JP5113321B2 - 有被膜錯体凝集体の製造方法 - Google Patents
有被膜錯体凝集体の製造方法 Download PDFInfo
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- JP5113321B2 JP5113321B2 JP2005031729A JP2005031729A JP5113321B2 JP 5113321 B2 JP5113321 B2 JP 5113321B2 JP 2005031729 A JP2005031729 A JP 2005031729A JP 2005031729 A JP2005031729 A JP 2005031729A JP 5113321 B2 JP5113321 B2 JP 5113321B2
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Description
金属―有機骨格構造体からなる錯体を有機溶媒中で合成する工程と、
水素ガス分子が透過可能な水素透過性バインダを前記有機溶媒に添加し、前記水素透過性バインダで前記錯体を被覆して有被膜錯体を形成する工程と、
前記有被膜錯体と前記有機溶媒とを分離するとともに、前記水素透過性バインダを介して前記有被膜錯体同士を結合させて凝集体を得る工程と、
を有することを特徴とする。
20…沈殿物層 30…円筒型高圧容器
32…ディスク状成形体 42、62…真空ポンプ
44、50…配管 52…供給ライン
54…排出ライン 56…水素ガスボンベ
Claims (4)
- 錯体が被膜で被覆された有被膜錯体を凝集させて凝集体とすることで得られ、水素吸着材として機能する有被膜錯体凝集体の製造方法であって、
水素ガスを吸着可能な金属―有機骨格構造体からなる錯体を有機溶媒中で合成する工程と、
水素ガス分子が透過可能な水素透過性バインダを前記有機溶媒に添加し、前記水素透過性バインダで前記錯体を被覆して有被膜錯体を形成する工程と、
前記有被膜錯体と前記有機溶媒とを分離するとともに、前記水素透過性バインダを介して前記有被膜錯体同士を結合させて凝集体を得る工程と、
を有することを特徴とする有被膜錯体凝集体の製造方法。 - 請求項1記載の製造方法において、前記水素透過性バインダの添加量を、前記錯体1gに対して0.1〜0.3gとすることを特徴とする有被膜錯体凝集体の製造方法。
- 請求項1又は2記載の製造方法において、前記水素透過性バインダとして、ポリビニルピロリドン、ポリイミド、ポリスルホンからなる被膜を設けることを特徴とする有被膜錯体凝集体の製造方法。
- 請求項1〜3のいずれか1項に記載の製造方法において、前記凝集体として成形体を設けることを特徴とする有被膜錯体凝集体の製造方法。
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JP2005031729A JP5113321B2 (ja) | 2005-02-08 | 2005-02-08 | 有被膜錯体凝集体の製造方法 |
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JP2005031729A JP5113321B2 (ja) | 2005-02-08 | 2005-02-08 | 有被膜錯体凝集体の製造方法 |
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JP2006218349A JP2006218349A (ja) | 2006-08-24 |
JP5113321B2 true JP5113321B2 (ja) | 2013-01-09 |
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JP2005031729A Expired - Fee Related JP5113321B2 (ja) | 2005-02-08 | 2005-02-08 | 有被膜錯体凝集体の製造方法 |
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Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101641152B (zh) * | 2007-01-24 | 2014-04-23 | 加利福尼亚大学董事会 | 结晶的3d-和2d-共价有机构架 |
JP5759175B2 (ja) | 2008-09-29 | 2015-08-05 | 日本碍子株式会社 | ガス吸着材料、その前駆体及びガス吸着材料の製造方法 |
CN116036798B (zh) * | 2021-10-28 | 2024-08-02 | 中国石油化工股份有限公司 | 一种分离氢气混合气体的方法及系统和应用 |
Family Cites Families (8)
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US5648508A (en) * | 1995-11-22 | 1997-07-15 | Nalco Chemical Company | Crystalline metal-organic microporous materials |
JPH11116958A (ja) * | 1997-10-14 | 1999-04-27 | Mitsui Chem Inc | ポリアミノ酸を含有する顆粒の製造方法 |
JPH11128739A (ja) * | 1997-10-23 | 1999-05-18 | Elf Atochem Japan Kk | 吸着性ハニカム構造体と、その製造方法 |
JP2000210559A (ja) * | 1999-01-22 | 2000-08-02 | Osaka Gas Co Ltd | ガス貯蔵性有機金属錯体、その製造方法およびガス貯蔵装置 |
US6893564B2 (en) * | 2002-05-30 | 2005-05-17 | Basf Aktiengesellschaft | Shaped bodies containing metal-organic frameworks |
US7481866B2 (en) * | 2002-06-19 | 2009-01-27 | University Of Iowa Research Foundation | Gas storage materials and devices |
EP1633760B1 (en) * | 2003-05-09 | 2010-05-05 | The Regents of The University of Michigan | MOFs with a high surface area and methods for producing them |
US7309380B2 (en) * | 2003-06-30 | 2007-12-18 | Basf Aktiengesellschaft | Gas storage system |
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