JP4735124B2 - Pneumatic tire manufacturing method - Google Patents

Pneumatic tire manufacturing method Download PDF

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JP4735124B2
JP4735124B2 JP2005236371A JP2005236371A JP4735124B2 JP 4735124 B2 JP4735124 B2 JP 4735124B2 JP 2005236371 A JP2005236371 A JP 2005236371A JP 2005236371 A JP2005236371 A JP 2005236371A JP 4735124 B2 JP4735124 B2 JP 4735124B2
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vulcanizing
bladder
vulcanization
presses
bladders
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JP2007050571A (en
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宏匡 齋藤
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Yokohama Rubber Co Ltd
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本発明は、空気入りタイヤの製造方法に関し、更に詳しくは、加硫時のゴム流れ不良を効果的に改善するようにした空気入りタイヤの製造方法に関する。   The present invention relates to a method for manufacturing a pneumatic tire, and more particularly, to a method for manufacturing a pneumatic tire that effectively improves poor rubber flow during vulcanization.

一般に、空気入りタイヤの製造では、成形したグリーンタイヤ(未加硫タイヤ)を加硫する際に、加硫機の金型にセットしたグリーンタイヤを所定の内圧でインフレートした加硫用ブラダーにより内側から押圧し、金型内面に押し当てて加硫するようにしている。   Generally, in the production of pneumatic tires, when a molded green tire (unvulcanized tire) is vulcanized, a green tire set in a mold of a vulcanizer is blown with a vulcanizing bladder that is inflated with a predetermined internal pressure. It is pressed from the inside and pressed against the inner surface of the mold for vulcanization.

インフレートする加硫用ブラダーは、先ずグリーンタイヤのクラウン部に当接し、次いでサイドウォール部に当接した後、ショルダー部に当接してグリーンタイヤを内側から押圧するが、特に近年市販されている偏平率が低いタイヤでは、このようにインフレートして加硫用ブラダーによりグリーンタイヤを押圧すると、ゴム流れ不良が発生し易くなるという問題があった。   The inflating vulcanizing bladder first contacts the crown portion of the green tire, then contacts the sidewall portion, and then contacts the shoulder portion to press the green tire from the inside. In a tire with a low flatness ratio, when the green tire is pressed with a bladder for vulcanization in this way, there is a problem that a rubber flow failure is likely to occur.

そこで、加硫用ブラダーの肉厚を調整することにより、インフレートした加硫用ブラダーの形状を変更する技術が知られている(例えば、特許文献1参照)。サイドウォール部を押圧するブラダー部分の肉厚をトレッド部を押圧するブラダー部分の肉厚より薄くすることにより、インフレートする加硫用ブラダーを先ずサイドウォール部側に当接させ、次いでトレッド部に当接させてグリーンタイヤを内側から押圧することができるようになる。それによりビード部まで延在するカーカス層をビード部側を先に固定することができるので、グリーンタイヤが金型形状に追従し易くなり、加硫時におけるゴム流れ不良の発生を抑制することが可能になる。しかしながら、サイド部プロファイルラインの曲率変化が複雑となる偏平率が低いタイヤでは、ゴム流れ不良の改善効果が不十分であり、更なる改善が求められていた。
特開2003−231128号公報
Therefore, a technique for changing the shape of an inflated vulcanizing bladder by adjusting the thickness of the vulcanizing bladder is known (for example, see Patent Document 1). By making the thickness of the bladder part that presses the sidewall part thinner than the thickness of the bladder part that presses the tread part, the vulcanizing bladder to be inflated is first brought into contact with the sidewall part side, and then on the tread part. The green tire can be pressed from the inside by abutting. As a result, the carcass layer extending to the bead portion can be fixed first on the bead portion side, so that the green tire can easily follow the mold shape and suppress the occurrence of poor rubber flow during vulcanization. It becomes possible. However, a tire with a low flatness that complicates the change in curvature of the side profile line is insufficient in improving the rubber flow failure, and further improvement has been demanded.
Japanese Patent Laid-Open No. 2003-231128

本発明の目的は、加硫時のゴム流れ不良を効果的に改善することが可能な空気入りタイヤの製造方法を提供することにある。   The objective of this invention is providing the manufacturing method of the pneumatic tire which can improve the rubber | gum flow defect at the time of vulcanization effectively.

上記目的を達成する本発明の空気入りタイヤの製造方法は、加硫機の金型にセットしたグリーンタイヤを所定の内圧でインフレートした加硫用ブラダーにより内側から押圧し、金型内面に押し当てて加硫する際に、グリーンタイヤのトレッド部と両サイドウォール部をそれぞれ独立して押圧可能な複数の加硫用ブラダーを使用し、両サイドウォール部を押圧する加硫用ブラダーの内圧をトレッド部を押圧する加硫用ブラダーの内圧より高くすることを特徴とする。   The method for producing a pneumatic tire of the present invention that achieves the above object is to press a green tire set in a mold of a vulcanizer from the inside with a vulcanizing bladder inflated with a predetermined internal pressure and push it on the inner surface of the mold. When vulcanizing by applying a plurality of vulcanization bladders that can press the tread part and both side wall parts of the green tire independently, the internal pressure of the vulcanization bladder that presses both side wall parts is adjusted. It is characterized by being higher than the internal pressure of the vulcanizing bladder that presses the tread portion.

上述した本発明によれば、加硫工程において、グリーンタイヤのトレッド部と両サイドウォール部をそれぞれ独立して押圧可能な複数の加硫用ブラダーを使用し、両サイドウォール部を押圧する加硫用ブラダーの内圧をトレッド部を押圧する加硫用ブラダーの内圧より高くすることで、両サイドウォール部を押圧する加硫用ブラダーを先に両サイドウォール部に当接させ、更に両サイドウォール部を高い圧力で金型内面に押し当てることが可能になり、それによりビード部まで延在するカーカス層をビード部に強固に固定することができるので、サイド部プロファイルラインの曲率変化が複雑となる偏平率が低いタイヤであってもグリーンタイヤがその金型形状に追従し易くなり、加硫時のゴム流れ不良を効果的に改善することが可能になる。   According to the present invention described above, in the vulcanization step, vulcanization is performed by using a plurality of vulcanization bladders that can independently press the tread portion and both sidewall portions of the green tire and pressing both sidewall portions. By making the internal pressure of the bladder for pressure higher than the internal pressure of the vulcanizing bladder that presses the tread part, the vulcanizing bladder that presses both side wall parts is first brought into contact with both side wall parts, and both side wall parts Can be pressed against the inner surface of the mold with high pressure, and the carcass layer extending to the bead portion can be firmly fixed to the bead portion, so that the curvature change of the side portion profile line becomes complicated. Even if the tire has a low flatness ratio, the green tire can easily follow the mold shape, and it is possible to effectively improve the rubber flow failure during vulcanization.

以下、本発明の実施の形態について添付の図面を参照しながら詳細に説明する。
図1は、本発明の空気入りタイヤの製造方法における加硫工程の要部断面図を示し、1は加硫機、2は金型、3,4,5は加硫用ブラダー、Tは金型2にセットしたグリーンタイヤ(未加硫タイヤ)である。
Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings.
FIG. 1 shows a cross-sectional view of the main part of a vulcanization process in the method for producing a pneumatic tire of the present invention, where 1 is a vulcanizer, 2 is a mold, 3, 4 and 5 are vulcanization bladders, and T is a metal mold. A green tire (unvulcanized tire) set in the mold 2.

金型2は、グリーンタイヤTの一方のサイドウォール部Taを成型するための上型2a、グリーンタイヤTの他方のサイドウォール部Tbを成型するための下型2b、グリーンタイヤTのトレッド部Tcを成型するための複数のセグメント2c、及び上下のビードリング2dを備えている。   The mold 2 includes an upper mold 2a for molding one sidewall portion Ta of the green tire T, a lower mold 2b for molding the other sidewall portion Tb of the green tire T, and a tread portion Tc of the green tire T. Are provided with a plurality of segments 2c and upper and lower bead rings 2d.

複数の加硫用ブラダー3,4,5は、それぞれ編物や織物を埋設したゴム層から構成されており、加硫用ブラダー3はグリーンタイヤTのトレッド部Tcを押圧可能に形成され、加硫用ブラダー4,5は両サイドウォールTa,Tbをそれぞれ押圧可能に形成され、複数の加硫用ブラダー3,4,5は内圧の付与によりインフレートした際に、図1に示すように、グリーンタイヤTのトレッド部Tcと両サイドウォール部Ta,Tbをそれぞれ独立して押圧できるようになっている。   The plurality of vulcanization bladders 3, 4, and 5 are each composed of a rubber layer in which a knitted fabric or a woven fabric is embedded. The vulcanization bladder 3 is formed so as to be able to press the tread portion Tc of the green tire T, and vulcanized. The bladders 4 and 5 are formed so as to be able to press both side walls Ta and Tb, respectively. When the plurality of vulcanization bladders 3, 4 and 5 are inflated by applying an internal pressure, as shown in FIG. The tread portion Tc of the tire T and both sidewall portions Ta and Tb can be pressed independently.

6は加硫用ブラダー5の気室5aに加圧媒体と加熱媒体を供給する供給路であり、この供給路6から接続路7を介して加圧加熱媒体を加硫用ブラダー5内に供給するようになっている。同様に、加硫用ブラダー3にも不図示の供給路から接続路8を介して加圧媒体と加熱媒体が気室3aに供給され、更に加硫用ブラダー4にも不図示の供給路から接続路9を介して加圧媒体と加熱媒体が気室4aに供給できるようにしてある。   Reference numeral 6 denotes a supply path for supplying the pressurized medium and the heating medium to the air chamber 5 a of the vulcanizing bladder 5, and the pressurized heating medium is supplied into the vulcanizing bladder 5 from the supply path 6 through the connection path 7. It is supposed to be. Similarly, a pressure medium and a heating medium are supplied to the air chamber 3a from a supply path (not shown) to the vulcanization bladder 3 via a connection path 8, and further to the vulcanization bladder 4 from a supply path (not shown). A pressurizing medium and a heating medium can be supplied to the air chamber 4a through the connection path 9.

以下、図1を参照しながら、本発明の空気入りタイヤの製造方法を説明する。
先ず、従来と同様の工程でグリーンタイヤTを成形する。得られたグリーンタイヤTを加硫機1の金型2にセットした後、加硫を開始する。加硫用ブラダー3,4,5にはそれぞれ所定内圧の加圧媒体と所定温度の加熱媒体が接続路7,8,9を介して供給され、インフレートした加硫用ブラダー3,4,5がグリーンタイヤTを内側から押圧し、金型2の内面に押し当てる。
Hereinafter, the manufacturing method of the pneumatic tire of this invention is demonstrated, referring FIG.
First, the green tire T is formed by the same process as the conventional one. After the obtained green tire T is set in the mold 2 of the vulcanizer 1, vulcanization is started. The vulcanization bladders 3, 4, 5 are respectively supplied with a pressurizing medium having a predetermined internal pressure and a heating medium having a predetermined temperature through the connection paths 7, 8, 9, and are inflated. Presses the green tire T from the inside and presses it against the inner surface of the mold 2.

この際、両サイドウォール部Ta,Tbを押圧する加硫用ブラダー4,5に供給する加圧媒体の圧力をトレッド部Tcを押圧する加硫用ブラダー3に供給する加圧媒体の圧力より高くなるようにし、加硫用ブラダー4,5の内圧を加硫用ブラダー3の内圧より高くする。例えば、乗用車用タイヤであれば、加硫用ブラダー4,5の内圧を2.0〜3.0MPa、加硫用ブラダー3の内圧を1.5〜2.0MPaとすることができる。   At this time, the pressure of the pressurized medium supplied to the vulcanizing bladders 4 and 5 that press both sidewall portions Ta and Tb is higher than the pressure of the pressurized medium supplied to the vulcanizing bladder 3 that presses the tread portion Tc. Thus, the internal pressure of the vulcanizing bladders 4 and 5 is set higher than the internal pressure of the vulcanizing bladder 3. For example, in the case of a tire for a passenger car, the internal pressure of the vulcanizing bladders 4 and 5 can be set to 2.0 to 3.0 MPa, and the internal pressure of the vulcanizing bladder 3 can be set to 1.5 to 2.0 MPa.

これにより、加硫用ブラダー4,5が両サイドウォール部Ta,Tbに当接した後、加硫用ブラダー3がトレッド部Tcに当接し、更に両サイドウォール部Ta,Tbを高い圧力で押圧するので、ビード部Tdまで延在するカーカス層(不図示)をビード部Tdに従来より強固に固定する。好ましくは、両サイドウォール部Ta,Tbを押圧する加硫用ブラダー4,5に加圧媒体を供給(内圧を付与)した後、トレッド部Tcを押圧する加硫用ブラダー3に加圧媒体を供給(内圧を付与)するのがよい。   As a result, the vulcanizing bladders 4 and 5 come into contact with both sidewall portions Ta and Tb, the vulcanizing bladder 3 comes into contact with the tread portion Tc, and further presses both sidewall portions Ta and Tb with high pressure. Therefore, a carcass layer (not shown) extending to the bead portion Td is firmly fixed to the bead portion Td. Preferably, after a pressurized medium is supplied to the vulcanizing bladders 4 and 5 that press both sidewall portions Ta and Tb (applying an internal pressure), the pressurized medium is applied to the vulcanizing bladder 3 that presses the tread portion Tc. Supply (apply internal pressure) is good.

また、加硫用ブラダー3,4,5には同じ温度の加熱媒体を供給してもよいが、好ましくは、両サイドウォール部Ta,Tbを押圧する加硫用ブラダー4,5内には、トレッド部Tcを押圧する加硫用ブラダー3内に供給する加熱媒体より温度が低い加熱媒体を供給するのがよい。例えば、トレッド部Tcを押圧する加硫用ブラダー3内に供給する加熱媒体の温度を220℃、両サイドウォール部Ta,Tbを押圧する加硫用ブラダー4,5内に供給する加熱媒体の温度を180℃とする。   The vulcanization bladders 3, 4 and 5 may be supplied with a heating medium having the same temperature. Preferably, the vulcanization bladders 4 and 5 for pressing both sidewall portions Ta and Tb are provided with It is preferable to supply a heating medium having a temperature lower than that of the heating medium supplied into the vulcanizing bladder 3 that presses the tread portion Tc. For example, the temperature of the heating medium supplied into the vulcanizing bladder 3 that presses the tread portion Tc is 220 ° C., and the temperature of the heating medium that is supplied into the vulcanizing bladders 4 and 5 that press both sidewall portions Ta and Tb. Is 180 ° C.

通常、タイヤのトレッド部はサイドウォール部より厚いため、単一の温度で加硫すると、トレッド部の加硫が終了するまで加硫するので、サイドウォール部が過加硫になる。そこで、両サイドウォール部Ta,Tbを押圧する加硫用ブラダー4,5内に供給する加熱媒体の温度を下げることで、サイドウォール部の過加硫を回避し、架橋密度を均一化することが可能になる。   Usually, since the tread portion of the tire is thicker than the sidewall portion, when vulcanized at a single temperature, vulcanization is performed until the vulcanization of the tread portion is completed, and thus the sidewall portion becomes overvulcanized. Therefore, by reducing the temperature of the heating medium supplied into the vulcanization bladders 4 and 5 that press both side wall portions Ta and Tb, the overvulcanization of the side wall portions can be avoided and the crosslink density can be made uniform. Is possible.

加硫終了後、加硫済タイヤを加硫機1から取り出し、空気入りタイヤの製造が終了する。   After the vulcanization is completed, the vulcanized tire is taken out from the vulcanizer 1 to complete the production of the pneumatic tire.

上述した本発明によれば、加硫工程において、グリーンタイヤTのトレッド部Tcと両サイドウォール部Ta,Tbをそれぞれ独立して押圧可能な複数の加硫用ブラダー3,4,5を使用し、両サイドウォール部Ta,Tbを押圧する加硫用ブラダー4,5の内圧をトレッド部Tcを押圧する加硫用ブラダー3の内圧より高くするため、ビード部Tdまで延在するカーカス層(不図示)をビード部Tdに強固に固定することができるので、サイド部プロファイルラインの曲率変化が複雑となる偏平率が低いタイヤであってもグリーンタイヤがその金型形状に追従し易くなり、加硫時のゴム流れ不良を効果的に改善することができる。   According to the present invention described above, a plurality of vulcanization bladders 3, 4, and 5 capable of independently pressing the tread portion Tc and both sidewall portions Ta and Tb of the green tire T are used in the vulcanization process. In order to make the internal pressure of the vulcanizing bladders 4 and 5 that press both side wall portions Ta and Tb higher than the internal pressure of the vulcanizing bladder 3 that presses the tread portion Tc, a carcass layer (not non-circular) extends to the bead portion Td. (Shown) can be firmly fixed to the bead portion Td, so that even if the tire has a low flatness that complicates the change in the curvature of the side portion profile line, the green tire can easily follow its mold shape. It is possible to effectively improve poor rubber flow during vulcanization.

図2は、本発明の空気入りタイヤの製造方法における加硫工程の他の例を示し、それぞれ独立して押圧可能な複数の加硫用ブラダーとして、両サイドウォール部Ta,Tbを押圧する加硫用ブラダー11,12、及びトレッド部Tcのクラウン部Teを押圧する加硫用ブラダー13と両ショルダー部Tfを押圧する加硫用ブラダー14,15を使用したものであり、他の構成は図1と同じである。なお、図2では隣接するブラダー部分の厚さを省略し、図面を簡略化している。   FIG. 2 shows another example of the vulcanization process in the method for manufacturing a pneumatic tire according to the present invention, and a plurality of vulcanization bladders that can be pressed independently of each other to press both sidewall portions Ta and Tb. The vulcanization bladders 11 and 12 and the vulcanization bladder 13 that presses the crown portion Te of the tread portion Tc and the vulcanization bladders 14 and 15 that press both shoulder portions Tf are used. Same as 1. In FIG. 2, the thickness of the adjacent bladder portion is omitted, and the drawing is simplified.

このような加硫用ブラダー11,12,13,14,15を用いて加硫する場合は、両サイドウォール部Ta,Tbを押圧する加硫用ブラダー11,12に供給する加圧媒体の圧力を加硫用ブラダー13,14,15に供給する加圧媒体の圧力より高くなるようにする。   When vulcanizing using such vulcanizing bladders 11, 12, 13, 14, and 15, the pressure of the pressurized medium supplied to the vulcanizing bladders 11 and 12 that press both sidewall portions Ta and Tb. Is made higher than the pressure of the pressurized medium supplied to the vulcanizing bladders 13, 14, 15.

また、加硫用ブラダー11,12,13,14,15に供給する加熱媒体の温度を異ならせる場合には、通常、最も肉厚が厚くなる両ショルダー部Tfを押圧する加硫用ブラダー14,15に供給する加熱媒体の温度を最も高く、次いで肉厚が厚くなるクラウン部Teを押圧する加硫用ブラダー13に供給する加熱媒体の温度を高く、そして両サイドウォール部Ta,Tbを押圧する加硫用ブラダー11,12に供給する加熱媒体の温度を最も低くする。但し、両サイドウォール部Ta,Tbのゴムより加硫進行速度を早くしたゴムをクラウン部Teに使用した場合には、加硫用ブラダー11,12に供給する加熱媒体の温度より加硫用ブラダー13に供給する加熱媒体の温度を低くする。   Further, when the temperature of the heating medium supplied to the vulcanizing bladders 11, 12, 13, 14, and 15 is made different, the vulcanizing bladders 14 that press both shoulder portions Tf that are usually thickest are usually used. The temperature of the heating medium supplied to 15 is the highest, and then the temperature of the heating medium supplied to the vulcanizing bladder 13 that presses the crown portion Te where the thickness is increased is increased, and both the sidewall portions Ta and Tb are pressed. The temperature of the heating medium supplied to the vulcanizing bladders 11 and 12 is made the lowest. However, in the case where rubber whose vulcanization progress speed is faster than that of the rubber of both side wall portions Ta and Tb is used for the crown portion Te, the vulcanizing bladder from the temperature of the heating medium supplied to the vulcanizing bladders 11 and 12 The temperature of the heating medium supplied to 13 is lowered.

なお、本発明では、複数の加硫用ブラダーとは、上述したようにそれぞれを独立した単一のブラダーから構成する他、単一の加硫用ブラダーを隔壁で複数の気室に区分した場合にも、複数の加硫用ブラダーとみなすものとする。例えば、単一の加硫用ブラダーを3つの気室に区分した場合には、3つの加硫用ブラダーを有するものとし、加圧加熱媒体を充填する気室の数を加硫用ブラダーの数とする。   In the present invention, the plurality of vulcanization bladders are configured as independent single bladders as described above, and the single vulcanization bladder is divided into a plurality of air chambers by partition walls. In addition, it shall be regarded as a plurality of vulcanizing bladders. For example, if a single vulcanizing bladder is divided into three air chambers, it shall have three vulcanizing bladders, and the number of air chambers filled with a pressurized heating medium will be the number of vulcanizing bladders. And

本発明は、特に偏平率が55%以下の空気入りタイヤを製造するのに好ましく用いることができるが、それに限定されない。   The present invention can be preferably used for producing a pneumatic tire having an aspect ratio of 55% or less, but is not limited thereto.

本発明の空気入りタイヤの製造方法における加硫工程の要部断面図である。It is principal part sectional drawing of the vulcanization | cure process in the manufacturing method of the pneumatic tire of this invention. 本発明の空気入りタイヤの製造方法における加硫工程の他の例を示す要部断面図である。It is principal part sectional drawing which shows the other example of the vulcanization | cure process in the manufacturing method of the pneumatic tire of this invention.

符号の説明Explanation of symbols

1 加硫機
2 金型
3,4,5 加硫用ブラダー
11,12,13,14,15 加硫用ブラダー
T グリーンタイヤ
Ta,Tb サイドウォール部
Tc トレッド部
1 Vulcanizer 2 Mold 3, 4, 5 Vulcanization bladder 11, 12, 13, 14, 15 Vulcanization bladder T Green tire Ta, Tb Side wall portion Tc Tread portion

Claims (3)

加硫機の金型にセットしたグリーンタイヤを所定の内圧でインフレートした加硫用ブラダーにより内側から押圧し、金型内面に押し当てて加硫する際に、グリーンタイヤのトレッド部と両サイドウォール部をそれぞれ独立して押圧可能な複数の加硫用ブラダーを使用し、両サイドウォール部を押圧する加硫用ブラダーの内圧をトレッド部を押圧する加硫用ブラダーの内圧より高くする空気入りタイヤの製造方法。   When a green tire set in a mold of a vulcanizer is pressed from the inside by a vulcanizing bladder that is inflated with a predetermined internal pressure and pressed against the inner surface of the mold, the tread and both sides of the green tire are vulcanized. Use multiple vulcanizing bladders that can press the wall part independently, and make the internal pressure of the vulcanizing bladder that presses both side wall parts higher than the internal pressure of the vulcanizing bladder that presses the tread part. Tire manufacturing method. 前記両サイドウォール部を押圧する加硫用ブラダーに内圧を付与した後、前記トレッド部を押圧する加硫用ブラダーに内圧を付与する請求項1に記載の空気入りタイヤの製造方法。   The method for producing a pneumatic tire according to claim 1, wherein an internal pressure is applied to the vulcanizing bladder that presses the tread portion after an internal pressure is applied to the vulcanizing bladder that presses the both sidewall portions. 前記両サイドウォール部を押圧する加硫用ブラダー内に、前記トレッド部を押圧する加硫用ブラダー内に供給される加熱媒体より温度が低い加熱媒体を供給して加硫する請求項1または2に記載の空気入りタイヤの製造方法。
The vulcanization bladder that presses both the side wall portions is vulcanized by supplying a heating medium having a temperature lower than that of the heating medium supplied to the vulcanization bladder that presses the tread portion. The manufacturing method of the pneumatic tire of description.
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KR20230060656A (en) * 2021-10-28 2023-05-08 금호타이어 주식회사 Tire vulcanization bladder

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JP4816761B2 (en) * 2009-05-07 2011-11-16 横浜ゴム株式会社 Pneumatic tire manufacturing method
JP4851562B2 (en) * 2009-05-25 2012-01-11 住友ゴム工業株式会社 Pneumatic tire manufacturing method
KR101425038B1 (en) * 2012-10-26 2014-08-06 금호타이어 주식회사 multi pressure tire bladder
CN105531091B (en) * 2013-09-25 2017-05-03 成都优阳机电产品设计有限公司 Multi-chamber tire manufacturing mold
JP6582914B2 (en) * 2015-11-19 2019-10-02 横浜ゴム株式会社 Pneumatic tire vulcanizing apparatus and method
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KR20230060656A (en) * 2021-10-28 2023-05-08 금호타이어 주식회사 Tire vulcanization bladder
KR102533945B1 (en) 2021-10-28 2023-05-26 금호타이어 주식회사 Tire vulcanization bladder

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