JP5086100B2 - ポリヘドラルオリゴメリックシルセスキオキサンシラノールによる表面変性 - Google Patents
ポリヘドラルオリゴメリックシルセスキオキサンシラノールによる表面変性 Download PDFInfo
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- JP5086100B2 JP5086100B2 JP2007553305A JP2007553305A JP5086100B2 JP 5086100 B2 JP5086100 B2 JP 5086100B2 JP 2007553305 A JP2007553305 A JP 2007553305A JP 2007553305 A JP2007553305 A JP 2007553305A JP 5086100 B2 JP5086100 B2 JP 5086100B2
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- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 title description 13
- 230000004048 modification Effects 0.000 title description 9
- 238000012986 modification Methods 0.000 title description 9
- 238000000034 method Methods 0.000 claims description 34
- 239000000126 substance Substances 0.000 claims description 24
- 239000000945 filler Substances 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 22
- 238000000576 coating method Methods 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 19
- 229920000642 polymer Polymers 0.000 claims description 19
- 239000011248 coating agent Substances 0.000 claims description 14
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 13
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 11
- 239000011707 mineral Substances 0.000 claims description 11
- 239000002904 solvent Substances 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 238000011282 treatment Methods 0.000 claims description 8
- 230000000704 physical effect Effects 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 5
- 239000011521 glass Substances 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 238000010521 absorption reaction Methods 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims description 2
- 239000000758 substrate Substances 0.000 claims 12
- 229910021536 Zeolite Inorganic materials 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 1
- 239000007921 spray Substances 0.000 claims 1
- 229920002994 synthetic fiber Polymers 0.000 claims 1
- 239000010457 zeolite Substances 0.000 claims 1
- 239000002086 nanomaterial Substances 0.000 description 13
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 12
- 229910052901 montmorillonite Inorganic materials 0.000 description 12
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- 229910000077 silane Inorganic materials 0.000 description 10
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 9
- 229930195733 hydrocarbon Natural products 0.000 description 8
- 150000002430 hydrocarbons Chemical class 0.000 description 8
- -1 olefinic Chemical group 0.000 description 8
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- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
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- 239000003153 chemical reaction reagent Substances 0.000 description 6
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- 238000005516 engineering process Methods 0.000 description 6
- 150000004819 silanols Chemical class 0.000 description 6
- 150000004760 silicates Chemical class 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- 125000000524 functional group Chemical group 0.000 description 5
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- 239000002356 single layer Substances 0.000 description 5
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- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 description 4
- 238000007740 vapor deposition Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
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- 150000004820 halides Chemical class 0.000 description 3
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- 239000002114 nanocomposite Substances 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
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- 125000001424 substituent group Chemical group 0.000 description 3
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- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 2
- 238000001994 activation Methods 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 150000004703 alkoxides Chemical class 0.000 description 2
- RREGISFBPQOLTM-UHFFFAOYSA-N alumane;trihydrate Chemical compound O.O.O.[AlH3] RREGISFBPQOLTM-UHFFFAOYSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 229910052601 baryte Inorganic materials 0.000 description 2
- 239000010428 baryte Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
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- 230000007797 corrosion Effects 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000007613 slurry method Methods 0.000 description 2
- 150000003384 small molecules Chemical class 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 239000010455 vermiculite Substances 0.000 description 2
- 229910052902 vermiculite Inorganic materials 0.000 description 2
- 235000019354 vermiculite Nutrition 0.000 description 2
- 239000010456 wollastonite Substances 0.000 description 2
- 229910052882 wollastonite Inorganic materials 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
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- 239000004642 Polyimide Substances 0.000 description 1
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- 239000004743 Polypropylene Substances 0.000 description 1
- 229910008051 Si-OH Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910006358 Si—OH Inorganic materials 0.000 description 1
- OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical group [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920006397 acrylic thermoplastic Polymers 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
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- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
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- 238000013461 design Methods 0.000 description 1
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- 238000004090 dissolution Methods 0.000 description 1
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- 230000008030 elimination Effects 0.000 description 1
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- 150000002118 epoxides Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000005641 methacryl group Chemical group 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000010129 solution processing Methods 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 238000007751 thermal spraying Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004634 thermosetting polymer Substances 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/21—Cyclic compounds having at least one ring containing silicon, but no carbon in the ring
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/11—Compounds covalently bound to a solid support
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Nanotechnology (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- General Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Ceramic Engineering (AREA)
- Physics & Mathematics (AREA)
- Composite Materials (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Geochemistry & Mineralogy (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Silicon Polymers (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US64832705P | 2005-01-27 | 2005-01-27 | |
| US60/648,327 | 2005-01-27 | ||
| PCT/US2006/003120 WO2006081512A2 (en) | 2005-01-27 | 2006-01-27 | Surface modification with polyhedral oligomeric silsesquioxanes silanols |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2008530257A JP2008530257A (ja) | 2008-08-07 |
| JP2008530257A5 JP2008530257A5 (enExample) | 2009-02-12 |
| JP5086100B2 true JP5086100B2 (ja) | 2012-11-28 |
Family
ID=36741123
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007553305A Expired - Fee Related JP5086100B2 (ja) | 2005-01-27 | 2006-01-27 | ポリヘドラルオリゴメリックシルセスキオキサンシラノールによる表面変性 |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP1841592A4 (enExample) |
| JP (1) | JP5086100B2 (enExample) |
| KR (1) | KR101288000B1 (enExample) |
| CN (1) | CN101203378B (enExample) |
| RU (1) | RU2425082C2 (enExample) |
| TW (1) | TWI399297B (enExample) |
| WO (1) | WO2006081512A2 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200730558A (en) * | 2005-12-16 | 2007-08-16 | Hybrid Plastics Inc | POSS nanostructured chemicals as dispersion aids and friction reducing agents |
| JP2011144238A (ja) | 2010-01-13 | 2011-07-28 | Tdk Corp | 被覆粒子の製造方法 |
| CN103304149B (zh) * | 2013-03-26 | 2016-05-25 | 厦门大学 | 一种在玻璃表面构筑疏水涂层的方法及涂层物质 |
| CN103553709B (zh) * | 2013-10-31 | 2015-04-08 | 哈尔滨工业大学 | 一种poss基高发射率纳米涂层的制备方法 |
| CN104927403B (zh) * | 2015-06-18 | 2017-06-06 | 合肥工业大学 | 一种高性能润滑油添加剂的制备方法 |
| CA2996443C (en) * | 2015-08-28 | 2024-01-02 | Sintef Tto As | Method for manufacturing a surface-treated particulate inorganic material |
| CN109180943A (zh) * | 2018-07-26 | 2019-01-11 | 东华大学 | 一种多羟基功能poss杂化材料的制备方法 |
| EP3715396A1 (de) * | 2019-03-26 | 2020-09-30 | PolyU GmbH | Zusammensetzung und verfahren zur herstellung silylierter polymere und deren verwendung |
| KR102172856B1 (ko) * | 2019-06-13 | 2020-11-02 | 국방과학연구소 | 반응성 섬유, 이의 제조방법 및 이를 포함하는 화생방 보호의 외피 |
| CN110669423B (zh) * | 2019-09-23 | 2023-01-24 | 明基材料有限公司 | 高硬度可挠硬涂层膜及显示器 |
| KR102068100B1 (ko) | 2019-10-24 | 2020-01-21 | 이민영 | 도막형 바닥재용 조성물 및 이를 이용한 바닥 시공방법. |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US4729371A (en) * | 1983-10-11 | 1988-03-08 | Minnesota Mining And Manufacturing Company | Respirator comprised of blown bicomponent fibers |
| US5484867A (en) * | 1993-08-12 | 1996-01-16 | The University Of Dayton | Process for preparation of polyhedral oligomeric silsesquioxanes and systhesis of polymers containing polyhedral oligomeric silsesqioxane group segments |
| US5891930A (en) * | 1995-08-17 | 1999-04-06 | Dsm N.V. | High temperature coating composition for glass optical fibers, a method of making a coating composition and a coated optical glass fiber |
| FR2765225B1 (fr) * | 1997-06-30 | 2000-01-14 | Atochem Elf Sa | Composante catalytique solide pour la polymerisation des olefines |
| RU2195050C2 (ru) * | 1998-06-05 | 2002-12-20 | Джорджиэ Тек Рисеч Копэрейшн | Способ получения пористой изоляционной композиции (варианты), композиция, используемая для получения пористого изоляционного материала (варианты), и полупроводниковое устройство |
| CA2374862C (en) * | 1999-06-11 | 2010-02-09 | Gas Separation Technology, Inc. | Porous gas permeable material for gas separation |
| CN1214034C (zh) * | 1999-08-04 | 2005-08-10 | 杂混复合塑料公司 | 形成多面体低聚倍半硅氧烷的方法 |
| US6716919B2 (en) * | 2000-03-24 | 2004-04-06 | Hybrid Plastics | Nanostructured chemicals as alloying agents in polymers |
| WO2001012221A1 (en) * | 1999-08-16 | 2001-02-22 | Henceforth Hibernia, Inc. | Therapeutic and prophylactic compositions including catalytic biomimetic solids and methods to prepare and use them |
| IT1321283B1 (it) * | 2000-05-30 | 2004-01-08 | Gd Spa | Dispositivo formatore di gruppi di sigarette. |
| DE10156619A1 (de) * | 2001-11-17 | 2003-05-28 | Creavis Tech & Innovation Gmbh | Verfahren zur Herstellung funktionalisierter oligomerer Silasesquioxane sowie deren Verwendung |
| TWI257404B (en) * | 2001-12-20 | 2006-07-01 | Ind Tech Res Inst | Polyolefin-based nanocomposite and preparation thereof |
| CA2475567A1 (en) * | 2002-02-07 | 2003-08-14 | Covalent Partners, Llc | Nanofilm and membrane compositions |
| US6873026B1 (en) * | 2002-03-04 | 2005-03-29 | Novellus Systems, Inc. | Inhomogeneous materials having physical properties decoupled from desired functions |
| JP2003277649A (ja) * | 2002-03-25 | 2003-10-02 | Asahi Kasei Corp | 無機機能付与剤 |
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2006
- 2006-01-26 TW TW095103086A patent/TWI399297B/zh not_active IP Right Cessation
- 2006-01-27 WO PCT/US2006/003120 patent/WO2006081512A2/en not_active Ceased
- 2006-01-27 JP JP2007553305A patent/JP5086100B2/ja not_active Expired - Fee Related
- 2006-01-27 EP EP06734021A patent/EP1841592A4/en not_active Withdrawn
- 2006-01-27 KR KR1020077019457A patent/KR101288000B1/ko not_active Expired - Fee Related
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|---|---|
| RU2425082C2 (ru) | 2011-07-27 |
| KR101288000B1 (ko) | 2013-07-19 |
| RU2007132158A (ru) | 2009-03-10 |
| EP1841592A2 (en) | 2007-10-10 |
| JP2008530257A (ja) | 2008-08-07 |
| WO2006081512A2 (en) | 2006-08-03 |
| TWI399297B (zh) | 2013-06-21 |
| CN101203378B (zh) | 2013-03-27 |
| WO2006081512A3 (en) | 2007-11-01 |
| CN101203378A (zh) | 2008-06-18 |
| TW200639058A (en) | 2006-11-16 |
| EP1841592A4 (en) | 2011-04-20 |
| KR20070121648A (ko) | 2007-12-27 |
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