JP5281824B2 - Polishing agent and cleaning sheet for hard surface - Google Patents
Polishing agent and cleaning sheet for hard surface Download PDFInfo
- Publication number
- JP5281824B2 JP5281824B2 JP2008145238A JP2008145238A JP5281824B2 JP 5281824 B2 JP5281824 B2 JP 5281824B2 JP 2008145238 A JP2008145238 A JP 2008145238A JP 2008145238 A JP2008145238 A JP 2008145238A JP 5281824 B2 JP5281824 B2 JP 5281824B2
- Authority
- JP
- Japan
- Prior art keywords
- oil
- component
- polish
- sheet
- polishing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 55
- 238000005498 polishing Methods 0.000 title claims description 46
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 55
- 239000000463 material Substances 0.000 claims abstract description 42
- 239000003921 oil Substances 0.000 claims abstract description 40
- 235000019198 oils Nutrition 0.000 claims abstract description 40
- 239000004094 surface-active agent Substances 0.000 claims abstract description 26
- 239000003925 fat Substances 0.000 claims abstract description 19
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 17
- 235000019486 Sunflower oil Nutrition 0.000 claims abstract description 11
- 239000002600 sunflower oil Substances 0.000 claims abstract description 11
- 238000001035 drying Methods 0.000 claims abstract description 9
- 239000004006 olive oil Substances 0.000 claims abstract description 7
- 235000008390 olive oil Nutrition 0.000 claims abstract description 7
- 239000010495 camellia oil Substances 0.000 claims abstract description 4
- 229920001577 copolymer Polymers 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 21
- 239000004359 castor oil Substances 0.000 claims description 13
- 235000019438 castor oil Nutrition 0.000 claims description 13
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 13
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 13
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 10
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- 239000003549 soybean oil Substances 0.000 claims description 5
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- 235000021388 linseed oil Nutrition 0.000 claims description 4
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- 244000236655 Diospyros kaki Species 0.000 claims description 2
- 229940087559 grape seed Drugs 0.000 claims 1
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- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
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- 125000000217 alkyl group Chemical group 0.000 description 7
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- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
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- 229920005862 polyol Polymers 0.000 description 4
- 150000003077 polyols Chemical class 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000002344 surface layer Substances 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 229920001214 Polysorbate 60 Polymers 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- 229930006000 Sucrose Natural products 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 239000003242 anti bacterial agent Substances 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 229940121375 antifungal agent Drugs 0.000 description 3
- 239000003429 antifungal agent Substances 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
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- 150000003242 quaternary ammonium salts Chemical class 0.000 description 3
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- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 2
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- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
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- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
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Landscapes
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
- Detergent Compositions (AREA)
Abstract
Description
本発明は、つや出し剤に関し、特に床などの硬質表面に高光沢を付与できるつや出し剤及びこれを用いた硬質表面用清掃シートに関する。 The present invention relates to a polishing agent, and more particularly to a polishing agent capable of imparting high gloss to a hard surface such as a floor and a cleaning sheet for a hard surface using the same.
従来、床などの硬質表面のつや出しをする場合、髪や埃などの汚れを取り除く洗浄剤や布、スポンジ等と、つや出しを行うワックス剤（つや出し剤）とを用い、洗浄処理、ワックス処理を順次行っていた。このため、硬質表面のつや出しを行なうには多大な手間と時間がかかっていた。 Conventionally, when polishing hard surfaces such as floors, cleaning agents, cloths, sponges, etc. that remove dirt such as hair and dust, and waxing agents (polishing agents) that polish are used, and washing and waxing are sequentially performed. I was going. For this reason, it took a lot of labor and time to polish the hard surface.
特許文献１には、硬質表面のワックス仕上げ処理を効果的且つ省力的に行うことのできるワックス剤として、アルカリ金属の炭酸塩及び重炭酸塩の少なくとも１つを含む水溶液を電気分解して得られた電解洗浄液と、人体への健康阻害要因となりにくい天然ワックスを主成分とするワックス剤とを含有する洗浄ワックス剤が記載されている。 Patent Document 1 discloses an aqueous solution containing at least one of an alkali metal carbonate and bicarbonate as a wax agent capable of effectively and labor-saving wax finishing of a hard surface. In addition, there is described a cleaning wax agent containing an electrolytic cleaning solution and a wax agent mainly composed of a natural wax which is not likely to be a health inhibiting factor for the human body.
天然ワックスを主成分とするワックス剤は、つや出し剤を塗布後に、磨き上げのための仕上げ拭きが必要である。しかし、特許文献１に記載の洗浄ワックス剤は、仕上げ拭きの必要はなく簡便ではあるが、満足できるつや効果を付与できない。 The wax agent mainly composed of natural wax requires a finish wiping for polishing after applying the polish. However, the cleaning wax agent described in Patent Document 1 is simple and does not require finishing wiping, but cannot provide a satisfactory gloss effect.
従って、本発明の目的は、天然油脂を用いたつや出し剤でありながら、合成樹脂を用いたつや出し剤の様な高光沢を付与することができるつや出し剤及びこれを用いた硬質表面用清掃シートを提供することを目的とする。 Accordingly, an object of the present invention is to provide a polishing agent capable of imparting high gloss like a polishing agent using a synthetic resin and a hard surface cleaning sheet using the same, although it is a polishing agent using natural fats and oils. The purpose is to provide.
本発明者らは、硬質表面に高光沢を付与し得るつや出し剤について種々検討した結果、オレイン酸等の不飽和結合（二重結合）の少ない脂肪酸を多く含んだ特定の天然油脂が優れた光沢付与能を有しているとの知見を得、更に検討した結果、該特定の天然油脂と、特定の高分子乳化剤と、特定の界面活性剤との３成分を含有する組成物が、つや出し剤として有効であり、また、前記高分子乳化剤を含むことで、塗布時の油性感やべたつき感が著しく抑制され、さらっとした感触と所望する粘度を得ることができるとの知見を得た。 As a result of various investigations on polishes capable of imparting high gloss to hard surfaces, the present inventors have found that specific natural fats and oils containing a large amount of unsaturated bonds (double bonds) such as oleic acid have excellent gloss. As a result of obtaining and finding that it has an imparting ability, a composition containing three components of the specific natural oil and fat, a specific polymer emulsifier, and a specific surfactant is a polish. As a result, it was found that the oily feeling and stickiness at the time of application were remarkably suppressed by containing the above-mentioned polymer emulsifier, and a smooth feel and a desired viscosity could be obtained.
本発明は、前記知見に基づきなされたもので、（Ａ）不乾性油又は乾性油から選択される１種以上の天然油脂と、（Ｂ）アクリル酸・メタクリル酸アルキルコポリマーと、（Ｃ）ＨＬＢ８〜１４の界面活性剤とを含有するつや出し剤を提供することにより、前記目的を達成したものである。 The present invention has been made on the basis of the above knowledge, and (A) one or more natural oils and fats selected from non-drying oils or drying oils, (B) acrylic acid / alkyl methacrylate copolymers, and (C) HLB8. The object is achieved by providing a polishing agent containing -14 surfactants.
また本発明は、前記つや出し剤をシート基材に含浸させてなる硬質表面用清掃シートを提供することにより、前記目的を達成したものである。 Moreover, this invention achieves the said objective by providing the cleaning sheet for hard surfaces which makes a sheet base material impregnate the said polish.
本発明のつや出し剤によれば、床などの硬質表面に拭きスジを生じさせずに高光沢を効率的に付与することができる。また、本発明の硬質表面用清掃シートによれば、硬質表面の汚れを除去しつつ高光沢を付与することができ、合成樹脂を用いたワックス剤のように溶剤を多量に含まないため、作業環境を悪化させない。更に、塗布前の洗浄作業、及び一度つや出し処理を施した硬質表面に対して、再度つや出し処理を行う場合の被膜を除去する作業を必要としないため作業の軽減が図られる。 According to the polishing agent of the present invention, high gloss can be efficiently imparted without causing wiping lines on a hard surface such as a floor. Further, according to the cleaning sheet for hard surface of the present invention, it is possible to impart high gloss while removing dirt on the hard surface, and it does not contain a large amount of solvent like a wax agent using a synthetic resin. Does not deteriorate the environment. Furthermore, since the cleaning work before coating and the work for removing the coating when the polishing process is performed again on the hard surface once subjected to the polishing process are not required, the work can be reduced.
以下、先ず、本発明のつや出し剤について説明する。
本発明のつや出し剤は、下記（Ａ）〜（Ｃ）の３成分を必須成分として含有する。
・（Ａ）成分：不乾性油又は乾性油から選択される１種以上の天然油脂
・（Ｂ）成分：アクリル酸・メタクリル酸アルキルコポリマー
・（Ｃ）成分：ＨＬＢ８〜１４の界面活性剤
Hereinafter, first, the polish of the present invention will be described.
The polish of the present invention contains the following three components (A) to (C) as essential components.
Component (A): One or more natural fats and oils selected from non-drying oils or drying oils Component (B): acrylic acid / alkyl methacrylate copolymer Component (C): surfactants of HLB 8-14
（Ａ）成分の天然油脂は、つや出し成分であり、主として塗布ムラや拭きスジを生じさせずに高光沢のつや出し効果の発現に寄与する。塗布ムラは、塗布時につや出し剤がきれいに塗布できない箇所である。また、拭きスジは、塗布時につや出し剤がきれいに塗布されたにもかかわらず、該つや出し剤の乾燥後に光沢を発現しない箇所である。
（Ａ）成分の天然油脂としては、ハイオレイックサフラワー油（紅花）、ハイオレイックヒマワリ油、オリーブ油、椿油、ヒマシ油等の不乾性油；グレープシード油、大豆油、あまに油、えの油、きり油、サフラワー油、ヒマワリ油等の乾性油が挙げられ、本発明ではこれらの１種を単独で又は２種以上を適宜組み合わせて使用することができる。これらの天然油脂は、何れも植物油であり、２５℃で液状又はペースト状のものである。
The component (A) natural fat / oil is a glossy component, and contributes to the development of a glossy effect with high gloss without mainly causing uneven coating and wiping lines. The coating unevenness is a portion where the polishing agent cannot be applied cleanly at the time of coating. Further, the wiping lines are places where gloss does not appear after the polishing agent is dried, even though the polishing agent is neatly applied at the time of application.
Non-drying oils such as high oil safflower oil (safflower), high oleic sunflower oil, olive oil, camellia oil, castor oil; grape seed oil, soybean oil, linseed oil, These oils can be used alone or in combination of two or more, as appropriate, in the present invention. These natural fats and oils are all vegetable oils and are liquid or pasty at 25 ° C.
本発明のつや出し剤は、つや出し成分として（Ａ）成分の天然油脂を用いることにより、つや出し成分として合成樹脂やシリコーンを用いたつや出し剤に比して、遜色の無い光沢感及び拭きスジ防止性を示し、且つ再度のつや出し処理においては、前回のつや出し処理で形成された被膜の除去処理を行う必要が無く、常法通りつや出し剤を１度塗りするだけで、拭きスジの無い高光沢を実現できる。更に、シリコーンを用いた時のように、塗布面に滑りが生じないため、転倒などの危険性がない。 The polish of the present invention uses the natural fat or oil of component (A) as a polish component, and has a glossiness that is inferior to the polish using synthetic resin or silicone as a polish component and wiping streak prevention. In the glossing process shown again, it is not necessary to remove the coating formed in the previous glossing process, and it is possible to achieve high gloss without wiping lines by simply applying the glossing agent once as usual. . Furthermore, since there is no slip on the coated surface as in the case of using silicone, there is no danger of falling.
上述した天然油脂の中でも、特に、不飽和結合（二重結合）の少ない脂肪酸であるオレイン酸又はリノール酸〔オレイン酸（炭素数１８）の二重結合の数１、リノール酸（炭素数１８）の二重結合の数２〕を主成分とする（全組成中に５０質量％以上含有する）ものが好ましく、とりわけ、ハイオレイックサフラワー油、ハイオレイックヒマワリ油、オリーブ油、椿油、ヒマシ油、あまに油、えの油、きり油、サフラワー油、ヒマワリ油、大豆油及びグレープシード油は、少量で高いつや出し効果が得られるため、本発明で好ましく用いられる。中でも、ハイオレイックヒマワリ油、オリーブ油、椿油、グレープシード油、大豆油が好ましく、更に好ましくはハイオレイックヒマワリ油、オリーブ油、椿油、グレープシード油である。ハイオレイックヒマワリ油は、通常のヒマワリ油に比して、オレイン酸の含有量が多いという特徴がある。 Among the above-mentioned natural fats and oils, in particular, oleic acid or linoleic acid, which is a fatty acid with few unsaturated bonds (double bonds) [number of double bonds of oleic acid (carbon number 18), linoleic acid (carbon number 18) Of the number of double bonds in the composition (containing 50% by mass or more in the total composition), particularly high oleic safflower oil, high oleic sunflower oil, olive oil, camellia oil, and castor oil. Amarine oil, linseed oil, persimmon oil, safflower oil, sunflower oil, soybean oil and grape seed oil are preferably used in the present invention because a high gloss effect can be obtained in a small amount. Among these, high oleic sunflower oil, olive oil, cocoon oil, grape seed oil, and soybean oil are preferable, and high oleic sunflower oil, olive oil, cocoon oil, and grape seed oil are more preferable. High oleic sunflower oil is characterized by a high content of oleic acid compared to normal sunflower oil.
（Ａ）成分の天然油脂は、単独で又は２種以上を組み合わせて使用することができ、つや出し効果の観点から、全組成中に０．０１〜７０質量％、好ましくは０．０１〜５０質量％、更に好ましくは０．０１〜４５質量％含有される。 The component (A) natural fats and oils can be used alone or in combination of two or more thereof, and from the viewpoint of the glossing effect, 0.01 to 70% by mass, preferably 0.01 to 50% by mass, in the total composition. %, More preferably 0.01 to 45% by mass.
（Ｂ）成分のアクリル・メタクリル酸アルキルコポリマーは、アクリル酸とメタクリル酸アルキル（好ましくはアルキル基の炭素数１０〜３０）との共重合体であり、本発明のつや出し剤においては主として（Ａ）成分の天然油脂の乳化剤及びつや出し剤の増粘剤として作用する。（Ａ）成分の天然油脂と共に（Ｂ）成分のアクリル・メタクリル酸アルキルコポリマーを併用することにより、つや出し剤中における油脂の油滴径が小さくなり、さらに、併用する界面活性剤量を低減することができると共に塗布時の油性感やべたつき感が著しく抑制され、さらっとした感触と所望する粘度を得ることができる。 The (B) component acrylic / methacrylic acid copolymer is a copolymer of acrylic acid and alkyl methacrylate (preferably an alkyl group having 10 to 30 carbon atoms). In the polish of the present invention, (A) Acts as an emulsifier for natural fats and oils and as a thickener for polishes. By using together the natural fats and oils of component (A) and the acrylic / alkyl methacrylate copolymer of component (B), the oil droplet diameter of the fats and oils in the polish is reduced, and the amount of surfactant used in combination is reduced. In addition, the oily feeling and stickiness at the time of application can be remarkably suppressed, and a dry feel and a desired viscosity can be obtained.
（Ｂ）成分のアクリル・メタクリル酸アルキルコポリマーとしては、例えば、下記一般式（１）で表される化合物（共重合体）が好ましい。下記式（１）中、Ｒは炭素数１０〜３０のアルキル基を示し、Ｘ及びＹはそれぞれ共重合体における各ユニットのモル％を示し、Ｘ=８０．０〜９９．９モル％、Ｙ=０．１〜２０．０モル％である。 As the acrylic / alkyl methacrylate copolymer as the component (B), for example, a compound (copolymer) represented by the following general formula (1) is preferable. In the following formula (1), R represents an alkyl group having 10 to 30 carbon atoms, X and Y represent mol% of each unit in the copolymer, X = 80.0 to 99.9 mol%, Y = 0.1 to 20.0 mol%.
（Ｂ）成分のアクリル・メタクリル酸アルキルコポリマーとしては、市販品を用いることもでき、例えば、ペムレンＴＲ−１、ペムレンＴＲ−２、カーボポール１３８２、カーボポールＥＴＤ２０２０（商品名、Noveon Inc.社製）、アクペックＨＶ５０１ＥＲ（住友精化社）等の市販品を使用することができる。本発明ではこれらの1種を単独で又は２種以上を適宜組み合わせて使用することができる。これらの中でも、乳化安定性と増粘性の観点から、ペムレンＴＲ−２が好ましい。 As the (B) component acrylic / alkyl methacrylate copolymer, commercially available products may be used. For example, Pemlen TR-1, Pemlen TR-2, Carbopol 1382, Carbopol ETD2020 (trade name, manufactured by Noveon Inc.) ), Commercially available products such as ACPEC HV501ER (Sumitomo Seika Co., Ltd.) can be used. In this invention, these 1 type can be used individually or in combination of 2 or more types as appropriate. Among these, Pemlene TR-2 is preferable from the viewpoints of emulsion stability and thickening.
（Ｂ）成分のアクリル・メタクリル酸アルキルコポリマーは、つや出し剤の乳化安定性及び光沢付与効果と粘度とのバランスの観点から、全組成中に好ましくは０．０１〜２質量％、更に好ましくは０．０１〜１質量％含有される。 The component (B), which is an acrylic / alkyl methacrylate copolymer, is preferably 0.01 to 2% by mass, more preferably 0, in the total composition from the viewpoint of the emulsification stability of the polish and the balance between the gloss-imparting effect and the viscosity. 0.01 to 1% by mass is contained.
（Ｃ）成分のＨＬＢ８〜１４の界面活性剤は、その界面活性作用により、本発明のつや出し剤の乳化安定性を高め、延いては光沢付与能を高める上で重要な成分である。ここで、ＨＬＢ（親水性・親油性バランス）は、下記のグリフィンの式により計算されるものである。（Ｃ）成分の界面活性剤のＨＬＢは、好ましくは９〜１３である。界面活性剤のＨＬＢが８未満又は１４を超えると、光沢性能及び乳化安定性に劣る。
＜グリフィンの式＞
ＨＬＢ＝２０×｛（界面活性剤中に含まれる親水基の分子量）／（界面活性剤の分子量）｝
Component (C) HLB 8-14 surfactant is an important component for enhancing the emulsification stability of the polish of the present invention and, hence, the gloss-imparting ability, due to its surface active action. Here, HLB (hydrophilic / lipophilic balance) is calculated by the following Griffin equation. The HLB of the surfactant (C) is preferably 9-13. When the HLB of the surfactant is less than 8 or exceeds 14, the gloss performance and the emulsion stability are inferior.
<Griffin formula>
HLB = 20 × {(molecular weight of hydrophilic group contained in surfactant) / (molecular weight of surfactant)}
（Ｃ）成分のＨＬＢ８〜１４の界面活性剤としては、ポリオキシエチレンヒマシ油または硬化ヒマシ油誘導体、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレングリコールの脂肪酸エステル、ポリオキシエチレンアルキルエーテル、ポリオキシエチレン脂肪酸エステル、ポリグリセリンアルキルエーテル、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル等の非イオン性界面活性剤が挙げられ、本発明ではこれらの１種を単独で又は２種以上を適宜組み合わせて使用することができる。これらの中でも、ツヤ出し効果と乳化安定性の観点から、ポリオキシエチレン硬化ヒマシ油、ポリエチレングリコールモノオレエート、ポリオキシエチレンオレイルエーテル、テトラオレイン酸ポリオキシエチレンソルビット、ポリオキシエチレンソルビタンモノオレエート、ポリオキシエチレンソルビタントリオレエートが好ましい。 (C) Component HLB8-14 surfactants include polyoxyethylene castor oil or hardened castor oil derivative, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene glycol fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene Nonionic surfactants such as fatty acid esters, polyglycerin alkyl ethers, polyglycerin fatty acid esters, and sucrose fatty acid esters may be mentioned. In the present invention, one of these may be used alone or two or more may be used in appropriate combination. Can do. Among these, from the viewpoint of the glossing effect and emulsion stability, polyoxyethylene hydrogenated castor oil, polyethylene glycol monooleate, polyoxyethylene oleyl ether, polyoxyethylene sorbite tetraoleate, polyoxyethylene sorbitan monooleate, Polyoxyethylene sorbitan trioleate is preferred.
（Ｃ）成分の界面活性剤は、ツヤ出し効果と乳化安定性の観点から、全組成中に好ましくは０．１〜３質量％、更に好ましくは０．１〜２質量％含有される。 The surfactant (C) is preferably contained in the total composition in an amount of 0.1 to 3% by mass, more preferably 0.1 to 2% by mass, from the viewpoint of the glossing effect and the emulsion stability.
本発明のつや出し剤は、つや出し効果及び拭きスジ防止と乳化安定性と粘度のバランスの観点から、（Ａ）成分の天然油脂を全組成中に０．０１〜７０質量％、好ましくは０．０１〜５０質量％、更に好ましくは０．０１〜４５質量％、（Ｂ）成分のアクリル酸・メタクリル酸アルキルコポリマーを全組成中に０．０１〜２質量％、好ましくは０．０１〜１質量％、（Ｃ）成分の界面活性剤を全組成中に０．１〜３質量％、好ましくは０．１〜２質量％含有することが好ましい。 The glossing agent of the present invention is 0.01 to 70% by mass, preferably 0.01% of the natural fat / oil of the component (A) in terms of the glossing effect, the prevention of wiping lines, and the balance between emulsification stability and viscosity. To 50% by mass, more preferably 0.01 to 45% by mass, and (B) component acrylic acid / alkyl methacrylate copolymer in an overall composition of 0.01 to 2% by mass, preferably 0.01 to 1% by mass. The surfactant of component (C) is 0.1 to 3% by mass, preferably 0.1 to 2% by mass in the total composition.
本発明のつや出し剤は、前記（Ａ）〜（Ｃ）の３成分に加えて、バランス量の水を含有する。水の含有量は、つや出し剤の全質量に対して好ましくは２５〜９９．８質量％である。 The polish of the present invention contains a balance amount of water in addition to the three components (A) to (C). The water content is preferably 25 to 99.8% by mass relative to the total mass of the polish.
また、本発明のつや出し剤には、前記（Ａ）〜（Ｃ）の３成分及び水に加えて更に、本発明の効果を妨げない範囲で、この種のつや出し剤に使用される他の成分を適宜含有させることができる。他の成分としては、前記（Ｂ）成分以外の高分子乳化剤、前記（Ｃ）成分以外の界面活性剤、抗菌・抗カビ剤、ｐＨ調整剤、粘度調整剤、酸化防止剤、香料、色素、水溶性有機溶媒、水溶性ポリオール類等を挙げることができる。これら他の成分の含有量は特に制限されないが、つや出し剤の全質量に対して好ましくは０．００１〜１０質量％である。 In addition to the three components (A) to (C) and water, the polishing agent of the present invention further includes other components used in this type of polishing agent within a range not impeding the effects of the present invention. Can be appropriately contained. As other components, a polymer emulsifier other than the component (B), a surfactant other than the component (C), an antibacterial / antifungal agent, a pH adjuster, a viscosity adjuster, an antioxidant, a fragrance, a pigment, Examples thereof include water-soluble organic solvents and water-soluble polyols. The content of these other components is not particularly limited, but is preferably 0.001 to 10% by mass with respect to the total mass of the polish.
また、本発明のつや出し剤には、前記（Ｂ）成分のアクリル酸・メタクリル酸アルキルコポリマー以外の高分子乳化剤として、アルキル変性水溶性高分子を適宜含有させることができる。アルキル変性水溶性高分子の市販品としては、アキュリン33（ISP社）等のアクリル酸アルキル共重合体；；Natrosol Plus 330CS、polysurf 67（以上、Aqualon Group、Hercules Inc.に所属）等のアルキル変性ヒドロキシエチルセルロース等が挙げられる。さらに、（メタ）アクリル酸・（メタ）アクリル酸アルキル共重合体の誘導体又はその塩として、（メタ）アクリル酸・（メタ）アクリル酸アルキル共重合体にポリオキシエチレンアルキルエーテルがエステル結合した、アクリル酸・メタクリル酸・アクリル酸アルキル・メタクリル酸アルキル・メタクリル酸のポリオキシエチレンアルキルエーテルエステル共重合体（例えばアクリル酸アルキル・メタクリル酸アルキル・ポリオキシエチレン（20）ステアリルエーテル共重合体（アキュリン22（ISP社））等の市販品を使用することもできる。 The polish of the present invention can appropriately contain an alkyl-modified water-soluble polymer as a polymer emulsifier other than the component (B) acrylic acid / alkyl methacrylate copolymer. Commercially available alkyl-modified water-soluble polymers include alkyl acrylate copolymers such as Aculin 33 (ISP); alkyl-modified such as Natrosol Plus 330CS and polysurf 67 (above, belonging to Aqualon Group and Hercules Inc.) Examples thereof include hydroxyethyl cellulose. Furthermore, as a derivative of (meth) acrylic acid / alkyl (meth) acrylate copolymer or a salt thereof, polyoxyethylene alkyl ether is ester-bonded to (meth) acrylic acid / alkyl (meth) acrylate copolymer, Acrylic acid / methacrylic acid / alkyl acrylate / alkyl methacrylate / methacrylic acid polyoxyethylene alkyl ether ester copolymer (for example, alkyl acrylate / alkyl methacrylate / polyoxyethylene (20) stearyl ether copolymer (Aculin 22) (ISP)) can also be used.
また、本発明のつや出し剤には、前記（Ｃ）成分以外の界面活性剤として、非イオン性界面活性剤、陰イオン性界面活性剤、陽イオン性界面活性剤、両性界面活性剤を適宜含有させることができる。非イオン性界面活性剤としては、ポリオキシエチレンヒマシ油、ポリオキシエチレン硬化ヒマシ油、ラウリン酸ポリオキシエチレン硬化ヒマシ油、イソステアリン酸ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレン硬化ヒマシ油、ピログルタミン酸イソステアリン酸ジエステル等のポリオキシエチレンヒマシ油、又は硬化ヒマシ油誘導体；ポリオキシエチレンソルビタンモノラウレート、ポリオキシエチレンソルビタンモノパルミテート、ポリオキシエチレンソルビタンモノステアレート、ポリオキシエチレンソルビタンモノイソステアレート、ポリオキシエチレンソルビタンテトラオレエート等のポリオキシエチレングリセリルモノイソステアレート、ポリオキシエチレングリセリルトリイソステアレート等のポリオキシグリコールの脂肪酸エステル；ポリオキシエチレンラウリルエーテル、ポリオキシエチレンヘキシルデシルエーテル、ポリオキシエチレンセチルエーテル、ポリオキシエチレンステアリルエーテル、ポリオキシエチレンオクチルドデシルエーテル、ポリオキシエチレンベヘニルエーテル、ポリオキシエチレンノニルフェニルエーテル、ポリオキシエチレンポリオキシプロピレンデシルテトラデシルエーテル等のポリオキシエチレンアルキルエーテル；ポリオキシエチレンモノオレエート等のポリオキシエチレン脂肪酸エステル；等のポリオキシエチレン付加型界面活性剤のほか、ポリグリセリンアルキルエーテル、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、アルキル（炭素数８〜２２の直鎖又は分岐鎖）グリコシド（平均糖縮合度１〜５）等が挙げられる。非イオン性界面活性剤としては低泡性であることが望ましい。陰イオン性界面活性剤としては、ポリオキシエチレンラウリルエーテル硫酸トリエタノールアミン等のポリオキシエチレンアルキル硫酸塩系界面活性剤；ラウロイルサルコシンナトリウム、ラウロイルメチルアラニンナトリウム等のＮ-アシルアミン酸塩系界面活性剤；ポリオキシエチレンラウリルエーテルリン酸ナトリウム、ポリオキシエチレンセチルエーテルリン酸ナトリウム、ジポリオキシエチレンアルキルエーテルリン酸、トリポリオキシエチレンアルキルエーテルリン酸、ジポリオキシエチレンノニルフェニルエーテルリン酸、ポリオキシエチレンラウリルエーテルリン酸ナトリウム、ジポリオキシエチレンラウリルエーテルリン酸ナトリウム等のポリオキシエチレンアルキルエーテルリン酸塩系界面活性剤などが挙げられる。両性界面活性剤としては、アルキルベタイン、アルキルアミドベタイン、アルキルアミンオキサイド等が挙げられる。陽イオン性界面活性剤としては、ジ長鎖アルキル四級アンモニウム塩、モノ長鎖アルキル四級アンモニウム塩、ジ長鎖アルキルポリオキシエチレン四級アンモニウム塩、ビス（ヒドロキシアルキル）四級アンモニウム塩、アミド／エステル結合を有する四級アンモニウム塩等が挙げられる。これらの成分（前記（Ｃ）成分以外の界面活性剤）は、単独で、又は２種以上を組み合わせて使用することができる。 Further, the polish of the present invention appropriately contains a nonionic surfactant, an anionic surfactant, a cationic surfactant, an amphoteric surfactant as a surfactant other than the component (C). Can be made. Nonionic surfactants include polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil, polyoxyethylene hydrogenated castor oil laurate, polyoxyethylene hydrogenated castor oil isostearate, polyoxyethylene hydrogenated castor oil, isostearic pyroglutamate. Polyoxyethylene castor oil such as acid diester, or hardened castor oil derivative; polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monopalmitate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monoisostearate, poly Polyoxyglycols such as polyoxyethylene glyceryl monoisostearate such as oxyethylene sorbitan tetraoleate and polyoxyethylene glyceryl triisostearate Fatty acid ester; polyoxyethylene lauryl ether, polyoxyethylene hexyl decyl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene octyldodecyl ether, polyoxyethylene behenyl ether, polyoxyethylene nonylphenyl ether, polyoxy Polyoxyethylene alkyl ethers such as ethylene polyoxypropylene decyl tetradecyl ether; polyoxyethylene fatty acid esters such as polyoxyethylene monooleate; polyoxyethylene addition type surfactants such as polyglycerin alkyl ether, polyglycerin Fatty acid ester, sucrose fatty acid ester, alkyl (linear or branched chain having 8 to 22 carbon atoms) glycoside (average sugar condensation degree 1 to 5) Etc. The. The nonionic surfactant desirably has low foaming properties. Examples of the anionic surfactant include polyoxyethylene alkyl sulfate surfactants such as polyoxyethylene lauryl ether sulfate triethanolamine; N-acylamine surfactants such as sodium lauroyl sarcosine and sodium lauroylmethylalanine ; Sodium polyoxyethylene lauryl ether, sodium polyoxyethylene cetyl ether, dipolyoxyethylene alkyl ether phosphoric acid, tripolyoxyethylene alkyl ether phosphoric acid, dipolyoxyethylene nonylphenyl ether phosphoric acid, polyoxyethylene lauryl Examples thereof include polyoxyethylene alkyl ether phosphate surfactants such as sodium ether phosphate and sodium dipolyoxyethylene lauryl ether phosphate. Examples of amphoteric surfactants include alkyl betaines, alkyl amide betaines, and alkyl amine oxides. Cationic surfactants include di-long-chain alkyl quaternary ammonium salts, mono-long-chain alkyl quaternary ammonium salts, di-long-chain alkyl polyoxyethylene quaternary ammonium salts, bis (hydroxyalkyl) quaternary ammonium salts, amides / Quaternary ammonium salts having an ester bond are mentioned. These components (surfactants other than the component (C)) can be used alone or in combination of two or more.
特につや出し効果の観点から、本発明のつや出し剤には前記特定の陽イオン性界面活性剤を含有させることが好ましい。この場合、つや出し剤における前記（Ｂ）成分のアクリル・メタクリル酸アルキルコポリマーと陽イオン性界面活性剤との含有質量比は、（Ｂ）成分：陽イオン性界面活性剤＝１：０．５〜１：２、更に好ましくは１：１〜１：１．５の範囲にあることが好ましい。 In particular, from the viewpoint of the polishing effect, the polishing agent of the present invention preferably contains the specific cationic surfactant. In this case, the content mass ratio between the acrylic / alkyl methacrylate copolymer of the component (B) and the cationic surfactant in the polishing agent is (B) component: cationic surfactant = 1: 0.5- It is preferably in the range of 1: 2, more preferably 1: 1 to 1: 1.5.
本発明のつや出し剤に含有可能な抗菌・抗カビ剤としては、例えば安息香酸、安息香酸ナトリウム、オルトフェニルフェノール、オルトフェニルフェノールナトリウム、ジフェニル、ソルビン酸、ソルビン酸カリウム、チアベンダゾール、デヒドロ酢酸、デヒドロ酢酸ナトリウム、パラオキシ安息香酸エチル、パラオキシ安息香酸ブチル、パラオキシ安息香酸プロピル、パラオキシ安息香酸イソブチル、パラオキシ安息香酸イソプロピル、プロピオン酸、プロピオン酸カルシウム、プロピオン酸ナトリウム、サリチル酸、２−（２−フリル）−３−（５−ニトロ−２−フリル）アクリル酸アミド、ラウリルトリメチルアンモニウム−２，４，５−トリクロルフェノキサイド、パラオキシ安息香酸メチル、フェノキシエタノール、イソプロピルメチルフェノール、塩化ベンザルコニウム、塩化ペンゼトニウム、トリクロロカルバニリド、５−クロロ−２−メチル−４−イソチアゾリン−３−オンと２−メチル−４−イソチアゾリン−３−オンとの混合物（ケーソンＣＧ）、イミダゾリジニルウレア、１，３−ジメチロール−５，５−ジメチルヒダントイン（ＤＭＤＭヒダントイン）、トリクロサン、塩化セチルピリジニウム、パラフェノールスルホン酸亜鉛、塩化アルキルトリメチルアンモニウム、塩化ジアルキルジメチルアンモニウム、１，２−ベンズイソチアゾリン−３−オン（ＢＩＴ）及びその誘導体（プロキセルＢＤＮ）、ε−ポリリジン、乳酸ナトリウム、ナイシン、カテキン、１，２−ジブロモ−２，４−ジシアノブタン等が挙げられる。これらの抗菌・抗カビ剤は単独で、又は２種以上を組み合わせて使用することができる。 Antibacterial and antifungal agents that can be contained in the polish of the present invention include, for example, benzoic acid, sodium benzoate, orthophenylphenol, sodium orthophenylphenol, diphenyl, sorbic acid, potassium sorbate, thiabendazole, dehydroacetic acid, dehydroacetic acid Sodium, ethyl paraoxybenzoate, butyl paraoxybenzoate, propyl paraoxybenzoate, isobutyl paraoxybenzoate, isopropyl paraoxybenzoate, propionic acid, calcium propionate, sodium propionate, salicylic acid, 2- (2-furyl) -3- (5-Nitro-2-furyl) acrylic acid amide, lauryltrimethylammonium-2,4,5-trichlorophenoxide, methyl paraoxybenzoate, phenoxyethanol, isopropyl Tylphenol, benzalkonium chloride, benzethonium chloride, trichlorocarbanilide, a mixture of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one (Caisson CG) , Imidazolidinyl urea, 1,3-dimethylol-5,5-dimethylhydantoin (DMDM hydantoin), triclosan, cetylpyridinium chloride, zinc paraphenolsulfonate, alkyltrimethylammonium chloride, dialkyldimethylammonium chloride, 1,2-benz Examples include isothiazoline-3-one (BIT) and derivatives thereof (proxel BDN), ε-polylysine, sodium lactate, nisin, catechin, 1,2-dibromo-2,4-dicyanobutane, and the like. These antibacterial and antifungal agents can be used alone or in combination of two or more.
本発明のつや出し剤に含有可能な水溶性有機溶媒としては、例えばエタノール、プロパノール、イソプロパノール、エチレングリコール、プロピレングリコール（ＰＧ）、グリセリン、１，３−ブチレングリコール等が挙げられる。これらの水溶性有機溶媒は単独で、又は２種類以上を組み合わせて使用することができる。 Examples of the water-soluble organic solvent that can be contained in the polish of the present invention include ethanol, propanol, isopropanol, ethylene glycol, propylene glycol (PG), glycerin, 1,3-butylene glycol, and the like. These water-soluble organic solvents can be used alone or in combination of two or more.
本発明のつや出し剤に含有可能な水溶性ポリオール類は、分子内に水酸基を２個以上有する多価アルコールであり、例えばエチレングリコール、プロピレングリコール、１，３−ブチレングリコール、１，４−ブチレングリコール等のアルキレングリコール；ジプロピレングリコール等のポリアルキレングリコール；グルコース、マルトース、マルチトース、ショ糖、フラクトース、キシリトール、ソルビトール、マルトトリオース、スレイトール等の糖アルコール；グリセリン、ポリグリセリン、エリスリトール、及び澱粉分解還元アルコール等が挙げられる。これらの水溶性ポリオール類は単独で、又は２種類以上を組み合わせて使用することができる。 Water-soluble polyols that can be contained in the polish of the present invention are polyhydric alcohols having two or more hydroxyl groups in the molecule, such as ethylene glycol, propylene glycol, 1,3-butylene glycol, 1,4-butylene glycol. Alkylene glycol such as dipropylene glycol; sugar alcohol such as glucose, maltose, maltose, sucrose, fructose, xylitol, sorbitol, maltotriose, threitol; glycerin, polyglycerin, erythritol, and starch degradation reduction Alcohol etc. are mentioned. These water-soluble polyols can be used alone or in combination of two or more.
本発明のつや出し剤に含有可能なｐＨ調整剤としては、例えば塩酸や硫酸などの無機酸、クエン酸、コハク酸、リンゴ酸、フマル酸、酒石酸、マロン酸、マレイン酸などの有機酸などの酸剤や、水酸化ナトリウムや水酸化ナトリウムや水酸化カリウム、アンモニアやその誘導体、モノエタノールアミンやジエタノールアミン、トリエタノールアミン等のアミン塩など、２−アミノ−２−メチル−１−プロパノール、炭酸ナトリウム、炭酸カリウムなどのアルカリ剤等が挙げられる。これらのｐＨ調整剤は単独で、又は２種類以上を組み合わせて使用することが出来る。 Examples of the pH adjuster that can be contained in the polish of the present invention include inorganic acids such as hydrochloric acid and sulfuric acid, acids such as citric acid, succinic acid, malic acid, fumaric acid, tartaric acid, malonic acid, and maleic acid. Agents, sodium hydroxide, sodium hydroxide, potassium hydroxide, ammonia and derivatives thereof, amine salts such as monoethanolamine, diethanolamine, triethanolamine, 2-amino-2-methyl-1-propanol, sodium carbonate, Examples include alkaline agents such as potassium carbonate. These pH adjusters can be used alone or in combination of two or more.
本発明のつや出し剤に含有可能な粘度調整剤としては、例えば天然多糖類、セルロース系高分子及び澱粉系高分子等の半合成高分子、ビニル系高分子及びポリエチレンオキシド等のその他合成高分子、ポリアクリル酸系、アクリル酸・メタクリル酸アルキル共重合体系、粘土鉱物等の水溶性高分子が挙げられる。これらの粘度調整剤は単独で、又は２種類以上を組み合わせて使用することができる。 Examples of the viscosity modifier that can be contained in the polish of the present invention include, for example, natural polysaccharides, semi-synthetic polymers such as cellulose polymers and starch polymers, other synthetic polymers such as vinyl polymers and polyethylene oxide, Examples thereof include water-soluble polymers such as polyacrylic acid, acrylic acid / alkyl methacrylate copolymer, and clay mineral. These viscosity modifiers can be used alone or in combination of two or more.
本発明のつや出し剤は、前記各成分を含有してなる、液状の水系組成物とすることができる。本発明のつや出し剤は、対象面に直接塗布してから、又は使用時に清掃シートに含浸してから、又は予め含浸してある清掃シートを用い、対象面を拭くという形で使用される。使用時には、モップなどの掃除具に装着して使用することができる。 The polish of the present invention can be made into a liquid aqueous composition containing the above-mentioned components. The polishing agent of the present invention is used in such a form that the target surface is wiped after being applied directly to the target surface, impregnating the cleaning sheet at the time of use, or using a pre-impregnated cleaning sheet. At the time of use, it can be used by attaching to a cleaning tool such as a mop.
前記使用方法が可能なつや出し剤の粘度は、ブルックフィールド粘度（２５℃）で、１〜１００００ｍＰａ・ｓ、好ましくは１〜１０００ｍＰａ・ｓ、更に好ましくは１〜８００ｍＰａ・ｓである。つや出し剤の粘度が斯かる範囲内にあると、安定した徐放性、及び含浸工程でのハンドリングの点で特に好ましい。ここで、前記粘度はブルックフィールド型粘度計を用いて測定される。使用ローター及び回転数は、つや出し剤粘度に応じて適宜変更する。つや出し剤の粘度調整は、上述した水溶性有機溶媒、水溶性ポリオール類、ｐＨ調整剤及び粘度調整剤を適宜組み合わせて用いることにより行なうことができる。 The viscosity of the polish that can be used is 1 to 10000 mPa · s, preferably 1 to 1000 mPa · s, and more preferably 1 to 800 mPa · s in Brookfield viscosity (25 ° C.). When the viscosity of the polish is within such a range, it is particularly preferable in terms of stable sustained release and handling in the impregnation step. Here, the viscosity is measured using a Brookfield viscometer. The rotor used and the number of rotations are changed as appropriate according to the viscosity of the polish. The viscosity of the polish can be adjusted by appropriately combining the above-described water-soluble organic solvent, water-soluble polyols, pH adjuster, and viscosity adjuster.
また、本発明のつや出し剤のｐＨ（液温２５℃におけるｐＨ）はつや出し効果、乳化安定性、安全性、洗浄性能の観点から、好ましくは３〜１０、更に好ましくは５〜９．５である。 Moreover, the pH (pH at a liquid temperature of 25 ° C.) of the polishing agent of the present invention is preferably 3 to 10, more preferably 5 to 9.5, from the viewpoints of polishing effect, emulsion stability, safety, and washing performance. .
本発明のつや出し剤は、常法により製造することができる。例えば、水に（Ｂ）成分のアクリル・メタクリル酸アルキルコポリマー、（Ｃ）成分の界面活性剤、（Ａ）成分の天然油脂、更に必要に応じて他の成分を順次添加することにより製造することができる。 The polish of the present invention can be produced by a conventional method. For example, it is manufactured by sequentially adding (B) component acrylic / alkyl methacrylate copolymer, (C) component surfactant, (A) natural fat and oil, and other components as necessary to water. Can do.
本発明のつや出し剤は、従来の液状のつや出し剤と同様に使用することができ、床、家具、木製品等の硬質表面のつや出し剤として有効である。本発明のつや出し剤によれば、少量で、硬質表面に拭きスジを生じさせずに高光沢とさらっとした感触を付与することができ、合成樹脂を用いたワックス剤のように溶剤を多量に含まないため、作業環境を悪化させない。また、再度のつや出し処理においては、硬質表面に残留している被膜の除去や仕上げ拭き等の作業をせずに、新たにつや出し剤を塗布するだけでつや出し効果が得られるため、作業性にも優れる。 The polish of the present invention can be used in the same manner as a conventional liquid polish and is effective as a polish for hard surfaces such as floors, furniture and wooden products. According to the polish of the present invention, a small amount can impart a high gloss and a light feel without causing wiping lines on a hard surface, and a large amount of solvent like a wax agent using a synthetic resin. Does not include, so does not deteriorate the work environment. In addition, in the re-polishing process, the effect of polishing can be obtained by simply applying a new polishing agent without removing the film remaining on the hard surface or wiping the finish. Excellent.
次に、本発明の硬質表面用清掃シート（以下清掃シートともいう）について説明する。
本発明の清掃シートは、上述した本発明のつや出し剤をシート基材に含浸させてなるものである。斯かる清掃シートは、つや出し剤による優れた光沢付与能のみならず、シート基材による硬質表面の汚れ捕集能も有しているため、硬質表面を該清掃シートで一度拭くだけで、硬質表面の洗浄とつや出しを同時に行なうことができ、硬質表面のつや出し処理の軽減を図ることができる。
Next, the hard surface cleaning sheet (hereinafter also referred to as a cleaning sheet) of the present invention will be described.
The cleaning sheet of the present invention is obtained by impregnating a sheet base material with the above-described polishing agent of the present invention. Such a cleaning sheet has not only an excellent gloss imparting ability due to the polish, but also a dirt collecting ability of the hard surface by the sheet base material, so that the hard surface can be wiped once with the cleaning sheet. The cleaning and polishing of the surface can be performed at the same time, and the polishing of the hard surface can be reduced.
本発明の清掃シートにおいては、つや出し剤をシート基材の全質量に対し、１〜８倍、特に２〜５倍の質量比で含浸させることが好ましい。シート基材につや出し剤を含浸させる方法としては、例えば、適当な容器に収容されているつや出し剤中に、シート材を浸漬する方法が挙げられる。 In the cleaning sheet of the present invention, the polishing agent is preferably impregnated at a mass ratio of 1 to 8 times, particularly 2 to 5 times the total mass of the sheet base material. Examples of the method of impregnating the sheet base material with the polishing agent include a method of immersing the sheet material in the polishing agent contained in an appropriate container.
前記シート基材としては、上述した本発明のつや出し剤を保持し得るものであれば良く、例えば、織布、不織布、編布、紙、等を用いることができる。シート基材の坪量や厚みは、清掃シートの用途等に応じて適宜設定することができる。また、前記シート基材の形成材料としては、レーヨン、コットン、パルプ、ポリエチレン系繊維、ポリプロピレン系繊維、ポリビニルアルコール繊維、ポリエステル系繊維、ポリアクリロニトリル系繊維、ナイロン繊維、アセテート繊維、ポリ塩化ビニル系繊維、親水性セルロース繊維、熱可塑性繊維、等が好ましく用いられる。これらのシート基材の形成材料は単独で、又は２種類以上を組み合わせて使用することができる。 As the sheet base material, any material can be used as long as it can hold the above-described polish of the present invention. For example, a woven fabric, a nonwoven fabric, a knitted fabric, paper, or the like can be used. The basis weight and thickness of the sheet base material can be appropriately set according to the use of the cleaning sheet. The sheet base material is formed of rayon, cotton, pulp, polyethylene fiber, polypropylene fiber, polyvinyl alcohol fiber, polyester fiber, polyacrylonitrile fiber, nylon fiber, acetate fiber, polyvinyl chloride fiber. Hydrophilic cellulose fibers, thermoplastic fibers, and the like are preferably used. These sheet base materials can be used alone or in combination of two or more.
前記シート基材の好ましい実施形態として、下記シート基材Ａが挙げられる。
シート基材Ａ：繊維長が２〜１５ｍｍで且つ繊度が１０〜１５０ｄｔｅｘの熱可塑性繊維を１０〜９０重量％、及びセルロース系繊維を１０〜９０重量％含み、表面に前記熱可塑性繊維の先端部が多数存在して、清掃対象面に存する汚れに対する研摩性ないし掻き取り性を有するシート基材。
The following sheet base material A is mentioned as preferable embodiment of the said sheet base material.
Sheet base material A: 10 to 90% by weight of a thermoplastic fiber having a fiber length of 2 to 15 mm and a fineness of 10 to 150 dtex, and 10 to 90% by weight of a cellulosic fiber, and a tip portion of the thermoplastic fiber on the surface A sheet base material having a large number of and having an abrasive property or a scraping property against dirt existing on the surface to be cleaned.
前記シート基材Ａに本発明のつや出し剤を含浸させて得られた清掃シートの一面を清掃対象面（硬質表面）に押し当てて、こすりつけることにより、該清掃シートに含浸されているつや出し剤が洗浄対象面に放出され、清掃対象面に存する汚れを膨潤、溶解ないし浮き上がらせる。これと共に、清掃シートの洗浄表面に多数存在している前記熱可塑性繊維の先端部が、清掃対象面に存する汚れを研摩ないし掻き取る。これらの機械的及び化学的作用によって、汚れが清掃対象面から除去される。除去された汚れは、つや出し剤中に溶け込むかあるいは分散して、つや出し剤と共に清掃シートに吸収される。このようにして、清掃対象面が清浄な状態となると共に、つや出し剤の作用により清掃対象面に高光沢が付与される。 The polishing agent impregnated in the cleaning sheet by pressing and rubbing one surface of the cleaning sheet obtained by impregnating the sheet base material A with the polishing agent of the present invention onto the surface to be cleaned (hard surface). Is discharged to the surface to be cleaned, and the dirt existing on the surface to be cleaned swells, dissolves or floats. At the same time, the tip portions of the thermoplastic fibers present on the cleaning surface of the cleaning sheet polish or scrape off the dirt present on the surface to be cleaned. By these mechanical and chemical actions, dirt is removed from the surface to be cleaned. The removed dirt is dissolved or dispersed in the polishing agent and absorbed by the cleaning sheet together with the polishing agent. In this way, the surface to be cleaned becomes clean and high gloss is imparted to the surface to be cleaned by the action of the polish.
前記シート基材Ａとしては、本出願人の先の出願に係る特開２００３−６１８８５号公報に記載の清掃用シートを用いることができる。前記シート基材Ａの坪量は５０〜５００ｇ／ｍ2であることが好ましい。 As the sheet substrate A, a cleaning sheet described in JP-A-2003-61885, which is related to the previous application of the present applicant, can be used. The basis weight of the sheet base material A is preferably 50 to 500 g / m 2 .
また、前記シート基材の好ましい別の実施形態として、下記シート基材Ｂが挙げられる。
シート基材Ｂ：繊維ウエブの繊維絡合で形成された不織布からなり、本発明のつや出し剤が含浸された該不織布における清掃対象面と接触する表面層の、サンドペーパー（粒度１２００番）に対する静摩擦抵抗値が９００〜２５００ｃＮであるシート基材。
前記静摩擦抵抗値は、前記表面層の繊維交絡状態の指標となるものであり、静摩擦抵抗値が９００〜２５００ｃＮ、好ましくは１１００〜２２００ｃＮ、更に好ましくは１２００〜２０００ｃＮの範囲にあることによって、髪の毛や埃等の汚れの捕集性とシート強度及びシート操作性とのバランスが良好となる。
Moreover, the following sheet base material B is mentioned as another preferable embodiment of the said sheet base material.
Sheet base material B: Static friction of the surface layer of the nonwoven fabric formed by entanglement of the fiber web and in contact with the surface to be cleaned of the nonwoven fabric impregnated with the polish of the present invention against sandpaper (particle size # 1200) A sheet base material having a resistance value of 900 to 2500 cN.
The static friction resistance value is an index of the fiber entanglement state of the surface layer, and the static friction resistance value is in the range of 900 to 2500 cN, preferably 1100 to 2200 cN, and more preferably 1200 to 2000 cN. The balance between the collection of dirt such as dust, the sheet strength, and the sheet operability is improved.
前記静摩擦抵抗値は、本出願人の先の出願に係る特開２００１−２６９３００号公報の図２に示す方法で測定される。即ち、サンドペーパー（３Ｍ社製耐水ペーパー Techno sander粒度１２００番）を張り付けた、底面が１０ｃｍ×１０ｃｍの重り（サンドペーパーを含む全重量４００ｇ）を、水平な台上にしっかりと固定された、つや出し剤の含浸されたシート材（２００ｍｍ×２８０ｍｍ）表面に、サンドペーパーのサンド面がシート材に対面するように載置する。重りの側面に糸を取り付け、この糸の他端を滑車を介して引張試験機（オリエンティック社製、ＲＴＭ−２５）のロードセルに取り付ける。引張試験機を作動させ、重りを５００ｍｍ／ｍｉｎの速度で水平に３０ｍｍ移動させ、その際の初期の最大静摩擦抵抗値を測定し、これを前記静摩擦抵抗値とする。測定は、シート基材の製造工程におけるシートの流れ方向（ＭＤ）と幅方向（ＣＤ）について実施し、サンドペーパーは１回の測定ごとに新しいものに交換する。ＭＤ及びＣＤの静摩擦抵抗値の何れもが前記範囲にあることが好ましい。 The static friction resistance value is measured by the method shown in FIG. 2 of Japanese Patent Laid-Open No. 2001-269300 according to the previous application of the present applicant. That is, a sandpaper (3M water resistant paper Techno sander particle size No. 1200) with a 10cm x 10cm bottom weight (400g total weight including sandpaper) is firmly fixed on a horizontal base. The sheet material (200 mm × 280 mm) impregnated with the agent is placed so that the sand surface of the sandpaper faces the sheet material. A thread is attached to the side of the weight, and the other end of the thread is attached to a load cell of a tensile tester (Orientic, RTM-25) via a pulley. The tensile tester is operated, the weight is moved horizontally by 30 mm at a speed of 500 mm / min, the initial maximum static friction resistance value at that time is measured, and this is defined as the static friction resistance value. The measurement is performed in the sheet flow direction (MD) and the width direction (CD) in the manufacturing process of the sheet base material, and the sandpaper is replaced with a new one for each measurement. It is preferable that both the static friction resistance values of MD and CD are in the above range.
前記シート基材Ｂは、例えば、内層と該内層を上下から挟持する一体の外層とが一体化された積層シートが挙げられる。外層は、前記表面層に相当する層であり、例えば、親水性セルロース繊維を３０〜９８質量％、及び低融点の熱可塑性繊維を２〜７０質量％程度含んで構成され、スパンレース法により製造することができる。内層は、紙、不織布、織物、樹脂ネット等の種々のシート材料から構成することができる。 Examples of the sheet base material B include a laminated sheet in which an inner layer and an integrated outer layer that sandwich the inner layer from above and below are integrated. The outer layer is a layer corresponding to the surface layer, and includes, for example, 30 to 98% by mass of hydrophilic cellulose fiber and 2 to 70% by mass of low melting point thermoplastic fiber, and is manufactured by a spunlace method. can do. The inner layer can be composed of various sheet materials such as paper, nonwoven fabric, woven fabric, and resin net.
前記シート基材Ｂとしては、本出願人の先の出願に係る特開２００１−２６９３００号公報に記載の床用清掃シートを用いることができる。前記シート基材Ｂの坪量は３０〜３００ｇ／ｍ2であることが好ましい。 As the sheet base material B, a floor cleaning sheet described in JP-A No. 2001-269300 according to an earlier application of the present applicant can be used. The basis weight of the sheet base material B is preferably 30 to 300 g / m 2 .
また、前記シート基材の好ましい別の実施形態として、下記シート基材Ｃが挙げられる。
シート基材Ｃ：繊維ウエブを水流交絡させて形成された繊維集合体で、少なくとも一面が、該繊維集合体の構成繊維の交絡によって形成された多数の凸部と該凸部を取り囲む形状の凹部とを有し、前記繊維集合体の前記一面は、サンドペーパー（粒度１２００番）に対する静摩擦抵抗値が９００〜２５００ｃＮであるシート基材。
シート基材Ｃに係る静摩擦抵抗値は、上述したシート基材Ｂに係る静摩擦抵抗値と同じ意味である。シート基材Ｃは、髪の毛や固形ゴミを始めとするダストの捕集性能が高く、また、清掃時の摩擦抵抗が低く、操作性が良好なものである。
Moreover, the following sheet base material C is mentioned as another preferable embodiment of the said sheet base material.
Sheet base material C: a fiber assembly formed by hydroentangling a fiber web, at least one surface of which is formed by entanglement of the constituent fibers of the fiber assembly and a recess that surrounds the projection And the one surface of the fiber assembly is a sheet base material having a static friction resistance value of 900 to 2500 cN with respect to sandpaper (particle size # 1200).
The static friction resistance value related to the sheet base material C has the same meaning as the static friction resistance value related to the sheet base material B described above. The sheet base material C has high dust collection performance including hair and solid dust, and has low frictional resistance during cleaning and good operability.
前記シート基材Ｃは、繊度５ｄｔｅｘ以下の繊維を５０重量％以上、特に３．５ｄｔｅｘ以下の繊維を７０重量％以上含んでいることが、清掃シートに孔あきの発生を防止する点、充分な嵩高さの発現及びその維持の点、並びに髪の毛の汚れ捕集性及び保持性の向上の点で好ましい。 The sheet base material C contains 50% by weight or more of fibers having a fineness of 5 dtex or less, particularly 70% by weight or more of fibers having a size of 3.5 dtex or less, which prevents the occurrence of perforation in the cleaning sheet. It is preferable in terms of the expression of the thickness and the maintenance thereof, and the improvement of the dirt collection and retention of the hair.
前記シート基材Ｃとしては、本出願人の先の出願に係る特開２００７−１５１８２１号公報に記載の床用清掃シートを用いることができる。前記シート基材Ｃの坪量は３０〜３００ｇ／ｍ2であることが好ましい。 As the sheet base material C, a floor cleaning sheet described in Japanese Patent Application Laid-Open No. 2007-151821 related to the previous application of the present applicant can be used. The basis weight of the sheet base material C is preferably 30 to 300 g / m 2 .
また、前記シート基材の好ましい別の実施形態として、下記シート基材Ｄが挙げられる。
シート基材Ｄ：液透過性の表面シート及び液保持性の吸収シートを具備してなり、該表面シートと該吸収シートとが一体化されている。前記表面シートは、パルプ繊維と熱可塑性繊維とを含む繊維混合物により形成されており、且つ表面に複数の凸部を有している。前記繊維混合物における前記熱可塑性繊維の含有量は、該繊維混合物の全重量に対して４０〜９５重量％である。前記吸収シートは、親水性セルロース系繊維と熱可塑性繊維とからなる繊維混合物により形成されており、該熱可塑性繊維の含有量は、該吸収シートの全重量に対して５〜５０重量％である。
Moreover, the following sheet base material D is mentioned as another preferable embodiment of the said sheet base material.
Sheet base D: A liquid-permeable surface sheet and a liquid-retaining absorbent sheet are provided, and the surface sheet and the absorbent sheet are integrated. The surface sheet is formed of a fiber mixture including pulp fibers and thermoplastic fibers, and has a plurality of convex portions on the surface. The content of the thermoplastic fiber in the fiber mixture is 40 to 95% by weight with respect to the total weight of the fiber mixture. The absorbent sheet is formed of a fiber mixture composed of hydrophilic cellulosic fibers and thermoplastic fibers, and the content of the thermoplastic fibers is 5 to 50% by weight with respect to the total weight of the absorbent sheet. .
前記シート基材Ｄにおいては、前記吸収シートの坪量は１０〜３００ｇ／ｍ2が好ましい。吸収シートの坪量が１０ｇ／ｍ2未満であると水分の保持量が少なくなり清掃面積が狭くなり、３００ｇ／ｍ2を超えると生産コストが高くなり、また清掃具での把持性が悪くなることがあるので好ましくない。また、前記表面シートの坪量は５〜１００ｇ／ｍ2が好ましい。表面シートの坪量が５ｇ／ｍ2未満であるとシート強度が弱くなり、破れたりヨレたりし、１００ｇ／ｍ2を超えると吸収シートから被清掃面への水分移行が悪くなり清掃性が悪くなるので、好ましくない。 In the sheet base D, the basis weight of the absorbent sheet is preferably 10 to 300 g / m 2 . If the basis weight of the absorbent sheet is less than 10 g / m 2 , the amount of moisture retained will be reduced and the cleaning area will be reduced, and if it exceeds 300 g / m 2 , the production cost will increase, and the gripping ability with the cleaning tool will deteriorate. This is not preferable. Moreover, 5-100 g / m < 2 > of the basic weight of the said surface sheet is preferable. If the basis weight of the top sheet is less than 5 g / m 2 , the sheet strength will be weak, and it will be torn or twisted. If it exceeds 100 g / m 2 , the moisture transfer from the absorbent sheet to the surface to be cleaned will be poor and the cleaning property will be poor This is not preferable.
前記シート基材Ｄとしては、本出願人の先の出願に係る特許第３６２１２２３号公報に記載の清掃シートを用いることができる。前記シート基材Ｄの坪量は２０〜７００ｇ／ｍ2であることが好ましい。 As the sheet substrate D, a cleaning sheet described in Japanese Patent No. 3612223 according to the previous application of the present applicant can be used. The basis weight of the sheet substrate D is preferably 20 to 700 g / m 2 .
本発明の清掃シートは、単層構造でも良く２層以上の多層構造でも良い。また、本発明の清掃シートの表面（洗浄面）にエンボス加工等により凹凸構造が形成されていても良い。 The cleaning sheet of the present invention may have a single layer structure or a multilayer structure of two or more layers. Moreover, the uneven structure may be formed by the embossing etc. on the surface (cleaning surface) of the cleaning sheet of this invention.
以下、本発明を実施例により更に具体的に説明するが、本発明は斯かる実施例に限定されるものではない。 EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples, but the present invention is not limited to such examples.
〔実施例１〜１０及び比較例１〜５〕
下記表１に示す組成のつや出し剤をそれぞれ作製し、これらを実施例及び比較例のサンプルとした。各実施例及び比較例においては、（Ａ）成分の天然油脂として、ハイオレイックヒマワリ油（横関油脂（株）製）、オリーブ油、大豆油、アマニ油（以上、和光純薬工業（株）製）、サフラワー油（MP Biomedicals社製）を用い、（Ｂ）成分のアクリル酸・メタクリル酸アルキルコポリマーとして、ペムレンＴＲ−２（Noveon Inc.社製）を用い、（Ｃ）成分の界面活性剤として、エマルゲン４２０（ＨＬＢ１４）、レオドールＴＷ−Ｏ３２０Ｖ（ＨＬＢ１１）、エマノーン４１１０（ＨＬＢ１２）、レオドールＳＰ−Ｐ１０（ＨＬＢ７）、レオドールＴＷ−Ｏ１２０Ｖ（ＨＬＢ１５）（以上、花王（株）製）を用いた。各実施例及び比較例におけるつや出し剤の作製手順は次の通りである。
[Examples 1 to 10 and Comparative Examples 1 to 5]
Polishing agents having the compositions shown in Table 1 below were prepared, and these were used as samples for Examples and Comparative Examples. In each of the examples and comparative examples, as the natural fat / oil of component (A), high oleic sunflower oil (manufactured by Yokoseki Oil & Fat Co., Ltd.), olive oil, soybean oil, linseed oil (above, manufactured by Wako Pure Chemical Industries, Ltd.) ), Safflower oil (manufactured by MP Biomedicals), and (B) component, acrylic acid / alkyl methacrylate copolymer, Pemlen TR-2 (manufactured by Noveon Inc.), (C) component surfactant Emulgen 420 (HLB14), Rheodor TW-O320V (HLB11), Emanon 4110 (HLB12), Rhedol SP-P10 (HLB7), Rheodor TW-O120V (HLB15) (above, manufactured by Kao Corporation) were used. The procedure for producing the polish in each example and comparative example is as follows.
（実施例１〜５におけるつや出し剤の作製手順）
下記表１に示す割合で、８０℃に加熱したイオン交換水に（Ｂ）成分をプロペラ等で攪拌して分散させる。均一に分散後、（Ｃ）成分及び陽イオン性界面活性剤を加えてさらに攪拌し、ｐＨ調整剤を加えて所定のｐＨに調整する。残りのイオン交換水、及び（Ａ）成分を加えて、ホモミキサー（10000rpm）で攪拌後、室温まで冷却してつや出し剤を得る。
(Procedure for producing polishing agent in Examples 1 to 5)
In the ratio shown in Table 1 below, the component (B) is dispersed in ion-exchanged water heated to 80 ° C. with a propeller or the like. After uniformly dispersing, the component (C) and a cationic surfactant are added and further stirred, and a pH adjuster is added to adjust to a predetermined pH. The remaining ion-exchanged water and the component (A) are added and stirred with a homomixer (10000 rpm), and then cooled to room temperature to obtain a polish.
（実施例６〜１０におけるつや出し剤の作製手順）
下記表１に示す割合で、８０℃に加熱したイオン交換水に（Ｂ）成分をプロペラ等で攪拌して分散させる。均一に分散後、（Ｃ）成分を加えてさらに攪拌し、ｐＨ調整剤を加えて所定のｐＨに調整する。残りのイオン交換水、及び（Ａ）成分を加えて、ホモミキサー（10000rpm）で攪拌後、室温まで冷却してつや出し剤を得る。
(Procedure for producing polishing agent in Examples 6 to 10)
In the ratio shown in Table 1 below, the component (B) is dispersed in ion-exchanged water heated to 80 ° C. with a propeller or the like. After uniformly dispersing, the component (C) is added and further stirred, and a pH adjuster is added to adjust to a predetermined pH. The remaining ion-exchanged water and the component (A) are added and stirred with a homomixer (10000 rpm), and then cooled to room temperature to obtain a polish.
（比較例１におけるつや出し剤の作製手順）
下記表１に示す割合で、８０℃に加熱したイオン交換水に（Ｂ）成分をプロペラ等で攪拌して分散させる。均一に分散後、（Ｃ）成分を加えてさらに攪拌し、ｐＨ調整剤を加えて所定のｐＨに調整する。残りのイオン交換水を加えて更に攪拌し、室温まで冷却してつや出し剤を得る。
(Procedure for producing a polishing agent in Comparative Example 1)
In the ratio shown in Table 1 below, the component (B) is dispersed in ion-exchanged water heated to 80 ° C. with a propeller or the like. After uniformly dispersing, the component (C) is added and further stirred, and a pH adjuster is added to adjust to a predetermined pH. The remaining ion exchange water is added and further stirred, and cooled to room temperature to obtain a polish.
（比較例２におけるつや出し剤の作製手順）
下記表１に示す割合で、８０℃に加熱したイオン交換水に（Ｃ）成分を加えて攪拌し、残りのイオン交換水、及び（Ａ）成分を加えて、ホモミキサー（10000rpm）で攪拌後、室温まで冷却してつや出し剤を得る。
(Procedure for producing a polishing agent in Comparative Example 2)
Add the component (C) to the ion-exchanged water heated to 80 ° C. and stir the mixture at the ratio shown in Table 1 below, add the remaining ion-exchanged water and the component (A), and stir with a homomixer (10000 rpm). Cool to room temperature to obtain a polish.
（比較例３におけるつや出し剤の作製手順）
下記表１に示す割合で、８０℃に加熱したイオン交換水に（Ｂ）成分をプロペラ等で攪拌して分散させる。均一に分散後、ｐＨ調整剤を加えて所定のｐＨに調整する。残りのイオン交換水、及び（Ａ）成分を加えて、ホモミキサー（10000rpm）で攪拌後、室温まで冷却してつや出し剤を得る。
(Procedure for producing a polishing agent in Comparative Example 3)
In the ratio shown in Table 1 below, the component (B) is dispersed in ion-exchanged water heated to 80 ° C. with a propeller or the like. After uniformly dispersing, a pH adjuster is added to adjust to a predetermined pH. The remaining ion-exchanged water and the component (A) are added and stirred with a homomixer (10000 rpm), and then cooled to room temperature to obtain a polish.
（比較例４〜５におけるつや出し剤の作製手順）
下記表１に示す割合で、８０℃に加熱したイオン交換水に（Ｂ）成分をプロペラ等で攪拌して分散させる。均一に分散後、（Ｃ）成分を加えてさらに攪拌し、ｐＨ調整剤を加えて所定のｐＨに調整する。残りのイオン交換水、及び（Ａ）成分を加えて、ホモミキサー（10000rpm）で攪拌後、室温まで冷却してつや出し剤を得る。
(Procedure for producing a polishing agent in Comparative Examples 4 to 5)
In the ratio shown in Table 1 below, the component (B) is dispersed in ion-exchanged water heated to 80 ° C. with a propeller or the like. After uniformly dispersing, the component (C) is added and further stirred, and a pH adjuster is added to adjust to a predetermined pH. The remaining ion-exchanged water and the component (A) are added and stirred with a homomixer (10000 rpm), and then cooled to room temperature to obtain a polish.
また、上記のようにして得られたつや出し剤を用いて次の手順で清掃シートを作製し、これらを実施例及び比較例の清掃シートのサンプルとした。
芯がポリプロピレンからなり鞘がポリエチレンからなる芯鞘構造で、立体クリンプ形状をもつ低融点繊維（２．８ｄｔｅｘ×５１ｍｍ）を用いて坪量２７ｇ／ｍ２のエアースルー不織布を作製した。一方、レーヨン繊維（１．７ｄｔｅｘ×４０ｍｍ）と、アクリル繊維（１．０ｄｔｅｘ×５１ｍｍ）と、芯がポリプロピレンからなり鞘がポリエチレンからなる芯鞘繊維（１．０ｄｔｅｘ×３８ｍｍ）とを重量比５０／２５／２５の比率で混合し、常法のカード機で作製した坪量１９ｇ／ｍ2の繊維ウエブを、前記エアースルー不織布の上下に積層した。次いで低エネルギー条件でウォーターニードリング処理を施し、エアースルー不織布と繊維ウエブとを交絡させて繊維自由度の高い表面層を有する坪量６５ｇ／ｍ2の複合スパンレースを不織布を調整した。超音波エンボス機を用い、得られた不織布の全面にダイヤ柄の凹凸模様からなるエンボス加工を施して清掃シートを得た。
得られた清掃シートに前記つや出し剤を清掃シート重量に対して２５０重量％含浸させた。
Moreover, the cleaning sheet was produced in the following procedure using the polishing agent obtained as described above, and these were used as the cleaning sheet samples of Examples and Comparative Examples.
An air-through nonwoven fabric having a basis weight of 27 g / m 2 was produced using a low melting point fiber (2.8 dtex × 51 mm) having a core-sheath structure in which the core is made of polypropylene and the sheath is made of polyethylene and has a three-dimensional crimp shape. On the other hand, a rayon fiber (1.7 dtex × 40 mm), an acrylic fiber (1.0 dtex × 51 mm), and a core-sheath fiber (1.0 dtex × 38 mm) whose core is made of polypropylene and whose sheath is made of polyethylene are weight ratio 50 / A fiber web having a basis weight of 19 g / m 2 mixed at a ratio of 25/25 and produced by a conventional card machine was laminated on the top and bottom of the air-through nonwoven fabric. Next, a water needling treatment was performed under low energy conditions, and an air-through nonwoven fabric and a fiber web were entangled to prepare a nonwoven fabric of a composite spunlace having a basis weight of 65 g / m 2 having a surface layer with a high degree of freedom of fibers. Using an ultrasonic embossing machine, the entire surface of the obtained non-woven fabric was embossed with a diamond pattern uneven pattern to obtain a cleaning sheet.
The resulting cleaning sheet was impregnated with 250% by weight of the polishing agent with respect to the weight of the cleaning sheet.
〔評価〕
実施例及び比較例のつや出し剤について、上述したブルックフィールド粘度（２５℃）及び液温２５℃でのｐＨを測定し、下記方法により乳化状態、液安定性、光沢付与性及び表面外観をそれぞれ評価した。また、実施例及び比較例の清掃シートについて、下記方法により清掃性能を評価した。これらの結果を下記表１に示す。
[Evaluation]
For the polishes of Examples and Comparative Examples, the Brookfield viscosity (25 ° C.) and the pH at a liquid temperature of 25 ° C. are measured, and the emulsified state, liquid stability, gloss imparting property and surface appearance are evaluated by the following methods. did. Moreover, about the cleaning sheet of the Example and the comparative example, the cleaning performance was evaluated by the following method. These results are shown in Table 1 below.
＜乳化状態の評価方法＞
調製直後（調製してから６時間以内）のつや出し剤をスライドガラス上に適量のせ、デジタルマイクロスコープ（ＫＥＹＥＮＣＥ社製 ＶＨＸ−５００）で乳化した油滴粒子の状態を観察し、下記の基準で評価した。下記の基準において、△は、○には劣るものの、実用に堪えうるレベルである。
○：油滴粒子径が５μｍ以下で均一である
△：油滴粒子径が５μｍ以下であるが粒子径の均一性にやや劣る
×：油滴粒子径が５μｍより大きいものが含まれる
<Evaluation method of emulsified state>
Immediately after preparation (within 6 hours after preparation), apply an appropriate amount of a polish on a slide glass, observe the state of oil droplet particles emulsified with a digital microscope (VHX-500 manufactured by KEYENCE), and evaluate according to the following criteria: did. In the following criteria, Δ is a level that can be practically used although it is inferior to ○.
○: Oil droplet particle size is uniform at 5 μm or less Δ: Oil droplet particle size is 5 μm or less but slightly inferior in particle size uniformity ×: Oil droplet particle size larger than 5 μm is included
＜液安定性の評価方法＞
つや出し剤を１００ｍｌ入りガラス瓶に充填し、室温（２５℃）で静置保存した。静置保存開始から４日後及び７日後それぞれの時点におけるつや出し剤の状態を目視観察し、下記の基準で評価した。下記の基準において、△は、○には劣るものの、実用に堪えうるレベルである。
○：分離が認められない
△：分離がやや認められるが攪拌で容易に元に戻る（分離が解消される）
×：分離が認められる（攪拌しても分離が解消されない）
<Method for evaluating liquid stability>
A 100 ml glass bottle was filled with the polish and stored at room temperature (25 ° C.). The state of the polishing agent at each time point after 4 days and 7 days from the start of stationary storage was visually observed and evaluated according to the following criteria. In the following criteria, Δ is a level that can be practically used although it is inferior to ○.
○: Separation is not observed △: Separation is slightly recognized, but can be easily restored by stirring (separation is eliminated)
X: Separation is observed (separation is not eliminated even with stirring)
＜光沢付与性の評価方法＞
ＭＩＮＯＬＴＡ社製光沢度計Ｍｕｌｉｔ Ｇｌｏｓｓ２６８を用い、入射角と受光角をそれぞれ６０°に設定して、松下電工製フローリングウッディスーパーＦに対してつや出し剤をｗｅｔ塗布量３〜４ｇ／ｍ2で塗布し、塗布前と塗布後との光沢差（Δ光沢度）を
求めた。この光沢差が大きいほど、光沢付与性は高評価となる。
<Glossiness evaluation method>
Using a gloss meter Multi Gloss 268 manufactured by MINOLTA, the incident angle and the light receiving angle are each set to 60 °, and a polish is applied to the flooring woody super F made by Matsushita Electric Works at a wet coating amount of 3 to 4 g / m 2. The gloss difference (Δ glossiness) before and after coating was determined. The greater the difference in gloss, the higher the gloss impartability.
＜表面外観（目視光沢性）の評価方法＞
前記＜光沢付与性の評価方法＞において光沢差がΔ５以上であったもの（つや出し効果
が得られたもの）のみについて、つや出し剤を塗布してから５分後の塗布面の外観を目視観察し、以下の基準で評価した。
◎：塗布面全体が光沢を発現しているのが容易に判る
○：塗布面全体が光沢を発現しているのが判る
△：塗布面の一部が光沢を発現しているのが判る
×：塗布面が光沢を発現しない
<Method for evaluating surface appearance (visual glossiness)>
For only those having a gloss difference of Δ5 or more in the above <Glossiness Evaluation Method> (those with a gloss effect), the appearance of the coated surface after 5 minutes from the application of the polish was visually observed. The evaluation was based on the following criteria.
◎: It can be easily seen that the entire coated surface is glossy. ○: It can be seen that the entire coated surface is glossy. △: It can be seen that a part of the coated surface is glossy. : The coated surface does not exhibit gloss
＜清掃性能の評価方法＞
市販の床用清掃具（商品名クイックルワイパー、花王（株）製）に清掃シートを装着した。１００ｃｍ×１００ｃｍフローリング（松下電工製 ウッディタイルＭＴ６１３Ｔ）上にＪＩＳ試験用ダスト７種（関東ローム層、細粒）を０．１ｇ散布（刷毛を用いて均一に散布）し、フローリングを１往復で４列清掃した。この操作を６回繰り返した後、汚れた清掃シートを乾燥させて重量（清掃シートとつや出し剤由来の不揮発成分とダストとの合計重量）を測定し、この測定重量から、含浸前に測定した清掃シートの重量と理論上残留するつや出し剤由来の不揮発成分の重量とを差し引いて、ダストの捕集量を算出した。捕集されたダストの重量を、散布した全ダスト重量（０．６ｇ＝０．１ｇ×６回）で除し、これに１００を乗じてその値をダストの捕集率（％）とし、以下の基準で評価した。
○：捕集率８０％以上（ダストの残留が目視では判らず、清浄な状態）
△：捕集率５０〜７９％（ダストが清掃面の一部に残留している状態）
×：捕集率５０％未満（ダストが清掃面全体に残留している状態）
<Evaluation method for cleaning performance>
A cleaning sheet was attached to a commercially available floor cleaning tool (trade name: Quickle Wiper, manufactured by Kao Corporation). Disperse 0.1g of JIS test dust (Kanto loam layer, fine particles) 0.1g on a 100cm x 100cm flooring (Matsushita Electric Works Woody Tile MT613T) (spray uniformly with a brush). The column was cleaned. After repeating this operation 6 times, the dirty cleaning sheet is dried and the weight (total weight of the cleaning sheet, the non-volatile component derived from the polish and the dust) is measured, and the cleaning measured before impregnation from this measured weight The amount of dust collected was calculated by subtracting the weight of the sheet and the theoretically remaining weight of the non-volatile component derived from the polish. The collected dust weight is divided by the total dust weight (0.6 g = 0.1 g × 6 times), and multiplied by 100 to obtain the dust collection rate (%). Evaluation based on the criteria.
○: Collection rate of 80% or more (the residue of dust is not visually recognized and is in a clean state)
(Triangle | delta): The collection rate 50-79% (The state in which dust remains in a part of cleaning surface)
X: Collection rate less than 50% (Dust remaining on the entire cleaning surface)
表１の記載から明らかなように、実施例１〜１０は、つや出し剤安定性と光沢性能に優れたものであった。
これに対し、比較例１は、（Ａ）成分の天然油脂が配合されていないため、光沢付与性が劣るものであった。
また、比較例２は、（Ｂ）成分のアクリル酸・メタクリル酸アルキルコポリマーが配合されていないため、つや出し剤の液安定性及び光沢付与性がやや劣るものであった。
また、比較例３は、（Ｃ）成分の界面活性剤が配合されていないため、つや出し剤の液安定性及び光沢付与性が劣るものであった。
また、比較例４は、つや出し剤の液安定性は良好であるものの、（Ｃ）成分の界面活性剤のＨＬＢが７であるため、光沢付与性が劣るものであった。
また、比較例５は、（Ｃ）成分の界面活性剤のＨＬＢが１５であるため、つや出し剤の液安定性及び光沢付与性が劣るものであった。
As is apparent from the description in Table 1, Examples 1 to 10 were excellent in the stability of the polish and the gloss performance.
On the other hand, since the natural fats and oils of (A) component were not mix | blended, the comparative example 1 was inferior in glossiness imparting property.
In Comparative Example 2, the acrylic acid / alkyl methacrylate copolymer (B) was not blended, so that the liquid stability and glossiness of the polish were slightly inferior.
Moreover, since the surfactant of (C) component was not mix | blended with the comparative example 3, the liquid stability and glossiness imparting property of a polish were inferior.
Further, in Comparative Example 4, although the gloss stability of the polish was good, the gloss imparting property was inferior because the HLB of the component (C) surfactant was 7.
In Comparative Example 5, since the HLB of the component (C) surfactant was 15, the liquid stability and gloss imparting property of the polish were inferior.
Claims (4)
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| JP5260210B2 (en) * | 2008-09-24 | 2013-08-14 | 花王株式会社 | Polishing detergent composition for floor |
| JP5988717B2 (en) * | 2012-06-11 | 2016-09-07 | 花王株式会社 | Wet sheet for hard surface |
| JP2013256567A (en) * | 2012-06-11 | 2013-12-26 | Kao Corp | Detergent |
| TWI616175B (en) * | 2012-06-11 | 2018-03-01 | 花王股份有限公司 | Wet sheet for hard surface |
| WO2023210498A1 (en) * | 2022-04-27 | 2023-11-02 | 花王株式会社 | Wiping sheet |
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| JPS5739825A (en) * | 1980-08-22 | 1982-03-05 | Duskin Franchise Co | Dust control product having longlasting dust adsorbing property |
| JPH10338619A (en) * | 1997-06-06 | 1998-12-22 | Pola Chem Ind Inc | Transparent cosmetic |
| JP4049414B2 (en) * | 1997-06-26 | 2008-02-20 | ポーラ化成工業株式会社 | Emulsified composition |
| JP2000001418A (en) * | 1998-06-12 | 2000-01-07 | Pola Chem Ind Inc | Non-oil cleaning gel composition |
| JP4791626B2 (en) * | 1999-11-05 | 2011-10-12 | 株式会社セラリカ野田 | Surface treatment agent for wood |
| JP3664981B2 (en) * | 2000-01-21 | 2005-06-29 | 花王株式会社 | Floor cleaning sheet |
| US6749673B2 (en) * | 2002-11-08 | 2004-06-15 | S. C. Johnson & Son, Inc. | Biliquid foam furniture polish |
| JP4688455B2 (en) * | 2004-09-09 | 2011-05-25 | ユニ・チャーム株式会社 | Cleaning tool |
| JP5342736B2 (en) * | 2005-04-06 | 2013-11-13 | 花王株式会社 | Oil-in-water emulsion and method for producing the same |
| JP4698319B2 (en) * | 2005-07-25 | 2011-06-08 | 旭化成ケミカルズ株式会社 | Wet wiper |
| JP4827509B2 (en) * | 2005-12-05 | 2011-11-30 | 花王株式会社 | Bulky sheet |
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