JP4620488B2 - Composition - Google Patents

Description

  The present invention has a beautiful and excellent appearance in which a water-in-oil emulsion composition, an oil-in-water emulsion composition, an oil-based composition or an aqueous composition is dispersed in a three-dimensional pattern in a transparent gel-like oily composition. The present invention also relates to a composition having an emollient effect, particularly a cosmetic.

  Conventionally, skin care cosmetics have been used to impart an action such as emollient to the skin.

  On the other hand, in recent years, consumer values for cosmetics have been diversified, and in addition to having functions as cosmetics such as skin care effects, visual beauty is also required. It has become like this.

  As a technology corresponding to the recent diversification of values for cosmetics, in a translucent gel base or a transparent gel base containing a water-soluble polymer or an inorganic gelling agent, Cosmetics made of a W / O / W type emulsion in which a water-in-oil emulsion, which is an internal phase, is stored in a three-dimensional pattern are developed (see Patent Document 1). This technology has a beautiful visual appearance and functions as a cosmetic. However, it has the effect of improving skin by oil-based active ingredients such as emollient effects on skin and oil-soluble medicinal ingredients. It's not enough.

JP-A-6-128133

  The present invention has been made in view of the above circumstances, and its purpose is a composition having excellent visual appearance, excellent functions such as emollient action and skin modifying action on the skin, and good temporal stability. Is to provide.

  As a result of intensive studies to solve the above-mentioned problems, the present inventor has obtained a water-in-oil emulsion composition having a specific viscosity in an oily composition comprising a transparent oily component such as a transparent oil component having a specific hardness forming an outer phase. The present inventors have found that the above-mentioned problems can be solved by dispersing an oil-in-water emulsion composition, an oily composition, or an aqueous composition in a three-dimensional pattern, and have completed the present invention.

  In the present invention, the outermost phase of the composition is an oil phase, and the object of the present invention can be achieved by forming a three-dimensional pattern in the transparent gel composition. In the composition of the present invention, since the outermost phase is an oil phase, a large amount of oil-based active ingredients can be blended.

  That is, the present invention is a composition in which the inner phase is dispersed in a three-dimensional pattern in the outer phase, the outer phase is a transparent oily composition having a hardness of 10 to 25, and the inner phase is in oil having a viscosity of 2000 to 20000 mPa · s. It is a composition characterized by being a water-type emulsion composition, an oil-in-water type emulsion composition, an oil-based composition, or an aqueous composition.

  The internal phase composition is preferably opaque.

  The internal phase is preferably an oil-in-water emulsion composition.

  Moreover, it is preferable that the composition of this invention is cosmetics.

  The value of hardness in the present invention is a value obtained by measuring a sample at 25 ° C. with FUDOH REO METER. In the measurement, a 10φ flat plate was used and the approach speed was 6 cm / min. The value when entering 20 mm is taken. In this invention, it measured using FUDOH REO METER made from Rheotech.

  The viscosity value in the present invention is a value obtained by measuring a sample at 25 ° C. with a B-type viscometer. In the measurement, a No. 4 rotor was used, and the value of viscosity after 120 seconds and the viscosity after 120 seconds was taken. In the present invention, measurement was performed using a B-type viscometer manufactured by Toki Sangyo Co., Ltd.

  In the present invention, those having a transmittance of 60% or more are referred to as transparent, and those having a transmittance of less than 60% are referred to as opaque. Although there is a semi-transparent region between transparent and opaque, in the present invention, transparency is defined as being divided into transparent and opaque. The transmittance is a value measured by the following method. That is, a 25 degreeC sample is put into a cell and it measures with the spectral color difference meter SE-2000. The measurement method is to measure the transmittance of a cell placed in the transmittance measurement mode. In the present invention, a spectral color difference meter manufactured by Nippon Denshoku Industries Co., Ltd. was used.

  In the present invention, solid state, liquid state, and paste state represent a state at normal temperature. Volatile means a property at normal pressure.

  According to the present invention, a transparent gel-like oily composition is used as the outer phase, the outermost phase is the oil phase, and the water-in-oil emulsion composition, the oil-in-water emulsion composition, and the oily composition are used as the inner phase of the outer phase. Alternatively, it is possible to stably obtain a composition in which an aqueous composition is preferably dispersed in a three-dimensional pattern with a rich color. The composition has a beautiful visual appearance, gives an excellent emollient effect to the skin, a skin modifying effect, and the like, and is particularly useful as a cosmetic.

  Hereinafter, the best mode for carrying out the present invention will be described in detail.

  The composition of the present invention is a composition comprising an outer phase and an inner phase, and the inner phase is dispersed in a three-dimensional pattern in the outer phase. Hereinafter, the composition of the present invention is also simply referred to as “composition”.

  Hereinafter, the outer phase will be described. The outer phase is a gel-like transparent oily composition having a hardness of 10 to 25 (hereinafter, the transparent oily composition is referred to as “oily composition (outer phase)”. The oily composition may also be indicated as “O”). And the outermost phase of the composition of the present invention is positioned to be an oil phase. If the hardness of the oily composition (outer phase) is less than 10, the inner phase formed in the outer phase cannot be stably maintained. On the other hand, if it exceeds 25, it becomes difficult to prepare the composition of the present invention.

  The oily composition (external phase) is composed of an oily component such as an oil component, and is preferably a transparent gel to which a liquid oil component and an oil gelling agent are added and adjusted to a hardness in the above range.

  The liquid oil is not particularly limited. For example, liquid oils such as olive oil, castor oil, macadamia nut oil, evening primrose oil and avocado oil, liquid waxes (esters) such as jojoba oil and liquid lanolin, liquid paraffin, squalane, Liquid hydrocarbons such as polybutene, light liquid isoparaffin, α-olefin oligomer, liquid fatty acid monoesters such as isopropyl myristate, isopropyl palmitate, cetyl 2-ethylhexanoate, octyldodecyl myristate, octyl stearate, octyl palmitate, Liquid dibasic acid diesters such as diisopropyl adipate and di-2-ethylhexyl sebacate, liquid glycol esters such as neopentyl glycol dicaprate, glyceryl tri-2-ethylhexanoate, triisostearic acid Liquid glycerol esters such as ceryl, liquid polyglycerol esters such as diglyceryl diisostearate and diglyceryl triisostearate, liquid pentaerythritol esters such as tetra-2-ethylhexanoic acid pentaerythritol and dioctanoic acid pentaerythritol, tri 2- Liquid esters such as trimethylolpropane ethylhexanoate, trimethylolpropane triisostearate, liquid malates such as diisostearyl malate, isostearic acid, oleic acid, linoleic acid, linolenic acid, etc. Liquid higher fatty acids, liquid higher alcohols such as isostearyl alcohol, oleyl alcohol, octyldodecanol, etc., liquid chains such as dimethylpolysiloxane and methylphenylpolysiloxane Liquid silicones such as liquid cyclic silicones such as polysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, etc., liquid modified polysiloxanes such as amino-modified polysiloxane, alkyl-modified polysiloxane, and fluorine-modified polysiloxane Examples thereof include liquid fluorine compounds such as oil and perfluoropolyether. One or more liquid oil components are selected and blended.

  The oil gelling agent is an oil gelling agent used in cosmetics, and is selected from those suitable for thickening liquid oil. Examples of the oil gelling agent include dextrin fatty acid ester and silicone gel. Of these, specific examples of dextrin fatty acid esters include dextrin palmitate, (palmitic acid / 2-ethylhexanoic acid) dextrin, and the like. Dextrin fatty acid esters are commercially available, and examples thereof include Leo Pearl KL and Leo Pearl TT (above, manufactured by Chiba Flour Milling Co., Ltd.). Specific examples of the silicone gel include cross-linked methylpolysiloxane and (vinyl dimethicone / lauryl dimethicone) crosspolymer. Silicone gels are commercially available, and examples thereof include KSG-16 and KSG-44 (manufactured by Shin-Etsu Chemical Co., Ltd.). One or more oil gelling agents can be arbitrarily selected and blended.

  A transparent composition (oil-based composition (external phase)) is obtained by gelling by adding an oil gelling agent to the liquid oil, and the adjustment to the hardness range is the type of oil gelling agent, It is carried out by a known ordinary method such as adjustment of the blend amount.

  In the oily composition (external phase), components other than those described above can be blended in accordance with the purpose of the composition of the present invention as long as the effects of the present invention are not impaired. For example, oil-soluble medicinal ingredients such as oil-soluble vitamins, and oil-soluble ingredients such as ultraviolet absorbers, preservatives, antioxidants, and fragrances.

Preparation of the oily composition (external phase) is not particularly limited, and for example, it can be prepared by mixing and stirring a liquid oil component, an oil gelling agent, and other components as required.

  Next, the internal phase of the composition of the present invention will be described. The internal phase is composed of a water-in-oil emulsion composition, an oil-in-water emulsion composition, an oily composition, or an aqueous composition (hereinafter, these compositions forming the internal phase are collectively referred to as “internal phase composition”). And dispersed in the outer phase to form a three-dimensional pattern.

  The viscosity of the internal phase composition is in the range of 2000 to 20000 mPa · s. When the viscosity is within this range, a three-dimensional pattern of the inner phase is formed, which is stably maintained, and the filling of the inner phase composition during preparation of the composition of the present invention is facilitated.

  Hereinafter, the inner phase composition having a viscosity of 2000 to 20000 mPa · s forming the inner phase will be described in more detail. First, the water-in-oil emulsion composition will be described. The water-in-oil emulsion composition may be indicated as “W / O”. Oil, water, and an emulsifier are blended as essential components in the water-in-oil emulsion composition. The oil component is not particularly limited, and is selected from those generally used in cosmetics and the like. For example, solid oils such as hydrogenated oil, owl, cacao butter, hydrogenated castor oil, partially hydrogenated sesame oil, partially hydrogenated beef tallow and partially hydrogenated palm oil; solid hydrocarbons such as solid paraffin, ceresin, microcrystalline wax and polyethylene wax Solid waxes (esters) such as beeswax, lanolin, gay wax, candelilla wax, carnauba wax, ibota wax, partially hydrogenated jojoba oil, rice bran wax; stearic acid, palmitic acid, myristic acid, 12-hydroxystearic acid, behenic acid Solid higher fatty acids such as cetyl alcohol, stearyl alcohol, cetostearyl alcohol, behenyl alcohol, and lanolin fatty acid; solid esters such as myristyl myristate, cetyl palmitate, and glyceryl trimyristate; Alkyl-modified polysiloxane waxes such solid oil component silicone wax,

  Liquid oils such as olive oil, castor oil, macadamia nut oil, evening primrose oil and avocado oil, liquid waxes (esters) such as jojoba oil and liquid lanolin, liquid such as liquid paraffin, squalane, polybutene, light liquid isoparaffin, α-olefin oligomer Liquids such as hydrocarbon, isopropyl myristate, isopropyl palmitate, cetyl 2-ethylhexanoate, octyldodecyl myristate, octyl stearate, octyl palmitate, etc., diisopropyl adipate, di-2-ethylhexyl sebacate, etc. Liquid glycol esters such as dibasic acid diesters, neopentyl glycol dicaprate, glyceryl tri-2-ethylhexanoate, glyceryl triisostearate, diisostearyl Liquid polyglycerol esters such as diglyceryl acid and diglyceryl triisostearate, liquid pentaerythritol esters such as tetra 2-ethylhexanoic acid pentaerythritol and dioctanoic acid pentaerythritol, tri-2-ethylhexanoic acid trimethylolpropane, tri Liquid trimethylolpropane esters such as trimethylolpropane isostearate, liquid esters such as liquid malate esters such as diisostearyl malate, liquid higher fatty acids such as isostearic acid, oleic acid, linoleic acid, linolenic acid, isostearyl alcohol Liquid higher alcohols such as oleyl alcohol and octyldodecanol, liquid chain polysiloxanes such as dimethylpolysiloxane and methylphenylpolysiloxane, and octamethylcyclotetrasiloxane Liquid silicone oils such as liquid cyclic silicones such as decamethylcyclopentasiloxane and dodecamethylcyclohexasiloxane, amino-modified polysiloxanes, alkyl-modified polysiloxanes, and fluorine-modified polysiloxanes, and perfluoropolyethers. Examples thereof include liquid oils such as liquid fluorine compounds. One or more oil components are arbitrarily selected and blended.

  The emulsifier is not particularly limited as long as it emulsifies the oil phase and the aqueous phase of the water-in-oil emulsion composition, but a nonionic surfactant is preferable, and HLB is 8 or less, particularly HLB 2 to 8. Are preferably used. These surfactants are generally selected from those used in cosmetics.

  In the water-in-oil emulsified composition, components other than those described above can be blended according to the purpose of the composition of the present invention as long as the effects of the present invention are not impaired. For example, oil-gelling agents, oil-soluble medicinal ingredients such as oil-soluble vitamins, UV-absorbing agents, preservatives, antioxidants, oil-soluble ingredients such as fragrances, polyhydric alcohols, moisturizers, Examples thereof include sticky agents (water gelling agents), water-soluble vitamins, amino acids, saccharides such as monosaccharides and polysaccharides, water-soluble components such as preservatives, and powders.

  Adjustment to the viscosity range of the water-in-oil emulsion composition is carried out by adjusting the ratio of the inner phase (water phase part) to the outer phase (oil phase part) of the water-in-oil emulsion composition, oil gelling agent, It is carried out by a known ordinary method such as adjustment of the type and the amount of the sticking agent (water gelling agent).

  For example, the ratio of the oil phase component and the water phase component in the water-in-oil emulsion composition is preferably such that the ratio of the oil phase component is 5 to 70% by mass in the total water-in-oil emulsion composition. .

  The preparation of the water-in-oil emulsion composition is not particularly limited. For example, the oil-in-water emulsion composition can be prepared by mixing, stirring and emulsifying an oil phase part, a water phase part, an emulsifier and the like.

  Next, the oil-in-water emulsion composition will be described. The oil-in-water emulsion composition may be indicated as “O / W”.

  Oil, water and an emulsifier are blended as essential components in the oil-in-water emulsion composition. As the oil, the same oil as that used in the water-in-oil emulsion composition is used.

  The emulsifier is not particularly limited as long as it emulsifies the oil phase and the aqueous phase of the oil-in-water emulsion composition. However, it is common to use a surfactant, preferably mainly a hydrophilic surfactant. is there. These surfactants are generally selected from those used in cosmetics.

  In the oil-in-water emulsified composition, components other than those described above can be blended according to the purpose of the composition of the present invention as long as the effects of the present invention are not impaired. As an arbitrary compounding component, the thing similar to the said water-in-oil emulsion composition is mentioned, for example.

  Adjustment to the viscosity range of the oil-in-water emulsion composition is performed by a known ordinary method as in the case of the water-in-oil emulsion composition.

  For example, the ratio of the water phase component to the oil phase component in the oil-in-water emulsion composition is preferably 50 to 99% by mass in the total oil-in-water emulsion composition.

  The preparation of the oil-in-water emulsion composition is not particularly limited, and it can be prepared in the same manner as the water-in-oil emulsion composition.

  Next, the oil-based composition (hereinafter, the oil-based composition forming the inner phase is referred to as “oil-based composition (inner phase)”) will be described.

  The oily composition (inner phase) is composed of oily components such as oil as in the case of the oily composition (outer phase), and liquid oil is preferably thickened with an oil gelling agent.

  The liquid oil is not particularly limited. For example, liquid oils such as olive oil, castor oil, macadamia nut oil, evening primrose oil and avocado oil, liquid waxes (esters) such as jojoba oil and liquid lanolin, liquid paraffin, squalane, polybutene , Liquid hydrocarbons such as light liquid isoparaffin and α-olefin oligomer, liquid fatty acid monoesters such as isopropyl myristate, isopropyl palmitate, cetyl 2-ethylhexanoate, octyldodecyl myristate, octyl stearate, octyl palmitate, adipine Liquid dibasic acid diesters such as diisopropyl acid, di-2-ethylhexyl sebacate, liquid glycol esters such as neopentyl glycol dicaprate, glyceryl tri-2-ethylhexanoate, glyceride triisostearate Liquid glycerin esters such as diglyceryl diisostearate, diglyceryl triisostearate, liquid pentaerythritol esters such as tetra-2-ethylhexanoic acid pentaerythritol and dioctanoic acid pentaerythritol, tri 2- Liquid esters such as trimethylolpropane ethylhexanoate, trimethylolpropane triisostearate, liquid malates such as diisostearyl malate, isostearic acid, oleic acid, linoleic acid, linolenic acid, etc. Liquid higher fatty acids, liquid higher alcohols such as isostearyl alcohol, oleyl alcohol, octyldodecanol, etc., and liquid chain polymers such as dimethylpolysiloxane and methylphenylpolysiloxane Liquid silicone oils such as liquid cyclic silicones such as siloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, etc., liquid modified polysiloxanes such as amino-modified polysiloxane, alkyl-modified polysiloxane, and fluorine-modified polysiloxane And liquid fluorine compounds such as perfluoropolyether. One or more liquid oil components are selected and blended.

The oil gelling agent is an oil gelling agent used in cosmetics, and is selected from those suitable for thickening liquid oil. Examples of the oil gelling agent include dextrin fatty acid ester, metal soap, organically modified clay mineral, and silicone gel. Of these, specific examples of dextrin fatty acid esters include dextrin palmitate, (palmitic acid / 2-ethylhexanoic acid) dextrin, and the like. Dextrin fatty acid esters are commercially available, and examples thereof include Leo Pearl KL and Leo Pearl TT (above, manufactured by Chiba Flour Milling Co., Ltd.). Specific examples of the metal soap include aluminum stearate. Specific examples of the organically modified clay mineral include dimethyl distearyl ammonium hectorite. Organically modified clay minerals are commercially available, for example, BENTONE
38VCG (made by Elementis Japan) is mentioned. Specific examples of the silicone gel include cross-linked methylpolysiloxane and (vinyl dimethicone / lauryl dimethicone) crosspolymer. Silicone gels are commercially available, and examples thereof include KSG-16 and KSG-44 (manufactured by Shin-Etsu Chemical Co., Ltd.). One or more oil gelling agents can be arbitrarily selected and blended.

  You may mix | blend a solid oil component with an oil-based composition (inner phase) as an oil component. Solid oils such as hardened oil, owl, cocoa butter, hardened castor oil, partially hydrogenated sesame oil, partially hydrogenated beef tallow, partially hydrogenated palm oil, etc .; solid paraffin, ceresin, microcrystalline wax, polyethylene wax, etc. Solid waxes such as beeswax, lanolin, gay wax, candelilla wax, carnauba wax, ibota wax, partially hydrogenated jojoba oil, rice bran wax, etc .; stearic acid, palmitic acid, myristic acid, 12-hydroxystearic acid, Solid higher fatty acids such as behenic acid; solid higher alcohols such as cetyl alcohol, stearyl alcohol, cetostearyl alcohol, behenyl alcohol, lanolin fatty acid; solids such as myristyl myristate, cetyl palmitate, glyceryl trimyristate Ester; silicone waxes such as alkyl modified polysiloxane wax. One or more solid oil components are arbitrarily selected and blended.

  In the oily composition (inner phase), components other than those described above can be blended according to the purpose of the composition of the present invention within a range not impairing the effects of the present invention. For example, oil-soluble medicinal components such as oil-soluble vitamins, UV-absorbing agents, preservatives, antioxidants, oil-soluble components such as fragrances, powders and the like can be mentioned.

  Adjustment to the said viscosity range of an oil-based composition (internal phase) is performed by well-known normal methods, such as adjustment of the kind of oil gelling agent, adjustment of compounding quantity, and adjustment of the compounding quantity of solid oil.

  The oil-based composition (inner phase) is not particularly limited, and can be prepared, for example, by mixing and stirring a liquid oil, an oil gelling agent, and other components as necessary. .

  Next, the aqueous composition will be described. The aqueous composition may be indicated as “W”.

  The aqueous composition is preferably composed of an aqueous component such as water, and water is thickened with a thickener (water gelling agent).

  The thickener (water gelling agent) is not particularly limited, and examples thereof include carboxyvinyl polymer, xanthan gum, bentonite, hydroxymethylcellulose, tamarind gum and the like.

  In the aqueous composition, components other than those described above can be blended according to the purpose of the composition of the present invention as long as the effects of the present invention are not impaired. Examples thereof include polyhydric alcohols, humectants, water-soluble vitamins, amino acids, saccharides such as monosaccharides and polysaccharides, water-soluble components such as preservatives, and powders.

  Adjustment to the viscosity range of the aqueous composition is performed by a known ordinary method such as adjustment of the type and blending amount of the thickener (water gelling agent).

  The aqueous composition is not particularly limited, and can be prepared, for example, by mixing and stirring water and a thickener (water gelling agent), and other components as necessary. .

  The inner phase composition is preferably opaque in order to make a three-dimensional pattern beautiful. Further, the internal phase composition is preferably colored by blending a colorant in order to improve the appearance aesthetics. The color material is not particularly limited as long as it is usually used in cosmetics, and examples thereof include color pigments, pearl agents, lame agents, organic dyes, and natural dyes. One or more color materials are selected and blended.

  Specific examples of the coloring material include, for example, inorganic white pigments such as titanium oxide, zinc oxide, barium sulfate, and zinc oxide coated or combined with anhydrous silicic acid; inorganic reds such as iron oxide (Bengara) and iron titanate Pigments; inorganic brown pigments such as γ-iron oxide; inorganic yellow pigments such as yellow iron oxide and ocher; inorganic black pigments such as black iron oxide, carbon black and low-order titanium oxide; manganese violet, cobalt violet, etc. Inorganic purple pigments; inorganic green pigments such as chromium oxide, chromium hydroxide and cobalt titanate; inorganic blue pigments such as ultramarine and bitumen; mica titanium, Bengala coated mica, Bengala coated mica titanium, carmine coated mica titanium, bitumen Coated mica titanium, titanium oxide coated synthetic phlogopite, Bengala / titanium oxide coated synthetic phlogopite, titanium oxide coated mica, titanium oxide coated oxychloride Sumas, titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, fish scale foil, titanium oxide coated glass flakes, bengara / titanium oxide coated glass flakes, titanium oxide coated alumina flakes, titanium oxide coated silica flakes, iron oxide / silica Coated aluminum, iron oxide / silica coated iron oxide, metal coated plate powder, polyethylene terephthalate / polymethylmethacrylate laminate film powder (may contain colorant), polyethylene terephthalate / polyolefin laminate film powder (contains colorant) ), Epoxy resin-coated aluminum-deposited polyethylene terephthalate (which may contain colorants), aluminum-deposited polyethylene terephthalate (which may contain colorants), urethane-resin-coated aluminum-deposited polyethylene Renterephthalate (which may contain colorants), acrylic resin-coated aluminum powder (which may contain colorants); organic pigments such as Red No. 504, Blue No. 1, Yellow No. 4; Licorice, Caramel, Shikon And natural pigments such as One or two or more of these color materials are selected and blended.

  The color material may have a hydrophilic surface or a hydrophobic surface. For example, when the surface is hydrophilic, it can be used as it is, or it can be made hydrophobic by hydrophobizing treatment. The hydrophobizing treatment method is not particularly limited. For example, coating baking using methylhydrogenpolysiloxane, metal soap, fatty acid dextrin, trimethylsiloxysilicic acid, dimethylpolysiloxane, methylphenylpolysiloxane, Examples thereof include a coating treatment with a polymer having a fluorine group.

  The blending amount of the color material in the case of blending the color material is not necessarily limited and varies depending on the target composition and the type of the color material used, but in the total amount of the internal phase composition, 0.001 to 30% by mass is preferred.

  In the present invention, an oil-in-water emulsion composition is most preferable among the internal phase compositions from the viewpoints of stability, aesthetics, usability and the like of the composition.

  The amount of the internal phase composition of the present invention is arbitrarily determined according to the use of the composition of the present invention, etc., but from the viewpoint of beauty in appearance, 0.1 to 0.1% of the total amount of the composition of the present invention. A range of 50% by weight is preferred. Within the said range, the effect of this invention, especially an aesthetic three-dimensional pattern can fully be acquired. The three-dimensional pattern composed of the internal phase composition is a form formed by a continuous phase or an intermittent phase of the internal phase composition, and examples thereof include a geometric pattern such as a spiral shape.

  In the present invention, in preparing the composition of the present invention by dispersing the inner phase in the outer phase in the three-dimensional pattern state, the method is not particularly limited. For example, an oily composition (outer phase) serving as the outer phase is placed in a container. Then, a filling nozzle (thin tube) through which the inner phase composition is discharged into the oily composition (outer phase) is placed at an arbitrary depth in the oily composition (outer phase) from the top of the container, for example, the bottom of the container And the inner phase composition is discharged from the filling nozzle. If the filling nozzle moves up and down, back and forth, and left and right and the container can rotate, the width of the pattern types can be expanded. When drawing a pattern, movement of the filling nozzle such as up / down, front / back, left / right, and rotation, and a bulk discharge amount may be controlled by a program, and the movement, size, bulk discharge amount, and the like may be adjusted.

  The composition of the present invention can also be prepared using a known method. As a known method, for example, there is a method described in Japanese Patent No. 2740518.

  In the composition of the present invention, a three-dimensional pattern is stably formed in an oily composition (external phase), and an aesthetic appearance is exhibited. Moreover, at the time of use, synergistic effects, such as the emollient effect based on an oil-based composition (outer phase) and an inner phase composition, are exhibited, Preferably it can apply effectively to cosmetics. Examples of the cosmetics include make-up cosmetics such as under makeup and lip gloss, skin care cosmetics such as massage cream, pack, essence cream, and eye cream, and hair care cosmetics such as hair wax.

  Hereinafter, the present invention will be specifically described with reference to examples. The blending amount is mass% unless otherwise specified. The unit of viscosity is mPa · s. Prior to the description of the examples, examples of the oily composition (outer phase) and inner phase composition used in the present invention and the method for testing the effect will be described.

(Production example)
Production Example 1 Oily composition (external phase)
Ingredient Amount (% by mass)
(1) Dextrin palmitate 5.0
(2) Squalane 50.0
(3) Methylpolysiloxane 10.0
(4) Glyzeryl tri-2-ethylhexanoate Residual amount (5) Di (phytosteryl · 2-octyldodecyl) N-lauroyl-L-glutamate 0.1
(6) Natural vitamin E appropriate amount (7) Paraben appropriate amount
Total 100.0

(1) to (7) were uniformly dispersed. This oily composition (external phase) was transparent and had a hardness of 15.

Production Example 2 Water-in-oil type emulsified composition component Amount (% by mass)
(1) Methylpolysiloxane 5.0
(2) Decamethylcyclopentasiloxane 15.0
(3) Jojoba oil 2.0
(4) Polyoxyethylene / methylpolysiloxane copolymer 5.0
(5) Silylated silica hydrate 0.5
(6) 1,3-butylene glycol 8.0
(7) PEG-20000 1.0
(8) Purified water remaining amount (9) Magnesium sulfate 1.0
(10) Polymethyl methacrylate 4.0
(11) Silicone-treated talc 3.0
(12) Silicone-treated mica titanium 2.0
(13) Silicone-treated aluminum oxide / cobalt 0.6
(14) Silicone-treated bengara 0.05
(15) Silicone-treated yellow iron oxide 0.1
Total 100.0

To (1) to (5) uniformly dispersed, (6) to (9) uniformly dispersed were added and uniformly dispersed. Thereafter, (10) to (15) were added and uniformly dispersed. This water-in-oil emulsion composition was blue and had a viscosity of 4000 mPa · s.

Production Example 3 Oil-in-water type emulsified composition component amount (% by mass)
(1) Squalane 5.0
(2) Decamethylcyclopentasiloxane 1.0
(3) Methylpolysiloxane 2.0
(4) Cetyl palmitate 1.0
(5) Behenyl alcohol 0.5
(6) Self-emulsifying glyceryl stearate 1.0
(7) sorbitan oleate 0.5
(8) Polyoxyethylene stearyl ether 0.5
(9) Natural vitamin E 0.05
(10) Ceramide 3 0.05
(11) 1,3-butylene glycol 6.0
(12) Glycerin 5.0
(13) Dipotassium glycyrrhizinate 0.1
(14) Carboxyvinyl polymer 0.3
(15) Potassium hydroxide appropriate amount (16) Phenoxyethanol appropriate amount (17) Paraben appropriate amount (18) Purified water remaining amount (19) Bengala-coated mica titanium 0.5
(20) Mica titanium 1.0
(21) Mica 2.0
Total 100.0

(Production method)
(1) to (10) were uniformly dispersed, and (11) to (18) were uniformly dispersed, and then uniformly dispersed. Thereafter, (19) to (21) were added and uniformly dispersed. This oil-in-water emulsion composition was red and had a viscosity of 6000 mPa · s.

Production Example 4 Oily Composition (Inner Phase)
Ingredient Amount (% by mass)
(1) Dextrin palmitate 2.0
(2) Diisostearyl malate 20.0
(3) Squalane 5.0
(4) Liquid paraffin remaining amount (5) Methylpolysiloxane 10.0
(6) Natural vitamin E 0.1
(7) Polyalkyl acrylate 4.0
(8) Silicone-treated Bengala-coated mica titanium 1.0
(9) Silicone-treated mica titanium 1.0
(10) Silicone-treated yellow iron oxide 0.5
(11) Silicone-treated titanium oxide 2.0
(12) Silicone-treated talc 1.5
Total 100.0

(Production method)
(1) to (6) were uniformly dispersed. Thereafter, (7) to (12) were added and uniformly dispersed. This oily composition (inner phase) was yellow and had a viscosity of 16000 mPa · s.

Production Example 5 Aqueous composition component Amount (% by mass)
(1) Carboxyvinyl polymer 0.2
(2) Hydroxymethylcellulose 0.3
(3) 1,3-butylene glycol 8.0
(4) Diglycerin 3.0
(5) PEG-4000 2.0
(6) Sorbite solution 10.0
(7) Potassium hydroxide Appropriate amount (8) Phenoxyethanol Appropriate amount (9) Edetic acid Appropriate amount (10) Paraben Appropriate amount (11) Red No. 504 0.002
(12) Blue No. 1 0.001
(13) Purified water remaining
Total 100.0

(Production method)
(1) to (13) were uniformly dispersed. This aqueous composition was red and had a viscosity of 9000 mPa · s.

Production Example 6 Oily Composition (Outer Phase)
Ingredient Amount (% by mass)
(1) Dextrin palmitate 2.0
(2) Squalane 50.0
(3) Methylpolysiloxane 10.0
(4) Glyzeryl tri-2-ethylhexanoate Residual amount (5) Di (phytosteryl · 2-octyldodecyl) N-lauroyl-L-glutamate 0.1
(6) Natural vitamin E appropriate amount (7) Paraben appropriate amount
Total 100.0

(1) to (7) were uniformly dispersed. This oily composition (external phase) was transparent and had a hardness of 5.

Production Example 7 Oil-based composition (external phase)
Ingredient Amount (% by mass)
(1) Dextrin palmitate 10.0
(2) Squalane 50.0
(3) Methylpolysiloxane 10.0
(4) Glyzeryl tri-2-ethylhexanoate Residual amount (5) Di (phytosteryl · 2-octyldodecyl) N-lauroyl-L-glutamate 0.1
(6) Natural vitamin E appropriate amount (7) Paraben appropriate amount
Total 100.0

(1) to (7) were uniformly dispersed. This oily composition (external phase) was transparent and had a hardness of 30.

Production Example 8 Oil-in-water emulsified composition component blending amount (% by mass)
(1) Squalane 2.0
(2) Cetyl 2-ethylhexanoate 0.5
(3) Self-emulsifying glyceryl stearate 0.5
(4) Sorbitan oleate 0.3
(5) Polyoxyethylene stearyl ether 0.3
(6) Natural vitamin E 0.05
(7) Ceramide 3 0.05
(8) 1,3-butylene glycol 6.0
(9) Glycerin 5.0
(10) Dipotassium glycyrrhizinate 0.1
(11) Carboxyvinyl polymer 0.15
(12) Potassium hydroxide appropriate amount (13) Phenoxyethanol appropriate amount (14) Paraben appropriate amount (15) Purified water remaining amount (16) Bengala-coated mica titanium 0.5
(17) Mica titanium 1.0
(18) Mica 2.0
Total 100.0

(Production method)
To (1) to (7) uniformly dispersed, (8) to (15) uniformly dispersed were added and uniformly dispersed. Thereafter, (16) to (18) were added and uniformly dispersed. This oil-in-water emulsion composition was yellow and had a viscosity of 1500 mPa · s.

(Effectiveness test method)
1. Stability Samples were stored in a thermostat bath and a room temperature of 50 ° C., 40 ° C., −5 ° C., 40 ° C. to −5 ° C., respectively, and the appearance change after one month was evaluated according to the following evaluation criteria.
(Evaluation criteria)
○: The three-dimensional pattern was stable under any conditions.
X: A change was seen in the three-dimensional pattern under any of the conditions.

2. Usage Test A usage test was conducted with 10 specialist panels, and each of the evaluation items of visual beauty (aesthetics) and emollient effect was evaluated based on the following evaluation point criteria. Subsequently, the evaluation points given by each person were totaled and evaluated based on the following evaluation criteria.

(Evaluation criteria)
5 points: Excellent.
4 points: Excellent.
3 points: Normal.
2 points: Inferior.
1 point: Very inferior.

(Evaluation criteria)
A: The total score is 40 points or more.
A: The total score is 30 points or more and less than 40 points.
Δ: The total score is 20 points or more and less than 30 points.
X: The total score is less than 20 points.

[Examples 1-4, Comparative Examples 1-3]
A transparent glass bottle was filled with the composition of any of Production Examples 1, 6, and 7 (oil composition (external phase)) having the blending amount shown in Table 1. Next, a filling nozzle (thin tube) for discharging any of the compositions (inner phase compositions) of Production Examples 2 to 5 and 8 having the blending amounts shown in Table 1 into the oily composition (outer phase) is provided. From the top of the container to the bottom of the container. Next, the inner phase composition was discharged from the nozzle while rotating the container to raise the nozzle to obtain a composition in which the three-dimensional pattern inner phase composition was formed in the outer phase. The evaluation results of the composition are shown in Table 1.

  As is clear from Table 1, all of the compositions of Examples 1 to 4 have a stable spiral pattern formed in the oily composition (external phase), and have a beautiful beauty (aesthetics) and emollient. It turns out that it is a composition excellent in the effect.

  On the other hand, the composition of Comparative Example 1 in which the viscosity of the inner phase is low is inferior in the stability of the spiral pattern, the visual beauty (aesthetics), and the composition of Comparative Example 2 in which the hardness of the outer phase is low. In addition, the composition of Comparative Example 3 is inferior in the stability of the spiral pattern, the visual beauty (aesthetics), the emollient effect, and the hardness of the outer phase is high. ), The emollient effect is inferior, and none of the effects of the present invention can be exhibited.

  In addition, the compositions of Examples 1 to 4 are applied to makeup cosmetics such as under makeup and lip gloss, skin care cosmetics such as massage creams, packs, essence creams, and eye creams, and hair care cosmetics such as hair waxes. Application was possible.

[Examples 5 to 9]
Table 2 shows the formulation of the oil-based composition (outer phase) according to the outer phase of Examples 5 to 9 and Table 3 shows the formulation of the inner phase composition according to the inner phase of Examples 5 to 9 and the state of the system. From the components shown in Table 2 and the oily composition (outer phase) obtained from the blending amount, and from the components and the internal phase composition obtained from the blending amounts shown in Tables 3 to 6, the oily composition (outer phase) contains A composition in which the phase composition was dispersed in a three-dimensional pattern was prepared according to the methods of Examples 1 to 4. In addition, the compounding quantity of the internal phase of the Example was as follows in all the compositions. Example 5: 5.0 mass%, Example 6: 15.0 mass%, Example 7: 10.0 mass%, Example 8: 40.0 mass%, Example 9: 1.0 mass%. The evaluation results are shown in Table 7.

In Table 2,
(Note 1) KSG-44 (manufactured by Shin-Etsu Chemical Co., Ltd.) is blended (the blending amount is the blending amount of KSG-44), and the blending amount of (vinyl dimethicone / lauryl dimethicone) crosspolymer is 30% by mass in KSG-44. is there.)

  As is apparent from Table 7, all of the compositions of Examples 5 to 9 according to the present invention have a stable spiral pattern formed in the oily composition (external phase), and have a beautiful appearance (aesthetics). ), An emollient effect. In addition, the compositions of Examples 5 to 9 are used for make-up cosmetics such as under makeup and lip gloss, skin care cosmetics such as massage creams, packs, essence creams, and eye creams, and hair care cosmetics such as hair waxes. Application was possible.

Claims (5)

In a composition in which the inner phase is dispersed in a three-dimensional pattern in the outer phase, the outer phase contains a liquid oil component and an oil gelling agent composed of a dextrin fatty acid ester or a (vinyl dimethicone / dimethicone or alkyl dimethicone) crosspolymer, and a rheometer measurement value Is a transparent gel-like oil composition having a hardness of 10 to 25 (measurement conditions: sample temperature 25 ° C., flat plate diameter 10 mm, penetration speed 6 cm / min, penetration length 20 mm) , and the inner phase is a three-dimensional pattern in the outer phase. The following (A) to (B) in which the viscosity of 0.1 to 50% by mass in the total amount of the composition dispersed in the state is 2000 to 20000 mPa · s ;
(A) An opaque oil-in-water emulsion composition in which a colorant having a water phase component content of 50 to 99% by mass in the total oil-in-water emulsion composition is dispersed .
(B) contain a liquid oil component and an oil gelling agent, in the outer phase, wherein the color material 0.001% by weight oily total composition is either opaque oil composition dispersed A composition in which the internal phase is dispersed in a three-dimensional pattern . The composition in which the inner phase is dispersed in a three-dimensional pattern in the outer phase according to claim 1 , wherein the outer phase contains an oil gelling agent comprising a liquid oil and a dextrin fatty acid ester or (vinyl dimethicone / dimethicone or alkyl dimethicone) crosspolymer. and, rheometer measurements by hardness 10-25 (measurement conditions: sample temperature 25 ° C., the flat plate diameter 10 mm, approach speed 6 cm / min, the penetration length 20 mm) was transparent gel oleaginous composition, internal phase in the external phase The content of the water phase component having a viscosity of 2000 to 20000 mPa · s in the total amount of the composition in which the internal phase is dispersed in a three-dimensional pattern is 50 to 99% by mass in the oil-in-water emulsion composition. 2. The composition in which the inner phase is dispersed in a three-dimensional pattern in the outer phase according to claim 1, which is an opaque oil-in-water emulsion composition in which the coloring material is dispersed . The composition in which the inner phase is dispersed in a three-dimensional pattern in the outer phase according to claim 1, wherein the outer phase contains an oil gelling agent comprising a liquid oil and a dextrin fatty acid ester or (vinyl dimethicone / dimethicone or alkyl dimethicone) crosspolymer. And a transparent gel-like oil composition having a hardness measured by rheometer of 10 to 25 (measurement conditions: sample temperature 25 ° C., plate diameter 10 mm, approach speed 6 cm / min, approach length 20 mm), and the inner phase is in the outer phase The total amount of the composition in which the internal phase is dispersed in a three-dimensional pattern contains a liquid oil component having a viscosity of 2000 to 20000 mPa · s and an oil gelling agent in a total amount of 0.001 to 0.001 in the total amount of the oily composition. 2. The composition in which the inner phase is dispersed in a three-dimensional pattern in the outer phase according to claim 1, wherein the composition is an opaque oily composition in which 30% by mass of a coloring material is dispersed . 4. The composition according to claim 3, wherein the oil gelling agent contained in the inner phase is a dextrin fatty acid ester. The composition in which an inner phase is dispersed in a three-dimensional pattern in the outer phase according to any one of claims 1 to 4, wherein the composition is a cosmetic in which the inner phase is dispersed in a three-dimensional pattern in the outer phase .