JP4744248B2 - RE oxide superconducting wire joining method - Google Patents

Description

The present invention relates to a joining method of joining RE-based oxide superconducting wires having a laminated structure coated with metal without degrading excellent superconducting characteristics, and RE-based oxide superconducting having a laminated structure coated with metal. The present invention relates to a joining method for joining a wire and a metal material or a member coated with a metal material.

  Applications of superconducting wires include coils, current leads, power transmission lines, etc., and many of them have already been put into practical use using intermetallic compound superconducting wires, Bi-based oxide superconducting wires, and the like.

  However, the intermetallic compound superconducting wire has a low critical temperature, while the Bi-based oxide superconducting wire has a high superconducting critical temperature, but the critical current density in a magnetic field at a liquid nitrogen temperature is a serious problem. For the above reasons, the former is a practical application at the liquid helium temperature, and the latter is a practical application only in the temperature range from the liquid helium temperature to about 20K.

  As for current leads, Bi-based oxide superconducting materials have been put into practical use at liquid nitrogen temperature, but the critical current density suddenly decreases in a magnetic field (particularly in a vertical magnetic field). There are still problems such as a limited layout in the apparatus and a quenching of the superconducting phenomenon easily.

  However, if RE-based oxide superconducting wires are used, a wide range of applications at liquid nitrogen temperature is possible, and the running cost required for cooling is reduced compared to applications of intermetallic compound superconducting wires and Bi-based oxide superconducting wires. It can be significantly reduced.

  Furthermore, since the RE-based oxide superconducting wire has a small decrease in critical current density in a magnetic field, the layout limitation in application to current leads is greatly relaxed compared to the case of using a Bi-based oxide superconducting wire. In general, excellent transport properties can be expected compared to intermetallic compound superconducting wires and Bi-based oxide superconducting wires in general applications.

  When putting such RE-based oxide superconducting wires into practical use, it is necessary to lengthen them. In particular, the length of RE-based oxide superconducting wires that can be continuously manufactured is not long enough for the application. It is essential to join the wires. In addition, in the application of the RE-based oxide superconducting wire, it is inevitably necessary to connect the RE-based oxide superconducting wire and the normal conducting member. For example, the joining of the RE-based oxide superconducting wire and the metal member is also performed. It is essential.

  For this reason, RE-based oxide superconducting wires or RE-based oxide superconducting wires and metal members must be joined. The transport characteristics, critical temperature, irreversible magnetic field, etc. of RE-based oxide superconducting wires In order not to impair the excellent superconducting properties, a low resistance junction must be formed.

  In the joining technique used for putting superconducting wire into practical use, superconducting joining that does not impair the superconducting properties at the joint is preferable for joining RE-based oxide superconducting wires, but at present, the technology has not been sufficiently developed. First, it is a mainstream to form a low-resistance joint using a low-resistance material such as solder (for example, see Patent Document 1).

  Soldering is a simple joining method. However, if the joining area is not increased, a low resistance cannot be ensured in the joining part, so the length of the joining part inevitably increases. Therefore, soldering is not necessarily an optimal joining method when a long superconducting wire is manufactured by joining.

  In addition, as a technique for forming a low-resistance joint, a joining method that does not use solder has been proposed (see, for example, Patent Document 2). However, since this joining is performed in a vacuum / high temperature, the RE system is used. When used as a joining method for oxide superconducting wires, oxygen is dissociated from the RE oxide layer of the RE oxide superconducting wire at high temperatures, and the superconducting properties of the RE oxide superconducting wire are impaired. .

  After all, a joining method that does not use solder is not necessarily an appropriate joining method when a long RE-based oxide superconducting wire is manufactured by joining.

JP 2000-133067 A Japanese Patent Laid-Open No. 11-16618

  The merit of replacing RE-based oxide superconducting wires with excellent superconducting properties at high temperatures such as liquid nitrogen temperature and high magnetic fields in place of intermetallic compound superconducting wires and Bi-based oxide superconducting wires as practical wires is: It is extremely large from the viewpoint of resource saving and energy saving.

Accordingly, the present invention is based on the above merits, and (i) without sacrificing the excellent characteristics of the RE-based oxide superconducting wire having a laminated structure that stably has low loss and high transport characteristics at liquid nitrogen temperature, and (Ii) It is an object of the present invention to provide a bonding method that can form a low-resistance bonding portion easily and with good reproducibility without requiring treatment such as oxygen annealing after bonding.

RE _{1 + x} Ba _2-x Cu ₃ O _y (RE oxide), which is a typical RE oxide superconducting material, is used for pinning centers in order to obtain a high critical current density (J _c ). or contain non-superconductive material, although it may of additives such as Ca is added, both the oxygen amount y in _{RE 1 + x Ba 2-x} Cu 3 O y is the oxygen partial pressure - temperature Depending on conditions, it changes reversibly in the range of 6+ (1/2) x to 7+ (1/2) x.

However, if the RE oxide is less than 6.8, the RE oxide superconducting material is inherently in critical temperature (T _c ), critical current density (J _c ), critical magnetic field (H _c ), etc. Does not exhibit the superior superconducting properties of the material, and even if it is made into a wire, sufficient transport properties for practical use cannot be obtained.

Therefore, when joining a RE-based oxide superconducting wire having a laminated structure, if the oxygen is dissociated from the RE-based oxide superconducting layer by heat treatment at the time of joining and y becomes less than 6.8, after joining, On the other hand, it is necessary to perform heat treatment such as oxygen annealing for introducing oxygen.

If the present inventor can form a low-resistance junction while maintaining the excellent superconducting properties of the RE-based oxide superconducting wire having a laminated structure, a treatment such as oxygen annealing after the joining becomes unnecessary, and thus the present invention is simple. and efficiently leads to the idea of the possible joining the RE-based oxide superconducting wire of the laminated structure, while maintaining excellent superconducting properties of the RE-based oxide superconducting wire of the laminated structure, forming a junction of low resistance I studied earnestly about how to do.

In order to form a low-resistance junction while maintaining the excellent superconducting properties of the RE-based oxide superconducting wire with a laminated structure, it maintains the superconducting properties while maintaining low resistance and the required bonding strength. Therefore, the relationship between the oxygen partial pressure and the temperature at which oxygen can be introduced simultaneously must be considered.

The present inventor has continued diligent research in consideration of the above-mentioned relationship. As a result, the RE-based oxide superconducting wire having a laminated structure coated with a metal material and a member coated with the metal material or the metal material (the laminated structure (Including RE partial oxide superconducting wire) (i) the oxygen partial pressure and the temperature of the bonding surface are set in the RE oxide constituting the superconducting layer of the RE oxide superconducting wire during the bonding process. In an oxidizing atmosphere maintained in an oxygen partial pressure-temperature range that can secure the amount of oxygen necessary for the RE-based oxide to exhibit superconducting properties , the joining surfaces are directly stacked (no solder or the like is required), (ii It has been found that if a thermal energy is applied to the joint surface and a pressure is applied, a low resistance joint having the required joint strength can be formed without impairing the superconducting properties of the RE-based oxide superconducting wire.

  The present invention has been made based on the above findings, and the gist thereof is as follows.

(1) In the joining method for joining RE-based oxide superconducting wire and a metal or metal material coated with it are members of the layered structure is coated with a metallic material (including RE-based oxide superconducting wire of a laminated structure) ,
(I) The oxygen partial pressure and the temperature of the bonding surface are required for the RE oxide to exhibit superconducting properties in the RE oxide constituting the superconducting layer of the RE oxide superconducting wire during the bonding process. In an oxidizing atmosphere maintained in an oxygen partial pressure-temperature range that can secure an oxygen amount ,
(Ii) A method for joining RE-based oxide superconducting wires, in which thermal energy is applied to a joint surface obtained by directly overlapping metal surfaces of a joint portion, and a pressure is applied to join the joint surface.
However, RE is one or more elements of La, Nd, Sm, Eu, Gd, Dy, Ho, Er, Tm, Yb, Lu, and Y.

( 2 ) The method for bonding an RE-based oxide superconducting wire according to (1 ) , wherein the bonding portion is heated with respect to the application of thermal energy to the bonding surface.

( 3 ) With respect to the application of thermal energy to the joining surface, the joining portion is subjected to any one or more treatments of energization, ultrasonic wave or electromagnetic wave application, and friction, and thermal energy is applied to the joining surface. The RE-based oxide superconducting wire joining method according to the above (1 ), which is induced.

( 4 ) Regarding the application of thermal energy to the bonding surface, the bonding portion is heated, and the bonding portion is subjected to any one or more treatments of energization, ultrasonic wave or electromagnetic wave application, and friction. The RE oxide superconducting wire joining method according to (1 ), wherein heat energy is induced on the joining surface.

( 5 ) The superconducting layer of the RE-based oxide superconducting wire is mainly composed of a RE-Ba-Cu-O-based oxide, and any one of (1) to ( 4 ) above Joining method of RE oxide superconducting wire.

( 6 ) The metal material is any one of Au, Ag, Cu, Pt, Ni, Al, Ti, W, In, Ir, and Rh, or any one of alloys containing these elements. The RE oxide superconducting wire joining method according to any one of (1) to ( 5 ) above, wherein

According to the present invention, compromising the RE-based oxide superconducting wire coated laminated structure with a metal, the coated member of a metal material or a metal, excellent superconducting properties of the RE-based oxide superconducting wire of a laminated structure In addition, it is possible to simply and efficiently join without requiring post-treatment after joining, and to form a joint having low resistance (reducing the conventional joint resistance by 1/10 or more) with good reproducibility. it can.

When joining RE-based oxide superconducting wires having a laminated structure covered with a metal material, the Ag layer (protective layer) at the end (joint) is opposed to each other, and an arbitrary area is overlapped to form an oxidizing atmosphere. among, but the heat treatment under pressure to the joining surface, this heat treatment, oxygen is dissociated from the RE-based oxide forming the superconducting layer of the RE-based oxide superconducting wire of the laminated structure, superconductivity such as T _c and J _c The properties must not be impaired.

The inventor forms two RE-based oxide superconducting wires 4 (a RE-based oxide superconducting layer 1 on a base material 3 and an Ag layer 2 on the RE-based oxide superconducting layer 1 in the bonding form shown in FIG. Is fixed under a required pressure, and heat treatment including cooling to room temperature (furnace cooling) is performed in an argon atmosphere and an oxygen atmosphere, and the resistance value of the junction and T _c And J _c were measured.

  The results are shown in Table 1.

From Table 1, when the heat treatment including cooling to room temperature is performed in an argon atmosphere, the resistance value of the junction is high, and T _c and J _c cannot be measured, and the superconducting characteristics are completely lost. I understand. On the other hand, when the heat treatment including cooling to room temperature is performed in a pure oxygen atmosphere, it can be seen that the resistance value of the joint is low and T _c and J _c are not changed before and after the joining.

  FIG. 2 shows a cross section (magnification × 50) of the joint portion of the Y-based oxide superconducting wire observed with an optical microscope. In the joint portion, it is necessary to be densely joined from the viewpoint of ensuring required strength and conductivity. According to the present invention, as shown in FIG. It is closely attached.

Based on the above findings, in the present invention, a laminated structure RE-based oxide superconducting wire coated with a metal material and a metal material or a member coated with a metal material ( stacked-structured RE-based oxide superconducting wire) Including)
(I) In an oxidizing atmosphere
(Ii) The basic idea is to apply thermal energy to the joint surface obtained by directly overlapping the metal surfaces of the joint portion and to apply pressure to join the joint surface.

  However, RE is one or more elements of La, Nd, Sm, Eu, Gd, Dy, Ho, Er, Tm, Yb, Lu, and Y.

RE oxides constituting the superconducting layer of the RE oxide superconducting wire are RE _{1 + x} Ba _2−x Cu ₃ O _y (0 ≦ x ≦ 0.2), REBa ₂ Cu ₄ O ₈ , RE ₂ Ba. ₄ Cu ₇ O _{15 and the} like, and these are the main components, and non-superconducting such as RE ₂ O ₃ , CeO ₂ , RE ₂ BaCuO ₅ (RE ₄ Ba ₂ Cu ₂ O ₁₀ when RE = Nd, La) One in which phases are dispersed or one to which Ca, Mg, Sr, Zr, Zn, Ti, Hf, or the like is added.

  The non-superconducting phase and additives are not particularly limited.

The RE-based oxide superconducting wire having a laminated structure usually has a surface of Au, Ag, Cu, Pt for reasons such as protection of the superconducting layer, bypass of current during quenching, or release of heat generated by voltage generated by quenching. , Ni, Al, Ti, W, In, Ir, and Rh, or any one of alloys containing these elements.

When joining a RE-based oxide superconducting wire having a laminated structure having such a covering metal layer, the surfaces of the covering metal layers are overlapped with each other at a required area at the joint. In this case, the surface treatment on the surface of the coated metal layer is not particularly required. However, in order to obtain a tighter and lower resistance bonding, the surface of the coated metal layer is subjected to a surface cleaning treatment such as washing or polishing. May be.

  For example, the joining portion obtained by superimposing the surfaces of the coated metal layers is fixed under a joining form as shown in FIG. 1A, and the joining portion is uniformly pressurized. Moreover, if the joining form as shown in FIG. 1B is adopted, the direction of the superconducting layer of the RE-based oxide superconducting wire can be made uniform.

  What is necessary is just to select suitably the pressure loaded to a junction part with the kind of coating metal, and a contact area, and it is not specifically limited. The pressure is usually preferably 10 MPa or more in terms of forming a tighter and lower resistance bond, but may be less than 10 MPa as long as a tighter and lower resistance bond can be formed.

  The atmosphere covering the bonding portion may be an atmosphere containing an oxidizing gas, and is not limited to a specific atmosphere, but is any one of a pure oxygen gas atmosphere, a mixed gas atmosphere of inert gas and oxygen, and air Is preferable.

The atmospheric pressure (total pressure) of the oxidizing atmosphere is not particularly limited, but the amount of oxygen necessary for the superconducting layer to exhibit superconducting properties (for example, RE _{1 + x} Ba _2-x Cu ₃ O _y In this case, it takes a long time to obtain y of 6.8 or more), and the superconducting layer may not be able to reliably obtain the oxygen amount in a stable manner, so that the atmospheric pressure (total pressure) Is preferably 1 atm or more in terms of shortening the junction time (that is, the time for introducing oxygen into the RE-based oxide) and securing the amount of oxygen in the stable RE-based oxide.

  In the present invention, the oxygen partial pressure of the oxidizing atmosphere is important, and this point will be described later.

  In the oxidizing atmosphere, heat energy is applied to the joint surface that has been uniformly pressurized at a required pressure to heat the joint surface.

  The method of applying thermal energy to the joint surface is not particularly limited, but may be performed by any one of heating of the joint, energization of the joint, application of ultrasonic waves or electromagnetic waves, and friction of the joint. preferable. Moreover, you may use together two or more of the methods of providing these thermal energy.

  The heating of the bonding portion may be performed by directly heating the bonding portion in an oxidizing atmosphere, or the bonding portion may be held in a heated oxidizing atmosphere.

  The energization is a method in which a current is passed across the bonded surfaces that are superimposed and pressed, and Joule heat is generated by the resistance generated on the bonded surfaces. The application of ultrasonic waves or electromagnetic waves is a method in which vibration is induced by external energy generated by ultrasonic waves or electromagnetic waves in the metal atoms on the bonded surfaces that are superposed and pressed. Friction is a method of generating frictional heat at the joint by, for example, rubbing the joint surfaces that are superposed and pressed together at high speed.

As described above, in order to form a low-resistance junction while maintaining the excellent superconducting characteristics of the RE-based oxide superconducting wire having a laminated structure, a junction that secures low resistance and required junction strength, and superconductivity Oxygen partial pressure at which oxygen can be introduced simultaneously to maintain the characteristics (for example, in the case of RE _{1 + x} Ba _2-x Cu ₃ O _y , the oxygen partial pressure at which y is 6.8 or more) The temperature relationship must be taken into account.

In the present invention, the oxygen partial pressure of the oxidizing atmosphere and the temperature of the bonding surface are adjusted during the bonding process including the cooling process after bonding, in the RE-based oxide constituting the superconducting layer of the RE-based oxide superconducting wire having a laminated structure. In addition, the RE oxide is maintained in an oxygen partial pressure-temperature region that can secure the amount of oxygen necessary for exhibiting superconducting properties. This is a feature of the present invention.

For example, when the RE oxide is RE _{1 + x} Ba _2−x Cu ₃ O _y , the oxygen partial pressure and temperature during the bonding process including the cooling process after bonding are set such that oxygen becomes y 6.8 or more. It must be maintained in the partial pressure-temperature range.

Although this oxygen partial pressure-temperature region varies depending on the RE oxide, for example, in the case of YBa ₂ Cu ₃ O _y , it is a region below the oxygen partial pressure-temperature curve shown in FIG.

3 is shown in FIG. 3 described in a paper by J. Shimoyama et al. (MRS Proceedings, 689 (2002) 265). In 1 (Oxygen nonstoichiometry of YBa ₂ Cu ₃ O _y ), the oxygen partial pressure and temperature at y = 6.8 were read and prepared.

That is, when RE _{1 + x} Ba _2-x Cu ₃ O _y is bonded to a RE-based oxide superconducting wire having a laminated structure in which a superconducting layer is formed, oxygen content is reduced during the bonding process including the cooling process after bonding. The pressure and temperature must be maintained in the region below the oxygen partial pressure-temperature curve shown in FIG.

Maintaining oxygen partial pressure and temperature related to the above-mentioned bonding process in the above-mentioned region, joining oxygen to ensure low resistance and required bonding strength, and introducing oxygen into RE-based oxides to maintain superconducting characteristics in the superconducting layer Can be performed simultaneously, and a low-resistance junction can be formed while maintaining the excellent superconducting properties of the RE-based oxide superconducting wire having a laminated structure .

  Hereinafter, examples of the present invention will be described, but the conditions adopted in the examples are one condition example adopted for demonstrating the feasibility or reproducibility of the present invention, and the present invention is included in this one condition example. It is not limited.

  The present invention can adopt various conditions as long as the object of the present invention is achieved without departing from the gist of the present invention.

Example 1
An Ag layer at each end of two Y-based oxide superconducting wires laminated in the order of Gd ₂ Zr ₂ O ₇ , CeO ₂ , YBa ₂ Cu ₃ O _y , Ag on the Hastelloy is 2 × Overlaid with an area of 5 mm ² .

  In particular, surface treatment such as cleaning or polishing was not performed on the Ag layer in the overlapped portion, but in order to measure accurate IV characteristics at the joint, in a predetermined portion of the Ag layer other than the overlapped portion, As shown in FIG. 4, the etching which removes Ag layer 2 was performed, and superconducting layer 1 was exposed.

  The removal of this Ag layer cuts off the current in the Ag layer when measuring the IV characteristics at the junction of the joined Y-based oxide superconducting wire, and the current flow in the junction becomes superconducting layer-Ag layer. -A superconducting layer.

  As shown in FIG. 5, the portion where the Ag layers of the Y-based oxide superconducting wire are opposed to each other is sandwiched from above and below by a plate 5 (for example, an Inconel plate), and both ends of the plate 5 are fixed by bolts and nuts 6. did. In this fixed state, the load applied to the joint surface of the Y-based oxide superconducting wire was substantially uniform and was about 50 MPa at room temperature.

  The joint in the fixed / pressurized state was heated to 500 ° C. in a pure oxygen atmosphere, held for 1 hour, and then furnace-cooled to room temperature. After the heat treatment in the oxidizing atmosphere was completed, the plate that had fixed the joint was removed, connected as shown in FIG. 6, and the IV characteristics were measured in liquid nitrogen.

As a result, the voltage at the junction increased in proportion to the current and exhibited ohmic IV characteristics. When the resistance is calculated from the result, it is 0.1 μΩ, and when this is converted into the resistance of the unit area, it is 10 nΩcm ² . This resistance value is one tenth of the resistance value obtained with the prior art.

  Further, it was confirmed by a simple tensile test that the joint has a joint strength that can sufficiently withstand a load applied in the longitudinal direction of the wire when used as a wire.

Furthermore, it joined by the method similar to the said joining method, making the joining area 2 * 10mm < ² >, 2 * 20mm < ² >, and measured the resistance of the junction part. As a result, the resistance values were 0.08 μΩ and 0.05 μΩ, respectively, and it was confirmed that the resistance value could be further reduced by increasing the junction area.

(Example 2)
A Y-based oxide superconducting wire laminated in the order of Gd ₂ Zr ₂ O ₇ , CeO ₂ , YBa ₂ Cu ₃ O _y , Ag on Hastelloy is cut out into a 2 × 70 mm ² shape, as shown in FIG. Wiring was performed, and IV characteristics were measured in liquid nitrogen. Next, the said wire was cut | disconnected in the center, the Ag layer of the edge part of two wires was made to oppose, and it overlap | superposed by the area of 2 * 20 mm < ² > (refer Fig.1 (a)).

  The Ag layer in the overlapped portion was not particularly subjected to surface treatment such as cleaning or polishing, and the portion where the Ag layer of the Y-based oxide superconducting wire was opposed to each other was fixed with an Inconel jig ( FIG. 8). In this fixed state, the load applied to the joint surface of the Y-based oxide superconducting wire was almost uniform and was about 10 MPa at room temperature.

  The joint in the fixed / pressurized state was heated to 500 ° C. in a pure oxygen atmosphere, held for 1 hour, and then furnace-cooled to room temperature. After the heat treatment in the oxidizing atmosphere was completed, the Inconel jig that fixed the joint was removed, connected as shown in FIG. 6, and the IV characteristics were measured in liquid nitrogen. The result is shown in FIG.

  As shown in FIG. 9, a current equivalent to that of the Y-based oxide superconducting wire before joining can be passed through the Y-based oxide superconducting wire after being joined by the method according to the present invention. Therefore, it has been confirmed that this joining method enables joining without degrading the superconducting layer of the superconducting wire.

Also, the resistance of the junction was calculated from the current and voltage values measured by a device capable of detecting a low voltage, and it was 0.03 μΩ, which was about 10 nΩcm ² when converted to a unit area resistance.

(Comparative example)
A Y-based oxide superconducting wire layered in the order of Gd ₂ Zr ₂ O ₇ , CeO ₂ , YBa ₂ Cu ₃ O _y , Ag on Hastelloy is placed on a hot plate heated to 250 ° C. An adhesive layer such as indium was melted and applied to the Ag layer. As a result, the commercially available solder had poor wettability on the Ag layer, aggregated in a spherical shape, and could not be applied uniformly. On the other hand, indium was very wettable on the Ag layer and could be applied uniformly.

Next, a joining experiment of a Y-based oxide superconducting wire was performed using indium. The Y-based oxide superconducting wire was cut into a 2 × 70 mm ² shape, connected as shown in FIG. 7, and the IV characteristics were measured in liquid nitrogen. Next, the said wire was cut | disconnected in the center and the melted indium was apply | coated uniformly on the 20-mm Ag layer from the edge of two wires, respectively.

The indium was applied by melting indium on a hot plate heated to 250 ° C. in the atmosphere. The Ag layers coated with molten indium were opposed to each other as shown in FIG. 10 so as to overlap each other with an area of 2 × 20 mm ² , removed from the hot plate as they were, and cooled and joined.

  The wire joined using the indium was connected as shown in FIG. 6, and the IV characteristics were measured in liquid nitrogen. The result is shown in FIG.

  As shown in FIG. 11, the Y-based oxide superconducting wire joined using indium can pass the same current as the Y-based oxide superconducting wire before joining. However, the generated voltage is much higher than the voltage generated in the wire joined by the method of the present invention shown in FIG. 9, and the resistance of the junction is calculated from the current and voltage values read in the vicinity of Ic. It was about.

  This is about 10 times the resistance of the above (Example 2), and it can be said that the resistance increases because the resistance of indium and the contact resistance of indium and the Ag layer are added. Compared with this, this bonding method can suppress the contact resistance between the Ag layer and the YBCO layer and the resistance other than the Ag layer to a very low value even if a voltage is generated. It was confirmed.

(Example 3)
_Two Y-based oxide superconducting wires laminated in the order of Gd ₂ Zr ₂ O ₇ , CeO ₂ , YBa ₂ Cu ₃ O _y , Ag on Hastelloy are cut out into a 2 × 70 mm ² shape, and FIG. As shown in Fig. 4, the wires were connected, and each IV characteristic was measured in liquid nitrogen. Next, one of the wires is cut at the center, and the other is cut at both ends to form a shape of 2 × 40 mm ² , with the Ag layer facing as shown in FIG. Overlapping with an area of 2 × 40 mm ² .

  The Ag layer in the overlapped portion was not particularly subjected to surface treatment such as cleaning or polishing, and the portion where the Ag layer of the Y-based oxide superconducting wire was opposed to each other was fixed with an Inconel jig. In this fixed state, the load applied to the joint surface of the Y-based oxide superconducting wire was almost uniform and was about 10 MPa at room temperature.

  The joint in the fixed / pressurized state was heated to 500 ° C. in a pure oxygen atmosphere, held for 1 hour, and then furnace-cooled to room temperature. After the heat treatment in the oxidizing atmosphere was completed, the Inconel jig that fixed the joint was removed, connected as shown in FIG. 12, and the IV characteristics were measured in liquid nitrogen.

  It was confirmed that the Y-based oxide superconducting wire after joining by the method according to the present invention can pass the same current as the Y-based oxide superconducting wire before joining. Therefore, it has been confirmed that this joining method enables joining without degrading the superconducting layer of the superconducting wire.

As described above, according to the present invention, the RE-based oxide superconducting wire having a laminated structure coated with metal and the metal material or a member coated with metal impair the superconducting properties inherent in the superconducting wire. Therefore, it is possible to easily and efficiently join without requiring post-treatment after joining, and to form a low-resistance joint with good reproducibility.

  Therefore, the present invention can be widely used for resource saving / energy technology, etc. in addition to a strong magnetic field generating coil, a current lead, and high voltage power transmission, and its applicability is extremely large.

It is a side view which shows the joining form of RE type oxide superconducting wire. (A) shows the joining form which makes a superconducting layer oppose, (b) shows the joining form which arranges a superconducting layer. It is a figure which shows the cross section (magnification x50) of the junction part of the joined Y type oxide superconducting wire. It is a diagram illustrating a YBa ₂ Cu ₃ O _y of y = 6.8 the oxygen partial pressure and temperature relation of. It is a top view which shows the form after removing the Ag layer of a Y-type oxide superconducting wire. It is a perspective view which shows the one aspect | mode which fixes the junction part of RE type oxide superconducting wire. It is a side view which shows the connection for measuring the IV characteristic in the junction part of a Y type oxide superconducting wire. It is a side view which shows the connection for measuring the IV characteristic before joining of a Y-type oxide superconducting wire. It is a perspective view which shows the one aspect | mode which fixes the junction part of RE type oxide superconducting wire. It is a figure which shows the IV characteristic before joining of Y type oxide superconducting wire, and after joining in the form of Fig.1 (a). As shown in FIG. 6, the IV characteristic after bonding is an IV characteristic measured with the bonding portion interposed therebetween. It is a side view which shows the one aspect | mode which joins RE type oxide superconducting wire using a contact bonding layer with the joining form of Fig.1 (a). It is a figure which shows the IV characteristic after joining in the form of FIG. 10 before joining of a Y type oxide superconducting wire, and using an indium for an adhesion layer. As shown in FIG. 6, the IV characteristic after bonding is an IV characteristic measured with the bonding portion interposed therebetween. It is a side view which shows the connection for measuring the IV characteristic of the Y type oxide superconducting wire joined by the joining form of FIG.1 (b).

Explanation of symbols

1 RE-based oxide superconducting layer 2 Ag layer 3 Base material 4 RE-based oxide superconducting wire 5 Plate 6 Bolt / nut 7 Adhesive layer

Claims (6)

The joining method for joining members (including the RE-based oxide superconducting wire of a laminated structure) that has been coated with a RE-based oxide superconducting wire and a metal or metallic material of the laminated structure being coated with a metallic material,
(I) The oxygen partial pressure and the temperature of the bonding surface are required for the RE oxide to exhibit superconducting properties in the RE oxide constituting the superconducting layer of the RE oxide superconducting wire during the bonding process. In an oxidizing atmosphere maintained in an oxygen partial pressure-temperature range that can secure an oxygen amount ,
(Ii) A method for joining RE-based oxide superconducting wires, in which thermal energy is applied to a joint surface obtained by directly overlapping metal surfaces of a joint portion, and a pressure is applied to join the joint surface.
However, RE is one or more elements of La, Nd, Sm, Eu, Gd, Dy, Ho, Er, Tm, Yb, Lu, and Y. Regard application of thermal energy to the bonding surface, the bonding method of the RE-based oxide superconducting wire according to claim 1, characterized by heating the joint. Regarding the application of thermal energy to the joint surface, the joint is subjected to any one or more treatments of energization, ultrasonic wave or electromagnetic wave application, and friction to induce thermal energy on the joint surface. method of bonding RE-based oxide superconducting wire according to claim 1, wherein the. Regarding the application of thermal energy to the bonding surface, the bonding portion is heated, and the bonding portion is subjected to any one or more treatments of energization, ultrasonic wave or electromagnetic wave application, and friction, and bonded. method of bonding RE-based oxide superconducting wire according to claim 1, characterized in that induces thermal energy to the surface. Superconducting layer of the RE-based oxide superconducting wire, RE-based oxide according to any one of claims 1 to 4, characterized in that it is constituted by R E-Ba-Cu-O based oxide Superconducting wire joining method. The metal material is any one of Au, Ag, Cu, Pt, Ni, Al, Ti, W, In, Ir, and Rh, or any one of alloys containing those elements. The joining method of RE type oxide superconducting wire of any one of Claims 1-5 characterized by these.