JP4916682B2 - Aqueous composition - Google Patents

Description

  The present invention relates to an aqueous composition containing a water-soluble dye and a fragrance.

As a cleaning composition containing a water-soluble dye, Patent Documents 1 to 4 can be referred to. Patent Documents 1, 2, and 4 describe a fragrance composition containing an aldehyde fragrance.
JP 2005-29756 A, JP 2004-220961 A, JP2003-193097, JP 2001-98300 A

  Liquid detergents for hard surfaces are often filled in transparent or translucent containers from an aesthetic point of view, and are colored with water-soluble dyes (see Patent Documents 1 to 4). Such colored dyes are generally used that are light-resistant, but it is known that even if such dyes are used in places where they are exposed to direct sunlight in summer, it is known that they cause discoloration. It has been done by using it. Therefore, there is a demand for a method that does not fade even with a small amount of water-soluble dye.

  On the other hand, as seen in Patent Documents 1, 2, and 4, fragrance compositions are widely used for liquid detergents. Among them, aldehyde-based fragrances are effective in improving the fragrance and sustainability of fragrances, and are particularly essential components for the purpose of improving the fragrance and sustainability of detergents containing surfactants. . When the cleaning composition is sprayed on or applied to a hard surface, it is preferred that a scent is felt immediately, and that a fresh and clean scent persists in the space after a while. Alcohol-based fragrances and hydrocarbon-based fragrances have a weak fragrance and poor sustainability, but aldehyde-based fragrances are superior in that respect. In the composition which does not contain the aldehyde type fragrance | flavor described in patent document 1 Example, there exists a subject in the fragrance standing of a composition or the persistence of fragrance. However, when a large amount of aldehyde-based fragrance is contained, it becomes difficult to suppress the fading of the water-soluble dye. Patent Document 2 deals with dye stability during high-temperature storage, and Patent Document 4 deals with fragrance stability of fragrances, but the light resistance of dyes has not been discussed.

  Accordingly, the problem to be solved by the present invention is an aqueous composition suitable for application to an aqueous composition, particularly a liquid detergent composition, which has excellent fragrance and scent persistence and suppresses discoloration of the dye used together. Is to provide.

  The present invention relates to an aqueous composition containing a water-soluble dye, a fragrance composition, and water, and having an aldehyde-based fragrance component content of 5 to 100 ppm.

  The present invention also relates to a liquid detergent composition containing a surfactant, a water-soluble dye, a fragrance composition, and water, and having an aldehyde-based fragrance component content of 5 to 100 ppm.

  The present invention also relates to an article in which a transparent or translucent container made of a thermoplastic resin containing a benzotriazole-based ultraviolet absorber is filled with the aqueous composition of the present invention or the liquid detergent composition of the present invention. .

  ADVANTAGE OF THE INVENTION According to this invention, the aqueous composition which suppresses the fading of the dye used together while being excellent in fragrance standing and fragrance sustainability is provided. The aqueous composition of the present invention can be blended into a liquid detergent composition for the purpose of flavoring, coloring, etc., in which case the fragrance and scent retention are excellent and the dye fading is suppressed. A liquid detergent composition is obtained.

  Examples of water-soluble dyes used in the present invention (hereinafter referred to as component (a)) include, for example, Dye Handbook (edited by the Society of Synthetic Organic Chemistry, issued July 20, 1970, Maruzen Co., Ltd.), Dye Note 22nd Edition (( Color dyes), legal dye handbook (edited by Japan Cosmetic Industry Association, published on November 28, 1988, Yakuho Nippo Co., Ltd.), etc. it can. In the present invention, a compound selected from an acid dye, a direct dye, a reactive dye, and a food coloring is particularly preferable, and an acid dye and a food coloring are most preferable. The water-soluble dye preferably has an aqueous group in the molecule, and is a water-soluble blue dye, green dye, red dye having an amino group, a sulfonyl group, or both an amino group and a sulfonyl group in the molecule, A purple dye, a yellow dye, etc. can be mentioned. The amino group used here does not mean a cyclic amino group such as a phthalocyanine group. Examples of the water-soluble dye as the component (a) include the following dyes.

(Blue dye)
CIDirect Blue1, CIDirect Blue2, CIDirect Blue6, CIDirect Blue15, CIDirect Blue41, CIDirect Blue86, CIAcid Blue1, CIAcid Blue7, CIAcid Blue9, CIAcid Blue15, CIAcid Blue22, CIAcid Blue29, CIAcid Blue62, CIAcid Blue74, CIAcid Blue83, CIAcid Blue93, CIAcid Blue93 CIAcid Blue100, CIAcid Blue103, CIAcid Blue104, CIAcid Blue112, CIAcid Blue117, CIAcid Blue138, CIFood Blue1, CIReactive Blue13, CIReactive Blue49, CIReactive Blue78, CIBasic Blue75, CIBasic Blue129.

(Green dye)
CIDirect green1, CIAcid green5, CIDirect green6, CIDirect green28, CIAcid green3, CIAcid green9, CIAcid green16, CIAcid green20, CIAcid green28, CIFood green3.

(Red dye)
CIDirect Red2, CIDirect Red13, CIDirect Red17, CIDirect Red28, CIDirect Red33, CIDirect Red46, CIDirect Red75, CIDirect Red79, CIAcid Red18, CIAcid Red27, CIAcid Red32, CIAcid Red33, CIAcid Red42, CIAcid Red51, CIAcid Red52, CIAcid Red87 CIAcid Red92, CIAcid Red94, CIAcid Red138.

(Purple dye)
CIDirect Violet1, CIAcid Violet11, CIAcid Violet15, CIAcid Violet41, CIAcid Violet49.

(Yellow dye)
CIAcid Yellow3, CIAcid Yellow17, CIAcid Yellow23, CIAcid Yellow36, CIReactive Yellow2, CIReactive Yellow102, CIReactive Yellow18, CIReactive Yellow85, CIBasic Yellow28, CIBasic Yellow36, CIBasicYellow51, CIBasic Yellow67, CIFood Yellow3.

  In the present invention, a dye having a triphenylmethane structure, a quinoline structure, a phthalocyanine structure or an anthraquinone structure is particularly preferred, and a dye having a triphenylmethane structure or a quinoline structure is more preferred.

  Suitable dyes include CIAcid Yellow3 having a quinoline structure, CIAcid Blue9 having a triphenylmethane structure, CIAcid Blue83, CIAcid Blue90, CIAcid Blue93, CIAcid Blue100, CIAcid Blue103, CIAcid Blue104, CIAcid green3, Examples include dyes selected from CIAcid green 5, CIAcid green 9, and CIFood green 3.

  In the present invention, a dye having a quinoline structure and a dye having a triphenylmethane structure may be used in combination, and when used in combination, the mass ratio of the quinoline dye to the triphenylmethane dye is 5 to 200, preferably 15 to 100. In this case, the light resistance of the dye can be improved synergistically.

  In the aqueous composition of the present invention, the component (a) is contained in the composition in an amount of 0.00001 to 0.01% by mass, more preferably 0.000025 to 0.0075% by mass, particularly 0.00005 to 0.005. It is preferable to contain it by mass%, and it becomes possible to suppress the fading by light in such a range to the level which can satisfy.

  The aqueous composition of the present invention contains a fragrance composition [hereinafter referred to as component (b)]. In the present invention, the content of the aldehyde-based fragrance component (hereinafter referred to as (b1) component) in the aqueous composition is in the range of 5 to 100 ppm, preferably 10 to 80 ppm. It is preferable to adjust. As a result of detailed studies on the fading properties of the dyes, the present inventors have found that aldehyde fragrances greatly affect the fading properties of the dyes. On the other hand, since aldehyde-based fragrances have an important role in fragrance composition and fragrance persistence of the fragrance composition, the present inventors have excellent fragrance formation and fragrance persistence, and also improve dye fading. The present inventors have found that the above range is very excellent as an improvement, and have completed the present invention.

  Aldehyde perfume ingredients include hexyl aldehyde, heptyl aldehyde, octyl aldehyde, nonyl aldehyde, decyl aldehyde, undecyl aldehyde, dodecyl aldehyde, tridecyl aldehyde, trimethyl hexyl aldehyde, methyl octyl acetaldehyde, methyl nonyl acetaldehyde, trans-2-hexenal Cis-4-heptenal, 2,6-nonadienol, cis-4-decenal, undecylene aldehyde, trans-2-dodecenal, trimethylundecenal, 2,6,10-trimethyl-5,9-undecadienal, Citral, Citronellal, Hydroxycitronellal, Perilaldehyde, Methoxydihydrocitronellal, Citronellyloxyacetaldehyde, Isocyclosito , Centenal, Bernaldehyde, Dupical, Macear, Boronal, Setneral, Phenylacetaldehyde, Phenylpropylaldehyde, Cinamic aldehyde, α-Amylcinnamic aldehyde, α-Hexylcinnamic aldehyde, Hydratropic aldehyde, Anisaldehyde, p- Methylphenylacetaldehyde, cuminaldehyde, cyclamenaldehyde, 3- (pt-butylphenyl) -propylaldehyde, p-ethyl-2,2-dimethylhydrocinnamaldehyde, 2-methyl-3- (p-methoxyphenyl)- Propyl aldehyde, pt-butyl-α-methyl hydrocinnamic aldehyde, salicyl aldehyde, heliotropin, helional, vanillin, ethyl vanillin, methyl Phosphorus, 10-undecenal, 1,2,3,4,5,6,7,8-octahydro-8,8-dimethyl-2-naphthaldehyde, 1-methyl-4- (4-methyl-3-pentenyl) -3-cyclohexene-1-carboxaldehyde, nonanal, 2,4-dimethyl-3-cyclohexene-1-carboxaldehyde, 3,5-dimethyl-3-cyclohexene-1-carboxaldehyde A mixture of -3-cyclohexene-1-carboxaldehyde and 3,5-dimethyl-3-cyclohexene-1-carboxaldehyde is commercially available as LIGUSTRAL from QUEST), benzaldehyde, mylacaldehyde, 4-tert-3 -(4-tert-Butylphenyl) -propanal (trade name = Lilia) / Dibodan), 4- (4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde and 3- (4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde (Trade name = Lilal / IFF), 3,6 (4,6) -dimethyl-3-cyclohexene-1carboaldehyde (trade name = cyclobeltal / Kao).

In the effect of the present invention, these large influence of aromatic aldehydes among affect particular heliotropin, lilial, Baie lens aldehyde, cinnamic aldehyde, alpha-hexyl cinnamic aldehyde, the fading of the cumin aldehyde dye . Therefore, the content of the aromatic aldehyde is preferably 25 ppm or less, preferably 20 ppm or less in the aqueous composition, and it is preferable to adjust the component (b) so as to satisfy this.

The fragrance composition of the present invention contains a fragrance component other than the component (b1) [hereinafter referred to as component (b2)]. Examples of the component (b2) include hydrocarbon fragrances, alcohol fragrances, ether fragrances, ketone fragrances, ester fragrances, lactone fragrances, cyclic ketone fragrances, and nitrogen-containing fragrances. Moreover, you may use the natural essential oil which contains (b2) component as a main component, if it is a range which does not inhibit the effect of invention.
Further, in the component (b), a solvent or a diluent may be used, but in the present invention, the blending amounts of the components (b1) and (b2) in the aqueous composition and the cleaning composition are all these. The mass% or mass ratio excluding the solvent and diluent. Examples of solvents and diluents include benzyl benzoate, ethanol, ethylene glycol, triethyl citrate, dipropylene glycol, propylene glycol, dimethyl phthalate, diethyl phthalate, isopropyl myristate, and the like.

<Hydrocarbon fragrance>
α-pinene, β-pinene, camphene, myrcene, limonene, terpineol, terpinolene, osymene, γ-terpinene, α-ferrandylene, p-cymene, β-caryophyllene, β-farnesene, 1,3,5-undecatriene , Diphenylmethane

<Alcohol-based fragrance>
Trans-2-hexenol, cis-3-hexenol, 3-octanol, 1-octen-3-ol, 2,6-dimethyl-2-heptanol, 9-decenol, 4-methyl-3-decen-5-ol, 10-undecenol, trans-2-cis-6-nonadienol, linalool, geraniol, nerol, citronellol, rosinol, myrsenol, lavandulol, tetrahydrogeraniol, tetrahydrolinalol, hydroxycitronellol, dihydromyrsenol, aloocimenol, terpineol, Tarpinen-4-ol, l-menthol, borneol, isopulegol, nopol, farnesol, nerolidol, bisabolol, cedrol, patchouliol, vetiverol, 2,4-dimethyl-3- Chlohexene-1-methanol, 4-isopropylcyclohexanol, 4-isopropylcyclohexanemethanol 1- (4-isopropylcyclohexyl) -ethanol, 2,2-dimethyl-3- (3-methylphenyl) -propanol, pt-butyl Cyclohexanol, ot-butylcyclohexanol, ambrinol, benzyl alcohol, phenylethyl alcohol, phenoxyethanol, styryl alcohol, anis alcohol, cinnamic alcohol, phenylpropyl alcohol, dimethylbenzyl carbinol, phenylethylmethylethyl carbinol, 3-methyl-5-phenylpentanol, thymol, carvacrol, orcinol monomethyl ether, eugenol, isoeugenol, sun Roll, isobornyl cyclohexanol, Sandaroa, Bagudanoru, sandal Mai Sol core, Buramanoru, Ebanoru, poly San tall, 2-ethoxy-4-methoxy-methylphenol

<Ether perfume>
Nerol oxide, miloxide, 1,8-cineole, rose oxide, limetol, mentfuran, linalool oxide, butyldimethyldihydropyran, acetoxyamyltetrahydropyran, cedolmethyl ether, methoxycyclododecane, 1-methyl-1-methoxycyclo Dodecane, ethoxymethylcyclododecyl ether, tricyclodecenyl methyl ether, rubofix, cedroxide, ambroxan, glycalva, voidiris, anisole, dimethylhydroquinone, paracresylmethylether, acetanisole, anethole, dihydroanethole, estragole, Diphenyl oxide, methyl eugenol, methyl isoeugenol, benzyl isoeugenol, phenyl ethyl isoamyl ester Ter, β-naphthylmethyl ether, β-naphthylethyl ether, β-naphthylisobutyl ether, 2,4-dimethyl-4-phenyltetrahydrofuran, galaxide, 2,2,5,5-tetramethyl-4-isopropyl-1, 3-Dioxane (Brand name = Verdoxan / Kao).

<Ketone perfume>
Acetoin, diacetyl, methyl amyl ketone, ethyl amyl ketone, methyl hexyl ketone, methyl nonyl ketone, methyl heptyl ketone, acetyl diisoamylene, camphor, carvone, menthone, d-pulegone, piperiton, fencheon, geranylacetone, cedrylmethyl Ketone, nootkatone, α-ionone, β-ionone, methylionone, α-n-methylionone, β-n-methylionone, α-isomethylionone, β-isomethylionone, allylionone, α-iron, β-iron, γ-iron, α-damascon, β-damascon, δ-damascon, damasenone, α-dynascon, β-dynascon, maltol, ethyl maltol, 2,5-dimethyl-4-hydroxyfuranone, sugar lactone, pt-butylcyclo Hexanone, amylcyclopentanone, heptylcyclopentanone, dihydrojasmon, cis-jasmon, florex, plicatone, 4-cyclohexyl-4-methyl-2-pentanone, p-menten-6-ylpropanone, acetophenone, p-methylacetophenone, Benzyl acetone, calone, raspberry ketone, anisyl acetone, methyl naphthyl ketone, benzophenone. The dynascon may be α-dynascon, β-dynascon, or a mixture of α-dynascon and β-dynascon (trade name = Dinascon 10 / Filmenich).

<Ester perfume>
Ethyl formate, cis-3-hexenyl formate, linalyl formate, citronellyl formate, geranyl formate, benzyl formate, phenylethyl formate, ethyl acetate, butyl acetate, isoamyl acetate, methyl cyclopentylidene acetate, hexyl acetate, cis-3-hexenyl acetate , Trans-2-hexenyl acetate, isononyl acetate, citronellyl acetate, lavandulyl acetate, geranyl acetate, linalyl acetate, mircenyl acetate, tarpinyl acetate, menthyl acetate, menthanyl acetate, nopylacetate, n-bornyl acetate, isobornyl acetate, p-t -Butylcyclohexyl, tert-butylcyclohexyl acetate, tricyclodecenyl acetate, 2,4-dimethyl-3-cyclohexene-1-methanyl acetate, benzyl acetate, phenylethyl acetate, styryl acetate, cinnamyl acetate, vinegar Anisyl, paracresyl acetate, heliotropyl acetate, acetyl eugenol, acetylisoeugenol, guayl acetate, cedol acetate, vetiberyl acetate, ethyl propionate, isoamyl propionate, citronellyl propionate, geranyl propionate, linalyl propionate, terpinyl propionate, propionic acid Benzyl, cinnamyl propionate, allyl cyclohexylpropionate, tricyclodecenyl propionate, ethyl butyrate, ethyl 2-methylbutyrate, butyl butyrate, isoamyl butyrate, hexyl butyrate, linalyl butyrate, geranyl butyrate, citronellyl butyrate, benzyl butyrate, iso Cis-3-hexenyl butyrate, citronellyl isobutyrate, geranyl isobutyrate, linalyl isobutyrate, benzyl isobutyrate, phenylethyl isobutyrate, isobutyric acid Licyclodecenyl, ethyl isovalerate, propyl valerate, citronellyl isovalerate, geranyl isovalerate, benzyl isovalerate, cinnamyl isovalerate, phenylethyl isovalerate, ethyl caproate, allyl caproate, ethyl enanthate, enanthate Acid allyl, ethyl caprate, citronellyl tiglate, methyl benzoate, ethyl benzoate, isobutyl benzoate, isoamyl benzoate, geranyl benzoate, linalyl benzoate, benzyl benzoate, phenylethyl benzoate, methyl phenylacetate, phenylacetic acid Ethyl, isobutyl phenylacetate, isoamyl phenylacetate, geranyl phenylacetate, benzyl phenylacetate, phenylethyl phenylacetate, p-cresyl phenylacetate, methyl cinnamate, ethyl cinnamate, benzyl cinnamate, cinnamate Nannyl, phenylethyl cinnamate, methyl salicylate, ethyl salicylate, isobutyl salicylate, amyl salicylate, hexyl salicylate, cis-3-hexenyl salicylate, benzyl salicylate, phenylethyl salicylate, methyl jasmonate, methyl dihydrojasmonate, flutate, 2-pentyl Allyl oxyglycolate, ethyl 3-methyl-3-phenylglycidate, ethyl 2-pentanoate, 4-acetoxy-3-amyltetrahydropyran, cyclohexyl salicylate, ethyl 2-cyclohexylpropionate (trade name = Poarenate / Kao ), Ethyltricyclo [5.2.1.0 ^2,6 ] decane-2-carboxylate (trade name = Flutate / Kao), 2-methylpentyl 2-methylpentylate (trade name = Peranat) G / Kao).

<Lactone-based fragrance, cyclic ketone-based fragrance>
γ-octalactone, γ-nonalactone, γ-decalactone, γ-undecalactone, δ-decalactone, coumarin, dihydrocoumarin, jasmolactone, jasmine lactone, muscone, cybetone, cyclopentadecanone, cyclohexadecenone, cyclopenta Decanolide, 12-ketocyclopentadecanolide, cyclohexadecanolide, cyclixadecenolide, 12-oxa-16-hexadecanolide, 11-oxa-16-hexadecanolide, 10-oxa-16-hexadecanolide, ethylene Brasilero, ethylenedodecanedioate

<Nitrogen-containing fragrance>
6-sec-butylquinoline, 5-methyl-3-heptanone oxime, citronellyl nitrile

  Examples of the natural essential oil mainly containing the component (b2) include peppermint oil, spearmint oil, mint oil, orange oil, bergamot oil, anise oil, almoase oil, basil oil, camphor oil, cedar leaf oil, and camomil oil.

  The aqueous composition of the present invention preferably contains (b) component in an amount of 0.005 to 0.5% by mass, further 0.01 to 0.3% by mass, and particularly 0.03 to 0.1% by mass. Moreover, (b) component of this invention is (b1) / (b2) = 0.01-1.5 by the mass ratio with respect to the said (b1) component and (b2) component, Furthermore, 0.05-0.4. What is contained is preferable. Furthermore, the mass ratio of the component (a) / the component (b1) is preferably 0.25 to 2, more preferably 0.3 to 1.5 from the viewpoint of the anti-fading property of the component (a). The knowledge about these mass ratios is the same in the liquid detergent composition according to the present invention described later.

  The aqueous composition of the present invention may contain a surfactant for the purpose of dispersing or solubilizing the component (b). The aqueous composition in the present invention includes a water-soluble dye, a fragrance composition, and water, and a surfactant content of less than 1% by mass.

  The aqueous composition of the present invention is preferably applied to a liquid detergent composition, and is preferably applied to a liquid detergent composition containing a surfactant [hereinafter referred to as component (c)]. In particular, the liquid detergent composition according to the present invention preferably has a component (b1) content of 5 to 100 ppm and an aromatic aldehyde fragrance component content of 25 ppm or less.

  Suitable surfactants used in the aqueous composition or liquid detergent composition include one or more selected from cationic surfactants, anionic surfactants, nonionic surfactants, and amphoteric surfactants. It is done.

  As a cationic surfactant (hereinafter referred to as component (c1)), 1 to 3 hydrocarbon groups having 8 to 16 carbon atoms and the rest being an alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms, or a benzyl group. Certain quaternary ammonium compounds are preferred. (C1) As a component, the compound of the following general formula (1)-(3) can be mentioned.

[Wherein, R ^1a and R ^2a are alkyl groups having 5 to 16 carbon atoms, preferably 6 to 14 carbon atoms, or alkenyl groups, preferably alkyl groups, and R ^1c and R ^1d are alkyl groups having 1 to 3 carbon atoms. Or it is a hydroxyalkyl group. A is -COO-, OCO-, -CONH-, -NHCO-,

It is. a is a number of 0 or 1. R ^1b is an alkylene group having 1 to 6 carbon atoms or — (O—R ^1f ) _b —. Here, R ^1f is an ethylene group or a propylene group, preferably an ethylene group, and b is a number of 1 to 10, preferably 1 to 5. R ^1e is an alkylene group having 1 to 5 carbon atoms, preferably 1 to 3 carbon atoms. One of these R ^3a , R ^3b , R ^3c and R ^3d is an alkyl group having 8 to 16 carbon atoms, and the remainder is an alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms. X ^- is an anionic group, preferably a halogen ion or an alkyl sulfate ion having 1 to 3 carbon atoms. ]

  Examples of the most preferred cationic surfactant of the present invention include the following.

  As an anionic surfactant (hereinafter referred to as component (c2)), an alkyl (or alkenyl) benzene sulfonate having an alkyl group or alkenyl group having 10 to 18 carbon atoms, an alkyl group or alkenyl group having 10 to 18 carbon atoms Polyoxyalkylene alkyl (or alkenyl) ether sulfate salt having an alkyl group having 10 to 18 carbon atoms or an alkyl (or alkenyl) sulfate ester salt having an alkenyl group, α-olefin (10 to 18 carbon atoms) sulfonate , Α-sulfo fatty acid salt (10 to 18 carbon atoms), α-sulfo fatty acid (10 to 18 carbon atoms) lower alkyl (1 to 2 carbon atoms) ester salt, secondary alkane sulfonate (13 to 18 carbon atoms) , Polyoxyethylene alkyl (alkyl having 10 to 18 carbon atoms) ether carboxylate, polyoxy Chi Ren amidoalkyl (number of carbon atoms in the alkyl 10-18) ether carboxylates, or anionic surfactant selected from fatty acid salts.

Any alkylbenzene sulfonate can be used as long as the average carbon number of the alkyl chain is 10 to 18 among those commonly distributed in the detergent surfactant market. For example, Kao Corporation Neoperex F25 made by Shell, Dobs102 made by Shell, etc. can be used. Industrially, alkylbenzene widely distributed as a detergent raw material can be obtained by sulfonation using an oxidizing agent such as chlorosulfonic acid or sulfurous acid gas. As for the average carbon number of an alkyl group, 10-14 are preferable. Moreover, as polyoxyalkylene alkyl ether sulfate, an average of 10 to 18 carbon atoms, preferably 10 to 16 linear or branched primary alcohols or linear secondary alcohols, and an average of 0.5 per molecule of EO. ˜5 mol can be added, and this can be obtained by sulfation using the method described in JP-A-9-137188, for example. The average carbon number of the alkyl group is preferably 10-16. The alkyl sulfate salt is obtained by sulfonating a linear or branched primary alcohol or linear secondary alcohol having 10 to 16 carbon atoms, preferably 10 to 14 with SO ₃ or chlorosulfonic acid, and neutralizing. it can. As the α-olefin sulfonate, a compound having a hydroxy group in a hydrocarbon group, which can be formed by sulfonating an α-alkene having 10 to 18 carbon atoms with SO ₃ and hydrating / neutralizing, A mixture of compounds in which an unsaturated bond is present. In addition, as the α-sulfo fatty acid lower alkyl ester salt, the alkyl group preferably has 10 to 16 carbon atoms, and methyl ester or ethyl ester is preferable from the viewpoint of washing effect. As polyoxyethylene alkyl ether carboxylate and polyoxyethylene amide alkyl ether carboxylate, those having an average addition mole number of ethylene oxide (hereinafter referred to as EO) of 1 to 10 are preferable. As the fatty acid salt, a saturated fatty acid salt having 8 to 14 carbon atoms, preferably caprylate, caprate, laurate and myristate are preferred. In addition, fatty acid salts having an alkyl distribution derived from palm oil or palm kernel oil can also be used.
In the present invention, a polyoxyethylene alkyl sulfate salt having 10 to 14 carbon atoms and 1 to 5 EO average addition moles is particularly preferable from the viewpoint of cleaning effect.

  As salts of these anionic surfactants, sodium salts, potassium salts, magnesium salts, calcium salts, alkanolamine salts, and ammonium salts are preferable, and sodium salts, potassium salts, and magnesium salts are preferable from the viewpoint of cleaning effect.

As the nonionic surfactant [hereinafter referred to as component (c3)], a compound of the following general formula (4) and / or general formula (5) is preferable.
R ^4a —O— (R ^4b O) _d —H (4)
[Wherein, R ^4a is an alkyl group or alkenyl group having 8 to 18 carbon atoms, preferably 10 to 16 carbon atoms, and R ^4b is an alkylene group having 2 or 3 carbon atoms, preferably an ethylene group. d represents an average added mole number of 3 or more and less than 20, preferably 4 or more and 15 or less, particularly preferably 5 or more and 10 or less. ]
R ^5a − (OR ^5b ) _e G _f (5)
[Wherein R ^5a is a linear alkyl group having 8 to 16, preferably 10 to 16, particularly preferably 10 to 14 carbon atoms, and R ^5b is an alkylene group having 2 to 4 carbon atoms, preferably ethylene group or propylene. A group, particularly an ethylene group, G is a residue derived from a reducing sugar, e is an average value of 0-6, f is an average value of 1-10, preferably 1-5, particularly preferably 1-2. Indicates. ]

Particularly preferable compounds among the compounds of the general formula (4) include the compounds of the following general formula (4-1) or the compounds of the general formula (4-2).
R ^4c —O (EO) _g —H (4-1)
[Wherein, R ^4c is a primary linear alkyl group, branched alkyl group or secondary alkyl group having 10 to 18 carbon atoms, preferably 10 to 16 carbon atoms. EO is ethylene oxide, and g is 3 or more and less than 20 as an average added mole number. ]
R ^4d -O [(EO) _h / (PO) _i ] -H (4-2)
[Wherein, R ^4d is a primary alkyl group having 10 to 18 carbon atoms, preferably 10 to 16 carbon atoms. EO represents ethylene oxide and PO represents propylene oxide. h is an average added mole number of 3 to 15, i is an average added mole number of 1 to 5, and the sum of h and i is less than 20. EO and PO may be random addition or EO addition followed by PO addition and vice versa. ]

  In the compound of the general formula (5), G is a residue derived from a reducing sugar, and the starting reducing sugar may be either aldose or ketose, and a triose having 3 to 6 carbon atoms. , Tetrose, pentose, hexose. Specific examples of aldose include apiose, arabinose, galactose, glucose, lyxose, mannose, galose, aldose, idose, talose and xylose, and examples of ketose include fructose. In the present invention, among these, aldopentose or aldohexose having 5 or 6 carbon atoms is particularly preferred, and glucose is most preferred. As the reducing sugar of G, the above monosaccharide is preferable, but an oligosaccharide obtained by condensing 2 to 5, preferably 2 or 3 of these monosaccharides may be used. Further, a mixture of monosaccharide and oligosaccharide may be used. In this case, the average degree of condensation is 1 to 5, preferably 1 to 3, particularly preferably 1 to 2, and most preferably 1 to 1.5. preferable.

The compound of the general formula (5) can be easily synthesized by subjecting R ^5a — (OR ^5b ) _e —OH and a reducing sugar to an acetalization reaction or a ketalization reaction using an acid catalyst. In the case of an acetalization reaction, these may have a hemiacetal structure or a normal acetal structure.

  As a more specific compound of the amphoteric surfactant [hereinafter referred to as component (c4)], a compound of the following general formula (6) and a compound of the following general formula (7) are preferable.

[Wherein, R ^6a is an alkyl group or alkenyl group having 8 to 16 carbon atoms, R ^6b is an alkylene group having 1 to 6 carbon atoms, and B is —COO—, —CONH—, —OCO—, — It is a group selected from NHCO-. j is a number of 0 or 1, and R ^6c and R ^6d are each an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group. ]

[Wherein, R ^7a is an alkyl or alkenyl group having 9 to 23 carbon atoms, and R ^7b is an alkylene group having 1 to 6 carbon atoms. D is a group selected from —COO—, —CONH—, —OCO—, —NHCO—, and —O—, and k is a number of 0 or 1. R ^7c and R ^7d are each an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group, and R ^7e is an alkylene group having 1 to 5 carbon atoms which may be substituted with a hydroxy group. E is a group selected from —SO ₃ ⁻ , —OSO ₃ ⁻ and —COO ⁻ . ]

In the general formula (6), R ^6a is preferably an alkyl group or alkenyl group having 10 to 14 carbon atoms, particularly preferably a lauryl group (or lauric acid residue) and / or a myristyl group (or myristic acid residue). ). B is preferably —COO— or —CONH—, and most preferably —CONH—. R ^6b preferably has 2 or 3 carbon atoms, and R ^6c and R ^6d are preferably methyl groups.

In the present invention, R ^6a in the general formula (6) may be a single alkyl (or alkenyl) chain length or a mixed alkyl group (or alkenyl group) having different alkyl (or alkenyl) chain lengths. In the latter case, those having a mixed alkyl (or alkenyl) chain length derived from a vegetable oil selected from coconut oil and palm kernel oil are preferred. Specifically, the cleaning effect is such that the molar ratio of lauryl group (or lauric acid residue) / myristyl group (or myristic acid residue) is 95/5 to 20/80, preferably 90/10 to 30/70. And from the viewpoint of foaming property.

In the general formula (7), R ^7a is preferably an alkyl group having 9 to 15 carbon atoms, particularly 9 to 13 carbon atoms, and R ^7b is preferably an alkylene group having 2 or 3 carbon atoms. D is preferably -CONH-. R ^7c and R ^7d are preferably a methyl group or a hydroxyethyl group. E is preferably —SO ₃ ⁻ or —COO ^— , and when E is —SO ₃ ^— , R ^7e is preferably —CH ₂ CH (OH) CH ₂ —, and R is R when E is —COO ^{—. 7e} is preferably a methylene group.

  In the aqueous composition of the present invention, for the purpose of dispersing or solubilizing the component (b), the component (c2) is a polyoxyethylene alkyl ether sulfate ester salt (EO average addition mole number is 1 to 5, (C3) component is polyoxyethylene alkyl ether (EO average addition mole number is 1-10, carbon number of alkyl group) 10 to 16 and the alkyl group is preferably a straight chain or branched chain. (Secondary type may be used.) As component (c4), lauroylamidopropylcarboxybetaine is preferable. The content of the component (c) in the aqueous composition is preferably 0.005% by mass or more and less than 1% by mass.

  When the aqueous composition of the present invention is used as a liquid detergent composition, from the viewpoint of cleaning effect, (c1) component is octyldibenzyldimethylammonium chloride, and (c2) component is polyoxyethylene alkyl ether sulfate. Ester salt (EO average addition mole number 1-5, alkyl group carbon number 10-16, alkyl group is preferably linear or branched, sodium salt), (c3) Polyoxyethylene alkyl ether as component (EO average addition mole number is 1-10, carbon number of alkyl group is 10-16, alkyl group is preferably straight chain or branched chain, secondary type may be used), (c4) component is lauroyl Amidopropyl carboxybetaine is preferred. Moreover, (c1) component is 0.5-3 mass% in cleaning composition, (c2) component is 0.5-3 mass%, (c3) component is 0.5-3 mass%, (c4) It is preferable to contain 0.5-3 mass% of components, and it is suitable to contain 1-15 mass% of all (c) components in a liquid detergent composition.

  The aqueous composition of the present invention may contain a water-soluble solvent [hereinafter referred to as component (d)] for the purpose of dispersing or solubilizing component (b). As the component (d), glycol solvents such as alcohol (C1-12), ethylene glycol, polyethylene glycol, propylene glycol, polypropylene glycol and the like are preferable from the viewpoint of dispersion or solubilization of the component (b). Specifically, ethanol, n-propyl alcohol, isopropyl alcohol, 1,3-propanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, ethylene glycol, propylene glycol, diethylene glycol Dipropylene glycol, glycerin and isoprene glycol are preferred. Furthermore, when using this invention for a liquid cleaning composition, it is preferable to contain (d) component from the point of a cleaning effect and a storage stability, and a boiling point is 100 degreeC or more, especially 100-300 degreeC water solubility. Solvents are preferred. Here, the water-soluble solvent referred to in the present invention is a solvent that dissolves in water at an arbitrary ratio at 20 ° C. As the component (d), (d1) a polyhydric alcohol having 4 to 12 carbon atoms, (d2) a compound represented by the following general formula (d-1), (d3) the following general formula (d-2) (D4) A compound represented by the following general formula (d-3) is preferable from the viewpoint of the storage stability of the liquid detergent composition.

[Wherein, R ¹⁹ and R ²⁰ each represent a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a phenyl group, or a benzyl group, except that both R ¹⁹ and R ²⁰ are hydrogen atoms. m represents a number from 0 to 10, and n represents a number from 0 to 10, except when both m and n are 0. R ²¹ and R ²² represent an alkyl group having 1 to 3 carbon atoms. R ²³ represents an alkyl group having 1 to 8 carbon atoms. ]

  Examples of the polyhydric alcohol having 4 to 12 carbon atoms of (d1) include isoprene glycol, 2,2,4-trimethyl-1,3-pentanediol, 1,8-octanediol, 1,9-nonanediol, and ethylene glycol. , Propylene glycol, diethylene glycol, dipropylene glycol and glycerin are preferred.

In the general formula (d-1), the compound (d2) preferably has 1 to 4 carbon atoms when R ¹⁹ and R ²⁰ are alkyl groups. Moreover, in general formula (d-1), m and n of the average addition mole number of EO and a propylene oxide (it is hereafter described as PO) are the numbers of 0-10, respectively, These additions are used. The order is not particularly limited, and may be randomly added. Specific examples of the compound (d2) include ethylene glycol monobutyl ether, dipropylene glycol dimethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, propylene glycol monobutyl ether, propylene glycol monoethyl ether, propylene glycol dimethyl ether, Polyoxyethylene (p = 2 to 3) polyoxypropylene (p = 2 to 3) glycol dimethyl ether (p represents the average number of moles added), polyethylene (p = 1 to 5) glycol phenyl ether, phenyl carbitol, phenyl Examples include cellosolve and benzyl carbitol. Among these, propylene glycol monomethyl ether, diethylene glycol monobutyl ether, and polyoxyethylene (p = 1 to 4) glycol phenyl ether are preferable from the viewpoint of detergency and storage stability.

Examples of the compound (d3) include 1,3-dimethyl-2-imidazolidinone and 1,3-diethyl-2-imidazolidinone, and examples of the compound (d4) include alkylglyceryl. An ether compound is preferred, and R ²³ is an alkyl group having 3 to 8 alkyl groups.

  Among these, water-soluble solvents (d1), (d2), and (d4) are preferable in order to satisfy the properties of the present invention, and in particular, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, glycerin, isoprene glycol, diethylene glycol mono A water-soluble solvent selected from butyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, pentyl glyceryl ether, and octyl glyceryl ether is preferred. The content of the component (d) in the aqueous composition or in the liquid detergent composition is preferably 3 to 20% by mass, more preferably 5 to 15% by mass.

  When the present invention is applied to a liquid detergent composition, it is preferable to contain a metal sequestering agent [hereinafter referred to as component (e)] for the purpose of further improving detergency. Specific examples of the metal sequestering agent include the following compounds.

(1) Phosphoric acid compounds such as phytic acid or alkali metal salts or alkanolamine salts thereof.
(2) ethane-1,1-diphosphonic acid, ethane-1,1,2-triphosphonic acid, ethane-1-hydroxy-1,1-diphosphonic acid and its derivatives, ethanehydroxy-1,1,2-triphosphonic acid Phosphonic acids such as ethane-1,2-dicarboxy-1,2-diphosphonic acid and methanehydroxyphosphonic acid, or alkali metal salts or alkanolamine salts thereof.
(3) Phosphonocarboxylic acids such as 2-phosphonobutane-1,2-dicarboxylic acid, 1-phosphonobutane-2,3,4-tricarboxylic acid, α-methylphosphonosuccinic acid, or alkali metal salts or alkanolamine salts thereof .
(4) Amino acids such as aspartic acid, glutamic acid and glycine, or alkali metal salts or alkanolamine salts thereof.
(5) Nitrilotriacetic acid, iminodiacetic acid, ethylenediaminetetraacetic acid. Diethylenetriaminepentaacetic acid, glycol etherdiaminetetraacetic acid, hydroxyethyliminodiacetic acid, triethylenetetraaminehexaacetic acid, diencoric acid, alkylglycine-N, N-diacetic acid, aspartic acid-N, N-diacetic acid, serine-N, Aminopolyacetic acid such as N-diacetic acid, glutamic acid diacetic acid, ethylenediamine succinic acid or a salt thereof, preferably an alkali metal salt or an alkanolamine salt.
(6) Organic acids such as diglycolic acid, oxydisuccinic acid, carboxymethyloxysuccinic acid, citric acid, lactic acid, tartaric acid, oxalic acid, malic acid, oxydisuccinic acid, gluconic acid, carboxymethyl succinic acid, carboxymethyl tartaric acid or the like Alkali metal salt or alkanolamine salt.
(7) Aminopoly (methylenephosphonic acid) or an alkali metal salt or alkanolamine salt thereof, or polyethylenepolyamine poly (methylenephosphonic acid) or an alkali metal salt or alkanolamine salt.

  Among these, at least one selected from the group consisting of (2), (5), and (6) is preferable, and at least one selected from the group consisting of (5) and (6) is more preferable. . The most preferred component (e) is citric acid or a salt thereof.

  In addition, (e) component can also be mix | blended with the aqueous composition of this invention. The content of the component (e) is preferably 0.2 to 5% by mass, and preferably 0.5 to 3% by mass in the aqueous composition or the liquid detergent composition.

  The aqueous composition or liquid detergent composition of the present invention is preferably in the form of an aqueous solution in which the components (a) and (b), and optionally the components (c) to (e) are dissolved in water, It is preferable to use ion-exchanged water, distilled water or sterilized water sterilized with hypochlorite or chlorine from the viewpoint of preventing dye fading, especially iron. Since ions, nickel ions, and copper ions greatly affect the fading properties, it is preferable to use water in which the total amount of these metal ions is reduced to less than 1 ppm.

  In addition, the aqueous composition or liquid detergent composition of the present invention preferably has a pH at 20 ° C. of 5 to 9, and more preferably 6 to 8, and the effects of the present invention can be enjoyed within such a pH range. it can. Examples of pH adjusters include inorganic acids such as hydrochloric acid and sulfuric acid, organic acids such as citric acid, succinic acid, malic acid, fumaric acid, tartaric acid, malonic acid, maleic acid, and the sequestering agent as component (c) above. An acid agent can be used. Moreover, it is preferable to use sodium hydroxide, potassium hydroxide, sodium carbonate, or potassium carbonate as the alkali agent.

  The liquid detergent composition of the present invention can be used for hard surfaces, clothing, body, etc., and preferably for hard surfaces, especially for bathrooms, toilets, dishes, and kitchen areas.

  The present invention provides an article in which a transparent or translucent container made of a thermoplastic resin containing a benzotriazole-based ultraviolet absorber is filled with the aqueous composition or liquid detergent composition of the present invention. Here, transparent or translucent is defined as a container having a light transmittance of 660 nm of 30% or more, preferably 50% or more, particularly preferably 80% or more. The light transmittance can be measured using a spectrophotometer.

  The thermoplastic resin constituting the container includes polyolefin resins such as low density polyethylene resin (LDPE), linear low density polyethylene resin (LLDPE), high density polyethylene resin (HDPE), homopolypropylene, block polypropylene, and random polypropylene. Polyester resin such as polyethylene terephthalate (PET), acid-modified polyolefin, polyvinyl chloride, polystyrene polymer (polystyrene, acrylonitrile-styrene resin, styrene-butadiene block copolymer) and the like are usually used. In the present invention, polyolefin resins and polyester resins are preferred from the viewpoint of transparency or translucency, and polyester resins are particularly preferred from the viewpoint of transparency.

  The polyester resin is obtained by polymerization of a polyvalent carboxylic acid and a polyhydric alcohol. Examples of the polyvalent carboxylic acid include terephthalic acid, isophthalic acid, naphthalene 2,6-dicarboxylic acid, succinic acid, sebacic acid, and adipic acid. , At least one of succinic acid is preferable. Examples of the polyhydric alcohol include glycols such as ethylene glycol, propylene glycol, butylene glycol and 1,4-cyclohexanedimethanol, polyethylene glycol, polypropylene glycol, polytetramethylene glycol, and the like At least one of the polyoxyalkylene glycols is preferred. The thermoplastic polyester resin of the present invention may be made of an oxyacid polymer or an oxyacid copolymer. Examples of the oxyacid include lactic acid, ε-caprolactone, p-oxybenzoic acid, and p-β-hydroxyethoxybenzoic acid.

  Specific examples of the polyester resin include aromatic polyester resins such as polyethylene terephthalate resin and polyethylene naphthalate resin, aliphatic polyester resins such as polyethylene succinate resin and polybutylene succinate resin, polylactic acid resin, and polycaprolactone resin. A polymer of such an oxyacid or a polyester elastomer obtained by copolymerizing an aromatic polyester with a polyoxyalkylene glycol is preferred, and a polyethylene terephthalate resin is particularly preferred from the viewpoint of the transparency of the container.

  In the present invention, such a thermoplastic resin, preferably a thermoplastic polyester resin, contains a benzotriazole ultraviolet absorber. Examples of the benzotriazole ultraviolet absorber include 2- (2′-hydroxy-3′-tert-butyl-5′-methylphenol) -5-chlorobenzotriazole (trade name = Tinuvin 326 / Nippon Ciba-Geigy), 2- (2H-benzotriazol-2-yl) -p-cresol, 2- [5-chloro (2H) -benzotriazol-2-yl] -4-methyl-6- (tert-butyl) phenol, 2,4-tert -Butyl-6- (5-chlorobenzotriazol-2-yl) phenol, 2- (2H-benzotriazol-2-yl) -4,6-bis (1-methyl-1-phenylethyl) phenol, 2- Benzotriazol-2-yl-4,6-di-tert-butylphenol, 2- (2H-benzotriazol-2-yl) -4,6 Di-tert-pentylphenol and 2- (2H-benzotriazol-2-yl) -4- (1,1,3,3-tetramethylbutyl) phenol are preferred, especially 2- (2′-hydroxy- 3'-tert-butyl-5'-methylphenol) -5-chlorobenzotriazole 2- (2H-benzotriazol-2-yl) -p-cresol, 2- [5-chloro (2H) -benzotriazole-2 1] or more selected from yl] -4-methyl-6- (tert-butyl) phenol and 2,4-tert-butyl-6- (5-chlorobenzotriazol-2-yl) phenol.

  In the present invention, the ultraviolet absorber is preferably used in an amount of 0.001 to 0.5 parts by weight, particularly preferably 0.005 to 0.3 parts by weight, based on 100 parts by weight of a thermoplastic resin, particularly a polyester resin resin. This is preferable from the viewpoint of transparency of the container and suppression of fading of the dye.

  Examples of the method for producing a container according to the present invention include a method including a step of melt-kneading a thermoplastic resin and an ultraviolet absorber by dry blending. When performing these melt-kneading, it is possible to use a single-screw extruder, a twin-screw extruder, or a Brabender type kneader. The container made of this thermoplastic resin can be obtained by a molding method such as injection molding, (stretch) blow molding, injection blow molding or the like. In addition, a masterbatch containing UV absorber and pigment was prepared using the above kneader, and dry blended so that the UV absorber had a concentration in the target range was evaluated by a molding method such as injection molding. A plate may be created. Moreover, the container which is these thermoplastic resin moldings can use not only a single layer of a thermoplastic resin but also these thermoplastic resins, especially a polyester resin, as one layer of a multilayer molding.

  It is also possible to cool the molten resin kneaded using these kneaders by water cooling or air cooling to form a film, and after pelletizing the sample extruded onto the strand, molding methods such as injection molding, vacuum compression molding, etc. You may make the plate for evaluation.

  As the development of the molded body of the thermoplastic resin composition of the present invention, various forms such as a film molded body, a sheet molded body, a bottle molded body, and a tray molded body other than the above-described plate are possible. For film, use a technique such as inflation or extrusion lamination. For a sheet, use a technique such as extrusion or extrusion lamination. For bottles, use a molding method such as injection molding, (stretch) blow molding, or injection blow molding. Then, it is possible to form a sheet molded product by a technique such as vacuum compression molding. In addition to these molded products, various molded products can be obtained.

<Preparation of perfume composition and cleaning composition>
The fragrance | flavors 1-6 shown in Table 1 were prepared. Furthermore, the aqueous composition of Table 2 was prepared using these fragrance | flavor compositions. About these aqueous compositions, fragrance standing and persistence of fragrance and light resistance were evaluated using the following container 1.

<Evaluation method of fragrance standing and scent sustainability>
Scent standing and scent persistence are sensory evaluations. The fragrance is the intensity of the scent felt immediately after spraying, and the scent persistence means whether or not the intensity of the scent drifting in the space is sufficient when a certain time has elapsed after spraying. The persistence of the scent is an indicator of how much scent drifts after cleaning for 30 minutes using, for example, an aqueous composition.

  Place a plastic wash basin in the evaluation stainless steel booth (frontage 96cm x depth 98cm x height 195cm; side window with an open / close window for evaluation, booth temperature 25 ° C, humidity 30% RH) and trigger an aqueous composition Sprayed 3 times (2.5 g) into the basin with a sprayer. 30 seconds after spraying, the evaluation window was opened from the outside of the booth to evaluate the strength of the scent (scent formation) in the booth. Moreover, the intensity | strength of fragrance (persistence of fragrance) was evaluated by the same method after 30 minutes progress. In any case, sensory evaluation was performed by 10 professional panelists according to the following evaluation criteria.

Aroma intensity (5 levels)
0: No smell 1: Scent that can finally be detected 2: Weak scent that understands what smell it is 3: Smell that can be easily detected 4: Strong smell

Aroma standing and scent persistence (3 steps)
Ten evaluators evaluated the intensity of the scent in the booth by the method shown above, and determined the average value based on the following criteria.
(Scented)
○: Average value is 3 or more ・ ・ ・ Good fragrance △: Average value is 2 or more and less than 3 ・ ・ ・ Slight fragrance is slightly good ×: Average value is less than 2 ・ ・ ・ Poor fragrance (fragrance Sustainability)
○: Average value is 3 or more ・ ・ ・ Aroma persistence is good △: Average value is 2 or more and less than 3 ・ ・ ・ Aroma persistence is slightly good ×: Average value is less than 2 Poor persistence

<Light resistance evaluation>
(Container 1)
100 parts by weight of polyethylene terephthalate resin was melted and 0.1 part by weight of 2- (2H-benzotriazol-2-yl) -p-cresol was added. A twin screw extruder was used for these kneading. A polyester resin composition was prepared by drying the molten resin extruded by a twin screw extruder. Using this polyester resin composition, a stretch blow bottle (container 1) having an average wall thickness of 0.9 mm and an internal volume of 1000 ml was formed by stretch blow molding.

The container 1 filled with 1000 ml of the aqueous composition shown in Table 1 and capped is allowed to stand in a place exposed to direct sunlight outdoors. An integrated illuminance meter PH-11-UT (Suga Test Instruments Co., Ltd.) with an ultraviolet (300-400 nm) integrated irradiance reaching 10 MJ / m ² (about 8-10 days in fine weather) is immediately incorporated. The difference in color was visually observed and evaluated according to the following criteria.
○: No change from the initial stage.
Δ: Slightly different from the initial color ×: Totally different color from the initial

The components in Table 2 are as follows.
・ Green 3: CIFood green 3 (Edible Green 3 / Made by Kasei Kasei Co., Ltd.)
-Blue No. 1: CIAcid Blue 9 (Edible Blue No. 1 / Eisen Hodogaya Co., Ltd.)
-Yellow No. 203: CIAcid Yellow 3 (Yellow No. 203 Quinoline Yellow WS / Chuo Gosei Co., Ltd.)
Polyoxyethylene alkyl ether sulfate ester salt: EO average added mole number 4 and alkyl group is straight chain alkyl group having average carbon number 12 and sodium salt

Below, the example in the case of using the aqueous composition of this invention as a liquid detergent composition is shown.
(A) CIFood green 3 (Brand name = Edible Green No. 3 / Koji Kasei) 0.0001% by mass
(B) Perfume 1 in Table 1 0.05% by mass
(C1) Octylbenzyldimethylammonium chloride 2% by mass
(C2) Polyoxyethylene alkyl ether sulfate ester salt (EO average addition mole number 4, alkyl group is straight chain alkyl group having 12 average carbon atoms, sodium salt) 2% by mass
(C3) Polyoxyethylene alkyl ether (EO average addition mole number 7, alkyl group is secondary alkyl group having average carbon number 12) 2% by mass
(C4) Lauroylamidopropylcarboxybetaine 2% by mass
(D) Diethylene glycol monobutyl ether 8% by mass
(E) Trisodium citrate 3% by mass
The remaining ion exchange water

  Among the above components, components other than ion-exchanged water were mixed, adjusted to pH = 7 (20 ° C.) with sodium hydroxide or citric acid, and then adjusted with ion-exchanged water to have the above ratio.

  The liquid cleaning composition is composed of (b1) component: 0.0040% by mass, aromatic aldehyde-based fragrance component: 0.0015% by mass, (b2) component: 0.0407% by mass, (b1) / (b2). Mass ratio: 0.10, (a) / (b1) mass ratio: 1.28.

  The liquid detergent composition is a hard surface liquid detergent excellent in light resistance, fragrance formation, and fragrance persistence.

Claims (10)

A water-soluble dye (hereinafter referred to as component (a)), a perfume composition and water,
The content of an aldehyde-based fragrance component (hereinafter referred to as (b1) component) selected from lyral, ligustral, heliotropin, lyial, benzaldehyde, cinnamaldehyde, α-hexylcinnamaldehyde and cuminaldehyde is 10 to 80 ppm,
The content of an aromatic aldehyde-based fragrance component selected from heliotropin, lyial, benzaldehyde, cinnamic aldehyde, α-hexyl cinnamic aldehyde and cumin aldehyde is 25 ppm or less,
The mass ratio of the fragrance component other than the component (b1) (hereinafter referred to as the component (b2)) and the component (b1) is (b1) / (b2) = 0.01 to 1.5,
The mass ratio of (a) component / (b1) component is 0.25 to 2 ,
Aqueous composition.   The aqueous composition according to claim 1, wherein the water-soluble dye is one or more selected from acid dyes.   The aqueous composition according to claim 1 or 2, wherein the water-soluble dye is selected from triphenylmethane dyes and quinoline dyes. The aqueous composition according to any one of claims 1 to 3 , which has a pH of 5 to 9 at 20 ° C. A surfactant, a water-soluble dye (hereinafter referred to as component (a)), a fragrance composition and water,
The content of an aldehyde-based fragrance component (hereinafter referred to as (b1) component) selected from lyral, ligustral, heliotropin, lyial, benzaldehyde, cinnamaldehyde, α-hexylcinnamaldehyde and cuminaldehyde is 10 to 80 ppm,
The content of an aromatic aldehyde-based fragrance component selected from heliotropin, lyial, benzaldehyde, cinnamic aldehyde, α-hexyl cinnamic aldehyde and cumin aldehyde is 25 ppm or less,
The mass ratio of the fragrance component other than the component (b1) (hereinafter referred to as the component (b2)) and the component (b1) is (b1) / (b2) = 0.01 to 1.5,
The mass ratio of (a) component / (b1) component is 0.25 to 2 ,
Liquid detergent composition. The liquid detergent composition of Claim 5 containing a water-soluble solvent. The liquid cleaning composition of Claim 5 or 6 containing a metal sequestering agent. The liquid detergent composition according to any one of claims 5 to 7, which has a pH of 5 to 9 at 20 ° C. The aqueous composition according to any one of claims 1 to 4 or the aqueous composition according to any one of claims 5 to 8 in a transparent or translucent container made of a thermoplastic resin containing a benzotriazole ultraviolet absorber. Articles filled with a liquid detergent composition. The benzotriazole-based UV absorber is 2- (2′-hydroxy-3′-tert-butyl-5′-methylphenol) -5-chlorobenzotriazole, 2- (2H-benzotriazol-2-yl) -p -Cresol, 2- [5-chloro (2H) -benzotriazol-2-yl] -4-methyl-6- (tert-butyl) phenol, and 2,4-tert-butyl-6- (5-chlorobenzotriazole) The article according to claim 9 , wherein the article is one or more selected from -2-yl) phenol.