JP4832931B2 - Method for producing sintered electrode for cold cathode tube - Google Patents

Description

  The present invention relates to a method for producing a sintered electrode for a cold cathode tube.

Conventionally, a sintered electrode for a cold cathode tube and a cold cathode tube including the electrode have been used as a backlight of a liquid crystal display device, for example. Such a cold cathode tube for liquid crystal has high brightness,
In addition to high efficiency, long life is required.
In general, a cold-cathode tube useful as a backlight for liquid crystal is filled with a trace amount of mercury and a rare gas in a glass tube coated with a phosphor on the inner surface, and lead wires and lead rods (for example, KOV) are provided at both ends of the glass tube. (Foil + refractory metal lead-in wire + jumet wire). In such a cold-cathode tube, when the voltage is applied to the electrodes at both ends, mercury enclosed in the glass tube evaporates and emits ultraviolet rays, and the phosphor that absorbs the ultraviolet rays emits light.
Conventionally, nickel materials are mainly used as electrodes. However, such Ni
In the electrode, in addition to the high cathode fall voltage necessary for emitting electrons from the electrode to the discharge space, the lamp life tends to be reduced due to the phenomenon of so-called sputtering. Here, the sputtering phenomenon refers to a phenomenon in which the electrode receives a collision from ions while the cold cathode tube is lit, the electrode material is scattered, and the scattered material and mercury accumulate on the inner wall surface of the glass tube. is there.

Since the sputtering layer formed by the sputtering phenomenon takes in mercury and makes the mercury unusable for light emission, when the cold cathode tube is lit for a long time, the brightness of the lamp is extremely lowered and the end of life is reached. For this reason, if the sputtering phenomenon can be reduced, the mercury consumption cost can be suppressed, so that the lifetime can be extended even with the same amount of mercury enclosed.
Therefore, attempts have been made to reduce both the cathode fall voltage and the suppression of sparring. In recent efforts, an electrode is designed to reduce both the cathode fall voltage by the holocathode effect and to suppress sputtering by making the electrode into a cylindrical shape with a bottom (Japanese Patent Laid-Open No. 2001-1764).
No. 45, Patent Document 1). Also, the cathode drop voltage is set to 2 instead of the conventional nickel.
Mo, Nb, or the like that can be lowered by about 0 V is used.
The bottomed cylindrical cold-cathode tube electrode of Patent Document 1 is preferable in terms of cathode fall voltage drop and life as compared with the conventional nickel electrode, but both are plate materials (usually having a thickness of 0.07).
Since a bottomed cylindrical shape is obtained by drawing, a material yield is poor, and cracks and the like occur during machining for metals with poor drawability. There was a problem. Further, the drawing process from the plate material has a problem that the cost becomes high.
In order to cope with such a problem, Japanese Patent Application Laid-Open No. 2004-178875 (Patent Document 2) obtains a bottomed cylindrical shape with a sintered body such as Mo.

JP 2001-176445 A JP 2004-178875 A JP 2003-242927 A

Certainly, by obtaining a bottomed cylindrical shape with a sintered body, the cost can be greatly reduced compared to drawing from a plate material. Normally, a bottomed cylindrical electrode has a KOV foil (
The lead-in wire is welded via the Kovar foil), but the welding process of the lead-in wire requires complicated steps such as alignment and high-frequency heating, and the cost cannot be reduced sufficiently.
In order to cope with such a problem, Japanese Patent Application Laid-Open No. 2003-242927 (Patent Document 3) proposes an introduction wire and an electrode that are integrally formed by injection molding. However, those formed integrally by injection molding have insufficient bonding strength between the lead-in wire and the electrode.

The present invention has been made to solve the above-described problems. The first method for producing a sintered electrode for a cold cathode tube is for a tubular cold cathode tube having a bottom portion on one side and an opening portion on the other side. In the method for producing a sintered electrode, a step of forming a powder by molding a cylindrical shaped body having a bottom portion on one side and an opening on the other side, an introduction that has been processed to a density of 92% or more in advance at the bottom portion of the shaped body It is characterized by having a step of sintering after producing an integrated molded body in which the molded body and the lead-in wire are integrated by performing a step of inserting a wire.
Further, the second method for producing a sintered electrode for a cold cathode tube is a method for producing a cylindrical cold cathode tube sintered electrode having a bottom portion on one side and an opening on the other side. When producing a cylindrical molded body having an opening on the other side, an integrated molded body in which the introduction line and the molded body are integrated by disposing an introduction line that has been previously processed to a density of 92% or more at the bottom. It has the process of sintering after producing this.
Further, when the density of the sintered electrode is d1 and the density of the lead-in wire is d2, it is preferable that d2 / d1> 1 is satisfied. Moreover, it is preferable that the main components of the sintered electrode and the lead-in wire are the same. In addition, it is preferable that the sintered electrode is mainly composed of at least one of tungsten, molybdenum, niobium, tantalum, rhenium, and nickel. Moreover, it is preferable that the joining interface between the sintered electrode and the lead-in wire is sintered and joined.
Moreover, it is preferable to provide the process for making the surface roughness (Sm) of the inner surface of the said sintered electrode into 100 micrometers or less after sintering. The surface roughness (Sm) of the inner surface of the sintered electrode is 100 μm.
It is preferable that at least one of barrel polishing or blasting is included as a step for setting m or less.
The d1 has a density of 85% to 98%, and the d2 has a density of 92% to 10%.
It is preferably 0% or less.
Moreover, it is preferable that the sintering temperature of the said process to sinter is 1600-2300 degreeC.

The method for producing a sintered electrode for a cold cathode tube according to the present invention can produce a sintered electrode for a cold cathode tube in which the sintered electrode and the lead wire are integrally joined, so that the joining strength between the lead wire and the electrode is high, It has good mass productivity and can be manufactured at low cost.

The first method for producing a sintered electrode for a cold cathode tube according to the present invention is the method for producing a sintered electrode for a cold cathode tube having a bottom on one side and an opening on the other side. The molded body and the introduction line are formed by performing a step of producing a cylindrical molded body having an opening on the other side, and a step of inserting an introduction line that has been processed to a density of 92% or more into the bottom of the molding body. It has the process of sintering, after producing the integrated molded object united.
Further, the second method for producing a sintered electrode for a cold cathode tube is a method for producing a cylindrical cold cathode tube sintered electrode having a bottom portion on one side and an opening on the other side. When producing a cylindrical molded body having an opening on the other side, an integrated molded body in which the introduction line and the molded body are integrated by disposing an introduction line that has been previously processed to a density of 92% or more at the bottom. It has the process of sintering after producing this.
The sintered electrode for a cold cathode tube is a cylindrical sintered electrode for a cold cathode tube having a bottom portion on one side and an opening on the other side, and an introduction line is integrally joined to the bottom portion, and the density of the sintered electrode D
1. It is preferable that d2 / d1> 1 is satisfied, where d2 is the density of the lead-in wire.
FIG. 1 is a sectional view showing an example of a sintered electrode for a cold cathode tube according to the present invention. In the figure, 1 is a sintered electrode for a cold cathode tube, 2 is a side surface portion of the sintered electrode, 3 is a bottom surface portion of the sintered electrode, 4 is an opening portion of the sintered electrode, 5 is an inner surface of the sintered electrode, 6 is The lead wire 7 is a lead wire.

In the present invention, when the density of the sintered electrode 1 is d1, and the density of the lead-in wire 6 is d2, d2 / d1> 1.
It is characterized by satisfying. d2 / d1> 1 means that the sintered electrode 1
This means that the density of the lead-in wire 6 is larger than the density of the lead wire 6, that is, the density is high. Moreover, although the upper limit of d2 / d1 is not specifically limited, 1.18> = d2 / d1>
A range of 1 is preferable. If d2 / d1 exceeds 1.18, the density difference is too large, and the bonding strength between the sintered electrode 1 and the lead-in wire 6 may be insufficient. More preferably 1.1
0 ≧ d2 / d1> 1.
The density of the present invention is a relative density. The measurement method is as follows. (1) The bottom of the sintered electrode for a cold cathode tube is cut and removed by a method such as wire electric discharge machining, and a sample is taken. (2) Subsequently, the sample of the side wall obtained in 1 is cut in half by a method such as wire electric discharge machining on the object of the axis. Here, the reason for cutting the bottom portion is that if there is a bottom portion, bubbles enter the closed space inside the sintered electrode for a cold cathode tube and accurate measurement cannot be performed. (3) The sample obtained in (2) is N = 5 by Archimedes method defined in JIS-Z-2501 (2000).
The average value when measured is taken as the representative value. (4) The lead wire density is also cut to an arbitrary length, and the average value when N = 5 is measured by the Archimedes method defined in JIS-Z-2501 (2000) is taken as the representative value.

It is preferable that the density d1 of the sintered electrode 1 is 85% to 98%, and the density d2 of the lead-in wire 6 is 92% to 100%. If the density d1 of the sintered electrode 1 is less than 85%, the strength of the sintered electrode is lowered. On the other hand, when the density d1 exceeds 98%, pores are not formed on the electrode surface, so that the surface area cannot be increased. When pores are present on the electrode surface, minute irregularities can be formed on the surface to increase the coverage of the electron-emitting material (emitter material) and improve the bondability between the electron-emitting material and the sintered electrode by the anchor effect. Can do. Considering the increase in strength and surface area, the preferred density d1 is 90 to 96%.
Moreover, it is preferable that the density d2 of the introduction line 6 is 92 to 100%. The lead-in wire 6 is a portion that becomes a sealing portion when being mounted on the cold cathode tube. Specifically, a cold cathode tube is obtained by applying a sealing material such as glass beads and fixing it to a tubular light-transmitting bulb (for example, a glass tube) by heating. If the density d2 of the lead-in line 6 is less than 92%, the density of the lead-in line is insufficient, and there is a possibility that the confidentiality of the cold cathode tube cannot be sufficiently maintained. Moreover, when the density of the lead-in wire 6 is low, the bonding strength with the sintered electrode 1 is also low. In consideration of confidentiality and bonding strength, the density d2 is preferably 97 to 100%.
The sintered electrode for a cold cathode tube according to the present invention preferably contains a refractory metal as a main component. For example, at least one metal selected from W, Nb, Ta, Ti, Mo, Re, or an alloy thereof is used. Can be mentioned. Preferred alloys include W—Mo alloys, Re—W alloys, Ta—
A Mo alloy can be exemplified.

Further, the sintered electrode for a cold cathode tube may contain an electron radioactive substance (emitter material). As the electron-emitting material, rare earth oxides such as La, Ce, and Y, rare earth carbonates (particularly preferably, “rare earth element (R) —carbon (C) —oxygen (O) compound”, light elements such as Ba, Mg, and Ca) In addition, if necessary, it may be a mixture of an electron-emitting substance and a refractory metal, and Ni, Cu, Fe, P or the like may be used as a sintering aid (for example, 1).
(Mass% or less) may be added. Usually, in the manufacturing process of a cold cathode tube, nitrogen gas is used for replacement at a high temperature, and therefore, a Mo-based or W-based one that is less susceptible to nitriding than an Nb-based or Ta-based one is preferable. Of the Mo system and the W system, a Mo system in which sintering proceeds at a low temperature is more preferable.
Moreover, it is preferable that the average particle diameter of the crystal grain of a sintered compact (sintered electrode 1) is 100 micrometers or less. The aspect ratio (major axis / minor axis) of the crystal grains of the sintered body is preferably 5 or less.
The lead wire 6 is preferably made of a refractory metal as a main component, for example, W, N
Examples thereof include at least one metal selected from b, Ta, Ti, Mo, and Re, or an alloy thereof. As will be described later, when the sintered electrode 1 is formed, the introduction wire 6 is integrally formed and sintered. Therefore, the introduction wire 6 is also preferably a refractory metal. From this point, it is necessary to form the lead-in wire 6 with a material having a melting point equal to or higher than the melting point of the main component of the sintered electrode 1.

The present invention is characterized in that the lead-in wire 6 is integrally joined to the bottom 3 of the sintered electrode 1. The term “joint integrally” means that joining is performed without using a brazing filler metal layer such as KOV (Kovar) foil as in the conventional case. At this time, the molded body before sintering the sintered electrode 1 and the lead-in wire 6 are integrally molded and sintered, whereby the sintered electrode 1 and the lead-in wire 6 can be sintered and joined. If it is sintering joining, it will become metal joining, and if the main components of the sintered electrode 1 and the lead-in wire 6 are the same, it will become a stronger joining state.
Further, when “joining together”, it is preferable that the leading end of the lead-in wire 6 does not penetrate the bottom portion 3. If the leading end of the introduction wire 6 does not penetrate the bottom portion 3, the contact area between the bottom portion 3 and the leading end of the introduction wire 6 is increased, so that the bonding strength is further improved.
As described above, the sintered electrode for a cold cathode tube according to the present invention has a cylindrical side wall portion, a bottom portion at one end of the side wall portion, and a sintered portion for the cold cathode tube having an opening portion at the other end of the side wall portion. Electrode.
At this time, the surface roughness (Sm) of the inner surface of the electrode is preferably 100 μm or less.

In the present invention, the “surface roughness (Sm)” is based on the “average unevenness interval (Sm)” defined in JIS-B-0601 (1994), that is, from the “roughness curve, the average line direction. The reference length l is extracted from the above and the sum of the lengths of the average lines corresponding to one peak and one adjacent valley is obtained, and the average value is expressed in millimeters (mm).

Means.
1 and 2 to 5 are sectional views showing an example of a sintered electrode for a cold cathode tube according to the present invention. Each of these drawings shows a cross section parallel to the longitudinal axis direction of the sintered electrode for a cold cathode tube.
A sintered electrode 1 for a cold cathode tube shown in FIG. 1 has a cylindrical side wall 2, a bottom 3 at one end of the side wall 2, and an opening 4 at the other end of the side wall 2. It is a sintered electrode for cathode tubes, and the surface roughness (Sm) of the inner surface 5 of the electrode is 100 μm or less. In the present specification, as shown in FIG. 1, the “side wall portion” means the deepest portion of the sintered electrode 1 for a cold cathode tube (that is, the edge surface 4 ′ of the opening 4 and the inner wall surface of the electrode). The portion having the longest distance (L1) is the portion existing on the edge surface 4 ′ side. The “bottom part” refers to a part of the sintered electrode 1 for a cold cathode tube that is present on the opposite side of the edge face 4 ′ from the deepest part. The inner surface 5 is
This refers to both the inner surface of the cylindrical side wall 2 and the inner surface of the bottom 3 of the sintered electrode 1 for cold cathode tubes.
In the present invention, the surface roughness of the inner surface 5 is preferably within a predetermined Sm range. However, in the present invention, it is not always necessary that each region of the inner surface 5 has the same Sm value. In the present invention, substantially the entire area of the inner surface 5 (preferably an area of 30% or more, particularly preferably 50% or more of the inner surface 5) may be within the predetermined Sm range. It is not necessary that all the areas of 5 are always within the predetermined Sm range. Therefore, in some cases, a partial region of the inner surface 5 may not be within the predetermined Sm range.
On the other hand, Sm is not specified for the outer surface of the sintered electrode 1 for cold cathode tubes (that is, including the outer surface of the cylindrical side wall 2, the outer surface of the bottom 3, and the edge surface 4 ′). That is, the Sm of the outer surface of the cold cathode tube sintered electrode 1 is arbitrary, and may be the same as or different from the Sm range defined for the inner surface of the cold cathode tube sintered electrode 1.

In the present specification, the “thickness” of the bottom portion means a distance (L2) between the deepest portion and the outer surface of the bottom portion of the sintered electrode for a cold cathode tube at the bottom portion. Also, the “thickness” of the side wall
Is the distance (L3 between the inner surface and the outer surface of the sintered electrode for a cold cathode tube in the side wall portion.
)
An introduction wire 6 is integrally joined to the bottom 3 of the sintered electrode 1 for cold cathode tubes. A lead wire 7 is joined to the leading end of the introduction wire 6. The lead wire 7 is preferably made of a material that can be joined to the lead-in wire 6 such as a dumet wire or a nickel wire, and that can conduct as the lead wire.
As described above, the sintered electrode for a cold cathode tube according to the present invention has a surface roughness (Sm) of 10 on the inner surface.
It is preferably 0 μm or less. This is advantageous for lowering the operating voltage in a bottomed electrode, in particular, the larger the surface area of the electrode, the more advantageous. In particular, since discharge occurs mainly inside the electrode, the surface area inside the electrode should be increased. This is because it is desirable. Sm value is 100
If it exceeds μm, the advantageous effect on the operating voltage is poor, and the mercury consumption tends to increase significantly. The purpose of the present invention, that is, the operating voltage is low, and the mercury consumption is remarkably suppressed. It is difficult to achieve a long-life cold cathode tube. A preferable range of Sm is 30 μm or more and 90 μm or less, and particularly preferably 40 μm or more and 50 μm or less.

For the surface roughness (Sm) of the inner surface, the production conditions of the sintered body (for example, the particle size of the raw material powder) are set so that such a sintered electrode of the inner surface is obtained, or the sintered body is After being obtained, it can be obtained by performing appropriate processing (for example, polishing processing such as barrel polishing, blasting, etching processing, etc.).
The average thickness of the side portion is preferably in the range of 0.1 mm to 0.7 mm. When operating as a cold cathode tube, if the average thickness is less than 0.1 mm, the strength is insufficient,
This is because problems such as perforation may occur. If it exceeds 0.7 mm, the surface area inside the sintered electrode for the cold cathode tube is reduced, and the effect of reducing the operating voltage cannot be sufficiently obtained. The average thickness of the side surface is preferably 0.3 mm or more and 0.6 mm or less, particularly preferably 0.35 mm or more and 0.
. It is 55 mm or less.
On the other hand, the average thickness of the bottom portion is preferably in the range of 0.25 mm to 1.5 mm. This is because it is preferable that the inner side of the bottom surface of the electrode is thicker than 0.25 mm because the wear is significant. However, when the thickness exceeds 1.5 mm, the inner surface area becomes small, and the effect of reducing the operating voltage cannot be sufficiently obtained as described above. The preferred average thickness of the bottom is 0.4 m
m to 1.35 mm, particularly preferably 0.6 mm to 1.15 mm.
The length of the sintered electrode for a cold cathode tube according to the present invention [i.e., the edge surface 4 'surface and the outer surface of the bottom surface furthest from the edge surface 4' (in the case of having a protrusion, the surface of the tip of the protrusion) ) Is determined mainly depending on the size and performance of the cold cathode tube in which the electrode is incorporated, but is preferably 3 mm or more and 8 mm or less, particularly preferably 4 mm or more and 7 mm or less.

Similarly, the diameter of the sintered electrode for a cold cathode tube is determined according to the size and performance of the cold cathode tube in which the electrode is incorporated, but preferably has a diameter of 1.0 mm to 3.0 mm, particularly preferably 1.3 mm. The above is φ2.7 mm or less.
The ratio (length / diameter) of the length and diameter of the sintered electrode for a cold cathode tube is preferably 2 or more and 3 or less,
Particularly preferred is 2.2 or more and 2.8 or less.
In addition, the sintered electrode for a cold cathode tube according to the present invention has a large surface area, and is easy to manufacture and process, and from the viewpoint of workability when mounted on a hollow bulb when manufacturing a cold cathode tube,
The shape of the cylindrical inner space shown in the cross section parallel to the longitudinal axis direction is preferably a rectangular shape as shown in FIG. 1 or a trapezoidal shape as shown in FIG. 2, but is not limited to the above. 3 (
It can have various shapes such as a cross-section V-shape, FIG. 4 (cross-section U-shape), and FIG. For the same reason, it is preferable that the outer shape of the side wall portion is a cylindrical shape, but other shapes (for example, an ellipse or a polygon) may be used. Further, the outer shape of the sintered electrode for cold cathode tubes and the inner shape of the sintered electrode for cold cathode tubes may be different.
With the above-described configuration, a long-life cold cathode tube with a low operating voltage and significantly reduced mercury consumption is provided. Moreover, since it is not necessary to join the lead-in wire using a KOV foil as in the prior art, a significant cost reduction can be achieved.

Next, the manufacturing method of the sintered electrode for cold cathode tubes of this invention is demonstrated. The following manufacturing method will be described by taking a manufacturing method of a sintered electrode mainly composed of molybdenum (Mo) as an example.
First, Mo wire to be an introduction wire is prepared. The Mo wire preferably has a density of 92% or more. In order to set the density to a predetermined value, a high-density sintered body may be used in advance, or a wire processed by a drawing process may be used. In particular, the wire processed by wire drawing is a sintered ingot (
Alternatively, a melted ingot) is made into a wire using forging, rolling, drawing, or the like, so that a high-density lead wire can be easily obtained.
Next, the sintered electrode for a cold cathode tube can be manufactured by mixing raw material powder, granulating it, shaping it into a predetermined shape, and then sintering it. As the raw material powder, molybdenum powder having an average particle diameter of 1 μm to 5 μm and a purity of 99.95% or more is used. This powder is mixed with pure water and a binder (polyvinyl alcohol (PVA) is preferred as the binder) and granulated. Thereafter, a cup-shaped (cylindrical) shaped product is obtained by single press, rotary press or injection molding.
When the molded body is produced, by molding together with the above-described lead wire, a molded body in which the cup-shaped molded body and the lead wire are integrated can be obtained. In another method, after the molded body is once formed, a molded body in which the cup-shaped molded body and the introduction line are integrated may be obtained by using a step of inserting the lead wire into the molded body.
Moreover, the 2nd component as a Mo alloy and an electron radioactive substance (emitter material) may be added as needed.

Subsequently, degreasing is performed in wet hydrogen at 800 to 1100 ° C. Subsequently, 1600-23
Sintering in hydrogen at 00 ° C for 5-24 hours, further 1300-1700 ° C as required
Hot isostatic pressing (HIP) treatment is performed at 100 to 300 MPa. When the surface roughness inside the bottomed shape portion is not within the predetermined Sm range, or in order to obtain a more preferable Sm range, the surface roughness (Sm) inside the bottomed shape portion can be adjusted. Examples of the method include barrel polishing and blasting. At this time, the abrasive to be used, the work content, etc. can be appropriately selected or adjusted. In addition, the sintering electrode and the lead-in wire can be integrally joined by this sintering process. At this time, if the main component of the sintered electrode and the main component of the lead-in wire are the same, a metal bond occurs at the contact surface between the sintered electrode and the lead-in wire, so that a stronger bond can be obtained.
Then, it wash | cleans and anneals at the temperature of 700-1000 degreeC. Thereafter, the lead wires are welded to complete the assembly of the electrodes.
The sintered electrode for a cold cathode fluorescent lamp according to the present invention composed of such a sintered body has the sintered electrode and the lead wire joined together, so that it is not necessary to perform welding using a KOV foil or the like. Can be planned.

In the present invention, as described above, a long-life cold cathode tube having a low operating voltage and significantly reduced mercury consumption is obtained, and a bonding strength per unit cross-sectional area of the lead-in is 250.
A sintered electrode for a cold cathode tube having N / mm 2 or more can be obtained.
Note that the bonding strength per unit cross-sectional area of the lead-in wire is such that the cold-cathode tube sintered electrode 1 is fixed in the slit formed in the chucking A while the lead-in wire 6 is chucked as shown in FIG. It shall be fixed by B and measured by pulling chucking A at a speed of 10 mm / min.

Next, a method for manufacturing a cold cathode tube will be described. A cold cathode tube according to the present invention includes a hollow tube-shaped light-transmitting bulb in which a discharge medium is enclosed, a phosphor layer provided on an inner wall surface of the tube-shaped light-transmitting bulb, and the tube-shaped light-transmitting bulb. A pair of the sintered electrodes for cold-cathode cathode tubes,
It is characterized by comprising. In the cold cathode tube according to the present invention, the discharge medium, the tube-shaped translucent bulb, the phosphor layer, and the like, which are essential components other than the sintered electrode for the cold cathode tube, have been conventionally used in this type of cold cathode tube, particularly a liquid crystal display. What has been used in the cold cathode tube for the backlight can be used as it is or after appropriate modification.
What can be applied and preferably used in the cold cathode tube according to the present invention is, for example, a rare gas-mercury type as a discharge medium (argon, neon, xenon, krypton,
Examples of such phosphors include phosphors that emit light upon stimulation with ultraviolet light, preferably calcium halophosphate phosphors. The hollow tubular light-transmitting bulb has a length of 60 mm or more and 700 mm or less and a diameter of 1.6 mm or more.
A glass tube of 8 mm or less can be exemplified.
Moreover, in the cold cathode tube of the present invention, it is preferable that the structure be sealed to the tubular translucent bulb by the lead-in portion. Since the lead-in wire has a high density, it is easy to maintain confidentiality in the bulb when sealed with glass beads or the like.
Next, a liquid crystal display device will be described. The liquid crystal display device according to the present invention includes the cold cathode tube, a light guide disposed in proximity to the cold cathode tube, a reflector disposed on one surface side of the light guide, and the light guide. And a liquid crystal display panel disposed on the other surface side of the liquid crystal display panel. FIG. 7 is a sectional view showing an example of the liquid crystal display device according to the present invention.

The liquid crystal display device 20 shown in FIG. 7 includes a cold cathode tube 21, a light guide 22 disposed in the vicinity of the cold cathode tube 21, and a reflector disposed on one surface side of the light guide 22. 23 and a liquid crystal display panel 24 disposed on the other surface side of the light guide 22, and a light diffuser 25 is disposed between the light guide 22 and the liquid crystal display panel 24. A cold-cathode tube reflector 27 that reflects light from the cold-cathode tube 21 toward the light guide 22 is disposed.
In the present invention, the number of cold-cathode tubes is arbitrary, and for example, as shown in FIG. 7, a total of two cold-cathode tubes 21 can be arranged in the vicinity of two opposing sides of the light guide 22. 1 of the light guide
One or two or more cold cathode tubes can be arranged in the vicinity of the side (or three or more sides). The number and shape of the anti-light diffusers 25 are also arbitrary. For example, a sheet-like light diffuser 25a having light diffusibility by making light diffusing particles present inside, or a lens-like or prism-like light diffuser 25b having light diffusivity by adjusting the surface shape. Can be disposed between the light guide 22 and the liquid crystal display panel 24. Also,
On the viewer side of the liquid crystal display panel 24, a light diffuser 25c and a surface protector 2 are provided as necessary.
8. An antireflection body 29, an antistatic body 30, and the like that prevent or reduce reflection or reflection of external light can be provided. Two or more of these light diffusers 25a, 25b, 25c, surface protector 28, antireflection body 29, antistatic body 30 and the like are combined, and one or two layers having a plurality of functions are combined. It is also possible to provide the above. Note that the light diffusers 25a, 25b, and 25c, the surface protection body 28, the antireflection body 29, the antistatic body 30, and the like do not have to be disposed if a desired function is exhibited as a liquid crystal display device. In addition, each component of the liquid crystal display device 20 (that is, the cold cathode tube 21, the light guide 22, the reflector 23, the liquid crystal display panel 24, the light diffusers 25a, 25b, and 25c, the surface protector 28, and the antireflector 29). In addition, a support substrate 26 that holds the antistatic body 30 and the like in a predetermined position, a frame, a spacer, and a case that accommodates each of these components can be provided, and a heat dissipation member 31 and the like can also be provided. Similarly to the conventional liquid crystal display device, the liquid crystal display device according to the present invention is also provided with electric wiring for supplying a driving voltage to the liquid crystal display panel 24, LSI chip, electric wiring for supplying the driving voltage to the cold cathode tube 21, and unnecessary portions. A sealing material or the like for preventing the leakage of light and the entry of dust and moisture into the apparatus can be provided at a necessary portion.

In the present invention, only the cold cathode tube 21 needs to satisfy the predetermined requirements detailed above.
Various components other than the cold cathode tube 21 (for example, the light guide 22, the reflector 23, the liquid crystal display panel 24, the light diffusers 25a, 25b, 25c, the support substrate 26, the cold cathode tube reflector 27, the surface protector) 28, the antireflection body 29, the antistatic body 30, the heat radiating member 31, the frame, the case, the sealing material, etc.) that have been conventionally used can be used. FIG. 7 illustrates a liquid crystal display device having a sidelight type backlight structure, but a direct type backlight structure may be applied to the liquid crystal display device of the present invention.

(Example)
(Examples 1 and 2)
100% by weight of molybdenum powder having an average particle diameter of 2 μm (purity of 99.95% or more) is prepared, and pure water and a PVA binder are mixed and granulated. Thereafter, a cup-shaped molded body is obtained by a single press.
On the other hand, the drawn molybdenum wire is cut to a predetermined length and then fixed to the bottom of the cup-shaped body. Subsequently, degreasing is performed in wet hydrogen at 900 to 1100 ° C. Subsequently, sintering was performed in hydrogen at 1800 to 2100 ° C. for 8 to 15 hours, and a sintered electrode for a cold cathode tube in which the sintered electrode and the lead wire according to Example 1 and Example 2 were integrally joined was produced. .
(Examples 3 to 7)
The drawn molybdenum wire is cut into a predetermined length to form an introduction wire.
Next, 100% by weight of molybdenum powder having an average particle diameter of 2 μm (purity of 99.95% or more) is prepared, and pure water and a PVA binder are mixed and granulated. Thereafter, a cup-shaped molded body is obtained by a single press. At this time, it shape | molded so that an introductory line might be fixed to a molded object bottom part.
Subsequently, degreasing is performed in wet hydrogen at 800 to 1100 ° C. Subsequently, 1700-220
Sintering was carried out in hydrogen at 0 ° C. for 5 to 20 hours to prepare a sintered electrode for a cold cathode tube in which the sintered electrode according to Examples 3 to 7 and the lead-in wire were integrally joined.
In all of Examples 1 to 7, the lead wire has a shape that does not penetrate the bottom of the sintered electrode. Moreover, the outer diameter of the sintered electrode was unified to 2.3 mm, and the thickness of the bottom part was unified to 0.8 mm. The surface roughness (Sm) of the inner surface of the sintered electrode was 80 μm or less. The sintered electrode used had an average crystal grain size of 100 μm or less and an aspect ratio of 5 or less.

(Comparative Example 1)
A sintered electrode for a cold cathode tube according to Comparative Example 1 was the same as Example 1 except that the lead wire was joined using a KOV foil.
(Comparative Example 2)
A sintered electrode for a cold cathode tube according to Comparative Example 2 was the same as Example 1 except that a molded body in which the lead wire and the cup-shaped molded body were integrated by injection molding.
(Comparative Example 3)
Example 1 except that the relationship between the density d2 of the lead-in wire and the density d1 of the sintered electrode was d2 / d1 <1.
The same as in Comparative Example 3 was used.
Cold cathode tubes were produced using the sintered electrodes for cold cathode tubes according to Examples and Comparative Examples. A dumet wire was joined to the sintered electrode for the cold cathode tube. The cold cathode tube used was a glass tube having a diameter (outer diameter) of 3.2 mm and a distance between electrodes of 350 mm. Glass beads were attached to the lead-in portion of the sintered electrode for the cold cathode tube and sealed with the glass tube. The glass tube is provided with a structure necessary for a cold cathode tube such as mercury or a phosphor layer.
With respect to such a cold cathode tube, the leakage failure rate, the electrode dropout failure rate, and the joining strength of the lead-in wire were measured. For the leak defect rate, the ratio of occurrence of a leak defect at the sealed portion when the cold cathode tube was operated was measured. As for the electrode dropout failure rate, the ratio of occurrence of dropout failure of the sintered electrode in which the sintered electrode and the lead-in wire were separated when the cold cathode tube was produced was examined. Bonding strength is chucking A and B as described above.
Was used to measure the bonding strength between the sintered electrode and the lead-in wire.
The results are shown below.

Table 1 shows the configuration of the sintered electrode for a cold cathode tube, and Table 2 shows the measurement results.
Since the cold cathode tube according to the embodiment uses high-density Mo wire as the lead-in wire, it has high confidentiality and thus has a low incidence of leakage failure. Moreover, since the lead-in wire and the sintered electrode were joined together, no electrode dropout failure occurred. On the other hand, in Comparative Example 1, since the joining with the KOV foil was weak, it was confirmed that the sintered electrode was dropped. In Comparative Example 2, the lead wire and the sintered electrode are formed into the same molded body by injection molding. However, in such a structure, the lead wire portion is easily broken because the bond between the lead wire and the sintered electrode is weak. In addition, since the joining strength of the sintered electrode for cold cathode fluorescent lamps according to this example uses sintered joining, a strong joining state can be obtained. In addition, “ppm” in the table means 1 / million, for example, the leakage defect of 2 ppm in Example 1 means that when one million cold cathode tubes were produced, two leakage defects occurred. That means.
Such a sintered electrode for a cold cathode tube and a cold cathode tube using the same have high reliability because there are few occurrences of leakage defects and the like, and the handling property is also good because there is no electrode dropout. In addition, since brazing with KOV foil or the like is unnecessary, significant cost reduction can be achieved.
Further, when a backlight was constructed using the cold cathode tube according to this example and incorporated in a liquid crystal display device, good results were obtained. Moreover, it was applicable to both the sidelight type backlight and the direct type backlight.

(Examples 8 to 11)
By blasting the inner surface of the sintered electrode, the surface roughness was set to (Sm) 40 μm in Example 8, (Sm) set to 100 μm, Example 9 (Sm) set to 200 μm A device similar to that of Example 1 was prepared except that Example 10 was used.
Example 11 was the same as Example 8 except that 2% by weight of lanthanum oxide (La ₂ O ₃ ) was added as an electron-emitting substance (emitter material).
Cold cathode tubes were produced using the sintered electrodes for cold cathode tubes. The operating voltage and mercury evaporation in each cold cathode tube were measured. As the operating voltage, an initial voltage (V) required for lighting the cold cathode tube was measured. In addition, the amount of mercury evaporated was measured after 10,000 hours. The results are shown below.

As can be seen from the above results, the surface roughness of the inner surface is preferably 100 μm or less in terms of (Sm). In other words, by using the sintered electrode for the cold cathode tube in which the sintered electrode and the lead-in wire are integrally joined, not only the reliability, handleability and cost reduction but also the characteristics as an electrode can be improved. . In addition, it was confirmed that the initial voltage and the amount of mercury evaporation were improved by containing an electron radioactive substance.

Sectional drawing which shows an example of the sintered electrode for cold cathode tubes of this invention. Sectional drawing which shows another example of the sintered electrode for cold cathode tubes of this invention. Sectional drawing which shows another example of the sintered electrode for cold cathode tubes of this invention. Sectional drawing which shows another example of the sintered electrode for cold cathode tubes of this invention. Sectional drawing which shows another example of the sintered electrode for cold cathode tubes of this invention. The figure which shows the outline | summary of the measuring method of the joining strength of a lead wire and a sintered electrode. Sectional drawing which shows an example of the liquid crystal display device by this invention.

Explanation of symbols

1: Sintered electrode for cold cathode tube 2: Side wall portion 3: Bottom portion 4: Opening portion 5: Inner surface of electrode 6: Lead wire 7: Lead wire 20: Liquid crystal display device 21: Cold cathode tube 22: Light guide 23: Reflector 24: Liquid crystal display panel 25a, 25b, 25c: Light diffuser

Claims (8)

In a method for manufacturing a cylindrical cold cathode tube sintered electrode having a bottom on one side and an opening on the other side, a step of forming a powder to form a cylindrical molded body having a bottom on one side and an opening on the other side An integrated molded body in which the molded body and the lead-in wire are integrated by performing a step of inserting a lead wire that has been previously processed to have a density in the range of 97 to 100% into the bottom of the molded body. Having a step of sintering after fabrication,
The cooling electrode is characterized in that when the density of the sintered electrode is d1 and the density of the lead-in wire is d2, d2 / d1> 1 is satisfied and d1 of the sintered electrode is in the range of 90 to 96%. Manufacturing method of sintered electrode for cathode tube. In the manufacturing method of a cylindrical cold cathode tube sintered electrode having a bottom on one side and an opening on the other side, when forming a cylindrical molded body having a bottom on one side and an opening on the other side by molding the powder In addition, a step of sintering after producing an integrated molded body in which the introduction line and the molded body are integrated by disposing an introduction line that has been processed so that the density is in the range of 97 to 100% at the bottom. Have
The cooling electrode is characterized in that when the density of the sintered electrode is d1 and the density of the lead-in wire is d2, d2 / d1> 1 is satisfied and d1 of the sintered electrode is in the range of 90 to 96%. Manufacturing method of sintered electrode for cathode tube.   The method for producing a sintered electrode for a cold cathode tube according to claim 1 or 2, wherein the main components of the sintered electrode and the lead-in wire are the same.   The sintered electrode for a cold cathode tube according to any one of claims 1 to 3, wherein the sintered electrode is mainly composed of at least one of tungsten, molybdenum, niobium, tantalum, rhenium, and nickel. Manufacturing method.   The method for producing a sintered electrode for a cold cathode tube according to any one of claims 1 to 4, wherein a joining interface between the sintered electrode and the lead-in wire is sintered and joined.   The cold cathode tube according to any one of claims 1 to 5, further comprising a step for setting the surface roughness (Sm) of the inner surface of the sintered electrode to 100 µm or less after sintering. A method for producing a sintered electrode.   7. The method for producing a sintered electrode for a cold cathode tube according to claim 6, wherein the step of making the surface roughness (Sm) of the inner surface of the sintered electrode at least 100 [mu] m includes at least one of barrel polishing and blasting. Method. The method for producing a sintered electrode for a cold cathode tube according to any one of claims 1 to 7 , wherein a sintering temperature in the sintering step is 1600 to 2300 ° C.

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