JP5364972B2 - プリント配線板の製造方法 - Google Patents
プリント配線板の製造方法 Download PDFInfo
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- JP5364972B2 JP5364972B2 JP2006310154A JP2006310154A JP5364972B2 JP 5364972 B2 JP5364972 B2 JP 5364972B2 JP 2006310154 A JP2006310154 A JP 2006310154A JP 2006310154 A JP2006310154 A JP 2006310154A JP 5364972 B2 JP5364972 B2 JP 5364972B2
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- Prior art keywords
- printed wiring
- wiring board
- resin
- metal foil
- weight
- Prior art date
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 33
- 238000000034 method Methods 0.000 title claims abstract description 23
- 229910052751 metal Inorganic materials 0.000 claims abstract description 50
- 239000002184 metal Substances 0.000 claims abstract description 50
- 239000011888 foil Substances 0.000 claims abstract description 43
- 229910000679 solder Inorganic materials 0.000 claims abstract description 35
- 238000007788 roughening Methods 0.000 claims abstract description 32
- 238000010030 laminating Methods 0.000 claims abstract description 12
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- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 27
- 239000002245 particle Substances 0.000 claims description 27
- 239000011889 copper foil Substances 0.000 claims description 26
- 239000000853 adhesive Substances 0.000 claims description 25
- 230000001070 adhesive effect Effects 0.000 claims description 24
- 239000000126 substance Substances 0.000 claims description 19
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 16
- 229920002554 vinyl polymer Polymers 0.000 claims description 14
- 239000011354 acetal resin Substances 0.000 claims description 13
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- DHKHKXVYLBGOIT-UHFFFAOYSA-N 1,1-Diethoxyethane Chemical compound CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 11
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- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical class C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 claims description 7
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
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- 125000003118 aryl group Chemical group 0.000 description 4
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 4
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- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- 239000004962 Polyamide-imide Substances 0.000 description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 3
- 125000003277 amino group Chemical group 0.000 description 3
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- 235000010290 biphenyl Nutrition 0.000 description 3
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- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 3
- 125000003700 epoxy group Chemical group 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
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- JHWIEAWILPSRMU-UHFFFAOYSA-N 2-methyl-3-pyrimidin-4-ylpropanoic acid Chemical compound OC(=O)C(C)CC1=CC=NC=N1 JHWIEAWILPSRMU-UHFFFAOYSA-N 0.000 description 2
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- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 2
- ZNBNBTIDJSKEAM-UHFFFAOYSA-N 4-[7-hydroxy-2-[5-[5-[6-hydroxy-6-(hydroxymethyl)-3,5-dimethyloxan-2-yl]-3-methyloxolan-2-yl]-5-methyloxolan-2-yl]-2,8-dimethyl-1,10-dioxaspiro[4.5]decan-9-yl]-2-methyl-3-propanoyloxypentanoic acid Chemical compound C1C(O)C(C)C(C(C)C(OC(=O)CC)C(C)C(O)=O)OC11OC(C)(C2OC(C)(CC2)C2C(CC(O2)C2C(CC(C)C(O)(CO)O2)C)C)CC1 ZNBNBTIDJSKEAM-UHFFFAOYSA-N 0.000 description 2
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- QHWKHLYUUZGSCW-UHFFFAOYSA-N Tetrabromophthalic anhydride Chemical compound BrC1=C(Br)C(Br)=C2C(=O)OC(=O)C2=C1Br QHWKHLYUUZGSCW-UHFFFAOYSA-N 0.000 description 1
- SIZDMAYTWUINIG-UHFFFAOYSA-N [4-[1-(4-cyanatophenyl)ethyl]phenyl] cyanate Chemical compound C=1C=C(OC#N)C=CC=1C(C)C1=CC=C(OC#N)C=C1 SIZDMAYTWUINIG-UHFFFAOYSA-N 0.000 description 1
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- 229910001430 chromium ion Inorganic materials 0.000 description 1
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- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- PPTYNCJKYCGKEA-UHFFFAOYSA-N dimethoxy-phenyl-prop-2-enoxysilane Chemical compound C=CCO[Si](OC)(OC)C1=CC=CC=C1 PPTYNCJKYCGKEA-UHFFFAOYSA-N 0.000 description 1
- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical compound C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
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- 238000005868 electrolysis reaction Methods 0.000 description 1
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- 150000002148 esters Chemical class 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- 239000004210 ether based solvent Substances 0.000 description 1
- UHKJHMOIRYZSTH-UHFFFAOYSA-N ethyl 2-ethoxypropanoate Chemical compound CCOC(C)C(=O)OCC UHKJHMOIRYZSTH-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
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- 238000005040 ion trap Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000005453 ketone based solvent Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- MQWFLKHKWJMCEN-UHFFFAOYSA-N n'-[3-[dimethoxy(methyl)silyl]propyl]ethane-1,2-diamine Chemical compound CO[Si](C)(OC)CCCNCCN MQWFLKHKWJMCEN-UHFFFAOYSA-N 0.000 description 1
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- NXPPAOGUKPJVDI-UHFFFAOYSA-N naphthalene-1,2-diol Chemical compound C1=CC=CC2=C(O)C(O)=CC=C21 NXPPAOGUKPJVDI-UHFFFAOYSA-N 0.000 description 1
- 125000005609 naphthenate group Chemical group 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000010680 novolac-type phenolic resin Substances 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- QBDSZLJBMIMQRS-UHFFFAOYSA-N p-Cumylphenol Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=CC=C1 QBDSZLJBMIMQRS-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
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- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001230 polyarylate Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
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- 229940095064 tartrate Drugs 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
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- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- NJMOHBDCGXJLNJ-UHFFFAOYSA-N trimellitic anhydride chloride Chemical compound ClC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 NJMOHBDCGXJLNJ-UHFFFAOYSA-N 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
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Images
Landscapes
- Non-Metallic Protective Coatings For Printed Circuits (AREA)
- Manufacturing Of Printed Wiring (AREA)
Description
(実施例1)
下記の組成よりなる樹脂組成物Aを作成した。
(樹脂組成物A)
・エポキシ樹脂,NC3000S−H(日本化薬株式会社製) 65重量部
・カルボン酸変性アクリロニトリルブタジエンゴム粒子,XER−91SE−15(JSR株式会社製) 5重量部
・カルボン酸変性ポリビニルアセタール樹脂,KS−23Z(積水化学工業株式会社製) 5重量部
・フェノール樹脂,フェノライトEXB−9829(窒素含有量18重量%,水酸基当量151,大日本インキ化学工業株式会社製) 20重量部
・アミン化合物,1,8−ジアザビシクロウンデセン,DBU(関東化学株式会社製) 0.3重量部
・溶剤,メチルエチルケトン 150重量部
(接着補助剤付金属箔A)
電解銅箔(F0−WS−18,古河サーキットフォイル株式会社製,18μm厚、Rz=1.8μm)のシランカップリング剤処理された被接着面に樹脂組成物Aを塗工した。塗工後は残溶剤が5重量%以下になるように160℃で10分程度の乾燥を行った。塗工した樹脂組成物Aの厚みは3.0μmであった。
実施例1において,接着補助剤付金属箔Aを作製する際,樹脂組成物Aを8μmの厚みに塗布したこと以外は実施例1と同様に基板を作製した。
実施例1において,エポキシ樹脂(NC3000S−H)の配合量を80重量部,カルボン酸変性アクリロニトリルブタジエンゴム粒子(XER−91SE−15)の配合量を2重量部,カルボン酸変性ポリビニルアセタール樹脂(KS−23Z)の配合量を5重量部,トリアジン環含有クレゾールノボラック型フェノール樹脂(フェノライトEXB−9829)の配合量を13重量部、アミン化合物 DBUの配合量を0.3量部、メチルエチルケトンの配合量を150重量部とした。その他は,実施例1と同様にして行った。
実施例1において,カルボン酸変性アクリロニトリルブタジエンゴム粒子(XER−91SE−15)5重量部の代わりに,ブタジエンゴム−アクリル樹脂のコアシェル粒子,EXL−2655(呉羽化学工業株式会社)5重量部を用いた。その他は,実施例1と同様にして行った。
実施例1において,トリアジン環含有クレゾールノボラック型フェノール樹脂20重量部の代わりに,フェノールノボラック樹脂,HP−850N(日立化成工業株式会社)15重量部を用いた。その他は,実施例1と同様にして行った。
実施例1において,ビフェニル構造を有するノボラック型エポキシ樹脂(NC3000S−H)の配合量を55重量部,トリアジン環含有クレゾールノボラック型フェノール樹脂(フェノライトEXB−9829)の配合量を15重量部とし,さらにフェノール性水酸基含有リン化合物,HCA−HQ(三光株式会社製)15重量部とした。その他は,実施例1と同様にして行った。
実施例1において,ソルダーレジストを太陽インキ製造株式会社製 PFR−800AUS402(30μm)に変更し、下記表3の条件で積層した。その他は,実施例1と同様にして行った。
実施例1において,化学粗化を行わないでソルダーレジストを積層した。その他は,実施例1と同様にして行った。
接着補助剤付金属箔Aを積層する代わりに電解銅箔(F0−WS−18)を積層し,化学粗化を行わないでソルダーレジストを積層した以外は実施例1と同様に基板を作製した。
接着補助剤付金属箔Aを積層する代わりに電解銅箔(F3−WS−18、Rz=3.3μm)を積層し,化学粗化を行わないでソルダーレジストを積層した以外は実施例1と同様に基板を作製した。
実施例1〜7,比較例1〜3用基板及び評価用サンプルの吸湿耐熱試験を行った。基板の試験は各サンプルを121℃,湿度100%,2気圧の条件で2時間処理し,その後260℃のはんだ浴に20秒浸漬して,ソルダーレジストに膨れ等が発生しないかどうかの確認を行った。試験には平山製作所製飽和型PCT装置PC−242を用いた。
実施例1〜7,比較例1〜3用基板及び評価用サンプルの長期吸湿試験を行った。基板の試験は各サンプルを121℃,湿度100%,2気圧の条件で196時間処理し,ソルダーレジストに膨れ等が発生しないかどうかの確認を行った。試験には平山製作所製飽和型PCT装置PC−242を用いた。
実施例1〜7,比較例1〜3用の評価サンプルの導体引き剥がし強さを測定した。引き剥がしは垂直引き剥がし強さを測定した。測定は常に20℃で行った。測定は,島津製作所(株)製オートグラフAC−100型を用い,引き剥がし速度50mm/min,試験幅5mmで行った。
試験結果を下記表4に示す。実施例1〜7で作製した基板及び評価用サンプルはソルダーレジストの膨れ等は発生せず,導体引き剥がし強さはすべて0.6kN/m以上と高い値であった。一方比較例1で得られた基板は吸湿耐熱試験後ソルダーレジストと絶縁樹脂の間で膨れが発生した。
2:ソルダーレジスト
3:接着補助剤
4:プリプレグ
Claims (7)
- 表面の十点平均粗さ(Rz)が2.0μm以下の金属箔を用いるプリント配線板の製造方法において、
前記金属箔とプリプレグの間に化学粗化可能な接着補助剤の層を形成する工程を有し、前記接着補助剤が、(A)エポキシ樹脂、(B)化学粗化可能な高分子成分、(C)エポキシ樹脂硬化剤、及び(D)硬化促進剤を含み、前記(B)成分が、ポリビニルアセタール樹脂およびカルボン酸変性ポリビニルアセタール樹脂から選択される少なくとも一種を含み、
さらにソルダーレジストを塗布または積層する際の前処理として、ソルダーレジストとの界面となる前記接着補助剤の層に粗化処理を施す工程を有することを特徴とするプリント配線板の製造方法。 - 表面の十点平均粗さ(Rz)が2.0μm以下の金属箔が、粗化処理を施していない銅箔である、請求項1に記載のプリント配線板の製造方法。
- 前記接着補助剤の層を形成する工程において、前記金属箔と前記プリプレグの間に厚さ0.1〜50μmの前記接着補助剤の層を形成することを特徴とする請求項1または2に記載のプリント配線板の製造方法。
- 前記(B)成分が、さらに、架橋ゴム粒子を含むことを特徴とする請求項1に記載のプリント配線板の製造方法。
- 前記架橋ゴム粒子が、カルボン酸変性アクリロニトリルブタジエンゴム粒子及びブタジエンゴム−アクリル樹脂のコアシェル粒子から選択される少なくとも一種を含むことを特徴とする請求項4に記載のプリント配線板の製造方法。
- 前記接着補助剤において、前記(A)成分100重量部に対し、前記(B)成分が0.5〜25重量部含有されている、請求項1〜5のいずれかに記載のプリント配線板の製造方法。
- ソルダーレジストを塗布または積層する際の前処理としての粗化処理が、アルカリ過マンガン酸塩水溶液での粗化処理である請求項1〜6のいずれかに記載のプリント配線板の製造方法。
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