JP5027577B2 - 燃料電池のアノード化学量論制御 - Google Patents
燃料電池のアノード化学量論制御 Download PDFInfo
- Publication number
- JP5027577B2 JP5027577B2 JP2007180912A JP2007180912A JP5027577B2 JP 5027577 B2 JP5027577 B2 JP 5027577B2 JP 2007180912 A JP2007180912 A JP 2007180912A JP 2007180912 A JP2007180912 A JP 2007180912A JP 5027577 B2 JP5027577 B2 JP 5027577B2
- Authority
- JP
- Japan
- Prior art keywords
- anode
- valve
- nitrogen
- exhaust gas
- anode exhaust
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000446 fuel Substances 0.000 title claims description 55
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 118
- 239000007789 gas Substances 0.000 claims description 95
- 229910052757 nitrogen Inorganic materials 0.000 claims description 59
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 50
- 239000001257 hydrogen Substances 0.000 claims description 47
- 229910052739 hydrogen Inorganic materials 0.000 claims description 47
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- 238000000034 method Methods 0.000 claims description 21
- 239000012528 membrane Substances 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 8
- 230000035699 permeability Effects 0.000 claims description 6
- 230000005484 gravity Effects 0.000 claims description 4
- 238000004364 calculation method Methods 0.000 claims description 3
- 238000011144 upstream manufacturing Methods 0.000 claims description 3
- 230000003068 static effect Effects 0.000 claims 2
- 239000003054 catalyst Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- 239000012495 reaction gas Substances 0.000 description 3
- 230000033764 rhythmic process Effects 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 239000012809 cooling fluid Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04305—Modeling, demonstration models of fuel cells, e.g. for training purposes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
- H01M8/04097—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with recycling of the reactants
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04223—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
- H01M8/04231—Purging of the reactants
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
- H01M8/0444—Concentration; Density
- H01M8/04462—Concentration; Density of anode exhausts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
- H01M8/04492—Humidity; Ambient humidity; Water content
- H01M8/04514—Humidity; Ambient humidity; Water content of anode exhausts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04746—Pressure; Flow
- H01M8/04761—Pressure; Flow of fuel cell exhausts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M2008/1095—Fuel cells with polymeric electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04992—Processes for controlling fuel cells or fuel cell systems characterised by the implementation of mathematical or computational algorithms, e.g. feedback control loops, fuzzy logic, neural networks or artificial intelligence
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Energy (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Fuel Cell (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/457,880 | 2006-07-17 | ||
| US11/457,880 US8524404B2 (en) | 2006-07-17 | 2006-07-17 | Fuel cell anode stoichiometry control |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2008047518A JP2008047518A (ja) | 2008-02-28 |
| JP2008047518A5 JP2008047518A5 (https=) | 2011-07-07 |
| JP5027577B2 true JP5027577B2 (ja) | 2012-09-19 |
Family
ID=38949644
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007180912A Expired - Fee Related JP5027577B2 (ja) | 2006-07-17 | 2007-07-10 | 燃料電池のアノード化学量論制御 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US8524404B2 (https=) |
| JP (1) | JP5027577B2 (https=) |
| CN (1) | CN100585930C (https=) |
| DE (1) | DE102007032528B4 (https=) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8974976B2 (en) * | 2007-01-31 | 2015-03-10 | GM Global Technology Operations LLC | Method of humidifying fuel cell inlets using wick-based water trap humidifiers |
| US8855942B2 (en) * | 2007-06-15 | 2014-10-07 | GM Global Technology Operations LLC | Anode bleed control strategy for improved water management and hydrogen utilization |
| US8057941B2 (en) * | 2007-06-15 | 2011-11-15 | GM Global Technology Operations LLC | Comprehensive method for triggering anode bleed events in a fuel cell system |
| US8962206B2 (en) * | 2008-11-24 | 2015-02-24 | Daimler Ag | Methods of operating fuel cell stacks and systems related thereto |
| US8771895B2 (en) * | 2010-02-03 | 2014-07-08 | GM Global Technology Operations LLC | Online anode pressure bias to maximize bleed velocity while meeting emission constraint |
| US8906566B2 (en) * | 2010-03-03 | 2014-12-09 | GM Global Technology Operations LLC | Fuel cell stack shutdown operation controlling anode pressure using discharge fuel consumption estimate |
| US8673515B2 (en) * | 2010-07-27 | 2014-03-18 | GM Global Technology Operations LLC | Diagnosis and remediation of low anode hydrogen partial pressure in a PEM fuel cell system |
| US8974975B2 (en) * | 2011-08-09 | 2015-03-10 | GM Global Technology Operations LLC | Method to correct for permeation uncertainties using a concentration sensor |
| DE102011088120A1 (de) * | 2011-12-09 | 2013-06-13 | Robert Bosch Gmbh | Brennstoffzellensystem und Verfahren zu dessen Betrieb |
| GB2518681B (en) | 2013-09-30 | 2021-08-25 | Intelligent Energy Ltd | Anode bleed control in a fuel cell stack |
| KR101592683B1 (ko) * | 2014-04-14 | 2016-02-12 | 현대자동차주식회사 | 연료전지 퍼지 제어 방법 |
| JP2016096047A (ja) | 2014-11-14 | 2016-05-26 | トヨタ自動車株式会社 | 燃料電池システム |
| FR3047092B1 (fr) * | 2016-01-26 | 2018-02-09 | Safran Aircraft Engines | Systeme de regulation de pression, ensemble de pile a combustible et utilisation du systeme de regulation |
| JP6237861B1 (ja) * | 2016-11-04 | 2017-11-29 | 富士電機株式会社 | 燃料電池システム及びその運転方法 |
| KR102687160B1 (ko) * | 2016-12-15 | 2024-07-22 | 현대자동차주식회사 | 연료전지 애노드의 수소농도 추정방법 및 추정시스템 |
| DE102017215501A1 (de) | 2017-09-05 | 2019-03-07 | Audi Ag | Verfahren zum Betreiben eines Brennstoffzellensystems sowie Brennstoffzellensystem |
| KR102554935B1 (ko) | 2018-03-14 | 2023-07-12 | 현대자동차주식회사 | 연료전지의 수소 농도 제어방법 및 제어시스템 |
| KR102030145B1 (ko) | 2018-03-14 | 2019-10-08 | 현대자동차(주) | 연료전지의 수소 농도 추정방법 및 추정시스템 |
| US10916788B2 (en) * | 2019-01-31 | 2021-02-09 | Toyota Jidosha Kabushiki Kaisha | Hydrogen supply system low pressure state estimator |
| AT523373B1 (de) * | 2019-12-18 | 2021-10-15 | Avl List Gmbh | Sensorvorrichtung für ein Brennstoffzellensystem |
| CN111799490B (zh) * | 2020-06-12 | 2021-11-16 | 上海发电设备成套设计研究院有限责任公司 | 一种封闭容器的除氢系统 |
| DE102020209740A1 (de) * | 2020-08-03 | 2022-02-03 | Robert Bosch Gesellschaft mit beschränkter Haftung | Verfahren zum Betreiben eines Brennstoffzellensystems, Auswerteeinheit für ein Brennstoffzellensystem |
| CN112510229B (zh) * | 2020-12-04 | 2022-07-22 | 上海捷氢科技股份有限公司 | 一种燃料电池系统、及其氢气计量比的计算方法及装置 |
| CN115483417A (zh) * | 2021-05-31 | 2022-12-16 | 未势能源科技有限公司 | 一种燃料电池氢气含量测试方法及系统 |
| US12381238B2 (en) * | 2021-09-10 | 2025-08-05 | Cummins Inc. | Systems and methods to measure or control fuel cell stack excess hydrogen flow using humidity |
| CN114464848B (zh) * | 2022-01-24 | 2023-11-24 | 同济大学 | 一种车载供氢系统氢气流量负载匹配控制方法和装置 |
| JP7441870B2 (ja) * | 2022-03-11 | 2024-03-01 | 本田技研工業株式会社 | 燃料電池システム及び燃料電池システムの弁制御方法 |
| CN114759233B (zh) * | 2022-05-24 | 2024-01-26 | 苏州溯驭技术有限公司 | 一种适用于氢燃料系统的排氮阀控制方法及其排氮阀系统 |
| CN115939464B (zh) * | 2022-11-16 | 2025-04-11 | 一汽解放汽车有限公司 | 排气控制方法、装置、计算机设备和存储介质 |
| CN116053530B (zh) * | 2023-01-28 | 2023-06-13 | 江苏重塑能源科技有限公司 | 燃料电池阳极组分的浓度计算方法和计算装置 |
| DE102023204701B3 (de) | 2023-05-19 | 2024-09-26 | Robert Bosch Gesellschaft mit beschränkter Haftung | Diagnoseverfahren zum Bestimmen eines Zustands eines Brennstoffzellensystems |
| DE102024205675A1 (de) * | 2024-06-19 | 2025-12-24 | Robert Bosch Gesellschaft mit beschränkter Haftung | Verfahren und Steuergerät zum Betreiben eines Brennstoffzellensystems sowie Brennstoffzellensystem |
| CN119133536B (zh) * | 2024-08-26 | 2025-04-18 | 电子科技大学 | 一种燃料电池发动机阳极排气方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09204226A (ja) | 1996-01-25 | 1997-08-05 | Mitsubishi Electric Corp | 圧力制御装置 |
| US6569549B1 (en) * | 2000-11-02 | 2003-05-27 | Utc Fuel Cells, Llc | Method for increasing the operational efficiency of a fuel cell power plant |
| JP4506102B2 (ja) * | 2003-05-26 | 2010-07-21 | 日産自動車株式会社 | 燃料電池システム |
| US7399542B2 (en) * | 2004-02-17 | 2008-07-15 | General Motors Corporation | Fuel cell system burp control |
| JP4710246B2 (ja) * | 2004-05-14 | 2011-06-29 | トヨタ自動車株式会社 | 燃料電池システム |
| US20060003204A1 (en) * | 2004-07-01 | 2006-01-05 | Callahan Christopher W | Controlling fuel cell fuel purge in response to recycle fuel blower operating conditions |
| US7524571B2 (en) * | 2004-09-28 | 2009-04-28 | Sebastian Lienkamp | Method for controlling nitrogen fraction in a fuel cell |
-
2006
- 2006-07-17 US US11/457,880 patent/US8524404B2/en not_active Expired - Fee Related
-
2007
- 2007-07-10 JP JP2007180912A patent/JP5027577B2/ja not_active Expired - Fee Related
- 2007-07-12 DE DE102007032528.4A patent/DE102007032528B4/de not_active Expired - Fee Related
- 2007-07-17 CN CN200710136852A patent/CN100585930C/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US8524404B2 (en) | 2013-09-03 |
| JP2008047518A (ja) | 2008-02-28 |
| DE102007032528A1 (de) | 2008-02-21 |
| DE102007032528B4 (de) | 2024-03-07 |
| CN101110483A (zh) | 2008-01-23 |
| CN100585930C (zh) | 2010-01-27 |
| US20080014472A1 (en) | 2008-01-17 |
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