JP5192495B2 - 飽和および不飽和アルデヒドの不飽和カルボン酸への酸化のための触媒、およびその製造方法と使用方法 - Google Patents
飽和および不飽和アルデヒドの不飽和カルボン酸への酸化のための触媒、およびその製造方法と使用方法 Download PDFInfo
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- JP5192495B2 JP5192495B2 JP2009549085A JP2009549085A JP5192495B2 JP 5192495 B2 JP5192495 B2 JP 5192495B2 JP 2009549085 A JP2009549085 A JP 2009549085A JP 2009549085 A JP2009549085 A JP 2009549085A JP 5192495 B2 JP5192495 B2 JP 5192495B2
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- catalyst
- compound
- binder
- heteropolyacid
- heteropolyacid compound
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
- B01J27/198—Vanadium
- B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/612—Surface area less than 10 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
- C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0036—Grinding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/04—Mixing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/702,395 US8178718B2 (en) | 2007-02-05 | 2007-02-05 | Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof |
| US11/702,395 | 2007-02-05 | ||
| PCT/US2008/001461 WO2008097516A1 (en) | 2007-02-05 | 2008-02-04 | Catalyst for oxidation of saturated and unsaturated aldehydes to unasturated carboxylic acid, method of marking and method of using thereof |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010517761A JP2010517761A (ja) | 2010-05-27 |
| JP2010517761A5 JP2010517761A5 (enExample) | 2011-03-24 |
| JP5192495B2 true JP5192495B2 (ja) | 2013-05-08 |
Family
ID=39676744
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009549085A Expired - Fee Related JP5192495B2 (ja) | 2007-02-05 | 2008-02-04 | 飽和および不飽和アルデヒドの不飽和カルボン酸への酸化のための触媒、およびその製造方法と使用方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US8178718B2 (enExample) |
| EP (1) | EP2117706A4 (enExample) |
| JP (1) | JP5192495B2 (enExample) |
| KR (2) | KR101579702B1 (enExample) |
| CN (2) | CN104437638A (enExample) |
| WO (1) | WO2008097516A1 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SG172273A1 (en) * | 2008-12-26 | 2011-07-28 | Nippon Catalytic Chem Ind | Process for producing acrylic acid |
| US8481448B2 (en) | 2010-07-19 | 2013-07-09 | Saudi Basic Industries Corporation | Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof |
| CN102652922B (zh) * | 2012-03-23 | 2013-09-04 | 太原理工大学 | 一种负载型磷钒铯镧催化剂及其应用 |
| CA2901968C (en) * | 2013-04-08 | 2019-11-12 | Saudi Basic Industries Corporation | Catalyst for conversion of propylene to product comprising a carboxylic acid moiety |
| CN103801398A (zh) * | 2014-01-02 | 2014-05-21 | 上海东化催化剂有限公司 | 用于制取甲基丙烯酸的催化剂的制备方法 |
| US9115067B1 (en) | 2014-12-22 | 2015-08-25 | Novus International, Inc. | Process for the manufacture of acrolein |
| WO2016147324A1 (ja) * | 2015-03-17 | 2016-09-22 | 日本化薬株式会社 | 不飽和アルデヒドおよび/または不飽和カルボン酸製造用触媒およびその製造方法ならびに不飽和アルデヒドおよび/または不飽和カルボン酸の製造方法 |
| KR20180055154A (ko) * | 2016-11-16 | 2018-05-25 | 주식회사 엘지화학 | 촉매의 제조 방법 |
| EP3348551A1 (en) * | 2017-01-16 | 2018-07-18 | Basf Se | Process for preparing an organic heterocyclic compound |
| CN110142063B (zh) * | 2018-02-11 | 2021-12-17 | 中国科学院大连化学物理研究所 | 用于异丁烷选择氧化制甲基丙烯酸催化剂及其制备方法 |
| CN112058281B (zh) * | 2020-05-14 | 2023-02-17 | 哈尔滨理工大学 | 锗钼多酸钴配合物衍生的双金属硫化物晶体的制备和应用 |
| EP3945086B1 (de) * | 2020-07-30 | 2022-10-26 | Röhm GmbH | C-4 basiertes verfahren zur herstellung von mma unter rückführung und recyclierung von methacrolein |
| US12106791B2 (en) * | 2022-06-30 | 2024-10-01 | Western Digital Technologies, Inc. | Doped BiSb (012) or undoped BiSb (001) topological insulator with GeNiFe buffer layer and/or interlayer for SOT based sensor, memory, and storage devices |
| CN116510742B (zh) * | 2023-04-06 | 2024-08-23 | 济南大学 | 一种钼钒氧簇修饰的碳基锰酸铁复合催化剂的制备方法及其应用 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE789241A (fr) * | 1971-09-28 | 1973-03-26 | Halcon International Inc | Catalyseur pour l'oxydation d'aldéhydes non saturés |
| US3998876A (en) * | 1973-08-16 | 1976-12-21 | Mitsubishi Rayon Co., Ltd. | Catalytic process for preparation of unsaturated carboxylic acids |
| US3939096A (en) * | 1974-09-24 | 1976-02-17 | Celanese Corporation | Supported catalyst for acrolein oxidation |
| US3962322A (en) * | 1974-09-25 | 1976-06-08 | Celanese Corporation | Process for unsaturated aldehyde oxidation using a supported catalyst |
| YU41495B (en) * | 1979-01-23 | 1987-08-31 | Nippon Kayaku Kk | Process for obtaining methacrolein and methacrylic acid |
| JPS5637050A (en) | 1979-09-04 | 1981-04-10 | Ube Ind Ltd | Preparation of catalyst for preparing unsaturated acid |
| US4347163A (en) * | 1980-10-03 | 1982-08-31 | Standard Oil Company | Te-containing methacrolein oxidation catalysts and their use |
| US4358610A (en) | 1981-03-02 | 1982-11-09 | The Standard Oil Company | Process for the production of methacrylic acid from isobutyraldehyde |
| DE3145091A1 (de) * | 1981-11-13 | 1983-05-19 | Röhm GmbH, 6100 Darmstadt | Verfahren zur herstellung von methacrylsaeure |
| US4558029A (en) * | 1982-09-13 | 1985-12-10 | The Standard Oil Company | Antimony-containing C4 oxidation catalysts |
| US4760153A (en) * | 1985-03-26 | 1988-07-26 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Process for producing maleic anhydride |
| DE3721865A1 (de) * | 1987-07-02 | 1989-01-12 | Basf Ag | Verfahren zur herstellung von methacrylsaeure |
| US5191116A (en) * | 1989-05-22 | 1993-03-02 | Asahi Kasei Kogyo Kabushiki Kaisha | Process for the preparation of methacrylic acid and methacrolein |
| JP2994706B2 (ja) * | 1990-08-06 | 1999-12-27 | 株式会社日本触媒 | メタクリル酸製造用触媒および該触媒を用いたメタクリル酸の製造方法 |
| DE4240085A1 (de) * | 1992-11-28 | 1994-06-01 | Roehm Gmbh | Katalytische Oxidation von Isobutan zu Methacrylsäure und Methacrolein |
| DE19533484A1 (de) * | 1995-09-12 | 1997-03-13 | Basf Ag | Monomodale und polymodale Katalysatorträger und Katalysatoren mit engen Porengrößenverteilungen und deren Herstellverfahren |
| JP2000024502A (ja) * | 1997-09-25 | 2000-01-25 | Mitsui Chemicals Inc | メタクリル酸製造用触媒およびその製造方法 |
| US6172245B1 (en) * | 1999-12-16 | 2001-01-09 | Eastman Chemical Company | Gas phase process for the epoxidation of non-allylic olefins |
| US6946422B2 (en) * | 2002-12-12 | 2005-09-20 | Saudi Basic Industries Corporation | Preparation of mixed metal oxide catalysts for catalytic oxidation of olefins to unsaturated aldehydes |
| JP4421558B2 (ja) * | 2003-05-30 | 2010-02-24 | 日本化薬株式会社 | メタクリル酸製造用触媒の製造方法 |
| JP4424180B2 (ja) * | 2003-12-03 | 2010-03-03 | 三菱化学株式会社 | 不飽和アルデヒド及び不飽和カルボン酸製造用触媒の製造方法 |
| JP4756890B2 (ja) | 2005-03-29 | 2011-08-24 | 日本化薬株式会社 | メタクリル酸製造用触媒及びその製造方法 |
| US7649112B2 (en) * | 2005-07-25 | 2010-01-19 | Saudi Basic Industries Corporation | Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon |
| US7649111B2 (en) * | 2005-07-25 | 2010-01-19 | Saudi Basic Industries Corporation | Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same |
| US20050259658A1 (en) * | 2005-08-06 | 2005-11-24 | Logan James D | Mail, package and message delivery using virtual addressing |
-
2007
- 2007-02-05 US US11/702,395 patent/US8178718B2/en active Active
-
2008
- 2008-02-04 KR KR1020147035671A patent/KR101579702B1/ko not_active Expired - Fee Related
- 2008-02-04 CN CN201410616173.6A patent/CN104437638A/zh active Pending
- 2008-02-04 CN CNA2008800040459A patent/CN101610841A/zh active Pending
- 2008-02-04 WO PCT/US2008/001461 patent/WO2008097516A1/en not_active Ceased
- 2008-02-04 JP JP2009549085A patent/JP5192495B2/ja not_active Expired - Fee Related
- 2008-02-04 KR KR1020097018453A patent/KR20090108121A/ko not_active Withdrawn
- 2008-02-04 EP EP08725138A patent/EP2117706A4/en not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| US8178718B2 (en) | 2012-05-15 |
| CN104437638A (zh) | 2015-03-25 |
| KR20090108121A (ko) | 2009-10-14 |
| US20080188681A1 (en) | 2008-08-07 |
| JP2010517761A (ja) | 2010-05-27 |
| WO2008097516A1 (en) | 2008-08-14 |
| EP2117706A1 (en) | 2009-11-18 |
| CN101610841A (zh) | 2009-12-23 |
| KR101579702B1 (ko) | 2015-12-23 |
| KR20150011391A (ko) | 2015-01-30 |
| EP2117706A4 (en) | 2011-10-26 |
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