 description 1
- 235000018936 Vitellaria paradoxa Nutrition 0.000 description 1
- 239000002386 air freshener Substances 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 229940043376 ammonium acetate Drugs 0.000 description 1
- 235000019257 ammonium acetate Nutrition 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000000640 cyclooctyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- BEPAFCGSDWSTEL-UHFFFAOYSA-N dimethyl malonate Chemical compound COC(=O)CC(=O)OC BEPAFCGSDWSTEL-UHFFFAOYSA-N 0.000 description 1
- QRVSDVDFJFKYKA-UHFFFAOYSA-N dipropan-2-yl propanedioate Chemical compound CC(C)OC(=O)CC(=O)OC(C)C QRVSDVDFJFKYKA-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- BKULVIZFOHJLLV-UHFFFAOYSA-N ethyl 2-benzoyldec-2-enoate Chemical compound CCCCCCCC=C(C(=O)OCC)C(=O)C1=CC=CC=C1 BKULVIZFOHJLLV-UHFFFAOYSA-N 0.000 description 1
- IFQUWYZCAGRUJN-UHFFFAOYSA-N ethylenediaminediacetic acid Chemical compound OC(=O)CNCCNCC(O)=O IFQUWYZCAGRUJN-UHFFFAOYSA-N 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 125000002541 furyl group Chemical group 0.000 description 1
- 125000001072 heteroaryl group Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 125000002883 imidazolyl group Chemical group 0.000 description 1
- YJSUCBQWLKRPDL-UHFFFAOYSA-N isocyclocitral Chemical compound CC1CC(C)=CC(C)C1C=O YJSUCBQWLKRPDL-UHFFFAOYSA-N 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 125000002560 nitrile group Chemical group 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 229960001679 octinoxate Drugs 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 125000003386 piperidinyl group Chemical group 0.000 description 1
- 239000011252 protective cream Substances 0.000 description 1
- 230000009993 protective function Effects 0.000 description 1
- 125000004309 pyranyl group Chemical group O1C(C=CC=C1)* 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- 125000000719 pyrrolidinyl group Chemical group 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 230000008786 sensory perception of smell Effects 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002884 skin cream Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- SNOOUWRIMMFWNE-UHFFFAOYSA-M sodium;6-[(3,4,5-trimethoxybenzoyl)amino]hexanoate Chemical compound [Na+].COC1=CC(C(=O)NCCCCCC([O-])=O)=CC(OC)=C1OC SNOOUWRIMMFWNE-UHFFFAOYSA-M 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 description 1
- 125000003718 tetrahydrofuranyl group Chemical group 0.000 description 1
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 1
- GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K1/00—Housing animals; Equipment therefor
- A01K1/015—Floor coverings, e.g. bedding-down sheets ; Stable floors
- A01K1/0152—Litter
- A01K1/0155—Litter comprising organic material
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C59/40—Unsaturated compounds
- C07C59/76—Unsaturated compounds containing keto groups
- C07C59/90—Unsaturated compounds containing keto groups containing singly bound oxygen-containing groups
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K1/00—Housing animals; Equipment therefor
- A01K1/015—Floor coverings, e.g. bedding-down sheets ; Stable floors
- A01K1/0152—Litter
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C233/00—Carboxylic acid amides
- C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C233/02—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
- C07C233/09—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with carbon atoms of carboxamide groups bound to carbon atoms of an acyclic unsaturated carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
- C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
- C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
- C07C45/74—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups combined with dehydration
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/04—Saturated compounds containing keto groups bound to acyclic carbon atoms
- C07C49/12—Ketones containing more than one keto group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/20—Unsaturated compounds containing keto groups bound to acyclic carbon atoms
- C07C49/203—Unsaturated compounds containing keto groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/20—Unsaturated compounds containing keto groups bound to acyclic carbon atoms
- C07C49/255—Unsaturated compounds containing keto groups bound to acyclic carbon atoms containing ether groups, groups, groups, or groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/76—Ketones containing a keto group bound to a six-membered aromatic ring
- C07C49/84—Ketones containing a keto group bound to a six-membered aromatic ring containing ether groups, groups, groups, or groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/602—Dicarboxylic acid esters having at least two carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/73—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids
- C07C69/738—Esters of keto-carboxylic acids or aldehydo-carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0007—Aliphatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0007—Aliphatic compounds
- C11B9/0015—Aliphatic compounds containing oxygen as the only heteroatom
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0007—Aliphatic compounds
- C11B9/0015—Aliphatic compounds containing oxygen as the only heteroatom
- C11B9/0019—Aliphatic compounds containing oxygen as the only heteroatom carbocylic acids; Salts or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0061—Essential oils; Perfumes compounds containing a six-membered aromatic ring not condensed with another ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2072—Aldehydes-ketones
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/507—Compounds releasing perfumes by thermal or chemical activation
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
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- Biodiversity & Conservation Biology (AREA)
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Description
XおよびYは独立して、−CR1R2R3、−NR4R5および−OR6からなる群から選択され、ここでR1〜R5は、Hおよび少なくとも1つの酸素、窒素またはケイ素原子を任意に含む本質的に炭化水素である部分から選択され、R6は、少なくとも1つの酸素、窒素またはケイ素原子を任意に含む本質的に炭化水素である部分から選択され、および
Aは、少なくとも1つの酸素、硫黄、窒素またはケイ素原子を任意に含む本質的に炭化水素である部分であり、ただし化合物A−CHOは芳香性アルデヒドである、
で表される少なくとも1種の化合物の添加を含む、用品(application)に芳香を付与する方法を提供する。
8,8−ジメチル−1,2,3,4,5,6,7,8−オクタヒドロ−ナフタレン−2−カルバルデヒド、
(4−イソプロピル−フェニル)−エタナール、
2,4−ジメチル−シクロヘキサ−3−エン−1−カルバルデヒド、
1,3,5−トリメチル−シクロヘキサ−1−エン−4−カルバルデヒド、
4−(4−ヒドロキシ−4−メチルペンチル)−シクロヘキサ−3−エン−1−カルバルデヒド、
ヘキサ−2−エナール、
ヘプタナール、
2,6−ジメチル−ヘプタ−5−エナール、
デカナール、
デカ−9−エナール、
デカ−4−エン−1−アール、
2−メチル−デカナール、
ウンデカ−10−エン−1−アール、
ウンデカナール、
ドデカナール、
2−メチル−ウンデカナール、
トリデカ−2−エナール、
オクタナール、
ノナナール、
ノナ−2−エナール、
ウンデカ−9−エナール、
2−フェニル−プロパナール、
2−(4−メチル−フェニル)−エタナール、
3,7−ジメチル−オクタナール、
ジヒドロファルネサール、
7−ヒドロキシ−3,7−ジメチル−オクタナール、
3−(3−イソプロピル−フェニル)−ブタナール、
2−(3,7−ジメチル−オクタ−6−エン−オキシ)−エタナール、
4−(4−メチル−ペンタ−3−エニル)−シクロヘキサ−3−エン−1−カルバルデヒド、
2,3,5,5,−テトラメチル−ヘキサナール、
ロンギホル(longifolic)アルデヒド、
2−メチル−4−(2,6,6−トリメチルシクロヘキサ−2−エン−1−イル)−ブタナール、
2−メチル−3−(4−tert−ブチルフェニル)−プロパナール、
3−(4−tert−ブチル−フェニル)−プロパナール、
2−(4−イソプロピル−フェニル)−プロパナール、
3−(ベンゾ[1,3]ジオキソール−5−イル)−2−メチル−プロパナール、
2−メチル−3−(4−イソプロピルフェニル)−プロパナール、
4−tert−ブチル−シクロヘキサン−1−カルバルデヒド、
4−(オクタヒドロ−4,7−メタノ−5H−インデン−5−イリデン)−ブタナール、
(3,7−ジメチル−オクタ−6−エニルオキシ)−エタナール、
(2E,6Z)−ノナジエナール、
2,4−ジメチル−2,6−ヘプタジエナール、
(E)−デカ−2−エナール、
ドデカ−2−エナール、
3,7−ジメチル−オクタ−2,6−ジエナール、
2,4−ジエチル−ヘプタ−2,6−ジエナール、
3,7−ジメチル−ノナ−2,6−ジエナール、
3−プロピル−ヘプタ−2−エナール、および
4−イソプロペニル−シクロヘキサ−1−エン−1−カルバルデヒド。
(a)直鎖状または分枝状であり、酸素、窒素またはケイ素原子を任意に含有する、C1〜C20アルキル、例えばメチル、エチル、プロピル、ブチル、イソブチル、2−エチルヘキシル、tert−ブチル;
(b)酸素、窒素またはケイ素原子を任意に含有する、シクロプロピル、シクロペンチル、シクロヘキシル、シクロオクチル、例えばテトラヒドロフラニル、ピラニル、ピペリジニル、ピロリジニル;
(c)酸素、窒素またはケイ素原子を任意に含有する、C3〜C20アルキルシクロアルキル、例えばメチルシクロヘキシル、エチルシクロヘキシル、メチルシクロペンチル;
(e)直鎖状または分枝状であり、酸素、窒素またはケイ素原子を任意に含有する、C3〜C10アルケニル、例えばプロペニル、イソプロペニル、イソブテニル;
(f)任意の置換基を有する、C6〜C10アリール、例えばフェニル、o−またはp−メトキシフェニル;
(g)任意の置換基を有し、酸素、窒素またはケイ素原子を任意に含有する、C7〜C10アルキルアリール、例えばベンジル、メトキシベンジル;
(g)C5〜C10ヘテロアリール、例えばピリジニル、フラニル、ピリル、イミダゾリル;
(i)−NR4R5、式中、R4およびR5は互いに独立して、H;直鎖状または分枝状であり、酸素または窒素原子を任意に含有するC1〜C20アルキル、例えばメチル、エチル、プロピル、ブチル、イソブチル、2−エチルヘキシル;またはシクロペンチル、シクロヘキシル;またはNR4R5は3、5または6員環を共に形成する
から選択され、
Aは、C7〜C17直鎖状または分枝状アルキル、シクロアルキル、アルキルシクロアルキルまたはシクロアルキルアルキル、C7〜C15直鎖状または分枝状アルケニルおよびC6〜C10アリールからなる群から選択される。
i)XおよびYは同じであり、
a)−OR6、式中、R6は、メチル、エチル、プロピル、イソプロピル、ブチル、イソブチル、t−ブチル、ベンジルからなる群から選択される;または
b)フェニル、メチル、エチル、プロピル、イソプロピル、ブチル、イソブチル;
から選択されるか、あるいは
で表される化合物を提供する。
(a)式II
で表される化合物を、クネーフェナーゲル縮合が行われる条件下で塩基の存在下で芳香性アルデヒドと配合するステップ
および
(b)(a)の生成物を組成物に添加するステップ
を含む。
下式で表される化合物である2−ベンゾイル−デカ−2−エン酸エチルエステルの調製
以下の化合物を、適切な芳香性アルデヒドおよび1,3−ジカルボニル化合物を使って、請求項1に記載の方法により作る。
柔軟剤における利用
2種のエステルクオートタイプの標準の無香料の柔軟剤基剤の試料の夫々に以下の1つを添加する。
1)0.20%wt/wtの2−メチルウンデセナール
2)0.32%wt/wtの2−アセチル−4−メチルトリデカ−2−エン酸エチル(例11)、0.20%wt/wtの2−メチルウンデカナールと同等。
液体洗剤における利用
4種の標準の無香料の重質液体洗剤基剤の試料の夫々に以下の1つを添加する。
1)0.20%wt/wtの2−メチルウンデセナール
2)0.32%wt/wtの2−アセチル−4−メチルトリデカ−2−エン酸エチル(例11)、0.20%wt/wtの2−メチルウンデカナールと同等。
3)0.20%wt/wtの3−(3−イソプロピルフェニル)ブタナール
4)0.32%wt/wtの2−アセチル−5−(3−イソプロピルフェニル)ヘキサ−2−エン酸エチル(例10)、0.20%wt/wtの3−(3−イソプロピルフェニル)ブタナール)と同等。
Claims (5)
- 部分Aが由来する芳香性アルデヒドが、2,6,10−トリメチルウンデカ−9−エナール、8,8−ジメチル−1,2,3,4,5,6,7,8−オクタヒドロ−ナフタレン−2−カルバルデヒド、(4−イソプロピル−フェニル)−エタナール、2,4−ジメチル−シクロヘキサ−3−エン−1−カルバルデヒド、1,3,5−トリメチル−シクロヘキサ−1−エン−4−カルバルデヒド、4−(4−ヒドロキシ−4−メチルペンチル)−シクロヘキサ−3−エン−1−カルバルデヒド、ヘキサ−2−エナール、3,5,5−トリメチル−ヘキサナール、ヘプタナール、2,6−ジメチル−ヘプタ−5−エナール、デカナール、デカ−9−エナール、デカ−4−エン−1−アール、2−メチル−デカナール、ウンデカ−10−エン−1−アール、ウンデカナール、ドデカナール、2−メチル−ウンデカナール、トリデカナール、トリデカ−2−エナール、オクタナール、ノナナール、ノナ−2−エナール、ウンデカ−9−エナール、2−フェニル−プロパナール、2−(4−メチル−フェニル)−エタナール、3,7−ジメチル−オクタナール、ジヒドロファルネサール、7−ヒドロキシ−3,7−ジメチル−オクタナール、2,6−ジメチル−オクタ−5−エン−1−アール、3−(3−イソプロピル−フェニル)−ブタナール、2−(3,7−ジメチル−オクタ−6−エン−オキシ)−エタナール、4−(4−メチル−ペンタ−3−エニル)−シクロヘキサ−3−エン−1−カルバルデヒド、2,3,5,5−テトラメチル−ヘキサナール、ロンギホルアルデヒド、2−メチル−4−(2,6,6−トリメチルシクロヘキサ−2−エン−1−イル)−ブタナール、2−メチル−3−(4−tert−ブチルフェニル)−プロパナール、3−(4−tert−ブチル−フェニル)−プロパナール、2−(4−イソプロピル−フェニル)−プロパナール、3−(ベンゾ[1,3]ジオキソール−5−イル)−2−メチル−プロパナール、3,7−ジメチル−オクタ−6−エン−1−アール、2−メチル−3−(4−イソプロピルフェニル)−プロパナール、4−tert−ブチル−シクロヘキサン−1−カルバルデヒド、4−(オクタヒドロ−4,7−メタノ−5H−インデン−5−イリデン)−ブタナール、(3,7−ジメチル−オクタ−6−エニルオキシ)−エタナール、(2E,6Z)−ノナジエナール、2,4−ジメチル−2,6−ヘプタジエナール、(E)−デカ−2−エナール、ドデカ−2−エナール、3,7−ジメチル−オクタ−2,6−ジエナール、2,4−ジエチル−ヘプタ−2,6−ジエナール、3,7−ジメチル−ノナ−2,6−ジエナール、3−プロピル−ヘプタ−2−エナール、および4−イソプロペニル−シクロヘキサ−1−エン−1−カルバルデヒドからなる群から選択される、請求項1に記載の方法。
- フレグランスが湿気への曝露によって徐々に放出される芳香組成物の製造方法であって、
(a)式II
で表される化合物を、クネーフェナーゲル縮合が行われる条件下で塩基の存在下で芳香性アルデヒドと配合するステップ
および
(b)(a)の生成物を組成物に添加するステップ
を含む、前記方法。
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GB0611770.9 | 2006-06-15 | ||
PCT/CH2007/000294 WO2007143873A1 (en) | 2006-06-15 | 2007-06-13 | Fragrance compounds |
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GB0611770D0 (en) * | 2006-06-15 | 2006-07-26 | Givaudan Sa | Compounds |
WO2009124888A1 (en) * | 2008-04-07 | 2009-10-15 | Symrise Gmbh & Co. Kg | Use of carboxylic acid esters as a fragrance substance |
EP2512527A1 (en) * | 2009-12-17 | 2012-10-24 | The Procter & Gamble Company | Freshening compositions comprising malodor binding polymers and malodor control components |
CN103140208A (zh) * | 2010-06-25 | 2013-06-05 | 奇华顿股份有限公司 | 包含醛香料前体的包封组合物 |
US8414870B2 (en) | 2010-12-06 | 2013-04-09 | Sytheon, Ltd. | Benzylidene substituted 2,4-pentanedione compounds and use thereof as stabilizers |
US8617528B2 (en) | 2010-12-06 | 2013-12-31 | Sytheon Ltd. | Compositions and methods for stabilizing ingredients using 2,4-pentanedione compounds |
CN104284879A (zh) * | 2012-05-16 | 2015-01-14 | 索尔维公司 | 1-取代甲叉基化合物的制备 |
WO2016074118A1 (en) | 2014-11-10 | 2016-05-19 | Givaudan Sa | Improvements in or relating to organic compounds |
CN107074732B (zh) * | 2014-11-10 | 2020-08-18 | 奇华顿股份有限公司 | 有机化合物中或与之相关的改进 |
MX2017004871A (es) * | 2014-11-10 | 2017-07-04 | Givaudan Sa | Mejoramientos en o relacionados a compuestos organicos. |
WO2017214455A1 (en) * | 2016-06-08 | 2017-12-14 | Takasago International Corporation (Usa) | Fragrance material |
GB201620044D0 (en) * | 2016-11-28 | 2017-01-11 | Givaudan Sa | Improvements in or relating to organic compounds |
US11802258B2 (en) | 2017-09-25 | 2023-10-31 | Takasago International Corporation | Perfume precursor |
EP3533786A1 (en) | 2018-03-02 | 2019-09-04 | Givaudan SA | Thioether precursors for fragrant ketones and aldehydes |
BR112021010594A2 (pt) | 2018-12-17 | 2021-08-24 | Givaudan Sa | Método de combater o mau cheiro em uma máquina de lavar que compreende a adição de um precursor de fragrância |
CN113195697A (zh) | 2018-12-17 | 2021-07-30 | 奇华顿股份有限公司 | 加香方法 |
BR112021018601A2 (pt) | 2019-03-20 | 2021-11-23 | Firmenich & Cie | Compostos pró-perfume encapsulados |
JP2022539003A (ja) | 2019-06-27 | 2022-09-07 | フイルメニツヒ ソシエテ アノニム | 賦香された消費者製品 |
CN111333509B (zh) * | 2020-04-14 | 2022-06-10 | 东莞波顿香料有限公司 | 苹果风味化合物及其制备方法和食品添加剂 |
WO2022261956A1 (en) | 2021-06-18 | 2022-12-22 | Givaudan Sa | Fragrance compounds |
WO2023065203A1 (en) | 2021-10-21 | 2023-04-27 | Givaudan Sa | Organic compounds |
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KR20090024701A (ko) | 2009-03-09 |
US8575386B2 (en) | 2013-11-05 |
BRPI0713765B1 (pt) | 2017-04-18 |
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