JP4946823B2 - Substrate cleaning device - Google Patents

Substrate cleaning device Download PDF

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JP4946823B2
JP4946823B2 JP2007303550A JP2007303550A JP4946823B2 JP 4946823 B2 JP4946823 B2 JP 4946823B2 JP 2007303550 A JP2007303550 A JP 2007303550A JP 2007303550 A JP2007303550 A JP 2007303550A JP 4946823 B2 JP4946823 B2 JP 4946823B2
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cleaning
substrate
plasma
cleaned
wiping
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JP2009125671A (en
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清郎 三宅
哲朗 上野
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Panasonic Corp
Panasonic Holdings Corp
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Matsushita Electric Industrial Co Ltd
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本発明は、液晶ディスプレイ用やプラズマディスプレイ用のガラス基板などの各種基板の被洗浄表面を洗浄する基板洗浄装置に関するものである。 The present invention relates to a substrate cleaning equipment for cleaning a object to be cleaned surfaces of various substrates such as a glass substrate for a liquid crystal display for or a plasma display.

従来、上記ガラス基板の製造工程においては、ガラス基板の側縁部に形成された電極に各種部品を実装する工程がある。その実装工程では、供給されたガラス基板における電極が配置されている側縁部に付着している異物を除去する洗浄工程を行い、次に電極が配置されている側縁部に異方性導電膜(ACF)を貼り付けるACF貼付工程を行い、次に電極配置位置に部品を供給して仮圧着した後、仮圧着より高い熱と圧力を加えて本圧着する工程が行われる。   Conventionally, in the manufacturing process of the glass substrate, there is a process of mounting various components on the electrodes formed on the side edges of the glass substrate. In the mounting process, a cleaning process is performed to remove foreign substances adhering to the side edge where the electrode is arranged on the supplied glass substrate, and then anisotropic conductive is applied to the side edge where the electrode is arranged. An ACF attaching process for attaching a film (ACF) is performed, and then a component is supplied to the electrode placement position and temporarily bonded, and then a process of applying pressure and heat higher than the temporary bonding and performing a final bonding is performed.

上記基板の側縁部の表面付着物を洗浄する基板洗浄装置として、押圧子の基板表面に対する対向面にテープ状の洗浄クロスを供給するとともに、押圧子における前記対向面より洗浄クロスの送り方向上手側で吐出ヘッドから洗浄クロスに向けてエタノールやその他の有機溶剤などからなる洗浄剤を吐出し、押圧子にて洗浄剤を含んだ洗浄クロスを基板の側縁部に押し付けた状態で押圧子と基板を相対移動させて基板の側縁部表面を洗浄するようにしたものが知られている(例えば、特許文献1参照)。   As a substrate cleaning apparatus for cleaning the surface deposits on the side edge of the substrate, a tape-shaped cleaning cloth is supplied to the surface of the pressing element facing the substrate surface, and the cleaning cloth feed direction is better than the facing surface of the pressing element. On the side, a cleaning agent made of ethanol or other organic solvent is discharged from the discharge head toward the cleaning cloth, and the pressing cloth is pressed against the side edge of the substrate with the pressing cloth. A substrate in which the substrate is relatively moved to clean the surface of the side edge portion of the substrate is known (see, for example, Patent Document 1).

また、単一の装置に、互いに異なる洗浄を行う第1と第2の洗浄部及び第1と第2の基板保持部を並列して配設し、各々の基板保持部にて基板を保持して各々の洗浄部を通過させ、それぞれで基板の洗浄を行い、かつ各基板保持部に対する基板の受け渡しを基板搬送手段にて行うようにしたものが知られている(例えば、特許文献2参照)。なお、洗浄の内容としては、例えば第1の洗浄部では超音波エアブロー洗浄と大気圧プラズマ洗浄を行い、第2の洗浄部では拭き取り洗浄と超音波エアブロー洗浄を行うようにしたものが記載されている。   In addition, the first and second cleaning units and the first and second substrate holding units that perform different cleanings are arranged in parallel in a single apparatus, and the substrate is held by each substrate holding unit. In other words, the substrate is passed through each cleaning unit, the substrate is cleaned by each, and the substrate is transferred to each substrate holding unit by a substrate transfer means (see, for example, Patent Document 2). . As the contents of cleaning, for example, the first cleaning unit performs ultrasonic air blow cleaning and atmospheric pressure plasma cleaning, and the second cleaning unit performs wiping cleaning and ultrasonic air blow cleaning. Yes.

また、オゾン水加熱部で加熱されて活性酸素濃度が高まり酸化力が高まったオゾン水を貯留された洗浄槽内に基板を浸漬させることで、有機物の除去などの処理を行うようにしたものが知られている(例えば、特許文献3参照)。
特許第3503512号明細書 特開2005−99595号公報 特開2000−301085号公報
In addition, the substrate is immersed in a cleaning tank in which ozone water heated by an ozone water heating unit and having increased active oxygen concentration and increased oxidizing power is stored, thereby performing processing such as removal of organic substances. It is known (see, for example, Patent Document 3).
Japanese Patent No. 3503512 JP 2005-99595 A JP 2000-301085 A

ところで、基板上にごみやガラス片などが付着している状態でそのまま部品を実装すると接合不良を発生するという問題があるため、特許文献1に記載されているように、部品実装の直前の工程として、洗浄剤を含んだ洗浄クロスにて基板表面を拭き取り洗浄する工程を行っている。また、洗浄剤としてエタノールやIPA(イソプロピルアルコール)などの有機溶剤を適用すると、基板上にごみやガラス片だけでなく、油分が付着している場合にも効果的に除去することができるが、有機溶剤の管理の面から有機溶剤を用いない洗浄が求められ、一方有機溶剤に代えて水を適用した場合には油分を十分に除去することができず、その結果部品の接合不良の発生原因になってしまうという問題がある。なお、特許文献3には、例えば80℃程度まで加熱したオゾン水に基板を浸漬して洗浄することが開示されているが、大掛かりな洗浄槽内に基板を浸漬して有機物を除去するものであり、洗浄クロスによる拭き取り洗浄へのオゾン水の適用を示唆するものではない。また、オゾン水は濃度が高いと洗浄クロス自体も溶解する性質があり、またオゾンガスは低濃度でも作業者に悪影響を与える可能性があるため、洗浄クロスにオゾン水を含浸させて拭き取り洗浄することは考えられていない。   By the way, since there is a problem in that if a component is mounted as it is in a state where dust or a glass piece adheres to the substrate, there is a problem that a bonding failure occurs. Therefore, as described in Patent Document 1, a process immediately before component mounting is performed. The substrate surface is wiped and cleaned with a cleaning cloth containing a cleaning agent. In addition, when an organic solvent such as ethanol or IPA (isopropyl alcohol) is applied as a cleaning agent, not only dust and glass pieces but also oil can be effectively removed on the substrate. From the aspect of organic solvent management, cleaning without using an organic solvent is required. On the other hand, when water is applied instead of an organic solvent, the oil cannot be removed sufficiently, resulting in the occurrence of defective joining of parts. There is a problem of becoming. For example, Patent Document 3 discloses that the substrate is immersed and cleaned in ozone water heated to about 80 ° C. However, the substrate is immersed in a large cleaning tank to remove organic substances. Yes, it does not suggest application of ozone water to wiping and cleaning with a cleaning cloth. Also, since ozone water has the property of dissolving the cleaning cloth itself when the concentration is high, and ozone gas may have an adverse effect on the operator even at low concentrations, the cleaning cloth should be impregnated with ozone water and cleaned. Is not considered.

また、基板に設けられた電極上には酸化膜が発生したり、ニッケルが析出していることがあり、その場合もそのまま部品の接合を行うと接合不良の発生原因となるという問題があるが、この基板電極上の酸化膜等の異物は大気圧プラズマを照射して除去することが可能である。そこで、特許文献2に記載されているように、例えば第1の洗浄部で大気圧プラズマを照射して洗浄した後、第2の洗浄部に搬送し、第2の洗浄部で拭き取り洗浄するようにすることによって、接合不良の発生を抑制することができる。   In addition, an oxide film or nickel may be deposited on the electrode provided on the substrate, and even in this case, there is a problem in that joining the components as it is may cause a bonding failure. Foreign substances such as an oxide film on the substrate electrode can be removed by irradiation with atmospheric pressure plasma. Therefore, as described in Patent Document 2, for example, after cleaning by irradiating atmospheric pressure plasma in the first cleaning unit, it is transported to the second cleaning unit and wiped and cleaned in the second cleaning unit. Thus, the occurrence of bonding failure can be suppressed.

ところが、従来の比較的大型の平行平板電極で構成される大気圧プラズマによる洗浄手段と有機溶剤を用いた拭き取り洗浄手段とを近距離で並列配置するのは、特に小型基板等の洗浄の際には困難であるため、特許文献2に示すように、第1と第2の基板保持部をそれぞれ設けて、第1の基板保持部に対応して大気圧プラズマ洗浄部を、第2の基板保持部に対応して拭き取り洗浄部をというように、複数の基板保持部にそれぞれ対応した洗浄部を設けた構成を取る必要があり、設備が大型化し、さらに大気圧プラズマ洗浄装置と拭き取り洗浄装置を別々に設けてその間を搬送手段にて基板を搬送するなどして洗浄処理工程に複数の装置とその間の搬送装置を必要とするため、設備コストが高くなるという問題がある。   However, the conventional arrangement of the cleaning means using atmospheric pressure plasma composed of relatively large parallel plate electrodes and the wiping cleaning means using an organic solvent are arranged in parallel at a short distance, particularly when cleaning a small substrate or the like. Therefore, as shown in Patent Document 2, the first and second substrate holding units are provided, and the atmospheric pressure plasma cleaning unit is set to the second substrate holding corresponding to the first substrate holding unit. It is necessary to adopt a configuration in which a cleaning unit corresponding to each of the plurality of substrate holding units is provided, such as a wiping cleaning unit corresponding to each part, the equipment becomes larger, and an atmospheric pressure plasma cleaning device and a wiping cleaning device are installed. Since a plurality of apparatuses and a transfer apparatus between them are required for the cleaning process by providing them separately and transferring the substrate between them by a transfer means, there is a problem that the equipment cost becomes high.

本発明は、上記従来の問題に鑑み、基板の被洗浄表面上に付着あるいは析出した種類の異なる異物や油分等を基板の一度の相対移動工程中に確実に除去して洗浄することができる基板洗浄装置を提供することを目的とする。 In view of the above-described conventional problems, the present invention is capable of reliably removing and cleaning different kinds of foreign matters, oils, and the like attached or deposited on the surface to be cleaned of the substrate during one relative movement process of the substrate. and to provide a cleaning equipment.

本発明の基板洗浄装置は、基板の被洗浄表面に向けて大気圧プラズマを吹き出すプラズマ洗浄手段と、プラズマ洗浄手段と並列して配設され、テープ状の洗浄クロスにて基板の被洗浄表面を拭き取り洗浄する拭取洗浄手段と、基板の被洗浄表面をプラズマ洗浄手段と拭取洗浄手段の並列方向に相対移動させる移動手段とを備え、プラズマ洗浄手段は、第1の不活性ガスの誘導結合型プラズマからなる一次プラズマを吹き出す誘導結合型プラズマ発生部と、第2の不活性ガスと反応性ガスの混合ガス領域に一次プラズマを衝突させてプラズマ化した混合ガスから成る二次プラズマを発生するプラズマ展開部とを有し、拭取洗浄手段は洗浄クロスにオゾン水を含浸させる手段を有するものであり、また拭取洗浄手段は、基板の被洗浄表面に押圧される押圧子と、押圧子の被洗浄表面に対する対向面に洗浄クロスを間欠的に送る洗浄クロス送給手段と、洗浄クロスにオゾン水を吐出するオゾン水供給手段とを備え、また一対又は複数対の押圧子が、基板の被洗浄表面を有する側縁部を両面から挟むように配設され、移動手段は押圧子を基板の前記側縁部に沿って相対移動させるThe substrate cleaning apparatus of the present invention is arranged in parallel with a plasma cleaning means for blowing atmospheric pressure plasma toward the surface to be cleaned of the substrate, and the plasma cleaning means, and the surface to be cleaned of the substrate is cleaned with a tape-shaped cleaning cloth. Wiping and cleaning means for wiping and cleaning; and moving means for relatively moving the surface to be cleaned of the substrate in the parallel direction of the plasma cleaning means and the wiping and cleaning means. The plasma cleaning means is inductively coupled with the first inert gas. An inductively coupled plasma generator that blows out a primary plasma composed of a plasma, and a secondary plasma composed of a mixed gas obtained by causing the primary plasma to collide with a mixed gas region of a second inert gas and a reactive gas. and a plasma expansion unit, wipe cleaning means all SANYO having means for impregnating the ozone water in the cleaning cloth, also wipe cleaning means, pressing it is to be cleaned surface of the substrate A pressing cloth, a cleaning cloth feeding means for intermittently sending the cleaning cloth to the surface of the pressing element facing the surface to be cleaned, and an ozone water supply means for discharging ozone water to the cleaning cloth. The pressing member is disposed so as to sandwich the side edge portion of the substrate having the surface to be cleaned from both sides, and the moving means relatively moves the pressing member along the side edge portion of the substrate .

この構成によれば、大気圧プラズマを吹き付けることで電極上に発生した酸化膜や析出したニッケルを効果的に除去することできるとともに、洗浄クロスにオゾン水を含浸させて拭き取り洗浄することで被洗浄表面にごみやガラス片に限らず油分が付着していてもオゾン水の作用で確実に除去することができる。特に、プラズマ洗浄手段において、プラズマ密度の高い誘導結合型プラズマからなる一次プラズマが第2の不活性ガスと反応性ガスの混合ガス領域に衝突することで、第2の不活性ガスが雪崩れ現象的(玉突き状に拡散)にプラズマ化して拡散し混合ガス領域の全体に展開し、プラズマ化した第2の不活性ガスのラジカルなどにて反応性ガスがプラズマ化し、その結果プラズマ密度が高くしかもプラズマ温度が低い二次プラズマが発生し、この二次プラズマを吹き出してプラズマ処理を行うことで、被洗浄表面に熱ダメージを与えることなく、基板を移動させながら確実に洗浄することができる。したがって、基板の被洗浄表面上に付着あるいは析出した種類の異なる異物や油分等を基板の一度の移動工程中に確実に除去して洗浄することができ、簡単な装置構成にて効率的に洗浄することができる。   According to this configuration, it is possible to effectively remove the oxide film generated on the electrode and the deposited nickel by blowing atmospheric pressure plasma, and to clean the object by wiping and cleaning the cleaning cloth with ozone water. Not only dust and glass pieces on the surface, even if oil is attached, it can be reliably removed by the action of ozone water. In particular, in the plasma cleaning means, the primary plasma composed of inductively coupled plasma having a high plasma density collides with the mixed gas region of the second inert gas and the reactive gas, so that the second inert gas is avalanche phenomenon. The target gas (diffusion in the shape of a ball) is converted to plasma and diffused to spread over the entire mixed gas region, and the reactive gas is turned into plasma by the radicals of the second inert gas that has been converted to plasma, resulting in high plasma density. Secondary plasma having a low plasma temperature is generated, and the secondary plasma is blown out to perform plasma treatment, so that the substrate can be reliably cleaned while being moved without causing thermal damage to the surface to be cleaned. Therefore, different types of foreign matter and oil adhering or depositing on the surface to be cleaned of the substrate can be reliably removed and cleaned during a single movement process of the substrate, and cleaning is performed efficiently with a simple apparatus configuration. can do.

また、拭取洗浄手段を、基板の被洗浄表面に押圧される押圧子と、押圧子の被洗浄表面に対する対向面に洗浄クロスを間欠的に送る洗浄クロス送給手段と、洗浄クロスにオゾン水を吐出するオゾン水供給手段とを備えた構成とすると、押圧子の対向面にてオゾン水を含んだ洗浄クロスを基板の被洗浄表面に押し付けた状態で、基板と押圧子を相対移動することで、洗浄クロスにて基板の被洗浄表面を確実に拭き取り洗浄することができる。   Further, the wiping and cleaning means includes a pressing element pressed against the surface to be cleaned of the substrate, a cleaning cloth feeding means for intermittently sending the cleaning cloth to the surface of the pressing element facing the surface to be cleaned, and ozone water in the cleaning cloth. When the cleaning cloth containing ozone water is pressed against the surface to be cleaned on the opposite surface of the pressing element, the substrate and the pressing element are moved relative to each other. Thus, the surface to be cleaned of the substrate can be reliably wiped and cleaned with the cleaning cloth.

また、一対又は複数対の押圧子が、基板の被洗浄表面を有する側縁部を両面から挟むように配設され、移動手段は押圧子を基板の前記側縁部に沿って相対移動させるものであると、基板の側縁部の表裏両面の被洗浄表面を同時に洗浄できるとともに、基板の側縁部を裏面から支持する必要がないので、基板の支持構成を簡単にできて装置構成をコンパクトにできる。   In addition, a pair or a plurality of pairs of pressing elements are arranged so as to sandwich the side edge portion of the substrate having the surface to be cleaned from both sides, and the moving means relatively moves the pressing elements along the side edge portion of the substrate. In this case, the surface to be cleaned on both the front and back sides of the side edge of the substrate can be cleaned at the same time, and it is not necessary to support the side edge of the substrate from the back side. Can be.

本発明の基板洗浄装置によれば、大気圧プラズマの二次プラズマを吹き付けるプラズマ洗浄と、オゾン水を含浸させたテープ状の洗浄クロスによる拭き取り洗浄とを、基板の被洗浄表面を相対的に移動させつつその移動方向に間隔あけた位置で並行して行うことにより、基板の被洗浄表面上に付着あるいは析出した種類の異なる異物や油分等を基板の一度の移動工程中に確実に除去して洗浄することができ、簡単な装置構成にて効率的に洗浄することができる。 According to the substrate cleaning equipment of the present invention, a plasma cleaning blowing secondary plasma in atmospheric pressure plasma, and a cleaning wipe with ozone water tape-shaped cleaning cloth impregnated, to be cleaned surface of the substrate relatively By moving in parallel at positions spaced in the moving direction while moving, it is possible to reliably remove different types of foreign matter and oil adhering or depositing on the surface to be cleaned of the substrate during a single moving process of the substrate. Can be cleaned efficiently, and can be cleaned efficiently with a simple apparatus configuration.

以下、本発明を、液晶表示パネルのガラス基板の側縁部の被洗浄表面を洗浄して付着した異物を除去する基板洗浄装置に適用した各実施形態について、図1〜図9を参照して説明する。   Hereinafter, with reference to FIGS. 1 to 9, each embodiment in which the present invention is applied to a substrate cleaning apparatus that cleans a surface to be cleaned of a side edge portion of a glass substrate of a liquid crystal display panel and removes adhered foreign matters will be described with reference to FIGS. explain.

(第1の実施形態)
まず、本発明の第1の実施形態の基板洗浄装置について、図1〜図7を参照して説明する。
(First embodiment)
First, a substrate cleaning apparatus according to a first embodiment of the present invention will be described with reference to FIGS.

図1〜図4において、本実施形態の基板洗浄装置は、ガラス基板などの基板1を基板洗浄装置に搬入する基板搬送手段2と、基板搬送手段2から基板1を受け取って洗浄動作に伴う移動を行う移動手段3と、基板1の側端部の表裏両面の被洗浄表面の拭き取り洗浄を行う拭取洗浄手段4と、基板1の被洗浄表面に大気圧プラズマを吹き出してプラズマ洗浄を行うプラズマ洗浄手段5とを備え、各々基台20上に配設されている。なお、基板1の搬出は、後続工程であるACF貼付装置(図示せず)に設けられた、基板搬送手段2と同様の基板搬送手段(図示せず)にて行われる。   1 to 4, the substrate cleaning apparatus according to the present embodiment includes a substrate transfer means 2 that carries a substrate 1 such as a glass substrate into the substrate cleaning apparatus, and a movement that accompanies the cleaning operation after receiving the substrate 1 from the substrate transfer means 2. Moving means 3 for performing cleaning, wiping / cleaning means 4 for wiping and cleaning the surfaces to be cleaned on the front and back surfaces of the side edges of the substrate 1, and plasma for performing plasma cleaning by blowing atmospheric pressure plasma to the surface to be cleaned of the substrate 1 The cleaning means 5 is provided on the base 20. The unloading of the substrate 1 is performed by a substrate transfer means (not shown) similar to the substrate transfer means 2 provided in an ACF sticking apparatus (not shown) as a subsequent process.

基板搬送手段2は、基板1を載置して両持支持する一対の支持アーム6a、6aを有する基板載置部6と、基板載置部6を基板搬送方向であるX方向に往復移動させる駆動機構7にて構成されている。駆動機構7は、基板載置部6を移動自在に支持する支持レール部7aと、モータ7cにて駆動されて基板載置部6を移動させる送りねじ機構7bにて構成されている。   The substrate transport means 2 reciprocally moves the substrate platform 6 having a pair of support arms 6a, 6a for placing and supporting the substrate 1 in both directions, and the substrate platform 6 in the X direction which is the substrate transport direction. The drive mechanism 7 is used. The drive mechanism 7 includes a support rail portion 7a that movably supports the substrate platform 6, and a feed screw mechanism 7b that is driven by a motor 7c to move the substrate platform 6.

移動手段3は、基板1の中央部を載置支持する基板保持部8と、基板保持部8をX方向と、それに直行するY方向と、垂直なZ方向と、Z軸回りのθ方向の移動及び位置決めを行う移動テーブル9にて構成されている。この移動手段3は、基板1を基板保持部8上に保持し、プラズマ洗浄手段5及び拭取洗浄手段4における後述の拭取洗浄部10が、基板1の側縁部の表面及び表裏両面の被洗浄表面の一端から他端まで相対移動するように基板1を移動させる。その相対移動速度は、40〜250mm/s程度に設定され、好適には100〜250mm/s程度の高速に設定される。   The moving means 3 includes a substrate holding portion 8 for placing and supporting the central portion of the substrate 1, a substrate holding portion 8 in the X direction, a Y direction perpendicular thereto, a vertical Z direction, and a θ direction around the Z axis. It is comprised by the movement table 9 which performs a movement and positioning. The moving unit 3 holds the substrate 1 on the substrate holding unit 8, and a wiping cleaning unit 10 described later in the plasma cleaning unit 5 and the wiping cleaning unit 4 is provided on the surface of the side edge of the substrate 1 and on both the front and back surfaces. The substrate 1 is moved so as to relatively move from one end to the other end of the surface to be cleaned. The relative movement speed is set to about 40 to 250 mm / s, preferably about 100 to 250 mm / s.

次に、拭取洗浄手段4について説明する。拭取洗浄部10は、図2、図4に示すように、基板保持部8にて保持された基板1の側縁部の上下に対向するように配置された一対の押圧子11a、11bを備えている。押圧子11a、11bとしては、耐薬品性に優れるとともに摺動性に優れたポリアセタール(POM)などの材料で構成するのが好適である。そして、両押圧子11a、11bをチャック機構(図示せず)にて開閉駆動して、これら押圧子11a、11bにて基板1の側縁部の上下両面の被洗浄表面にテープ状の洗浄クロス12を押し付けるように構成されている。両押圧子11a、11bのチャック力は、4〜9N程度が好適である。なお、押圧子11a、11b及びチャック機構(図示せず)は、基板1の高さ位置との位置ずれを吸収できるように上下方向に弾性的に支持されている。   Next, the wiping / cleaning means 4 will be described. As shown in FIGS. 2 and 4, the wiping / cleaning unit 10 includes a pair of pressing elements 11 a and 11 b arranged so as to face the upper and lower sides of the side edge of the substrate 1 held by the substrate holding unit 8. I have. The pressers 11a and 11b are preferably made of a material such as polyacetal (POM) that is excellent in chemical resistance and slidable. Both pressing elements 11a and 11b are opened / closed by a chuck mechanism (not shown), and a tape-like cleaning cloth is applied to the surfaces to be cleaned on both upper and lower sides of the side edge of the substrate 1 by these pressing elements 11a and 11b. 12 is pressed. The chucking force of both pressing elements 11a and 11b is preferably about 4 to 9N. Note that the pressers 11a and 11b and the chuck mechanism (not shown) are elastically supported in the vertical direction so as to absorb the positional deviation from the height position of the substrate 1.

洗浄クロス12は、図1に示すように、押圧子11a、11bにそれぞれ対応して設けられた、洗浄クロス送給手段としての供給リール13a、13bから適宜ガイドローラ14を介して押圧子11a、11bの相対移動方向と直交する方向から押圧子11a、11bに供給される。供給された洗浄クロス12は、押圧子11a、11bにおける基板1の被洗浄表面に対向する対向面15の上手側に傾斜形成されたガイド部16を通過して対向面15に導かれる。対向面15にて基板1の被洗浄表面に接触されて洗浄を行った後の洗浄クロス12は、適宜ガイドローラ14を介して回収リール17a、17bに巻き取られる。洗浄クロス12に作用させる張力は、0.5〜1.8N程度である。洗浄クロス12は、供給リール13a、13bと回収リール17a、17bにて1回の洗浄動作毎にピッチ送りされる。   As shown in FIG. 1, the cleaning cloth 12 is provided correspondingly to the pressing elements 11 a and 11 b, respectively, and the pressing elements 11 a and 13 b as appropriate from the supply reels 13 a and 13 b serving as cleaning cloth feeding means via the guide rollers 14. It is supplied to the pressers 11a and 11b from a direction orthogonal to the relative movement direction of 11b. The supplied cleaning cloth 12 is guided to the opposing surface 15 through a guide portion 16 that is inclined on the upper side of the opposing surface 15 that opposes the surface to be cleaned of the substrate 1 in the pressing elements 11a and 11b. The cleaning cloth 12 after being cleaned by being brought into contact with the surface to be cleaned of the substrate 1 at the facing surface 15 is wound around the collection reels 17a and 17b through the guide roller 14 as appropriate. The tension applied to the cleaning cloth 12 is about 0.5 to 1.8N. The cleaning cloth 12 is pitch-fed for each cleaning operation by the supply reels 13a and 13b and the recovery reels 17a and 17b.

押圧子11a、11bのガイド部16には、洗浄剤としての低濃度のオゾン水を洗浄クロス12に向けて吐出するように、吐出口18が開口されている。オゾン水は、洗浄クロス12がピッチ送りされる前に、後述のオゾン水供給手段から押圧子11a、11bに設けられた流路を介して吐出口18に所定量づつ圧送されて洗浄テープ12に向けて吐出される。押圧子11a、11bのガイド部16に対向して、洗浄クロス12がオゾン水で濡れることで生じる色調変化を検出する検出センサ19が配設され、洗浄クロス12に所要量のオゾン水が適正に吐出されたことを確認できるように構成されている。   A discharge port 18 is opened in the guide portion 16 of the pressing elements 11a and 11b so that low-concentration ozone water as a cleaning agent is discharged toward the cleaning cloth 12. Before the cleaning cloth 12 is pitch-fed, the ozone water is pumped by a predetermined amount from the ozone water supply means described later to the discharge port 18 through a flow path provided in the pressers 11a and 11b, and is supplied to the cleaning tape 12. It is discharged toward. A detection sensor 19 that detects a change in color tone that occurs when the cleaning cloth 12 is wetted with ozone water is disposed opposite to the guide portions 16 of the pressers 11a and 11b, and a required amount of ozone water is appropriately supplied to the cleaning cloth 12. It is comprised so that it can confirm that it discharged.

押圧子11a、11bの対向面15には、押圧子11a、11bの相対移動方向と直交する方向に延びる突部15aが形成されている。対向面15及び突部15aの長さは、基板1の被洗浄表面の幅寸法より大きく設定されている。突部15aの高さhは、洗浄クロス12の厚さの3〜5倍程度が好適であり、具体例では、洗浄クロス12の厚さが0.2〜0.3mmであるため、突部15aの高さは1mm程度が好適である。また、押圧子11a、11bの対向面15の両側部には、突部15aの両側に間隔をあけて洗浄クロス12の両側縁の位置規制を行う規制突部15bが設けられている。規制突部15bの高さは突部15aの高さと同じ高さに設定され、突部15aと規制突部15bの頂面が同一平面上に位置するように構成されている。   On the opposing surface 15 of the pressing elements 11a and 11b, a protrusion 15a extending in a direction orthogonal to the relative movement direction of the pressing elements 11a and 11b is formed. The lengths of the facing surface 15 and the protrusion 15a are set larger than the width dimension of the surface to be cleaned of the substrate 1. The height h of the protrusion 15a is preferably about 3 to 5 times the thickness of the cleaning cloth 12, and in the specific example, the thickness of the cleaning cloth 12 is 0.2 to 0.3 mm. The height of 15a is preferably about 1 mm. In addition, on both sides of the opposing surface 15 of the pressing elements 11a and 11b, there are provided restricting protrusions 15b that restrict the positions of both side edges of the cleaning cloth 12 with a gap on both sides of the protrusion 15a. The height of the restricting protrusion 15b is set to be the same as the height of the protruded part 15a, and the top surfaces of the protruded part 15a and the restricting protruded part 15b are located on the same plane.

次に、プラズマ洗浄手段5について、図2〜図4を参照して説明する。断面円形の反応空間21を形成する誘電体からなる円筒状の反応容器22の周囲にコイル状のアンテナ23を配設し、アンテナ23に高周波電源24から高周波電圧を印加して反応空間21に高周波電界を印加し、反応容器22の上端22aから第1の不活性ガス25を供給し、点火装置(図示せず)で高電圧を印加して点火することで、反応容器22の下端22bから、プラズマ密度が高く高温の誘導結合型プラズマからなる一次プラズマ26を吹き出すように構成されている。この反応容器22が誘導結合型プラズマ発生部を構成している。   Next, the plasma cleaning means 5 will be described with reference to FIGS. A coiled antenna 23 is disposed around a cylindrical reaction vessel 22 made of a dielectric material that forms a reaction space 21 having a circular cross section, and a high frequency voltage is applied to the antenna 23 from a high frequency power supply 24 to generate a high frequency in the reaction space 21. By applying an electric field, supplying the first inert gas 25 from the upper end 22a of the reaction vessel 22, and applying a high voltage with an ignition device (not shown) to ignite, from the lower end 22b of the reaction vessel 22, A primary plasma 26 made of high temperature inductively coupled plasma is blown out. This reaction vessel 22 constitutes an inductively coupled plasma generator.

反応容器22の下端22b近傍の周囲に角筒形状の混合ガス容器27が配設され、その四周壁上部に混合ガス28を内部に供給する複数のガス供給口29が配設されている。混合ガス容器27は、反応容器22の下端22bより下方に延出され、反応容器22の下端22bより下方の部分に、一次プラズマ26が衝突して二次プラズマ31を発生する下端開放の混合ガス領域30が形成されている。この混合ガス容器27がプラズマ展開部を構成している。   A rectangular mixed gas container 27 is disposed around the vicinity of the lower end 22b of the reaction container 22, and a plurality of gas supply ports 29 for supplying the mixed gas 28 to the inside are disposed at the upper part of the four peripheral walls. The mixed gas container 27 extends below the lower end 22 b of the reaction container 22, and the lower end open mixed gas in which the primary plasma 26 collides with a portion below the lower end 22 b of the reaction container 22 to generate the secondary plasma 31. Region 30 is formed. This mixed gas container 27 constitutes a plasma developing part.

アンテナ23に高周波電圧を供給する高周波電源24としては、その出力周波数帯が100MHzに代表されるVHF周波数帯が好適であるが、マイクロ波周波数帯のものなどを使用することもできる。高周波電源24とアンテナ23との間には、アンテナ23で発生する反射波を抑制する整合器(マッチング回路)(図示せず)が介装されている。また、第1及び第2の不活性ガスは、アルゴン、ネオン、キセノン、ヘリウム、窒素から選択された単独ガス又は複数の混合ガスが適用される。また、反応性ガスとしては、本実施形態では電極のクリーニングや表面改質に好適な酸素ガスが適用されている。   As the high frequency power supply 24 for supplying a high frequency voltage to the antenna 23, a VHF frequency band whose output frequency band is typified by 100 MHz is suitable, but a microwave frequency band or the like can also be used. Between the high frequency power supply 24 and the antenna 23, a matching unit (not shown) that suppresses a reflected wave generated by the antenna 23 is interposed. In addition, as the first and second inert gases, a single gas or a mixed gas selected from argon, neon, xenon, helium, and nitrogen is applied. As the reactive gas, oxygen gas suitable for electrode cleaning and surface modification is applied in the present embodiment.

プラズマ洗浄手段5及び拭取洗浄部10は、図5に示すように、それぞれ発生したオゾンガスが周囲に流出するのを防止するため、オゾン回収手段としてのカバー体32、34で覆うとともに内部のガスを排気ファン33、35にて吸引するように構成されている。排気ファン33、35にて吸引されたオゾンガスは、オゾン濃度調整部36にて所要量のオゾンガスを回収し、過剰のオゾンガスは排気ファン37にてガス処理部(図示せず)にて無害化処理されて大気中に放出される。回収されたオゾンガスは、溶解水が供給されるオゾン水生成部38内に送給され、オゾン水生成部38内で超音波振動印加手段39にて印加された超音波振動を受けて溶解水にオゾンガスが効果的に溶解され、比較的低濃度の所定濃度のオゾン水が生成される。生成されるオゾン水のオゾン濃度は、通常の拭き取り洗浄時に、洗浄クロス12が溶解せず、かつ基板1に付着した油分(油膜)を効果的に除去できる程度の濃度に設定される。数値で示すと、0.01PPM以下とすることで上記作用が確実に得られる。この濃度調整が上記オゾン濃度調整部36にて行われる。なお、オゾン水生成部38において、超音波振動印加手段39に代えて、若しくは併用して熱エネルギーを印加するヒータを適用しても良い。   As shown in FIG. 5, the plasma cleaning means 5 and the wiping cleaning unit 10 are covered with cover bodies 32 and 34 as ozone recovery means and the internal gas in order to prevent the generated ozone gas from flowing out to the surroundings. Is sucked by the exhaust fans 33 and 35. The ozone gas sucked by the exhaust fans 33 and 35 collects a required amount of ozone gas by the ozone concentration adjusting unit 36, and the excess ozone gas is made harmless by the gas processing unit (not shown) by the exhaust fan 37. And released into the atmosphere. The recovered ozone gas is fed into an ozone water generation unit 38 to which dissolved water is supplied, and is subjected to ultrasonic vibration applied by the ultrasonic vibration applying means 39 in the ozone water generation unit 38 to be dissolved water. The ozone gas is effectively dissolved, and ozone water having a relatively low concentration and a predetermined concentration is generated. The ozone concentration of the generated ozone water is set to such a concentration that the cleaning cloth 12 does not dissolve and the oil (oil film) adhering to the substrate 1 can be effectively removed during normal wiping cleaning. In terms of numerical values, the above effect can be reliably obtained by setting it to 0.01 PPM or less. This concentration adjustment is performed by the ozone concentration adjusting unit 36. In the ozone water generation unit 38, a heater that applies thermal energy instead of or in combination with the ultrasonic vibration applying unit 39 may be applied.

生成されたオゾン水は、高圧エア源40からバルブ41を介してオゾン水生成部38内に高圧エアを供給して加圧し、オゾン水生成部38内のオゾン水をバルブ42を介してオゾン水供給管43を通して押圧子11a、11bに供給するとともに、バルブ42の開閉制御によって所要時に所定量づつ吐出口18から洗浄クロス12に向けてオゾン水が吐出される。これら高圧エア源40、バルブ41、42、オゾン水供給管43及び吐出口18にてオゾン水供給手段が構成されている。以上のような構成により、プラズマ洗浄手段5及び拭取洗浄部10で発生したオゾンガスを回収し、オゾン水を生成して拭取洗浄部10に送給し、オゾンを循環使用することができる。なお、オゾン水生成部38でのオゾン水の生成は連続的に行っても、バッチ方式で間欠的に行うようにしても良い。   The generated ozone water is pressurized by supplying high-pressure air from the high-pressure air source 40 through the valve 41 into the ozone water generation unit 38 and the ozone water in the ozone water generation unit 38 is supplied through the valve 42 to the ozone water. While being supplied to the pressers 11a and 11b through the supply pipe 43, ozone water is discharged from the discharge port 18 toward the cleaning cloth 12 by a predetermined amount as required by opening / closing control of the valve 42. These high-pressure air source 40, valves 41 and 42, ozone water supply pipe 43 and discharge port 18 constitute ozone water supply means. With the above configuration, ozone gas generated in the plasma cleaning means 5 and the wiping cleaning unit 10 can be collected, ozone water can be generated and sent to the wiping cleaning unit 10, and ozone can be circulated and used. The ozone water generation unit 38 may generate ozone water continuously or intermittently using a batch method.

次に、このような構成の基板洗浄装置にて基板1の側縁部の被洗浄表面を洗浄する工程を図1、図2、図4及び図6を参照して説明する。まず、基板1を基板搬送手段2にて基板洗浄装置に搬入する。搬入された基板1は移動手段3の基板保持部8上に受け取られ、移動手段3にて基板1の側縁部が、プラズマ洗浄手段5と拭取洗浄部10を順次通過するように移動制御される。そのため、まず移動手段3にて基板1の側縁部の一端がプラズマ洗浄手段5に対向位置するように位置決めされる。この搬入動作と並行して、ガイド部16に対向位置している洗浄クロス12に対して吐出口18からオゾン水を吐出し、洗浄クロス12に所要量のオゾン水が含浸された状態とする。なお、洗浄クロス12にオゾン水を十分に含んでいることが検出センサ19にて検出される。   Next, the process of cleaning the surface to be cleaned at the side edge of the substrate 1 with the substrate cleaning apparatus having such a configuration will be described with reference to FIGS. 1, 2, 4, and 6. First, the substrate 1 is carried into the substrate cleaning apparatus by the substrate transfer means 2. The loaded substrate 1 is received on the substrate holding unit 8 of the moving unit 3, and movement control is performed by the moving unit 3 so that the side edge of the substrate 1 sequentially passes through the plasma cleaning unit 5 and the wiping cleaning unit 10. Is done. Therefore, first, the moving means 3 is positioned so that one end of the side edge portion of the substrate 1 faces the plasma cleaning means 5. In parallel with this carry-in operation, ozone water is discharged from the discharge port 18 to the cleaning cloth 12 facing the guide portion 16 so that the cleaning cloth 12 is impregnated with a required amount of ozone water. The detection sensor 19 detects that the cleaning cloth 12 sufficiently contains ozone water.

次に、移動手段3にて基板1の側縁部を上記のように移動させることで、基板1の被洗浄表面がプラズマ洗浄手段5の下を通過し、大気圧プラズマが照射されて大気圧プラズマ洗浄が行われる。また、基板1の側縁部の移動が開始されると、拭取洗浄部10で洗浄クロス12が所定量送給され、押圧子11a、11bの対向面15と基板1の被洗浄表面との間に洗浄剤を含んだ部分を送給される。   Next, the moving surface 3 moves the side edge of the substrate 1 as described above, so that the surface to be cleaned of the substrate 1 passes under the plasma cleaning device 5 and is irradiated with atmospheric pressure plasma to be atmospheric pressure. Plasma cleaning is performed. When the movement of the side edge portion of the substrate 1 is started, a predetermined amount of the cleaning cloth 12 is fed by the wiping cleaning unit 10, and the opposing surface 15 of the pressers 11 a and 11 b and the surface to be cleaned of the substrate 1 are moved. A part containing the cleaning agent is fed in between.

プラズマ洗浄手段5による大気圧プラズマ洗浄においては、反応容器22の下端22bから誘導結合型プラズマから成る一次プラズマ26を吹き出している状態で、混合ガス容器27内に混合ガス28を供給することで、混合ガス領域30内で混合ガス28に一次プラズマ26が衝突して二次プラズマ31が発生し、その二次プラズマ31が混合ガス領域30の全領域に展開するとともにさらにこの混合ガス領域30から下方に吹き出す。その二次プラズマ31は、一次プラズマ26(約250℃)に比してプラズマ温度が低く(約80℃)、かつ従来のプラズマ密度が低い平行平板電極等で構成される容量結合型プラズマに比してプラズマ密度が数10倍から数百倍と高いものである。この二次プラズマ31を基板1の被洗浄表面に照射することで、短時間に効率的に所望のプラズマ処理を行うことができ、また容量結合型である平行平板電極方式では、電極間でプラズマが発生するが、加工のための相対プラズマ密度を向上させるために、加工対象である基板に電極を近付け過ぎると基板に対し放電が生じるためにあまり近付けられないが、本発明の二次プラズマ31を吹き付ける場合は、基板までの距離を2mm程度まで近付けることができ、基板に対して高いプラズマ密度を付与できる。以上のことにより、基板1を100〜150mm/sec程度で移動させながらでも適切なプラズマ処理を確実に行うことができる。このときの基板洗浄面の温度は40℃程度である。また、一次プラズマ26の衝突により拡散する高密度の二次プラズマ31に対するプラズマ着火機能の役割を有する一次プラズマ26は、従来の一次プラズマを直接基板に照射する誘導結合型プラズマ(熱プラズマ)方式に比べて少ない量の不活性ガスを着火させるため、50W程度と小さな出力でかつ発熱量も1/50程度の250℃と低く、コイルの空冷が可能であるため、よりコンパクトな構成とすることができ、またこのように二次プラズマ31が大きく展開するので、反応容器22の断面積に比して大きな領域のプラズマ処理を短時間で効率的かつ確実に行うことができ、また混合ガス28の供給・停止制御によって応答性良く二次プラズマ31の照射・ 停止制御を行うことができ、基板1の移動中に必要箇所のみプラズマ処理が可能である。以上のことにより、低出力の投入パワー比が小さい高密度プラズマで、コンパクトな大気圧プラズマ洗浄が構成できる。   In the atmospheric pressure plasma cleaning by the plasma cleaning means 5, the mixed gas 28 is supplied into the mixed gas container 27 while the primary plasma 26 made of inductively coupled plasma is blown out from the lower end 22 b of the reaction container 22. In the mixed gas region 30, the primary plasma 26 collides with the mixed gas 28 to generate a secondary plasma 31, and the secondary plasma 31 develops in the entire region of the mixed gas region 30 and further from the mixed gas region 30 downward. To blow out. The secondary plasma 31 has a plasma temperature lower than that of the primary plasma 26 (about 250 ° C.) (about 80 ° C.) and a conventional capacitively coupled plasma composed of parallel plate electrodes having a low plasma density. The plasma density is as high as several tens to several hundreds. By irradiating the surface to be cleaned of the substrate 1 with the secondary plasma 31, a desired plasma treatment can be performed efficiently in a short time. In the parallel-plate electrode method that is a capacitive coupling type, plasma is generated between the electrodes. However, in order to improve the relative plasma density for processing, if the electrode is too close to the substrate to be processed, a discharge is generated with respect to the substrate, but the secondary plasma 31 of the present invention is not very close. , The distance to the substrate can be reduced to about 2 mm, and a high plasma density can be imparted to the substrate. As described above, appropriate plasma processing can be reliably performed even when the substrate 1 is moved at about 100 to 150 mm / sec. The temperature of the substrate cleaning surface at this time is about 40 ° C. The primary plasma 26 having a role of a plasma ignition function for the high-density secondary plasma 31 diffused by the collision of the primary plasma 26 is a conventional inductively coupled plasma (thermal plasma) system in which the substrate is directly irradiated with the primary plasma. Compared to igniting a small amount of inert gas, the output is as low as about 50 W and the calorific value is as low as 250 ° C., which is about 1/50, and the coil can be air-cooled. In addition, since the secondary plasma 31 expands greatly in this way, plasma processing in a large area compared to the cross-sectional area of the reaction vessel 22 can be performed efficiently and reliably in a short time, and the mixed gas 28 Irradiation / stop control of the secondary plasma 31 can be performed with good responsiveness by supply / stop control, and plasma processing can be performed only at necessary locations while the substrate 1 is moving. Is possible. As described above, a compact high-pressure plasma cleaning can be configured with a high-density plasma having a low output power ratio with a low output.

次に、移動手段3による基板1の移動に伴って基板1の側縁部の一端が拭取洗浄部10における一対の押圧子11a、11bの間に位置すると、拭取洗浄部10のチャック機構(図示せず)にて一対の押圧子11a、11b間の隙間が閉じられ、押圧子11a、11bの対向面15に形成された突部15aにて洗浄クロス12が基板1の被洗浄表面に接触された状態となる。このように押圧子11a、11bの突部15aにて洗浄クロス12が基板1の被洗浄表面に接触されている状態で基板1が継続して移動し、押圧子11a、11bが基板1の側縁部に沿って被洗浄表面の他端に向けて相対移動することで、基板1の被洗浄表面が洗浄される。なお、この洗浄動作は、1方向の移動のみによって、あるいは1又は複数回の往復移動によって行われる。   Next, when one end of the side edge portion of the substrate 1 is positioned between the pair of pressing elements 11 a and 11 b in the wiping cleaning unit 10 as the substrate 1 is moved by the moving unit 3, the chuck mechanism of the wiping cleaning unit 10 (Not shown), the gap between the pair of pressing elements 11a and 11b is closed, and the cleaning cloth 12 is brought into contact with the surface to be cleaned of the substrate 1 by the protrusion 15a formed on the opposing surface 15 of the pressing elements 11a and 11b. It will be in contact. In this way, the substrate 1 continues to move while the cleaning cloth 12 is in contact with the surface to be cleaned of the substrate 1 at the protrusions 15a of the pressing members 11a and 11b, and the pressing members 11a and 11b are moved to the substrate 1 side. The surface to be cleaned of the substrate 1 is cleaned by moving relative to the other end of the surface to be cleaned along the edge. This cleaning operation is performed only by movement in one direction or by one or more reciprocating movements.

その後、チャック機構(図示せず)にて一対の押圧子11a、11bを開き、移動手段3にて基板1をプラズマ洗浄手段5及び拭取洗浄部10から離間させ、後続工程のACF貼付装置の基板搬送装置(図示せず)に受け渡されて搬出される。そして、基板搬送手段2にて次の基板1が搬入され、以上の洗浄工程が繰り返される。   Thereafter, a pair of pressing elements 11a and 11b are opened by a chuck mechanism (not shown), the substrate 1 is separated from the plasma cleaning means 5 and the wiping cleaning unit 10 by the moving means 3, and the ACF sticking device of the subsequent process is separated. It is delivered to a substrate transfer device (not shown) and carried out. And the next board | substrate 1 is carried in in the board | substrate conveyance means 2, and the above washing | cleaning process is repeated.

以上の本実施形態によれば、プラズマ洗浄手段5にて基板1の被洗浄表面に大気圧プラズマ(二次プラズマ31)を吹き付けることで、被洗浄表面の電極上に発生した酸化膜や析出したニッケルを効果的に除去することできるとともに、拭取洗浄部10で低濃度のオゾン水を含浸させた洗浄クロス12にて拭き取り洗浄することで、被洗浄表面にごみやガラス片に限らず油分が付着していてもオゾン水の作用で確実に除去することができる。また、拭取洗浄部10にオゾン水を適用したことでプラズマ洗浄手段5が近接して並列配置されていても安全性に問題を生じる恐れがない。したがって、単一の装置に拭取洗浄手段4とプラズマ洗浄手段5を並列配置した簡単な装置構成にて、基板1の一度の移動工程中に、基板1の被洗浄表面上に付着あるいは析出した種類の異なる異物をすべて確実に除去することができ、基板1の洗浄を効率的に行うことができる。   According to the present embodiment described above, the plasma cleaning means 5 sprays atmospheric pressure plasma (secondary plasma 31) onto the surface to be cleaned of the substrate 1, so that an oxide film generated on the electrode on the surface to be cleaned and deposited. Nickel can be effectively removed and wiped and washed with a cleaning cloth 12 impregnated with low-concentration ozone water in the wiping and cleaning unit 10, so that the surface to be cleaned is not limited to dust and glass pieces but has oil content. Even if it adheres, it can be reliably removed by the action of ozone water. Further, since ozone water is applied to the wiping / cleaning unit 10, there is no possibility of causing a problem in safety even if the plasma cleaning means 5 are arranged close to each other in parallel. Therefore, in a simple apparatus configuration in which the wiping cleaning means 4 and the plasma cleaning means 5 are arranged in parallel in a single apparatus, the substrate 1 is deposited or deposited on the surface to be cleaned during the single movement process of the substrate 1. All kinds of foreign matters can be surely removed, and the substrate 1 can be cleaned efficiently.

また、プラズマ洗浄手段5において、酸素ガスを含む反応性ガスを適用し、そのプラズマ洗浄手段5で発生したオゾンガス、及びオゾン水を適用した拭取洗浄手段4で発生したオゾンガスを回収し、この回収したオゾンガスにてオゾン生成部38でオゾン水を生成し、拭取洗浄手段4に供給するようにしているので、基板1の被洗浄表面を酸素プラズマにて処理することで濡れ性の高い表面処理ができて高い接合性を確保でき、かつそのプラズマ処理で発生したオゾンガスを利用して拭取洗浄手段4で使用するオゾン水を生成し、また拭取洗浄手段4のオゾン水から発生したオゾンガスも利用することで、プラズマ処理やオゾン水から発生したオゾンガスの有効利用を図ることができる。なお、プラズマ洗浄手段5で発生したオゾンガスを回収してオゾン水を生成するのではなく、別途に設けたオゾン水製造装置にて製造したオゾン水を拭取洗浄手段4の拭取洗浄部10に供給するようにしても良い。   In the plasma cleaning means 5, a reactive gas containing oxygen gas is applied, and the ozone gas generated in the plasma cleaning means 5 and the ozone gas generated in the wiping cleaning means 4 to which ozone water is applied are recovered, and this recovery is performed. Since ozone water is generated by the ozone generation unit 38 using the ozone gas and supplied to the wiping / cleaning means 4, the surface of the substrate 1 to be cleaned is treated with oxygen plasma so that the surface has high wettability. The ozone water generated by the wiping cleaning means 4 can be generated using the ozone gas generated by the plasma treatment, and the ozone gas generated from the ozone water of the wiping cleaning means 4 can also be secured. By using it, it is possible to effectively use ozone gas generated from plasma treatment or ozone water. Note that ozone water generated by the plasma cleaning means 5 is not collected to generate ozone water, but ozone water produced by a separately provided ozone water production apparatus is supplied to the wiping cleaning section 10 of the wiping cleaning means 4. You may make it supply.

以上の説明では、基板1の移動方向の上手側にプラズマ洗浄手段5を配設し、下手側に拭取洗浄手段4を配設した構成にて、図6に示すように、大気圧プラズマによる洗浄を行った後に、拭き取り洗浄を行うようにした例を示したが、逆に基板1の移動方向の上手側に拭取洗浄手段4を配設し、下手側にプラズマ洗浄手段5を配設した構成とし、図7に示すように、拭き取り洗浄を行った後に、大気圧プラズマによる洗浄を行うようにし手も良い。こうすると、拭取洗浄工程で濡れた被洗浄表面をプラズマ洗浄工程の熱で乾燥させることが可能で、次工程を速やかに実施することができる。   In the above description, the plasma cleaning means 5 is disposed on the upper side in the moving direction of the substrate 1 and the wiping cleaning means 4 is disposed on the lower side, as shown in FIG. Although an example in which wiping and cleaning is performed after cleaning is shown, wiping and cleaning means 4 is disposed on the upper side in the moving direction of the substrate 1 and plasma cleaning means 5 is disposed on the lower side. As shown in FIG. 7, after performing wiping and cleaning, cleaning with atmospheric pressure plasma may be performed. If it carries out like this, the to-be-cleaned surface wet in the wiping washing | cleaning process can be dried with the heat of a plasma washing | cleaning process, and the next process can be implemented rapidly.

(第2の実施形態)
次に、本発明の第2の実施形態の基板洗浄装置について、図8、図9を参照して説明する。なお、第1の実施形態で説明したものと実質的同一の構成要素については、同一の参照符号を付して説明を省略し、主として相違点についてのみ説明する。
(Second Embodiment)
Next, a substrate cleaning apparatus according to a second embodiment of the present invention will be described with reference to FIGS. In addition, about the component substantially the same as what was demonstrated in 1st Embodiment, the same referential mark is attached | subjected and description is abbreviate | omitted, and only a different point is mainly demonstrated.

上記第1の実施形態の拭取洗浄手段4の拭取洗浄部10においては、一対の押圧子11a、11bを有するものを例示したが、本実施形態においては、拭取洗浄部50を、図9に示すように、洗浄クロス12を基板1の一側端の被洗浄表面の長手方向、すなわち基板1の相対移動方向に沿って送り移動可能に配設するとともに、その長手方向に間隔をあけて配設した第1の押圧位置P1と第2の押圧位置P2にそれぞれ押圧子としての押圧ローラ51a、51bと、押圧ローラ52a、52bを配設した構成とし、第1の押圧位置P1で洗浄クロス12にオゾン水を滴下してウェット洗浄し、第2の押圧位置P2で乾燥した状態の洗浄クロス12にて水分を拭き取るようにしている。   In the wiping / cleaning unit 10 of the wiping / cleaning means 4 of the first embodiment, the wiping / cleaning unit 50 is illustrated as having a pair of pressers 11a and 11b. As shown in FIG. 9, the cleaning cloth 12 is disposed so as to be capable of being fed and moved along the longitudinal direction of the surface to be cleaned at one end of the substrate 1, that is, the relative movement direction of the substrate 1, and is spaced apart in the longitudinal direction. The first pressing position P1 and the second pressing position P2 are provided with pressing rollers 51a and 51b as pressing elements and pressing rollers 52a and 52b, respectively, and cleaning is performed at the first pressing position P1. Ozone water is dropped onto the cloth 12 to perform wet cleaning, and moisture is wiped off with the cleaning cloth 12 in a dry state at the second pressing position P2.

図8、図9において、供給リール53aから引き出された洗浄クロス12は、ガイドローラ54aを介して押圧ローラ52aに送られた後、ガイドローラ55aを介して押圧ローラ51aに送られ、その後ガイドローラ56aを介して回収リール57aに巻き取られる。同様に、供給リール53bから引き出された洗浄クロス12は、ガイドローラ54bを介して押圧ローラ52bに送られた後、ガイドローラ55bを介して押圧ローラ51bに送られ、その後ガイドローラ56bを介して回収リール57bに巻き取られる。   8 and 9, the cleaning cloth 12 drawn from the supply reel 53a is sent to the pressing roller 52a through the guide roller 54a, and then sent to the pressing roller 51a through the guide roller 55a, and then the guide roller. It is wound around the collection reel 57a through 56a. Similarly, the cleaning cloth 12 drawn out from the supply reel 53b is sent to the pressing roller 52b through the guide roller 54b, then sent to the pressing roller 51b through the guide roller 55b, and then through the guide roller 56b. It is wound around the collection reel 57b.

また、本実施形態では、拭取洗浄手段4及びプラズマ洗浄手段5は、移動装置58にて基板1の一側端における被洗浄表面の長手方向に沿って矢印D方向に移動させるように構成されている。59は、被洗浄表面の汚れの除去度合いを認識する認識カメラである。また、60は、基板洗浄装置の動作を統括的に制御する制御部である。   In this embodiment, the wiping cleaning means 4 and the plasma cleaning means 5 are configured to move in the direction of arrow D along the longitudinal direction of the surface to be cleaned at one end of the substrate 1 by the moving device 58. ing. A recognition camera 59 recognizes the degree of removal of dirt on the surface to be cleaned. Reference numeral 60 denotes a control unit that comprehensively controls the operation of the substrate cleaning apparatus.

本実施形態においても、単一の装置に拭取洗浄手段4とプラズマ洗浄手段5を並列配置した簡単な装置構成にて、基板1の一度の移動工程中に、基板1の被洗浄表面上に付着あるいは析出した種類の異なる異物や油分等を確実に除去することができ、基板1の洗浄を効率的に行うことができる。   Also in the present embodiment, a simple apparatus configuration in which the wiping cleaning means 4 and the plasma cleaning means 5 are arranged in parallel in a single apparatus on the surface to be cleaned of the substrate 1 during a single moving process of the substrate 1. Different kinds of foreign matters, oils, and the like that have adhered or deposited can be reliably removed, and the substrate 1 can be cleaned efficiently.

本発明の基板洗浄装置によれば、基板の一度の相対移動工程中に基板の被洗浄表面上に付着あるいは析出した種類の異なる異物や油分等を確実に除去することができ、コンパクトでかつ簡単な装置構成にて基板の洗浄を効率的に行うことができることができるので、各種基板に各種部品を実装する部品実装装置に好適に利用することができる。 According to the substrate cleaning equipment of the present invention, it is possible to reliably remove the different foreign substances or oil or the like of the type adhering or precipitated in the relative moving step of once the substrate onto the cleaned surface of the substrate, and a compact Since the substrate can be efficiently cleaned with a simple apparatus configuration, it can be suitably used for a component mounting apparatus for mounting various components on various substrates.

本発明の基板洗浄装置の第1の実施形態の全体概略構成を示す斜視図。The perspective view which shows the whole schematic structure of 1st Embodiment of the board | substrate cleaning apparatus of this invention. 同実施形態の要部構成を示す斜視図。The perspective view which shows the principal part structure of the embodiment. 同実施形態のプラズマ洗浄手段の斜視図。The perspective view of the plasma cleaning means of the embodiment. 同実施形態の要部構成を示す縦断正面図。The longitudinal cross-sectional front view which shows the principal part structure of the embodiment. 同実施形態におけるオゾン水生成構成を示す構成図。The block diagram which shows the ozone water production | generation structure in the embodiment. 同実施形態における基板洗浄動作のフロー図。The flowchart of the board | substrate cleaning operation | movement in the embodiment. 同実施形態における他の基板洗浄動作のフロー図。The flowchart of the other board | substrate cleaning operation | movement in the same embodiment. 本発明の基板洗浄装置の第1の実施形態の全体概略構成を示す斜視図。The perspective view which shows the whole schematic structure of 1st Embodiment of the board | substrate cleaning apparatus of this invention. 同実施形態における要部構成を示す構成図。The block diagram which shows the principal part structure in the embodiment.

符号の説明Explanation of symbols

1 基板
3 移動手段
4 拭取洗浄手段
5 プラズマ洗浄手段
10 拭取洗浄部
11a、11b 押圧子
12 洗浄クロス
13a、13b 供給リール(洗浄クロス送給手段)
18 吐出口(オゾン水供給手段)
22 反応容器(誘導結合型プラズマ発生部)
25 第1の不活性ガス
26 一次プラズマ
27 混合ガス容器(プラズマ展開部)
28 混合ガス
30 混合ガス領域
31 二次プラズマ
32、34 カバー体(オゾン回収手段)
36 オゾン濃度調整部
38 オゾン水生成部
39 超音波振動印加手段
40 高圧エア源(オゾン水供給手段)
43 オゾン水供給管(オゾン水供給手段)
50 拭取洗浄部
51a、51b 押圧ローラ(押圧子)
52a、52b 押圧ローラ(押圧子)
53a、53b 供給リール(洗浄クロス送給手段)
DESCRIPTION OF SYMBOLS 1 Board | substrate 3 Moving means 4 Wipe cleaning means 5 Plasma cleaning means 10 Wipe cleaning part 11a, 11b Press 12 Cleaning cloth 13a, 13b Supply reel (cleaning cloth feeding means)
18 Discharge port (Ozone water supply means)
22 Reaction vessel (inductively coupled plasma generator)
25 1st inert gas 26 Primary plasma 27 Mixed gas container (plasma expansion part)
28 Mixed gas 30 Mixed gas region 31 Secondary plasma 32, 34 Cover body (ozone recovery means)
36 Ozone concentration adjusting unit 38 Ozone water generating unit 39 Ultrasonic vibration applying means 40 High pressure air source (ozone water supplying means)
43 Ozone water supply pipe (Ozone water supply means)
50 Wiping cleaning part 51a, 51b Press roller (pressor)
52a, 52b Pressing roller (pressing element)
53a, 53b Supply reel (cleaning cloth feeding means)

Claims (1)

基板の被洗浄表面に向けて大気圧プラズマを吹き出すプラズマ洗浄手段と、プラズマ洗浄手段と並列して配設され、テープ状の洗浄クロスにて基板の被洗浄表面を拭き取り洗浄する拭取洗浄手段と、基板の被洗浄表面をプラズマ洗浄手段と拭取洗浄手段の並列方向に相対移動させる移動手段とを備え、プラズマ洗浄手段は、第1の不活性ガスの誘導結合型プラズマからなる一次プラズマを吹き出す誘導結合型プラズマ発生部と、第2の不活性ガスと反応性ガスの混合ガス領域に一次プラズマを衝突させてプラズマ化した混合ガスから成る二次プラズマを発生するプラズマ展開部とを有し、拭取洗浄手段は洗浄クロスにオゾン水を含浸させる手段を有するものであり、
また拭取洗浄手段は、基板の被洗浄表面に押圧される押圧子と、押圧子の被洗浄表面に対する対向面に洗浄クロスを間欠的に送る洗浄クロス送給手段と、洗浄クロスにオゾン水を吐出するオゾン水供給手段とを備え、
また一対又は複数対の押圧子が、基板の被洗浄表面を有する側縁部を両面から挟むように配設され、移動手段は押圧子を基板の前記側縁部に沿って相対移動させることを特徴とする基板洗浄装置。
A plasma cleaning means for blowing out atmospheric pressure plasma toward the surface to be cleaned; a wiping cleaning means disposed in parallel with the plasma cleaning means for wiping and cleaning the surface to be cleaned with a tape-shaped cleaning cloth; And a moving means for relatively moving the surface to be cleaned of the substrate in the parallel direction of the plasma cleaning means and the wiping cleaning means, and the plasma cleaning means blows out primary plasma composed of inductively coupled plasma of the first inert gas. An inductively coupled plasma generating section; and a plasma expanding section for generating a secondary plasma composed of a mixed gas obtained by causing the primary plasma to collide with the mixed gas region of the second inert gas and the reactive gas, The wiping cleaning means has means for impregnating the cleaning cloth with ozone water ,
Further, the wiping and cleaning means includes a pressing element pressed against the surface to be cleaned of the substrate, a cleaning cloth feeding means for intermittently sending the cleaning cloth to the surface of the pressing element facing the surface to be cleaned, and ozone water to the cleaning cloth. An ozone water supply means for discharging,
A pair or a plurality of pairs of pressing elements are arranged so as to sandwich the side edge portion of the substrate having the surface to be cleaned from both sides, and the moving means moves the pressing elements relative to each other along the side edge portion of the substrate. A substrate cleaning apparatus.
JP2007303550A 2007-11-22 2007-11-22 Substrate cleaning device Expired - Fee Related JP4946823B2 (en)

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