JP5369614B2 - Extruder for powder raw material and method for producing thermoplastic resin composition - Google Patents

Description

  The present invention relates to an extruder for powder raw materials, and more specifically, by extruding a powder raw material having a low apparent density with high efficiency, and by a gas generated when molding a thermoplastic resin composition obtained after discharging from the extruder. The present invention relates to an extruder for reducing trouble and a method for producing a thermoplastic resin composition using the extruder.

  In general, a thermoplastic resin composition is made by adding a powdery reinforcing material such as a filler component to a thermoplastic resin and various function-imparting materials, granulated into pellets through an extruder, and then producing a product by a molding machine. Is done.

  However, when extruding a powder raw material that contains a thermoplastic resin or a large amount of powder reinforcing material, the apparent density is lower than that of the pellet-shaped raw material. Has inferior properties. For this reason, the amount of extrusion decreased, and efficient production could not be performed.

  Conventionally, the following techniques are known for extruding powder raw materials.

  For example, Patent Document 1 describes a method of using a screw configuration in which a single screw and a kneading block having a specific twist angle are combined to improve the productivity of a resin composition containing a filler component at a high concentration.

Patent Document 2 describes a method of using a screw configuration in which a single screw and a specific kneading block are arranged to improve the productivity of a resin composition using a powder raw material.
JP 9-29814 A JP-A-10-24483

  However, in the production methods described in Patent Document 1 and Patent Document 2, the space volume in the extruder is narrow, and there is a limit to improving the productivity.

Further, when the productivity is improved by the conventional technique, the deaeration in the extruder cannot be sufficiently performed, and the amount of gas contained in the thermoplastic resin composition increases. The thermoplastic resin composition pellets obtained by cutting after being discharged from the extruder are produced using a molding machine, but in general injection molding, from the thermoplastic resin composition pellets. When the amount of generated gas increases, there are problems that the surface appearance of the molded product is deteriorated and that the mold is frequently cleaned due to contamination on the mold.

  An object of the present invention is to further improve the extrusion efficiency in the prior art as described above, and to reduce the amount of gas generated in the thermoplastic resin composition obtained by cutting after discharging from the extruder. It is providing the manufacturing method of the thermoplastic resin composition which uses the machine and the extruder for powder raw materials.

The present inventors diligently studied to solve these problems, and reached the present invention. That is, the manufacturing method of the thermoplastic resin composition using the extruder for powder raw materials and the extruder for powder raw materials of the present invention is as follows.
1. A co-rotating twin-screw extruder having a screw configuration having a first conveying unit to which powder raw materials are supplied, two or more kneading units and two or more conveying units on the downstream side of the first conveying unit Having a screw element with a ratio D / d of at least one screw major axis D and screw minor axis d of 1.65 to 1.85 in the conveying unit, and the first kneading unit following the first conveying unit is The ratio L _m1 / D between the overall length L _m1 and the screw major axis D is 3 to 15, and the ratio W / D between the disk width W and the screw major axis D is 0.00 in the first kneading part. a 3 to 1, twist angle is 10 to 30 °, comprising an extruder for powder material having a kneading block of the right twist, polyphenylene sulfide and polyamide resin, a thermoplastic resin selected from polyester resin Supply powder raw material, kneading press Method for producing a thermoplastic resin composition.
2. 2. The thermoplastic resin composition according to 1 , wherein a raw material containing a powder raw material having an apparent density of 0.1 to 0.7 g / ml or an average particle diameter of 1 to 500 μm is supplied to an extruder for powder raw material and kneaded and extruded. Manufacturing method.
3. 3. The method for producing a thermoplastic resin composition according to 1 or 2, wherein the powder raw material contains 20 to 100% by weight of polyphenylene sulfide.
4). The ratio L _c1 / D of the overall length L _c1 of the first conveying unit and the screw major axis D is 4 to 20, and at least one of the constituent screw elements is the ratio of the screw major axis D to the screw minor axis d. The D / d is 1.65 to 1.85, and the ratio L ₁ / D between the lead length L ₁ and the screw major diameter D is 0.7 to 2, which is a single screw element. producing how the thermoplastic resin composition.
5 . 1 has a vent port in the conveyance section downstream of the first kneading section, and the conveyance section has a screw element having a ratio D / d of the screw major axis D to the screw minor axis d of 1.65 to 1.85. the method for producing a thermoplastic resin composition according to any one of 1 to 4.
6 . The manufacturing method of the thermoplastic resin composition in any one of 1-5 which has a vacuum vent downstream from the 2nd kneading part of the downstream of a 2nd conveyance part.

  Since the powder raw material extruder of the present invention is configured as described above, it has excellent extrusion efficiency and can reduce the amount of gas generated in the thermoplastic resin composition obtained by cutting after discharge from the extruder. .

  The present invention is a co-rotating twin-screw extruder for a powder raw material, and includes a first transport unit, two or more kneading units on the downstream side of the first transport unit, and two or more transport units. It relates to an extruder.

  In the present invention, the screw configuration has a great feature, and as the screw of the conveying portion, a flight-like screw element that is usually used for the conveying portion, such as a single screw element, a double screw element, or a triple screw element, is used. Although it is possible, it is important to have a screw element having a ratio D / d of the screw major axis D to the screw minor axis d of 1.65 to 1.85 in at least a part of the conveying unit.

  The ratio D / d between the screw major axis D and the screw minor axis d can be used as an index indicating the space volume in the extruder. When supplying the powder raw material to the extruder, the larger the space volume in the extruder, the higher the biting property of the raw material, and the higher the extrusion efficiency. Accordingly, D / d is preferably 1.65 to 1.85, and more preferably D / d is 1.75 to 1.85.

Further, in order to reduce the amount of gas generated thermoplastic resin composition obtained by cutting after discharge from the extruder, performs the degassing from a vent was attached to the transport unit of the extruder, increase the degassing efficiency For this purpose, it is effective to increase the resin surface area. By setting D / d of the screw element to 1.65 to 1.85, the resin surface area in the screw groove portion is increased, and deaeration can be performed effectively. More preferably, D / d is 1.75 to 1.85.

In addition, the larger the D / d, the larger the space volume and the higher the extrusion efficiency, and the higher the deaeration efficiency. However, if the thickness of the screw shaft and the screw groove is too thin, the strength becomes insufficient and the screw segment becomes D / d needs to be 1.85 or less because it may cause troubles such as cracking or bending of the screw shaft.

  Hereinafter, embodiments of the powder raw material extruder according to the present invention will be described with reference to the drawings.

  FIG. 1 shows an apparatus schematic diagram of a co-rotating twin-screw extruder 1 according to an embodiment of the present invention. The extruder 1 is a twin-screw extruder that can change the screw configuration by rearranging the segmented screws, and is mixed with a first conveying unit 4 that conveys the powder raw material supplied from the supply port 2 and mixed with the powder. A first kneading part 5 for melting at least a part of the body material, a second conveying part 6 having an open vent vent 9, a second kneading part 7 for kneading and melting, and a third conveying part having a vacuum vent 10 8.

The length of the extruder 1 is preferably such that the ratio L / D between the overall length L and the screw major diameter D is 20 to 70. If the L / D is less than 20, the degassing part is shortened or it is difficult to apply the side feed method when supplying a fibrous reinforcing material. If the L / D exceeds 70, thermal degradation of the resin occurs. It becomes easy.

The 1st conveyance part 4 is a part which makes a powder raw material bit into an extruder. As the screw, a flight-like screw element that is usually used in a conveying section such as a single screw element or a double screw element can be used, but the D / d of at least one screw element is 1.65 to 1.85. It is preferable to use a screw element in order to increase the extrusion efficiency. The ratio L _c1 / D between the total length L _c1 and the screw diameter D of the first feeding section is preferably 7-20, more preferably from 7.0 to 20.0. Moreover, it is preferable that ratio L / D of the whole length L of a screw with D / d of 1.65 to 1.85 and a screw major axis is 4-20, More preferably, it is 4.0-20.0. It is.

Moreover, it is preferable to use a single screw element with a high conveyance capability for the first conveying unit, and the lead length of the single screw element is such that the ratio L _l / D of the L _l and the screw major diameter D is 0.7-2. Preferably, the ratio L / D between the overall length L of the single screw element and the screw major diameter D is preferably 4 to 20, and more preferably 4.0 to 20.0. If the L / D of the lead length of the single screw is less than 0.7, the conveying capacity is lowered. If the lead length L / D exceeds 2, the conveying capacity is too large and the molten state in the first kneading part. Will become unstable and cause trouble. Further, if the L / D of the entire length of the single screw is less than 4, the conveying ability is lowered, and even if the L / D of the entire length exceeds 20, further improvement of the conveying ability cannot be expected.

  As a more preferable form, it is preferable to dispose a single screw element from the lower part of the supply port 2 which is the upstream side of the first transport unit 4. In this case, a double screw can be used on the downstream side of the first conveying unit 4, but when used simultaneously with the single screw, it can be used via a transition screw element.

  In addition, a double screw can also be used for the 1st conveyance part 4 independently.

The first kneading part 5 following the first transport part 4 is a part for applying a shearing force to the powder resin and kneading. As the screw used in the first kneading part 5, a screw element usually used in the kneading part such as a kneading block or a mixing screw can be used. The length of the first mixing section, Ri 3.0 to 15 der ratio L _m1 / D and its overall length _{L m1} and the screw diameter D, 3.5 to 15.0 virtuous preferable.

  In the first kneading section, a combination of a right twist kneading block and a neutral kneading block is particularly preferably used. Preferably, at least a part of the kneading block is a right twist kneading block, and the disk width W and screw A disk having a W / D ratio of 0.3 to 1.0 indicating a ratio to the major axis D is disposed at a twist angle of 10 to 30 °, and L / of the entire length of the kneading block portion of the right twist. It is preferable to have a screw configuration in which D is 3.0 to 15.0. If W / D is less than 0.3, sufficient shearing force is not applied and the molten state becomes unstable, causing trouble. On the other hand, if W / D exceeds 1.0, a sufficient propulsive force cannot be obtained and the resin stays, causing a trouble that powder flows into the supply port 2 and backflows together with air. Also, if the twist angle is less than 10 °, sufficient propulsive force cannot be obtained and the resin stays, causing the trouble that powder flows into the supply port 2 and backflows with air. The body causes trouble that the powder is ejected from the vent opening 9 through the gap between the disks. If the total length L / D is less than 3.0, the molten state is insufficient, and if it exceeds 15.0, the resin is completely melted, and the powder enters the supply port 2 and flows back together with air. Cause trouble.

The second transport unit 6 is a part that removes air entrained in the extruder together with the powder material and volatile components contained in the powder material from the vent port 9. As the screw, a double screw element, a triple screw element, or the like, a flight-like screw element that is usually used in a conveyance unit can be used, but at least one screw element has a D / d of 1.65 to 1.85. It is preferable to use the screw element in order to increase the deaeration efficiency. More preferably, a screw element having a D / d of 1.75 to 1.85 is used. Further, the length L / D is preferably 2 to 10, and more preferably 2.0 to 10.0.

  The vent port 9 attached to the second transport unit 6 may be an air vent or a vacuum vent. However, when the powder raw material is sucked by the vacuum vent, the air vent is preferably used. Can be used.

  The second kneading part 7 is a part for applying a shearing force to the powder resin to melt and knead it, and is a part for obtaining a kneading state appropriate for the thermoplastic resin composition. Similar to the screw used in the first kneading unit 5, a screw element normally used in the kneading unit such as a kneading block or a mixing screw can be used. Further, the length is preferably L / D = 2 to 10, and more preferably 2.0 to 10.0.

The third transport unit 8 is a part that removes, from the vent port 10, volatile components contained in the powder raw material, volatile components generated by thermal decomposition of the raw material, and the like. As the screw, a double screw element, a triple screw element, or the like, a flight-like screw element that is usually used in a conveyance unit can be used, but at least one screw element has a D / d of 1.65 to 1.85. It is preferable to use the screw element in order to increase the deaeration efficiency. More preferably, D / d is 1.75 to 1.85. Further, the length is preferably L / D = 2 to 10, and more preferably 2.0 to 10.0.

The vent port 10 attached to the third transport unit 8 may be an air vent vent or a vacuum vent, but a vacuum vent can be preferably used in order to increase the deaeration efficiency.

  Further, in the configuration of the screw 3, when a screw element or kneading block having a different D / d is used in combination, a step may be generated between the screw segments due to the difference in D / d. The step may cause the resin to stagnate and generate carbides or damage the screw segment. Therefore, when combining screw segments having different D / d, it is also possible to use a transition element that changes the inner diameter and smoothly connects the screw segments.

  Further, in order to improve the properties such as mechanical strength of the thermoplastic resin composition, a reinforcing material may be blended. By using the extruder of the present invention, for example, as shown in FIG. It is also possible to apply a side feed method in which a reinforcing material is mixed. In that case, the 1st conveyance part 4 which conveys the powder raw material supplied from the supply port 2, the 1st kneading part 5 which knead | mixes and melt | dissolves at least one part, and the 2nd conveyance which has the air release vent port 9 Part 6, second kneading part 7 for kneading and melting, third conveying part 8 for conveying the reinforcing material supplied from supply port 12, third kneading part 13 for dispersing the reinforcing material, and vacuum vent port 10 The screw structure which has the 4th conveyance part 14 to have is applicable.

  The manufacturing method of a thermoplastic resin composition is demonstrated using the extruder 1 of this invention.

  The powder raw material supplied from the supply port 2 is conveyed while being melt-kneaded toward the discharge port 11 by heating the extruder barrel and rotating the screw 3. The raw materials are uniformly melt-kneaded in the kneading zone 5 and kneading zone 7 or the kneading zone 13 to form a thermoplastic resin composition. The thermoplastic resin composition is discharged from the discharge port 11 and pelletized by a granulator or sent to a directly connected molding apparatus.

  In the melt kneading production method of the thermoplastic resin composition as described above, the barrel temperature of the extruder is also important, and is set to the melting point temperature of the powder raw material to 350 ° C. or lower, or the glass transition temperature to 350 ° C. or lower. It is preferable to do so. If the barrel temperature is too low, the kneading state of the powder raw material tends to be unstable, while if too high, adverse effects such as thermal decomposition of the resin may occur.

  The extruder of the present invention is suitable for melt kneading of powder raw materials. Here, examples of the powder raw material include a powder resin. Specific examples of the powder resin include polyolefin resins (high density polyethylene, low density polyethylene, polypropylene, etc.) polyphenylene ether, polyphenylene sulfide, polyamide resins (nylon 6, nylon 66, etc.), polyester resins (polyethylene terephthalate, poly Butylene terephthalate, polybutylene naphthalate, polycarbonate, etc.), polyoxymethylene (polyacetal, etc.), acrylonitrile / butadiene / styrene copolymer, polystyrene, liquid crystal plastic, etc. can be employed.

  It is also effective for powder raw materials in which powder resin and powder filler are mixed. As a powder filler, what is conventionally used as a powder filler of a thermoplastic resin composition can be used, and a silicate mineral, a silicate mineral, and various minerals are pulverized by processing such as grinding. Needle-like and granular ones are preferably used. Specific examples include bentonite, dolomite, montmorillonite, barlite, finely divided silicic acid, aluminum silicate, silicon oxide, dosonite, shirasu balloon, clay, sericite, feldspar, talc, calcium carbonate, lithium carbonate, kaolin, zeolite ( (Including synthetic zeolite), talc, mica, synthetic mica and wollastonite (including synthetic wollastonite), glass flakes, glass beads, hydrotalcite and silica.

  In the method for producing a thermoplastic resin composition using the extruder of the present invention, the raw material supplied from the supply port 2 is, in particular, an apparent density of 0.1 to 0.7 g / ml, or an average particle size of 1 to 1. This is effective when the raw material contains a bulky powder of 500 μm. In addition, an apparent density says the value measured by the method shown by JISK7365, and an average particle diameter says the value measured by the method shown by JISK5600-9-3.

  The raw material of the thermoplastic resin composition of the present invention contains the above powder raw material, and in addition to the powder raw material, raw materials such as pellets and fibers may be used in combination.

  Further, the reinforcing material is supplied from the supply port 2 and / or the supply port 12. However, in the case of a material that is easily cut when a strong shearing force is applied, such as a fibrous reinforcing material, it is preferably supplied from the supply port 12. The type of the reinforcing material is not particularly limited, and those conventionally used as reinforcing fibers of thermoplastic resin compositions can be used. Specific examples include glass fibers, carbon fibers, asbestos fibers, carbon fibers, Graphite fiber, metal fiber, potassium titanate whisker, aluminum borate whisker, magnesium-based whisker, silicon-based whisker, slag fiber, gypsum fiber, silica fiber, silica-alumina fiber, zirconia fiber, boron nitride fiber, silicon nitride fiber and boron Inorganic reinforcing fiber such as fiber, polyester fiber, nylon fiber, acrylic fiber, regenerated cellulose fiber, acetate fiber, kenaf, ramie, cotton, jute, hemp, sisal, flax, linen, silk, manila hemp, sugar cane, wood pulp, paper waste, Organic reinforcing fibers such as waste paper and wool It is below.

  Furthermore, an additional component can be added from the supply port 2 and / or the supply port 12. For example, an elastomer, a flame retardant, an antioxidant, a weather resistance improver, a release agent, an antistatic agent, a nucleating agent, a coloring agent, and the like can be added.

  Next, the effects of the present invention will be specifically described with reference to Examples and Comparative Examples.

  The extruder used was a twin screw extruder (TEX44, L / D = 35.0) manufactured by Nippon Steel Works, Ltd., and the powder raw material was supplied from the supply port 2, and the vent port 9 was opened to the atmosphere. The strand-shaped resin composition discharged through an extruder having 10 as a vacuum vent was water-cooled and solidified to form thermoplastic resin composition pellets with a granulator.

  The screw configuration is such that the length L / D of the first transport unit 4, the first kneading unit 5, the second transport unit 6, the second kneading unit 7, and the third transport unit 8 is 10.5, 5. The experiment was conducted by changing the D / d of the conveying unit and the kneading unit as shown in Table 1 in various ways.

  The discharge amount was measured by setting the screw rotation speed of the extruder at 350 rpm and the barrel temperature at a constant 300 ° C., and measuring the discharge amount at which the powder raw material was not caught.

  Moreover, the thermoplastic resin composition pellets were treated at 320 ° C. for 2 hours, and the loss on heating was measured from the change in weight before and after the treatment.

  The powder raw materials used in Examples 1 to 3 and Comparative Examples 1 to 3 were an apparent density of 0.39 g / ml, an average particle size of 60 μm polyphenylene sulfide (L4230 manufactured by Toray Industries, Inc.), 60 wt%, and an apparent density. A mixed powder material having an apparent density of 0.41 g / ml and an average particle size of 30 μm, obtained by mixing 40 wt% of 0.43 g / ml calcium carbonate (KS-1000 manufactured by Calfine Co., Ltd.) having an average particle size of 5 μm. used. The apparent density was measured by the method shown in JIS K7365, and the average particle size was measured by the method shown in JIS K5600-9-3. Moreover, in the comparative example 4, the said mixed powder raw material was used, the strand-shaped resin composition discharged through the extruder was water-cooled solidified, and the pellet obtained by pelletizing with a granulator was used as a raw material.

  From Table 1, it can be seen that, compared with the comparative example, the example has an increased discharge amount and excellent extrusion efficiency, and can reduce the amount of gas generated in the thermoplastic resin composition obtained by cutting after discharge from the extruder.

It is a cross-sectional view of an example of an extruder used in the present invention. It is a cross-sectional view of an example of an extruder to which the side feeder used in the present invention is applied. The top view and side view of a single screw element used for the conveyance part of this invention. The top view and side view of a double screw element used for the conveyance part of this invention. The top view and side view of a kneading block used for the kneading part of this invention.

Explanation of symbols

1: Extruder 2: Supply port 3: Screw 4: First transport unit 5: First kneading unit 6: Second transport unit 7: Second kneading unit 8: Third transport unit 9: Vent port 10: Vent port 11 : Discharge port 12: Second supply port 13: Third kneading section 14: Fourth transport section

Claims (6)

A co-rotating twin-screw extruder having a screw configuration having a first conveying unit to which powder raw materials are supplied, two or more kneading units and two or more conveying units on the downstream side of the first conveying unit Having a screw element with a ratio D / d of at least one screw major axis D and screw minor axis d of 1.65 to 1.85 in the conveying unit, and the first kneading unit following the first conveying unit is The ratio L _m1 / D between the overall length L _m1 and the screw major axis D is 3 to 15, and the ratio W / D between the disk width W and the screw major axis D is 0.00 in the first kneading part. A powder containing a thermoplastic resin selected from polyphenylene sulfide, polyamide-based resin and polyester-based resin in an extruder for powder raw material having a kneading block with a right twist having a twist angle of 10 to 30 which is 3 to 1 Supply body materials, kneading extrusion Method for producing a thermoplastic resin composition that. The thermoplastic resin according to claim 1 , wherein a raw material containing a powder raw material having an apparent density of 0.1 to 0.7 g / ml or an average particle diameter of 1 to 500 µm is supplied to an extruder for powder raw material and kneaded and extruded. A method for producing a resin composition.   The method for producing a thermoplastic resin composition according to claim 1 or 2, wherein the powder raw material contains 20 to 100% by weight of polyphenylene sulfide. The ratio L _c1 / D of the overall length L _c1 of the first conveying unit and the screw major axis D is 4 to 20, and at least one of the constituent screw elements is the ratio of the screw major axis D to the screw minor axis d. The D / d is 1.65 to 1.85, and the ratio L _l / D between the lead length L _l and the screw major diameter D is a single screw element of 0.7 to 2. 4. The manufacturing method of the thermoplastic resin composition as described in any one of. The conveyance part on the downstream side of the first kneading part has a vent port, and the conveyance part has a screw element having a ratio D / d of the screw major axis D to the screw minor axis d of 1.65 to 1.85. Item 5. A method for producing a thermoplastic resin composition according to any one of Items 1 to 4 . The method for producing a thermoplastic resin composition according to any one of claims 1 to 5 , further comprising a vacuum vent on the downstream side of the second kneading part on the downstream side of the second transport part.

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