JP5270359B2 - 低温用途向けパーフルオロエラストマー組成物 - Google Patents
低温用途向けパーフルオロエラストマー組成物 Download PDFInfo
- Publication number
- JP5270359B2 JP5270359B2 JP2008537876A JP2008537876A JP5270359B2 JP 5270359 B2 JP5270359 B2 JP 5270359B2 JP 2008537876 A JP2008537876 A JP 2008537876A JP 2008537876 A JP2008537876 A JP 2008537876A JP 5270359 B2 JP5270359 B2 JP 5270359B2
- Authority
- JP
- Japan
- Prior art keywords
- composition
- perfluoroelastomer
- perfluoro
- mole percent
- vinyl ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 62
- 229920006169 Perfluoroelastomer Polymers 0.000 title claims description 36
- -1 perfluoro Chemical group 0.000 claims description 26
- 239000010702 perfluoropolyether Substances 0.000 claims description 22
- 239000000178 monomer Substances 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 12
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 7
- 150000002825 nitriles Chemical class 0.000 claims description 7
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 4
- 150000002170 ethers Chemical class 0.000 claims description 4
- 150000003606 tin compounds Chemical class 0.000 claims description 2
- BLTXWCKMNMYXEA-UHFFFAOYSA-N 1,1,2-trifluoro-2-(trifluoromethoxy)ethene Chemical compound FC(F)=C(F)OC(F)(F)F BLTXWCKMNMYXEA-UHFFFAOYSA-N 0.000 description 21
- 238000004132 cross linking Methods 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- 150000001451 organic peroxides Chemical class 0.000 description 7
- 150000002978 peroxides Chemical class 0.000 description 7
- 239000000654 additive Substances 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000007906 compression Methods 0.000 description 5
- 230000006835 compression Effects 0.000 description 5
- 229920001973 fluoroelastomer Polymers 0.000 description 5
- 229920002313 fluoropolymer Polymers 0.000 description 5
- 239000004811 fluoropolymer Substances 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000000945 filler Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 230000009477 glass transition Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- 230000004580 weight loss Effects 0.000 description 3
- KHXKESCWFMPTFT-UHFFFAOYSA-N 1,1,1,2,2,3,3-heptafluoro-3-(1,2,2-trifluoroethenoxy)propane Chemical compound FC(F)=C(F)OC(F)(F)C(F)(F)C(F)(F)F KHXKESCWFMPTFT-UHFFFAOYSA-N 0.000 description 2
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 2
- AYCANDRGVPTASA-UHFFFAOYSA-N 1-bromo-1,2,2-trifluoroethene Chemical group FC(F)=C(F)Br AYCANDRGVPTASA-UHFFFAOYSA-N 0.000 description 2
- HSTOKWSFWGCZMH-UHFFFAOYSA-N 3,3'-diaminobenzidine Chemical compound C1=C(N)C(N)=CC=C1C1=CC=C(N)C(N)=C1 HSTOKWSFWGCZMH-UHFFFAOYSA-N 0.000 description 2
- GVCWGFZDSIWLMO-UHFFFAOYSA-N 4-bromo-3,3,4,4-tetrafluorobut-1-ene Chemical compound FC(F)(Br)C(F)(F)C=C GVCWGFZDSIWLMO-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KSSJBGNOJJETTC-UHFFFAOYSA-N COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC Chemical compound COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC KSSJBGNOJJETTC-UHFFFAOYSA-N 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000001565 modulated differential scanning calorimetry Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- JMGNVALALWCTLC-UHFFFAOYSA-N 1-fluoro-2-(2-fluoroethenoxy)ethene Chemical compound FC=COC=CF JMGNVALALWCTLC-UHFFFAOYSA-N 0.000 description 1
- LYIPDZSLYLDLCU-UHFFFAOYSA-N 2,2,3,3-tetrafluoro-3-[1,1,1,2,3,3-hexafluoro-3-(1,2,2-trifluoroethenoxy)propan-2-yl]oxypropanenitrile Chemical compound FC(F)=C(F)OC(F)(F)C(F)(C(F)(F)F)OC(F)(F)C(F)(F)C#N LYIPDZSLYLDLCU-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- ODBCKCWTWALFKM-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhex-3-yne Chemical compound CC(C)(C)OOC(C)(C)C#CC(C)(C)OOC(C)(C)C ODBCKCWTWALFKM-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- WPXLSICRBPNKEI-UHFFFAOYSA-N OC(=O)OC(C)CC(C)(C)OOC(C)(C)C Chemical compound OC(=O)OC(C)CC(C)(C)OOC(C)(C)C WPXLSICRBPNKEI-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000005394 methallyl group Chemical group 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- BLYOHBPLFYXHQA-UHFFFAOYSA-N n,n-bis(prop-2-enyl)prop-2-enamide Chemical compound C=CCN(CC=C)C(=O)C=C BLYOHBPLFYXHQA-UHFFFAOYSA-N 0.000 description 1
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000006551 perfluoro alkylene group Chemical group 0.000 description 1
- 229920005548 perfluoropolymer Polymers 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000011417 postcuring Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000001721 transfer moulding Methods 0.000 description 1
- KJWHEZXBZQXVSA-UHFFFAOYSA-N tris(prop-2-enyl) phosphite Chemical compound C=CCOP(OCC=C)OCC=C KJWHEZXBZQXVSA-UHFFFAOYSA-N 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/002—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds
- C08G65/005—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds containing halogens
- C08G65/007—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds containing halogens containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/18—Homopolymers or copolymers or tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G2650/28—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type
- C08G2650/46—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type containing halogen
- C08G2650/48—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type containing halogen containing fluorine, e.g. perfluropolyethers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/257,539 | 2005-10-25 | ||
| US11/257,539 US7381774B2 (en) | 2005-10-25 | 2005-10-25 | Perfluoroelastomer compositions for low temperature applications |
| PCT/US2006/041468 WO2007050600A1 (en) | 2005-10-25 | 2006-10-25 | Perfluoroelastomer compositions for low temperature applications |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009513784A JP2009513784A (ja) | 2009-04-02 |
| JP2009513784A5 JP2009513784A5 (OSRAM) | 2009-10-08 |
| JP5270359B2 true JP5270359B2 (ja) | 2013-08-21 |
Family
ID=37703866
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008537876A Active JP5270359B2 (ja) | 2005-10-25 | 2006-10-25 | 低温用途向けパーフルオロエラストマー組成物 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US7381774B2 (OSRAM) |
| EP (1) | EP1951808B1 (OSRAM) |
| JP (1) | JP5270359B2 (OSRAM) |
| DE (1) | DE602006006093D1 (OSRAM) |
| WO (1) | WO2007050600A1 (OSRAM) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009133770A1 (ja) * | 2008-04-30 | 2009-11-05 | Dic株式会社 | 活性エネルギー線硬化型塗料組成物、その硬化物、及び新規硬化性樹脂 |
| US8318850B2 (en) * | 2009-02-26 | 2012-11-27 | E I Du Pont De Nemours And Company | Cured perfluoroelastomer article |
| FI20096134A0 (fi) | 2009-11-03 | 2009-11-03 | Pulse Finland Oy | Säädettävä antenni |
| FI20096251A0 (sv) | 2009-11-27 | 2009-11-27 | Pulse Finland Oy | MIMO-antenn |
| US8847833B2 (en) | 2009-12-29 | 2014-09-30 | Pulse Finland Oy | Loop resonator apparatus and methods for enhanced field control |
| FI20105158L (fi) | 2010-02-18 | 2011-08-19 | Pulse Finland Oy | Kuorisäteilijällä varustettu antenni |
| US9406998B2 (en) | 2010-04-21 | 2016-08-02 | Pulse Finland Oy | Distributed multiband antenna and methods |
| KR101853987B1 (ko) * | 2010-07-14 | 2018-05-02 | 솔베이 스페셜티 폴리머스 이태리 에스.피.에이. | 플루오로 엘라스토머 조성물 |
| WO2012084749A1 (en) * | 2010-12-20 | 2012-06-28 | Solvay Specialty Polymers Italy S.P.A. | Thermoprocessable per(halo)fluoropolymer composition |
| FI20115072A0 (fi) | 2011-01-25 | 2011-01-25 | Pulse Finland Oy | Moniresonanssiantenni, -antennimoduuli ja radiolaite |
| US8648752B2 (en) | 2011-02-11 | 2014-02-11 | Pulse Finland Oy | Chassis-excited antenna apparatus and methods |
| US9673507B2 (en) | 2011-02-11 | 2017-06-06 | Pulse Finland Oy | Chassis-excited antenna apparatus and methods |
| US9290619B2 (en) | 2011-03-04 | 2016-03-22 | 3M Innovative Properties Company | Triazine containing fluoropolyether elastomers having low glass transition temperature |
| US8866689B2 (en) | 2011-07-07 | 2014-10-21 | Pulse Finland Oy | Multi-band antenna and methods for long term evolution wireless system |
| US9450291B2 (en) | 2011-07-25 | 2016-09-20 | Pulse Finland Oy | Multiband slot loop antenna apparatus and methods |
| US9123990B2 (en) | 2011-10-07 | 2015-09-01 | Pulse Finland Oy | Multi-feed antenna apparatus and methods |
| US9531058B2 (en) | 2011-12-20 | 2016-12-27 | Pulse Finland Oy | Loosely-coupled radio antenna apparatus and methods |
| US9484619B2 (en) | 2011-12-21 | 2016-11-01 | Pulse Finland Oy | Switchable diversity antenna apparatus and methods |
| US8988296B2 (en) | 2012-04-04 | 2015-03-24 | Pulse Finland Oy | Compact polarized antenna and methods |
| US9979078B2 (en) | 2012-10-25 | 2018-05-22 | Pulse Finland Oy | Modular cell antenna apparatus and methods |
| US10069209B2 (en) | 2012-11-06 | 2018-09-04 | Pulse Finland Oy | Capacitively coupled antenna apparatus and methods |
| US9315644B2 (en) * | 2012-12-03 | 2016-04-19 | E I Du Pont De Nemours And Company | Cured perfluoroelastomer article |
| US10079428B2 (en) | 2013-03-11 | 2018-09-18 | Pulse Finland Oy | Coupled antenna structure and methods |
| US9647338B2 (en) | 2013-03-11 | 2017-05-09 | Pulse Finland Oy | Coupled antenna structure and methods |
| US9634383B2 (en) | 2013-06-26 | 2017-04-25 | Pulse Finland Oy | Galvanically separated non-interacting antenna sector apparatus and methods |
| US9680212B2 (en) | 2013-11-20 | 2017-06-13 | Pulse Finland Oy | Capacitive grounding methods and apparatus for mobile devices |
| US9590308B2 (en) | 2013-12-03 | 2017-03-07 | Pulse Electronics, Inc. | Reduced surface area antenna apparatus and mobile communications devices incorporating the same |
| US9350081B2 (en) | 2014-01-14 | 2016-05-24 | Pulse Finland Oy | Switchable multi-radiator high band antenna apparatus |
| US9973228B2 (en) | 2014-08-26 | 2018-05-15 | Pulse Finland Oy | Antenna apparatus with an integrated proximity sensor and methods |
| US9948002B2 (en) | 2014-08-26 | 2018-04-17 | Pulse Finland Oy | Antenna apparatus with an integrated proximity sensor and methods |
| US9722308B2 (en) | 2014-08-28 | 2017-08-01 | Pulse Finland Oy | Low passive intermodulation distributed antenna system for multiple-input multiple-output systems and methods of use |
| CN104486075B (zh) * | 2014-10-13 | 2018-01-19 | 国家电网公司 | 一种智能变电站icd模型文件数字签名的验证方法 |
| US9906260B2 (en) | 2015-07-30 | 2018-02-27 | Pulse Finland Oy | Sensor-based closed loop antenna swapping apparatus and methods |
| JPWO2017094710A1 (ja) * | 2015-11-30 | 2018-07-12 | ニチアス株式会社 | 架橋性エラストマー組成物、成型品、シール材、該シール材を含むプラズマ処理装置及び半導体製造装置、並びに、成型品の硬度低下剤、成型品の製造方法 |
| JP2019507826A (ja) * | 2016-03-11 | 2019-03-22 | ソルベイ スペシャルティ ポリマーズ イタリー エス．ピー．エー． | フルオロエラストマー組成物を硬化させるためのポリ不飽和化合物 |
| JP6376304B1 (ja) * | 2017-05-22 | 2018-08-22 | ダイキン工業株式会社 | 極低温シール材 |
| JP2021535261A (ja) * | 2018-08-27 | 2021-12-16 | スリーエム イノベイティブ プロパティズ カンパニー | 内部フッ素化可塑剤を含む過酸化物硬化性高フッ素化ポリマー及びそれからの物品 |
| WO2020102271A2 (en) | 2018-11-14 | 2020-05-22 | 3M Innovative Properties Company | Copolymers of perfluorocycloaliphatic methyl vinyl ether |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4035565A (en) * | 1975-03-27 | 1977-07-12 | E. I. Du Pont De Nemours And Company | Fluoropolymer containing a small amount of bromine-containing olefin units |
| JPS53125491A (en) * | 1977-04-08 | 1978-11-01 | Daikin Ind Ltd | Fluorine-containing polymer easily curable and its curable composition |
| US4413094A (en) * | 1982-09-29 | 1983-11-01 | E. I. Du Pont De Nemours & Co. | Perfluoroelastomer blends |
| IT1209669B (it) * | 1985-11-15 | 1989-08-30 | Ausimont Spa | Composizioni vulcanizzabili fluoroelastomeri aventi migliorate caratteristiche di processabilita'e di stabilita' chimica. |
| JPH075810B2 (ja) * | 1986-09-30 | 1995-01-25 | ダイキン工業株式会社 | 低温特性及び加工性の優れた含フツ素弾性状共重合体架橋用組成物 |
| JP2670793B2 (ja) * | 1988-01-29 | 1997-10-29 | 日本メクトロン株式会社 | 含フッ素エラストマー組成物 |
| US4983680A (en) * | 1988-05-25 | 1991-01-08 | E. I. Du Pont De Nemours And Company | Cured perfluoroelastomers and their preparation |
| US5214106A (en) * | 1991-05-22 | 1993-05-25 | E. I. Du Pont De Nemours And Company | Cured fluoroelastomer compositions |
| US5268405A (en) * | 1993-03-31 | 1993-12-07 | E. I. Du Pont De Nemours And Company | Low temperature perfluoroelastomers |
| IT1265461B1 (it) * | 1993-12-29 | 1996-11-22 | Ausimont Spa | Fluoroelastomeri comprendenti unita' monomeriche derivanti da una bis-olefina |
| JP3327016B2 (ja) * | 1994-12-06 | 2002-09-24 | ダイキン工業株式会社 | 低温シール性に優れたフッ素ゴム共重合体及びその硬化用組成物 |
| US5545693A (en) * | 1995-03-10 | 1996-08-13 | E. I. Du Pont De Nemours And Company | Nitrile containing perfluoropolyether-perfluoroelastomer blends |
| US5696189A (en) * | 1995-12-01 | 1997-12-09 | E. I. Du Pont De Nemours And Company | Perfluoroelastomer compositions |
| US5877264A (en) * | 1996-11-25 | 1999-03-02 | E. I. Du Pont De Nemours And Company | Fast-curing perfluoroelastomer composition |
| US5936060A (en) * | 1996-11-25 | 1999-08-10 | E. I. Du Pont De Nemours And Company | Perfluoroelastomer composition having improved processability |
| US6191208B1 (en) * | 1998-05-20 | 2001-02-20 | Dupont Dow Elastomers L.L.S. | Thermally stable perfluoroelastomer composition |
| US6281296B1 (en) * | 1998-08-10 | 2001-08-28 | Dupont Dow Elastomers L.L.C. | Curable perfluoroelastomer composition |
| WO2001027194A1 (en) * | 1999-10-08 | 2001-04-19 | Dyneon Llc | Fluoroelastomer compositions and articles made therefrom |
| US6992143B2 (en) * | 2003-08-15 | 2006-01-31 | Dupont Dow Elastomers Llc | Curable perfluoroelastomer composition |
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2005
- 2005-10-25 US US11/257,539 patent/US7381774B2/en active Active
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- 2006-10-25 JP JP2008537876A patent/JP5270359B2/ja active Active
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|---|---|
| JP2009513784A (ja) | 2009-04-02 |
| WO2007050600A1 (en) | 2007-05-03 |
| US7381774B2 (en) | 2008-06-03 |
| DE602006006093D1 (de) | 2009-05-14 |
| US20070093608A1 (en) | 2007-04-26 |
| EP1951808B1 (en) | 2009-04-01 |
| EP1951808A1 (en) | 2008-08-06 |
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