JP4896566B2 - Cosmetics - Google Patents
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- JP4896566B2 JP4896566B2 JP2006100248A JP2006100248A JP4896566B2 JP 4896566 B2 JP4896566 B2 JP 4896566B2 JP 2006100248 A JP2006100248 A JP 2006100248A JP 2006100248 A JP2006100248 A JP 2006100248A JP 4896566 B2 JP4896566 B2 JP 4896566B2
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- skin
- firmness
- phytosteryl
- behenyl
- isostearyl
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- 239000002537 cosmetic Substances 0.000 title claims description 14
- 239000002253 acid Substances 0.000 claims description 21
- 229920002148 Gellan gum Polymers 0.000 claims description 14
- 239000000216 gellan gum Substances 0.000 claims description 14
- 235000010492 gellan gum Nutrition 0.000 claims description 14
- -1 isostearyl Chemical group 0.000 claims description 14
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 13
- 239000000539 dimer Substances 0.000 claims description 13
- 125000005645 linoleyl group Chemical group 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 6
- CIRMGZKUSBCWRL-LHLOQNFPSA-N (e)-10-[2-(7-carboxyheptyl)-5,6-dihexylcyclohex-3-en-1-yl]dec-9-enoic acid Chemical compound CCCCCCC1C=CC(CCCCCCCC(O)=O)C(\C=C\CCCCCCCC(O)=O)C1CCCCCC CIRMGZKUSBCWRL-LHLOQNFPSA-N 0.000 claims description 3
- 239000000463 material Substances 0.000 claims 1
- 238000011156 evaluation Methods 0.000 description 9
- 230000037393 skin firmness Effects 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 230000037394 skin elasticity Effects 0.000 description 6
- 239000006071 cream Substances 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000003020 moisturizing effect Effects 0.000 description 2
- 239000000419 plant extract Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 102000029816 Collagenase Human genes 0.000 description 1
- 108060005980 Collagenase Proteins 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920002683 Glycosaminoglycan Polymers 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 239000004264 Petrolatum Substances 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000001166 anti-perspirative effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000003213 antiperspirant Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 229960002424 collagenase Drugs 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 230000005808 skin problem Effects 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
Description
本発明は、肌にハリや弾力を与え、肌なじみや肌への伸びに優れ、しかもベタツキが少ない化粧料に関する。 The present invention relates to a cosmetic that gives firmness and elasticity to the skin, is excellent in familiarity with the skin and stretched to the skin, and has less stickiness.
従来、肌にハリや弾力を与える化粧料は数多く市販されている。肌にハリや弾力を与える化粧料としては、優れた保水性・吸水性を有する種々の水溶性多価アルコール、ムコ多糖、高分子等の保湿成分を配合したり、肌にハリや弾力を与える植物抽出物等の有効成分を配合した化粧料がある。しかしながら、これらの保湿成分を配合した化粧品は、肌にハリや弾力を与える効果効果を有するものの肌なじみやベタツキがのこるといった使用感に問題を有するものが殆どであった。 Conventionally, many cosmetics that give firmness and elasticity to the skin are commercially available. Cosmetics that give skin firmness and elasticity include various water-soluble polyhydric alcohols, mucopolysaccharides, and polymers that have excellent water retention and water absorption, and give skin elasticity and elasticity. There are cosmetics containing active ingredients such as plant extracts. However, most cosmetics containing these moisturizing ingredients have the effect of imparting firmness and elasticity to the skin, but most have problems with the feeling of use such as skin familiarity and stickiness.
上記のような従来の問題を解消するために、配合する保湿成分の種類や配合量において種々検討された化粧料が提案され、また、肌のハリや弾力を低下させ原因の一つであるコラゲナーゼ活性阻害効果のある成分を配合した化粧料も提案されているが、未だに肌のハリや弾力を与え、肌なじみ及び肌への伸びに優れ、かつベタツキの少ない使用感触に優れた化粧料を得るに至っていない。
本発明の課題は、肌にハリや弾力を与え、肌なじみ及び肌への伸びに優れ、しかもベタツキの少ない使用感触に優れた化粧料を提供することである。 An object of the present invention is to provide a cosmetic that gives firmness and elasticity to the skin, is excellent in familiarity with the skin and stretched to the skin, and is excellent in use feeling with little stickiness.
本発明者は、上記問題を解決するため鋭意研究を重ねた結果、ダイマージリノール酸ダイマー酸リノレイルビス（フィトステリル／ベヘニル／イソステアリル）とジェランガムとを組合せて一定量配合することで、肌にハリや弾力を与え、肌なじみ及び肌への伸びに優れ、しかもベタツキの少ない優れた使用感触が得られることを見出し、本発明の完成することに至った。 As a result of intensive studies to solve the above problems, the present inventor has formulated a certain amount of dimerlinoleic acid dimer acid linoleyl bis (phytosteryl / behenyl / isostearyl) and gellan gum, so The present inventors have found that an excellent feeling of use can be obtained that gives elasticity, is excellent in skin conformity and elongation to the skin, and has little stickiness.
即ち、ダイマージリノール酸ダイマー酸リノレイルビス（フィトステリル／ベヘニル／イソステアリル）を１重量％〜５重量％とジェランガムを０．０１重量％〜０．５重量％を組合せて配合することにより、相乗的に作用し、肌にハリや弾力を与え、肌なじみや肌への伸びに優れ、ベタツキの少ない優れた使用感触を得ることを見出し、本発明の完成することに至った。 That is, by synthesizing dimerlinoleic acid dimer linoleyl bis (phytosteryl / behenyl / isostearyl) in a combination of 1 wt% to 5 wt% and gellan gum in a combination of 0.01 wt% to 0.5 wt%. It has been found that it works, gives skin firmness and elasticity, is excellent in familiarity with the skin and stretched to the skin, and has an excellent feeling of use with little stickiness, and has led to the completion of the present invention.
本発明のダイマージリノール酸ダイマー酸リノレイルビス（フィトステリル／ベヘニル／イソステアリル）とジェランガムを組合せて一定量配合した化粧料は、肌にハリや弾力を与え、肌なじみ及び肌への伸びに優れ、しかもベタツキの少ない優れた使用感触が得られる効果併せて有する。 A cosmetic composition containing a certain amount of dimerlinoleic acid dimer acid linoleyl bis (phytosteryl / behenyl / isostearyl) and gellan gum according to the present invention gives the skin firmness and elasticity, and is excellent in skin conformance and elongation to the skin. It also has the effect of obtaining an excellent feeling of use with little stickiness.
以下、本発明をより詳しく説明する。
本発明のダイマージリノール酸ダイマー酸リノレイルビス（フィトステリル／ベヘニル／イソステアリル）は、ダイマージリノール酸ダイマー酸リノレイルビス（フィトステリル／ベヘニル／イソステアリル）であれば特に限定はされず、「Ｐｌａｎｄｏｏｌ−Ｇ」（日本精化株式会社製）等が例示できる。
Hereinafter, the present invention will be described in more detail.
The dimer linoleic acid dimer acid linoleyl bis (phytosteryl / behenyl / isostearyl) of the present invention is not particularly limited as long as it is dimer linoleic acid dimer acid linoleyl bis (phytosteryl / behenyl / isostearyl), and “Plandool-G” ( Nippon Seika Co., Ltd.) etc. can be illustrated.
本発明に用いるダイマージリノール酸ダイマー酸リノレイルビス（フィトステリル／ベヘニル／イソステアリル）の配合量は、有効であれば特に限定はされないが、１重量％〜５重量％が好ましい。また、配合量が１重量％より少なくなるとその効果が得られない場合が、５重量％を超えるとベタツキ感等が発生し使用感触が悪くなる虞がある。 The amount of dimerlinoleic acid dimer acid linoleyl bis (phytosteryl / behenyl / isostearyl) used in the present invention is not particularly limited as long as it is effective, but is preferably 1% by weight to 5% by weight. Further, when the blending amount is less than 1% by weight, the effect cannot be obtained. However, when the blending amount exceeds 5% by weight, a sticky feeling or the like may occur and the use feeling may be deteriorated.
本発明のジェランガムは、市販されているジェランガムであれば特に限定はされず、ケルコゲル（三晶株式会社，大日本住友製薬株式会社等）が例示できる。 The gellan gum of the present invention is not particularly limited as long as it is a commercially available gellan gum, and examples thereof include Kelcogel (Mishiki Co., Ltd., Dainippon Sumitomo Pharma Co., Ltd., etc.).
本発明に用いるジェランガムの配合量は、有効であれば特に限定はされないが、０．０１重量％〜０．５重量％が好ましい。また、配合量が０．０１重量％より少なくなるとその効果が得られない場合が、０．５重量％を超えるとベタツキ感等が発生し使用感触が悪くなる虞がある。 The amount of gellan gum used in the present invention is not particularly limited as long as it is effective, but is preferably 0.01% by weight to 0.5% by weight. Further, when the blending amount is less than 0.01% by weight, the effect cannot be obtained. However, when the blending amount exceeds 0.5% by weight, a sticky feeling or the like is generated, and the use feeling may be deteriorated.
本発明の化粧料には、本発明の有効性を損なわない範囲で、界面活性剤、保湿剤、高級アルコール、金属イオン封鎖剤、天然若しくは合成高分子、紫外線吸収剤、血行促進剤、各種の動植物抽出物、無機及び有機粘土鉱物、疎水化処理粉末、色剤、防腐剤、酸化防止剤、色素、増粘剤、ｐＨ調整剤、香料、冷感剤、制汗剤、殺菌剤、皮膚賦活剤、その他の薬剤等を配合することができ、液体状、乳液状、エッセンス状、クリーム状等の種々の剤型が例示できる。 In the cosmetic of the present invention, a surfactant, a moisturizer, a higher alcohol, a sequestering agent, a natural or synthetic polymer, an ultraviolet absorber, a blood circulation promoter, various kinds of agents, as long as the effectiveness of the present invention is not impaired. Animal and plant extracts, inorganic and organic clay minerals, hydrophobized powder, colorants, preservatives, antioxidants, pigments, thickeners, pH adjusters, fragrances, cooling agents, antiperspirants, fungicides, skin activation Agents, other drugs, and the like can be blended, and various dosage forms such as liquid, emulsion, essence, and cream can be exemplified.
以下、本発明を実施例及び試験例を例に挙げて詳しく説明するが、本願発明がこれらの例に限定されるものではない。 EXAMPLES Hereinafter, although an Example and a test example are given and this invention is demonstrated in detail hereafter, this invention is not limited to these examples.
ダイマージリノール酸ダイマー酸リノレイルビス（フィトステリル／ベヘニル／イソステアリル）及びジェランガムを配合した本発明の乳液の処方例及び比較例を表１及び表２に示す。
なお、乳液の製法は常法に従って行い、油相及び水相を加熱後乳化し、冷却後、試料を調製した。
Tables 1 and 2 show formulation examples and comparative examples of the emulsions of the present invention containing dimerlinoleic acid dimer acid linoleyl bis (phytosteryl / behenyl / isostearyl) and gellan gum.
The emulsion was prepared according to a conventional method, and the oil phase and the aqueous phase were emulsified after heating, and the sample was prepared after cooling.
比較例として、ダイマージリノール酸ダイマー酸リノレイルビス（フィトステリル／ベヘニル／イソステアリル）に替わる成分としてワセリン及びラノリン、ジェランガムに替わる成分としてキサンタンガム、カルボキシビニルポリマーを比較対照に試料を調製した。 As comparative examples, samples were prepared using petrolatum and lanolin as components in place of dimerlinoleic acid dimer acid linoleyl bis (phytosteryl / behenyl / isostearyl), xanthan gum and carboxyvinyl polymer as components in place of gellan gum.
また、試料の評価は専門パネラーによる官能により実施し、詳細は以下に説明する。 In addition, the evaluation of the sample is carried out by a sensuality by a specialized panelist, and details will be described below.
〔官能評価方法〕
１．官能評価項目
Ｉ塗布直後の肌のハリ感、II翌朝の肌のハリ感、III肌なじみ感、IV肌への伸び感、Ｖベタツキ感の５項目について実施した。
２．評価方法
表１及び表２に示す実施例処方及び比較例処方で作成したクリームを用い、専門女性
パネラー１０名に試料をランダムに使用させる方法を用いた。詳細には、１つの試料について毎日就寝前に連続３日間適量を顔面に塗布し、塗布直後の肌のハリ感、翌朝の肌のハリ感、塗布時の肌へのなじみ感、塗布時のクリームの伸び、塗布後のベタツキの５項目について５段階で自己採点し、評価とした。そして、１０名の平均を４段階に分け評価値とした。評価内容を表３に、実施例及び比較例の評価を表４に示す。なお、本評価を実施する際、皮膚刺激等の肌トラブル等は全くなかった。
[Sensory evaluation method]
1. Sensory evaluation item I was carried out on 5 items of skin firmness immediately after application, II next morning skin firmness, III skin familiarity, IV skin stretch feeling, and V stickiness.
2. Evaluation method Using creams prepared in the example formulations and comparative example formulations shown in Tables 1 and 2, a method was used in which 10 professional female panelists randomly used samples. In detail, an appropriate amount is applied to the face for 3 consecutive days before going to bed for each sample, and the skin feels immediately after application, the skin feeling of the next morning, the feeling of familiarity to the skin at the time of application, the cream at the time of application The five items of elongation and stickiness after coating were self-scored in five stages for evaluation. And the average of 10 persons was divided into 4 grades and used as evaluation values. Table 3 shows the evaluation contents, and Table 4 shows the evaluation of the examples and comparative examples. In conducting this evaluation, there were no skin problems such as skin irritation.
表４より、本発明である実施例１〜実施例６は、比較例と比べ、塗布直後の肌のハリ感、翌朝の肌のハリ感、塗布時の肌へのなじみ感、塗布時のクリームの伸び、塗布後のベタツキの５項目全てに優れていることが判明した。また、各比較例の結果より、ダイマージリノール酸ダイマー酸リノレイルビス（フィトステリル／ベヘニル／イソステアリル）に替えて他の成分とジェランガムを組合せ配合した場合やジェランガムに替えて他の高分子を配合した場合やダイマージリノール酸ダイマー酸リノレイルビス（フィトステリル／ベヘニル／イソステアリル）及びジェランガムの配合量を本発明で示す特定量より多く又は少なく配合した場合においても、塗布直後の肌のハリ感、翌朝の肌のハリ感、塗布時の肌へのなじみ感、塗布時のクリームの伸び、塗布後のベタツキの５項目全てにおいて満足できる結果は得られなかった。このことは、ダイマージリノール酸ダイマー酸リノレイルビス（フィトステリル／ベヘニル／イソステアリル）及びジェランガムの組合せが特異的であり、相乗的作用し、肌のハリ感、肌なじみ感、肌への伸び及びベトツキ感の全ての使用感に関係し、全てを向上させていることを意味している。 From Table 4, Examples 1 to 6 according to the present invention, compared with the comparative example, the firmness of the skin immediately after application, the firmness of the skin the next morning, the familiarity to the skin at the time of application, the cream at the time of application It was found that all five items of elongation and stickiness after coating were excellent. Also, from the results of each comparative example, when dimerinolinoleic acid dimer acid linoleyl bis (phytosteryl / behenyl / isostearyl) is combined with other ingredients and gellan gum, or when other polymers are blended instead of gellan gum Even when the blending amount of dimerlinoleic acid dimer linoleyl bis (phytosteryl / behenyl / isostearyl) and gellan gum is greater or less than the specific amount shown in the present invention, the firmness of the skin immediately after application, Satisfactory results could not be obtained for all five items of firmness, familiarity to the skin during application, cream elongation during application, and stickiness after application. This is because the combination of dimerlinoleic acid dimer acid linoleyl bis (phytosteryl / behenyl / isostearyl) and gellan gum acts synergistically, and the skin feels smooth, familiar to the skin, stretches to the skin and feels sticky. It is related to all feelings of use and means that everything is improved.
本発明のダイマージリノール酸ダイマー酸リノレイルビス（フィトステリル／ベヘニル／イソステアリル）とジェランガムを組合せて一定量配合した化粧料は、肌にハリを与え、肌なじみ及び肌への伸びに優れ、しかもベタツキの少ない優れた使用感触が得られる効果併せて有するため、広く化粧料に応用が期待できる。 A cosmetic comprising a combination of dimerlinoleic acid dimer acid linoleyl bis (phytosteryl / behenyl / isostearyl) and gellan gum according to the present invention gives the skin firmness, is excellent in skin familiarity and extension to the skin, and is also smooth. Since it has the effect of obtaining a few excellent use feelings, it can be widely applied to cosmetics.
Claims (1)
フィトステリル／ ベヘニル／ イソステアリル）
の配合量が１ 重量％ 〜５ 重量％ であることを特徴とする化粧料。
The gellan gum content is 0. 0 1 wt% to 0. 5% by weight, dimer linoleic acid dimer acid linoleyl bis (
Phytosteryl / behenyl / isostearyl)
A cosmetic material characterized in that the blending amount of is 1% by weight to 5% by weight.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006100248A JP4896566B2 (en) | 2006-03-31 | 2006-03-31 | Cosmetics |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006100248A JP4896566B2 (en) | 2006-03-31 | 2006-03-31 | Cosmetics |
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| Publication Number | Publication Date |
|---|---|
| JP2007269746A JP2007269746A (en) | 2007-10-18 |
| JP4896566B2 true JP4896566B2 (en) | 2012-03-14 |
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| JP2006100248A Active JP4896566B2 (en) | 2006-03-31 | 2006-03-31 | Cosmetics |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP5700222B2 (en) | 2009-10-26 | 2015-04-15 | 日産化学工業株式会社 | Cosmetics, external preparation for skin, and medical equipment |
| EP2550954B1 (en) * | 2010-03-25 | 2020-03-04 | The Nisshin OilliO Group, Ltd. | Vaseline-like composition, and cosmetic preparation |
| WO2013101171A1 (en) * | 2011-12-30 | 2013-07-04 | L'oreal | Compositions containing an acrylic film former, a tackifier and an ester |
| JP6124746B2 (en) * | 2013-09-20 | 2017-05-10 | 株式会社ノエビア | Oil-in-water emulsified cosmetic |
| JP6986329B2 (en) * | 2015-06-16 | 2021-12-22 | クラシエホームプロダクツ株式会社 | Wrinkle-relieving skin cleanser |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JPS62114905A (en) * | 1985-11-12 | 1987-05-26 | San Ei Chem Ind Ltd | Cosmetic |
| JP3802227B2 (en) * | 1998-04-10 | 2006-07-26 | 大日本住友製薬株式会社 | Cosmetics |
| JP2001131016A (en) * | 1999-08-23 | 2001-05-15 | Shiseido Co Ltd | Composition for external use |
| JP3881607B2 (en) * | 2002-09-26 | 2007-02-14 | 株式会社コーセー | Cosmetics |
| JP4331584B2 (en) * | 2003-02-04 | 2009-09-16 | 日本精化株式会社 | Oily base and cosmetics and skin external preparations containing the same |
| JP4589050B2 (en) * | 2003-12-22 | 2010-12-01 | 日本精化株式会社 | Diesters and oils, and cosmetics and skin external preparations |
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2006
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