JP4809552B2 - Plant protection paste - Google Patents

Plant protection paste Download PDF

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Publication number
JP4809552B2
JP4809552B2 JP2001251273A JP2001251273A JP4809552B2 JP 4809552 B2 JP4809552 B2 JP 4809552B2 JP 2001251273 A JP2001251273 A JP 2001251273A JP 2001251273 A JP2001251273 A JP 2001251273A JP 4809552 B2 JP4809552 B2 JP 4809552B2
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JP
Japan
Prior art keywords
paste
polysaccharide
plant protection
cut
trees
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2001251273A
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Japanese (ja)
Other versions
JP2003063903A (en
Inventor
弘文 二宮
良平 野口
光雄 森川
貴雄 富所
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Mitsubishi Chemical Corp
Mitsubishi Rayon Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical Corp, Mitsubishi Rayon Co Ltd filed Critical Mitsubishi Chemical Corp
Priority to JP2001251273A priority Critical patent/JP4809552B2/en
Publication of JP2003063903A publication Critical patent/JP2003063903A/en
Application granted granted Critical
Publication of JP4809552B2 publication Critical patent/JP4809552B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Paints Or Removers (AREA)

Description

【0001】
【発明の属する技術分野】
本発明は、樹木等植物の腐らん防止のためのペーストに関するものであり、特に果樹の感染防止や観葉植物の切口の腐敗抑制などに広く利用されるペーストに関するものである。
【0002】
【従来の技術】
樹木は、枝切口や幹・枝の皮はがれ部分より子のう菌類(Valsa ceratosperma)が感染し、枝腐らんや胴腐らんを引き起こす。こうした感染により、枝腐らんの場合は先枯れ症状が発生し、又、胴腐らんの場合は樹皮の褐変腐敗や、一部木質部の腐敗が発生し、特に果樹については重大な問題となっている。従来、樹木の陥没部に感染を防ぐ目的等でセメントを充填することが試みられた。しかしながら、セメントは、樹木との接着性が悪く剥がれが起こるなど、様々な問題が発生した。これらの問題を解決する方法として、特開平11−155396号公報には、珪藻土、セメント、木粉、及び抗菌剤を混合したペーストを樹木の陥没部や切口にコーティングした後、硬化する方法が開示されている。又、合成樹脂であるウレタンや塩化ビニル素材に防腐剤を添加したものをコーティングすることも行われている。
【0003】
【発明が解決しようとする課題】
しかしながら、セメントや合成樹脂素材は樹木との接着性が充分でなく、又手で直接取り扱えず作業性や安全性に問題があった。更に、合成樹脂の場合は環境面においても好ましくなかった。そこで、安全で容易に取り扱うことができ、樹木との接着性に優れ、感染を確実に防止できる植物保護用素材が望まれていた。
【0004】
【課題を解決するための手段】
本発明者らは、上記課題を解決するために鋭意検討した結果、樹木の感染防止のための抗菌剤のペースト化剤として多糖類が優れていることを見出し、本発明に到達した。すなわち、本発明は、ゲル化能を有する多糖類、又はゲル化能を有する多糖類を一種以上含む多糖類混合物によりペースト化した酸化チタン系又は酸化亜鉛系の光半導体の微粒子からなる抗菌剤を含んでなる、植物保護用ペーストである。
【0005】
【発明の実施の形態】
本発明においてペースト化剤として用いる多糖類(その誘導体も含む)としては、天然多糖類を使用することができるが、コーティング後のペーストの耐水性付与の観点からゲル化能を有する多糖類、又はゲル化能を有する多糖類を1種以上含む多糖類混合物が好ましい。ゲル化能を有する多糖類としては、特に限定されず、寒天、アルギン酸及びその塩類、カラギナン、コンニャクイモ抽出物、ローカストビーンガム/キサンタンガム混合物、ジェランガム等を挙げることができるが、ペーストの展延性の経日的な安定性の点からカラギナンが好ましい。
【0006】
尚、本発明で云うゲル化能を有する多糖類としては、単独ではゲル化能を発現しないものであっても、特定の塩等の成分の添加でゲル化能を発現する多糖類、及び他の多糖類との組み合わせにより、ゲル化能を発現する多糖類も含まれる。こうしたゲル化能を有する多糖類の添加によって、コーティングされたペーストの耐水性が向上し、降雨や散水によってもペーストの剥がれや流出が防がれるのである。
【0007】
本発明のペーストに含まれる抗菌剤としては、樹木の感染を防止できるものなら特に限定されないが、抗菌性能の長期安定化の点で、無機系の二酸化チタンや酸化亜鉛系などの光半導体の微粒子が好ましい。これらの光半導体は、光触媒作用を有し抗菌効果があることは公知であるが、形態としては微粒子で存在するためペースト内に存在する限り降雨や散水により流出することはなく、抗菌作用が維持される。
【0008】
尚、本発明のペーストには、着色料、栄養素、保存料、無機充填材、保湿剤等を適宜添加混合しても差し支えない。
【0009】
【実施例】
以下実施例により本発明を更に具体的に説明する。
【0010】
(実施例1)
以下の組成でペーストを作成し、チューブに充填した。
キサンタンガム 0.5質量%
酸化チタン系光半導体粉末 1.0質量%
グリセリン 15.0質量%
シリカ粉末 20.0質量%
安息香酸ナトリウム 0.5質量%
水 63.0質量%
得られたペーストをりんごの枝の切口に指で塗布し、無処理の切口と比較した。尚、ペーストは指で切口全体に容易に均一塗布することができた。3ヵ月後の切口の状況を確認したところ、無処理の切口の腐らん発生に対し、本ペーストを塗布した切口は若干のペーストの流出が認められたものの、切口自体には全く異常が認められなかった。又、ペースト作成後、チューブで6ヶ月間常温保管したものについて、ペーストの硬さの変化や分離状況を確認したが、変化は全く認められず、コーティングもスムーズに実施できた。
【0011】
(実施例2)
以下の組成でペーストを作成し、チューブに充填した。
カラギナン 1.0質量%
酸化チタン系光半導体粉末 1.0質量%
グリセリン 20.0質量%
シリカ粉末 20.0質量%
安息香酸ナトリウム 0.5質量%
水 57.5質量%
得られたペーストを実施例1と同様に、りんごの枝の切口に指で塗布し、無処理の切口と比較した。尚、ペーストは指で切口全体に容易に均一塗布することができた。3ヵ月後の切口の状況を確認したところ、無処理の切口の腐らん発生に対し、本ペーストを塗布した切口はペーストの流出も認められず、切口自体にも全く異常が認められなかった。又、ペースト作成後、チューブで6ヶ月間常温保管したものについて、ペーストの硬さの変化や分離状況を確認したが、変化は全く認められず、コーティングもスムーズに実施できた。
【0012】
【発明の効果】
本発明の植物保護用ペーストは、ペースト化剤として多糖類(その誘導体を含む)を使用するので、樹木の皮剥がれ部や切口に安全且つ容易にコーティングすることができ、しかも多糖類は天然物で樹木組織との親和性に優れていて、樹木との接着性が良好であることから、樹木の感染を確実に防止することができる。更に、ペーストのコーティング後もコーティング剤を通して、酸素通過性及び水分通過性が保持されるので、樹木にとって最適な環境を維持することができる。
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a paste for preventing the decay of plants such as trees, and more particularly to a paste widely used for preventing infection of fruit trees and suppressing the decay of cuts of foliage plants.
[0002]
[Prior art]
Trees are infected with peanut fungus (Valsa ceratosperma) from the cuts of branches, trunks and branches, causing branch rot and trunk rot. Due to such infection, in the case of branch rot, pre-breaking symptoms occur, and in the case of trunk rot, browning of the bark and partial rot of the wood occur, and this is a serious problem especially for fruit trees. In the past, attempts have been made to fill cement in the depressions of trees to prevent infection. However, the cement has various problems such as poor adhesion to trees and peeling. As a method for solving these problems, Japanese Patent Application Laid-Open No. 11-155396 discloses a method in which a paste mixed with diatomaceous earth, cement, wood powder, and an antibacterial agent is coated on a depression or cut of a tree and then cured. Has been. Further, a synthetic resin such as urethane or vinyl chloride is added with a preservative added.
[0003]
[Problems to be solved by the invention]
However, cement and synthetic resin materials have insufficient adhesion to trees, and cannot be handled directly by hand, resulting in problems in workability and safety. Furthermore, in the case of a synthetic resin, it was not preferable in terms of environment. Therefore, a plant protection material that can be handled safely and easily, has excellent adhesion to trees, and can reliably prevent infection has been desired.
[0004]
[Means for Solving the Problems]
As a result of intensive studies to solve the above problems, the present inventors have found that polysaccharides are excellent as pasting agents for antibacterial agents for preventing infection of trees, and have reached the present invention. That is, the present invention relates to an antibacterial agent comprising fine particles of a titanium oxide-based or zinc oxide-based optical semiconductor pasted with a polysaccharide having gelling ability or a polysaccharide mixture containing at least one polysaccharide having gelling ability. It is a paste for plant protection comprising .
[0005]
DETAILED DESCRIPTION OF THE INVENTION
As the polysaccharide (including derivatives thereof) used as a pasting agent in the present invention, natural polysaccharides can be used, but from the viewpoint of imparting water resistance to the paste after coating, A polysaccharide mixture containing at least one polysaccharide having gelling ability is preferred. The polysaccharide having gelling ability is not particularly limited, and examples thereof include agar, alginic acid and salts thereof, carrageenan, konjac potato extract, locust bean gum / xanthan gum mixture, gellan gum and the like. Carrageenan is preferred from the viewpoint of stability over time.
[0006]
The polysaccharide having gelling ability referred to in the present invention includes polysaccharides that exhibit gelling ability by addition of a component such as a specific salt, etc. Polysaccharides that exhibit gelling ability by combination with other polysaccharides are also included. The addition of such a gelling polysaccharide improves the water resistance of the coated paste, and prevents the paste from peeling off or flowing out due to rain or water spray.
[0007]
The antibacterial agent contained in the paste of the present invention is not particularly limited as long as it can prevent infection of trees, but in terms of long-term stabilization of antibacterial performance, fine particles of inorganic semiconductors such as inorganic titanium dioxide and zinc oxide Is preferred. These photo-semiconductors are known to have photocatalytic action and antibacterial effect, but since they exist in the form of fine particles, they do not flow out due to rainfall or watering as long as they exist in the paste, and the antibacterial action is maintained. Is done.
[0008]
In addition, a coloring agent, a nutrient, a preservative, an inorganic filler, a humectant, etc. may be added and mixed suitably to the paste of this invention.
[0009]
【Example】
Hereinafter, the present invention will be described more specifically with reference to examples.
[0010]
(Example 1)
A paste was prepared with the following composition and filled into a tube.
Xanthan gum 0.5% by mass
Titanium oxide optical semiconductor powder 1.0% by mass
Glycerin 15.0% by mass
Silica powder 20.0% by mass
Sodium benzoate 0.5% by mass
Water 63.0% by mass
The obtained paste was applied to the cuts of the apple branch with a finger and compared with an untreated cut. The paste could be easily and uniformly applied to the entire cut with a finger. After confirming the condition of the cut after 3 months, the cut with this paste was found to be slightly outflowed against the untreated cut, but there was no abnormality in the cut itself. It was. In addition, after the paste was prepared, changes in the hardness and separation of the paste were confirmed for the tubes stored at room temperature for 6 months, but no changes were observed and the coating could be carried out smoothly.
[0011]
(Example 2)
A paste was prepared with the following composition and filled into a tube.
Carrageenan 1.0% by mass
Titanium oxide optical semiconductor powder 1.0% by mass
Glycerin 20.0% by mass
Silica powder 20.0% by mass
Sodium benzoate 0.5% by mass
57.5% by weight of water
The obtained paste was applied with fingers to the cuts of apple branches in the same manner as in Example 1 and compared with the untreated cuts. The paste could be easily and uniformly applied to the entire cut with a finger. When the condition of the cut after 3 months was confirmed, no outflow of the paste was observed in the cut to which this paste was applied, and no abnormality was found in the cut itself in response to the occurrence of corrosion in the untreated cut. In addition, after the paste was prepared, changes in the hardness and separation of the paste were confirmed for the tubes stored at room temperature for 6 months, but no changes were observed and the coating could be carried out smoothly.
[0012]
【The invention's effect】
Since the paste for plant protection of the present invention uses polysaccharides (including derivatives thereof) as a pasting agent, it can be safely and easily coated on the peeled-off portions and cuts of trees, and polysaccharides are natural products. Therefore, since it is excellent in affinity with the tree structure and has good adhesiveness with the tree, infection of the tree can be surely prevented. Furthermore, since the oxygen permeability and moisture permeability are maintained through the coating agent even after the paste is coated, an optimum environment for the tree can be maintained.

Claims (1)

ゲル化能を有する多糖類、又はゲル化能を有する多糖類を一種以上含む多糖類混合物によりペースト化した酸化チタン系又は酸化亜鉛系の光半導体の微粒子からなる抗菌剤を含んでなる、植物保護用ペースト。Plant protection comprising an antibacterial agent comprising fine particles of a titanium oxide-based or zinc oxide-based optical semiconductor pasted with a polysaccharide having gelling ability or a polysaccharide mixture containing at least one polysaccharide having gelling ability For paste.
JP2001251273A 2001-08-22 2001-08-22 Plant protection paste Expired - Fee Related JP4809552B2 (en)

Priority Applications (1)

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Applications Claiming Priority (1)

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JP2003063903A JP2003063903A (en) 2003-03-05
JP4809552B2 true JP4809552B2 (en) 2011-11-09

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Country Status (1)

Country Link
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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012067027A (en) * 2010-09-22 2012-04-05 Sumika Life Tech Co Ltd Aqueous gel composition, gel insecticide, method of killing insect pests, and insecticide tool
EP3386289B1 (en) * 2015-12-10 2020-08-12 Premier Citrus APZ, LLC Method for using light energy to facilitate penetration of substances in plants

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS554336A (en) * 1978-06-23 1980-01-12 Kyoritsu Sanitarii Kk Solid or pasty emulsion composition
JPH0830001B2 (en) * 1986-09-27 1996-03-27 神東塗料株式会社 Pasty wood antiseptic insecticide
JP2000287544A (en) * 1999-04-02 2000-10-17 Kyoee:Kk Controlling agent for tree and controlling of tree

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