JP4861930B2 - Ultra-high strength high-fluidity cement composition and ultra-high-strength high-fluidity cement hardened material - Google Patents

Description

The present invention relates to an ultra-high-strength high-fluidity cement composition and a super-high-strength high-fluidity cement hardened body, and more specifically, has high strength development and high fluidity compared to conventional cement compositions, An ultra-high-strength and high-fluidity cement composition capable of obtaining a compressive strength exceeding 200 N / mm ² in an ultra-high-strength region where the water binder ratio is 18.0% or less, and this ultra-high-strength and high-fluidity The present invention relates to an ultra-high-strength, high-fluidity cement cured material obtained by kneading a cement composition with water and curing it.

In general, the compressive strength of a mortar product, a concrete structure or the like greatly depends on the quality of aggregates contained therein, particularly the quality of fine aggregates. Normally, natural river sand, mountain sand (land sand), sea sand, crushed sand, etc. are used as fine aggregates, but the problem of large variations in quality depending on the production area, host rock type, lot, etc. can be avoided. Absent. In particular, in a very high strength area where the compressive strength exceeds 200 N / mm ² , if poor quality fine aggregate is mixed into the specimen or structure, etc., the quality of the fine bone will be reduced when external stress is applied. Stress concentrates on the part including the material and breaks at a strength lower than the strength that should be exhibited (expected), that is, a fine aggregate with poor quality becomes a structural defect.

Similarly, the fluidity of the cement composition contained in mortar, ready-mixed concrete, etc. is greatly influenced by physical properties such as fine aggregate density, particle shape, maximum particle size, particle size distribution, and water absorption rate. When produced fine aggregate is used, the fluidity of the cement composition depends greatly on the quality of the fine aggregate used.
Therefore, blast furnace slag fine aggregate, ferrochrome slag fine aggregate, ferronickel slag fine aggregate, copper slag fine aggregate, as fine aggregate with high crushing strength (hardness) and wear resistance and stable quality, Various techniques using slag fine aggregate such as electric furnace oxidation slag have been proposed.

  For example, ultra-fine powder such as hydraulic substance (cement), silica dust (silica fume) and siliceous dust, high-performance water reducing agent, ferrochrome slag pulverized product pulverized to a particle size of about 5 mm or less, and ultra-high Strong aggregate composition (Patent Document 1), fine aggregate composed of slag spheres or slag subspheres, part or all of fine aggregates used as a constituent material of concrete or mortar by kneading with cement and water ( Patent Document 2), a ferroalloy slag made of ferroalloy slag such as ferrochrome slag, ferronickel slag, silicon manganese slag, ferromanganese slag, etc., which is crushed into a diameter of 5 mm or less and mixed with sand to form a concrete aggregate. Method of use (Patent Document 3), Ferronickel slag produced by air-crushing method with a particle size of 2.5 mm And a fine aggregate for high fluidity concrete (patent document 4) prepared by mixing the mixture ratio in the fine aggregate to 30% or more, a fine mineral powder consisting of a fine natural powder or a fine artificial mineral powder, And a mortar and concrete composition excellent in fluidity and strength expression using a fine aggregate lacking fine particles such as ferronickel slag fine aggregate having a particle size of 0.3 to 5 mm (Patent Document 5), cement, A high-strength mortar composition (Patent Document 6) composed of granular cement clinker, water reducing agent, aggregate having a specific gravity of 2.7 or more, ultrafine powder, and the like has been proposed.

According to these technologies, mortar or concrete excellent in strength and fluidity can be obtained, and ferroalloy slag such as ferrochrome slag, ferronickel slag, silicon manganese slag, ferromanganese slag, etc., which has been limited in use until now, can be obtained. There is an effect that it can be effectively used as a fine aggregate.
Japanese Patent No. 2653402 Japanese Patent Laid-Open No. 5-32439 Japanese Patent Laid-Open No. 5-262542 JP-A-8-325047 Japanese Patent Laid-Open No. 9-52744 JP 2005-119885 A

By the way, in the conventional well-known technique, since all the fine aggregates have a maximum particle size of 2.5 to 5 mm or have been subjected to a special spheroidizing treatment, these fine aggregates are used. The hardened body obtained by curing and curing the cement composition in an ultra-high strength region with a water binder ratio of 18.0% or less is not sufficient to obtain a compressive strength exceeding 200 N / mm ^2. There was a problem that.

The present invention has been made to solve the above-described problems, and has high strength development and high fluidity as compared with conventional cement compositions, and the water binder ratio is 18.0% or less. An object of the present invention is to provide an ultra-high strength and high fluidity cement composition and an ultrahigh strength and high fluidity cement cured body that can obtain a compressive strength exceeding 200 N / mm ² even in the ultrahigh strength region.

The present inventors have conducted extensive studies to solve the above problem results, more than 10% by weight of cement and 30% by weight or less specific surface area by BET method of 1 m 2 ^{/ g} or more and 20 m 2 / ^g or less of A hydraulic binder substituted with siliceous fine powder and an artificial high-density fine aggregate having a maximum particle size of 1.2 mm or less, an absolute dry density of 2.90 g / cm ³ or more, and a water absorption of 0.90% or less And a cement composition containing a chemical admixture, kneaded with water at a water binder ratio of 18.0% or less and cured, and an ultra-high strength and high fluidity cement having a compressive strength of 200 N / mm ² or more. The present inventors have found that a cured product can be easily obtained and have completed the present invention.

In other words, ultra high strength and high fluidity cement composition of the present invention, cement 10 wt% or more and 30 wt% or less specific surface area by BET method of 1 m 2 ^{/ g} or more and 20 m 2 / ^g or less siliceous fine powder Chemically mixed with the hydraulic binder replaced with the above, a high-density fine aggregate with a maximum particle size of 1.2 mm or less, an absolute dry density of 2.90 g / cm ³ or more, and a water absorption of 0.90% or less. It is characterized by containing an agent.

The artificial high-density fine aggregate is preferably one or more selected from the group of ferronickel slag fine aggregate, copper slag fine aggregate, and electric furnace oxidized slag fine aggregate.
The unit volume of the artificial high-density fine aggregate is preferably 180 L / m ³ or more and 350 L / m ³ or less.
The unit volume of the hydraulic binder is preferably 400 L / m ³ or more and 600 L / m ³ or less.

The ultra-high-strength high-fluidity cement hardened body of the present invention is an ultra-high-strength high-fluidity cement composition obtained by kneading and curing the ultra-high-strength high-fluidity cement composition of the present invention with water at a water binder ratio of 18.0% or less. The compressible strength of this ultra-high strength, high-fluidity cement cured body is 91 days at 20 ° C., and 7 days at 50 ° C. or more and 80 ° C. or less for 7 days. When cured, it is 200 N / mm ² or more.

According to ultra high strength and high fluidity cement composition of the present invention, more than 10% by weight of cement and 30% by weight or less specific surface area by the BET method 1 m 2 ^{/ g} or more and 20 m 2 / ^g or less siliceous fine powder Chemically mixed with the hydraulic binder replaced with the above, a high-density fine aggregate with a maximum particle size of 1.2 mm or less, an absolute dry density of 2.90 g / cm ³ or more, and a water absorption of 0.90% or less. Therefore, compared with the conventional cement composition, it has excellent strength development and fluidity.
Further, in the ultra-high strength region where the water binder ratio is 18.0% or less, a compressive strength exceeding 200 N / mm ² can be obtained, and the compressive strength is superior to the conventional cement composition. ing.

According to the ultra-high-strength and high-fluidity cement cured body of the present invention, ultra-high-strength and high-temperature when cured at any one of conditions of 91 days at 20 ° C. and 7 days at 50 ° C. or more and 80 ° C. or less. Since the compressive strength of the hardened fluid cement is 200 N / mm ² or more, a compressive strength exceeding 200 N / mm ² can be easily obtained even in an ultrahigh strength region where the water binder ratio is 18.0% or less. . In addition, the compressive strength can be maintained over a long period of time, so that the long-term reliability is excellent.
Therefore, it is possible to provide an ultra-high-strength, high-fluidity cement hardened body that is superior in compressive strength and long-term reliability compared to conventional cement hardened bodies.

The best mode of the ultrahigh strength and high fluidity cement composition and the ultrahigh strength and high fluidity cement cured product of the present invention will be described with reference to the drawings.
The present embodiment is specifically described for better understanding of the gist of the invention, and does not limit the invention unless otherwise specified.

Ultra high strength and high fluidity cement composition of the present embodiment, more than 10% by weight of cement and 30% by weight or less specific surface area by BET method of 1 m 2 ^{/ g} or more and 20 m 2 / ^g or less siliceous fine powder in Substituted hydraulic binder, artificial high density fine aggregate with maximum particle size of 1.2 mm or less, absolute dry density of 2.90 g / cm ³ or more and water absorption of 0.90% or less, and chemical admixture And a cement composition comprising:

Here, the ultra-high strength and high fluidity cement composition of the present embodiment will be described in detail.
As cement, normal, moderate heat, low heat, early strength, super early strength, sulfate-resistant portland cement, blast furnace cement, fly ash cement, silica cement and other mixed cements, alumina cement, jet cement and other super fast curing Examples thereof include cement and erwin cement.
From these various cements, it is possible to select one type, or to select and mix two or more types in consideration of specifications and prices required for cement compositions such as mortar and ready-mixed concrete. it can.

In order to obtain the ultra-high strength and high fluidity cement composition of the present embodiment, low heat Portland cement containing a large amount of belite (C ₂ S: 2CaO · SiO ₂ / dicalcium silicate) A content of 40% or more) and moderately hot Portland cement are particularly preferable.

The siliceous fine powder is for replacing 10% by weight or more and 30% by weight or less of the total amount of the above cement, and has a specific surface area of 1 m ² / g or more and 20 m ² / g or less by the BET method. Silica fine powder, for example, zirconia-derived siliceous fine powder produced as a by-product when producing electrofused zirconia, silica fume produced as a by-product when producing silicon or ferrosilicon, silica glass Siliceous fine powder produced as a by-product during production, amorphous siliceous fine powder synthesized from silicon or silicon dioxide, fly ash classified or finely pulverized to a particle size of 10 μm or less to enhance pozzolanic activity, etc. Is mentioned.

From these various siliceous fine powders, in consideration of the specifications and price required for ultra-high strength and high fluidity cement composition, select one type, or select and mix two or more types. Can do.
In particular, as a siliceous fine powder suitable for the ultrahigh strength and high fluidity cement composition of the present embodiment, the SiO ₂ content is 85% or more and the specific surface area by the BET method is 1 m ² / g or more and 20 m ² / g. The following zirconia-derived siliceous fine powder and silicon-derived silica fume are particularly mentioned.

The substitution rate of the siliceous fine powder with respect to the cement is preferably 10% by weight or more and 30% by weight or less, and more preferably 10% by weight or more and 20% by weight or less in the total amount of the cement.
This is because when the substitution rate of the siliceous fine powder with respect to the cement is out of the above range, it becomes difficult to maintain the cement hardened body at 200 N / mm ² or more when the cement hardened body is used. In some cases, kneading becomes difficult and the practicality is greatly reduced.

The hydraulic binder is a combination of the cement and the siliceous fine powder, and the unit volume of the hydraulic binder in the cement composition of the present embodiment is 400 L / m ³ or more and 600 L / m ³ or less. , more preferably 500L / ^{m 3} or more and 550L / ^{m 3} or less.
This is because when the unit volume of the hydraulic binder is out of the above range, it becomes difficult to maintain the cement hardened body with a compressive strength of 200 N / mm ² or more. In some cases, kneading becomes difficult and the practicality is greatly reduced.

Artificial high-density fine aggregate is a fine aggregate for imparting ultra-high strength and high fluidity, has high hardness and excellent wear resistance, has a maximum particle size of 1.2 mm or less, and an absolutely dry density. An artificial high-density fine aggregate having 2.90 g / cm ³ or more and a water absorption rate of 0.90% or less, preferably 0.70% or less is suitably used.
Here, if any one of the maximum particle size, the absolute dry density, and the water absorption rate of the artificial high-density fine aggregate is out of the above range, the cement composition containing the artificial high-density fine aggregate is made into a hardened cement body. In this case, the compressive strength or fluidity is greatly reduced, which is not preferable.

Unit volume in the cement compositions of the artificial dense fine aggregate is preferably 180L / ^{m 3} or more and 350L / ^{m 3} or less, and more preferably not more than 200L / ^{m 3} or more and 250L / ^{m 3.}
If the unit volume of the artificial high-density fine aggregate is out of the above range, when it is a cement hardened body, its compressive strength is lowered and it becomes difficult to keep it at 200 N / mm ² or more. In some cases, kneading becomes difficult and the practicality is greatly reduced.

  As this artificial high-density fine aggregate, for example, ferronickel slag fine aggregate (Japanese Industrial Standard JIS A 501-2-2 FNS1.2 compliant product), copper slag fine aggregate (Japanese Industrial Standard JIS A 5011-3 CUS1.2 compliant product), electric furnace oxidation slag fine aggregate (Japan Industrial Standard JIS A 5011-4 EFS1.2 N or H compliant product) Can be used.

As the chemical admixture, a general polycarboxylic acid-based high performance AE water reducing agent having a high water reduction rate is preferably used, and it is preferable to use a defoaming agent such as a polyoxyalkylene alkyl ether if necessary. .
The addition amount of this polycarboxylic acid-based high-performance AE water reducing agent is appropriately adjusted according to the target fluidity of the cement composition, but as a general addition amount, hydraulic property consisting of cement and siliceous fine powder is used. It is preferable to add in the range of 0.5 wt% or more and 4.0 wt% or less with respect to the total amount of the binder.

The amount of antifoaming agent added is appropriately adjusted according to the target air amount of the cement composition, but the general amount added is the total amount of hydraulic binder made of cement and siliceous fine powder. It is preferable to add in the range of 0.01% by weight or more and 0.1% by weight or less.
Moreover, as this chemical admixture, either powder form or liquid form can be used. In particular, a powdery material is preferable because it can be premixed with cement or the like.

  In addition, in order to add various performances to the cement composition of the present embodiment, expansion material, shrinkage reducing agent, synthetic resin powder, synthetic resin fiber, metal fiber, carbon fiber, glass fiber, polymer, monomer, oligomer, limestone You may add 1 type, or 2 or more types selected from the group of a fine powder, a fluidizing agent, a setting accelerator, and a setting retarder.

Next, the ultra-high-strength and high-fluidity cement hardened body of this embodiment will be described.
The ultra-high strength and high-fluidity cement hardened body of the present embodiment is an ultra-high strength obtained by kneading and curing the ultra-high-strength and high-fluidity cement composition of the present embodiment with water at a water binder ratio of 18.0% or less. It is a high strength fluidity cement hardened body, and the compressive strength of this ultrahigh strength high fluidity cement hardened body is any one of 91 days at 20 ° C. ± 1 ° C. and 7 days at 50 ° C. or higher and 80 ° C. or lower. It is a cured product that is 200 N / mm ² or more when cured under the above conditions.

The water binder ratio, that is, the weight ratio between the hydraulic binder made of cement and siliceous fine powder and the mixing water (the chemical admixture is regarded as water) is preferably 18.0 or less.
Here, the reason for setting the water binder ratio of the ultra-high strength and high fluidity cement composition to 18.0% or less is that when the water binder ratio exceeds 18.0%, the ultra-high strength and high fluidity cement composition. This is because the compressive strength of the ultra-high strength and high fluidity cement cured material obtained by kneading the composition with water and curing is less than 200 N / mm ² .

This ultra-high strength and high fluidity cement composition was kneaded with water at a water binder ratio of 18.0% or less, and the resulting mortar or ready-mixed concrete was subjected to 50 ° C. or more and 80 ° C. or less at 20 ° C. for 91 days. Is cured under any of the conditions for 7 days to obtain an ultra-high-strength, high-fluidity cement cured material.
The compressive strength of the ultra-high-strength, high-fluidity cementitious body thus obtained always maintains 200 N / mm ² or more.

EXAMPLES Hereinafter, although an Example , a reference example, and a comparative example demonstrate this invention concretely, this invention is not limited by these Examples.

The following were used as cement, siliceous fine powder, artificial high-density fine aggregate, chemical admixture, antifoaming agent and water used in Examples , Reference Examples and Comparative Examples.
"cement"
Low heat Portland cement (C ₂ S content 56%, absolute dry density 3.24 g / cm ³ , Blaine specific surface area 3300 cm ² / g, manufactured by Sumitomo Osaka Cement Co., Ltd.) (hereinafter abbreviated as LC)

"Silica fine powder A"
Zirconia-derived siliceous fine powder: SF-SILICAFUME (SiO ₂ content 94.7%, absolute dry density 2.26 g / cm ³ , BET specific surface area 9.1 m ² / g, manufactured by Sakai Kogyo Co., Ltd.) , Abbreviated as ZSF)
"Silica fine powder B"
Silicon-derived silica fume: Microsilica 940-U (SiO ₂ content 94.4%, absolute dry density 2.20 g / cm ³ , BET specific surface area 17.6 m ² / g, manufactured by Elchem Japan Co., Ltd.) (Abbreviated as SF)

"Artificial high-density fine aggregate A"
1.2 mm ferronickel slag fine aggregate (JIS A 5011-2 FNS 1.2 compliant product, maximum particle size 1.2 mm or less, absolute dry density 3.01 g / cm ³ , water absorption 0.7%, FM: 2 .21) (hereinafter abbreviated as FNS1.2)
"Artificial high-density fine aggregate B"
5 mm ferronickel slag fine aggregate (JIS A 501-2 FNS5 compliant product, maximum particle size 5 mm or less, absolute dry density 2.97 g / cm ³ , water absorption 0.9%, FM: 2.47) (hereinafter, (Abbreviated as FNS5)
"Artificial high density fine aggregate C"
1.2 mm copper slag fine aggregate (JIS A 5011-3 CUS1.2 compliant product, maximum particle size 1.2 mm or less, absolute dry density 3.35 g / cm ³ , water absorption 0.9%, FM: 2. 24) (hereinafter abbreviated as CUS1.2)

"Artificial high-density fine aggregate D"
5 mm copper slag fine aggregate (JIS A 5011-3 CUS5 compliant product, maximum particle size 5 mm or less, absolute dry density 3.30 g / cm ³ , water absorption 1.2%, FM: 2.64) (hereinafter, CUS5 Abbreviated)
"Artificial high density fine aggregate E"
1.2mm electric furnace oxidized slag fine aggregate (JIS A 5011-4 EFS1.2N compliant product, maximum particle size 1.2mm or less, absolute dry density 3.52g / cm ³ , water absorption 1.0%, FM: 2.89) (hereinafter abbreviated as EFS1.2)
"Artificial high density fine aggregate F"
5mm electric furnace oxidation slag fine aggregate (JIS A 5011-4 EFS5N compatible product, maximum particle size 5mm or less, absolute dry density 3.49g / cm ³ , water absorption 1.7%, FM: 3.10) (below , Abbreviated as EFS5)

"Natural fine aggregate G"
Aichi Prefecture dry silica sand No. 4 and No. 7 mixed sand (maximum particle size 1.2 mm or less, absolute dry density 2.66 g / cm ³ , water absorption 0.7%, FM: 2.46) (hereinafter SS1. (Abbreviated as 2)
"Natural fine aggregate H"
Chiba Prefecture mountain sand (maximum particle size 1.2 mm or less, absolute dry density 2.56 g / cm ³ , water absorption 2.28%, FM: 2.18) (hereinafter abbreviated as HS 1.2)

`` Chemical admixture ''
Polycarboxylic acid-based high-performance AE water reducing agent: SEICAMENT 1200N (manufactured by Nippon SEICA Co., Ltd.) (hereinafter abbreviated as SP)
"Antifoaming agent"
Seeker Anti-Form W (Nihon Seeca Co., Ltd.)
"water"
Tap water

Using the cement, siliceous fine powder, artificial high-density fine aggregate, chemical admixture, antifoaming agent and water, ultrahigh strength and high fluidity mortars of Examples , Reference Examples and Comparative Examples were prepared.
Tables 1 and 2 show the compositions of the ultrahigh strength and high fluidity mortars of Examples , Reference Examples and Comparative Examples.
In these ultra-high strength and high fluidity mortars, the unit water volume is a constant value of 220 kg / m ³ in all compositions, the target air volume is a constant value of 2%, and the unit volume of fine aggregate is as follows: did.

In Examples 1, 2, Reference Example 1 and Comparative Examples 1-5, the substitution rate of siliceous fine powder (ZSF) was 20%, and the unit volume of fine aggregate was 221 L / m ³ .
In Comparative Example 6, the substitution rate of siliceous fine powder (ZSF) was 5%, and the unit volume of the fine aggregate was 254 L / m ³ .
In Comparative Example 7, the substitution rate of siliceous fine powder (ZSF) was 35%, and the unit volume of the fine aggregate was 201 L / m ³ .
In Example 3 , the substitution rate of siliceous fine powder (ZSF) was 20%, and the unit volume of the fine aggregate was 340 L / m ³ .
In Comparative Example 8, the substitution rate of siliceous fine powder (ZSF) was 20%, and the unit volume of fine aggregate was 392 L / m ³ .

In Examples 4 and 5, Reference Example 2 and Comparative Examples 9 to 13, the substitution rate of siliceous fine powder (SF) was 10%, and the unit volume of fine aggregate was 241 L / m ³ .
In Comparative Example 14, the substitution rate of the siliceous fine powder (SF) was 5%, and the unit volume of the fine aggregate was 253 L / m ³ .
In Comparative Example 15, the substitution rate of siliceous fine powder (SF) was 35%, and the unit volume of fine aggregate was 194 L / m ³ .
In Comparative Example 16, the substitution rate of the siliceous fine powder (SF) was 10%, and the unit volume of the fine aggregate was 404 L / m ³ .
In addition, about the high performance AE water reducing agent and the antifoaming agent, it considered that it was mixing water and correct | amended the water quantity.

Next, a kneading test of each of the ultrahigh strength and high fluidity mortars of Examples 1 to 5, Reference Examples 1 and 2, and Comparative Examples 1 to 16 was performed.
For Examples 1 to 3, Reference Example 1 and Comparative Examples 1 to 8, the cement, siliceous fine powder (ZSF), and fine aggregate were placed in a constant temperature room at 20 ° C. to have the composition shown in Table 1. Put into a 10 L mortar mixer and knead for 15 seconds, then add mixing water, high-performance AE water reducing agent and antifoaming agent so as to have the composition shown in Table 1 and knead for 120 seconds. Then, the kneading was further performed for 120 seconds.
Moreover, about Example 4, 5, Reference Example 2, and Comparative Examples 9-16, a composition shall be shown in Table 2 and this kneading was made into 300 second, Example 1-3, Reference Example 1, and a comparison Same as Examples 1-8.
In Examples 1 to 5, Reference Examples 1 and 2, and Comparative Examples 1 to 16, the mixing amount of one batch was set to 5.5 L (constant).

  Immediately after the kneading, the mortar flow is measured in accordance with Japanese Industrial Standard JIS R 5201 “Cement physical test method”, and the flow of the mortar is measured by measuring the zero striking flow that does not give 15 drop motions after pulling up the flow cone. evaluated.

In addition, each of Examples 1 to 5, Reference Examples 1 and 2, and Comparative Examples 1 to 16 was cured and cured under certain conditions, and the compressive strength was measured.
Twenty-four cylindrical specimens each having a diameter of 50 mm and a height of 100 mm were produced as specimens for measurement. The prepared specimen was sealed with a vinyl film and a rubber band until immediately before demolding in order to prevent water from evaporating and sealed and cured in a constant temperature room at 20 ° C. until the age of 2 days.
18 of the produced specimens were demolded at 2 days of material age, and were subjected to standard curing in water at 20 ° C. until a predetermined material age. The remaining 6 pieces were immersed in 70 ° C warm water together with the formwork with the specimen head sealed from the second day of material age, heat-cured, removed from the warm water at the age of seven days, and released to room temperature in the air. After cooling, the mold was removed.

  The compressive strength of the mortar was measured according to Japanese Industrial Standard JIS A 1108 “Concrete Compression Test Method”. Here, the number of specimens of one material age was six, and the coefficient of variation was calculated from the compression strength data of the six specimens measured. In addition, the age of the material for measuring the compressive strength was set to three types of days for standard curing, 7, 28, and 91 days, and when heated at 70 ° C., the age was set to 7 days. In addition, about all the test bodies, both end surfaces were grind | polished just before performing a compression test.

The results of measurement of zero stroke flow and compressive strength of each of Examples 1 to 3, Reference Example 1 and Comparative Examples 1 to 8 are shown in Table 3, and each of Examples 4, 5, Reference Example 2 and Comparative Examples 9 to 16 are each subjected to 0 stroke. The measurement results of flow and compressive strength are shown in Table 4, respectively.

According to these measurement results, in Examples 1 and 2 and Reference Example 1 , the fluidity of the obtained mortar is very good, and the compressive strength is also 223 to 232 N / mm at the age of 91 days at 20 ° C. standard curing. ² , It was very favorable with 229-247 N / mm < ² > in the age 7 days of 70 degreeC heat curing. In particular, the compressive strength of Example 1 using FNS 1.2 was the highest.
On the other hand, in Comparative Examples 1 to 3, the mortar fluidity was the same as or slightly inferior to Examples 1 and 2 and Reference Example 1 , but the compressive strength was lower than that of Examples 1 and 2 and Reference Example 1 . Moreover, since Comparative Example 4 used quartz sand and Comparative Example 5 used mountain sand, both the fluidity and compressive strength of the mortar were significantly lower than those of Examples 1 and 2 and Reference Example 1 .
In Comparative Example 6, since the substitution rate of the siliceous fine powder (ZSF) was 5% by weight, the mortar could not be kneaded under the present test conditions.
In Comparative Example 7, since the substitution rate of the siliceous fine powder (ZSF) was 35% by weight, the flowability of the mortar was equivalent to that of Example 1, but the compressive strength was lower than that of Example 1.

In Example 3 , the water binder ratio was 18.0%, and the substitution rate of siliceous fine powder (ZSF) was 20% by weight. The flowability of the mortar was the same as in Examples 1 and 2 and Reference Example 1 . Equivalently, the compressive strength was lower than those of Examples 1 and 2 and Reference Example 1 , but it exceeded 200 N / mm ² at the age of 91 days of standard curing at 20 ° C and the age of 7 days of heating curing at 70 ° C. The compression strength after curing was excellent.
On the other hand, in Comparative Example 8, the water binder ratio was 20.0%, the substitution rate of the siliceous fine powder (ZSF) was 20% by weight, and the fluidity of the mortar was equivalent to that of Example 1, The compressive strength was remarkably lower than that of Example 1, and was below 200 N / mm ² in both the standard curing age of 91 days at 20 ° C. and the heating curing age of 7 days at 70 ° C.

Moreover, when substituted using siliceous fine powder (SF), in Examples 4, 5 and Reference Example 2 , the fluidity of the obtained mortar is good, and the age of standard curing at 20 ° C. In 91 days, it was 201-208 N / mm < ² >, and it was 206-218 N / mm < ² > as favorable in the age of 7 days of the heat curing at 70 degreeC. In particular, the compressive strength of Example 4 using FNS 1.2 was the highest.
On the other hand, in Comparative Example 9 to 11, although the fluidity of the resulting mortar was much inferior equal to or slightly and Examples 4, 5 and Reference Example 2, compression strength than Examples 4, 5 and Reference Example 2 It was low.
Further, since Comparative Example 12 used silica sand and Comparative Example 13 used mountain sand, both the fluidity and compressive strength of the mortar were lower than those of Examples 4 and 5 and Reference Example 2 .

In Comparative Example 14, the substitution rate of siliceous fine powder (SF) was 5% by weight, and in Comparative Example 15 the substitution rate of siliceous fine powder (SF) was 35% by weight. I couldn't work out.
In Comparative Example 16, the water binder ratio was 20.0% and the substitution rate of the siliceous fine powder (SF) was 10% by weight. The flowability of the mortar was the same as that of Example 4 , but the compressive strength Was significantly lower than that of Example 4 , and was lower than 200 N / mm ² in both the age of the standard curing at 20 ° C. and the age of 7 in the heating curing at 70 ° C.

As explained above, mortar using artificial high-density fine aggregate (ferronickel slag fine aggregate, copper slag fine aggregate, electric furnace oxidized slag fine aggregate) with a maximum particle size of 1.2 mm has the maximum particle size. Fluidity and compressive strength superior to mortar using 5 mm artificial high-density fine aggregate or natural fine aggregate (silica sand, mountain sand) with a maximum particle size of 1.2 mm are obtained, and the coefficient of variation of compressive strength is greatly increased. It turned out to be small.
In addition, when the substitution rate of the siliceous fine powder (ZSF, SF) with respect to the cement is less than 10% by weight or more than 30% by weight, the decrease in the compressive strength of the cement composition is large or mixing becomes difficult. It turned out that practicality falls significantly.
Furthermore, in order for the compressive strength to exceed 200 N / mm ² in both the age of standard curing at 20 ° C. and the age of heat curing at 70 ° C., the water binder ratio is 18.0% or less. Was found to be an essential requirement.

Claims (5)

A hydraulic binder that the specific surface area by 10% or more by weight and the BET method of 30 wt% or less has been replaced with a ^{1 m} 2 / g or more and ^{20 m} 2 / g or less siliceous fine powder cement, the maximum particle size of 1. Super high strength and high strength characterized by containing an artificial high density fine aggregate having a thickness of 2 mm or less, an absolute dry density of 2.90 g / cm ³ or more and a water absorption of 0.90% or less, and a chemical admixture. Flowable cement composition.   The artificial high-density fine aggregate is one or more selected from the group consisting of ferronickel slag fine aggregate, copper slag fine aggregate, and electric furnace oxidized slag fine aggregate. 2. The ultrahigh strength and high fluidity cement composition according to 1. ^3. The ultrahigh strength and high fluidity cement composition according to claim 1, wherein a unit volume of the artificial high-density fine aggregate is 180 L / m ³ or more and 350 L / m ³ or less. 4. The ultrahigh strength and high fluidity cement composition according to claim 1, wherein a unit volume of the hydraulic binder is 400 L / m ³ or more and 600 L / m ³ or less. An ultra-high-strength, high-fluidity cement hardened body obtained by kneading and curing the ultra-high-strength, high-fluidity cement composition according to any one of claims 1 to 4 with water at a water binder ratio of 18.0% or less. Because
The compressive strength of this ultra-high-strength, high-fluidity cementitious cement is 200 N / mm ² or more when cured under any conditions of 91 days at 20 ° C., 7 days at 50 ° C. or more and 80 ° C. or less. An ultra-high-strength, high-fluidity cementitious cement that is characterized by