JP5260210B2 - Polishing detergent composition for floor - Google Patents
Polishing detergent composition for floor Download PDFInfo
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- JP5260210B2 JP5260210B2 JP2008243888A JP2008243888A JP5260210B2 JP 5260210 B2 JP5260210 B2 JP 5260210B2 JP 2008243888 A JP2008243888 A JP 2008243888A JP 2008243888 A JP2008243888 A JP 2008243888A JP 5260210 B2 JP5260210 B2 JP 5260210B2
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- 239000000203 mixture Substances 0.000 title claims abstract description 50
- 239000003599 detergent Substances 0.000 title claims abstract description 17
- 238000005498 polishing Methods 0.000 title claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 34
- -1 polyoxyethylene Polymers 0.000 claims abstract description 27
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 16
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 15
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 12
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 11
- 150000005215 alkyl ethers Chemical class 0.000 claims abstract description 11
- 238000004140 cleaning Methods 0.000 claims description 23
- 239000000178 monomer Substances 0.000 claims description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
- 239000000839 emulsion Substances 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 5
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000003021 water soluble solvent Substances 0.000 claims description 3
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 2
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims description 2
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 claims description 2
- WHNPOQXWAMXPTA-UHFFFAOYSA-N 3-methylbut-2-enamide Chemical compound CC(C)=CC(N)=O WHNPOQXWAMXPTA-UHFFFAOYSA-N 0.000 claims description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 2
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims description 2
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 claims description 2
- 239000001530 fumaric acid Substances 0.000 claims description 2
- 229920001519 homopolymer Polymers 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 2
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims description 2
- 239000011347 resin Substances 0.000 abstract description 10
- 229920005989 resin Polymers 0.000 abstract description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 239000002736 nonionic surfactant Substances 0.000 description 7
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 7
- 125000000217 alkyl group Chemical group 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- 241000047703 Nonion Species 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 238000009408 flooring Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 235000014121 butter Nutrition 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229930195734 saturated hydrocarbon Natural products 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- OHJYHAOODFPJOD-UHFFFAOYSA-N 2-(2-ethylhexoxy)ethanol Chemical compound CCCCC(CC)COCCO OHJYHAOODFPJOD-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000001931 aliphatic group Polymers 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 235000013873 oxidized polyethylene wax Nutrition 0.000 description 1
- 239000004209 oxidized polyethylene wax Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- WTLBZVNBAKMVDP-UHFFFAOYSA-N tris(2-butoxyethyl) phosphate Chemical compound CCCCOCCOP(=O)(OCCOCCCC)OCCOCCCC WTLBZVNBAKMVDP-UHFFFAOYSA-N 0.000 description 1
Abstract
Description
本発明は、床用つや出し洗浄剤組成物に関する。 The present invention relates to a floor polish cleaning composition.
家屋のフローリング床及び合成樹脂系の床材に対する保護つや出し剤に関しては、スチレン・アクリル共重合体ラテックス等をベースとした樹脂ポリマーが用いられている。特許文献１にはレベリング剤としてポリアルコキシル化された線状脂肪族アルコールを用いたつや出し剤が開示されている。特許文献２においても、ポリエトキシ化脂肪族第２級アルコールの添加すると塗り伸ばし性及びレベリング性が向上すると記載されている。また床用つや出剤に洗浄力を付与し、一度の拭きそうじで汚れを落とし、つや出しも行うことができる床用つや出し洗浄剤として特許文献３〜５などがある。特許文献３によると、揮発性のアミノアルコールを用いることで、においがよく洗浄性と使用感に優れたつや出し洗浄剤を得ることができる。また特許文献４によると、ポリエチレンワックス、ポリプロピレンワックス及びアルカノールアミンを用いることで、洗浄性、つや及び耐傷性を併せ持つつや出し洗浄剤を得ることができる。一方、特許文献５によれば、アルカノールアミンのようなアルカリ剤を用いなくても洗浄性とつや、及び滑りにくさを併せ持つつや出し洗浄剤が得られるとしている。
つや出し洗浄剤においては、洗浄性とつや出し性能は重要であるが、それに加えて、重ね塗りする場合にもきれいなつやが得られること、さらに、つや出し剤を塗布した床の耐水性、すなわち水をこぼしてその上に摩擦力がかかるような場面があってもムラや曇りを生じない、といった性能を併せ持つことも要求される。特許文献３、特許文献４に示されているようなつや出し洗浄剤は、アルカリ成分を含有するために、ポリマー樹脂膜を膨潤させて膜表面を薄く溶解させることも期待できるため高い洗浄性を示すが、その一方で、生乾きのうちに重ね塗りをすると、乾燥不十分な膜が重ね塗られたつや出し洗浄液によって部分的に溶解し、重ね塗りで期待される高いつやが出るどころか、反対に曇りが生じることがある。これを回避するためにアルカリ剤を低減させると、今度は汚れに対する洗浄性も低下してしまう。これを補うために界面活性剤を添加あるいは増量することが考えられるが、単純に界面活性剤を増やすだけでは、洗浄性と得られた樹脂膜の耐水性の両立は困難であった。すなわち、特許文献５で用いられているようなエチレンオキサイド付加モル数が１０以上といった比較的付加モル数の多いエチレンオキサイド型非イオン界面活性剤を用いると、洗浄性は向上するが耐水性が低下し、逆に、特許文献１や特許文献２で用いられているような、エチレンオキサイド付加モル数が３程度といった比較的付加モル数の少ないエチレンオキサイド型非イオン界面活性剤を用いると、膜の耐水性はよいが、洗浄性の不足が目立ってしまう。 In polish cleaners, cleanability and polish performance are important, but in addition to that, it is possible to obtain a clean gloss even when overcoated, and the water resistance of the floor to which the polish is applied, i.e. spilling water. In addition, even if there is a scene where a frictional force is applied on it, it is also required to have a performance that does not cause unevenness or cloudiness. Since the polishing detergents shown in Patent Document 3 and Patent Document 4 contain an alkaline component, they can be expected to swell the polymer resin film and dissolve the film surface thinly, thus exhibiting high detergency. On the other hand, when overcoating while being dry, the film with insufficient drying is partially dissolved by the overcoated glossy cleaning solution, and on the contrary, the high gloss expected by overcoating is produced, and on the contrary, cloudy May occur. If the alkaline agent is reduced in order to avoid this, the detergency against dirt is also lowered. In order to compensate for this, it is conceivable to add or increase the amount of a surfactant. However, simply increasing the surfactant makes it difficult to achieve both cleanability and water resistance of the resulting resin film. That is, when an ethylene oxide type nonionic surfactant having a relatively large number of added moles, such as the number of moles of ethylene oxide added as used in Patent Document 5, is used, the detergency is improved but the water resistance is lowered. On the other hand, when an ethylene oxide type nonionic surfactant having a relatively small number of added moles, such as the number of moles of ethylene oxide added, as used in Patent Document 1 or Patent Document 2, is used, Water resistance is good, but lack of cleanliness is noticeable.
従って本発明の目的は、洗浄性及びつや出し性能に優れ、更には、重ね塗りした場合にも曇りが生じにくく、耐水性の高い樹脂膜を形成する、という４つの性質を併せ持つ、床用つや出し洗浄剤組成物を提供することにある。 Therefore, the object of the present invention is excellent in cleaning properties and polish performance, and further, when coated again, it is difficult to cause fogging and forms a highly water-resistant resin film. It is to provide an agent composition.
本発明は、（ａ）アクリル系樹脂〔以下、（ａ）成分という〕、（ｂ）平均エチレンオキサイド付加モル数が０超５．５未満のポリオキシエチレンアルキルエーテル〔以下、（ｂ）成分という〕、（ｃ）平均エチレンオキサイド付加モル数が５．５以上１５以下のポリオキシエチレンアルキルエーテル〔以下、（ｃ）成分という〕を含有し、（ｂ）＋（ｃ）＝０．０１〜２重量％、（ｂ）／（ｃ）＝０．５〜１０（重量比）である、床用つや出し洗浄剤組成物に関する。 The present invention includes (a) an acrylic resin (hereinafter referred to as component (a)), (b) a polyoxyethylene alkyl ether having an average ethylene oxide addition mole number of more than 0 and less than 5.5 [hereinafter referred to as component (b). (C) polyoxyethylene alkyl ether having an average ethylene oxide addition mole number of 5.5 to 15 (hereinafter referred to as component (c)), and (b) + (c) = 0.01 to 2 The present invention relates to a polishing detergent composition for floor, wherein the weight percentage is (b) / (c) = 0.5 to 10 (weight ratio).
本発明によれば、洗浄性及びつや出し性能に優れ、更には、重ね塗りした場合にも曇りが生じにくく、耐水性の高い樹脂膜を形成する、という４つの性質を併せ持つ、床用つや出し洗浄剤組成物が提供される。 According to the present invention, it is excellent in detergency and polishing performance, and further has four properties of forming a resin film with high water resistance, which is less likely to be fogged even when it is overcoated, and is a floor polishing and cleaning agent. A composition is provided.
＜（ａ）成分＞
本発明の（ａ）成分であるアクリル系樹脂としては、アクリロニトリル、メタクリロニトリル、メタクリル酸メチル、メタクリル酸エチル、メタクリル酸ブチル、メタクリル酸２エチルヘキシル、アクリル酸メチル、アクリル酸エチル、アクリル酸ブチル、アクリル酸２エチルヘキシル、メタクリル酸、アクリルアミド、ジメチルアクリルアミド及びアクリル酸から選ばれるアクリル系モノマーから生成されるホモポリマー又はコポリマーや、前記アクリル系モノマーとその他モノマーとして、スチレン、ビニルトルエン、イタコン酸、クロトン酸、フマル酸、マレイン酸のモノマー群から選ばれるモノマーとのコポリマーから選ばれる一種以上の水不溶性の樹脂等が例示され、より好ましくは（ｉ）スチレンと（ii）メタクリレート、アクリレート、メタクリル酸およびアクリル酸から選ばれる一種以上とのコポリマーが例示される。これらアクリル系樹脂は乳化重合により合成することができる。また、アクリル系樹脂は、アクリル系樹脂が水中に分散したアクリル系樹脂エマルジョンを使用することができる。アクリル系樹脂は、充分な光沢を得る為に、床用つや出し洗浄剤組成物に、好ましくは２〜２５重量％、より好ましくは３〜８重量％含有される。なお、床用つや出し洗浄剤組成物の調製時には、乳化重合後のエマルジョンの形態で配合することが好ましく、配合量はエマルジョン中の有効量（Active）に基づいて決めることができる。
<(A) component>
Examples of the acrylic resin as component (a) of the present invention include acrylonitrile, methacrylonitrile, methyl methacrylate, ethyl methacrylate, butyl methacrylate, 2-ethylhexyl methacrylate, methyl acrylate, ethyl acrylate, butyl acrylate, Homopolymers or copolymers formed from acrylic monomers selected from 2-ethylhexyl acrylate, methacrylic acid, acrylamide, dimethylacrylamide and acrylic acid, and the acrylic monomers and other monomers include styrene, vinyltoluene, itaconic acid, crotonic acid And one or more water-insoluble resins selected from copolymers with monomers selected from monomer groups of fumaric acid and maleic acid, more preferably (i) styrene and (ii) methacrylate, Rate, copolymers of one or more selected from methacrylic acid and acrylic acid. These acrylic resins can be synthesized by emulsion polymerization. As the acrylic resin, an acrylic resin emulsion in which an acrylic resin is dispersed in water can be used. In order to obtain a sufficient gloss, the acrylic resin is preferably contained in the floor polish cleaning composition in an amount of 2 to 25% by weight, more preferably 3 to 8% by weight. In addition, it is preferable to mix | blend with the form of the emulsion after emulsion polymerization at the time of preparation of the glossiness | cleaning detergent composition for floors, and a compounding quantity can be determined based on the effective amount (Active) in an emulsion.
＜（ｂ）成分＞
（ｂ）成分は、平均エチレンオキサイド（以下、ＥＯという）付加モル数が０超５．５未満のポリオキシエチレンアルキルエーテルであり、アルキル基の炭素数は好ましくは８〜２２、より好ましくは１０〜１８である。アルキル基は直鎖でも分岐鎖でもよいが、アルキル基は飽和炭化水素が好ましい。ＥＯ付加のタイプとしては、１級に限らず２級又は高級であっても構わない。光沢を得るために平均ＥＯ付加モル数として、好ましくは０．５〜５、より好ましくは０．５〜３．５である。（ｂ）成分としては、ポリオキシエチレン２−エチルヘキシルエーテル（平均ＥＯ付加モル数１〜５）、ポリオキシエチレンラウリルエーテル（１級又は２級、平均ＥＯ付加モル数１〜５）が好ましい。
<(B) component>
The component (b) is a polyoxyethylene alkyl ether having an average ethylene oxide (hereinafter referred to as EO) addition mole number of more than 0 and less than 5.5, and the alkyl group preferably has 8 to 22 carbon atoms, more preferably 10 ~ 18. The alkyl group may be linear or branched, but the alkyl group is preferably a saturated hydrocarbon. The EO addition type is not limited to the first grade, and may be a second grade or high grade. In order to obtain gloss, the average EO addition mole number is preferably 0.5 to 5, more preferably 0.5 to 3.5. As the component (b), polyoxyethylene 2-ethylhexyl ether (average EO addition mole number 1 to 5) and polyoxyethylene lauryl ether (primary or secondary, average EO addition mole number 1 to 5) are preferable.
＜（ｃ）成分＞
（ｃ）成分は、平均ＥＯ付加モル数が５．５以上１５以下のポリオキシエチレンアルキルエーテルであり、アルキル基の炭素数は好ましくは８〜２２、より好ましくは１０〜１８である。アルキル基は直鎖でも分岐鎖でもよいが、アルキル基は飽和炭化水素が好ましい。ＥＯ付加のタイプとしては、１級に限らず２級又は高級であっても構わない。洗浄力を得るために平均ＥＯ付加モル数として、好ましくは６〜１５、より好ましくは６〜１２である。（ｃ）成分としては、ポリオキシエチレン２−エチルヘキシルエーテル（平均ＥＯ付加モル数６〜１２）、ポリオキシエチレンラウリルエーテル（１級又は２級、平均ＥＯ付加モル数６〜１２）が好ましい。なお、（ｂ）成分と（ｃ）成分との平均ＥＯ付加モル数の差は０．５以上であることが好ましい。
<(C) component>
Component (c) is a polyoxyethylene alkyl ether having an average EO addition mole number of 5.5 or more and 15 or less, and the alkyl group preferably has 8 to 22 carbon atoms, more preferably 10 to 18 carbon atoms. The alkyl group may be linear or branched, but the alkyl group is preferably a saturated hydrocarbon. The EO addition type is not limited to the first grade, and may be a second grade or high grade. In order to obtain detergency, the average number of added EO moles is preferably 6 to 15, more preferably 6 to 12. As the component (c), polyoxyethylene 2-ethylhexyl ether (average EO addition mole number 6 to 12) and polyoxyethylene lauryl ether (primary or secondary, average EO addition mole number 6 to 12) are preferable. In addition, it is preferable that the difference of the average EO addition mole number of (b) component and (c) component is 0.5 or more.
（ｂ）成分と（ｃ）成分の合計含有量が少なすぎると十分な洗浄力及び光沢が得られず、多すぎると耐水性に劣る。そのため、本発明の床用つや出し洗浄剤組成物は、洗浄力、光沢及び耐水性のバランスの観点から、（ｂ）成分と（ｃ）成分の合計含有量が（ｂ）＋（ｃ）＝０．０１〜２重量％であり、好ましくは０．２〜１．５重量％、更に好ましくは０．２５〜１．２５重量％である。また、同じく洗浄力、光沢及び耐水性のバランスの観点から、（ｂ）成分と（ｃ）成分の重量比は、（ｂ）／（ｃ）＝０．５〜１０であり、好ましくは０．８〜８、更に好ましくは１〜５である。 If the total content of the component (b) and the component (c) is too small, sufficient detergency and gloss cannot be obtained, and if too large, the water resistance is poor. Therefore, the floor polish cleaning composition of the present invention has a total content of (b) component and (c) component of (b) + (c) = 0 from the viewpoint of the balance of detergency, gloss and water resistance. 0.01 to 2% by weight, preferably 0.2 to 1.5% by weight, and more preferably 0.25 to 1.25% by weight. Similarly, from the viewpoint of the balance of detergency, gloss and water resistance, the weight ratio of the component (b) to the component (c) is (b) / (c) = 0.5-10, preferably 0.8. It is 8-8, More preferably, it is 1-5.
この比率を満たした上で、本発明の床用つや出し洗浄剤組成物における（ｂ）成分の含有量は、０．１〜１．５重量％、更に０．２〜１．０重量％の範囲から選択されることが好ましく、また、（ｃ）成分の含有量は、０．０５〜１．０重量％、更に０．１〜０．７重量％の範囲から選択されることが好ましい。 After satisfying this ratio, the content of the component (b) in the polishing polish composition for floor of the present invention is in the range of 0.1 to 1.5% by weight, more preferably 0.2 to 1.0% by weight. The content of component (c) is preferably selected from the range of 0.05 to 1.0% by weight, more preferably 0.1 to 0.7% by weight.
本発明によれば（ｂ）成分を含有することで、洗浄力のみならず光沢も向上する。このメカニズムについては定かではないが、平均ＥＯ付加モル数の比較的小さい非イオン界面活性剤である（ｂ）成分が、従来多用されていたトリブトキシエチルフォスフェートのような可塑剤として樹脂膜中に残留し、造膜性向上、レベリング性向上等に働き、結果的に光沢の増加に関与しているものと推定される。平均ＥＯ付加モル数の比較的大きい非イオン界面活性剤である（ｃ）成分は洗浄力向上には効果的ではあるが、過剰に用いると膜の耐水性低下につながる。本発明は平均ＥＯ付加モル数の異なる非イオン界面活性剤を組み合わせて用いることで、従来は得られなかった洗浄力、光沢、耐水性、及び重ね塗りをした場合にも曇りが生じにくいといったバランスのとれた床用つや出し洗浄剤組成物が得られたものと考えられる。 According to the present invention, by including the component (b), not only detergency but also gloss is improved. Although it is not clear about this mechanism, the component (b), which is a nonionic surfactant having a relatively small average EO addition mole number, is used as a plasticizer such as tributoxyethyl phosphate in the resin film. It is presumed that it remains in the film and works to improve film-forming properties, leveling properties, etc., and as a result, is involved in the increase in gloss. The component (c), which is a nonionic surfactant having a relatively large average EO addition mole number, is effective in improving the detergency, but if used in excess, it leads to a decrease in water resistance of the membrane. The present invention uses a combination of nonionic surfactants having different average EO addition mole numbers, and has a balance that has not been obtained in the past, such as detergency, gloss, water resistance, and that even when overcoated, fogging is unlikely to occur. It is considered that a smooth polishing composition for floor was obtained.
＜床用つや出し洗浄剤組成物＞
本発明の床用つや出し洗浄剤組成物は、造膜性向上、光沢向上、洗浄力向上の観点から、更に、（ｄ）水溶性溶剤を含有することが好ましい。（ｄ）成分としては、エチルカルビトール、ブチルカルビトール、モノエタノールアミン、モノプロパノールアミン、エタノール、プロパノール、等が挙げられ、なかでも、エチルカルビトール、モノエタノールアミン、エタノールが好ましい。（ｄ）成分としてこれらの中から選ばれる１種以上の水溶性溶剤を、組成物中に合計として、０．５〜１０重量％、更に２〜８重量％含有することが好ましい。なお、モノエタノールアミン、モノプロパノールアミンといったアルカノールアミン類は、洗浄力及び光沢の向上に大きな効果を示すが、過剰に含有させると、重ね塗りをした場合に曇りを生じる場合がある。これは過剰なアルカノールアミン類によって床用つや出し洗浄剤組成物全体のｐＨが上がり、膜を構成する樹脂がアルカリ性に弱い場合に、下地の樹脂膜を過度に荒らしてしまうためであると考えられる。これを防ぐために、アルカノールアミン類の含有量は、組成物中、好ましくは０．５重量％以下、さらに好ましくは０．３重量％以下である。
<Finishing detergent composition for floor>
The polishing polish composition for floors of the present invention preferably further contains (d) a water-soluble solvent from the viewpoint of improving the film forming property, improving the gloss, and improving the detergency. Examples of the component (d) include ethyl carbitol, butyl carbitol, monoethanolamine, monopropanolamine, ethanol, propanol, etc. Among them, ethylcarbitol, monoethanolamine, and ethanol are preferable. As the component (d), one or more water-soluble solvents selected from these are preferably contained in the composition in an amount of 0.5 to 10% by weight, more preferably 2 to 8% by weight. In addition, although alkanolamines such as monoethanolamine and monopropanolamine have a great effect on improvement of detergency and gloss, if they are contained excessively, they may be clouded when overcoated. This is presumably because excessive alkanolamines raise the pH of the entire polishing polish composition for flooring and excessively roughen the underlying resin film when the resin constituting the film is weakly alkaline. In order to prevent this, the content of alkanolamines in the composition is preferably 0.5% by weight or less, more preferably 0.3% by weight or less.
上記と同様に、膜を構成する樹脂がアルカリ性に弱い場合には、耐水性を得る観点及び重ね塗りをしても曇りを生じにくいという観点から、本発明の床用つや出し洗浄剤組成物は、２５℃におけるｐＨが６．０〜１１．０、更に６．０〜９．０、より更に６．０〜８．０であることが好ましい。 Similarly to the above, when the resin constituting the film is weak in alkalinity, from the viewpoint of obtaining water resistance and being less likely to cause fogging even if it is overcoated, the floor polishing detergent composition of the present invention is The pH at 25 ° C is preferably 6.0 to 11.0, more preferably 6.0 to 9.0, and still more preferably 6.0 to 8.0.
本発明の床用つや出し洗浄剤組成物には、耐水性を損なわない範囲で、成分（ｂ）及び成分（ｃ）以外の非イオン性界面活性剤などの界面活性剤を配合してもよい。また、その他配合できる成分として、酸化ポリエチレンワックス、酸化ポリプロピレンワックス、シリコーンオイル、変性シリコーン、防腐剤、香料等が挙げられる。 In the floor polish cleaning composition of the present invention, a surfactant such as a nonionic surfactant other than the component (b) and the component (c) may be blended as long as the water resistance is not impaired. Other components that can be blended include oxidized polyethylene wax, oxidized polypropylene wax, silicone oil, modified silicone, preservatives, and fragrances.
本発明の床用つや出し洗浄剤組成物は、上記（ａ）〜（ｃ）成分、更に必要に応じて配合される（ｄ）成分やその他の成分と、水とを含有する。水の含有量は、組成物中６０〜９８重量％、更に８０〜９５重量％が好ましい。 The floor polish cleaning composition of the present invention contains the above components (a) to (c), the component (d) and other components blended as necessary, and water. The water content is preferably 60 to 98% by weight, more preferably 80 to 95% by weight in the composition.
本発明の床用つや出し洗浄剤組成物は、定法に従い、上記（ａ）〜（ｃ）成分、更に必要に応じて配合される（ｄ）成分やその他の成分と、水とを、混合することにより製造することができ、その使用法としては、スクイズボトル、トリガー式スプレー等により床に直接適用する、あるいはこれらの手段で床に適用した後、雑巾、モップ等の手段で床に塗り拡げる、雑巾、モップ、シート等の手段に担持させて床に適用する、等の方法が挙げられる。 The floor polish cleaning composition of the present invention is prepared by mixing the above components (a) to (c), (d) component and other components blended as necessary, and water according to a conventional method. As a method of use, it can be applied directly to the floor with a squeeze bottle, trigger spray, etc., or after being applied to the floor with these means, it can be spread on the floor with means such as a rag, mop, Examples thereof include a method of applying to a floor by carrying it on a means such as a dust cloth, mop, or sheet.
本発明の床用つや出し洗浄剤組成物を用いた床の処理では、該組成物を重ね塗りする場合にもきれいなつやが得られる。すなわち、該組成物を複数回床に適用する場合に、適用間隔が短くて十分に組成物が乾燥していない状態（生乾きの状態）で更に組成物が適用されるような場合でも、重ね塗りによるより高いつや出し効果が発揮される。よって、本発明により、本発明の床用つや出し洗浄剤組成物、好ましくは２５℃におけるｐＨが６．０〜８．０である組成物を、床に複数回適用する、床のつや出し処理方法が提供される。 In the treatment of the floor using the floor polish detergent composition of the present invention, a clean gloss can be obtained even when the composition is overcoated. That is, when the composition is applied to the floor a plurality of times, even when the composition is further applied in a state where the application interval is short and the composition is not sufficiently dried (freshly dried state) Higher gloss effect is exhibited by. Therefore, according to the present invention, there is provided a method for polishing floor polishing, wherein the floor polishing detergent composition of the present invention, preferably a composition having a pH of 6.0 to 8.0 at 25 ° C, is applied to the floor a plurality of times. Provided.
また、本発明により、（ａ’）アクリル系樹脂エマルジョン、（ｂ）平均ＥＯ付加モル数が０超５．５未満のポリオキシエチレンアルキルエーテル（ｃ）平均ＥＯモル数が５．５以上１５以下のポリオキシエチレンアルキルエーテルを含む成分を混合する工程を有する、床用つや出し洗浄剤組成物の製造方法であって、（ｂ）と（ｃ）を（ｂ）＋（ｃ）＝０．０１〜２重量％（全原料中の比率）且つ（ｂ）／（ｃ）＝０．５〜１０（重量比）で用いる製造方法が提供される。 Further, according to the present invention, (a ′) an acrylic resin emulsion, (b) a polyoxyethylene alkyl ether having an average EO addition mole number of more than 0 and less than 5.5 (c) an average EO mole number of 5.5 to 15 A process for producing a polishing detergent composition for floors, comprising a step of mixing a component containing polyoxyethylene alkyl ether of (b) and (c) (b) + (c) = 0.01 to The production method used is 2 wt% (ratio in all raw materials) and (b) / (c) = 0.5 to 10 (weight ratio).
以下の実施例で用いた配合成分を示す。
＜配合成分＞
・アクリル樹脂エマルジョンａ−１：「ＮＴ−２６２４」（有効分３８重量％）ローム＆ハース社製のポリアクリル系樹脂エマルジョン
・ノニオンｂ−１：「ソフタノール３０」（株）日本触媒製ポリオキシエチレンラウリルエーテル（２級、平均ＥＯ付加モル数３）
・ノニオンｂ−２：「ソフタノール５０」（株）日本触媒製ポリオキシエチレンラウリルエーテル（２級、平均ＥＯ付加モル数５）
・ノニオンｂ−３：「２エチルヘキシルグリコール」日本乳化剤（株）製エチレングリコールモノ２−エチルヘキシルエーテル（１級、平均ＥＯ付加モル数１）
・ノニオンｃ−１：「エマルゲン１０８」花王（株）製ポリオキシエチレンラウリルエーテル（１級、平均ＥＯ付加モル数６）
・ノニオンｃ−２：「ソフタノール７０」（株）日本触媒製ポリオキシエチレンラウリルエーテル（２級、平均ＥＯ付加モル数７）
・ノニオンｃ−３：「ソフタノール１２０」（株）日本触媒製ポリオキシエチレンラウリルエーテル（２級、平均ＥＯ付加モル数１２）
・ノニオンｃ’−１：「エマルゲン１４７」花王（株）製ポリオキシエチレンラウリルエーテル（１級、平均ＥＯ付加モル数１９）
The compounding components used in the following examples are shown.
<Blending ingredients>
・ Acrylic resin emulsion a-1: “NT-2624” (effective weight 38% by weight) Polyacrylic resin emulsion manufactured by Rohm & Haas Co., Ltd. Nonion b-1: “Softanol 30” polyoxyethylene manufactured by Nippon Shokubai Co., Ltd. Lauryl ether (secondary, average EO addition mole number 3)
-Nonion b-2: "Softanol 50" Co., Ltd. Nippon Shokubai polyoxyethylene lauryl ether (secondary, average EO addition mole number 5)
Nonion b-3: “2 ethylhexyl glycol” manufactured by Nippon Emulsifier Co., Ltd. Ethylene glycol mono 2-ethylhexyl ether (first grade, average EO addition mole number 1)
Nonion c-1: “Emulgen 108” manufactured by Kao Corporation, polyoxyethylene lauryl ether (first grade, average EO addition mole number 6)
-Nonion c-2: "Softanol 70" polyoxyethylene lauryl ether manufactured by Nippon Shokubai Co., Ltd. (second grade, average EO addition mole number 7)
Nonion c-3: “Softanol 120”, manufactured by Nippon Shokubai Co., Ltd. polyoxyethylene lauryl ether (secondary, average EO addition mole number 12)
Nonion c′-1: “Emulgen 147” manufactured by Kao Corporation, polyoxyethylene lauryl ether (first grade, average EO addition mole number 19)
表１の床用つや出し洗浄剤組成物を調製し、下記の評価方法により洗浄力、光沢増分、耐水性、及び重ね塗り耐性を調べた。結果を表１に示す。
＜評価方法＞
（１）洗浄力
市販のバターをクロロホルムで１０％に希釈した液に、ＳＵＳ３０４試験片（ＪＩＳ Ｇ４３０５）を浸漬後、試験片表面が液面に対して垂直になるように過剰な液を落としながらゆっくりと引き上げる。これを乾燥させて薄く均一なバター膜を形成し、モデル汚れプレートとする。モデル汚れプレートに床用つや出し洗浄剤組成物を滴下し、１０秒後にミスト状にイオン交換水を噴霧し、機械力を与えないように注意しながら床用つや出し洗浄剤組成物を洗い流す。操作後、床用つや出し洗浄剤組成物を滴下した部分の面積に対するバターが除去された面積の比（％）を求め、その値をもって洗浄力の指標とした。
The floor polish compositions for floors shown in Table 1 were prepared, and the detergency, gloss increment, water resistance, and overcoat resistance were examined by the following evaluation methods. The results are shown in Table 1.
<Evaluation method>
(1) Detergency After immersing SUS304 test piece (JIS G4305) in a solution of commercial butter diluted to 10% with chloroform, dropping excess liquid so that the test piece surface is perpendicular to the liquid surface Pull it up slowly. This is dried to form a thin and uniform butter film to obtain a model dirt plate. The floor polishing detergent composition is dropped onto the model dirt plate, and after 10 seconds, ion exchange water is sprayed in a mist form, and the floor polishing detergent composition is washed away so as not to give mechanical force. After the operation, the ratio (%) of the area from which the butter was removed to the area of the portion where the polished polishing composition for floor was dropped was determined, and the value was used as an index of cleaning power.
（２）光沢増分
光沢増分は、スガ試験機株式会社製デジタル変角光沢計ＵＧＶ−５Ｄ型を用い、入射角と反射角をともに６０°に設定して、松下電工製フローリングＫＥＣ１２ＵＥに対して、塗布前と、床用つや出し洗浄剤組成物の塗布と乾燥を３回繰り返した後の光沢の差を求めることによって得た。光沢増分が大きいほど、ワックス効果に優れることを意味する。
(2) Gloss increment The gloss increment is a digital variable angle gloss meter UGV-5D manufactured by Suga Test Instruments Co., Ltd., and both the incident angle and the reflection angle are set to 60 °. It was obtained by determining the difference in gloss before application and after repeating the application and drying of the polishing polish composition for floor three times. The larger the gloss increment, the better the wax effect.
（３）耐水性
２５℃／相対湿度４０％の環境下で、松下電工製フローリングＫＥＣ１２ＵＥに床用つや出し洗浄剤組成物を塗布し、所定時間乾燥後に、イオン交換水を０．１ｍＬ滴下して５分後に折りたたんだティッシュで強く拭き取る操作を行う。イオン交換水の拭き取り跡が残らなくなるまでの最低乾燥時間（時間）を耐水性の指標とした。値が小さいほど耐水性に優れることを意味しており、具体的には該床用つや出し洗浄剤組成物を塗布した後、乾燥時間を長時間とらなくても、床にこぼしてしまった水を拭き取るといった日常生活での使用に耐えることを意味している。
(3) Water resistance Under an environment of 25 ° C./40% relative humidity, floor polish KEC12UE manufactured by Matsushita Electric Works was applied with a floor polish cleaning composition, dried for a predetermined time, and then 0.1 mL of ion-exchanged water was dropped. Do a strong wipe with a folded tissue after a minute. The minimum drying time (hours) until no wiping trace of ion-exchanged water remains was used as an index of water resistance. The smaller the value, the better the water resistance. Specifically, after applying the floor polish cleaning composition, water that has spilled on the floor can be removed without taking a long drying time. It means that it can withstand daily use such as wiping.
（４）重ね塗り耐性
２５℃／相対湿度４０％の環境下で、松下電工製フローリングＫＥＣ１２ＵＥに床用つや出し洗浄剤組成物を塗布し、塗布終了後１分間隔で最大１０分後まで、同じ部分に床用つや出し洗浄剤組成物を再度塗布する。前述の光沢測定を行い、再度塗布による光沢の低下が起こらない最低乾燥時間（分）を重ね塗り耐性の指標とした。値が小さいほど重ね塗り耐性に優れることを意味しており、具体的には該床用つや出し洗浄剤組成物を塗布した後、重ね塗りをする場合にも、乾燥時間を長時間とらなくても、最初に塗布した下地の表面を荒らさず、曇りを生じるなどの悪影響を及ぼしにくいことを意味している。重ね塗りをする場面としては、一度該床用つや出し洗浄剤組成物を塗布した後さらに高い光沢を求める場合、あるいは、塗り残し部分を発見して追加で該床用つや出し洗浄剤組成物を使用したい場合にやむを得ず重ね塗り部分が生じてしまう場合、などが考えられる。これらの重ね塗りの必要な場面は決して例外的なものではなく、床用つや出し洗浄剤組成物が兼ね備えるべき重要な特性と考えられる。
(4) Overcoat resistance Under the environment of 25 ° C / 40% relative humidity, apply the floor polish cleaner composition to the flooring KEC12UE made by Matsushita Electric Works, and the same part up to 10 minutes at intervals of 1 minute after the application is completed Apply again the floor polish cleaning composition. The gloss measurement described above was carried out, and the minimum drying time (minutes) at which the gloss did not deteriorate again due to coating was used as an index for the overcoat resistance. The smaller the value, the better the resistance to repeated coating. Specifically, even after applying the polishing polish composition for flooring, even when performing repeated coating, it does not take a long drying time. This means that the surface of the base applied first is not roughened, and does not adversely affect such as cloudiness. In the case of overcoating, if you want to obtain a higher gloss after applying the floor polish cleaning composition once, or if you want to use the floor polish cleaning composition after discovering the unpainted area In such a case, a case where an overcoated portion is unavoidable may be considered. These scenes requiring recoating are by no means exceptional and are considered important properties that must be combined with a floor polish composition.
（注）表中の重量％は有効分の濃度を示す（以下同様）。 (Note) The weight% in the table indicates the concentration of the effective component (the same applies hereinafter).
表１より、（ｂ）＋（ｃ）、（ｂ）／（ｃ）が、それぞれ特定範囲にある場合に洗浄力、高光沢、耐水性、及び重ね塗り耐性という４つの性質を併せもつことがわかる。特許文献２の実施例にあるように、界面活性剤として（ｂ）成分のみ含有する比較例１では実施例１と比較して十分な洗浄力が得られないことがわかる。比較例２のように異なる（ｂ）成分を組み合わせても大きな改善は見られない。反対に比較例３のように界面活性剤として（ｂ）成分を用いず異なる（ｃ）成分を組み合わせた場合は、光沢の不足が見られる。特許文献５の実施例にあるように、界面活性剤として平均ＥＯ付加モル数の大きな非イオン界面活性剤を用いる比較例４では、洗浄力と光沢の両立はおろか、耐水性の低下も招くこととなる。（ｂ）／（ｃ）の比率が大きすぎる比較例５については、特定比率を保っている実施例３に比べて、洗浄力の不足が見られる。 According to Table 1, when (b) + (c) and (b) / (c) are in specific ranges, they have the four properties of detergency, high gloss, water resistance, and overcoat resistance. Recognize. As shown in the Examples of Patent Document 2, it can be seen that Comparative Example 1 containing only the component (b) as a surfactant does not provide sufficient detergency compared to Example 1. Even when different components (b) are combined as in Comparative Example 2, no significant improvement is observed. On the other hand, when the component (b) is not used as a surfactant and a different component (c) is combined as in Comparative Example 3, a lack of gloss is observed. As shown in the Examples of Patent Document 5, Comparative Example 4 using a nonionic surfactant having a large average EO addition mole number as a surfactant not only achieves both cleaning power and gloss, but also causes a decrease in water resistance. It becomes. In Comparative Example 5 in which the ratio of (b) / (c) is too large, the cleaning power is deficient as compared with Example 3 in which the specific ratio is maintained.
表２は一律にモノエタノールアミンを０．１重量％含有する弱アルカリの系について評価をまとめた。表１の実施例１〜４（中性系）と表２の実施例５〜８との比較から、耐水性及び重ね塗り耐性については実施例１〜４の中性系でより良好であり、洗浄力及び光沢については実施例５〜８の弱アルカリ系でより良好であることがわかる。 Table 2 summarizes the evaluation of weakly alkaline systems containing 0.1% by weight monoethanolamine. From comparison between Examples 1 to 4 (neutral system) in Table 1 and Examples 5 to 8 in Table 2, water resistance and overcoat resistance are better in the neutral system of Examples 1 to 4, It can be seen that the detergency and gloss are better in the weak alkaline systems of Examples 5-8.
また、（ｂ）成分と（ｃ）成分を特定比率で併用している実施例５に対して、（ｃ）成分のみ含有し（ｂ）成分を含有しない比較例６は光沢及び耐水性で劣ることがわかる。（ｃ）成分の含有量を２倍にした比較例７についても、同じく光沢及び耐水性の不足が見られる。（ｂ）／（ｃ）の比率が大きすぎる比較例８については、特定比率を保っている実施例６に比べて、洗浄力の不足が見られる。比較例９のように（ｂ）／（ｃ）の比率が本発明の範囲であっても、（ｂ）＋（ｃ）の総量が過多の場合は耐水性の低下が見られる。 Moreover, compared with Example 5 which uses (b) component and (c) component together by specific ratio, the comparative example 6 which contains only (c) component and does not contain (b) component is inferior in glossiness and water resistance. I understand that. Regarding Comparative Example 7 in which the content of the component (c) is doubled, the gloss and water resistance are similarly insufficient. In Comparative Example 8 in which the ratio of (b) / (c) is too large, the cleaning power is insufficient as compared with Example 6 in which the specific ratio is maintained. Even when the ratio of (b) / (c) is within the range of the present invention as in Comparative Example 9, when the total amount of (b) + (c) is excessive, a decrease in water resistance is observed.
Claims (5)
（ａ１）アクリロニトリル、メタクリロニトリル、メタクリル酸メチル、メタクリル酸エチル、メタクリル酸ブチル、メタクリル酸２エチルヘキシル、アクリル酸メチル、アクリル酸エチル、アクリル酸ブチル、アクリル酸２エチルヘキシル、メタクリル酸、アクリルアミド、ジメチルアクリルアミド及びアクリル酸から選ばれるアクリル系モノマーから生成されるホモポリマー又はコポリマー、並びに、(A1) Acrylonitrile, methacrylonitrile, methyl methacrylate, ethyl methacrylate, butyl methacrylate, 2-ethylhexyl methacrylate, methyl acrylate, ethyl acrylate, butyl acrylate, 2-ethylhexyl acrylate, methacrylic acid, acrylamide, dimethylacrylamide And a homopolymer or copolymer produced from an acrylic monomer selected from acrylic acid, and
（ａ２）前記アクリル系モノマーと、スチレン、ビニルトルエン、イタコン酸、クロトン酸、フマル酸、マレイン酸のモノマー群から選ばれるモノマーとのコポリマー(A2) Copolymer of the acrylic monomer and a monomer selected from the monomer group of styrene, vinyl toluene, itaconic acid, crotonic acid, fumaric acid and maleic acid
から選ばれる一種以上の水不溶性のアクリル系樹脂である、請求項１〜３の何れか１項記載の床用つや出し洗浄剤組成物。The polishing composition for floor polishes of any one of Claims 1-3 which is 1 or more types of water-insoluble acrylic resin chosen from these.
（ｂ）と（ｃ）を（ｂ）＋（ｃ）＝０．０１〜２重量％（全原料中の比率）且つ（ｂ）／（ｃ）＝０．５〜１０（重量比）で用いる、(B) and (c) are used at (b) + (c) = 0.01 to 2% by weight (ratio in all raw materials) and (b) / (c) = 0.5 to 10 (weight ratio) ,
床用つや出し洗浄剤組成物の製造方法。A method for producing a floor polish cleaning composition.
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| DE4335046A1 (en) * | 1993-10-14 | 1995-04-20 | Henkel Kgaa | Aqueous floor cleaning agent |
| PT876458E (en) * | 1995-12-29 | 2000-12-29 | Procter & Gamble | CLEANING COMPOSITIONS FOR HARD SURFACES |
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| US6403546B1 (en) * | 2001-01-31 | 2002-06-11 | S. C. Johnson Commercial Markets, Inc. | Floor cleaner and gloss enhancer |
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