JP5109053B2 - 水素ガスの製造方法および製造装置 - Google Patents
水素ガスの製造方法および製造装置 Download PDFInfo
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- JP5109053B2 JP5109053B2 JP2008153527A JP2008153527A JP5109053B2 JP 5109053 B2 JP5109053 B2 JP 5109053B2 JP 2008153527 A JP2008153527 A JP 2008153527A JP 2008153527 A JP2008153527 A JP 2008153527A JP 5109053 B2 JP5109053 B2 JP 5109053B2
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- gas
- hydrogen gas
- hydrogen
- water
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 258
- 238000000034 method Methods 0.000 title description 26
- 238000006243 chemical reaction Methods 0.000 claims description 160
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 118
- 229910001868 water Inorganic materials 0.000 claims description 115
- 239000007789 gas Substances 0.000 claims description 114
- 238000003860 storage Methods 0.000 claims description 83
- 239000001257 hydrogen Substances 0.000 claims description 63
- 229910052739 hydrogen Inorganic materials 0.000 claims description 63
- 239000002245 particle Substances 0.000 claims description 50
- 239000007787 solid Substances 0.000 claims description 50
- 239000011777 magnesium Substances 0.000 claims description 49
- 229910052783 alkali metal Inorganic materials 0.000 claims description 48
- 150000001340 alkali metals Chemical class 0.000 claims description 48
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 48
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 48
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 47
- 229910052749 magnesium Inorganic materials 0.000 claims description 47
- 238000004519 manufacturing process Methods 0.000 claims description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 83
- 239000011261 inert gas Substances 0.000 description 75
- 229910001873 dinitrogen Inorganic materials 0.000 description 71
- 238000001816 cooling Methods 0.000 description 18
- 229910045601 alloy Inorganic materials 0.000 description 15
- 239000000956 alloy Substances 0.000 description 15
- 238000010438 heat treatment Methods 0.000 description 14
- 239000012528 membrane Substances 0.000 description 11
- 239000012510 hollow fiber Substances 0.000 description 9
- 238000000926 separation method Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 6
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 229910002091 carbon monoxide Inorganic materials 0.000 description 6
- 229910001882 dioxygen Inorganic materials 0.000 description 6
- 238000007599 discharging Methods 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 239000002699 waste material Substances 0.000 description 6
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 239000000571 coke Substances 0.000 description 4
- 238000005868 electrolysis reaction Methods 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000004071 soot Substances 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- -1 and at the same time Chemical compound 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229910052792 caesium Inorganic materials 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000012466 permeate Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 229910052701 rubidium Inorganic materials 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052743 krypton Inorganic materials 0.000 description 1
- DNNSSWSSYDEUBZ-UHFFFAOYSA-N krypton atom Chemical compound [Kr] DNNSSWSSYDEUBZ-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052754 neon Inorganic materials 0.000 description 1
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 1
- 229910001120 nichrome Inorganic materials 0.000 description 1
- 229920005597 polymer membrane Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229910052705 radium Inorganic materials 0.000 description 1
- 229910052704 radon Inorganic materials 0.000 description 1
- SYUHGPGVQRZVTB-UHFFFAOYSA-N radon atom Chemical compound [Rn] SYUHGPGVQRZVTB-UHFFFAOYSA-N 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P90/00—Enabling technologies with a potential contribution to greenhouse gas [GHG] emissions mitigation
- Y02P90/45—Hydrogen technologies in production processes
Landscapes
- Filling Or Discharging Of Gas Storage Vessels (AREA)
- Hydrogen, Water And Hydrids (AREA)
Description
ここで、図1は、窒素ガスを含む不活性ガスまたは水素ガスを供給可能にした本願発明を示した図であり、図2は、本願発明の別の実施例を示した図である。
【実施例3】
図2に見られるように、実施例3が実施例1と異なる点は、実施例1では配設し構成していた不活性ガス供給装置10と、それに接続していたガス供給配管101とガス供給開閉弁201とガス供給配管102、及び窒素ガス濃度計202を構成していないことである。
10A・・・・・水素ガス供給装置
20・・・・・・固体粒子貯留装置
30A・・・・・反応タンク
30B・・・・・反応タンク
40・・・・・・給水装置
50・・・・・・加熱冷却手段
70・・・・・・水素貯蔵容器
101・・・・・ガス供給配管
102・・・・・ガス供給配管
103・・・・・高圧水素ガス配管
104・・・・・高圧水素ガス配管
105・・・・・水素ガス配管
111・・・・・固体粒子貯留配管
112・・・・・固体粒子貯留配管
113・・・・・固体粒子投入配管
114・・・・・固体粒子投入配管
115・・・・・不用滓取出配管
116・・・・・不用滓取出配管
121・・・・・気体排出配管
122・・・・・気体排出配管
131・・・・・貯水配管
132・・・・・貯水配管
133・・・・・給水配管
134・・・・・給水配管
141・・・・・水素ガス放出管
142・・・・・水素ガス放出管
201・・・・・ガス供給開閉弁
202・・・・・窒素ガス濃度計
202A・・・・水素ガス濃度計
203・・・・・圧力計
204・・・・・固体粒子投入開閉弁
205・・・・・固体粒子貯留用開閉弁
206・・・・・気体排出開閉弁
207・・・・・不用滓取出開閉弁
208・・・・・高圧水素ガス開閉弁
209・・・・・貯水開閉弁
210・・・・・給水開閉弁
211・・・・・減圧弁
212・・・・・水素ガス放出開閉弁
301・・・・・固体粒子投入口
302・・・・・不用滓取出口
303・・・・・気体排出口
304・・・・・水注入口
Claims (3)
- アルカリ金属またはアルカリ土類金属またはマグネシュウムの何れかと所定の温度の水を反応させて水素ガスを作り出すのに際し、その反応を水素ガスによって完全に満たされ密閉され外部と完全に遮断された反応タンク(30A)内で行うことで、前記反応タンク(30A)内の水素ガスの占める空間に対して、反応することで発生した水素ガスが加わることによって高圧水素ガスを作り出すことを特徴とする水素ガスの製造方法。
- 先ずアルカリ金属またはアルカリ土類金属またはマグネシュウムの何れかを送り込み、次に水素ガスを送り込むことによって内部の空気を排出して充満させ、最後に水を滴下して反応を開始させることを特徴とする請求項1に記載の水素ガスの製造方法。
- アルカリ金属またはアルカリ土類金属またはマグネシュウムの何れかと所定の温度の水を反応させて水素ガスを作り出す密閉され外部と完全に遮断された反応タンク(30A)に、水素ガスを供給することが出来る水素ガス供給装置(10A)を接続し、また水を滴下することが出来る給水装置(40)を接続し、更にアルカリ金属またはアルカリ土類金属またはマグネシュウムの何れかを落下可能に貯留した固体粒子貯留装置(20)を接続し、先ず前記固体粒子貯留装置(20)から前記反応タンク(30A)に、アルカリ金属またはアルカリ土類金属またはマグネシュウムの何れかを送り込み、次に前記水素ガス供給装置(10A)から前記反応タンク(30A)に、水素ガスを送り込むことによって内部の空気を排出して充満させ、最後に前記給水装置(40)から前記反応タンク(30A)に、水を滴下して反応を開始させ、前記反応タンク(30A)内の水素ガスの占める空間に対して、反応することで発生した水素ガスが加わることによって高圧水素ガスを作り出すことを特徴とする水素ガスの製造装置。
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JP2009274944A JP2009274944A (ja) | 2009-11-26 |
JP5109053B2 true JP5109053B2 (ja) | 2012-12-26 |
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Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2014136674A (ja) * | 2013-01-15 | 2014-07-28 | Fukuhara Co Ltd | 水素ガスの製造装置および製造方法 |
CN107010610B (zh) * | 2017-06-13 | 2023-09-19 | 王兆兵 | 一种高效节能的高纯氮化锰生产系统 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5823321B2 (ja) * | 1979-10-14 | 1983-05-14 | 鈴木 正弘 | 水素発生装置 |
JPS57188401A (en) * | 1981-05-13 | 1982-11-19 | Makoto Kameshima | Production of hydrogen by combination of sodium with water in cylinder and tank |
JPS6389401A (ja) * | 1986-10-02 | 1988-04-20 | Makoto Ogose | 水素発生装置 |
JP2003004199A (ja) * | 2001-06-19 | 2003-01-08 | Toyota Central Res & Dev Lab Inc | 水素ボンベ及び水素ガスの貯蔵方法 |
JP2003121593A (ja) * | 2001-10-11 | 2003-04-23 | Toshiba Corp | 金属ナトリウムの洗浄方法および装置 |
JP4073703B2 (ja) * | 2002-04-23 | 2008-04-09 | 本田技研工業株式会社 | 高圧容器への水素充填方法 |
JP4109942B2 (ja) * | 2002-09-19 | 2008-07-02 | 本田技研工業株式会社 | 高圧水素製造装置 |
JP4205052B2 (ja) * | 2003-12-26 | 2009-01-07 | 株式会社アイテック | 水素ガス発生装置及び水素ガス発生方法 |
JP4520331B2 (ja) * | 2005-03-04 | 2010-08-04 | シャープ株式会社 | 水素ガスの製造方法 |
JP4574487B2 (ja) * | 2005-08-08 | 2010-11-04 | 日立マクセル株式会社 | 水素の製造方法及び水素の製造装置並びに電源 |
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