JP4762072B2 - 畦 Block manufacturing method - Google Patents

Description

  The present invention relates to a method for manufacturing a kite block, and more particularly to a method for manufacturing a kite block using a regenerated polyolefin resin and fly ash.

Conventionally, for the purpose of cost reduction, the saddle block is made of a thermoplastic resin as a main raw material, and is manufactured using the following extrusion molding apparatus.
That is, an extruder for extruding the raw material by heating and melting, a flow path device for allowing the melt extruded from the extruder to flow into the mold, and a mold holding device for holding the mold, The provided extrusion molding apparatus is used (for example, refer patent document 1).
More specifically, as shown in FIG. 7, the extrusion molding apparatus 230 includes a vent type extruder 202 having a hopper 206 for charging raw materials, and a melt extruded from the vent type extruder 202 as a mold. A flow path device for flowing into 203 and a mold holding device 207 for holding the mold 203 are provided. Further, the discharge port of the vent type extruder 202 and the mold 203 are connected via a flow path device installed in the mold holding device 207. The mold holding device 207 is disposed on the discharge port side of the vent-type extruder 202, and a flow path device is installed near the center of the mold holding device 207 in the mold moving direction. A mold 203 is installed above the mold holding device 207. Here, a traveling rail 205a is provided above the mold holding device 207, and a plurality of molds 203 are movably installed on the traveling rail 205a.

On the other hand, a thermoplastic resin composition that is excellent in moldability, bending characteristics, and impact resistance and that can effectively use fly ash has been proposed (see, for example, Patent Document 2).
More specifically, the thermoplastic resin composition contains 1 to 50% by mass of an ethylene- (meth) acrylic acid ester copolymer and / or an ethylene-vinyl acetate copolymer, and the remainder contains a polyolefin resin. It comprises 0.1 to 5 parts by mass of a surface treating agent and 20 to 230 parts by mass of fly ash with respect to 100 parts by mass of the thermoplastic resin contained.
Japanese Patent Laying-Open No. 2005-410971 (Claims) JP-A-2005-187680 (Claims)

However, in the manufacturing method using the extrusion molding apparatus disclosed in Patent Document 1, even if it is a large molded product, there is little residual stress, and as a result, a wrinkle block excellent in durability and deformability can be obtained. Production costs were high and still economically disadvantageous.
Moreover, although the thermoplastic resin composition disclosed in Patent Document 2 is effectively used for fly ash, the main component is an ethylene- (meth) acrylate copolymer and / or ethylene-vinyl acetate. It is a copolymer and easily decomposed by heat or easily generates residual strain, so that it was unsuitable for injection molding of a large molded product such as a cocoon block. Furthermore, a predetermined amount of the surface treatment agent had to be used, and problems such as spillage to farmland where the straw block was used were observed.

Therefore, as a result of diligent investigation on the above-mentioned problems, a long and long ridge block having a predetermined shape is composed of a specific material as a main component, heated and mixed at a predetermined temperature, and injection molded in multiple stages. As a result, it was found that even a cocoon block, which is a large molded product, can be stably obtained at low cost as a hard / thick recycled product with reduced residual stress, and the present invention has been completed. It is.
In other words, an object of the present invention is to provide an economical and stable production of a cocoon block having a predetermined form by using a recycled polyolefin resin and fly ash as main components and adopting a predetermined injection molding method. It is to provide a method for manufacturing a block.

According to the present invention, the main plate and two side plates having different or the same length form a substantially U-shaped or substantially U-shaped cross-sectional shape, and the horizontally long eaves block It is a manufacturing method, Comprising: The manufacturing method of the eaves block characterized by including the following process (a)-(c) is provided, and can solve the problem mentioned above.
(A) A resin composition obtained by heating and mixing a resin composition containing 1 to 120 parts by weight of fly ash in a range of 150 to 250 ° C. with respect to 100 parts by weight of a recycled polyolefin resin as a main component. (B) An injection process in which the plasticized resin composition is injected into the mold in multiple stages using a plunger (c) The mold is cooled and plasticized. Molding process to make a ridge block molded product by solidifying

In other words, a large-sized molded product is formed by forming a cocoon block of a predetermined shape with a specific material (recycled polyolefin resin and fly ash) as a main component, heating and mixing at a predetermined temperature, and injection molding in multiple stages. Even a wrinkle block can be stably manufactured at a low cost as a hard / thick recycled product with reduced residual stress.
In addition, by adopting such heating and mixing temperature and multi-stage injection molding process, it is possible to effectively prevent thermal degradation and discoloration of recycled polyolefin resin without adding excessive antioxidants. Can do.
Moreover, the pressure can be changed for each stage by injecting it into the mold in multiple stages. Therefore, for example, by gradually increasing the pressure, it is easy to uniformly fill the resin composition in the mold, and it is possible to further reduce the residual stress in the wrinkle block that is a large molded product.
In addition, when multi-stage injection molding is performed, the main plate and the side plate are characterized in that traces easily remain depending on the number of multi-stages. However, since the fly ash on the surface of the heel block or the like shows a predetermined pattern, an effect that the decoration effect is excellent can be obtained.
In addition, the fly ash on the surface of the coral block shines in the outside light and the reflected light of the paddy field, and it looks whitish or looks like an arabesque pattern or a Pellsley pattern. You can get the effect of not getting close to birds such as birds and sparrows. Therefore, it is possible to obtain an effect that animal damage is reduced in paddy fields and the like using a straw block.

In addition, in carrying out the method for producing a kite block of the present invention, in the injection step (b), when the plasticized resin composition is added up, an injection speed of 0.1 to 30 minutes / one kite block It is preferable to inject in multiple stages.
By adopting such an injection speed, it is possible to further reduce the residual stress of the wrinkle block, which is a large molded product, and more effectively prevent thermal degradation and discoloration of the recycled polyolefin resin.

Further, in carrying out the manufacturing method of the saddle block of the present invention, in the injection step (b), the melt flow rate in the plasticized resin composition is 0.05 to 10 g / min (according to ASTM D1238, load 2.16 kg). , Measured at a temperature of 190 ° C.).
By using a resin composition having such a melt flow rate, it is possible to further reduce the residual stress of the cocoon block, which is a large molded product, and more effectively prevent thermal degradation and discoloration of the recycled polyolefin resin. Can do.

Moreover, when implementing the manufacturing method of the saddle block of this invention, it is preferable to mount a metal mold | die in an orthogonal | vertical direction in an injection process (b).
By using the resin composition having such a melt flow rate, the residual stress of the large block, which is a large molded product, can be further reduced, and subsequent mold cooling and removal of the vertical block can be easily performed. it can.

In carrying out the manufacturing method of the saddle block of the present invention, a cleaning step for filtering the plasticized resin composition is provided between the plasticizing step (a) and the injection step (b). Is preferred.
By providing such a cleaning process, it is possible to continuously and stably manufacture a large block molded cocoon block using recycled polyolefin resin or fly ash, which contributes to further cost reduction. be able to.

Moreover, when implementing the manufacturing method of the kite block of this invention, it is preferable to make the horizontal direction length of a kite block into the value within the range of 100-500 mm.
Even such a large-sized ridge block can reduce residual stress and can be manufactured continuously and stably.

Moreover, when implementing the manufacturing method of the scissors block of this invention, it is preferable that the side surface shape is a triangle and is provided with the further flat protrusion on the surface of the reinforcing rib.
Even such a ridge block having a complicated shape can reduce residual stress and can be manufactured continuously and stably.

Moreover, when implementing the manufacturing method of the collar block of this invention, it is preferable that the length of two side plates is the same, and makes the length of each side plate the value within the range of 10-50 cm.
Even with such an evenly shaped ridge block, the residual stress can be reduced, and it can be manufactured continuously and stably.

Further, in carrying out the manufacturing method of the saddle block of the present invention, the lengths of the two side plates are different, the length of one side plate is set to a value in the range of 30 to 50 cm, and the length of the other side plate Is preferably set to a value within the range of 3 to 20 cm.
Even such an unevenly shaped ridge block can reduce residual stress and can be manufactured continuously and stably.

  Hereinafter, an embodiment relating to a method for manufacturing a saddle block according to the present invention will be specifically described with reference to the drawings as appropriate.

[First embodiment]
In the first embodiment, as shown in FIGS. 1A to 1B or FIGS. 2A to 2B, the main plate and two side plates having different or the same length are substantially A method for manufacturing a scissor block having a letter-shaped or substantially square cross-sectional shape and having a horizontally long scissor block, comprising the following steps (a) to (c): It is a manufacturing method.
(A) A resin composition obtained by heating and mixing a resin composition containing 1 to 120 parts by weight of fly ash in a range of 150 to 250 ° C. with respect to 100 parts by weight of a recycled polyolefin resin as a main component. (B) An injection process in which the plasticized resin composition is injected into the mold in multiple stages using a plunger (c) The mold is cooled and plasticized. Fig. 1 (a)-(b) shows the mode and usage state of the heel block (type 1) when the lengths of both side plates are equal. FIGS. 2A to 2B show the state and use state of the saddle block (type 2) when the lengths of both side plates are different. However, the dimensions in FIGS. 1A and 2A are examples, and are not limited to these dimensions.

1. Plasticizing step (a)
(1) Recycled polyolefin resin The recycled polyolefin resin as the main component is preferably one containing a predetermined amount or more of recycled polypropylene resin or recycled polyethylene resin. Specifically, these recycled polypropylene resins and recycled polyethylene resins The content is preferably set to a value of 55% by weight or more with respect to the total amount of the recycled polyolefin resin.
The reason for this is that when the content is less than 55% by weight, not only the appearance of regenerated molded products and pellets is remarkably lowered, but also the adjustment of injection speed and melt flow rate during injection molding becomes difficult. Because there is.
Therefore, the content of the recycled polypropylene resin or the recycled polyethylene resin is more preferably set to a value within the range of 60 to 99% by weight, and within the range of 70 to 95% by weight with respect to the total amount of the recycled polyolefin resin. More preferably, it is a value.

Further, as the recycled polyolefin resin, it is preferable to use a recycled product obtained from a packaging film, a food film, a vehicle front panel, a vehicle bumper, a vehicle interior product, and the like.
The reason for this is that such recycled polyolefin resin is balanced in properties such as strength, heat resistance, and fluidity, and can greatly reduce the labor and cost of fractional collection.
In addition, the recycled polyolefin resin is often made of a thermoplastic olefin resin (TPO) having a melting point of 200 ° C. or higher, and rarely causes excessive phase separation or residual stress. Therefore, durability, heat resistance, or paintability can be improved in the obtained eaves block.

Moreover, it is preferable to grind | pulverize recycled polyolefin resin (a ground material, a pellet) using a crusher or a shear device, for example, to make the particle size into the value within the range of 0.01-20 mm.
This is because when the particle size of the recycled polyolefin resin is less than 0.01 mm, it may take excessive time and cost to produce. On the other hand, if the particle size of the recycled polyolefin resin exceeds 20 mm, it may be heated and mixed non-uniformly and it may be difficult to adjust the injection speed and the melt flow rate.
Therefore, when the recycled polyolefin resin is a pulverized product, the particle size is more preferably set to a value in the range of 0.1 to 15 mm, and further preferably set to a value in the range of 1 to 10 mm.
The shape of the pulverized product may be spherical or elliptical, but it is also preferably a polyhedron having many corners or a flake shape.

(2) Fly ash (2) -1 type The fly ash used in the present invention burns coal pulverized into powder in a thermal power plant in a boiler, and the particles of the combustion residue melted at that time are heated. Spherical particles that are suspended in the combustion gas and collected using, for example, a dust collector.
That is, by adding fly ash mainly composed of silica (SiO ₂ ), alumina (Al ₂ O ₃ ) or the like to the regenerated polyolefin resin, the weather resistance, mechanical strength, compression strain, In addition, by adjusting the fluidity and the like in a wide range, it is possible to obtain an aspect of a saddle block suitable not only for compatibility with the use environment but also for injection molding and the like.
In addition, by adding fly ash mainly composed of silica (SiO ₂ ) or the like to the regenerated polyolefin resin, the drainage, breathability, or water retention in the soot block is appropriately adjusted, and the use environment It is also possible to make a heel block with excellent compatibility.
Furthermore, since fly ash glows whitish by external light or reflected light of water, when mixed with recycled polyolefin resin to form a cocoon block, as described above, the effect of keeping small animals and birds away is obtained. be able to.

Here, the main components of fly ash are silica (SiO ₂ ) and alumina (Al ₂ O ₃ ).
For such a silica (SiO _2), based on the total amount, preferably a value within the range of 40 to 75 wt%, the alumina (Al ₂ O _3), based on the total amount, 15 to 35 A value within the range of% by weight is preferred.
Furthermore, fly ash contains iron oxide (Fe ₂ O ₃ ) in the range of 1 to 20% by weight or magnesium oxide (MgO) in the range of 0.1 to 10% by weight as a constituent component. It is also preferable to include in a range.
This is because the weather resistance and the mechanical strength can be further improved by adding such components. Also, if fly ash contains a predetermined amount of iron oxide (Fe ₂ O ₃ ) or magnesium oxide (MgO), the color unevenness is so strong that the flow unevenness when the glazed block is subjected to multistage injection molding is inconspicuous. This is because it can be done.
In addition, about the structural component of fly ash, it can obtain | require using the elemental-analysis method about an inorganic material, or an X-ray microanalyzer, for example.

(2) -2 Average particle diameter Moreover, it is preferable to make the average particle diameter of fly ash into the value within the range of 0.1-300 micrometers.
This is because when the average particle size of the fly ash is less than 0.1 μm, the weather resistance and mechanical strength may not be improved.
On the other hand, if the average particle size of the fly ash exceeds 300 μm, the fluidity is lowered and the moldability may be significantly lowered.
Therefore, the average particle size of fly ash is more preferably set to a value within the range of 1 to 150 μm, and further preferably set to a value within the range of 10 to 100 μm by weight.
The average particle size of fly ash can be determined, for example, from the micrograph using an image analysis device, or can be measured using a laser type or sedimentation type particle size distribution meter.

Further, regarding the average particle size of fly ash, the fineness (45 μm sieve residue) measured by a mesh sieving method is preferably 100 or less, more preferably 1 to 80. More preferably, the value is in the range of ˜40.
The reason for this is that when the fineness exceeds 100, the flowability of the regenerated polyolefin resin may be lowered, and the moldability may be greatly lowered. As a result, the weather resistance and mechanical strength of the obtained cocoon block are reduced. This is because there may be a significant decrease.
On the other hand, when the fineness of the fly ash is less than 1, it may be difficult to uniformly mix the recycled polyolefin resin or the fly ash itself may be difficult to handle.

(2) -3 Combination 1
It is also preferable to use a plurality of fly ash having different particle sizes as described above. More specifically, for example, it is preferable to use fly ash having a particle size of 1 to 40 and fly ash having a particle size exceeding 40 to 100 in combination.
The reason for this is that by using fly ash with different particle sizes, the weather resistance, mechanical strength, compression strain, fluidity, etc. of the reclaimed polyolefin resin can be adjusted even with relatively small amounts of use. It is because it can do.
In addition, although it is an example, it is preferable to make the usage rate of fly ash 40 to 100 or less into the value within the range of 1 to 120 parts by weight with respect to 100 parts by weight of fly ash having a particle size of 1 to 40.
In that case, it is preferable that the total addition amount of fly ash having different particle sizes is set to a value within the range of 10 to 60 parts by weight with respect to 100 parts by weight of the recycled polyolefin resin.

(2) -4 Combination 2
It is also preferable to use fly ash and clinker ash in combination. More specifically, for example, it is preferable to set the use ratio of clinker ash to a value within the range of 1 to 80 parts by weight with respect to 100 parts by weight of fly ash.
The reason for this is that by using clinker ash in this manner, the weather resistance, mechanical strength, compressive strain, fluidity, etc. of the regenerated polyolefin resin can be adjusted even with relatively small amounts of use. In other words, the drainage, breathability, or water retention of the dredge block can be adjusted in a wider range to provide a dredge block with excellent compatibility with the use environment.
Here, the form of the clinker ash to be used in combination is fine gravel or coarse sand. As its constituent components, for example, silica (SiO ₂ ) is 50 to 70% by weight, alumina (Al ₂ ) with respect to the total amount. 15 to 30% by weight of O ₃ ), ₃ to 15% by weight of iron oxide (Fe ₂ O ₃ ), 1 to 5% by weight of magnesium oxide (MgO), and 2 to 10% by weight of calcium oxide (CaO) It is preferable to set the value within the range.
When fly ash and clinker ash are used in combination, the total addition amount of fly ash and clinker ash should be within a range of 10 to 100 parts by weight with respect to 100 parts by weight of recycled polyolefin resin. Is preferable, and a value within the range of 20 to 80 parts by weight is preferable.

(2) -5 Addition amount The addition amount of fly ash is set to a value within the range of 1 to 120 parts by weight with respect to 100 parts by weight of the recycled polyolefin resin.
The reason for this is that when the amount of fly ash added is less than 1 part by weight, the weather resistance and mechanical strength of the soot block may be poorly improved.
Further, if the amount of fly ash added is too small, it will not be possible to remove it when stacking a plurality of straw blocks.
On the other hand, if the amount of fly ash added exceeds 120 parts by weight, the fluidity of the regenerated polyolefin resin is lowered, and the moldability may be greatly lowered.
Therefore, the amount of fly ash added is more preferably 10 to 80 parts by weight, and more preferably 20 to 50 parts by weight with respect to 100 parts by weight of the recycled polyolefin resin. Further preferred.
Here, in FIGS. 3A to 3D, the addition amount (parts by weight) of fly ash with respect to 100 parts by weight of the recycled polyolefin resin, the weather resistance, mechanical strength, shrinkage, and the recycled polyolefin resin The relationship with liquidity is shown.
From the characteristic curves shown in these figures, it was found that the weather resistance and mechanical strength of the cocoon block changed critically and increased as the amount of fly ash added increased. On the other hand, as the amount of fly ash added increases, the shrinkage rate in the cocoon block decreases, but the fluidity of the regenerated polyolefin resin changes critically and tends to decrease.
Therefore, by setting the addition amount of fly ash to a value within the range of 1 to 120 parts by weight, more preferably within the range of 50 to 80 parts by weight with respect to 100 parts by weight of the recycled polyolefin resin, It is understood that the balance of weather resistance, mechanical strength, shrinkage rate, and fluidity of the recycled polyolefin resin in the block is good.

(3) Additive (3) -1 types As additives to the resin composition, colorants (pigments, dyes), masking materials, antioxidants, ultraviolet absorbers, metal fillers, inorganic fillers, coupling agents, Examples of the lightening agent, the fiber material, the conductive material, the fluidizing agent, and the viscosity adjusting agent may be used alone or in combination of two or more.

(3) -2 Addition amount The addition amount of the additive is not particularly limited, but is, for example, a value within the range of 0.1 to 15% by weight with respect to the total amount. Is preferred.
The reason for this is that when the amount of the additive added is less than 0.1% by weight, the additive effect may not be exhibited. On the other hand, if the amount of the additive exceeds 15% by weight, the mechanical strength, durability, or flow characteristics of the resin composition may be significantly reduced.

(4) Plasticization condition (4) -1 temperature It is preferable that the plasticizing temperature is set to a value within the range of 150 to 250 ° C.
This is because when the plasticizing temperature is less than 150 ° C., the plasticization becomes insufficient and the molding processability may be greatly reduced. On the other hand, when the plasticizing temperature exceeds 250 ° C., the recycled polyolefin resin may be thermally decomposed or discolored.
Therefore, the plasticizing temperature is more preferably set to a value within the range of 160 to 230 ° C, and further preferably set to a value within the range of 180 to 210 ° C.

(4) -2 hours In addition, it is preferable to set the plasticizing time to a value within the range of 0.1 to 20 minutes.
This is because when the plasticizing time is less than 0.1 minutes, the mixed dispersion of the regenerated polyolefin resin and fly ash tends to be uneven. On the other hand, when the plasticizing time exceeds 20 minutes, the recycled polyolefin resin may be thermally decomposed or discolored depending on the plasticizing temperature.
Therefore, the plasticizing time is more preferably set to a value within the range of 0.5 to 10 minutes, and is preferably set to a value within the range of 1 to 5 minutes.

(4) -3 Plasticizing Device The plasticizing device 104 is preferably configured as shown in FIG.
That is, as the plasticizer 104, it is preferable to melt recycled polyolefin resin, fly ash, or the like supplied from the hopper 153 using a plasticizing screw or piston 142, and heat mix them with the heating cinder 141.

2. Injection process (b)
(1) Injection condition Moreover, it is preferable to make injection temperature into the value within the range of 180-300 degreeC.
This is because when the injection temperature is less than 180 ° C., the viscosity of the resin composition composed of the regenerated polyolefin resin and fly ash is too high, and it may be difficult to inject uniformly. . On the other hand, when the injection temperature exceeds 300 ° C., the recycled polyolefin resin may be thermally decomposed or discolored.
Therefore, the injection temperature is more preferably set to a value within the range of 190 to 270 ° C, and further preferably set to a value within the range of 200 to 250 ° C.
The injection temperature means the temperature of the nozzle tip in the injection molding apparatus, and can be measured using, for example, a thermocouple.

(2) Injection time Moreover, it is preferable to make injection time into the value within the range of 0.01 to 10 minutes.
This is because when the plasticizing time is less than 0.01 minutes, the injection molding of the resin composition composed of the regenerated polyolefin resin and fly ash tends to be excessively non-uniform.
On the other hand, when the plasticizing time exceeds 10 minutes, the recycled polyolefin resin may be thermally decomposed or discolored depending on the plasticizing temperature. Moreover, if the injection time is excessively long, it may adversely affect the cooling process of the saddle block.
Therefore, the plasticizing time is more preferably set to a value within the range of 0.1 to 5 minutes, and is preferably set to a value within the range of 0.5 to 3 minutes.

In addition, regarding the injection time, when the plasticized resin composition is injected in multiple stages, it is preferable to adjust the total injection time so that the injection speed is 0.1 to 30 minutes / one block injection speed. .
The reason for this is that by adopting such an injection speed, it is possible to further reduce the residual stress of the reed polyolefin block, which is a large molded product, and more effectively prevent thermal degradation and discoloration of the recycled polyolefin resin. This is because it can.

(3) Mold As shown in a part of FIG. 4, the mold 117 is preferably located at the end of the injection molding apparatus.
Here, the mold 117 of FIG. 4 shows a state in which the mold suitable for the saddle block in the case where the lengths of both side plates shown in FIG. For the saddle block in the case where the lengths of both side plates are different from each other, the side surfaces of the side blocks may be appropriately cut and removed after being molded using a mold so that the lengths of both side plates are equal.
And this metal mold | die 117 is comprised from the movable side metal mold | die 117a, the fixed side metal mold | die 117b, and two parts, The nozzle 114 of an injection molding apparatus is contained in a part of fixed side metal mold | die 117b, It is preferably fixed.

(4) Injection device Moreover, although a well-known thing can be used as an injection device, it is preferable to set it as the injection device 100 as shown in FIG. 4 as an example.
That is, a collecting chamber 110 for temporarily collecting the molten resin sent from the plasticizing device 104 is provided, and the molten resin sent from the plasticizing device 104 is used for the collecting chamber 110 and then into the high temperature channel 101. The protruding injection piston 135 and the like are preferably configured to inject molten resin.

(5) Cleaning device Moreover, it is preferable to provide a cleaning device for filtering the plasticized resin composition between the plasticizing device and the injection device.
The reason for this is that by providing such a cleaning device, a reed polyolefin resin or fly ash can be used to continuously and stably produce a large-sized molded eaves block. This is because it can contribute to cost reduction.
FIG. 5 shows an example of the cleaning device 200 as an example. According to the cleaning device 200, a hollow and cylindrical filter 202 is provided in the housing 201, and an inner chamber and an outer chamber are defined in relation to the filter 202. The melted material such as recycled polyolefin resin and fly ash is cleaned by the scraper 225 provided in the cleaning device 200.

3. Molding process (c)
(1) Cooling condition Moreover, it is preferable to make the cooling temperature of a metal mold into the value within the range of 10-80 degreeC.
This is because when the cooling temperature of the mold is less than 10 ° C., the mold made of a casting or the like may be thermally deteriorated.
On the other hand, if the cooling temperature of the mold exceeds 80 ° C., the resin composition constituting the heel block is not sufficiently solidified, and it may be difficult to maintain the desired shape. .
Therefore, the mold cooling temperature is preferably set to a value within the range of 20 to 75 ° C, and more preferably set to a value within the range of 30 to 70 ° C.

(2) Cooling device Further, the cooling device can be configured by spraying a cooling medium directly or by providing a cooling pipe through which the cooling medium has flowed on the back side of the mold.
In addition, in order to cool the metal mold | die of about 250-300 degreeC to less than 80 degreeC, as a cooling medium, cooling water, an alcohol compound, hydrocarbons, oils, hydrogen fluoride carbonized material, etc. are mentioned.

(3) Conveying device Further, it is necessary to convey the molded eaves block in order to cool it in another place or store it in a predetermined place.
On the other hand, the molded long eaves block usually has a weight of about 5 kg to 20 kg, although it depends on the size and shape.
Therefore, although not shown in the figure, after cooling in the mold arranged in the vertical direction and opening the mold, the vertical block against the ground is pulled out from the mold as it is by the transport device. At the same time, it is preferable to carry out complete cooling until it reaches room temperature while being rotated and inclined so as to be in the horizontal direction across both ends.
The reason for this is that by cooling in this way, thermal shrinkage during cooling is reduced and the residual stress can be reduced.
In addition, it can be said that it is further preferable to cool the cooling block while moving the roller block on the roller or the rotating plate so that the cooling medium (including air or the like) is uniformly applied from the periphery of the rod block during cooling.

4). As shown in FIG. 1 (a) or FIG. 2 (a), the basic structure of the eaves block includes two side plates 10a, 10b (20a) that are different in length or the same as the main plate 10d with anti-slip. 20b) has a substantially U-shaped or substantially U-shaped cross-sectional shape and is long in the horizontal direction.
And a main board is a member which protects an earthen paddle from upper direction with a side board, Comprising: After installation of a paddle block, it becomes a channel | path in a paddy field.
Further, the side plate is a member that protects the earthen paddle from the side in cooperation with the main plate, and after the paddle block is installed, it becomes a water retaining member for water in paddy fields and a protective member for small animals.
Here, it is preferable to set the horizontal length of the heel block to a value within the range of 100 to 500 mm.
The reason for this is that even such a wrinkle block of a large molded product can reduce residual stress and can be manufactured continuously and stably.

Further, as shown in FIG. 6 (b), on the surface of the square-bar-shaped reinforcing rib 10c arranged in parallel to the side plate 10a (10b), the side surface has a triangular shape and a flat plate-like further protrusion (triangle) (Projection) 10f is preferably provided.
The reason for this is that by providing such a triangular protrusion 10f, the square-bar-shaped reinforcing rib 10c can be further reinforced, and even when a plurality of ridge blocks are stacked, the triangular protrusion 10f functions as a stopper. This is because it becomes easy to remove later. In addition, such a reinforcing rib 10c or the triangular protrusion 10f on the surface of the reinforcing rib 10c can be easily and accurately injection-molded from two of a fixing mold and a movable mold.
In addition, according to the manufacturing method of this invention, even if it is such a complicated-shaped ridge block, while being able to reduce a residual stress, it can manufacture continuously and stably.

In addition, in the case of a saddle block (type 1) in which the lengths of the two side plates are the same, the length of each side plate is preferably set to a value in the range of 10 to 50 cm.
This is because even such an evenly shaped ridge block can reduce residual stress and can be manufactured continuously and stably.

Further, in the case of a saddle block (type 1) in which the lengths of the two side plates are different, the length of one side plate is set to a value within the range of 30 to 50 cm, and the length of the other side plate is set to 3 to 20 cm. A value within the range is preferable.
The reason for this is that even such a non-uniformly-shaped ridge block can reduce residual stress and can be manufactured continuously and stably.

Further, as shown in FIGS. 1A and 1B, it is preferable to provide a joint 10e (20e) for connection when using a plurality of heel blocks at the end of the heel block.
The form of the joint is not particularly limited, but may be, for example, a protrusion and a recess or hook engaged with the protrusion.

According to the manufacturing method of the cocoon block of the present invention, even if the cocoon block has a predetermined form, the recycled polyolefin resin and fly ash are the main components and a predetermined injection molding method is adopted, so that not only cost reduction is achieved. Moreover, it has become possible to produce a saddle block with excellent balance of mechanical properties and flowability.
And according to the manufacturing method of the soot block of this invention, since the regenerated olefin resin and fly ash are used as a main component, when discarding, it is easy to heat at low temperature and exhibit harmful gas even if burned There is no.
In addition, since a predetermined amount of fly ash is used for the regenerated olefin resin, it is possible to obtain an effect that the animal shines whitish, thereby preventing small animals and birds from approaching and reducing animal damage in paddy fields.
Furthermore, if the recycled polyolefin resin is biodegradable, it can be crushed and regenerated into paddy or paddy soil after being used for about 10 to 20 years.
In addition, although the manufacturing method of the cocoon block of the present invention uses a recycled polyolefin resin and fly ash as the main components and is a manufacturing technology that places an emphasis on cost reduction, a normal polyolefin resin is used instead of the recycled polyolefin resin. It can also be applied.

(A)-(b) is a figure provided in order to demonstrate the outline | summary of the saddle block (type 1) with which the length of a side plate is equal. (A)-(b) is a figure provided in order to demonstrate the outline | summary of the eaves block (type 2) from which the length of a side plate differs. (A)-(d) is a figure provided in order to demonstrate the influence of the addition amount of a fly ash with respect to the various characteristics of a resin composition. It is a figure provided in order to demonstrate the injection device provided with the plasticizing apparatus. It is a figure provided in order to explain a cleaning device. (A)-(b) is a figure provided in order to demonstrate a rib for reinforcement and a triangular protrusion. It serves for explaining a conventional extrusion molding machine.

Explanation of symbols

10: Hail block (Type 1)
10a: Left side plate 10b: Right side plate 10c: Rib 10d: Main plate 10e: Joint 10f: Triangular protrusion 11: Rice 12: Water 13: Earth 20: Coral block (Type 2)
20a: left side plate 20b: right side plate 20c: rib 20d: main plate 20e: joint 100: injection molding apparatus 101: high temperature channel 104: plasticizing apparatus 114: nozzle 117: mold 117a: movable side mold 117b: fixed side mold 153: Hopper 200: Cleaning device

Claims (9)

The main plate and two side plates having different or the same length have a substantially U-shaped or substantially U-shaped cross-sectional shape, and a method for producing a horizontally long eaves block, The manufacturing method of the ridge block characterized by including the following process (a)-(c).
(A) A resin composition obtained by heating and mixing a resin composition containing 1 to 120 parts by weight of fly ash in a range of 150 to 250 ° C. with respect to 100 parts by weight of a recycled polyolefin resin as a main component. (B) An injection process in which the plasticized resin composition is injected in multiple stages using a plunger in a mold (c) The mold is cooled and plasticized Molding process to mold the ridge block by solidifying the resin composition   In the injection step (b), the plasticized resin composition is injected in multiple stages so that the injection speed becomes 0.1 to 30 minutes / one block when the total is added. The manufacturing method of the scissors block of Claim 1 to do.   In the injection step (b), the melt flow rate in the plasticized resin composition is 0.05 to 10 g / min (based on ASTM D1238, measured at a load of 2.16 kg and a temperature of 190 ° C.) The method for manufacturing a saddle block according to claim 1 or 2.   The said block is mounted in the said injection | pouring process (b), The manufacturing method of the scissors block as described in any one of Claims 1-3 characterized by the above-mentioned.   5. A cleaning step for filtering the plasticized resin composition is provided between the plasticizing step (a) and the injection step (b). The manufacturing method of the cocoon block as described in claim | item.   The horizontal length of the said heel block is made into the value within the range of 100-500 mm, The manufacturing method of the heel block as described in any one of Claims 1-5 characterized by the above-mentioned.   The back surface of the main plate and the two side plates has reinforcing ribs, and the surface has a triangular shape on the side surface and further includes a flat plate-like protrusion. The manufacturing method of the cocoon block as described in any one.   The length of the said 2 side board is the same, Comprising: The length of each side board shall be a value within the range of 10-50 cm, The scissor block as described in any one of Claims 1-7 characterized by the above-mentioned. Manufacturing method.   The lengths of the two side plates are different, and the length of one side plate is set to a value within a range of 30 to 50 cm, and the length of the other side plate is set to a value within a range of 3 to 20 cm. The manufacturing method of the cocoon block as described in any one of Claims 1-7.

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